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By B. McFadzean, J. Taguta

The enthalpy of immersion is the heat change arising from the replacement of the solid-gas interface with the solid-liquid interface when a solid surface is immersed in a liquid. Although immersion calorimetry has been established as a valuable and reliable means of determining solid surface properties such as wettability, it has seldom been applied in mineral processing research. In this study, precision solution calorimetry was employed to measure the enthalpies of immersion of different minerals in water. The enthalpies of immersion were then related to the first-order flotation rate constant as determined by the microflotation technique. The same measurements were also made on sulphide minerals whose surfaces were modified to different degrees of hydrophobicity using different percentage coverages of amyl xanthate collector. The enthalpy of immersion technique was capable of distinguishing and ranking minerals according to their wettability. All mineral types and collector-treated minerals conformed to the same relationship that was found between the enthalpy of immersion and the flotation rate constant. This conformed, empirically, to a power law equation. As the enthalpy of immersion decreased, there were large increases in flotation response for very small changes in hydrophobicity. In addition, a critical enthalpy of immersion (CEI) was found, above which no flotation could occur. The scatter in the data points could be corrected for by adjusting the rate constant using the density of the minerals to produce a robust relationship between the rate constant and enthalpy of immersion. These results have shown that the enthalpy of immersion is able to indicate both the natural mineral hydrophobicity and the extent to which collectors can render a mineral hydrophobic. This technique has considerable potential to be used as a sensitive and accurate measure of mineral surface wettability in order to predict flotation performance.

Jan 1, 2018

By G. W. Zhang

Ultra-fine Stirred Mill is a kind of high energy efficient equipment for ultra-fine grinding, and has been the mainstream equipment in the submicron powder and slurry industry. This paper mainly describes flow-field numerical simulation of the three popular ultra-fine grinding mills: (respective-ly as) Disc Stirred Mill, Pin Stirred Mill and Spiral Stirred Mill, by means of the software Computational Fluid Dynamics (CFD). In the flow-field numerical simulation, the velocity gradient, shear rate dispersion of the flow-field, the viscosity dissipation rate were analyzed with CFD. It is discovered that Pin Stirred Mill has the highest velocity gradient in circular directions and the most homogeneous distribution of shear rate among the three. Flow-field numerical simulation provides a new way (and means to) for the parameter optimization design and project enlargement of Ultra-fine Stirred Mill. The experiments were also carried out, the results are consistent with the results of the simulation analysis. For example, in GCC grinding experiments under the same conditions, the specific energy consumption of Pin Stirred Mill with 3600L in volume is 15%~17% less, and its processing capability is 13%~15% better than Disc Stirred Mill. Now with its optimized structure and excellent performances, more than ten sets Pin Stirred Mill with 3600L in volume have been used in industrial production in Shandong, Guangdong and Hunan province.

Jan 1, 2014

By V. E. Vigdergauz

The work presented shows results of electrochemical study of pyrite hydrophobicity evaluated by air bubble induction time (IT) measurements. On the basis of measured IT?s an average thickness of the thin liquid film prior to its rupture has been evaluated, which confirms long-range character of the interactions between air bubbles and hydrophobic surfaces. Obtained data are discussed in the frame of recent studies of structures of solid-liquid interface based on molecular dynamics simulations and results of surface force measurements.

Jan 1, 2014

By Silvia Serranti, Giuseppe Bonifazi, Roberta Palmieri

The possibility to develop an efficient recovery and reuse of concrete materials from Demolition Waste (DW) represents one of the main targets applied to end-of-life constructions dismantling/recycling. The need to recycle end-of life concrete materials is strongly increasing in these last years for several reasons: i) the decrease of steady supplies of good quality natural aggregates, ii) the need to secure ample supplies of concrete aggregates to the construction industry and, finally, iii) the environmental constraints limiting the DW wastes disposal. The fulfilment of these goals produces several benefits, that is: i) a reduction of new resources consumption, ii) a strong reduction of the costs linked to transport and energy production, iii) the possibility to utilize materials, otherwise lost (e.g. land filled), iv) land preservation and, finally, v) the reduction of the environmental impact of new exploitation activities. A lot of efforts have been addressed to develop, set-up and apply innovative technologies to maximize DW conversion into useful secondary raw materials. The possibility to utilize efficient, reliable and low cost analytical tools to perform detection/control actions: i) to assess concrete characteristics, before demolition, and ii) to detect the presence of contaminants in coarse aggregates (e.g. bricks, gypsum, steel, glass, plastics, wood, etc.) represent the key issues to fulfil in order to develop innovative process/control actions/procedures inside the DW sector. In this paper a new technology, based on HyperSpectral Imaging (HSI) sensors is investigated to develop suitable and low cost strategies finalised to define and implement innovative smart detection engines for sorting and/or DW flow stream quality control, addressed to perform recovered materials and/or products certification. The proposed sensing architecture is fast, accurate, affordable and it can strongly contribute to bring down the economic threshold above which recycling is cost efficient.

Jan 1, 2014

By M. Niinae

Electrokinetic soil remediation by electroosmosis and ionic migration is restricted to soluble sub-stances. At a higher pH, the soil particles sorb more heavy metals, such as cadmium, than at a lower pH and the precipitation reactions of heavy metals are promoted. Both mechanisms make heavy metals immobile, rendering clean up more difficult and electrokinetic extraction inefficient. There-fore, the acidification of soils is very important to increase the clean up efficiencies of heavy metals, such as cadmium by electrokinetic method from contaminated soils. In the present study, acidification of soils and cadmium transport are predicted with a numerical method in which electrical flow is coupled with hydraulic flow, and the sorption process in the soils is induced in the model. The effects of some factors such as electrode configuration, electric field strength and electrode spacing for saturated soils are investigated using this numerical model. The results obtained this study are summarized as follows: The two-dimensional electrode configurations containing cathode surrounded by three or more anodes rapidly acidify the soils and remove cadmium from soils compared with one-dimensional electrode configuration. However, two-dimensional electrode configurations develop spots of inactive electric field between cathodes. A larger electrode spacing increases the processing time required, and it was also found that a larger electric field strength reduced the processing time required.

Jan 1, 2014

By Gianni Shena, Francesco Montanari

"Recent improvements in the resolution of X-ray computed tomography (CT) make it a promising alternative to traditional time consuming, error prone laboratory procedures for mineral liberation analysis, such as heavy liquid fractioning and measurements on polished sections. All indications are that in a few years CT will be well-established in many laboratories as a rapid technique for accurate liberation studies. In this scenario it would be able to provide liberation spectra or washability data in tens of minutes following sampling. However, although CT is a fast evolving technology, its on-line application is unlikely in the foreseeable future.Dual-energy (DE) radiography is another X-ray technique originating from non-destructive evaluation (NDE) and medical fields, which allows retrieval of the volumetric content of valuable components from two-phase particles in a fraction of second. Two radiographic images at different X-ray energies of a single particle or a monolayer of particles are taken in short time sequence. The thickness of the two phases is calculated particle by particle by image subtraction, whereupon particle grades can be derived. The development of the method for on-line applications requires the presentation of non-overlapping particles in the gap in the X-ray source detector measurement couple. Straightforward extension of the principle to multiphase systems is not possible. The paper reviews the state of the art of these two techniques as applied to mineral liberation problems."

Jan 1, 2003

By Ajay K. Jha1

Drilling and Blasting are two important unit operations in the production cycle of a mine and a strong link exists between these two and other unit operations/subsystems like loading, transportation, and crushing. Under the present concept of ? Mine to Mill?, it is important to optimize the drilling and blasting operations by applying scientific approach to drilling and blasting using sophisticated instruments and new technologies, which depends heavily on Information technology (IT) to meet this imperative. Development of innovative models and software has lead to blast optimization process. Till date, the blast results are evaluated in terms of available empirical approaches like powder factor, which are too simple to exclude some key parameters or lack in providing reliability because of non-availability of user friendly IT enabled techniques. Although with the help of developed approaches, formulation of user-friendly software to assist the site engineers in effective post blast assessment has started but there is a dearth of holistic approach to design an optimum blast considering the techno-economic feasibility of the subsystems and the geo-mining conditions to achieve blast optimization. The science of IT enablement in drilling and blasting is capable to build innovative models for achieving blast performances which will be doped with productivity, economy and safety with due regard to environment. The present paper discusses the use of existing IT enablement in various mines of India citing the Indian scenario and the future requirements for achieving the techno-economics in overall mining operations.

Sep 1, 2012

By B. Csoke

The Bond and the Hardgrove methods are widely used for the determination of the material?s grindability. Generally, the determination of the Bond work index of inhomogeneous materials can be carried out with high deviation using the conventional apparatuses and methods, because of the highly different grindability of components. This is more significant when the composite cement?s grindability is measured, which highly affects the design and operation of cement grinding mills. A possible solution can be the combined application of the Bond-method with the determination of the component?s weight ratio in the product and perform the Bond measurement until the steady state conditions of grindability coefficient (G) and chemical composition of the components are reached. To prove the applicability of the above mentioned idea systematic Bond and Hardgrove grindability tests were carried out of two phase composite materials. The experimental results showed that the application of the combined procedure is proven in order to have a more accurate and reliable calculation of the Bond work index of composite materials, especially when the components have significant difference in the grindability and concentration. The measurements also showed the possibilities and limits of the grindability test methods.

Sep 1, 2012

By S. Banisi, A. Ghasemi, S. Zare, F. Ghorbani, E. Nematollahi

"Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Working at the maximum operating capacity of comminution equipment plays a significant role in the efficiency of the circuit. Appropriate design of cone crusher feed box could result in the choked crushing which is known as a vital factor in achieving target performance. In this research, the non-uniform cone crusher feeding at the Sarcheshmeh copper complex was studied and appropriate measures were taken to solve the problem. The problem resulted in non-uniform and high wear rate of crusher liners and high fluctuations of power draw. In recent decades, the discrete element method (DEM) has been applied successfully to study the effect of different factors on the behavior of particles flow. In this work, various designs for feed box were tested using an in-house developed DEM software called KMPCDEM©. The best feed box design obtained from the simulations was selected, constructed and installed in of the cone crushers. The new feed box design resulted in more uniform feed distribution on the distributor plate of crusher indicated by a reduction of the standard deviation of power draw measurements from 13 to 3 kWh. The better control of the crusher, 49% increase in the crusher throughput and finer and narrower product size distribution were the main outcomes of the installation of the new feed box. Furthermore, the wear rate on mantle and liners of crusher not only decreased but it also became uniform.INTRODUCTION Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Reaching the maximum operating capacity in comminution equipment is a key sign of approaching the nominal productivity of the process. Due to the effect of crusher efficiency on the downstream circuit performance, optimization of the crushing circuits has received considerable attention (Herbst, & Potapov, 2004; Quist, & Evertsson, 2010; Li, Huiqi, McDowell, Glenn R, Lowndes and Ian, 2014; Cleary, Sinnott, Morrison, Cummins, & Delaney, 2017). Improving the performance of crushing circuits not only decreases the capital and operating costs but also increases the efficiency of downstream grinding circuits (Jacobson, Janssen, & Urbinatti, 2010). In cone crushers particles can be subjected to two different modes of compressive breakage; single particle breakage (free feeding) and inter-particle breakage (choked feeding). The maximum efficiency of the cone crusher directly depends on the type of feeding arrangement (Operation Manual, 1977). An appropriate feeding must lead to choked feeding the cone crusher. If the rate and method of feeding the crushers are correctly be executed, the maximum efficiency of the crushers could be available (Jacobson et al., 2010)."

Jan 1, 2018

By Leena Vesa, Antti Remes

Design of thickeners is based on laboratory test work, characterizing the material and determining the optimal reagents, dosages and settling regimes. Several methods for dimensioning plant scale equipment exist. Kynch and Talmage-Fitch design procedures has been applied widely for a long time. Nowadays, besides them, a dynamic laboratory test work is applied for design of high rate thickeners. In that the laboratory unit is operated with known solids load per area, feed and flocculation conditions and with raking of the underflow. All these test methods afford useful data for setting up and calibrating a dynamic simulation model of a plant scale thickener. This paper presents a flocculation kinetics based dynamic thickener simulation model and a procedure to calibrate the model parameters. With the model, the underflow stream composition can be simulated over time as a function of the thickener operating parameters, which are: the feed rate and composition, underflow pumping rate, flocculant dosage and dilution of the feed. In addition, the model incorporates calculation of the slurry bed level, the cone pressure, the yield stress and the rake torque. Such a dynamic modeling scheme enables setting up simulation aided operator trainings and developing and testing of advanced control strategies, for example. The unit model can be integrated as a part of concentrator-wide flow sheet simulation model as well. Here, calibration of the kinetic flocculation model based on a laboratory test case data and further the operation of a simulated plant scale thickener are presented.

Jan 1, 2014

By U. Ulusoy

Surface roughness and acuteness are known as the two of the main properties of the particle morphology affecting the behavior of the powders in the process. Since the techniques used for the morphological characterization of powders by 2-dimensional microscopic measurement from the polished sections that have some disadvantages, the 3-dimensional analysis has often relied on measurements of particle morphology. A review of literature data was presented for high-grade barite and pyrite particles ground by ball and autogenous mills to determine the morphological properties using a new 3-D approach based on BET nitrogen gas adsorption and Permaran methods. Micromeritics Flowsorb II 2300 instrument which employs BET nitrogen adsorption technique was used for the specific surface area measurements and the roughness of the particles. Permaran (manufactured by Outokumpu Oy) was used for the measurements of airflow resistance of powder samples for the acuteness. Spherical glass beads were used as reference sample for the acuteness measurements. The obtained parameters, which are surface roughness and acuteness, were corre-lated with the floatability performance of those mineral particles. The flotation performances of those particles ground in different mills (ball and autogenous) were also evaluated by a Hallimond tube. The results showed that lower roughness and acuteness values caused higher flotation recoveries for both barite and pyrite particles that were tested independently in different type of the mills. In other words; particles with smooth surfaces resulted in better floatability for barite and pyrite minerals studied.

Jan 1, 2014

By J. Sachweh

The last few years have shown a significant increase in the demands for fine products, which means everything under 10µm. There are more and more applications requesting extremely fine ground powders leading to the development of several milling machines which are better adapted to the new products. Cost saving machinery is important for the worldwide competition. Especially the energy consumption is extremely important for any fine ground product. A worthwhile field for mechanical engineering companies is the dry milling machinery as there are not as many solutions available compared with wet milling applications. In many cases wet mil-ling is the only solution to reach the requested quality, but there are also a lot of applications which can be performed in a dry way on the premise that the right mill and classifier are available. Dry milling permits to save energy and allows to influence the particle size distribution more easily, as a classifier can be used in that case. This will significantly reduce production costs and can enable the production of new products with better properties. The Tower Mill is well-known already in the field of wet grinding. Recent research work and end user reports have shown clearly that this mill has a lot of advantages compared to a ball mill. Up to now this advantage is limited to wet grinding as only few mills have been used for dry grinding. There is no doubt about the efficiency of dry grinding, but new and improved feeding and discharg-ing systems have to be developed in order to enable the full range of its advantages. Especially the high production capacities are a challenge for mill and classifier designers. The Tower Mill with its special grinding mechanism allows to cope with very high feed rates, because machines with more than 1 MW are available. Improved grinding efficiency will decrease the circulation load through the classifier and also lead to smaller classifier sizes. Together with im-proved mills the classifier can work more efficiently because the feed material is finer. Results of a test center plant production will be shown together with a comparison between stan-dard machinery and the MaxxMill®. Preferential applications for each mill will be explained.

Jan 1, 2014

By K. E. Waters, J. E. Nesset, F. Rosenblum, R. Langlois, J. A. Finch

"Some sulphide mineral mixtures when exposed to air and a warm and humid environment can exhibit a self-generating temperature rise, referred to as self-heating or spontaneous heating. The observed self-heating derives from the oxidation reactions of the active sulphides. In previous publications by the authors, it was proposed that the self-heating of sulphides proceed in three distinct stages; namely, Stage A, Stage B and Stage C. In Stage A (<100OC) the sulphides, in the presence of moisture are oxidized, generating heat through a series of sequential reactions and forming elemental sulphur as one of the products. In Stage B (>100OC) the elemental sulphur produced in Stage A is further oxidized to generate additional heat and SO2. Stage C (>~380OC), sometimes referred to as thermal runaway or roasting, is not addressed in this paper. This communication focuses on the type and role of elemental sulphur found in Stages A and B, and the sequence of reactions that is occurring in Stage A. The sequence is divided into two phases, the first based on galvanic interaction between the sulphide minerals that generates an acidic environment but little heat, and the second involving the production of H2S which rapidly oxidizes to produce heat and elemental sulphur. To date, data suggest that the primary oxidation product formed in Stage A is the stable orthorhombic a-S8 form of elemental sulphur. Above 96OC the a-S8 transforms to a monoclinic ß-S8 structure which is less stable and will readily oxidize to generate heat and SO2. Above 159OC a proportion of the ß-S8 sulphur will transition to a polymeric Sµ form of sulphur which can readily volatilize. INTRODUCTION Some particulate and granular materials, when exposed to appropriate atmospheric and physical conditions, can exhibit a self-induced temperature rise resulting from accumulated heat due to internal exothermic oxidation reactions. This phenomenon is commonly referred to as self-heating or spontaneous heating. Under favorable physical and environmental conditions, these reactions can elevate the temperature of a given material from ambient to the point of auto-ignition. Self-heating behaviour should not be equated to pyrophoric behaviour which describes a group of materials (e.g. certain finely powdered metals) that will ignite spontaneously in air below 55OC. There are numerous materials such as coals, hay, forestry wood products, food products to name a few that can exhibit self-heating behaviour. This publication continues the focus of the authors on the self-heating of sulphide mineral mixtures. Many of the metals of commercial use found in nature are in the form of these sulphides which must be mined, crushed, ground and concentrated prior to smelting or hydrometallurgical processing in order to produce primary metal. The issues of sulphide self-heating therefore pertain to the mining and processing of metals."

Jan 1, 2018

By V Radmehr

Ammonia and Amonium salts have been recognized as effective leaching agents in hydrometallurgical processes due to low toxicity and cost, easy recovery and high selective recovery of metals. New research findings of considerable advantages of leaching by these agents and elimination of problems associated with acid leaching has resulted in a new approach in the world to this method. The investigations in this field indicate more frequent use of this method for extracting copper from ore and concentrate relative to other basic metals. In this paper, we have attempted to describe the basis and different ammonia leaching methods and present the major research activities in this field for copper. We have also presented the latest findings and related novel processes. Comparative assessment of advantages and disadvantages of this method relative to acid leaching method, kinetic study of copper ammonia leaching and evaluation of Eh-pH diagrams in a system containing water and ammonia are other parts of our study. Finally, by describing the studies on copper extraction from the resulting pregnant solutions, the applicable extraction agents have been reviewed.

Sep 1, 2012

By Luís Marcelo Tavares, Juliana Segura

Comminution is one of the most energy consuming stages in a mineral processing plant. This consumption is not only related to the power supplied to equipment, but also to the indirect or embodied energy, mainly associated to materials that are worn during operation, including grinding media and liners. Until recently, preparation of iron ores in Brazil did not use comminution intensively, given that plants mainly produced sinter feed, natural pellet fines, besides lump ore. However, with decreasing ore grades, size reduction now occupies a centre stage in nearly all new plants. Technologies used up to date for processing low-grade iron ores in Brazil, in particular itabirites, have consisted of three or four stages of crushing followed by ball milling. A number of new plants are either being built or are currently being designed that will process the same type of ore, so that engineers are investigating alternative comminution routes. The paper analyses comparatively four comminution routes for processing a particular itabirite ore, many of which using technologies and layouts that have not yet been used in such application. Using data from bench scale and/or pilot-plant tests, the different routes are compared on the basis of sustainability principles in accordance to the Brazilian energy matrix, which is quite particular. It is concluded that if the sustainability criterion is used, then the optimal route would correspond to a circuit that uses HPGR technology with truncated feed followed by ball milling. Given the particular case of itabirite iron ores and specially to the one in the present work and the source of Brazilian energy, it is evident that indirect energy expenditure in comminution plays a significant role in greenhouse gas emissions when compared to direct energy, being the reason for the great attractiveness of HPGR technology. Evidently that these will have to be balanced against CAPEX, OPEX, NPV and other qualitative criteria, which can certainly lead to a different optimal circuit.

Jan 1, 2014

By Mahdi Shevrini, Hamed Haghi

"In this research, the operation of screen classifying in silica processing circuits was investigated and modified by replacement of available trommel screens with teetered bed separator (TBS). In addition the effect of the mentioned replacement and addition of attrition scrubber on quality of final product, impurities removal, recovery and production rate were inspected. Considering screen efficiency problems to achieve certain particle size distribution, hydraulic classifying system was selected instead of trommel screens. Application of suggested plan improved quality and particle size distribution of produced silica significantly. Optimization of size classification in process circuit resulted in increase in production rate up to 21% (from 67% to 81%), silica recovery (from 68.35% up to 83.11%) and relative enhancement in removal of impurities such as Fe2O3 and TiO2. After optimization and stabilization of grinding and size classification section, industrial attrition scrubbing tests were carried out and the best solid percent and retention time were determined i.e. 70% and 6 minutes, respectively. Using sodium carbonate during attrition scrubbing, has major effect on removal of surface coating and staining especially sharp increase in clay removal; therefore 2 kg/t of sodium carbonate can be optimistic point of industrial procedure for this silica processing plant. It should be mentioned that application of attrition scrubbing which is followed by screw classifier for de-sliming were useful for better cumulating of particles in the range of appropriate liberation degree (+106-300µm) and efficient removal of metallic (iron and titanium oxides) and non-metallic (clays and feldspars) impurities."

Jan 1, 2014

By Richard A. Williams

The mineral processing community have been amongst the pioneer developers and early adopters of key platform technologies in analytical methods, chemistry, physical separation and advanced modelling. Fundamental research will continue to have a significant impact driven by the continued development of sustainable practices. Major drivers and challenges for change in our industry in the next two decades include: reduction in energy uses in processing; discovery of new energy materials; adoption of green chemistry routes; safeguarding of water resources; and demonstration of adherence to best practice at all times. With increasingly global mining enterprises, the provision of internationally accepted benchmarks for performance will continue to drive the creative process. This lecture highlights major opportunities around a new paradigm of Multi-scale Measurement coupled with Multi-scale Modelling, based on advanced sensors, communications and computing. Connecting real-time measurement sensors with dynamic simulation models opens up new horizons for visualising the process behaviour from an experimental and theoretical basis. Examples are given of the potential of this methodology and its implications for better design.

Jan 1, 2003

By Zhiyong Gao, Ruiying Fan

"Crushing and grinding are the prerequisite processes in many industries, such as minerals processing and powder technology. During crushing and grinding, minerals will cleave or fracture along the directions by broken the interlayer bonds (e.g., ionic bonds), generating some commonly exposed surfaces. The broken (or dangling) bonds at the generated surface makes the surface more active and determine the reactivity of the surface. In this work, the population of broken (or dangling) bonds on commonly exposed surfaces of fluorite mineral (a chosen model mineral) was calculated. Based on the calculated broken bonds information, the anisotropic surface reactivity of fluorite such as surface energy, surface relaxation, dissolution, wettability, surface charge and adsorbability, were discussed. The results show that the surface broken bonds density, which is positively related to the surface energy, can be used to predict the cleavage nature, surface relaxation degree and surface stability of fluorite crystal. The distribution characteristic and the number of broken (or unsaturated) bonds of surface active atoms (like Ca for fluorite crystal) can be used to predict and explain the anisotropic wettability, surface charge and adsorption mode and strength of organic molecules on different commonly exposed surfaces. It is easy to conclude that the calculation of surface broken bonds can serve as a fast and accurate way to start the mineral chemistry studies. These findings will be helpful to the mineral/material chemistry research in related interfacial science communities.INTRODUCTIONGrinding for mineral liberation is a prerequisite for a successful flotation separation. Also grinding for size reduction is a prior process for a favorable powder technology. During the grinding process, the minerals / materials will cleave and fracture along certain crystal directions with relatively weak interlayer chemical bonds1 to form a number of common exposed surfaces. Exposed surfaces are the outer boundary of a solid substance. In the mineral / material block, the bonding orbital of the atoms is filled with electrons and the atoms are in a steady state. Atoms on these exposed surfaces appear to show dangling bonds (or broken bonds) by losing chemical bonds to adjacent atoms in the previous block. Therefore, surface broken bonds serves as an initial property of a fresh surface. The lattice arrangement and crystal orientations causes differences in the number of dangling bonds on each exposed surface, i.e., anisotropic surface broken bonds2. The anisotropic dangling bonds enable the exposed surfaces to show varying degrees of surface reactivity (including surface energy, surface charge, surface relaxation, dissolution, wettability and adsorption behavior), known as anisotropic surface reactivity."

Jan 1, 2018

By D. Szyszka

During passing gas bubbles through mineral suspensions, some mechanical carryover of fine particles to the froth layer always takes place. The entrainment of mineral particles is influenced by many parameters, mostly by the particle size and the concentration of the frother. The paper deals with influence of selected frothers (methylisobutylcarbinol (MIBC), a-terpineol, and hexadecane tricosaethyleneglycol ether (C16E23)), common laboratory flotation frothers, on the mechanical car-ryover of quartz, a typical gangue mineral component of ores. Entrainment tests were carried out in a laboratory Mechanobr flotation machine with quartz particles suspended in aqueous frother solu-tions. The mechanical recovery of quartz in the presence frother was increasing with time and reached plateau after about 20 minutes of flotation. The plateau level of quartz recovery depended on the frother concentration. Initially an increase of the plateau with frother concentration was observed until the plateau reached the highest level called the maximum recovery emax. The emax can be used as a parameter to characterize the ability of frothers to entrainment. In the studied quartz-frother flotation system the maximum entrainment was 32%, 50% and 80% for methylisobu-tylcarbinol (MIBC), a-terpineol, and monohexadecane tricosaethylene glycol ether (C16E23), re-spectively. A comparison of the maximum entrainment factor emax with other, known from literature, indices such as bubble critical coalescence concentration (CCC), dynamic foamability index (DFI), Jw, e =25%revealed, except DFI, their similarity.

Jan 1, 2014

By Q. W. Jiang

This paper presents a new process for producing industrial magnesium sulphate using waste water from titanium white plant and magnesium oxide from calcinations of magnesite ore as raw materials. With the laboratory experimental equipment, the waste liquid and magnesium dioxide react effectively at ambient temperature and under atmosphere pressure. Via the press filter, a clear liquid predominately containing magnesium sulphate is obtained. It is further evaporated and crystallized by cooling, separated by centrifuge and dried. Consequently a high quality of industrial magnesium sulphate is achieved as the final product. In the course of process, as the majority of valuable component (SO42-) is recovered in the final product, most of impurities from waste acid is being removed into the by- product. With the simple operational process, it is possible for titanium dioxide plant to resolve the environmental problem completely and benefit from the industrial magnesium sulphate product as well. The filter cakes containing valuable elements such as Mg, S, Fe, Mn, V, Ti are by-product proposed to be used for manufacture of agriculture fertilizer particularly for peanut planting.

Jan 1, 2014