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By D. S. Flett, A. V. Tolstov, M. A. Mulagaleeva, N. V. Gudkova, A. M. Zhizhaev, V. I. Kuzmin, Institute of Chemistry and Chemical Technology SB RAS, O. A. Logutenko, V. N. Kuzmina

The complex niobium-rare earth pyrochlore-monazite-crandallite ores of the Tomtor deposit, located in the Siberian Arctic, should be considered as a new type of rare metal materials. The major valuable components of the ore are niobium, rare earth elements, yttrium, and scandium; associated components are titanium, vanadium, aluminum, and phosphorus. Because of the irregular distribution of the rare earth metals and niobium according to grain-size, the extremely finely dispersed nature of the minerals and their close interpenetration to each other, ore processing by gravitation and flotation is not successful. The processes studied for the treatment of the Tomtor ores use direct alkaline-acid leaching to open the ore. A problem in the first stage of alkaline leaching is the high aluminum content, which decreases the activity of sodium hydroxide and alkaline-earth metals, which are bound to phosphorus. Ore processing using alkaline-nitrate and alkaline-chloride leaching was proposed and investigated. The first variant was used to obtain rare earth and scandium materials and a niobium-titanium concentrate, which can be a stock material for processors who use chlorination for the processing of ores and concentrates. The second variant is a complex advanced ore processing scheme with electrochemical regeneration of the waste chloride solutions obtaining sodium hydroxide, hydrochloric acid, and chloridizing agents. Moreover trisodium phosphate is used for purification of the waste mother liquors from metal cations. The complex salt, NaAlCl4, is proposed as the chloridizing agent for the decomposition of the niobium-titanium concentrate.

Jan 1, 2016

By A Hitchen

A general outline is given for the determination of copper, nickel, cobalt, zinc, lead, cadmium, bismuth, manganese, uranium, molybdenum, vanadium, sulphate and fluoride by polarographic or amperometric methods in a variety of ores or metallurgical products. The detection of oxygen in gas mixtures by an amperometric method used as a safety device is also discussed. Introduction I N this paper, a general outline will be given of the polarographic and amperometric methods used for the chemical analysis of various ores and metallurgical products in the Chemical Analysis Section of the Extraction Metallurgy Division of the Mines Branch. The methods to be discussed will be confined to those based on the use of normal D.C. polarography and will not include those methods which utilize a cathode-ray, square wave, pulse or A.C. type of polarograph. For the sake of convenience, ? the polarographic methods will be discussed according to the type of supporting electrolyte employed, as the same electrolyte may serve to determine more than one element in more than one type of ore. Amperometric methods will be discussed according to the element to be determined rather than

Jan 1, 1965

By D. Song

In this paper, the differential equations governing the mass transport and the electrochemical reaction in a cathode catalyst layer of polymer electrolyte membrane fuel cells are solved based on the polynomial series expansion method. Explicit expressions for the polarization curve as well as for the distributions of oxygen, current density and overpotential are obtained when a quadratic, cubic or quartic polynomial is employed to approximate the oxygen concentration distribution. These kinds of explicit solutions are desirable for MEA design and diagnosis purposes. The comparison between the conventional numerical approach and the explicit solution approach proposed here shows that satisfactory accuracy can be reached by the first four terms of the polynomial series. The effect of the catalyst layer thickness on the accuracy of the obtained explicit polynomial solutions is also discussed.

Jan 1, 2005

By A. McLean, Q. R. Yang, Y. D. Yang, G. F. Zhang, P. Wu

A considerable amount of waste slag from the pyrite roasting process is discharged every year. Recovery of iron from the waste slag is of great interest for comprehensive use of mineral resource, reduction of environment impact and improvement of economical benefit to related companies. The objectives of the present work are focused on: (1) Compare various procedures for recovery of iron from the waste slag and select a best procedure for industrial trial which is roasting of the waste slag under reducing condition followed by magnetic separation; (2) Investigate the optimum conditions for maximum recovery of iron from the waste slag. The experimental result shows that under the treatment condition found in this work about 36 to 40% of the iron oxide was recovered from the waste slag, where the iron content in the concentrate is 57%. The total recovery ratio of iron, up to 70%, from the waste slag was achieved. After the treatment, sulphur content in the waste slag was reduced significantly and gangue materials, such as SiO2, Al2O3 and TiO2, were reduced effectively.

Jan 1, 2011

By M. H. Kotze, V. Yahorava

A gold-selective ion exchange resin, containing tributylamine groups, was developed by Mintek for the recovery of gold from cyanide leach solutions. The Dow Chemical Company and, more recently, Purolite commercialized the production of this gold selective resin for use in the gold mining industry, and it is marketed as Dow XZ-91419.00 and Purolite A194 respectively. A novel application of this resin is the selective recovery and separation of AuCl4 - f rom p latinum group metals (PGMs) in chloride and nitrate solutions. The current paper describes potential benefits of this type of resin for selective recovery and upgrading of gold from low grade chloride or nitrate waste streams, and the possibility of gold separation from PGMs during their refining in chloride media.

Jan 1, 2014

By M. Sanchez

In the last decades, the Chilean copper mining and metallurgical industry have had to modify their technological processes to meet the environmental regulations implemented by the Chilean government, and also to support the pressure of the public opinion. Thus, air quality standards for sulfur dioxide and particulate matter (primary and secondary), plans for reducing emission of arsenic by the Chilean copper smelters, effluents discharge limits, among others regulations were applied by the environmental agency. Additionally, agreements on cleaner production were carried out by mining sector and government. Now, a draft law on mine closure, and another on environmental mining wastes (abandoned mines) are being discussed by the authorities and the mining sector. In the context, production and environmental impacts in different ways to produce copper in the Chilean mining industry are reviewed and regulatory tendencies as well as abatement technologies today used are exposed and discussed in this presentation. Pyro, hydro and electrometallurgical processes employed and their current effluent and contaminants are presented showing various alternatives of treatment in the copper industry. An update of regulations established in Chile vis a vis copper production, with an especial attention to mine closure are also presented.

Jan 1, 2007

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By J. D. Bosman, L. J. Gardner

"The Bushveld Complex is a large layered igneous intrusion, located in the northern parts of the Republic of South Africa. The complex hosts the largest known reserves of Platinum Group Metals in the world. On the western limb of the complex, mining of the Merensky economic horizon and UG2 chromitite layer has been conducted for many years by several mining companies, including Impala Platinum Limited. Over the past decade, Impala has planned a new generation of greenfield vertical shafts, commencing with comprehensive geological and geotechnical studies. As part of the geotechnical studies, numerous tests have been conducted to quantify the mechanical properties of the various near-reef rock types. These tests include point load tests conducted in the field, as well as uni-axial compressive strength, triaxial compressive strength, and Brazilian disc tensile strength tests conducted in specialist laboratories. The authors have compiled an extensive database containing a large number of tests for different rock types, ranging from felsic Anorthosite to mafic Pegmatoid. The database was analysed to quantify the mechanical properties and values for Mohr Coulomb and Hoek Brown failure criteria for each rock type typically exposed by mining. The paper will provide a data set of rock mechanical properties typically used in numerical modelling and other design processes. Using the significant number of tests available, data describing the variability of the various parameters will be included."

Jan 1, 2015

By A. M. Elmahdy, T. Hirajima, M. Farahat

"Separation of molybdenite from chalcopyrite is mainly achieved through flotation technique to raise their grades up to 25% to be extracted in smelters. However, molybdenite recovery and grade obtained from this process is not satisfactory in most cases due to the natural hydrophobicity of both minerals. The influence of conventional heat treatment on pure chalcopyrite and molybdenite minerals was investigated. X-ray diffraction, TG-DTA and XPS techniques were applied before and after heat treatment. The results showed phase changes for both minerals. Magnetic separation experiments of single and mixture of both minerals at several magnetic intensities were made. For single mineral experiments, 100% molybdenite recovery was obtained at all experimental conditions as non-magnetic fraction whereas ca. 100% chalcopyrite recovery was achieved under certain conditions. In case of 1:1 binary mixture, 87% and 83% molybdenum and copper recoveries, respectively, were obtained. The increase in chalcopyrite magnetic recovery is related to the formation of more magnetic phases as confirmed by characterization techniques.The objective of this study is to increase the magnetism of chalcopyrite to make its separation from molybdenite by magnetic separation possible and to understand the mechanism behind it. These results indicate that it may be possible to upgrade molybdenite ores using heat treatment followed by magnetic separation to the required grade by smelters which is difficult to attain by froth flotation and the other techniques."

Jan 1, 2016

By T. Fekete, D. L. Flocks, R. T. Hart

The plugging effect of bacteria was investigated by injecting various concentrations of dead bacteria cells though sandstone cores. Pressure profiles along the cores were recorded periodically during the injection cycles. The plugging effect was analyzed using a plot of the ratio of reduced permeabilities to the initial permeability versus input volume. Results indicated that Tock permeability has little effect on plugging, but that the concentration of bacteria in the injection water has a significant effect on plugging characteristics. The pressure profile curves showed that bacteria penetrated several inches through the core but that the greater portion of the bacteria accumulated at the in-put end of the core.

Jan 1, 1960

By D. Roy Eccles

A multi-element geochemical response, with contrasts of up to 29 times background, was obtained in soil above the Mountain Lake Diatreme, northwestern Alberta. The overall geochemical signature is indicative of an ultramafic source; geochemical responses contain elevated concentrations of Co, Cr,O, Cu and Ni with the presence of high Ba, Ga, HI, PO,, Rb, Ta, Ti and light rare earth elements suggestive ofa kimberlite or lamproite body. The shape, or morphology, of the enzyme leach-based geochemical signature over the Mountain Lake Diatreme combines moderately strong to strong oxidation halos, or a rabbit's- ear geochemical profile, with a sharply-defined apical geochemical profile. Because some Alberta diatremes discovered to date form positive topographic highs, the resultant geochemical signature may express the soil development profile that forms directly on top of kimberlitic and lamproitic bodies. The enzyme leach technique, which has proven to be a useful tool in base metal, precious metal and petroleum exploration, may have a significant impact on exploration for kimberlite, lamproite and related rocks in Alberta by providing industry with a useful and cost effective tool to probe blind and/or buried anomalies identified by airborne and ground magnetic surveys in areas of glacial overburden.

Jan 1, 2001

By G. G. Richards, Y. Oyediran, V. Chow

The oxygen softening process for partial removal of arsenic and antimony from lead bullion has been in use at Teck Cominco's Trail smelter since 1986. In this process, industrial oxygen is injected into bullion to remove As and Sb with the formation of an oxide slag. In Trail, the levels of these elements are reduced to concentrations suitable for processing in the Betts electrorefining plant. Recent moves toward the treatment of higher arsenic-bearing feeds have necessitated an increase in the process capacity to meet the specifications for drossing plant bullion. Process intensification trials were conducted in-plant to develop an operating strategy for higher bullion processing rates. This was preceded by a study conducted with McGill University to develop a fundamental understanding of the therm ochemistry and kinetics of the process. The results have yielded more effective control of the operation, and identified opportunities for further improvements.

Jan 1, 2008

By H. A. Steane

THIS PAPER describes the re-grind section in the 2,000-ton per day, lead-zinc flotation mill of Canadian Exploration Limited, near Salmo, B.C. There are two re-grind units in operation, one in the lead circuit, and one in the zinc circuit. In each unit, the rougher concentrate is re-ground ahead of the cleaning circuit. These re-grind units have made valuable improvements in the concentrate grade, and with no loss in recovery by over-grinding galena or sphalerite. Since the initial installation of this re-grind section, the plant throughput has been increased gradually from 1,600 tons to 2,000 tons per twenty-four hours, and, as shown by the screen analysis of mill tailing, a coarser overall grind has been accepted, from 55 per cent to 45 per ?cent minus 200 mesh. There has been no increase in grinding capacity, but two mills have been taken from the main grinding circuit and used for the re-grind circuit.

Jan 1, 1958

By L. A. Mells

"A laboratory test program was initiated by the Department of Energy, Mines and Resources as part of the National Uranium Tailings Program to investigate the applicability of a radium selective ion exchange complexer for removing radium from Canadian uranium mining effluents. The test program was carried out by Melis Consulting Engineers Ltd. under contract to the Department of Supply and Services using the Saskatchewan Research Council facilities located in Saskatoon, Saskatchewan.The results of this work showed the ion exchange complexer, Dowex XFS 43230.00, to be efficient in removing radium from contaminated water of uranium mining operations with the ultimate loading capacity of the resin on one type of water treated being determined as approximately 1,600 Bq/cm3 of new resin. Although this resin has potential application for treatment of effluent streams in uranium operations it has been identified that the resin efficiency and capacity is directly related to the chemistry of the water being treated and site-specific testwork is required in order to establish reliable design data for full-scale operations.IntroductionThe possible applicability of a radium-selective ion exchange complexer for removing radium from Canadian uranium mining effluents had been identified and discussed as a possible alternative to present radium removal methods during a review of disposal technology options for the National Uranium Tailings Program of the Department of Energy, Mines and Resources(1). Work by other workers(2.3) had shown the complexer to be very efficient in removing radium from contaminated water. Also, plant trials on contaminated minewater at the Mt. Taylor uranium mine in New Mexico is reported to have shown the resin complexer to be efficient under plant operating conditions.As a result, a laboratory test program was initiated by the Department of Energy, Mines and Resources as part of the National Uranium Tailings Program to investigate the suitability of this resin for Canadian uranium mining effluents. The test program was carried out by Melis Consulting Engineers Ltd. (MCEL) under contract to the Department of Supply and Services using the Saskatchewan Research Council (SRC) facilities located in Saskatoon, Saskatchewan."

Jan 1, 1985

By D. D. Hogarth

"IntroductionThe Hull iron range, comprising the Forsyth, Scott , Baldwin and Lawless properties (Fig. I), is in Gatineau Park, on the outskirt s o f the city of Hull , and about 6 miles (10 kilometres) northwest of the Federal Parliament Buildings.The deposits have been known many years and described numerous times, although the history has been treated lightly in former publications. Total ore shipments have been calculated at 122,700 long tons, of which over 80% were mined before 1900 and 74% in two brief periods: 1870-74 and 1880-82. It is surprising that the period 1870-74 has been overlooked by most authors and 1880-82 ignored altogether. More surprising, the essential data for these two periods are contained in manuscripts of the Robert Bell collection, which must have been available to officers of the Geological Survey o f Canada.The period 1801-1874 ha s already been covered by the writer in ""Pioneer mines”, but much information has come to light since publication. The present paper is therefore based o n new data and a fresh appraisal. However, little additional data were found for the early history (1801-1854) or for the legal cases involving A.H. Baldwin, and these parts were mainly summarized from the relevant sections of the above-mentioned publication.GeologyThe ore deposits are all situated somewhat below the middle of a graphitic, calcitic marble horizon, here folded into a northeast-plunging synform. The Forsyth, Scott and Baldwin deposits are on the south limb of the synform; the Lawless is on the north limb. The marble is underlain by three non-carbonate groups: biotite gneiss with interlayered quartzite (top), granite gneiss and skarn (middle), and biotite-garnet gneiss (bottom). Below these groups is a lower horizon of graphitic, calcitic marble. The whole sequence is Precambrian and has been subjected to high-grade (Grenvillian) metamorphism, but, in the north, is cut by an unmetamorphosed Cambro-Ordovician diabase dyke. For further information, the reader is referred to the summary by Baird."

Jan 1, 1983

By N. C. Carter, Wm. H. White, J. E. Harakal

"Of twenty-one ore deposits in British Columbia which are either in production or advanced stages of exploration, five have potassium-argon ages in a range of 165-205 m.y., eight are in a range of 44-55 m.y. and the remainder are either ca. 140 m.y. or ca. 100 m.y. old. Deposits of the oldest group have generally similar geological environments and radiometrically indistinguishable ages of magmatic and hydrothermal minerals. Deposits of the youngest group also have similar geological environments, with successive magmatic and hydrothermal events closely intermingled in time and place. Such deposits find no comfortable home in existing classifications of ore deposits. 1t is suggested, therefore, that those epigenetic deposits which can be shown by radiometrie and/or geologie means to be coeval with genetically related magmatism be designated as ""paramagmatic deposits."""

Jan 1, 1968

By M. Sokoto, H. Hata, K. Nishina, K. Haiki

Fluoride ions in zinc electrolyte cause corrosion to aluminum cathode plates at zinc electrowinning process, so we have developed an iron compound as a fluoride ion adsorbent used in zinc sulfate solution. The iron compound is synthesized from FeC13 solution with a small amount of sulfate ion by neutralizing reaction with Na2CO3 solution. The fluoride ions adsorbed on the surface of the iron compound are desorbed in alkaline solution and the iron compound can be reuse as a fluoride ion adsorbent. Moreover, if adsorption capacity of the iron compound decreases, it can be dissolved in HCl solution and re-synthesized.

Jan 1, 2008

By R. Grau

"After commissioning and start-up of the first 500m3 TankCell® flotation cell in 2014, the over 300m3 mechanical flotation cells have earned their place in large-scale flotation operations. These 500 to 630m3 cells, designed for projects with large throughputs, are proven to provide savings in project capital and operational expenditure through savings in foot print, energy consumption, and less equipment to install and maintain. Addition to savings in different phases of a project, these cells provides operational flexibility and has shown improvements in metallurgical performance. In this paper a case study from Kevitsa TankCell® e500 installation and Buenavista del Cobre TankCell® e630 installations will be given.INTRODUCTION After development (Grönstrand and Bourke, 2008), characterization (Morales et al. 2009; Yanez et al. 2009; Grönstrand at al. 2009), validation (Elgueta et al. 2009; Coleman and Dixon, 2010), and more than 350 industrial installations of the Outotec TankCell® e300 flotation cell, the well proven energy efficient TankCell® product family introduced the TankCell® e500 forced-air flotation cell late June 2012 (Outotec.com, 2012). The introduction of the 500 m3 flotation cell followed by introduction of a 630 m3 flotation cell, TankCell® e630, in October 2014 (Outotec.com, 2014). These large flotation cells are designed for projects with high throughputs where the number of cells needed for operation with smaller equipment would become large. The benefits of this size of flotation cells comes from the lower capital expenditures due to lower equipment costs, savings in plant footprint, less installation work with less auxiliary equipment, lower energy consumption, and less units per installation resulting in less components, spare parts and maintenance.The first TankCell® e500 was commissioned and taken into operation in October 2014 at FQML Kevitsa Cu-Ni-PGE concentrator, nowadays owned by New Boliden. The first TankCell e630 was taken into operation in January 2018 at GrupoMexico’s Buenavista del Cobre Cu-Mo concentrator. The start-ups of the first TankCell® e500 and TankCell® e630 followed with test work where the hydrodynamic performances of the cells were characterized and metallurgical performance studied. The results of the TankCell® e500 test work were presented in detail by Mattsson et al (2015a; 2015b) and TankCell® e630 by Grau et al. 2018. In this paper the metallurgical improvements achieved with the large cell installations will be presented."

Jan 1, 2019

By K. D. A. Whaley

Abstract -The Captain North Extension deposit consists of five sulfide lenses hosted in cherty and chloritic metasediment that is bounded by quartz-eye rhyolite and laminated rhyolite . Lens 2 consists of sphalerite and galena with silver-rich tetrahedrite in chert. Lens 3 contains massive pyrite, with chalcopyrite and minor gold, gradational to minor pyrite in a chloritic metasediment . The other lenses are unexplored. The sulfides occur as beds, fracture infills, and disseminated grains. Reserves are estimated at 207 555 tonnes grading 7.38% Zn, 2.76% Pb, and 91.81 g/t Ag. The deposit is isoclinally folded, dips steeply west, plunges 50 degrees south, and is faulted out to the north, where drag folding has reversed the plunge. Minor cross-faults contain talc and sericite. High sphalerite but low pyrite abundances result in poor responses to standard electromagnetic techniques. Lens 3, which contains more pyrite than Lens 2, responds better to induced polarization and allows detection. Geochemical anomalies are found in a nearby swamp and stream, but an impervious till cover inhibits the development of soil anomalies.

Jan 1, 1992

By F. E. Senftle

Introduction The usual laboratory methods of uranium analysis are either tedious, time-consuming chemical procedures or elaborate physical methods requiring sensitive equipment. There is thus an urgent need for a method of estimating the uranium content of ore samples by approximate analysis in the field. When a new property is being developed, it is desirable to know, with the least possible delay, the uranium content of channel samples in order to guide the diamond drilling and digging operations. Prospectors, too, require approximate analyses of their hand specimens to evaluate their discoveries. To satisfy the demand for these types of analyses, several field procedures have been tried. Two general plans can be followed. One is fast but will yield only a rough estimate. The other is slightly longer but, if done carefully, will give an assay probably within 10 per cent of the true value. For field operation it is necessary to strip the more accurate laboratory methods of analysis of all refinements because of the limited equipment and skilled techniques at hand. Most of the corrections normally applied, with the exception of that for equilibrium, will not alter the gross analysis to any appreciable extent. When uranium atoms in pitchblende disintegrate, they break down into other radioactive elements, and eventually the number of elements being formed is equal to the number breaking down. The ore is then said to be in equilibrium. Certain geological processes, however, such as leaching, may selectively remove some of these elements and hence reduce the radioactivity of the ore sample. The ore is then said to be out of equilibrium. The field analysis may then be in error by as much as 50 per cent since the apparatus is calibrated with standards that are in equilibrium. However, such a large error due to loss of equilibrium is the exception, and in most cases uncorrected field types of analyr.is are justified.

Jan 1, 1949