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By Ping K. Di

A naturally aged and synthesized manganese oxide-coated granular media was found in our laboratory to have the capability of the removal of soluble Mn(H) from mine drainage by adsorption and oxidation. Mine drainage commonly also includes other heavy metal ions. Extending this principle, this paper presents the removal of heavy metals including lead, copper, cobalt, zinc and nickel in the aqueous solution by using the synthesized manganese oxide-coated granular media. It was found that the adsorption of lead, copper, cobalt, zinc and nickel on the manganese oxide-coated media follows both Langmuir and Dubinin-Radushkevich adsorption isotherms except in the concentration range less than 0.1 mmole/L. The adsorption mechanism involves the ion exchange between the heavy metal ions and synthesized manganese oxide coated on the media. The synthetic manganese oxide surface has a strong metal binding ability to the heavy metals in the order of Pb2+ > Cu2+ > Ni2+ > Zn2+ > C02+ based on the adsorption results using batch and continuous column operations. The breakthrough curves of these heavy metals showed that the synthesized media could be used effectively in the removal of these heavy metal ions in a cell or packed column. The process can simultaneously facilitate the immobilization of the heavy metals on the synthesized manganese oxide coated media. A subsequent pH adjustment dislodges the heavy metals and regenerates the synthetic media. Thus, the process accomplishes the adsorption, immobilization and concentration of the heavy metal from waste stream in one monolithic procedure.

Jan 1, 1995

By W. C. Smith

Even with conservative mine planning, rib instability can progress from a nuisance to a major safety hazard. This Bureau of Mines paper examines the mechanisms of progressive rib failure in high mine openings and discusses techniques to control rib slabbing. A field test site in a longwall mine was instrumented to investigate rib behavior during mining. While data analysis showed minor pillar dilation. sporadic zones of progressive rib instability were detected that culminated in eventual rib failure. The failure occurred despite conservative pillar dimensions and shallow depth. Models were used to demonstrate the mechanisms of rib failure and then evaluate the influence of support and other mine-related parameters on rib behavior.

Jan 1, 1991

By T. C. Vogt

Earlier we described the uranium mineralogy of an areally broad sampling of Crownpoint ore, including the characterization of organic carbonaceous material associated with the uranium mineral. (1) We also reported on the leaching behavior of Crownpoint ores with a mild alkaline leaching system, oxygen (02)-sodium bicarbonate (NaHC03). (2) There was a wide range of leaching responses, with samples from some areas leaching at a slow rate with low uranium recovery. Evidence indicates that in these samples the organic material is intimately associated with the uranium mineral and shields it to some extent from contact by the leachate. (1,2) One method to obtain faster leach rates and higher recoveries is to use a chemically severe leaching system such as sodium hypochlorite (NaOCI) as an oxidant. (3) The use of sulfuric acid (H2SO4) and an oxidant for leaching ore in surface milling operations is widely practiced to effect high recovery of uranium (U308) from the ore. (4,5,6) The U308 is mobilized as the disulfate complex, U02(S04)224-, or possibly, the trisulfate complex, U02(S04)34-, is the soluble species. (7) Sulfuric acid leachate formulations were used in the first in-situ leaching operation in the Shirley Basin in Wyoming. (8) More recently H2S04 formulations have been used in the Rocky Mountain Energy field tests in the Powder River Basin (Bear Creek) and in the Teapot forma¬tion at Nine Mile Lake site near Casper. (9,10) Laboratory studies related to the use of H2SO4 for in-situ leaching have been reported (11-17) and Yan has .reported packed column leach studies on Crownpoint ore using H2504 and oxidant. (18)

Jan 1, 1981

By C. D. Broadbent

Open pit blasting can be a low cost routine or a high cost bottleneck depending on geology, environment and the operator's ability to master site conditions. Because blasting is a repetitive operation, there should be ample opportunity to optimize the process; but ordinarily this optimization is rarely achieved and then only if conditions remain consistent and predictable. Often, however, and particularly with porphyry coppers, hidden differences in rock characteristics nullify the operator's best efforts. At a porphyry copper deposit being mined by Kennecott Copper Corporation, there are all of the following rock types: oxidized and fresh porphyry, altered and silicified limestone, explosion breccia, rhyolite, sandstone, shale and several others. The units can cover large areas or be limited to a few tens of feet in maximum dimension. They are rarely visible on the bench surface and often do not show up in the bench slope. Even though the blastability of these rocks varies substantially, a generally-uniform blasting pattern was formerly used with disappointing results. Secondary blasting was often required and high bottoms occurred frequently; overblasting wasted drilling time, and explosives caused excessive throw. Several possible methods for improving the blast design were considered and a geophysical method was chosen for testing. There had been reports in the journals that seismic methods were being used in Europe as aids for blasting design. A literature search turned up work by Haxby 1/ on use of a refraction seismograph for measuring pit bench rock strength. Using his work as a springboard, equipment was purchased and a program was planned and carried out for developing, evaluating and implementing the seismic method for routine mine use. Following are discussions of the development program and results.

Jan 1, 1974

By C. G. Anderson

The treatment of materials for the recovery of the precious metals imposes many processing and environmental challenges. Sunshine Mining and Refining Company has developed hydrometallurgical technology for recovery of values from refractory precious metal materials. At Sunshine, the industrial focus of these processes has been for the direct recovery of silver without cyanidation. However, recent work has indicated that these technologies can provide a means for treating complex, refractory gold concentrates. This will be the focus of this paper. The practice of pretreating ores and concentrates to make them more amenable to cyanidation is becoming more common. Several pretreatment options for sulfide concentrates containing gold include roasting, bio-leaching, direct pressure oxidation and nitrogen species catalyzed pressure oxidation. The industrial use of nitrogen species catalyzed pressure oxidation has been limited to the Sunshine refinery where its focus has been for the treatment of silver concentrates. Much of the reluctance, outside of Sunshine, to use this type of technology may be based on the perception that high costs are associated with using nitrogen species (e.g. nitric acid, sodium nitrite) to leach. Also, the use of nitrogen species catalyzed pressure oxidation on an industrial scale is unfamiliar to most metallurgical professionals. A summary of pressure leaching processes which utilize nitrogen species as a catalyst is presented in Tables 1 and 2.

Jan 1, 1996

By E. R. Bauer

In response to the mandates in the MINER Act of 2006, the National Institute for Occupational Safety and Health (NIOSH) conducted refuge alternatives research that included characterizing the utility, practicality and survivability of refuge chambers and outby safe havens. NIOSH also prepared and delivered a report to Congress in late December 2007 that summarized the findings of the re-search, included recommendations concerning the design and performance specifications for refuge alternatives, and focused on specific information that could inform the regulatory process on refuge alternatives. This paper highlights NIOSH?s research and recommendations concerning refuge alternatives, survivability evaluations of refuge chambers and presents a brief review of the current deployment of refuge chambers in underground coal mines in the U.S. The research has lead to the conclusion that refuge alternatives have the potential for saving the lives of mine workers if they are part of a comprehensive escape and rescue plan and if appropriate training is provided.

Jan 1, 2009

By R. Miller

Lowering our globe’s emissions is a major effort as we move toward a future net-zero carbon environment requiring significant investment in a new, low-carbon infrastructure, along with key market incentives to change. Industry will play a key part in this transformation, requiring expertise in both energy and emissions. Key elements of the de-carbonization strategy are: energy data, emissions reporting method, governance, de-carbonization project generation and drivers, the MACC, electrification, and the de-carbonization checklist. For a zero carbon future, it will be key for business leaders to understand decarbonization, anticipate technological changes, and implement new business me

Mar 2, 2022

By D. C. McDonald, P. R. Whincup, H. Duke

Due to grade, overburden depth and stability and the presence of groundwater it was considered impractical to recover gold contained in unconsolidated palaeochannel sediments by conventional mining, dredging or borehole mining techniques. A series of field experiments was conducted to determine the feasibility of recovery of gold by in situ leaching from sediments located at a depth of about 80 metres. The test wellfield site and plant are described together with field test procedures, results and wellfield rehabilitation procedures. Choice of sodium cyanide as leachant and laboratory testing are discussed in relation to groundwater and sediment chemistry and problems encountered in field tests.

Jan 1, 1989

By D. F. Malott

The Michigan Department of State Highways makes extensive use of geophysics for subsurface surveying which would be applicable for uses in other fields. Examples of resistivity surveys are given which include a proposed large volume excavation with suggestions for land use after excavation, subsurface evaluation for engineering design, and a subsurface survey for land appraisal. An example of a combined refraction seismic and resistivity survey is shown where the resistivity is used for outlining the unconsolidated soils, while the seismic method Is used to outline bedrock and to evaluate it for rippability. A refraction seismic survey at the bottom of bridge caissons for evaluation of bedrock uniformity and a relative aid In assessing rock strength is reported.

Jan 1, 1968

By Vas Choudhry

The eighties are likely to witness the first commercial-size coal-to-gasoline plant(s) in the U.S., although uncertainty regarding crude prices and cautious involvement of the Federal Government in the synfuels development are evident. The formation of The U.S. Synthetic Fuels Corporation with passage of the Energy Security Act is projected to pave the way for some of the projects on a moderate scale. The corporate objectives (1) are to provide funds for supporting a number of feasibility studies and loan guarantees for the construction of at least some commercial-size plants and the possibility of product price supports or purchase commitments. There are a number of coal conversion processes (2) currently under evaluation for producing either gaseous or liquid plus gaseous fuels, the other processes such as SRC I are for producing desulfurized deashed clean solid fuel for commercial use.

Jan 1, 1982

By Brian Zelenko, William H. Hansmire

"By the time the latest expansion of the Washington Metropolitan Area Transit Authority (WMATA) system, known locally as Metro and which opened in 1976, is completed in 2020, the system will serve 97 stations and operate on 188 km (117 miles) of track on six interconnecting lines. Metro provides a critical transportation link to a population of approximately six million people within a 3,900-km2 (1,500-sq-mile) Washington Metropolitan area and has allowed job growth to expand to all corners of the region. In the 1950s and 1960s, when the system was first conceived and construction began, most jobs were centered in downtown Washington, and most of the workforce commuted by bus or car. Today, transit-oriented development has increased residential, commercial and government facilities near most of the existing 91 stations increasing the importance of the Metro system as a critical transportation link for the region. According to recent American Public Transportation Association (APTA) data, Metro is the second busiest transit system in the United States (after New York City’s transit system).During the nearly 50 years of construction on the Washington Metro system, technology improvements and lessons learned from the global tunneling industry were implemented. Portions of this background and history have been adapted from other work by the authors Roach et al. (2017) and expanded for use herein. For soil tunnels, these improvements included the change from a “two-pass” tunnel lining with a typical initial lining of steel ribs with wood lagging or segmental precast lining erected within the tunnel shield followed by a final lining of cast-in-place concrete to a one-pass lining system of pre-cast concrete gasketed segmental lining. Soil tunnels were originally excavated using open-face tunnel shields, but changed over time. By the late 1980s, tunneling using closed, pressurizedface tunnel boring machines (TBMs) using a one-pass tunnel lining consisting of segmental precast concrete permitted tunneling in a wider range of soil conditions with much less risk of damaging overlying utilities or structures, greater safety for tunnel construction personnel and without the need to dewater the soils. However, due to concerns about conditioning clays with earth pressure balance (EPB) TBMs, open face machines were still favored by contractors for their better advance rates, lower cost and ability to deal with boulders that were occasionally encountered in the Coastal Plain Terrace Deposits."

Jan 6, 2018

By ERIK CHARRIER, ADITYA JUGANDA, Jürgen Brune, Patrick Maier, Gregory E. Bogin Jr

Confined explosions are a major risk in underground coal mine operations. Depending on confinement, ignition location and obstacles in the flame path, methane explosions can transition to detonations. As a result, the severity of mine explosions ranges from minor damage to loss of lives and permanent mine closure. Experimental results have shown that the inclusion of obstacles can significantly increase the flame propagation velocity by inducing turbulence. This research focuses on explosion experiments in a 71 cm diameter, 30.5 m long reactor that includes rock piles as obstacles along with developing the corresponding CFD model that captures the observed flame behavior and interaction with the obstacles. The rock rubble increases the flame front propagation velocity by 500% compared to the maximum velocity observed in the empty reactor experiments. The 2D and 3D CFD models predict the experimental flame front propagation velocity, whereas the 3D model shows a more explicit conformity than the 2D model. Although the computational time to complete the simulation is much less for the 2D model than for the 3D model, the 2D model is not sufficient to simulate cases with rock rubble since it cannot capture the propagation of the flame through the small voids between the rocks with the same effective blockage ratio as the 3D model. The validated CFD model can be scaled up to simulate methane explosions in full scale mine and industrial settings.

Nov 20, 2023

By Mark C. Williams, Thomas P. Meloy

Particle shape characterization is a complex task made more difficult because of the human eye's sophisticated recognition of shapes, giving rise to the assumption that shape analysis is considered a simple problem. Further exacerbating the problem is the question of whether particles have a general shape. Old and new shape measuring techniques are discussed, particularly the new image analysis methods techniques such as Fourier, Haar, Walsh and Delta. Problems with the current image analysis equipment and future research equipment needs are presented.

Jan 1, 1989

By R. Gray, B. Hebblewhite

Experience from Australia had identified what is referred to as nonconventional surface subsidence behavior. This occurs under irregular surface topography, resulting in valley closure, valley floor uplift or “upsidence,” and far-field horizontal movements, occurring even beyond conventional “angle of draw” limits. This paper discusses such behavior recently observed in Pennsylvania and focuses on the 2005 case of Duke Lake Dam in Ryerson Station State Park. In July 2005, there was a significant increase in water leakage through a number of growing cracks in the dam, leading to the dam being breached to avoid an uncontrolled failure. An underground longwall mine was located approximately 900 ft to the north, mining at depths of 330 to 720 ft. Investigations, including a subsequent ground movement monitoring program, found a range of evidence in the vicinity suggesting that valley closure and farfield horizontal movements may have occurred, resulting from the adjacent mining. Besides discussing the phenomenon of nonconventional subsidence behavior and the Ryerson State Park case study, this paper includes an assessment of the mining, geology and subsidence impacts and suggested ground behavioral mechanisms.

Jan 1, 2015

By Xinming Chen, Huazhe Jiao, Qi Zhang, Yunfei Wang, Liuhua Yang

The effect of initial damage generated by weakly cemented interlayer surfaces on the physico-mechanical properties of layered cemented tailings backfill (LCTB) is considered for the interlayer inclination structure generated by multiple layered backfills in large-scale mining voids. Utilizing the theory of damage mechanics, the damage evolution and constitutive model of LCTB with interlayer inclination is constructed by considering the coupling of interlayer inclination effect and loading. Based on Mitchell’s mechanical model, we analyze the damage mechanism of the inclined cementation surface of LCTB, and derive the expression for the strength of LCTB considering interlayer inclination. The mechanical properties test of LCTB with different inclinations was carried out, and the results showed that the damage model of LCTB established was highly consistent with the experimental curves, which verified the correctness of the model. The initial inclination damage leads to the decrease of adhesive cohesion of cemented surface, and with the increase of inclination, the separation of layered surface, aggravation of misalignment, layered cemented surface is more prone to shear damage, and the mechanical properties of cemented tailings backfill in the lower part of layered surface are not effectively played, which reduces the overall performance of the material.

Nov 23, 2023

By T. Dombrowski

Acid-activated montmorillonite is used worldwide as a catalyst and as a sorbent for the enhancement and purification of petroleum products as well as vegetable and animal-based fats. The solid-acid character of the activated montmorillonite is imparted by the manufacturing process, giving it unique properties that are exploited in these industries. Several international companies and a multitude of local clay producers are focusing on improving the efficiency of their standard and specialized products. This paper will describe the use of acid-activated montmorillonite in traditional sorbent applications, as a solid acid catalyst, and other new uses.

Jan 1, 1997

By R. E. Nivens

In the past, Newmont Gold Company relied on cement for their ore agglomeration process. With assistance from Betz Industrial, Newmont began Investigating the use of polymers for ore agglomeration. If gold recovery would not be jeopardized, then polymers could replace cement and possibly reduce operational costs associated with cement agglomeration. The following outlines the preliminary testing conducted to determine the feasibility of polymer agglomeration with Newmont's ore and the results of the test heap, which was constructed so the program could be examined under actual operating conditions. Similar polymer agglomeration testing has been successfully performed in other Nevada gold operations. By eliminating the need for cement, a polymeric agglomeration program could improve material handling operations, as well as offer the following additional savings. First, the polymer application uses only lime for adjusting basicity, the polymer does not contribute any alkalinity to the heap. Because lime is more soluble than cement, detoxification of the heap becomes much faster and less costly for the mine relative to rinsing cement alkalinity. The following graph compares the detoxification rate of cement and polymer over a 33 day cycle.

Jan 1, 1993

By David A. Milligan

This paper describes the Darwin Silver Recovery project, located 66 km (40 miles) outside of Lone Pine, near Darwin, Inyo County, California. A lead-zinc mine and a flotation concentrator were operated there from 1945 to 1957. By the time the mine was shut down, 1.53 Tg (1.69 million short tons) of tailings had been stored in ponds. An average silver assay of 47 mg/kg (1.38 troy oz/st) of tailings stimulated interest for commercial silver recovery. A heap leach process was developed in 1981 at the Tucson Research Center of Anaconda Minerals Company, a division of Atlantic Richfield Company. Agglomeration techniques were used on the ore since the fine grind did not allow direct heap leaching. Lime and cement were required as binders, Early laboratory tests showed that recoveries equal to those from an agitated leach could be achieved at lower capital and operating costs. Laboratory tests determined cyanide requirements, lime and cement usages, and percolation or leach rates, as well as confirming that a zinc precipitation step could recover the silver from the leach solution.

Jan 1, 1983

By D. L. Leach

This report covers laboratory experiments simulating in situ copper recovery from primary sulfide ores in sulfuric acid systems pressurized with oxygen. Copper extraction and acid consumption data are correlated with temperature in the range 50-150°C and quenched pH in the range 0.25-2. Adverse changes in the chemical composition of the leach solution and the formation of gangue-mineral alteration products and secondary sulfides can severely limit the extraction of copper above 90°C. Keeping the pH below the self-buffered value of about 2 and the temperature below about 110°C produces the maximum extraction rates. Forcing the pH too low not only results in excessively high acid consumption but may also limit the extraction of copper at temperatures above 100°C.

Jan 1, 1975

By B. V. Knelson

Although the concept of centrifugal recovery has been around in one form or another for many years, it has not been until recent times that it has became clearly understood am properly put into perspective. Simplistic in theory, it is when one begins to examine the variables involved that the true complexities of this matter begin to emerge. In creating an enhanced g force concentrator, there are many aspects both positive and negative that are encountered.

Jan 1, 1989