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By G. W. Jones, F. E. Scott

"INTRODUCTION During the last war, considerable attention was given to the search for materials or combinations of materials for use as expelling agents for aerosols in the well-known ""aerosol bomb."" These materials must be free of fire and explosion hazards under normal conditions of use.In cooperation with the Department of Agriculture and other Federal agencies interested in the work, the Bureau of Mines carried out a laboratory investigation on the inflammability of- dimethyl ether-dichlorodifluoromethane air mixtures. 4/The method of investigation was essentially the same as that used in a similar investigation dealing with the inflammability of propane-butane-dichlorodifluoromethane mixtures. 4/SOURCE OF MATERIALSThe dichlorodifluoromethane (commonly known as freon-12) and the dimethyl ether were supplied by Dr. Lyle D. Goodhue., U. S. Department of Agriculture, Beltsville, Md. It was reported that the freon-12 was manufactured by the Kinetic Chemical Co. Wilmington, Del., and the dimethyl ether by the Carbide & Carbon Chemicals Corp., Charleston, W. Va..The materials were obtained in small metal cylinders and were used as received. Before using, the cylinders mere placed in an upright position, and 5 to 6 liters of the gas was released from each cylinder to the atmosphere to remove any trapped air that may have been introduced when the cylinders were filled."

Sep 1, 1947

By P. G. Clites

This bulletin summarizes the results of Bureau of Mines research on the development of the inductoslag melting process. Inductoslag melting is an induction melting technique using a segmented, water-cooled, copper crucible. The process was developed as part of the Bureau's work on effective utilization of reactive metal scrap, and the process has been applied to melting Ti, Zr, Cr, Co, Fe, Ni, and V. Construction details are given for the segmented crucibles and for both an ingot furnace and a casting furnace. The melting process is described, and results of tests conducted with a variety of reactive metals are given.

Jan 1, 1982

By C. Ortuglio

The effect of cracking by increasing the free space above the charge on the composition and yields of the volatile products from carbonization of Pittsburgh-bed coal and one industrially used blend from Eastern United States and one from Western United States was investigated with the BM-AGA carbonization apparatus. Increasing the free space above the charge from 1 inch to 3 inches, to 6 inches, and to 9 inches resulted in lower tar yields and increased gas and light oil yields. Anthracene and naphthalene yields were increased; quinoline and benzene insoluble fractions of both the tar and pitch increased considerably with increased free space, although the carbon content of the tars and pitches increased only slightly. Increased cracking, occasioned by the increase in free space, resulted in a decrease in the yields of tar acids, tar bases, neutral oils, olefins, aromatics, and paraffins and naphthenes. Gas composition was relatively constant; hydrogen and methane tended to increase and ethane decrease. Results of the investigation are being used to design a unit to upgrade the volatile products of carbonization by cracking the hot products as they leave the carbonization chamber.

Jan 1, 1970

By R. V. Lundquist, H. Leitch

Sodium aluminate is the principal aluminum compound formed in the sinters prepared by the lime - soda sinter process for recovering aluminum from silicate source materials . The properties and characteristics of this compound were studied to improve the efficiency of the process . Crystalline sodium aluminate was prepared by sintering stoichiometric quantities of soda ash and calcined alumina for 1 hour at 1,250 ° C. The extent of aluminum extraction from sodium aluminate was determined in water and in solutions of NaOH and Na₂ CO3 . Nearly complete extraction of aluminum from sodium aluminate was achieved only in solutions containing free NaOH in excess of that supplied by the salt through hydrolysis . About 42.2 to 68.8 percent of the aluminum was extracted in water or in solutions of Na₂ CO . The precipitation of alumina trihydrate from sodium aluminate solutions was shown to be part of a continuous , reversible reaction according to the equation Al (OH ) A1 (OH )3 + OHThe reverse reaction dissolves alumina trihydrate in NaOH solutions to produce sodium aluminate . Approximate equilibrium concentrations were determined for the reaction at 30° , 50 ° , and 70 ° C. False apparent equilibrium conditions for the dissolution reaction appear when only a small excess of alumina trihydrate is present in the NaOH solutions . A large excess of alumina trihydrate must be present before the true equilibrium point is assured . The engineering significance of the data is summarized , showing controls that should be exercised for a successful and efficient process .

Jan 1, 1964

By Walter T. Lewiecki

Bauxite was first discovered in-the United States near Rome, Ga., in 1887, Approximately 400,000 tons of bauxite ranging from 46 to-62 percent alumina were mined in the area from 1888 to 1930. In February 1943, The Republic Mining & Manufacturing Co. installed a dryer and began mining and reworking dumps from the old bauxite mines. Some 3,000 long tons were dried and shipped to the chemical industries from March 1943, to June 30, 1943. In 1941 and 1942, representatives of the Bureau of Mined and the Federal Geological Survey/ visited this area and proposed an exploratory project that at first was to be confined to the Heritage district northeast of Rome (see fig; I). The Bobo district, southwest of Rome, was to be explored after work .1n the Hermitage district was completed. The Hermitage district comprises an area of about 50 square miles in the northwest quarter of Bartow County and the adjacent portion of Floyd County. It is bounded on the north by the Gordon County line, on the east by U. S. Highway 41, on the south by U. S. Highway 441, and on the west by State Highway 53.

Jan 1, 1949

By Miles B. Royert

Crude Minnesota taconite was charged in the Bureau of Mines experimental blast furnace so that smelting characteristics of such highly siliceous raw materials could be studied and smelting costs compared with those of a standard Mesabi ore. The Bureau recognized that the highly siliceous nature of the crude ore and its relatively low metallic content would be serious economic deterrents to commercial use of the raw taconite, but compensating factors would be low capital investment in production facilities, large tonnage available on short notice, high recoveries of iron, and low delivered cost. Crude taconite smelted readily in the experimental blast furnace. Coke consumption per ton of metallic product was very high, compared with the average established requirements for smelting normal grades of metalliferous raw materials. Slag rates were also inordinately high. Metal quality was erratic as to silicon, and sulfur contents were objectionably high.

Jan 1, 1961

By R. L. Grant

The Bureau of Mines developed two new gap-sensitivity methods for explosives, and especially permissible explosives, to overcome certain disadvantages of the present routine half-cartridge method. The revised methods are based on the statistical up-and-down method and give more useful measurements of the 50-percent' gap values than the nonstatistical routine method. The new methods use full cartridges and incorporate certain physical improvements such as the use of cardboard tubes for containing the explosives and coal dust gaps to simulate actual mining conditions. A total of 60 samples of permissible explosives were evaluated simultaneously with the 2 improved methods and with the half-cartridge method

Jan 1, 1967

By J. B. Gayle

Oven widths for experimental and commercial slot-type ovens differ appreably in most instances; the experimental ovens usually ranging from 10 to 14 inches and the commercial units from 14 to 21 inches. Application of results obtained with experimental ovens to commercial practice thus requires major extrapolations. A critical survey of the literature indicated that sufficient information about the effects of variations in oven width on the carbonizing process is not available to permit such extrapolations to be made with any considerable degree of confidence.

Jan 1, 1960

By H. Tomlinson

This circular is one of a series of papers on coal mining methods and costs which being prepared by the United States Bureau of Mines for the purpose of making available to those interested in the industry a knowledge of the mining methods employed, the places here mechanical and hand loading are practiced, and coat data on the several operations pertaining to the removal of coal from the working faces and its transportation to the tipple for loading into railroad cars. Mining costs are governed by the relative efficiency of the mining method employed. The method is selected for Its adaptability to the local natural physical conditions such as the nature and thickness of the coal bed, its dip, the character of the coal, and the thickness of the overlying strata.

Jan 1, 1930

By Henry E. Blake

Defluorination studies on refractory fluoride - bearing compounds and minerals , particularly on partly defluorinated residues from high - temperature pyrohydrolysis , required a dependable and reasonably accurate analyticalcontrol method for the analysis of fluorine . The difficulty in liberating fluorine from the fluorides of metallic elements such as aluminum, zirconium , and rare earths by steam- distillation can be largely overcome if the distillation is made from a sulfuric - phosphoric acid solution of a sodium carbonate fusion of the sample material and if the distillation temperature is maintained at about 155 ° C. The data presented in this paper show that liberation of fluorine by this method is more complete and proceeds more rapidly than by usual distillations from perchloric or sulfuric acid alone or a mixture of phosphoric and perchloric acids . Fluorine in amounts ranging up to about 140 mg can be recovered by collecting only about 300 ml of distillate . Determination of fluoride in the distillate is made by the usual thorium nitrate titration .

Jan 1, 1963

By A. J. Kraemer, O. C. Blade

This report on the properties of motor fuels sold through service stations in the United States is a continuation of a series of reports made in accordance with a cooperative agreement between the Coordinating Fuel Research (C. F. R. ) Committee of the Coordinating Research Council (C. R. C.) and the Bureau of Mines of the United States Department of the Interior . The first of these reports contained data on motor gasolines sold during the winter of 1935-36 and further reports on motor gasolines sold during the succeeding summers and winters to the summer of 1941

Dec 1, 1943

By NIOSH NIOSH

This work explores application of a double alkaline leach method to extraction of alumina from Oregon ferruginous bauxitic materials. The process recovers a greater proportion of alumina from high-silica ores than is possible by a conventional single-leach method. This recovery is accomplished by calcining the ore, removing reactive silica in a preliminary dilute caustic soda leach, and then applying a second leach to dissolve alumina. Ores containing up to 15 percent Si~) 35 percent AI;:) Os, and 30 percent Os were examined. Under conditions of treatment established by experimentation, more than BO-percent alumina extraction was demonstrated. When and if conditions demand the use of low-grade materials, the double-leach process is capable of providing millions of tons of alumina from Oregon ferruginous bauxite.

Jan 1, 1963

By A. J. Kraemer

This paper on the physical and chemical properties of crude oils from California fields is one of a series of reports on the on the districts of the United States. The paper includes a short discussion of results, tabular data, and individual analyses of eight. California crudes. Analyses of other crude oils from California have been published it Reports of Investigations 2595, 2608, and 2846. The samples were obtained by members of the San Francisco office of the Bureau of Mines. The collecting 65 samples was facilitated by the courtesy of representatives of oil companies in California. The methods used in testing and analyzing the samples are described in detail in Bureau of Mines Bulletin 207. A discussion of the interpretation of crude-oil analyses, as made by the Bureau of Mines, is given in Bureau of Mines Report of Investigations 2806.

Jan 1, 1931

By Robert K. Koch, Henry E. Blake

Laboratory tests were made to determine if aluminum fluoride of commercial grade could be synthesized by reacting alumina hydrate with dilute ( 25 to 75 grams per liter of fluorine ) aqueous fluoride solutions . • Products containing up to 90 percent aluminum fluoride ( A1F ) were synthesized by reaction of alumina trihydrate ( A120 3H2O) with either dilute hydrofluoric acid ( HF ) or ammonium fluoride ( NHF) solutions , the ammonium fluoride solution resulting from ammonia ( NH ) desilication of a hydrofluoricfluosilicic acid ( HF - H₂ SiF ) solution . Fluorine recoveries of over 80 percent were obtained with either type of solution . The hydrated precipitates of AlF, and ( NH4 ) , A1F ( ammonium aluminum fluoride ) obtained by reacting hydrated alumina with these solutions were subsequently converted to anhydrous AlF, by controlled heating .

Jan 1, 1964

By James W. Miller

An investigation was begun by the Bureau of Mines in 1948 to determine the preparation characteristics of American coals. Results of the investigation were planned to be reported on a county basis and from the data developed, to determine: (a) Which coals either as mined or after beneficiation by conventional preparation are chemically suitable under present standards for producing metallurgical coke; (b) Which coals require special and more intensive treatment in preparation than is now practiced; and (c) Which coals cannot be considered potential sources of metallurgical coke, regardless of preparation. This report is one in this county series that describes the preparation characteristics of the coals of Perry County, Ky.

Jan 1, 1956

By R. Hogg, T. F. Dumm

"A procedure for evaluating the size/specific gravity distribution of ultrafine coal and the distributions of sulfur and ash with respect to particle size and specific gravity is described. The procedure is essentially an extension of the conventional coal washability technique in which special precautions are taken to ensure particle dispersion in the heavy organic liquids, centrifuges are used to obtain adequate separation rates, and micromesh sieves are used for size separation at fine sizes. An example of the application of this technique to the evaluation of the extent of liberation of sulfur and ash in a coal sample ground to 90Z passing 200 mesh (74 um) is described.INTRODUCTIONIn order to determine the potential for deep cleaning of coal by fine grinding to liberate sulfur and ash-forming minerals, it is necessary to obtain data on the distributions of these species by size and specific gravity. In conventional coal processing operations, this information is obtained by means of a standard ""washability"" analysis. Attempts to extend this procedure to ultrafine coal, however, have generally been unsatisfactory and have often led to unreliable and inconsistent results [11. The present authors have described a modified washability procedure in which cumulative specific gravity fractionation is combined with sub-sieve size analysis (by laser diffraction/light scattering) to determine the particle size/specific gravity distribution of ultrafine coal [2]. Unfortunately, because this technique does not involve separation of the individual fractions, only limited information can be obtained on the specific distributions of sulfur and ash.The objective of the work described in this paper was to develop and evaluate a procedure for size and specific gravity fractionation of ultrafine coal and to use conventional analyses for sulfur and ash to determine their relative distribution in the coal. The procedure is essentially a simple extension of the standard washability analysis [3] but incorporating special precautions for treating ultrafine particles.EXPERIMENTAL Material The material used in the development and evaluation of the ultrafine coal fractionation procedure was a medium volatile bituminous coal from the Lower Kittanning seam. A sample of the coal (nominally - 1/4 inch), obtained from the Penn State Coal Data Base, was ground to 90% passing 200 mesh by the following two-stage grinding procedure: About 2 kg of the as-received coal were ground to about 30Z passing 200 mesh in a Model 4-E Quakertown mill (""coffee grinder""). About 1 kg of this product was then ground to about 90Z passing 200 mesh in a Holmes Model 300 Pulverizer."

Jan 1, 1989

This paper on. the physical and chemical properties of crude oils from California fields is one of a series of reports on the oil-producing districts of the United States., The paper includes a short discussion of results, tabular data, and individual analyses of eight California crudes. Analyses of other crude oils from California have been published in Reports, of Investigations 2595,3/ 2608,4/ and 28465/. The samples were obtained by members of the San Francisco office of the Bureau of Mines. The collecting samples was facilitated by the courtesy of representatives of oil companies in California.

Jan 1, 1931

By Lex B. Golden

The purpose of this investigation was to evaluate the corrosion properties of certain alloys of titanium and to compare them with those of unalloyed titanium. Such information should make it possible to determine the desirability of substituting these alloys for commercially pure titanium in certain applications. Titanium-manganese, titanium-chromium-iron, and titanium-vanadium-iron alloys, with 2 types of unalloyed titanium, I consolidated by arc melting and the other by powder-metallurgy techniques, were included in the study. Tests were carried out in sulfuric, hydrochloric, phosphoric, nitric, and mixed acids and in chloride solutions. All solutions were saturated with air.

Jan 1, 1957

By B. W. Gandrud, G. D. Coe

"INTRODUCTION The Southern Experiment Station of the U.S. Bureau of Mines, cooperating with the University of Alabama and Alabama coal producers, has made a series of investigations of the washability of coal from commercially important bens of Alabama. The results of 13 investigations pertaining to the Mary Lee, Clark, Black Creek, Jefferson, Pratt, Corona, Carter Brookwood, Blue Creek, Thompson, and Woodstock beds have been published. 4/ This report, the fourteenth of the series, deals with run-of-mine coal from the Henry Ellen bed at the Acmar No. 5 mine of the Alabama Fuel & Iron Co.The Acmar mine is 1/2 mile west of Acmar, Saint Clair County, in the northern part of the Cahaba field. Present production at the mine is about 800 tons per day, all of which, accept the lump coal, is treated in jigs. The washability data were obtained by means of screen-sizing and float-and-sink tests. There are included, also, tests showing the extent of liberation of impurities by recrushing the coarser sizes of coal from the top bench and tests showing the flakiness in selected sizes.SAMPLING AT THE MINEThe Henry Ellen bed at Acmar consists of two benches separated by a shale parting. At the point of sampling the top bench was 6 feet 3 inches thick and contained a 1-inch and a 1 1/2-inch band of bone. The bottom bench was 5 feet thick and was separated from the top bench by 20 inches of shale. In taking the samples for the washability study the working face was squared up, and a representative 2-ton section was out from each bench. The shale parting was discarded, according to usual mining practice."

Nov 1, 1936

By M. H. Chetrick

Since 1945, a commercial-scale pilot plant for the gasification of lignite has been operated by the Bureau of Mines at Grand Forks, N. Dak. The description, operation, and objectives of this pilot plant have already been described in previous reports (6, 7, 8). Although the experimental data obtained from the operation of the externally heated retort have been tabulated and summarized (1, 7), few studies have been made in the correlation of these data. The purpose of the present investigation was to review the data taken in tests of the lignite-gasification pilot plant and to correlate the gas-composition data in terms of their basic factors.

Jan 1, 1950