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By Wilbert J. Huff, Raymond H. Moore

"Black powder is employed widely in peace and war. Its properties are therefore of considerable interest to many. The Bureau of Mines frequently is asked to furnish information on its use and safe handling in the mining and mineral industries in times of peace and is now engaged in studies of its application to the arts of war.Black powder has been the agent in many accidents - some very disastrous - and its handling and use are deemed very hazardous. The belief is widespread that the hazards are due principally to the ease with which the powder is ignited by a hot spark or flame in contradistinction to high explosives; these usually are ignited only with difficulty, and some burn incompl0tely and to a certain extent are self-extinguishing. Primary precautions, .therefore, should be taken to prevent the access of heat, spark, and flame.In black powder manufacturing operations a frequent source of disaster is the initiation of fires and explosions in the wheel mills in which the sulfur, charcoal, and nitrate are incorporated. Long experience has indicated that the wheel mill probably will fire if the powder is not kept moist enough; manufacturing supervision calls for the maintenance of a minimum moisture content, at least during the milling. Accidents occur elsewhere in the manufacturing line, and in an endeavor to minimize these, particularly those happening in corning mills, one of the writers suggested many years ago that a suitable humidity be maintained in other operations in the hope that it would serve protectively as in the wheel mill. The experience of one company for many years with this practice was favorable. It seemed desirable therefore, to explore the question experimentally."

Nov 1, 1944

By Oscar Lee, B. W. Gandrud, F. D. DeVaney

"IntroductionFlue dust which results from the smelting of ores containing appreciable quantities of fines is one of the troublesome products of iron blast-furnace practice. Gases issuing from the furnaces at a high velocity carry small particles of coke, ore and flux into dust-collecting chambers. These particles constitute the flue dust. Lasses of iron ore through the production of flue dust vary between wide limits in the different furnaces, and depend on a number of factors, such as size and design of furnace, amount of fines in the ore, the operating conditions and the blast pressure.Blast-furnace operators of the Birmingham district keenly realize this waste. The ores are comparatively low grade and require more fuel than is ordinarily used elsewhere. Hence the flue dust is low in iron content and high in coke. As a result it is not in suitable condition for direct sintering. In many other iron and steel centers direct sintering is a common practice. In the Birmingham district efforts have been made to prevent this loss by recharging the dust into the furnace, but, as might be expected, a material fine enough to be blown out once will very likely be carried over again.In general, the flue-dust losses in this district will average 250 pounds per ton of pig iron produced, but at times the losses at different furnaces are substantially higher or lower than this figure. On the basis of the present rate of pig-iron production, the annual loss of flue dust exceeds 300,000 tons. The iron content of the dust probably averages 25 per cent, therefore about 75,000 tons of iron is wasted yearly, or about 3 per cent of the iron mined is lost in flue dust."

Jul 1, 1926

By Zsuzsanna Zborovszky

Investigation of the discharge duration power and current relation required for ignition. The current and power amplitude-discharge time curve was found to flatten out over 3 ms. It is concluded that discharges having at least 3 ms power maximum are required for reliable testing of the ignition limit for resistive circuits. Investigation of the effect of molten cathode on the discharge duration and igniting ability of the discharge. The surface tension of the liquid metal causes a very fast separation and consequently a much shorter discharge duration than the solid electrode would have. The minimum discharge voltage effect overrides the effects of the temperature of electrode, material, or atmosphere. Investigation of the effect of different surface layers on the discharge duration. Oxides and sulfates were found to give significantly longer duration than the "clean" metal itself in most cases. The lowest ignition current was obtained with CdS04 coatings. Ignition was obtained with 0.7A at 30V, which is below the corresponding minimum igniting current obtained from the BASEEFA curve for circuits containing Cd, Zn or Mg.

Jan 1, 1977

By O. C. Blade

This report on the properties of aviation gasolines and aviation jet fuels produced in the United States during 1955 was made under a co-operative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. Analytical data are presented for 116 samples of aviation gasoline and for 38 samples of aviation jet fuel. The analyses were made on samples typical of the manufacturers' 1955 production in their laboratories and the results submitted to the Bureau of Mines for compilation. The products of 20 manufacturers of aviation gasolines and of 16 producers of aviation jet fuels are represented.

Jan 1, 1956

By E. D. Gardner

The American petroleum industry is supplying the present domestic demand for liquid fuels. Known reserves of petroleum in the ground, however, are limited, and the .cost per barrel of finding new oil pools is increasing. Any deficiencies of domestic production in the near future doubtlessly could be made up by imports: Dependence upon foreign oil for part of our industrial requirements is not necessarily cause for alarm, but in time of war an adequate, dependable, domestic source of liquid fuels is vital to the defense of the country. As a national defense measure, and to insure a future continuous oil supply for our economic machine, it would appear logical to take steps now to develop methods for producing petroleum substitutes within our own borders. This undoubtedly was in the mind of Congress when it passed the Synthetic Liquid Fuels Act (58 stat.190; 30 U. S. C. Sup. Secs. 321-325), Approved April 5, 1944.The title' of the Law reads: An Act authorizing the construction and operation of demonstration plants to produce synthetic liquid fuels from coal, oil shales, agricultural and forestry products, and other substances, in order to aid the prosecution of the war, to conserve and increase the oil resources of the Nation, and for other purposes. Congress authorized $30,000,000 for a 5-year program and directed the Bureau of Mines to carry it out. The part of the program pertaining to oil shale is being conducted on Naval Oil-Shale Reserves Nos. 1 and 3 (fig. 1) at Anvil Points, near Rifle, Colo.

Jan 1, 1948

This report is the 23d in a series summarizing research and technologic work by the Federal Bureau of Mines on coal and related investigations; it is the fifth report to be issued on a calendar-year basis.2/ Publications by Bureau personnel in 1958 are cited;3/ in addition work in progress during the year is briefly described. To conserve our reserves of coal the Bureau of Mines conducts a program concerned with the development of fundamental information on coal characteristics and behavior, and the improvement of technology related to its production and utilization. The ability to anticipate and meet future demands for coal depends on a number of factors: (1) Knowledge of reserves from a stand- point of both quantity and quality; (2) the development of improved mining methods, health and safety measures, and preparation techniques that will insure its most efficient exploitation; and (3) knowledge of the controlling factors in efficient use of coal in combustion, carbonization, gasification, direct and indirect hydrogenation, and other new processes. The Bureau is concerned with each of these areas.4/,5/

Jan 1, 1960

By B. W. Gandrud

This report, consisting mostly of float-and-sink data and washability curves, has been prepared in connection with an exhaustive study of coal preparation in Alabama conducted, by the U, S. Bureau of Mines and the University of Alabama with the cooperation of the different coal operators On the basis of the float-and-sink data, an attempt has been made to determine approximately the extent of ash and sulphur reduction obtainable under given conditions on coal from the mines which were sampled, In the coal-producing districts of Alabama a great deaf of attention has been given in recent years to the problem of improving preparation methods so as to obtain from various coal beds the best possible grade of washed coal. This is especially so where the washed coal is used for the making of metallurgical coke in by-product plants or where there are possibilities of using the coal for this purpose. In the manufacture of metallurgical coke, the sulphur content of the coal is a very important consideration. It is quite often the determining factor as to whether or not a certain coal can be used for coke making. In the studies which form the basis for this report, all samples have been analyzed for sulphur in order to obtain information regarding the possibilities of sulphur elimination as well as ash reduction, and the samples on which reports are made were obtained from beds that are characterized by rather high percentages of sulphur. In connection with the present investigations of coal preparation in Alabama a standardized method of interpreting float-and-sink data has been used extensively for predicting the ash and sulphur reduction and yields obtainable in a commercial washing plant from various sizes of raw coal and from the raw coal as a whole after a certain degree of crushing. This method, which will be explained in subsequent chapters, was used in interpreting the data contained in this report. The samples used for these washability studies were obtained from the following mines in the Warrior field of Alabama: Beltona mine on the Jefferson bed; Dolomite and Mulga mines on the Pratt bed; Coal Valley No. 163 and Coal Valley No. 11 mines on the Corona bed; Cedar Cove mine on the Carter bed.

Jan 1, 1932

By B. W. Candrud

This report, consisting mostly of float-and-sink data and washability curves, has been prepared in connection with an exhaustive study of coal preparation in Alabama conducted by the U. S. Bureau of Mines and the University of Alabama with the cooperation of the different coal operators on the basis of the float-and-sink data, an attempt has been made to deter-mine approximately the extent of ash and sulphur reduction obtainable under given conditions on coal from the mines which were sampled. In the coal-producing districts of Alabama a great deal of attention has been given in recent years to the problem of improving preparation methods so as to obtain from various coal beds the best possible grade of washed coal. This is especially so where the washed coal is used for the making of metallurgical coke in by-product plants or where there are possibilities of using the coal for this purpose. In the manufacture of metallurgical coke, the sulphur content of the coal is a very important consideration. It is quite often the determining factor as to whether or not a certain coal can be used for coke making. In the studies which form the basis for this report, all samples have been analyzed for sulphur in order to obtain information regarding the possibilities of sulphur elimination as well as ash reduction, and the samples on which reports are made were obtained from beds that are characterized by rather high percentages of sulphur. In connection with the present investigations of coal preparation in Alabama a standardized method of interpreting float-and-sink data has been used extensively for predicting the ash and sulphur reduction and yields obtainable in a commercial washing plant from various sizes of raw coal and from the raw coal as a whole after a certain degree of crushing. This method, which will be explained in subsequent chapters, was used in interpreting the data contained in this report. The samples used for these washability studies were obtained from the following mines in the Warrior field of Alabama: Beltona mine on the Jefferson bed; Dolomite and Mulga mines on the Pratt bed; Coal Valley No. 16B and Coal Valley No. 11 mines on the Corona bed; Cedar Cove mine on the Carter bed.

Jan 1, 1932

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of the significant coalbeds of Clay, Gilmer, and Lewis Counties, W. Va. In 1966, almost 1.3 million tons of coal was mined in these counties, of which more than one-half was from the Pittsburgh coalbed. Washability analyses were made of 16 coalbed samples. Of these, only 11 samples could be upgraded to metallurgical quality. For steam or power generation five of the coals were of low sulfur content as received. The remaining samples were generally of medium sulfur content even after upgrading.

Jan 1, 1969

By J. B. Cunningham

Lithium in the form of metal, salts, and alloys is particularly important because of increasing industrial uses resulting partly from wartime developments. Lithium carbonate and lithium strontium nitrate, which impart a brilliant red color to a flame, are used in pyrotechnics. Lithium chloride and fluoride are used in fluxes for welding aluminum to dissolve the oxide coating on the aluminum and prevent oxidation of the molten metal. Lithium carbonate is used in ceramics in raw alkaline glazes because of its unusual fluxing properties. The use of 9 to 12 percent lithium carbonate permits a marked increase in the amounts of alumina, calcium, and silica that may be Used and results in a more stable glaze with sufficient alkalinity to produce vivid copper blues and other typically alkaline colors. Lithium stearate is used as a grease in airplane engines because of its ability to withstand wide changes in temperature. In view of its great affinity for nitrogen, hydrogen, oxygen, sulfur, phosphorus, carbon, and silicon, lithium has an excellent scavenging action on molten metals. It forms stable nonmetallic compounds of low specific gravity or gases that are eliminated at pouring temperatures. Lithium is generally added to the melt in the form of a lithium-calcium alloy consisting of 50 percent of each ingredient or as an alloy of 98 percent copper and 2 percent lithium. The lithium-calcium alloy added to cast iron before pouring, acts as a scavenger and increases the fluidity of the melt. This alloy also is said to increase the corrosion-resistant properties of stainless steel alloys and to improve their polishing qualities.

Jan 1, 1948

By F. A. Patty

[Health and safety hazards from contamination of the atmosphere in places frequented by persons depend to a considerable extent on whether the contaminating agent possesses sense-perceptive properties which will give warning of its presence before it '.an create harmful conditions. If a distinct and easily recognized warning is given in advance of harmful conditions, hazards ace mitigated, but if warning properties are inadequate or absent, the hazards are augmented. When evaluating the hazard presented by a potentially harmful substance used under conditions of possible escape into the air of places frequented by persons, it is therefore necessary to consider the warning properties of the substance along with ether pertinent information such as toxicity, inflammability, physical properties, and mode of use. If the contaminating agent inherently lacks warning; properties it may be possible to impart them by adding to the hazardous substance a small quantity of a relatively harmless substance which has a high warning intensity.]

Jan 1, 1929

By Charles E. Semler

The possible utility of selected compositions in the systems SrO-ZrO2-MgO and SrO-ZrO2-Dolomite for commercial refractory products was confirmed in this study. Specifically the compositions of interest are located in the sub-systems SrZrO3-ZrO2-MgO and SrZrO3-ZrO2-Dolomite. Both sub-systems have regions that are not affected by hydration, but the sub-system SrZrO3-ZrO2-MgO has a larger candidate compositional region. Solid state phase relations were determined for the subject systems over the temperature range 1600°C to 1300°C, with compatibility diagrams presented for each. The systems appear to show good refractory character with no apparent low melting compositions. As the compositions of commercial interest lie mostly in the higher ZrO2 portion of each system, information is presented regarding the firing treatment required to develop stabilized cubic ZrO2. A list of suggestions for further study of these systems, to further delineate the characteristics required for possible commercial utilization, is presented.

Jan 1, 1982

By J. W. Thompson

CONSTRUCTION OF STATUTE-SALE BY ENTRYMAN. The timber and stone act (20 Stat., 89) does not forbid an entryman from alienating his interest in his claim; but the act makes illegal any prior agreement by which the entryman acts for another in the purchase. Worden v. United States, 204Fed., 1, p. 4, April, 1913. ASSUMPTION OF DEBT BY GRANTEE-LIABILITY TO CREDITOR OF GRANTOR. A grantee of a mine who agrees to pay the grantor's debts in part payment of the purchase price of the mines becomes to that extent the principal debtor, and the grantor becomes the surety, and the grantor's creditor may in equity enforce his claim against the grantee of the mine, and the grantor in such a case is not a necessary party. Silver King Coalition Mines Co. v. Silver King Consolidated Mining Co., 204Fed., 166, p. 169, April, 1913. RIGHT OF COTENANT TO MINE AND SELL. A cotentant in exclusive possession' of mining property who extracts and sells ore is entitled to charge against the proceeds of the sale the reasonable and necessary expense of its extraction and marketing, as in such case the cotenant is not a trespasser.

Jan 1, 1914

By P. A. Hendricks

This U.S. Bureau of Mines (USBM) report identifies and evaluates factors responsible for metal/nonmetal (M/NM) underground mining accidents involving mobile equipment. Information regarding the occurrence and severity of the accidents, the type of equipment involved, the primary and contributing causes, and preventive measures is included. The goal of this report is to provide information that will aid mine operators and safety managers in the recognition of hazards associated with operating mobile mining equipment in an underground mining environment.

Jan 1, 1994

By David A. Summers

Coal is increasingly viewed as one of the major fuel resources of this country for the remainder of this century. The need to extract a greater percentage of the coal in a given seam, together with advantages of improved safety, indicates that longwall mining will become more widely used within this time frame. A novel method of mining coal on a longwall face, utilizing high pressure water jets, is herein described. The mining machine proposed will exploit the stress conditions which exist on a longwall panel in order to achieve the required productivity while at the same time reducing respirable dust and methane ignition hazards. The water jets will excavate only the boundary of the extracted seam section, and thus the energy requirement of the machine will be minimized. The action of the machine is similar to that of an existing coal plow, except in that the wedge teeth of the plow are replaced by oscillating high pressure water jets. The machine can, therefore, cut to the depth and at the speed of existing shearer units at equivalent power levels. The removal of impact stresses from the machine will reduce downtime required for maintenance and replacement of picks and lower the load on the haulage motor of the system. The ability of the machine to increase the depth of cut without an increase in horsepower will further improve productivity when transportation systems to remove the greater production are in operation.

Jan 1, 1974

By Michael S. Wieland

This report investigates whether it is tractable and thereupon reasonable to remove the booster influences when ranking the toxic fumes of non-cap-sensitive mining explosives. The hazard potential is represented by relative fume toxicity RFT, the resultant influence computed from a formulated rule with a restricted set (tally) of fume components and multiplying constants. The RFT result is compared to the rule criterion that represents the worst case tolerable toxicity stipulated by regulations or otherwise. The typical nonstoichiometric booster composition can render notable unwanted influence on the RFT ranking results. Historically, the remedy was to shoot the booster separately and reduce the trial concentrations by the relevant subtractions. Unreal negative concentration results were noted on rare occasions, revealing the faulty nature of the reduction procedure. With thermodynamic reaction chemistry codes TDRC, on the other hand, the booster ingredients can be retained in or removed from the reactant tabulation, yielding reduction factors taken as the concentration ratios for the two circumstances. The underlying presumption regarding reduction factors is that the ratios of component concentrations with and without the booster ingredients when resolved theoretically ought to equal those rendered experimentally, when tractable. Upon rearranging the presumed relationship, the unadjusted fume concentrations divided by theoretical reduction factors yield the wanted readjusted fume concentrations, thereby removing the booster influence without generating unreal negative concentrations. The work principle from thermodynamics restricted by the constraint of zero-net interaction loss is utilized in conjunction with the TDRC to resolve the wanted (Z-state) fume spectrum. This circumvents the recognized difficulty with traditional hydrodynamic detonation theory that is related to the nonideal reaction characteristics of typical mining explosives. The tacit characteristic of the Z-state resolved from the non-trajectory work principle is that it can not be remedied or tampered with, unlike the traditional trajectory techniques where the reaction products can be readjusted by changing formula representations, nullifying specific reactions or otherwise manipulating the thermodynamic trajectory process. Though the work principle theory is an unfinished formulation, the Z-state results prove worthy enough for rendering trends and comparisons and reaching otherwise useful conclusions. Further refinements should yield more reliable fume spectra and indicate explosive composition readjustments that would reduce toxic effects within underground mines and the wider world environment.

By Robert M. Becker

This investigation (in five parts) extends the theory of sample reliability from a sample consisting of a fixed number of items to a sample consisting of a fixed amount of items. Examples of a fixed amount of items per sample are samples consisting of a fixed weight or a fixed volume of unequal size particles. The extension of the theory is confirmed by experimental laboratory sampling using standard procedures. The probability distribution functions (the binomial, hypergeometric, multinomial, generalized hypergeometric, and those here called the compound binomial and compound multimomial functions) are developed from fundamentals. Their distributions are generalized to include some measured characteristic of the items. Infinite population moments are derived from moment-generating functions, and finite population moments are developed from corresponding infinite population moments using a newly defined mathematical operation. The first three experimental moments in laboratory sampling to given weights of particles are compared with the theoretical moments of their corresponding compound mult.inomial distributions. The agreement is striking. The study is divided into five parts. Part 1 deals with probability or random sampling to n items and with all sampling to n items per sample from some one probability distribution. This is the area of sampling covered by well-known theory. Accordingly, the procedures may be different but many of the results are well known.

Dec 1, 1964

By John D. Foulkes, David A. Curtis, Robert L. Lagace, John L. Rothery

An investigation is made of the feasibility of developing compact transmit antennas and/or other means to efficiently couple VLF to MF band radio energy between portable wireless communication units in coal mines. The completely wireless communication ranges between two portable radios equipped with practically-sized reference loop antennas in representative coal mine environments are estimated. Antenna technology is assessed with respect to transmit moment, range, intrinsic safety, battery and wearability requirements to deter- mine the most suitable antenna types for use by miners. It is concluded that air-core bandolier loop antennas, and perhaps ferrite-loaded loop antennas, having peak transmit moments of about 2.5 ampere-m5 will be the most effective antenna choices for portable units. This choice, however, will not allow the range goal of 1350 feet to be attained in mines having unfavorable signal attenuation and noise environments. Rectangular air-core loops are compared with grounded horizontal-wire and vertical-wire mode exciters for fixed station applications. The potential for significantly increasing the wireless communication range by inductively coupling to communications and power lines in a mine is evaluated and found to be considerable based on theoretical coupling equations. Lastly, the theoretical performance of a hybrid noise cancelling diversity receiving technique that utilizes both the electric and magnetic field components of the ambient noise to improve the receiver output signal-to-noise ratio under certain adverse conditions is estimated and shown to be favorable when the magnetic and electric field noise components are highly correlated.

Jan 1, 1977

By Jay F. Colinet

Respirable dust exposure has long been known to be a serious health threat to workers in many industries. In coal mining, overexposure to respirable coal mine dust can lead to coal workers? pneumoconiosis (CWP). CWP is a lung disease that can be disabling and fatal in its most severe form. In addition, miners can be exposed to high levels of respirable silica dust, which can cause silicosis, another disabling and/or fatal lung disease. Once contracted, there is no cure for CWP or silicosis. The goal, therefore, is to limit worker exposure to respirable dust to prevent development of these diseases. The passage of the Federal Coal Mine Health and Safety Act of 1969 established respirable dust exposure limits, dust sampling requirements for inspectors and mine operators, a voluntary x-ray surveillance program to identify CWP in underground coal miners, and a benefits program to provide compensation to affected workers and their families. The tremen­dous human and financial costs resulting from CWP and silicosis in the U.S. underground coal mine workforce are shown by the following statistics: ? During 1970?2004, CWP was a direct or contributing cause of 69,377 deaths of U.S. underground coal mine workers. ? During 1980?2005, over $39 billion in CWP benefits were paid to underground coal miners and their families. ? Recent x-ray surveillance data for 2000?2006 show an increase in CWP cases. Nearly 8% of examined underground coal miners with 25 or more years of experience were diagnosed with CWP. ? ?Continuous miner operator? is the most frequently listed occupation on death certificates that record silicosis as the cause of death.

Jan 1, 2010

By R. P. Bush

The U.S. Bureau of Mines performed Cu exchange capacity (CuEe) tests on Ca and Na mont-morillonites and attapulgite clays. Mathematical models were developed from the data that the CuEe's are derived from for each clay as a function of pH, Cu concentration, and the concentrations of metal ions, which compete with Cu for exchange sites. An analysis was made of the impact of competing ions on Cu losses due to ion exchange. The results show that the CuEC's of clays, and hence Cu losses, are decreased by the presence of competing ions, and that AI and Mg have the largest impact of those cat-ions normally present in Cu leaching solutions.

Jan 1, 2010