Search Documents

By T. G. Carnahan

In-place leaching is being actively utilized to extract uranium, copper, and evaporites from low-grade and difficult-to-mine ores. The purpose of this report is to discuss in-place leaching technology, its advantages and disadvantages, and to give an overview of past, current, and envisioned in-place leaching operations in the U.S.A. Application of in-place leaching to uranium ores has been particularly successful because the conditions for leaching are nearly ideal. The ores are generally in highly permeable sandstone aquifers bounded above and below by impermeable shales. The uranium ore minerals are easily leached with oxidizing acid or base solution and the pregnant solutions are amenable to ion exchange concentration and purification prior to conventional solution neutralization for recovery of yellow cake. Copper is routinely recovered from sub-grade rock by dump leaching at most major copper mines. Acidified ferric sulfate is either sprayed on the surface of the dumps or is ponded on top of the dumps. The leaching solution migrates down through the rock and dissolves copper. The solution is collected from the base of the dumps and copper is recovered by solvent extraction-electrowinning or by cementation on detinned steel cans. True in-place copper leaching is being practiced in the caved stopes of an exhausted underground copper mine. Other innovative in-place copper leaching techniques have been tested commercially and laboratory- and pilot-scale experiments have been conducted to investigate proposed in-place leaching techniques for extracting copper from difficult-to-treat chalcopyrite ores. Solution mining of evaporites is being conducted commercially for the extraction of sodium chloride and potassium chloride. A large-scale experimental project for solution mining of trona has been undertaken.

Jan 1, 1982

By M. J. Ferrante

Laboratory-scale tests were undertaken to examine several electrolytes for possible use in separating nickel and cobalt from products being prepared at Nicaro, Cuba. The most extensive work was done with nickel sulfate-ammonium fluoride, ammonium fluoride, ammonium sulfate, and nickel sulfate-boric acid electrolytes. All four electrolytes exhibited some selectivity for dissolving nickel carbonate from Nicaro basic carbonate used for regeneration. The nickel sulfate-ammonium fluoride electrolyte exhibited less selectivity for dissolving nickel carbonate from Nicaro basic carbonate than it did from synthetic mixtures. Ammonium fluoride leaching experiments showed that a low concentration and high temperature gave a good nickel extraction with C. P. reagents; however, this was not confirmed in tests using Nicaro basic carbonate. Electrolytic tests employing ammonium fluoride leach liquors gave no further separation, since approximately 90 percent of the cobalt was deposited at the cathode with the nickel.

Jan 1, 1958

By Jacqueline A. McClaskey

The U.S. Bureau of Mines (USBM) Information and Analysis Directorate collects worldwide data on virtually every commercially important nonfuel mineral commodity. These data form the base for tracking and assessing the health of the minerals sector of the U.S. economy. The USBM's data collection activity was instituted by the 47th Congress in an appropriations act of August 7, 1882 (22 Stat. 329), which placed the collection of mineral statistics on an annual basis. The most recent authority for the USBM survey activity is the National Materials and Minerals Policy, Research and Development Act of 1980 (Public Law 96-479, 96th Congress). This act strengthens protection for proprietary data provided to the U.S. Department of the Interior by persons or firms engaged in any phase of mineral or mineral-material production or consumption.

Jan 1, 1995

By C. E. Rork

This paper discusses various mechanical improvements that have been gradually incorporated in the copper-willing plants of the Southwest daring the past 14 years, power plants for concentrators, use of large-size units of equipment, and the effect of plant capacities on costs. The improvements in mechanical equipment and plant design have contributed in the reduction of operating costs; in some instances a saving in the capital cost per ton of daily capacity milled has resulted.

Jan 1, 1935

By C. H. Manney

This report deals with the feasibility of the use of vocoders as an integral part of a mine electromagnetic voice communication system. Limitations imposed by the nature of the transmission path, background noise and equipment are examined. Some properties of vocoders and apparent advantages of the use of vocoders in a mine communication are discussed. The conclusion is reached that the man-made noise level will ultimately determine the workability of such a system.

Jan 1, 1972

By Pedro Lilienfeld

The objective of this program was the development, design, fabrication, and laboratory testing of a mine-worthy continuous respirable dust monitoring system (CRDMS). The operation of the sensor unit of this system is based on the light scattering intensity of the respirable fraction of airborne dust. The CRDMS is compatible with the typical environmental rigors that characterize coal mines and, in particular, the shock, vibration, impact, moisture and dust conditions prevailing at active training machines. The sampled area must be within the breathing zone of the mining machine's operator, whose dust exposure is to be monitored by the CRDMS sensor unit. Instantaneous, as well as shift-averaged dust concentrations, are displayed and recorded for later retrieval, Alarm indications and other diagnostic information are provided. The project was completed with the delivery of three sensor/display units (SDU), one data retrieval unit (DRU), two mining-machine-compatible power supplies, and two [auxilliary] battery packs.

Jan 1, 1983

By T. C. Green

A two-phase program evaluated commercial proximity warning devices and then served to design and develop an automatic electrostatic field strength measurement device with improved performance. The Phase I program consisted of test and evaluation of three commercial proximity warning devices, all of which operate on the principle of electrostatic field intensity measurement for determining proximity to high voltage power lines. Performance testing of these devices utilized full-scale cranes and power line systems and a scale model facility. The evaluation results were reported in the Phase I report entitled "Evaluation of Proximity Warning Devices" dated 22 February 1980. Under the Phase II program, a microproressor-based data acquisition system was designed and developed to collect and measure field strength at distributed points around the crane boom. This unit (referred to as the Distributed Sensor AC Electrometer) measures the field strength about a crane boom using 17 distributed sensors. Keyboard control is provided for the equipment operator. Measured field strength values are displayed on a line printer and recorded on magnetic tape. Laboratory testing of this unit demonstrated performance characteristics and field strength measurement accuracy within the design goals. A Phase III measurements program is proposed using the AC Electrometer to map the field strength contours about power line configurations.

Jan 1, 1981

By E. J. (Kirk) Conway

The objectives of this project were to: (1) determine the extent to which maintainability design concepts and principles have been applied to the design of underground coal mining equipment, (2) try to assess its impact on productivity and personnel safety, and (3) develop maintainability guidelines to enhance the design of new or rebuilt equipment. An equipment design review was completed at ten operational coal mines. The purpose was to identify design approaches and features that enhanced and degraded the maintenance process. Mine management, safety, and maintenance personnel were also interviewed to identify machine specific design problems. Six original equipment manufacturers were visited and the procedures used to enhance the maintainability of Their equipment discussed. Volume I of the Final Technical Report presents an overview of procedures and protocol used and a summary of the findings. Volume II includes the maintainability design guide for mobile underground mining equipment.

Jan 1, 1988

By R. Barany

This report contains the results of experimental work conducted by the Bureau of Mines to obtain the heats of formation at 298.15° K. of analcite, dehydrated analcite, lawsonite, anorthite, hexagonal anorthite, and leonhardite. Thermodynamic data for these minerals have applications in ceramics, extractive metallurgy, and particularly in geochemistry. Except for data on anorthite, no previous similar data existed. The present results will be a substantial aid in deriving the temperature-pressure-equilibrium relationships among these minerals. The heats of formation were determined by solution calorimetry, with hydrofluoric acid as the reaction medium. The results were expressed both in terms of the constituent oxides and in terms of the constituent elements. The heat of formation data were combined with related entropy values to obtain the free energies of formation at 298.15° K.

Jan 1, 1962

Electrical trailing cable used to power coal mining machinery is frequently damaged in usage because of tensile strain or crushing effect of mining machines running over the cable. One of the repair problems is finding the exact location of a short or open in this cable so it may be spliced or otherwise repaired. The U.S. Bureau of Mines and FMC corporation signed Contract No. H0 122011 in August, 1971, to develop instrumentation for finding faults in coal mine trailing cable. This report describes performance of several existing instruments as trailing cable fault locators and also construction details and performance records of several cable fault location instruments that FMC designed, built and tested as part of this project.

Jan 1, 1973

By Herman O. Ankenbruck

Analyses of statistical data indicate that haulage accidents are one of the largest sources of injuries and fatalities in underground coal mines, and that the rate of accidents in transportation has been increasing during the past few years. These previous analyses were performed by correlating accident or fatality data at a rather high level of miner activity. In this present investigation, underground surveys were made by observing conditions and activities in some detail at a rather low level of activity in an attempt to understand factors contributing to hazards in the specific situations observed. The aim of the current study was to derive preventive measures that might obviate the hazardous conditions and unsafe acts observed; and, following this, to provide recommendations for additional research and development to reduce accident potential in underground transportation. The major project tasks are diagrammed together with the task outputs in figure 1-1. Initially, a preliminary study of ell underground haulage operations was performed in order to establish the kinds of data needed and to provide the rationale leading to the data requirement. At the same time, the various types of haulage equipment used for each operation were defined. A preliminary analysis of each type of haulage operation was performed in order to establish the sequence of tasks required to operate haulage equipment. These tasks were transferred directly onto observation forms, and were used in developing interview forms. In parallel with the task analysis, a review was made of accidents and hazards that might occur during each type of operation.

Jan 1, 1975

By Leonard Obert

Part I of this report3/ proposed a sonic method for determining pressure, in situ, on rock pillar, arches, and other structures. The method required (1) a laboratory determination of the variation of the velocity of sound with pressure in samples of rock taken from mine pillars to establish a velocity pressure relationship for the type of rock, and (2) a measurement of the velocity of sound in the mine pillars from which the laboratory samples were taken. The pressure on the pillars could be determined by correlating the velocity in the pillar with the velocity-pressure relationship established in the laboratory. The success of this method depends on the extent to which velocity of sound varies with pressure. Furthermore, Young's modulus of elasticity, E, can be calculated from longitudinal velocity, V, by the relationship, E = V2d ...(1) where d = density. Hence, the variation of the elastic modulus with pressure also can be determined. It pointed out that this method might be extended to assist in the prediction of rock bursts, inasmuch as the rock is subjected to extreme pressure in these instances.

Jan 1, 1940

By Larry A. Haas

Carbonyl sulfide (COS) was decomposed to sulfur and CO in a silent electrical discharge. A threshold of about 4 kv at 60 Hz was required to dissociate the gas in a laboratory ozonizer at 790 torr with electrode gaps between 1 and 5.5 mm. Above the threshold value, the reaction rate increased with increasing voltage with helium or nitrogen diluent. With the latter diluent, higher voltages had to be applied to obtain the same yield in the 4-to 12-kv range. The COS decomposition rate increased with COS concentration, but a saturation value was reached at about 10 pct COS. The reaction rate decreased at low linear gas velocities as obtained at lower gas flows, larger electrode gaps, or larger reactor volumes. Increasing gas temperature also decreased the decomposition rate. The presence of solid adsorbents such as quartz wool, bauxite, or charcoal had no significant effect on the reaction rate. The addition of S02 did not affect the COS decomposition rate, but small amounts of water decreased the reaction rate. Over 50 pct of the COS was decomposed at room temperature and atmospheric pressure in a l7-kv ozonizer using a gas containing 0.9 pct COS in helium flowing at a rate of 0.3 liter/min. The average current was less than 5 ma. This method has possible application in eliminating the toxic air pollutant, COS, which is generated in petroleum refineries and in processes involving reactions between sulfurous and carbonaceous materials. Carbon monoxide that is formed can be further oxidized to CO2 after the collection of elemental sulfur.

Jan 1, 1972

By L. C. IlsLey

Many accidents rightly classifiable as electrically caused are not so classified for the reason that in numerous accidents the part that electricity played in causing the fatality is only suspected. For instance, a workman might receive a shock that would cause him to lose his balance and fall beneath a trip of cars; if no one saw the first part of the accident, the cause undoubtedly would be charged to "haulage." This paper covers a brief study of fatal and nonfatal electrical accidents. The first usually result from direct contact with the electrical circuit or electrical apparatus; the second more often are the result of arcing or flashing due to handling defective apparatus or making repairs on "live" equipment or circuits. It is hoped that helpful suggestions may be offered for minimizing accidents of these two classes.

Jan 1, 1938

By Leonard Obert

[Part I of this report3/ proposed a sonic method for determining pressure, in situ, on rock pillars, arches, and other structures. Tin r Loa required (1) a laboratory determination of the variation of the velocity of sound with pressure in samples of rock taken from mine pillars to establish a velocity pressure relationship for the type of rock, and (2) a measurement of the velocity of sound in the mine pillars from which the laboratory samples were taken. The pressure on the pillars could be determined by correlating the velocity in the pillar with the velocity-pressure relationship established in the laboratory. The success of this method depends on the extent to which velocity of sound varies with pressure. Furthermore, Young's modulus of elasticity, E, can be calculated from longitudinal velocity, V, by the relationship, E V2d .....(1) where d = density. Hence, the variation of the elastic modulus with pressure also can be determined. It pointed out that this method might be extended to assist in the prediction of rock bursts, inasmuch as the rock is subjected to extreme pressure in these instances.]

Jan 1, 1940

By W. L. Acherman

The Bureau of Mines found the chemical and galvanic corrosion behavior of the TZM and molybdenum-30 tungsten alloys to be generally equal or superior to that of unalloyed molybdenum in many aqueous solutions of acids, bases, and salts. Notable exceptions occurred in 1 [N] nitric acid, where both alloys corroded appreciably faster than molybdenum. In mercuric chloride solutions, the TZM alloy was susceptible to a type of crevice corrosion which was not due to differential aeration. The alloys were usually not adversely affected by con-tact with dissimilar metals in galvanic couple experiments, but the dissimilar metals sometimes corroded galvanically. Both alloys were resistant to substitute ocean water spray at 60° C.

Jan 1, 1968

By Henry C. Meeves

The Bureau of Mines, between 1956 and 1963, examined 18 major pegmatite districts in Arizona, Colorado, New Mexico, South Dakota, Utah, and Wyoming to evaluate their content of beryllium, a material in short domestic supply that has become increasingly important to modern industry. This examination report includes the salient statistics on the production of pegmatite minerals other than quartz and feldspar; and brief descriptions of 170 specific pegmatite deposits.

Jan 1, 1966

By Thomas L. Ochs

The stripping of iron-laden solvent with hydrochloric acid in the iron-removal step of the clay-hydrochloric acid process for the extraction of alumina from calcined kaolinitic clay results in a loaded ferric chloride stripping liquor. Treatment of this stripping liquor at boiling with calcined kaolin to form insoluble Fe203(s) and a dilute A1C13 solution was undertaken by the Bureau of Mines to characterize process problems and to aid in sizing of solids-liquid separation equipment. Variables identified as important in the chemical reaction were calcined kaolin particle size, ratio of calcined kaolin to FeC13, and reaction time. These parameters were tested for significance and their interactions investigated. Fine calcined kaolin (-65 mesh) at a greater than 1:1 mole ratio of contained acid-soluble A1203 to Fe203 equivalent of the FeC13 in the stripping liquor required less reaction time than coarser (-16 mesh) material. Solids-liquid separation of the reacted slurries by both settling and filtration requires flocculation.

Jan 1, 2011

By James E. Aplin

Previous studies have shown that fracturing of roof strata precedes ultimate failure, and that the fracture development causes an accompanying increase in the apparent resistivity of the strata. Using this principal, a microprocessor controlled resistivity roof fall warning system (RRFWS) was developed that automatically sequences through and records up to 32 electrodes that may serve as either voltage or current electrodes. This capability permits increased coverage with a minimal number of required electrodes. The data is stored in a nonvolatile memory and on an optional printout, making the system nonsusceptible to loss of mine-power. To further save battery power, the system's electronics shut down between readings, except for a carbon molybdenum steel real-time clock. At a preprogramed interval, the RRFWS reactivates and repeats the sequence. If the absolute change or the rate of change of resistivity exceeds a predetermined limit the system is capable of sounding an alarm. In addition to the monitor, a stainless steel mod led split-set electrode was also developed that permits long-term corrosion-free contact.

Jan 1, 1983

By M. C. Bleiweiss

Various light sources were evaluated for use in a fiber optic lighting system for mining machines. It was determined that a metal halide arc lamp was best because of its resistance to damage from shock and vibration and the high luminance of the arc. Measurements were made of the percent transmission of the ½ inch thick glass window and the fiber bundles, the total lumen output of the diffuser assembly with a known input and of the average surface luminance of the diffuser assembly. These data were then used to calculate the theoretical output of the system given an estimated input from the source. A prototype 55 watt, single-ended metal halide source was then developed. In order to provide greater efficacy and higher throughput through the fiber optic cables, a variation of the lamp with thallium iodide added to the fill was developed. The lamp was modified and a ballast was developed to allow it to hot restrike.

Jan 1, 1986