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By B. Das

The separation of iron values from a typical Indian iron ore slimes containing 57.2% Fe, 5.81% SiO2 and 7.05% Al2O3 by wet magnetic separation and selective magnetic coating is investigated. The iron phases, which are mostly paramagnetic in nature, have been coated with magnetite or colloidal magnetite in presence of surfactant by manipulating the surface properties of the minerals. The studies have indicated that an iron concentrate containing 62.32% Fe with 66.5% iron recovery can be obtained at medium magnetic intensity of 7.8 kG which is much less compared to normal magnetic intensity of 13 kG to14 kG required for hematite-goethite separation. The performance of this technique with respect to both grade and recovery is superior to conventional magnetic separation or flotation of iron ore slimes.

Jan 1, 2014

By A. Güney, G. Önal

"The tailings of the Bigadiç Colemanite Concentrator at the West of Turkey which contain 18 % B2O3 and 1.57 % SO3 are collected at the tailing dams near the Concentrator. In this research, it was aimed to obtain colemanite concentrates with a minimum content of 40 % B2O3 and a maximum 0.5 % SO3 from the tailings. At the experimental studies, decrepitation methods were systematically applied following attrition scrubbing and sizing. At the end of the tests, the best decrepitation result were described, at 500oC temperature for 15 min. duration, the final concentrate having 57.84 % B2O3, 0.44 % SO3 with 73 % recovery was obtained.Boron ores reserves of Turkey are about 2.5 billion tons and Turkey has the 63% share of the World’s boron reserves. The boron reserves are located at Eskisehir (Kirka), Kutahya (Emet), Balikesir (Bigadic) and Bursa (Kestelek) districts in Western Turkey. In 2002, the total amount of boron production of Turkey was about 1.4 million tons, which is 40 % of the World boron production.Bigadiç colemanite (Ca2B6O11. 5 H2O) ore with a content of 30-31 %B2O3 are concentrated by attrition tumbling and classification process. So the final concentrates with contents of 40 and 42 % B2O3 are obtained at the size fractions of –125+25mm and –25+ 3 mm respectively. The tailings materials with an 18 % B2O3 content are collected at the tailing dams near the Concentrator. In this research, it was aimed to obtain colemanite concentrates with a minimum content of 40 % B2O3 and a maximum 0.5 % SO3 from Bigadic tailings having 18 % B2O3 and 1.57 % SO3.In experimental tests, attrition scrubbing, wet sieving, gravity separation, electrostatic separation, flotation and decrepitation were adopted to the colemanite tailings, and optimum beneficiation conditions were obtained."

Jan 1, 2003

By M. Alvarez-Silva

The control of the amount of chromite reporting to the concentrate during the flotation of UG2 ore is of critical importance since its presence affects the downstream smelting process. It is generally reported that the main mechanism responsible for chromite recovery is through entrainment. This is reflected in analyzing the solids and water recoveries. These in turn are strongly dependent on the froth phase. In the present investigation a laboratory scale column flotation cell was used to investigate the role of the froth phase in the flotation of UG2 ore. Such a device is superior to a standard batch cell since it operates at steady state in open circuit and also allows for a greater degree of flexibility in terms of froth heights. The mass of solids and water recovered in the concentrate as well as chromite (Cr2O3) recovery by size class was determined as a function of froth height, superficial gas velocity and depressant dosage. The results showed that depressants had little effect on chromite recovery but increased the grade due to the depression of gangue minerals. A 60cm froth height always resulted in slightly lower solids, water and chromite recovery than for 30cm. Typically only 20-25 % of solids reaching the pulp-froth interface reached the launder. The relationship between solids and water recovery for a wide range of conditions indicated that chromite is mostly recovered by entrainment. Keywords: UG2 ore, column flotation cell

Sep 1, 2012

By A. Ekrem Yüce, Gülay Bulut, Feridun Boylu, Vecihi Gürkan, Istanbul Technical University, H. MustafaTarkan

"Nickel sulphide ores subjected to this investigation were taken from Orhaneli district where widespread chromite mineralisation can be occurred. Significant amounts of magnetite and chromite have been existed in the ore together with sulphide and oxide type nickel minerals. Ore sample is constituted about 70% magnetite, 15% sulphide minerals, 5% chromite and iron oxides as well as 10% gangue minerals.According to the chemical analysis results, the representative ore sample contains 1.32% Ni, 10.8% SiO2, 78.4% Fe2O3, 1.3 g/t Ag and 1.0 g/t Au. Mineralogical examinations showed that pentlandite (Fe, Ni)9S8, violarite (Ni, Fe)3S4, millerite NiS and asbolane (Co, Ni)MnO2.(OH)2.1-2H2O were the main nickel minerals and magnetite, chromite, chromium spinals, pyrite, pyrhotite, chalcopyrite, cubanite, goethite, hematite, limonite, rutile, chlorite, talc and serpentine group minerals as associated minerals.The aim of this investigation was to produce valuable nickel concentrates by using gravity separation, magnetic separation and flotation methods. As a results of laboratory scale studies, alternative flow sheets for the production of nickel sulphide concentrate were developed. The related experimental results are given in Table 1."

Jan 1, 2003

By T. Ueda, T. Oki, S. Koyanaka

"Accurate assessment of the liberation state of crushed ore particles is important for efficient mineral processing. In general, the liberation state is assessed by two-dimensional (2D) measurement of polished ore sample sections. However, this 2D measurement inevitably suffers from overestimation of the degree of liberation, known as stereological bias. This arises from the fact that biphase particle sections of which only one phase happens to have been cut are indistinguishable from liberated particles. To date, several stereological correction methods have been proposed, but their applicability for various types of particles has not yet been sufficiently examined, and this tends to undermine their practicality. We have addressed this problem using a numerical-analytical approach in which various types of biphase particles are modeled, and the 2D sectional information is compared with actual three-dimensional (3D) information. Through simulations, we revealed a general relationship between the internal mineral structure of particles and the stereological bias. Finally, we have developed a unique stereological correction method in which the texture (a 2D pattern characteristic) of particle sections is used to estimate the internal structure of particles, and thereby the stereological bias. KEYWORDS Mineral liberation, stereological bias, texture analysis INTRODUCTION Mineral liberation assessment of 2D particle sections inevitably suffers from stereological bias; that is, overestimation of the degree of liberation. Stereological bias is caused by the fact that a composite particle can be misidentified as a liberated particle when only one phase happens to have been cut in sectional measurement. Stereological bias has attracted attention since Gaudin pointed out its importance in 1939 (Gaudin, 1939). Several attempts have been made to measure the 3D liberation state directly, avoiding the bias, using X-ray computed tomography (Gay and Morrison, 2006; Lin and Miller, 1996; Miller et al., 2003; Miller et al., 2009; Reyes et al., 2017; Videla et al., 2007). These have provided useful information through laboratory testing, but further technical refinement is necessary for practical usage, to overcome the technique’s limitations in terms of resolution, assessment of minerals of similar density, and speed. Therefore, for practical purposes, detailed information regarding mineral phase geometry is obtained by sectional analysis, using automated scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDX)-based analysis (e.g., with a mineral liberation analyzer (MLA) (Fandrich et al., 2007; Sandmann, 2015)); and the development of an effective method of stereological correction, which predicts the relevant bias and transforms the measurable 2D degree of liberation into its 3D counterpart, is an important research aim."

Jan 1, 2018

By Ramon V. V de Araújo, Roberto B. E Trindade, Pablo R. Fica-Piras

"Lead has been reported to affect blood vessels and kidneys. It also produces adverse effects in the mental and physical development of children and nervous system of adults. It is also considered as a possible cause of cancer. Because of all these threats to the human life, the reduction of its environmental occurrence, by means of recycling, is an important additional advantage to the usual ones derived of the procedures of the secondary metallurgy: lead can be recycled several times maintaining its characteristics equivalent to the primary one.Furthermore, this way of producing the metal avoids the environmental impacts of primary lead melting. Also, as an additional advantage, it triggers the metallurgical process with a raw material in what we observe higher lead content than in the natural ores. Some of the potential sources for these purposes are: ashes, slags, electrode residues, anodic muds, spent electrolytes, solid and liquid wastes, industrial or automotive catalysts, worn-out or obsolete equipment components and/or final consumption products.About 40% of world’s lead production comes from automotive batteries, mainly composed of four parts: plastic box, electrolyte (diluted sulphuric acid), contacts and connectors of Pd-Sb and plates (PbSO4, PbO2 and PbO). The plates represent 75% of the total mass. Metallic parts can be melted at moderate temperatures and then refined. The remaining fraction, constituted by the non-metallic portions, can be recovered by hydro and electro-metallurgical routes. These routes are preferred instead of pyrometallurgical ones due to the ultimate emissions of lead particulates and sulphur dioxide.The principal constituent of the residual paste of batteries is the lead sulphate. In this process, the paste is treated in two stages: in the first, lixiviating with Na2CO3 (desulphurization of the paste), obtaining PbCO3 and Na2SO4; in the second, the lead carbonate is lixiviated with HNO3, producing Pb(NO3)2, soluble, that can be converted to metallic lead by electrolysis. The reaction of PbSO4 with Na2CO3 in aqueous solutions is fast: the global rate is limited by the diffusion of the carbonate ions inside the reaction medium."

Jan 1, 2003

By Markus A. Reuter, Joep Verwoerd, Marc J. A. Pijnenborg, Yongxiang Yang

"Incineration is a proven disposal technology for all waste materials with heat release potentials, and provides high degree of toxic destruction and control for a broad range of hazardous materials. In the Netherlands, all the hazardous wastes are processed at AVR-Chemie located at the Rotterdam harbour, through rotary kiln incinerators. The newly enforced regulations from the European Union with stricter emission levels require a better understanding of the incineration process and improved process control. However, the transport phenomena and combustion processes within the kiln system are very complex and not well understood. In order to get better understanding of the incineration process, research has been carried out to study the fluid flow and combustion behaviour of the incineration system. Computational Fluid-dynamics (CFD) was used to simulate the gas flow and waste combustion process, and temperature measurements of the operating rotary kiln incinerator were conducted to validate the CFD model. This paper will present the latest results from the current research project for simulating gas flow and combustion heat transfer for a wide range of hazardous waste streams.The simulation of the waste incineration process was carried out using a general-purpose CFD code Phoenics. The rotary kiln and the secondary combustion chamber (SCC), with a waste processing capacity of 50,000 ton/y and an energy input of 30 – 40 MW, is translated into a CFD model. The model includes a k-e turbulence model and a global gas-phase combustion model (3-gas or 7-gas combustion model). The 3- gas model (Simple Chemically-Reacting System, SCRS) predicts only the thermal effect of the fuel combustion, and only one global fuel is used, therefore, real chemical species are not taken into account. In the 7-gas combustion model, (an Extended SCRS, ESCRS), different forms of waste fed into the incinerator have been modelled into a mixture of a general hydrocarbon fuel C3H4 and other components such as CO, CO2 and H2O. Thus, all the incoming fuel streams with different compositions and calorific values can be properly converted into separate inlets. The combustion of the waste is assumed to take place only in gas phase in two steps: (1) primary combustion of the main fuel component C3H4 to form CO and H2, (2) secondary combustion of CO and H2O to form CO2 and H2O. The rate of each combustion reaction is assumed to be controlled by turbulent mixing of fuel and oxidant (air or oxygen), i.e. the Eddy-Break-up (EBU) model. The resulted temperature field was validated with temperature measurement data, and the simulated temperature distribution from both 3-gas and 7-gas model have reasonable agreement with the measured data."

Jan 1, 2003

By C. Raghu Kumar

Hydraulic or teetered bed separators (TBS) are finding new avenues for application in the field of mineral processing. Floatex Density Separator (FDS) is a hydraulic/teetered bed separator capable of operating at high tonnage due to its advanced instrumentation. FDS/TBS is being used in Indian mineral sand industry for classification and segregation of different minerals. The purpose of this paper is to provide details on the performance of the plant scale FDS in recovering the chromite from feed (below 1mm size). Historically this feed has been processed using hydrocyclones and spiral classifiers; however, there is a strong trend now to employ teetered bed separators, thus allowing significant changes to be made in the plant for improving process efficiency. In the present work, the performance of the plant scale FDS is described in terms of partition curve (yield, cut size, classification efficiency/Ep) for different combination of process variables and also in terms of metallurgical grade and recovery. It is found that, efficient classification can be achieved at a maximum cut size of 380 µm with and the imperfection is also reported as low as 0.16. The grade of the underflow product is enriched as maximum as 52.2% Cr2O3 from a feed assaying 40.4% Cr2O3.

Sep 1, 2012

By Y. E. Brylyakov, M. A. Kostrova

"The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. In this connection, the magnitude of cation exchange, along with the content of P2O5 and CO2, is an important property of apatite staffelite ore, which largely determines the performance of concentration processes. In the examined ASO samples, the magnitude of cation exchange measured in terms of Ca2+ is 2546-4790 g/ton. The conducted laboratory studies of apatite staffelite ores with various mineral composition showed that adding calcined soda improves the recovery of P2O5 into the flotation concentrate. Full-scale tests were conducted at the apatite staffelite ore processing plant at Kovdor Mining and Concentration Operation and demonstrated the high performance of the proposed agent treatment. The test results showed that in the flotation of apatite staffelite ores, the optimum calcined soda feed rates range from 3,500 to 5,000 g/ton of the flotation feed. With close flotation feed and concentrate grade parameters, the P2O5 recovery gain is 17%. The effect of adding soda is associated with the desorption of the hardness cations from the minerals, precipitation in the pulp and, accordingly, improvement in the ionic composition of the liquid phase of the flotation feed due to a reduced content of calcium ions. Based on the test results, the proposed agent treatment with an elevated feed rate of calcined soda was implemented at Kovdor Mining and Concentration Operation in the flotation of apatite staffelite ore. The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. These minerals have certain properties requiring a more detailed examination for a better understanding of the flotation properties of apatite staffelite ores."

Jan 1, 2018

By N. T. Beukes, W. Banda

Recovery of Co from slag is a recent advancement in the extractive metallurgy of nonferrous metals. In this study a DC arc technology at laboratory scale has been applied to investigate the selective recovery of Co from slag, under three different flux types with an emphasis on influencing the activity of FeOx, SiO2 and CoO in the slag. It is known that reduction of slag by carbon is only up to a certain level after which, the recovery will depend on the chemistry of the slag, hence the need to modify the slag chemistry. Two power settings were employed to induce higher temperatures and aggressive agitation. The results were interpreted by comparing how much Co and Fe was in the slag and alloy. TiO2 reduced the amount of Fe in the product alloy compared to when CaO and CaF2 were used. The change in power did not seem to have had a major effect on the recovery although the amount of material lost to flue dust was more at a higher power rate.

Jan 1, 2003

By Hiroshi Sasaki, Herman D. Mendoza

"The surface-chemical property of nickel slag fiber was modified in aqueous media in order to act as an active and efficient collector of colloidal amorphous silica from geothermal effluent. Colloidal amorphous silica (0.05 µm) from geothermal wastewater causes operational and ecological problems. It clogs geothermal pipes and waterways, and when disposed to the environment poses hazardous effects on both the flora and fauna ecology. Because colloidal amorphous silica is extremely fine and remains in suspension in aqueous media, conventional solid/liquid processes to remove colloidal silica from its bulk liquid are rendered ineffective.A rapid separation technique is then developed to remove effectively amorphous colloidal silica from its bulk liquid by attaching the extremely fine particles of silica onto a nickel slag fiber coated with magnesium hydroxide, Mg(OH)2. The nickel slag fiber has the following characteristics: a high surface area and predominantly possesses negative charge in aqueous media with an iso-electric point at pH ~2.5. When soaked and saturated with Mg(OH)2 solution, the surface of the nickel slag fiber becomes coated with fine and compacted Mg(OH)2 precipitates. This modifies the surface- chemical property of nickel slag fiber transforming the negatively charged surface into a positively charged surface in aqueous media with an iso-electric point of around pH 11.8, which corresponds to the iso-electric point of Mg(OH)2. When geothermal effluent containing negatively charged colloidal amorphous silica particles (i.e.p. of silica is pH 2) is passed through a column-bed packed with surface-chemically modified nickel slag fibers under natural pH conditions, the colloidal amorphous silica particles are recovered by attachment onto the surface of the surface- modified nickel slag fiber. The recovery of colloidal amorphous silica by attachment is 97-99%, resulting in the production of a relatively clean and silica free output. Aluminum hydroxide, Al(OH)3, was also used to modify the surface –chemical property of the nickel slag fiber. In the same way, it also exhibited a positive response with the collection of colloidal amorphous silica from its bulk liquid, but yielding a lower recovery of 90%. This may be attributed to the lower surface potential and iso-electric point of pH 9.3 for Al(OH)3. The separation process was evaluated and analysed using existing potential energy theories. Figure 1 shows a micrograph of the surface of an unmodified and the Al(OH)3 –modified surface of nickel slag fiber."

Jan 1, 2003

By M. M. Fan

In Florida?s phosphate industrial practice, the most favorable upper size limit of froth flotation is 1.18 mm which corresponds to particle weight of about 2.8 mg. Conventional froth flotation is not efficient in upgrading coarse particles (+0.425-1.18 mm). A limited number of studies have been devoted to understanding and improving coarse particle flotation. We have shown that the coarse particle flotation performance can be significantly improved by the presence of picobubbles generated by hydrodynamic cavitation. In this study, the size of picobubbles produced under certain hydrodynamic conditions was measured by a laser particle size analyzer. A size-by-size flotation performance analysis of coarse phosphate froth flotation in the presence of picobubbles is conducted in terms of flotation kinetics, selectivity and recovery. It was found that picobubbles doubled the flota-tion rate, increased the P2O5 recovery more significantly for +0.85-1.18 mm particles than +0.425- 0.6 mm and +0.60-0.85 mm particles. At a given acid insolubles (A.I.) rejection, the presence of picobubbles increased the P2O5 recovery by up to about 25%.

Jan 1, 2014

By I. Blayda

The purpose of this work is to study and make comparative analysis of germanium extraction and related valuable components of the sublimates from the burning of domestic power coals (product 1) and germanium sulfide materials, which are a waste of lead-zinc production (product 2), by traditional chemical methods (distillation of germanium in the form of tetrachloride from raw and preliminary burning source) and by microbial bioleaching of sulfur-oxidizing bacteria. The dependence of the germanium extraction by chemical methods from phase composition of the initial raw materials was installed. The germanium tetrachloride extraction from products 1 and 2 were 78.50 and 19.52%, respectively. Such difference in indexes on extraction, is caused by germanium confinement as concomitant trace component to the basic phases to carriers. The share of acid-non-soluble compounds (tetragonal modification GeO2 and silikogermanaties) in the product 1 account for 21.5 % of germanium. Ratio between acid-soluble and acid-not -soluble germanium forms are 19.52 and 80.48 %, respectively, in the product 2. Our experiments have shown, that implementation of restorative firing (with addition of 30-40 % carbon at 1150 0?) of sulfide product 2 considerably impacted on the extraction of germanium tetrachloride (91.76 %) in comparison with its low enough extraction at straight distillation of hydrochloric acid (19.52 %). The results are confirmed by a set of physical methods. The results of processing the same so-called hard phase?s material (product 2) with the help of microorganisms are presented. It Has been established, that selected strains of bacteria are capable of extracting from initial raw materials not only macro components (iron, zinc, lead, manganese, aluminum, nickel), but also micro impurity of rare metals (gallium, germanium, zirconium). It is important that these metals were not extracted by traditional chemical methods (with application of aggressive conditions and heats) independently of the phase composition of the source. Almost complete extractions of germanium in solution using sulfur-oxidizing bacteria take place in the first day of the process independently of the phase composition of the source and the type strain. The results have practical significance and can be the basis for developing a unified biotechnological method of technogenic waste processing with a purpose of their sterilization and detoxification with simultaneous obtaining concentrates of valuable metals. Keywords: germanium, extraction, sublimates, bioleaching, sulfur-oxidizing bacteria.

Sep 1, 2012

By Isaak I. Maksimov, Tatyana E. Koltunova, Mikhail F. Yemelyanov, Liudmila A. Otrozhdyonnova

"INTRODUCTIONMetals losses amount up to 50% in coarse fractions in (>100 µm) and composite particles, and to 20- 25% in fine fractions (<10 µm) at non-ferrous floatation concentrating plants of the CIS. Therefore, reduction of metals losses in difficult fractions is of high significance.IMPROVEMENT OF FLOATABILITY OF COARSE AND COMPOSITE PARTICLESReagent regimes with application of strong collectors – xanthates ?5-?8, combination of butyl xanthates and aerofloats ?10-?12, butyl xanthates with hydrocarbons are proposed for this purpose. Application of such reagent regimes for copper and copper-molybdenum ores permitted to increase copper and molybdenum recovery by 0.5-3.9%.Studies, performed by means of specially designed non-frothing flotation machine with independently controlled agitation intensity and narrow size-ranges of air bubbles, established that the best results are achieved with employment of bubbles of 0.5-0.8 mm size regarding particles of any size, with small amounts of up to 2 mm size “transport” bubbles to be expediently used for floatation of coarse particles.Energy dissipation in the main volume of floatation cells must be lower than 0.2-0.25 m2/s3.Performed experiments permitted to formulate requirements to development of machine for floatation of coarse and composite particles. Such floatation machine with volume of 8.5 m3 provided for weak agitation in the main volume of floatation cell and uniform distribution of coarse particles throughout the depth owing to establishing of pulp circulation with upward flows. In addition, in the upper part of floatation cell where agitation is considerably weaker, favorable conditions are created for attachment of particles to bubbles. Testing of this floatation machine demonstrated a 7.5% increase in recovery of +0.2 mm particles in pyrite floatation and a 12-14% increase in recovery of +0.2 mm particles in apatite floatation as compared with a reference floatation machine."

Jan 1, 2003

By A. Yörükoglu

In this study, thorium mineral that found in the complex ore deposit bearing bastnasite, fluorite, and barite from Eskisehir - Sivrihisar district has been tried to extract by using HCl and H2SO4 leaching. Ore sample of approximately 3 tons taken from the ore deposit has been homogenized in order to obtain composite samples by means of ore preparation techniques for experiments. Results of chemical analyses of composite samples are as given; 40.8% CaF2, 35.35% BaSO4, 2.01 Ce, 1.5% La, 0.39% and 0.1% Th. HCl and H2SO4 leaching processes have been performed to gain Th in the ore. For determining the optimum particle size, the samples have been ground under controlled conditions and brought to the sizes of 0.065, 0.2, 1 and 3 mm. Leaching experiments have been carried out in both HCl and H2SO4 acids without roasting and roasting at the temperature of 900°C for 1, 3 and 6 h retention times for all particle sizes determined before. In the experiments, the highest Th recoveries reached are as follows; 78.74% Th when H2SO4 and 1 mm particle sized sample used, and 1 h roasting applied and 73.38% Th when HCl and 1 mm particle sized sample used, and 3 h roasting applied. Keywords: thorium, leaching, concentration, sivrihisar, roasting

Sep 1, 2012

By Jiongtian Liu, Guixia Fan, Caom Yijun

A cyclonic-static micro bubble flotation column (FCSMC) is an effective separation device for fine grain treatment. The separation of fine ilmenite by FCSMC was explored in this work. The influence of reagents dosage (regulator, collector and auxiliary collector), pulp density, circulation pressure and aeration quantity on TiO2grade and recovery wasinvestigated.The optimal conditions of a rougher are follows: pulp density 45%, pH 5.0, MOH collector dosage 2800 g/t, diesel oil dosage 700 g/t, circulationpressure 0.19 MPa, aeration quantity 0.8 m3/(m2•min). The optimal conditions of a cleaner are follows: pH 4.0, circulation pressures 0.16 MPa, and aeration quantity 0.5 m3/(m2•min).A pilot plant continuous test with a rougher-cleaner by FCSMC for 72 hours was proceeded under the optimum conditions. Compared with industrial flotation machines, the concentrate grade of FCSMC is 48.11% with an improvement of 1.08 percentagepoints, while the recovery is 82.36% with 13.64 percentagepoints increment. Moreover, the flowsheet is simplified from six parts (a rougher-two scavenger-three cleaner) in flotation machines to two parts (a rougher-cleaner) in FCSMC. Proofs were also provided by the analysis of the by-size grade and recovery of concentrate.Results show the FCSMC is an effective separation device to recover -74 µm size fraction.

Jan 1, 2014

By X. M. Yu

A large amount of polluted sludge is produced by a nonferrous metal factory after treating waste water with lime/ferrous salt. The concentration of arsenic in the dried sludge is high to 5.84%, a toxicity test is taken on the sludge according to GB5085.3-2007 and the extraction content is 15.75mg/L, which surpasses the arsenic extraction standard [As]=5mg/L, the sludge is categorized as hazardous waste. If put outside without disposal, it would be very harmful to environments. Here we report an optimum protocol to extract arsenic; S2- alkaline liquor is utilized to treat the arsenic sludge. At 85?, 10L 7% S2- liquor is added into 1kg dried sludge and the resulting mixture is stirred for 120min at 250r/min, then separated by centrifugation and the compressed waste residue dried naturally. The average arsenic content is 1.40mg/L, lower than GB5085.3-2007 Standard and arsenic-free residue is consistent with GB18598-2001 Standard, which can be bury safely. The extracted arsenic is transferred into copper arsensite for use as addictive in copper electrolysis and the waste water can be recycle after calcium is removed.

Jan 1, 2014

By M. Nonaka

An attempt to produce fuel from biomass waste by hydrothermal treatment has been made with expectation to effectively utilize a renewable source of energy and an unexploited energy resource. In this paper, we have used empty fruit bunch (EFB) that is a residue after recovery of crude palm oil from palm oil trees in a plantation in a tropic country. A hydrothermal treatment was conducted using a 500 mL autoclave, with alkali (K2CO3) catalyst. EFB was decomposed more by alkali catalyst of lower alkali content and rather polymerized in higher catalytic region. The functional group composition of the solid phase oil is similar independent of alkali content, however its burning characteristic became more incombustible with increasing alkali content.

Jan 1, 2014

By R. X. Li

The overall flow-sheet of producing chromium (III) sulfate is described in this paper. The suitable conditions of each process such as sintering, leaching, aluminum removal, reduction, and de-composition conditions were experimentally studied. The results show it is reasonable to produce chromium (III) sulfate with the flow-sheet pointed out in this research work. The final product is Cr2(SO4)3 solution contained 150~250g/L Cr.

Jan 1, 2014

By D. Moradkhani

The heap leaching of oxide copper ores with copper cathode recovery by solvent extraction and electrowinning is now well established as a low-cost method of copper recovery. The main purpose of this study was to extract copper from the copper low-grade oxide ore of Chodarchaei mine using column leaching. The copper oxide ore contained 1.1% Cu and 1.75% Fe. The mineralogical analysis indicated the malachite (Cu2(OH)2CO3) was mainly composed of oxidized phases. The sulfuric acid leaching experiments were performed under the laboratory conditions. The influence of several parameters on the course of the reaction such as particle size, acid concentration, flow rate, and time was examined. The optimum collective extraction of copper and iron was obtained at a particle size of +10-15 mm for a leaching duration of 3 days with sulfuric acid concentration of 100 gpl and using a flow rate of 2.5 cc/min. Under these conditions, the recovery of copper and iron were 98.54% and 41.99%, respectively. Keywords: column leaching, copper, iron, working diagram.

Sep 1, 2012