Search Documents

By S. Timbillah, R. LaDouceur, C. A. Young

A low carbon-chain trithiocarbonate ((NaOOC)CH2SCSSNa), known as Orfom® D8, was tested as an organic depressant in the differential flotation separation of chalcopyrite and molybdenite in the presence of sodium isopropyl xanthate (SIPX) or potassium ethyl xanthate (KEX). Flotation studies show that Orfom® D8 depressed chalcopyrite while molybdenite remained floatable. A study of the mechanism of adsorption indicated that Orfom® D8 adsorbs on chalcopyrite through its trithiol (CS -) functional group via both chemisorption and Orfom® D8-metal complexation. The Orfom® D8 depressant is selective and does not form any Orfom® D8-molybdenite bonds. Thus, the combination of the depressant in the presence of either collectors depressed the chalcopyrite and floated the molybdenite. Fundamental parameters of the Orfom® D8 including pKa determination as well as possible decomposition products of the depressant are reported. This study includes an economic case illustrating why using Orfom® D8 can be beneficial. INTRODUCTION Depressants are incorporated in mineral flotation units in the minerals processing industry to make or keep certain minerals selectively hydrophilic. Most reagents used are inorganic and include, for instance, sodium hydrosulphide (NaHS) which is the major reagent used for depressing sulphide minerals, particularly those containing copper, iron and lead. However, the issues with its use include high toxicity, tendency to explode, strong odour, and high consumption due to required high dosages as well as its tendency to oxidise in air. The latter can be overcome by conducting flotation in inert atmosphere such as nitrogen and recycling of the flotation process water. The use of more novel depressants that are essentially organic including homopolar reagents with hydrophilic functional groups on both ends of its structure adsorb onto a target mineral surface with one polar end, the other polar end orients into the bulk solution making the surface hydrophilic and thus, ensuring that the desired mineral does not float. The stringent environmental and safety regulations being implemented in recent times mean that the search for more environmentally friendly chemical reagents is a must have. The use of organic depressants for flotation systems such as Cu-Mo sulfide bulk concentrates has become increasingly important because of the health, safety and environmental issues surrounding the use of inorganic depressants. Nagaraj et al. (1983) investigated the Cu-Mo sulphide flotation system using a structure-activity study of depressants. They found that a major advantage of organic depressants is the ability to tailor-make organic molecules to suit many requirements and thus, eliminate the guess work approach that was predominant in the industry.

Jan 1, 2019

By J. D. Bateman, A. S. Dadson

"The Giant claims are on the west side of Yellowknife bay about 1 ½ miles north of the settlement of Yellowknife. They were staked in 1935 by prospectors in the employ of Burwash Yellowknife Gold Mines, Limited, and were transferred to Giant Yellowknife Gold Mines, Limited, in 1937, on the incorporation of that Company. During the period 1936 to 1940 a number of surface discoveries were investigated by trenching, test pitting, and diamond drilling. A shallow inclined shaft was sunk on the Brock zone, a system of narrow and irregular quartz veins, and some 75 tons of high-grade ore was mined and shipped to the Trail smelter. In 1943 management control was acquired by Frobisher Exploration Company, Limited. An intensive campaign of diamond drilling was commenced in January 1944 and carried on continuously for 2 years. This drilling indicated the presence of substantial gold orebodies lying within well-developed shear zones. Two shafts, 1 ¼ miles apart, were sunk during 1946 and underground development started on two of the orebodies.The claims are underlain largely by rocks of the Yellowknife greenstone belt, which extends from the shore of Great Slave lake along the west side of Yell ow knife bay and northward . The most conspicuous structural features are the steeply dipping late faults. The chief of these is the West Bay, which bisects the greenstone belt at an acute angle and crosses the southern part of the Giant group. At the 'big bend' near the west boundary of the claims there is a remarkably sudden change in the strike of the fault, from about 12° N.W. to about 3° N.E. The apparent horizontal displacement along this fault is of the order of 3 miles, with the east side moved relatively north. There are also a large number of lesser faults with apparent horizontal displacements of a few feet up to l,70J feet for the Townsite fault. Most of these faults trend north to northwest. Surface examination indicates that, at least for most of them, the movement corresponds to that along the West Bay fault, that is, the east side moved relatively north. According to the available evidence, all or most•of the movem:nt along the West Bay fault and along the lesser faults was post-ore. Late diabase dyk:s that cut through ore-bearing shear zones, with chilled margins in contact with the mineralized material, are apparently displaced to the same extent as earlier geological markers. ( see Frontispiece. )"

Jan 1, 1954

By Adrianus (Adrian) Halim, Tomas Bolsöy, Stina Klemo

"This paper describes the ventilation system used in underground hard rock mines in Sweden and Finland, which is very different than the system used in other major mining countries such as Australia, Canada, South Africa, and USA. The system utilizes auxiliary fans with Variable Speed Drive to distribute primary airflow to working levels instead of regulators that are commonly used in other countries. Descriptions about Ventilation on Demand in this system and ventilation regulations in Sweden and Finland are presented in this paper. This paper also quantifies a comparison between the Nordic and the system used in other countries. KEYWORDS Auxiliary fan, Regulation, Ventilation on demand (VOD), Variable speed drive (VSD) INTRODUCTION The primary objective of an underground mine ventilation system is to provide sufficient airflow to dilute atmospheric contaminants that are produced by mining activities. Typically, a mine ventilation system consists of one to four primary fans, regulators to control primary airflow distribution to levels or panels, and auxiliary fans that distribute airflow to dead-end workings via ducts. Depending on circuit geometry, underground booster fans are sometimes used. This system is widely employed in many countries such as Australia, Canada, USA, United Kingdom, and South Africa. However, mines in Nordic countries such as in Sweden and Finland employ a different system, in which auxiliary fans instead of regulators are used to control primary airflow distribution, as well as distributing airflow to dead-end workings. This paper describes the general layout of Nordic ventilation system, its VOD and heating system, its comparison with the system that is widely used in other countries which is referred as “Non-Nordic ventilation system” in this paper, and the current ventilation regulations in Sweden and Finland. The comparison was quantified by doing simulations using Ventsim Design 5 software. DESCRIPTION OF NORDIC VENTILATION SYSTEM General System Layout Figure 1 shows a schematic of typical ventilation system used in Swedish and Finnish mines. The schematic was drawn by Franzen, Myran, Larsson, and Rustan from Stiftelsen bergteknik forskning (Swedish Rock Engineering Research Foundation) and the English translation is written next to the Swedish terminologies. The system is generally a push-pull system. None of Swedish and Finnish mines use exhaust system. As shown in Figure 1, the primary airflow is distributed to levels by auxiliary fans that are bolted to a bulkhead located in the access to intake raise/shaft. These intake fans are attached to ventilation ducts that distribute airflow to all working faces. The exhaust auxiliary fans, which are not attached to any ducts and also are bolted to a bulkhead located in the access to exhaust raise/shaft, then flow the exhaust airflow into the exhaust shaft. A small quantity of this exhaust air is directed into the ramp, which acts as another main exhaust airway. The deepest level is also equipped with booster fan(s) that draw air from the intake shaft/raise and direct it into the ramp to provide fresh air in the ramp. There is no free split in this system. Figure 2 shows a schematic of a level ventilation layout in the Nordic system. Figure 3 shows a photo of these auxiliary fans."

Jan 1, 2019

By V. A. Leão, M. L. M. Rodrigues, L. C. Sicupira, I. C. B. Rodrigues, T. C. Veloso

Brazilian sulphide ores can contain a significant content of chloride and fluoride, which are harmful to bacteria and thus bioleaching. This work summarizes a four-year research investigation on the effect of fluoride on both bacterial growth and sulphide bioleaching, supported by studies carried out with secondary copper ores. Firstly, the influence of fluoride on the kinetics of ferrous iron bio-oxidation with Sulfobacillus thermosulfidooxidans was addressed. Values as low as 10.0 mg/L F- fully inhibited bacterial growth, although fluoride toxicity could be overcome by the presence of aluminium, which reduced the concentration of hydrofluoric acid through the formation of aluminium-fluoride complexes. This required at least a 2:1 aluminium/fluoride molar ratio, which ensured bacterial growth rate values similar to that observed in the absence of fluoride ions. Subsequently, both batch and column bioleaching with mesofiles (30 ºC), moderate thermofile (50 ºC) or hyperthermophiles (67.5 ºC) of two secondary copper ore samples were analyzed with focus on the relevant effects of fluoride-containing minerals on the bioleaching of such sulphide ores.

Jan 1, 2014

By J .. R. Dalton

"Blasting in high sulphide content ores presents at least two major safety considerations: (1) compatibility of the explosives with the ore while resident in the borehole; and (2) introduction of a flame and shock producing explosive into this environment, while minimizing the risk of reactive ignition in the chemical reaction products/sulphide dust cloud resulting from the detonation. This paper will discuss only the second consideration, i.e. post detonation reactivity.The ETI (Explosives Technologies International) Technical organization, in consultation with the U.S. Bureau of Mines, reasoned that the most relevant considerations in the development of an explosive for this application are:• minimization of reactive gaseous detonation reaction products;• flame duration reduction;• flame temperature reduction;• increased explosive sensitivity;• reduced probability of ""low order"" detonation; and• maintenance of energy level as high as possible.Obviously, not all of these are totally independent properties, i.e. increased sensitivity will reduce the probability oj low order detonation as will higher energy levels. However, these considerations were examined separately as if they were independent."

Jan 1, 1994

By X. Cao, B. S. Naik, D. L. Chen, P. Wanjara

AZ31B-H24 Mg alloy sheets with a thickness of 2 mm were friction stir lap welded (FSLWed) at two tool rotational rates of 1000 and 1500 rpm and two welding speeds of 10 and 20 mm/s. The tensile behavior of the FSLWed AZ31B-H24 Mg alloy was then evaluated at low (-40°C), room (25°C), and high (180°C) temperatures. It was observed that the failure load increased with decreasing tool rotational rate and increasing welding speed. The maximum failure load occurred at a tool rotational speed of 1000 rpm and a welding speed of 20 mm/s at all temperatures tested. It was also noticed that at the high test temperature, the samples failed along the sheet interface, i.e. shear fracture. At the low and room temperatures, the samples failed on the advancing side (AS) of the top sheet near the interface between thermo-mechanically affected zone (TMAZ) and stir zone (SZ). The different modes of fracture observed are associated with the hooking defect.

Jan 1, 2014

By V. S. Sastri, G. R. Doey, R. W. Revie

"Different forms of corrosion, the various corrosive environments encountered, the mining equipment subject to corrosion and the methods to control corrosion in the mining industry are briefly reviewed along with the savings that could be achieved by corrosion control. IntroductionCorrosive conditions in mines and metallurgical plants, lead to deterioration and wastage of equipment and of materials. The cost of corrosion in the mining industry can be significant, and measures to minimize corrosion must be taken to reduce this cost(l-3). Although the data in Table I are twenty years old they indicate the significance of corrosion costs in four industrialized countries. The costs of corrosion in the U.S. metallic ores sector and in the Canadian mining industry are presented in Tables 2 and 3, respectively. Significant savings in the mining industry can be achieved by using corrosion control methods. For example, corrosion in the Canadian mining industry in 1991 cost $1460 million of which $97 million was avoidable. Indirect costs of corrosion associated with plant shutdown, lowered efficiency of equipment and overdesign are additional to the direct costs cited here."

Jan 1, 1994

By A. E. Gillis

"Some or all of the following benefits can be expected following application of automatic control to a grinding circuit:1. Maintenance of Optimum Mill Load Level2. Improved Uniformity of Grind3. Increased Productivity4. Decreased Power Costs per Unit of Product5, Reduced Ball Wear per Unit of Product6. Reduced Labour Costs per Unit of Product7. Reduced Operator SupervisionTo establish an indication of the benefits that could be expected through automation of the grinding circuit at East Malartic Mines Ltd. it was agreed that the Department of Mines and Milltronics Limited should jointly conduct a survey of the existing grinding circuit and operation.Aside from establishing feasibility, an important purpose of this survey was to determine costs of a suggested control system that East Malartic Mines Ltd. management might be in a position to assess the economics of the proposal and justification of the investment.The survey involved the taking of sound recordings of rod and ball mills during manual operations, locating circuit bottlenecks, establishing time constants and determining the number and location of sensors for good automatic control."

Jan 1, 1966

By S. C. Tadolini

"Roof bolts are the primary means of roof support in underground mines in the United States. Presently, post installation loads are measured on about 10% of the expansion anchor and combination bolts by using standard torque wrenches that Unit the accuracy of the measurements to about ±30%. No system has been available for measuring the loads generated on full-column resin grouted bolts. Mine roof bolts are long, slender, non-uniformly sized, roughly forged, and placed in a corrosive environment, creating obstacles for researchers trying to utilize ultrasonic reflection techniques to measure strain. A complete measurement system has now been developed by the U.S. Bureau of Mines, Denver Research Center. This system is being used successfully in determining loads measured on expansion anchor and combination bolting systems, examining the transfer mechanics of full-column, resin-grouted bolts, and measuring loads generated on bolts in an underground roadway support system.IntroductionMillions of roof bolts are used each year to provide structural support in underground U.S. metal, non-metal, and coal mines. Approximately 45% of the bolts used are expansion anchor, 45% are resin-assisted combination or full-column resin-grouted, and 10% are friction anchored. The effectiveness of these bolting types is dependent on a number of factors including rock density, bolt length, in situ stresses, rock properties, bolt pattern, installation tension, etc. When implementing expansion anchor and resin assisted combination bolts , installation and post-installation tension, or load, is a major determinant of support quality and subsequent behaviour of the reinforced roof. The method by which these systems carry roof loads is well understood and documented(1,2).The importance of these installation and long-term bolt tension measurements is well recognized and are required in the federal government regulations(3). A statistical sample of the bolts, lout of 4 during installation and lout of 10 inby the last open crosscut, is required to be measured using current torque wrench technology. The disadvantages of this system are the disturbance and weakening of the anchorage and limitations of accuracy to approximately ± 30%. The method by which resin-grouted bolting systems carry roof loads is much less understood, mainly because testing procedures used to evaluate point-anchor systems are not effective on resin-grouted bolts.Due to these problems, the U.S. Bureau of Mines designed a measurement technique that provided a highly accurate, low cost-per- bolt system that led to the development of ultrasonic pulse echo instrumentation. The original system was designed to measure the tension only on expansion anchor bolts. Recent developments and system modifications have permitted measurements on resin-assisted and full-column resin-grouted bolts. The use of these types of support systems has been increasing steadily in underground coal mines.The development of this instrumentation has provided laboratory and field results that help to explain the mechanics and relationships between the applied loads and the interaction between the grouted bolt system consisting of the bolt tendon, grout, and rock."

Jan 1, 1990

By S. Kobayashi, N. Ohara, T. Aoki, S. Sakurai, M. Iwano, M. Shimo, I. Otsuka

"This project is the upgrading of a commuter line of approximately 76 km to improve the railway system in Istanbul metropolitan area. Railway tracks have been connected between Asia and Europe through a tunnel under the Bosphorus Strait. The length of these underground structures sums up 13.6 km. In this paper, the observational construction management based on field measurement performed at large scale underground railway station (Sirkeci station) constructed by means of New Austrian Tunneling Method (NATM) is described and the mechanism for generation of ground surface settlement above this station is discussed.Buildings above Sirkeci station are overcrowded. About 60% of the buildings are made of reinforced-concrete (RC) and others are of brick. Based on the investigation into the predicted settlement and inclination, necessary actions such as structural reinforcement and soil improvement have been conducted for dilapidated buildings.Rock mass around Sirkeci station consists of alternative strata of sandstone and mudstone. It is overall soft rock with an elastic modulus of 150 MPa, partly including fractured zones. Overburden is about 30 to 40 m. The thickness of unconsolidated sand layer distributed on the bedrock is about 10 m. As a result of in-situ permeability tests, the coefficient of permeability of the sand layer is about 1.0x10-3 cm/s. Fill layer of about 10 to 25 m in thickness covers the sand layer at the ground surface. The fill layer contains a lot of artificial waste like splinters of wood, brick chips and mortar chips, etc. in addition to gravel, sand, silt and shells. The coefficient of permeability of fill layer is estimated to be 1.0 x10-2 cm/s, which is one-order greater than that of the sand layer. Fill layer consists of ancient city ruins of ages respectively from the Eastern Roman Empire, the Byzantine Empire and the Ottoman Empire and has a lot of gaps.The underground part of the Sirkeci station was excavated through a ventilation shaft. Ground surface settlement occurred more than predicted. Therefore, back analyses were performed in order to precisely predict the next-step settlement. However, back analyses with elasto-plastic models could not simulate the actual phenomena and hence, an anisotropic-damage-parameter model developed by Sakurai (1999) was adopted for the back analysis. Furthermore, as the excavation of tunnel proceeded, the ground surface settlement exceeded the predicted value again. Based on the monitoring results, it seemed that pore water pressure decreased by the tunnel excavation resulted in the soft rock and soil to be contracted due to the increase in the effective confining pressure. A coupled hydraulic-mechanical analysis was applied to explain the relationship between decreased pore water pressure and ground surface settlement. The settlement due to drainage from tunnel wall was well-estimated in the coupled hydraulic-mechanical analysis.However, further settlement occurred more than predicted again and again. Though it was very difficult to clarify the reason of the large settlement, it was recognized that the unexpected ground surface settlement resulted from the existence of the large gaps in the fill layer that was greatly compressed. The final settlement reached up to 327 mm."

Jan 1, 2015

By Denni Nikols

"Planning for coal beneficiation in the electric utility industry is relatively complex, involving the coordination of experts and specialists in a broad range of fields, as well as compliance with a wide variety of government regulations.This paper examines the role of the planner, reviews possible benefits of coal beneficiation, identifies potential problems and illustrates a typical planning schedule.The steps involved in the planning process are:Step I-Bench- and pilot- washability studyStep 2- Wash plant designStep 3- Power plant and boiler designStep 4-Mine designStep 5-Major environmental and technical problems to address.IntroductionElectrical utilities and coal have a long and intimate relationship . Cleaned coal is becoming an increasingly popular fuel with the utilities for a variety of reasons. Generally, the greatest impetus to burn a cleaned or prepared coal fuel comes from the need to control airborne pollutants.Long-range planning is a standard practice for electric utilities, forecasts of demand must be made well into the future. Since the lead time required to provide new facilities is often as long as 10 years and the cost very high , planning becomes an important task.For a utility that owns and directs the operation of its coal mines, the mine planning or fuel acquisition planning takes on the magnitude of other corporate planning functions. It is from this perspective that a utility would view coal preparation. Except for the interaction of a coal-fi red plant on the actual mine design the planning considerations o f a beneficiating facility for a captive mine or a contract raw coal supply are about the same. Because TransAlta Utilities is currently supplied from captive mines, this discussion will tend to focus in that direction.It is the role of a planner to plan. This is easy to say but it is not always easy to do. Often we are working within a context that resembles the geological time scale. Frequently the objectives are not clearly defined when we begin and ultimately our plans are tested in the waters of government regulations and cost benefit analyses .Planning for beneficiation of Plains coal, or any coal, provides just such a test. The planner's role in this endeavour requires a wide vision. While parts of the process may be amenable to classical methods of project scheduling, the broad range of subjects and interaction of seemingly unrelated tasks is sure to obscure some of the considerations that must be made. Therefore, the planner's chief role is coordinating the work of many experts and specialists toward the final objective.Among the specialists are combustion , geo technical, mining, civil , and mineral processing engineers , geologists, hydrogeologists, soil, and reclamation experts to list a few.When one considers coal beneficiation, the planning part o f that consideration is probably more complex than any other single engineering function. Due to the company's location in the Alberta Plains and the proximity o f the mine to the thermal generating station, this paper will tend to emphasize that situation.Beneficiation may offer some advantages over run-of-mine coal to the power plant opeator. Some of these advantages are: removal of a contaminant, power plant efficiency gains , lower plant capital costs (for new plants), possible lower mining costs."

Jan 1, 1984

By Aleksandar N. Nikoloski, Tendekayi Tapera, Glen P. O’Malley

Chalcopyrite (CuFeS2) and enargite (Cu3AsS4) are among the most important copper sulfides. At present, many known deposits of these minerals are uneconomic to process because they are of too low grade, insufficient size or too remote to be cost effectively treated with conventional technologies that can deal with their refractory nature. Therefore, developing an effective, low cost extraction process for recovery of copper from them is important. The research presented in this paper will deal with potentially cost effective strategies involving catalysed processing, studied under conditions relevant to recycle heap leach conditions. The present account summarises some of the main findings from the research program carried out at Murdoch University between 2014 and 2018 that has investigated the effects of the common leaching parameters, major and minor species present in the leach system and additives on the rate and extent of copper extraction from low-grade ores, in which primary copper sulfide minerals such as chalcopyrite and enargite were the dominant copper minerals. The study involved batch leaching tests, detailed structural and mineralogical characterisation and thermochemical modelling under conditions relevant to heap leaching. The results have demonstrated that silver in particular has a strong catalysing effect on the extraction of copper from ore under the leach recycle conditions and, at an adequate dosage, can effectively overcome surface passivation, enabling almost complete extraction of copper from chalcopyrite as well as enargite. The aim of this paper is to present the effect of the studied additives and to briefly elaborate on the mechanism of the silver catalysed leaching process. In addition, the presence of certain secondary agents was shown to lower the critical dosage of silver and promote extraction. The data from the study allowed the development of a theory for the silver catalysed reaction mechanism, which enables further optimisation and cost-effective application of this strategy in practice. INTRODUCTION Researching the extraction of copper from chalcopyrite is important as it is the most abundant copper mineral in the earth’s crust. The majority of ores containing this mineral are processed by flotation to produce a concentrate, followed by smelting and electrorefining. However, most reserves available nowadays are of low grade or limited in size, and therefore not suitable for this conventional approach. Hydrometallurgical processing via heap leaching with or without the aid of bacteria has been shown to be potentially economical. Chalcopyrite is refractory though and suffers from slow leaching kinetics and poor overall extraction, so understanding the mechanism of how it leaches has received significant attention by researchers working in this field over the past 50 years. The refractoriness, which is the main issue with the hydrometallurgical approach, is generally described as passivation of the chalcopyrite surface whereby a surface coating is formed that blocks the reaction interface or wetting of the chalcopyrite, limiting the copper extraction. Exactly what this layer is made of or how the issue could be overcome has been the subject of intense study and debate for many years. One of the limitations of the work to date is that much of the research focus has been on typical initial leaching conditions, while there has been relatively little research into how the leaching is affected under recycle solution conditions where certain metal ions (Fe, Mg, Al) have often accumulated in the liquor. This occurs because the leach solution exiting a heap contains many species from the dissolution of gangue minerals and typically this solution is returned to irrigate the heap, once the copper has been removed, leading to an accumulation of these species.

Jan 1, 2019

By Junto Nishiwaki, Shinji Kumai

"Mechanical and physical properties of the impact welded dissimilar metal joints are controlled by joint interface morphology. An intermediate layer (IML) is often formed at the joint interface and this deteriorates the interface quality in some metal combinations. Numerical and experimental studies were performed in order to examine the formation mechanism of the wavy interface and intermediate layer for explosive welded Al/Cu dissimilar metal joints. The impact welding process consists of (1) high-speed oblique collision of metal plates, (2) metal jet emission and large deformation and temperature increase at collision point and (3) rapid cooling at the joint interface. Euler-Lagrange coupling method, smooth particle hydrodynamic (SPH) method and modified laplacianFoam (LF) method were linked together to simulate a series of processes from (1) to (3), and the final interface morphology including the formation of IML was reproduced. The wavy morphology (wave-height, wavelength) and the position and composition of IML formed at the joint interface of Al/Cu joints were quantitatively in good agreement with those reproduced by numerical analysis. Our simulation results are useful for the control of the interface morphology, reduction of the amount of IML, and improvement of the mechanical properties of the impact welded dissimilar metal joints.INTRODUCTIONImpact welding is a kind of solid state joining method providing extremely high joint strength for both similar-and dissimilar metal combinations. Explosive welding and magnetic pulse welding are representative methods to achieve the impact welding. By a high-speed oblique collision between two metal plates, a metal jet is emitted from the collision point. The metal jet can remove any oxide films and contaminations on the plates and produce an active refreshed surface. Consequently, good metallurgical bonding can be achieved even for dissimilar metals (Crossland, 1982). Solid metals deform like fluids under the high pressure condition at the collision point and characteristic wavy interface is formed. In addition to the wavy interface, an intermediate layer (IML) is often formed at the joint interface in some metal combinations. Elimination or reduction of the amount of IML at the joint interface is desired since the excessive IML formation along the joint interface causes a large reduction in physical and mechanical properties. Formation of IML is considered to result from characteristic thermal history at the joint interface including partial melting due to the local temperature increase and successive rapid cooling behavior at the joint interface. In order to control the IML formation at the joint interface, it is necessary to reveal both heating and cooling processes at the joint interface. However, it is impossible to observe the phenomenon occurring at the joint interface and also difficult to investigate the temperature change at the joint interface directly during the impact welding. Therefore, simulation or numerical analysis is indispensable to overcome this problem. In the present study, the explosive welded Al/Cu joint, which is prone to form IML at the joint interface, was selected for the research. By using a newly developed numerical analysis method, not only the formation process of wavy interface, but also the local temperature increase and successive temperature decrease at the joint interface were reproduced. The formation process of IML was investigated by using both numerical analytic and experimental results."

Jan 1, 2018

By Mory M. Ghomshei

"The cost of deep underground mine cooling depends on a number of geological, environmental and economic factors such as the temperature gradient in the mine, the outside air temperature, and the local price of energy. While geological factors, being static, can be controlled to some extent during the mine design, the environmental and economic factors dynamically change and therefore can only be controlled through a flexible mine ventilation system.With an average temperature gradient of 20–25°C/km, the virgin rock temperature at 2,000 m can reach 45–60°C. Conventional cooling at such depths could lead to exorbitantly high costs. In-mine geothermal heat pumps can considerably reduce the cost of cooling through energy communication with the centralized absorption chillers, which service the mine from the surface.It is shown that in-mine heat pump systems can be a viable option for reducing operating expenses and providing some degree of flexibility to cope with fluctuating energy costs. The price of Natural gas and electrify are the most important variables for optimizing the level of interaction between the surface and inmine cooling systems. Deep mine waters can be used to carry a portion of the mine heat to the surface, where the heat from mine can be used as a supplementary energy source for absorption chillers. As an extra benefit, the heat output of the chillers can be used for district heating and or greenhouse growing.The case of cooling deep levels of deep mines in Sudbury Canada (e.g. Creighton Mine) has been discussed. It is shown that an initial 1MW in-mine geothermal heat pump system can save significantly on the cost of cooling. Such a demonstration project will allow R&D on viability of larger similar systems to be incrementally added in the future.INTRODUCTIONThe amount of heat generated in deep and ultra-deep mines depend primarily on the regional temperature gradient and the thermal conductivity of mine rocks. The conductive heat flow is quantifiable and can be minimized or optimized in the process of mine design. Another important heat source can be related to underground equipment such as diesel machinery which often have low efficiencies (approximately 25–35%). This heat source can be controlled and reduced though improving efficiencies or using electrical equipment, which offer a much better efficiency (approximately 80–90%). Mine waters can also be a significant heat source (convectively bringing large amounts of heat into the mine workings)."

Jan 1, 2019

By Eamonn F. Maher

Superconductivity is one of the most remarkable scientific phenomena ever investigated. It is the phenomenon whereby some materials exhibit zero resistance to the passage of an electric current when cooled to low temperatures, and requires a quantum mechanical explanation. Four Nobel prizes in physics have been awarded specifically on the subject of superconductivity, with many more enabled by superconducting technology. For example, particle beams are generated in accelerators and manipulated in ?particle beam lines? in the ?Big Physics? projects around the world eg. at CERN, Geneva, leading to major discoveries in fundamental particle physics. Similarly, at the JET Propulsion laboratory near Oxford, U.K, controlled nuclear fusion has been demonstrated, and magnetic containment of plasmas is key. In the chemical and biological sciences high field NMR spectroscopy has become indispensable for examining organic matter, revealing the mysteries of the workings of cells, genetics, and in the development of new polymers and pharmaceuticals. With all these very advanced uses for superconducting magnets, it is easy to forget that superconductivity is big business, not just a scientific curiosity. MRI (Magnetic Resonance Imaging) superconducting magnets, the key component of high resolution body scanners, use approximately half of the world?s superconducting wire ? the other half being mostly used in accelerator magnets. The MRI market is about 3 billion dollars per annum, and one MRI magnet uses 200km of wire. New applications for superconducting magnets are now appearing including ?Catheter steering?, enabling much shorter timescales for life-saving brain tumour removals and ?Functional MRI?, a whole new area in patient diagnostics. Whilst the use of low temperature superconductors (LTS) is now well established commercially in superconducting magnets and niche electronic applications, the application of LTS in electric power distribution and transport has been very limited to date. It is now more than fifteen years since the so-called High Temperature Superconductor (HTS) materials were discovered: these can be operated at liquid nitrogen temperatures rather than liquid helium temperatures. However, materials processing and scale-up issues have prevented their widespread use, and in particular the required price/performance criteria are only beginning to be reached except in certain niche markets. BSCCO (Bismuth Strontium Calcium Copper Oxide) tapes up to one km long are now readily available, and have been demonstrated in high current cables for power distribution networks, but the general consensus is that 1) it is difficult to reduce the price much further because of the silver matrix required and 2) in applications where coils are required eg. motors, generators, transformers etc the properties of BSCCO are rather poor because of the critical current dependence on magnetic field. Magnetic fields are always associated with coils and windings, and such fields are of course fundamental to the operation of all electrical machines. YBCO (Yttrium Barium Copper Oxide) however, has good characteristics in field and for the last few years there has been intensive research and development costing several tens of millions of dollars worldwide into the scale-up of production of so-called ?coated conductor?. This ?second generation? tape can be produced by any of many different film deposition techniques, with more or less success for short lengths, but as yet it is unavailable in lengths more than a few tens of metres.

Oct 1, 2003

By C. W. Chao, M. Melashvili, F. Hilário

The processing of a bulk concentrate containing copper as chalcocite, enargite, bornite and chalcopyrite along with pyrite and precious metals of silver and gold was studied. A leaching study was undertaken to examine the application of the atmospheric acid leaching process to a bulk copper concentrate for copper recovery followed by cyanidation or thiosulfate leaching for gold and silver recovery. The extraction of copper exceeded 90% under some conditions and the recovery of gold and silver reached a maximum of 44 and 45%, respectively. A sample of bulk concentrate was roasted in air to oxidize the sulfides with release of sulfur dioxide followed by acid leaching of the roaster calcine and cyanidation of the acid leach solution. The copper extraction reached over 92% and the gold extraction exceeded 88%. The sulfur dioxide may be captured for acid production. INTRODUCTION The processing of a large primary copper deposit in Indonesia is under investigation. One of the possible routes for processing involves flotation of a bulk copper-gold concentrate followed by treatment by an atmospheric leach/SX-EW process for copper recovery. The atmospheric leach residue would then be leached for recovery of gold and silver. A second route involves roasting of the concentrate followed by acid leaching and SX-EW for copper recovery. The leach residue from the roaster calcine would then be leached for recovery of gold and silver. The roaster off-gases could be used for sulfuric acid manufacture, enabling the production of a valuable by-product. The Cobre Las Cruces (CLC) process (Munoz, Garcia, & Delgado, 2017) was designed to treat a resource of copper discovered close to Seville, Spain. The process was developed by Outotec with MK Gold (original project owner). INMET Mining subsequently purchased the deposit from MK Gold and built the copper processing facility. The CLC process is similar to the Mt. Gordon Copper process; except that OKTOP reactors have been installed instead of a low temperature, low pressure autoclave process. The plant was designed to treat 1.3 mtpa of ore at a grade of 6.2% Cu to produce 72,000 tpa of cathode copper over a 15 year project life. The main gangue mineral at Cobre Las Cruces was pyrite. The Cobre Las Cruces ore is therefore similar to a rougher flotation concentrate containing copper minerals and pyrite. The roasting of a rougher flotation concentrate can be designed to produce hematite, basic copper oxides and sulfur dioxide off gas. The acid leaching of the basic copper oxides may produce soluble copper for SX-EW recovery of copper. The sulfur dioxide off-gas may be used to make sulfuric acid.

Jan 1, 2019

By P. Erskine

"Hyperaccumulator plants can be utilized as ‘metal crops’ in agromining operations. This emerging technology produces ‘bio-ore’ by growing ‘metal crops’ on sub-economic ore materials, such as natural ultramafic soils. In a typical application plant material is periodically harvested, followed by air-drying and incineration to produce the bio-ore intermediate. The bio-ore is of very high grade (>15 wt. % nickel), and of high purity, and may be processed into a number of different products (including nickel metal, nickelbased catalysts and pure nickel salts). Current research efforts from our team focus on Mediterranean climate field trials (Albania, Spain) and tropical climate field trials (Malaysia, Indonesia). Field-scale demonstrations are required to provide evidence of real-life performance and of economic viability. If the trials are successful, agromining may in the near future support local livelihoods with income opportunities as an alternative type of agriculture: to farm nickel.INTRODUCTION AND BACKGROUNDHyperaccumulators, plants with the exceptional ability to uptake and concentrate trace elements in their shoots, can be utilized as ‘metal crops’ in agromining operations (Van der Ent et al., 2013a; Chaney et al., 1998; 2007; Baker et al., 2010). Agromining produces ‘bio-ore’ from harvested ‘metal crops’ grown on unconventional resources such as natural ultramafic soils (Van der Ent et al., 2015a). The bio-ore is a high purity and very high-grade (>15 wt. % nickel) product intermediate that may be turned into a range of different nickel products (nickel metal, nickel-based catalysts and pure nickel salts). The potential for agromining is greatest in tropical regions (Asia-Pacific Region: Indonesia, Malaysia, Philippines, Papua New Guinea and New Caledonia) where very large expanses of ultramafic soils exist (Van der Ent et al., 2013b). Agromine operations may replace existing marginal agriculture on poor ultramafic soils, for example oil palm plantations that require high fertilizer inputs to be profitable, or take place under a cocropping regime. The ability of ‘metal crops’ to achieve high nickel concentrations in biomass (and hence in harvested bio-ore) from soils with just <0.5 wt. % nickel, makes it possible to access non-conventional resources, not accessible by traditional mining techniques. For example, agromining could be implemented both on the large ‘halo’ around the mine leases, and as part of the progressive rehabilitation process after conventional resource extraction. As with all methods for resource extraction, agromining will be finite due to the diminishing concentrations of nickel in the zone accessible by plant roots (Chaney et al., 2014). Nevertheless, considering soil materials with 0.2 wt. % nickel and ‘metal crops’ with a yield of 100 kg nickel ha-1 the agromining venture may be sustainable for decades (Van der Ent et al., 2015a)."

Jan 1, 2016

By C. Sui, J. E. Nesset, M. Li, J. Y. Kim, S. L. Chryssoulis

"A plant study of zinc rougher flotation at Brunswick Mining was conducted using lime, soda ash and a combination of both as the pH modifiers in order to establish the effects on sphalerite and pyrite kinetics and mineral selectivity. The plant sampling and analysis was augmented by surface analysis using TOF-LIMS, SEM and XPS as well as fundamental precipitation and surface-charge studies in the sphalerite Ca/C03/S04 system.The results revealed the important role of carbonate ions in cleaning the sphalerite surface for effective activation by CuS04 to occur, and the beneficial role of combined soda ash and lime in increasing pyrite and galena depression.1.0 IntroductionThe studies reported in this paper were initiated as part of an investigation into the causes of a particularly pronounced seasonal deterioration in metallurgical performance at the Brunswick Mining concentrator during the summer of 1995. The concentrator treats a complex base metal ore having a typical feed composition of 9.0% Zn, 3.5% Pb, 0.4% Cu and 100g/t Ag at a current throughput of 9,000 TPD, although at the time of the problem in 1995, the average production rate was closer to 10,500 TPD. Zinc, lead, copper and bulk (zinc-lead) concentrates are produced with overall metal recoveries of 86% zinc, 63% lead, 60% copper and 60% silver; results which are typical of the lower recoveries associated with fine-grained, highly complex VMS and SEDEX type deposits. The main economic minerals of interest are an iron-containing (7% Fe) sphalerite, galena and chalcopyrite with the main diluent (about 60% wt) being pyrite.Figure 1 shows a simplified flowsheet of the Brunswick milling circuit while the seasonal decrease in summer metallurgy in 1995 is illustrated in Figure 2. Of significance is the rapid drop in copper and lead recovery in June while there is an apparent delay until late August-September before the zinc deterioration reaches its lowest point. A more typical seasonal effect within the experience of the authors is the reverse of the Brunswick situation, namely an improvement in summer performance thought to be associated with improved differential flotation kinetics during warmer weather leading to better mineral selectivity. The historical Brunswick experience was particularly severe during the summer of 1995 with estimated incremental losses of $10 Million for this period. The potential of the very significant economic benefits to be gained from understanding and hopefully improving the annual drop in performance led to an investigation involving the minesite metallurgical group, the Noranda Technology Centre (NTC) as well as researchers in Professor Jim Finch's group at McGill and the surface analytical services and interpretive skills of AMTEL."

Jan 1, 1998

By Q. Li, X. -L. Lei

Accompanying global energy shortage and high energy prices, shale gas has been the focus of exploration and it has attracted great attention from both academia and industry. The combination of horizontal drilling and hydraulic fracturing enables the extraction of huge quantities of shale gas from impermeable shale formations. During the process of hydraulic fracturing, great amounts of water, sand and chemicals must be injected into the shale formation at a high pressure, which may trigger seismicity. Such events could occur due to the presence of faults or the reactivation of these potential faults. Shale is the main component of source rock in the Sichuan Basin, China, and has the greatest contribution to the natural gas of the basin. In order to investigate the fracturing mechanism of shale in the Sichuan Basin, China, a series of rock fracture tests under triaxial compression were carried out in the laboratory in order to investigate the hydraulic fracturing behavior in relation to the seismicity. Based on the high multichannel waveform recording system, the detailed spatio-temporal distribution of acoustic emission due to micro-cracking was used to examine the deformation and fracture behavior of shale. In addition, the effects of confining pressure on the deformation and fracture in shale under triaxial compression by acoustic emission monitoring and X-ray computed tomography were discussed in the paper. The experimental results indicate that the shale samples demonstrate brittle fracture behavior. The confining pressure has a great effect on the complexity of the fracture planes and the spatial distribution of acoustic emissions, but few contributions to the location of the major hydraulic fracturing plane. The foliation of shale plays a dominant role in the rupture process and the geometry of the major hydraulic fracturing plane. The high confining pressure increases the strength and restrains the deformation of shale during compression process. These results shed some light on the understanding of onset of hydraulic fracture initiation not only for shale gas exploration and production, but also for CO2 geological storage and underground energy storage.

Jan 1, 2015

By Q. Li, X. -L. Lei

Accompanying global energy shortage and high energy prices, shale gas has been the focus of exploration and it has attracted great attention from both academia and industry. The combination of horizontal drilling and hydraulic fracturing enables the extraction of huge quantities of shale gas from impermeable shale formations. During the process of hydraulic fracturing, great amounts of water, sand and chemicals must be injected into the shale formation at a high pressure, which may trigger seismicity. Such events could occur due to the presence of faults or the reactivation of these potential faults. Shale is the main component of source rock in the Sichuan Basin, China, and has the greatest contribution to the natural gas of the basin. In order to investigate the fracturing mechanism of shale in the Sichuan Basin, China, a series of rock fracture tests under triaxial compression were carried out in the laboratory in order to investigate the hydraulic fracturing behavior in relation to the seismicity. Based on the high multichannel waveform recording system, the detailed spatio-temporal distribution of acoustic emission due to micro-cracking was used to examine the deformation and fracture behavior of shale. In addition, the effects of confining pressure on the deformation and fracture in shale under triaxial compression by acoustic emission monitoring and X-ray computed tomography were discussed in the paper. The experimental results indicate that the shale samples demonstrate brittle fracture behavior. The confining pressure has a great effect on the complexity of the fracture planes and the spatial distribution of acoustic emissions, but few contributions to the location of the major hydraulic fracturing plane. The foliation of shale plays a dominant role in the rupture process and the geometry of the major hydraulic fracturing plane. The high confining pressure increases the strength and restrains the deformation of shale during compression process. These results shed some light on the understanding of onset of hydraulic fracture initiation not only for shale gas exploration and production, but also for CO2 geological storage and underground energy storage.

Jan 1, 2015