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By Corby G. Anderson

"Laboratory testing using industrial electrowinning solutions was performed to determine the best Faradic cell efficiency for copper cathode recovery. The variables tested were solution flow rate, recycle ratio, reagent addition combinations of guar and thiourea, and addition amount of acid mist suppressant CAL FAX DBA-70. The ideal flow rate was determined to be 37.85 litre/min. Additionally, the ideal recycle ratio was determined to be 10:1. The reagent addition scheme from testing which showed the highest efficiency was with 680 g/tonne guar of cathode copper won and with 135 g/tonne thiourea of cathode copper won. These values for reagent addition only reflect the best efficiency and should not be assumed to be the best reagent concentration for copper purity. The amount of foaming agent that showed the best efficiency was the test with 2 ppm of foaming agent. Again this amount of reagent is based on efficiency and should not be taken as the amount of reagent that does the best acid mist suppression. Additional proprietary surface characterization work indicates these additives may have enhanced the cathodic reduction surface morphology of some noble minor impurities. Subsequently, these operating parameters were introduced into the plant operation and proved successful after their implementation.BACKGROUNDCopper electrowinning has become a dominant technology for the production of marketable high grade copper cathode products. The literature is robust with applications, optimizations, additives and developments in this field (e.g., Classens & Harris, 1990; Pfalzgraff, 1999; Tozawa, Su, & Umetsu, 2003; San Martin, Otero, & Cruz, 2005; Houlachi, Edwards, & Robinson, 2007; Romero, Avila, Fester, & Yacher, 2007; Marsden, 2008; Beukes & Badenhorst, 2009; Vainio & Weatherseed 2009; Bender, 2010; Joy, Staley, Moats, Perkins, Uhrie, & Robinson, 2010; Khouraibchia & Moats, 2010; Moats, 2010; Rutledge & Anderson, 2015).Tests of forty hours duration and at room temperature were performed for this project using samples of actual industrial electrowinning solutions. These industrial solutions were comprised of 60 g/L Cu plus 65 g/L Ni, 3 g/L Fe, and 30 g/L free sulfuric acid. Other confidential minor impurities were also present including some solubilized precious metals. The testing apparatus utilizing stainless steel anodes and cathodes is illustrated in Figures 1 and 2."

Jan 1, 2016

By J. C. O'Rourke

"Gibraltar Mines Ltd. has been operating its open pit copper mine for fifteen years. In that time over 140 million tons of waste and low grade material has been placed on the mine waste dumps. Laboratory and in-situ testing indicated that enough leachable copper was recoverable from the dumps to justify a leaching operation which would include the construction of a solvent extraction-electrowinning plant. The plant, which was commissioned in October, 1984 was designed to process 3,000 usgpm of dilute copper solution to produce 5,000 tons per year of high quality cathode copper.This paper deals with the start up and initial year of operation of Gibraltar's SX-EW plant. The three areas: leaching solvent extraction and electrowinning are presented with emphasis on the innovations which were made to help overcome the problems unique to die Gibraltar operation.THE LEACHING CIRCUITThe mines waste dumps are leached to produce a pregnant copper solution as feed to the SX-EW plant. To achieve this the dumps are sprinkled with a mildly acidic solution which percolates through the dump. In travelling through the dumps the solution contacts the surfaces of the liberated copper minerals and disolves the soluble copper into the form of copper sulphate. The leaching reaction is achieved by a combination of bacterial action to oxidize the suphides and solublization of the copper into the acid solution.For the bacterial action to occur the dumps must be at or near the ideal pH of 1.9 - 2.1 and the necessary elements of the reaction must be present. Because a bacterial reaction is involved there is a lag time between the time when the conditions for bacterial growth are achieved and when the bacteria are in their active growth phase. Laboratory tests with Gibraltar ore indicated that bacterial action takes two to three months to reach its maximum rate. See figure 1.The expected lag time for the planned rate of bacterial leaching prompted Gibraltar to start irrigating the dumps in late June 1986 for a plant start up in early fall. The lag time proved to be longer than expected and the dumps took until November to start producing copper at the expected rate. See figure 2."

Jan 1, 1988

By A. Boucher, D. Marcotte

"Abstract- The accepted practice for the estimation of thin (2D) vein deposits recommends the use of the grade x thickness service variable (i.e., the accumulation). Grade estimates are obtained indirectly by the estimated accumulation/estimated thickness ratio. This practice stems from the varying support (thickness) problem and the resulting non-additive nature of the grade variable. We compare the actual performance of the direct grade estimation approach used by some practitioners to that of the indirect approach using accumulation. Our simulated and real data indicate that the direct approach is more accurate for point grade estimation where the grade-thickness correlation coefficient is positive (and vice-versa). Moreover, the relative gain of the direct method increases with the (positive) correlation coefficient. This finding contradicts common thinking that the indirect approach should be the preferred method where grade-thickness correlation is strongly positive. Also, for a given positive grade-thickness correlation, the relative gain of the direct method increases with the coefficient of variation of the grade and thickness. Résumé - L’estimation de veines minces (2D) minéralisées est normalement réalisée à l’aide de la variable auxiliaire épaisseur x teneur (i.e., accumulation). Les estimés des teneurs sont alors obtenus indirectement du rapport accumulation estimée/épaisseur estimée. Cette pratique découle du problème du support variable pour la teneur, l’épaisseur de la veine, qui fait que la teneur est alors une variable non-additive. Nous comparons les performances de l’estimation directe de la teneur, utilisée par certains praticiens, à celle de l’approche indirecte. Pour l’estimation ponctuelle des teneurs, nos données simulées et réelles indiquent une meilleure justesse de l’approche directe quand la corrélation teneur-épaisseur est positive (et vice-versa). De plus, le gain relatif de la méthode directe s’accroît avec la valeur de cette corrélation (positive). Ce résultat contredit l’opinion répandue que l’approche indirecte devrait être utilisée en présence de forte corrélation positive de la teneur et de l’épaisseur. Nous montrons également que pour une corrélation positive teneur-épaisseur donnée, le gain de l’approche directe augmente avec les coefficients de variation de l’épaisseur et de la teneur."

Jan 1, 2001

By E. McLaren, J. Sanftenberg, C. Cameron, H. Dello Sbarba

"A Ventilation on Demand (VOD) system has been optimized and maintained at Glencore’s Nickel Rim South Mine (NRS) in Sudbury, Ontario, Canada for the past seven years. The system monitors and controls air quality and quantity through real-time, dynamic automation of primary fans, secondary fans, automated airflow regulators, and air monitoring instrumentation with VentSim™ CONTROL, a VOD software. This paper will focus on the implementation of testing procedures and system maintenance methods. Overall, the results show a consistent reduction in energy usage.INTRODUCTIONThe Ventilation on Demand (VOD) system at Glencore’s Nickel Rim South (NRS) mine in Sudbury, Ontario, Canada, involves the control of two 2,980 kW centrifugal surface exhaust fans with Variable Frequency Drives (VFDs), three 335 kW vane-axial surface intake fans with VFDs, 21 automated airflow regulators, six automated dampers, seven automatic doors and 198 underground auxiliary fans with ON/OFF starters. Additionally, the system monitors airflow at 48 locations, carbon monoxide (CO) at 40 locations, nitrogen dioxide (NO2) at 21 locations, and dry bulb and wet bulb temperature at 21 locations. The VOD system is also integrated with a tagging and tracking system to modulate the ventilation system automatically and in real time according to the presence and position of the personnel and vehicles. The tracking system comprises of 75 vehicle tags with diesel status and hydraulic status (ON or OFF), 440 personnel tags, and 200 tracking zones. Finally, it also involves the configuration and updating of 55 level plan and interactive procedures and 24 daily scheduled events. NRS currently uses VentSim™ CONTROL, Ekahau Tracking and PI Datalink to control, monitor, and configure their VOD system."

Jan 1, 2019

By H. Al-Kazzaz

The effects of laser power and joint gap on the welding quality of 2-mm butt joints of ZE41A-T5 sand castings were investigated using a continuous wave 4 kW Nd:YAG laser system and 1.6-mm EZ33A-T5 filler wire at a welding speed of 6 m/min and surface defocusing. The smooth weld profiles with the minor welding defects were obtained at a laser power of 4 kW and joint gap of 0.3-0.4 mm. The hardness values in the fusion zone are similar to those of the base metal but there is a drop in the heat-affected zone after a natural aging of 18 months.

Jan 1, 2006

By M. Hamamoto, M. Furuta, S. Tanaka

The Tamano smelter and refinery has expanded its production from 228kt/y to 260kt/y since 2006. It was not a big jump, but efficient and economical improvements were executed. These were not only de-bottlenecking and modernization of the smelting plant, including the acid plant, but also additional processes were commissioned, e.g. slag cleaning furnace and steam dryer. On the other hand, a conversion to permanent cathode process in the #2 tank house made the biggest impact on production efficiency for the refinery plant. In order to overcome the drastic change of copper business, although each scale is not so big, continuous improvements are very important to survive. This paper mainly describes the recent improvements of the smelting plant.

Jan 1, 2007

By A. E. M. Warner, A. Vahed, P. J. Mackey

In the decade 2002 to 2012 some 6.7 million tonnes of new copper concentrate production capacity was brought on line, corresponding to 2 million tonnes of contained copper. This increase in concentrate supply necessitated the commissioning of a number of new copper smelters as well as the modernization and/or expansion of existing plants to meet the demand. This paper gives an overview of the copper extractive industry, reviews recent copper production trends and changes in the copper industry, including an examination of pyrometallurgical and hydrometallurgical technology developments. WorleyParsons has supported a number of the projects involved in these developments and this role is briefly discussed. The paper introduces a number of ideas related to possible future directions of the copper industry.

Jan 1, 2014

By R. Butar-Butar, J. Mosher, G. Banini, J. Hollow, A. Villanueva

The effect of High Pressure Grinding Rolls (HPGR), as a preceding stage to a conventional ball mill circuit at PT Freeport Indonesia’s C1/C2 concentrators, has been studied in terms of downstream grinding efficiency and circuit performance. When milling the product from the HPGR, mill capacity increased by 21% for the same product grind size, when compared to processing similar ore from a conventional crushing circuit. This achievement is a result of several reasons, among them: reduction in feed size (F80), fines generation beyond the proportional reduction in F80, reduction in ore hardness induced by HPGR comminution mechanism, optimization of the recycle system of the HPGR and ball string optimization in the ball mill circuit given the new feed to the mill.

Jan 1, 2012

By M. Bigdeli Karimi

In this study, the effect of strain level and holding time in semisolid temperature range via SIMA process on AS21 Mg alloy was investigated. Some cylindrical samples of this alloy with 1cm in height and 2.5cm in diameter (H/D=0.4) were compressed to 10%, 20%, 30% and 40% at 300-C. Then, the samples were reheated in semisolid temperature range at 614°C for various times. The results of optical microscopy and image analysis showed that with increasing of strain and holding time, dendritic structure changed to equi-axed structure, gradually. Also, the best conditions to obtain good globular structure were achieved. Furthermore, it was seen that after compression and reheating, Mg2Si intermetallics with Chinese script morphology converted to dispersed-fine particles which were distributed into the ci-Mg grains.

Jan 1, 2007

By A. A. Lavrinenko, N. I. Gluhova, L. M. Sarkisova, D. V. Makarov

"The investigated sulfide Cu-Ni ores are characterized by low PGE contents and emulgated impregnations of pentlandite and palladium minerals in the main ore-forming mineral pyrrhotite, which hinders their selective separation, requiring a collective flotation of sulfides to concentrate, and hydrometallurgical processing. As revealed by studies of floatability of Pt-Cu-Ni ore in a mixture of butyl xanthate and chelating phosphorus containing reagents, the most effective additive is Aerophine 3416 (a phosphinates mixture) manufactured by Cytec. Using collective flotation with a butyl xanthate – Aerophine 3416 composite in the ratio of 1:3 has afforded to enhance the Pt, Pd, and Ni recovery by 13.6 %, 9.2 %, and 9.4 %, respectively. The optimal ratios of Aerophine 3416 to butyl collector for the collective flotation are the following: 1:1 for Pt and Pd and 3:1 for Ni. The effect of these reagents on the electrode potential and surface hydrophobicity of pyrrhotite, pentlandite, and platinum black has been investigated. The extraction UV spectrophotometry experiments demonstrate that DIBDTPI exists on the pyrrhotite surface mainly in the form of disulfide in weak acid medium and in the form of compounds with Fe on the mineral surface in minute amounts. There appears some disulfide and few amount of (DIBDTPI)2Ni on the surface after interaction of DIBDTPI and pentlanditeINTRODUCTIONXanthates are widely used in flotation of copper-nickel ores containing platinum group metals (PGM) as sulfides collectors which can concentrate the most part of PGM connected with the sulfides. Though xanthates are hardly efficient for flotation of free PGM, the latter are floated more slowly compared to the sulfides of base metals. The reasons for poor floatation of free (mineral) forms of PGM are under-researched, however the key accepted reasons are: fine disseminations of free PGM, insufficient interaction with xanthate and negative influence of blue copperas and sulfur-containing ions which are sulfides oxidation products (Penberthy et al. 1999; Shackleton et al., 2007). That’s why an additional collector, normally dialkyldithiophosphates, is used during flotation of PGM-containing copper-nickel ores. A reagent DP-4 is used for recovery of PGM at Norilsk mining and metallurgical plant. The reagent represents a slightly-soluble organic calcium sulfonate which is given to flotation pulp in the form of water emulsion of 5% - solution in automotive diesel oil."

Jan 1, 2016

By V. C. Pandolfelli, P. Bonadia, F. A. O. Valenzuela, L. R. Bittencourt

Refractories for aluminum cells, if not properly selected, can lead to increased energy consumption and even shorten the pot life. Based on recent advances in understanding the deterioration mechanism of cathode materials, several commercial bricks in the SiO2-Al2O3 system were compared to the one used by an Alcoa smelter. Both physical and chemical properties were considered in the selection of the refractories. A more reliable method of permeability measurement, which takes into account inertial and viscous effects during the fluid flow, was applied. Additionally, the traditional cup test and other characterization techniques, such as thermal conductivity, X-ray diffraction, and mercury porosimetry, indicated that a brick with a relatively low alumina/silica ratio, presenting low open porosity and low permeability, far exceeded the performance of the brick currently in use.

Jan 1, 2004

By J. Dufour

Although the recovery of nitric and hydrofluoric acids from stainless steel pickle liquors has been solved by several methods, such as solvent extraction, acid retardation, evaporation or pyrohydrolysis, metals (mainly iron, chromium and nickel) are usually obtained as a waste or by-product that has to be disposed. Alternatively, the treatment requires a high liquor flow to be economical, as is the case for pyrohydrolysis. A new process has been developed for metals recovery, that produces metal oxides with a low fluoride content. This new technique is based on a selective precipitation mechanism, which produces nickel hydroxide with a purity of 90%, separate from a mixture of iron and chromium oxides and hydroxides suitable for recycling. The reaction mechanism is based on the precipitation of fluoride compounds of iron and chromium, K2FeF5 and CrF3. For this purpose, free fluoride must be added as potassium fluoride. Also, solid fluoride compounds are hydrolysed, releasing free fluoride. A part of the fluoride is recycled to the selective precipitation operation and the remainder is fed to the acid recovery stage. Nickel does not react in this operation; it remains in solution giving a high separation yield.

Jan 1, 2006

By T. Sugawara, H. Sekimoto

Electrorefining of low-grade copper alloys containing various amounts of nickel, lead, antimony, bismuth, arsenic, selenium, silver, and gold in sulfamic acid media was demonstrated. The copper concentration of the alloys used as an anode was 70–90 wt%. The electrolyte contained 100 g L-1 of free sulfamic acid and 40 g L-1 of cupric ion. Galvanostatic electrolysis was conducted at 200–300 A m-2 in the electrolyte using a low-grade copper alloy anode and a stainless steel cathode at 25C. The terminal voltage was approximately 0.8 V at the start of the electrolysis, although it increased periodically to approximately 2.0 V and then shortly returned to its initial value. Nickel, lead, and arsenic from the anode dissolved in the electrolyte and were removed. Antimony, bismuth, selenium, and silver were removed as solids. Consequently, a dense copper cathode was obtained, and the concentration of copper was evaluated by inductively coupled plasma – optical emission spectrometry to be 99.82–99.99 wt%. INTRODUCTION Electrorefining of copper is conventionally carried out in a sulfuric acid electrolyte using crude copper assaying at 99.5 wt% Cu as the anode (Biswas & Davenport, 1994). Elements more noble than copper do not react anodically, and consequently, they are distributed in anode slimes. Elements less noble than copper dissolve from the anode. Nickel and arsenic are stabilized as aqueous species. Lead, antimony, and bismuth react with water, sulfuric acid, or arsenic acid to form barely soluble compounds; thus, they are distributed in anode slimes. An emerging issue in the electrolytic refining of copper is an increase of impurities in crude copper used as the anode (Moats et al., 2013). This is due to an increase in the content of impurities in copper concentrates as well as an increase in the types of secondary copper feedstocks (e.g., E-Scraps, automotive shredder residues, and smelting residues) treated in the copper pyrometallurgical process. An extreme case is a copper smelter that does not use copper concentrates as feedstocks. In such a process, copper-bearing feedstocks are smelted in a top submerged lance furnace to prepare low-grade copper alloys assaying at 80– 90 wt% Cu (Sekimoto et al., 2013). Such low-grade copper is not acceptable as an anode in the conventional copper electrolytic refining process because it is easily passivated during electrolysis. Consequently, electrolytic copper is produced by leaching the atomized low-grade copper in a sulfuric acid solution with oxygen, followed by electrowinning. However, electrowinning should be avoided whenever possible because the electrical energy consumed in electrowinning is 5–10 times higher than that consumed in electrorefining. Therefore, the development of technologies for electrorefining of low-grade copper alloys is desirabl.

Jan 1, 2019

By C. Tan, A. Putz, P. Lacombe, R. Kemp, M. Kaya, B. J. Huls, A. R. Laplante

"This paper concentrates on the four recent plant trials/ applications of froth washing. Results showed that improved metallurgical performance can be achieved with wash water. Increased froth cleaning yielded better upgrading, and some cases slightly improved recovery. Froth sampling and salt tracer tests supported the findings of froth washing tests.At Falconbridge, Ni grade increased from l.47% to 2.15% and recovery from 85% to 87%. At Eastmaque, final Au grade increased from 2.3 to 2.7 oz/st at a slightly higher recovery. At Les Mines Selbaie, Cu grade increased from 24.5% to 25.S% and Zn grade from 54.5% to 56.l%. At Zinc Corp. of America, average Zn grade increased from 55% to 56. 8% at the same recovery for a 45-day period. A number of plants in Canada and the United States have evaluated and/or now practicing froth washing. Wash water has now proved itself in some plants over several months of operation.INTRODUCTIONFroth washing in mechanical flotation cells offers a number of metallurgical (i. e. increased grades and/or recoveries) and economical (i.e. decreased transportation and smelting & refining costs) benefits. Fundamental development work in laboratory and pilot scales performed at McGill yielded encouraging results. (Kaya and Laplante, 1988a and 1989a). Since laboratory and pilot flotation performance can differ from full-scale due to differences in hydrodynamics, kinetics, and froth characteristics (e.g. stability, loading etc.), plant trials were essential to prove the viability of this technology."

Jan 1, 1990

By A. M. Brown, P. V. Straznicky

Dimpling as a means of flush countersinking rivets is an old process predominantly used in secondary structures. The introduction of GLARE as an aerospace material has renewed interest in dimpling and its possible application in primary structures. The dimpling process is able to prevent the creation of a machined knife-edge in the thin aluminum plies of the GLARE sheets. In addition, dimpling eliminates the need to use reduced height rivets, such as the NAS 1097 rivet style. This investigation expands on an earlier study into dimpling of GLARE by Rans and Straznicky. In order to tailor the dimpling process to GLARE, FEM simulations were developed. After verification, a study was performed to find the best parameters for dimpling GLARE3-2/l. Coupon fatigue tests were carried out and the dimpled joints demonstrated increased fatigue lives over the conventional machine countersunk joints. Future wide panel fatigue tests are planned to confirm the usefulness of dimpling thin GLARE laminates.

Jan 1, 2006

By Julie Q. Shang

The electrokinetic (EK) technology for dewatering of two tailings from the uranium mines in Northern Saskatchewan is studied in bench scale experiments. The study includes four phases: 1. Characterization of two uranium mine tailings; 2. Assessment of voltage loss on the coated Ti anode and water interface. 3. EK cell test series to measure electrokinetic permeability (ke) of two tailings; 4. EK dewatering test series to study electrokinetic enhanced gravity dewatering on two tailings samples. The results have demonstrated that both tailings responded positively to the EK process. For the tailings containing gypsum, the EK dewatering should be a short term process (within one hour) with anode conditioning (pH adjustment). The tailings containing clay minerals responded well to EK dewatering, in which pH adjustment is optional and will further enhance the EK flow. Both tailings as tested have low hydraulic conductivity and are particularly suitable for EK dewatering and consolidation.

Aug 1, 2010

By G. N. Carlson, C. H. Hazelroth, D. R. Dorrance

"Located on the north shore of the St. Lawrence River at Pointe Noire, Quebec are the agglomeration and ship-ping facilities of the Wabush Mines complex. Here, the specular hematite concentrate from the Scully Mine is received for further processing. Modern facilities for handling the ore, either to the 1plant or to stockpile, provide quick and efficient operation of the ore receiving station. Physical preparation of the ore for balling is accomplished with regrind ball mills, filters, bentonite crushing and drying facilities, pumps and related conveying circuits. Rotating table feeders deliver the reground and de-watered ore from storage bins to balling drums, where green ball or green pellet formation is achieved. The green balls are then conveyed to the indurating section. Three Dravo-Lurgi travelling grates, producing a total of 6,000,000 long dry tons of pellets per year, are used in the indurating phase of the operation. These grates, having 38 windboxes and firing at a temperature of 2,500°F, harden the pellets for shipment to various blast furnaces throughout the world."

Jan 1, 1969

By L. S. Trenholme

"Belleterre Quebec Mines, Limited, is a subsidiary of Mcintyre Porcupine Mines, Limited. The property is in Guillet township, Quebec, 45 miles due east of Haileybury, Ontario. It is accessible by 72 miles of gravelled road from New Liskeard, Ontario (Fig. 1).Gold production at the property commenced in 1936 and to March 31st, 1945, had exceeded $9,000,000. For the past 3 years the milling rate has averaged 325 tons a day and the gold recovery about $14 a ton.GENERAL GEOLOGYThe rocks of the district consist of Keewatin-like volcanics conformably overlain by Timiskaming-like sediments. Together they form the remnant of an easterly plunging anticline engulfed by granite (Fig. 2). The pregranite intrusives consist of diorite, gabbro, and ultrabasic rocks, occurring as dykes, sills, and irregular stocks. Dykes of porphyry and lamprophyre presumably related to the batholithic intrusive are common in this area. The veins of quartz are also probably derived from the batholithic intrusives. A few dykes of Keweenawan-type diabase have been observed."

Jan 1, 1954

By Michel Dagbert

"In their paper, Marcotte and Boucher (2001) cast some new light on the old problem of 2D estimation of vein-type deposits with thickness and grade of intercepts. Using a theoretical approach, some extensive simulation experiments and the Walker Lake data, they show that the direct approach (interpolation of grade at points on a regular grid) gives better estimates of the true grade at those points than the indirect approach (interpolation of grade x thickness or accumulation and interpolation of thickness) when there is some positive correlation between grade and thickness and that this better performance increases with the correlation of grade and thickness as well as the variability of both variables.We would like to bring some reservations to that conclusion by showing that even if direct point grade estimates are better than indirect ones, it is not necessarily true for block estimates and in particular for the estimated grade of the whole orebody itself."

Jan 1, 2001

By R. Abel

During the last eight years, the Ventanas electrolytic refinery has been improving its results by applying a series of new operational practices, such as the reduction of electrode spacing from 115 mm to 105 mm., raising the current density to 305 A/m2, modification in the operators shifts to about 70% of the workers, reducing the pulling cycles by two hours, and the erection of a new anode preparation machine. These improvements allowed an increase in the refinery capacity from 323,000 to 382,000 metric tons of electrolytic copper per year. In the same period it has obtained certification under the ISO 9001:2000 and ISO 14001:2004 standards. All of these developments have been achieved using conventional technology with copper starting sheets. The continuous improvement that is covered in this paper has allowed Ventanas to optimize its production, costs, and operational results. For the next years, it is planned to follow the same tendency, bringing the productivity of the plant to higher levels.

Jan 1, 2007