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By J. R. Rodda

Stainless steels are widely used to handle concentrated sulphuric acid (H2SO4) solutions produced in the manufacturing process, The majority of corrosion rate data published for stainless steel in product acid conditions is typically complied in tables or in iso-corrosion diagrams (iso-corrosion rates plotted as a function of temperature and H2SO4 concentration), without any reported consideration as to the accuracy and relevance of the method used to obtain the data, Given the characteristic potential cycling associated with the active-passive corrosion behaviour exhibited by stainless steel in hot, concentrated H2SO4, weight loss is considered to be a more reliable method than electrochemical measurements to measure corrosion rates, Consequently, an effort is made herein to demonstrate the accuracy and relevance of weight loss to determine laboratory corrosion rates in product acid conditions.

Jan 1, 2010

By J. F. Wright

Introduction Previous to 1924 the mining fields of Manitoba and adjoining territory had not been prospected in detail, and the reports of the exploration of the mineral discoveries to that date had been discouraging. As a result of the apparent failure of all the mining operations, some considered that geological conditions in the country westward from lake Superior extending across western Ontario, eastern and northern Manitoba, and northern Saskatchewan, were different from those in the northeastern part of Ontario, where large gold mines had been developed. Discoveries of importance thus were necessary to renew interest in the mining possibilities of this part of the Canadian Shield, and the successful operations at Flin Flon and Howey in large part were responsible for the beginning of the present activity in what may be described as the part of the pre-Cambrian Shield within central Canada. In Manitoba, the more important developments at present are in the Central Manitoba, Gods Lake, and Knee Lake fields. The large area from west of Flin Flon east to Herb Lake, also, is being explored carefully for gold deposits of merit. A number of properties in Red Lake, Woman Lake, and Pickle Crow areas are being drilled and explored underground. Many of the mines of the Lake of the Woods area, that were producing gold 30 years ago, are re-opened, and new prospects in this field and in the country to the east are being explored. The recent development of Little Long Lac mine in an area near the railway, and considered by some to have been thoroughly prospected years ago, has stimulated interest in the areas formerly prospected. In the autumn of 1934, the belts of greenstone and sediments in the country east of lake Nipigon were staked, and deposits in these fields will be explored in detail this year. This paper is presented to discuss the general features of the geology and gold deposits of the various prospecting fields in Manitoba and adjoining territory. Details of a number of the areas and mines will be presented at this meeting in papers by Barton on Little Long Lac, Tanton on Sturgeon River, Baker on Gods Lake, and Brownell and Kinkel on Flin Flon. Although mining was not active in most of this territory previous to 1930, geologists of the various government departments continued field studies and interesting reports were issued.

Jan 1, 1935

By O. G. Olvera, D. G. Dixon, E. Asselin, L. S. Quiroz

Dissolution rates of chalcopyrite (CuFeS2) were calculated using electrochemical impedance spectroscopy (EIS). The calculated dissolution rate decreased by a factor of 3.2 after the electrode was passivated. The results presented in this work indicate that the reduction of Fe3+ was the rate-controlling step for fresh CuFeS2 electrodes while the transport of cations within the passive film limited the dissolution rate for the passivated electrode. The transfer of cations at the electrode/electrolyte and passive film/electrolyte interfaces did not affect the dissolution rates of the fresh and passivated CuFeS2 electrodes, respectively. The catalytic effect of pyrite (FeS2) on the dissolution of CuFeS2 continued after the passivating treatment. The contact of fresh and passivated CuFeS2 electrodes with different FeS2 particles resulted in increased dissolution rates, due to an increase in the reduction rate of Fe3+.

Jan 1, 2014

By Martin Lebeuf

The phenomena occurring in the cathode and at the cathode surface of aluminum electrolysis cells are very important in regards to cathode voltage drop and cathode wear. In the current study, laboratory-scale aluminum electrolysis cell cathodes were analyzed by X-ray microtomography. This technique allows an excellent visualization of the distribution of different substances, if their respective X-ray attenuation coefficients are different enough. In the current case, the important difference in the mean atomic number between cryolitic bath and graphitic carbon results in good contrasts. The volumetric bath penetration profile, porosity and impurities distribution in the cathode were thus obtained. Furthermore, metallic impurities and bath heterogeneities were observed at the cathode surface. Observations were also made with Scanning Electron Microscopy - Energy Dispersive Spectroscopy (SEM-EDS).

Jan 1, 2011

By K. Östcrdahl

We are developing a cost-saving and environmentally friendly process with low energy consumption to recover the metal content and recycle the acid from spent pickle baths. The metals are precipitated as metal fluorides, which can be turned into metal oxides and hydrofluoric acid by thermal hydrolysis. In the proposed process the solution is concentrated by nanofiltration and the metals are precipitated in a subsequent crystallization step. Different nanofiltration membranes have been evaluated in experimental batch tests. The membrane MPF-34 from Koch Membrane Systems offered both good flux and acceptable metal retention even after long periods of acid storage. The solubility of B-FeF3.3H20 has been measured at varying acid concentrations and at different temperatures. The solubility decreases with increasing hydrofluoric acid and nitric acid concentrations. This suggests that the crystallization process should be operated at high acid concentrations. The crystal growth rate of B-FeF3.3H2O is found to be quite low but increases significantly with temperature. This suggests that the crystallization process should be operated at higher temperatures (40 - 60°C). Within the project a pilot plant has been constructed where the spent pickle bath solution is concentrated by nanofiltration to the desired metal fluoride supersaturation, and B-FeF3.3H2O is crystallized in a 10 L continuous crystallizer.

Jan 1, 2006

By J. Bigu, M. G. Grenier, S. Hardcastle

"This study was undertaken in a belt conveyor drift of an underground hard rock mine. The conveyor transported ore or waste from a crushing operation located upwind from the drift sampling locations. A 250 m section of this drift was selected and several types of measurements were taken. Average respirable concentrations in the drift were 0.43 mg/m3 and 0.19 mg/m3 for total and silica dust, respectively. From the respirable dust concentration profile along the drift, it may be possible to estimate the contribution from extended sources such as dust produced by the belt and return idlers.The airborne dust in the drift had an average mass-median aerodynamic diameter of 4.2 micron. A continuous dust monitor showed that the crushing operation produced fairly high dust concentrations (sometimes greater than 4 mg/m3) over short periods of time.IntroductionAirborne dust in the respirable range is known to be the cause of various forms of lung ailments . In underground mines, respirable dust sources are created at many stages of production. All mining operators are responsible for de signing and establishing means of reducing airborne dust. In some cases, sources of dust are well defined and suppression methods are standard.In the case of interest here, the airborne dust cloud was formed from the contribution from many sources, which may be either discrete or extended. At the experimental site, the discrete or point sources were the crushing operation and the belt conveyor transfer point (tail pulley). These sources may be controlled by proper dust capture and scrubbing systems as well as dilution ventilation. Examples of extended dust sources in the area include dust produced by the re-entrainment of settled particles along the drift. Ventilation air movement and vehicular traffic both contribute to this phenomenon. Dust produced by the conveyor is another example of an extended dust source. Caked deposits on the return strand and idlers as well as the transportation of dry material on the belt, can be major contributors. Proper wetting of roadways and muck as well as proper belt cleaning techniques can help reduce these emissions. The cleaning apparatus, used on the belt where these experiments were conducted, is shown in Figure I. These and other belt cleaning techniques are described in more detail elsewhere."

Jan 1, 1987

By J. G. Whellock, R. J. Phillips, J. W. Matousek, P. J. Marcantonio

"Stillwater Mining Company (SMC), a partnership of Chevron Resources and Manville Corporation, produces a copper-nickel, platinum-palladium flotation concentrate at its Nye, Montana mine. The concentrate is then toll processed in Europe. Recognizing the economic advantage of treating the concentrates at the mine site and of retaining this strategic resource in the United States, the Company commissioned Tolltreck International Limited and International Process Research Corporation to conduct pilot scale smelting tests with a flowsheet that would maximize metal recoveries while satisfying the environmental requirements of operations at Stillwater.Primary smelting was conducted in a single phase, 50 k W, submerged-arc, electric furnace. Refining the product mattes to copper-nickel ""white-metal""; containing approximately 2% iron, was accomplished in a Tolltreck, IV-litre, top blown rotary converter. Over-all platinum and palladium recoveries were approximately 99%; copper and nickel recoveries averaged 94%. INTRODUCTION(l-4)Stillwater Mining Company (SMC) a partnership of Chevron Resources and Manville, operates a copper-nickel, platinum palladium mine and concentrator at Nye, Montana, located in the valley of the Stillwater River, approximately, 100 km southwest of Billings. It is North America's only primary producer of these precious metals. The Stillwater area was mined for chrome ore during World War U and the Korean War, but it was not until 1961 that attention was drawn to the similarities between the Stillwater Complex and the Bushveld Complex of South Africa with its deposits of platinum group metals.A concentrated search for platinum was begun by Manville Corporation in 1967. Its presence, together with palladium, in mineable quantities was confirmed in the period 1976-1978, and the first partnership to develop the deposits was formed by Manville and Chevron in 1979. Anaconda joined the group in 1983, and in 1985 its share was purchased by Lac Minerals. In 1988 the interests of Lac Minerals were purchased by Chevron and Manville.The decision to develop the mine and build a concentrator was made in 1986. Construction began in the fall of that year, and the first concentrate was produced six months later, in March 1987. Underground mining is done in a two-shift, five day- week operation. Since startup, the concentrator has operated on a 24 hour/day, 7 day/week schedule, treating an average of 635 tonnes of ore per day and producing approximately 10 tonnes of concentrate."

Jan 1, 1989

By R. L. Eadie, J. L. Luo

The effect of plastic deformation on near-neutral pH stress corrosion cracking (SCC) also known as environmentally assisted cracking was studied by cracking rate measurements. All the tests were conducted in a synthetic near-neutral pH solution. The traditional potential drop tests using compact toughness (C-T) specimens with 2-3 mm long pre-cracks showed varying plastic deformation by rolling would increase the material's susceptibility to SCC. This was confirmed by cyclic loading tests using double notched flat tensile specimens with 200-300 µm long pre-cracks which gave the same results that the specimen with large scale plastic deformation by tensile loading had a relatively faster crack growth rate than that with only small scale plastic deformation.

Jan 1, 2005

By S. Kursunoglu

The aim of this study was to investigate the effectiveness of Ascorbic (C6H8O6) Acid (AA), Activated Carbon (AC) and Guar Meal (C6H12O6) (GM) as a reductant for the simultaneous complete dissolution of zinc (Zn) and manganese (Mn) from a spent and mixed Zinc-Carbon (Zn-C) and alkaline battery powders in sulphuric acid (H2SO4) leaching. AA was tested previously as a reductant by other researchers while AC and GM were tested as a reductant for the first time in battery recycling. The effects of H2SO4 concentration, AA/AC/GM dosages, reaction temperature and leaching time on the Zn and Mn dissolutions were investigated according to 2k full factorial experimental design and Central Composite Design (CCD) technique; then, a simple optimization study was carried out for comparing the reductants. The optimum reductive acid leaching conditions for AA were determined at 3 hours leaching time, 70°C leaching temperature, 0.5M H2SO4 concentration, 13 g/L AA dosage, 1/20 g/mL solid/liquid (S/L) ratio and 200 rpm stirring speed. Under these conditions, the dissolution efficiencies were 99.9% for Zn and 99.3% for Mn. The best reductive acid leaching conditions for AC were determined at 3h leaching time, 80oC leaching temperature, 1M H2SO4 concentration, 3 g/L AC dosage and 400 rpm mixing speed. Under above conditions, Zn and Mn dissolutions were not complete. At 2M H2SO4 concentration, 10 g GM dosage, 700C leaching temperature, 200 rpm stirring speed, 1/20 g/mL solid/liquid (S/L) ratio and 3 hours leaching time, full dissolution of both Zn and Mn was achieved. As a result, three different reductants were evaluated in this study for complete simultaneous Zn and Mn dissolutions. This paper also compared present test results with previous spent battery recycling studies for Zn and Mn dissolutions. Full valuable metals dissolutions from spent batteries were achieved at low H2SO4 concentrations with AA and high concentrations with GM. Selective precipitations of Zn and Mn from acid solutions were carried out using NaOH and KOH. Using 3M NaOH as precipitating agent at room temperature and at pH 8; 95.4% of Zn and at pH 10; 93.7% of Mn were precipitated from the leach solution. Under the same conditions, using 3 M KOH at pH 8; 91.6% of Zn and at pH 10, 96.4% of Mn were precipitated. Based on the experimental results obtained, an appropriate flow sheet was proposed to recover both Zn and Mn.

Aug 1, 2013

By D. Chadwick, J. W. Matousek

Between 1860 and 1890 -- from the time of the American Civil War to the last decade of the 19th Century -- nickel production in North America was dominated (even monopolized) by the output of the industrial complex of the Gap Nickel Mine near Lancaster, Pennsylvania and the American Nickel Works in Camden, New Jersey. In some years, from one sixth to one third of the world's metallic nickel supply came from this enterprise. Mining and smelting were conducted at Lancaster; a matte of high iron content was shipped to Camden for pyrometallurgical and hydrometallurgical refining to produce nickel metal, copper sulfate, and cobalt oxide. The high purity nickel product was rolled into sheet for marketing, primarily for coinage, as nickel had few other uses at that time. The undertaking experienced all of the problems that face the mining and metallurgical industries of today: declining reserves, high labor and fuel costs, high transportation costs, fluctuating demand and prices, pollution concerns, and foreign competition. The technical features of the geology; the mining, smelting, and refining operations; and some of the economic aspects are assessed. The view is taken from that of the present time -- seeking those lessons from history that we are supposed to learn or face the prospect of repeating the mistakes of the past.

Jan 1, 2005

By Wm. D. Jr. Sheldon

THIS paper presents practical data to aid in the selection of a mine ventilating fan, and outlines considerations to be made to ensure satisfactory operation and optimum efficiency of the fan. Much has been published on the general subject of mine ventilation, but the writer has found few specific data on factors and considerations which govern the selection of a fan-data which should be available to the operator if his fan is to give satisfactory service within the range of the high-efficiency portion of its performance curve and deliver the specified air capacity when operating against the anticipated range of resistance of the mine. The total quantity of fresh air furnished by the ventilation system must be adequate to provide, and to ensure at all times, safe and healthful working conditions in the mine. It is assumed that the mine operator is able to determine the air quantities required for the various parts of the mine.

Jan 1, 1941

By P. J. Sylvester, S. J. Piercey, S. Maloney, S. M. Brueckner, L. Pilgrim, D. Hyde, G. Ogilvie

The 1806 zone is part of a Au-rich volcanogenic massive sulfide deposit at the Rambler Camp on the Baie \/erte Peninsula, northwestern Newfoundland, and is characterized by high Au grades (3.97 g/t), relatively low Cu and Zn grades (0.60 wt% Cu, 1.17 wt% Zn), and moderate Ag grades (27.83 g/t) at ca. 0.37 Mt ore. Gold and Ag occur as electrum and different Ag varieties including Ag-Hg ± Au alloys, miargyrite, and pyrargyrite that occur often in close proximity to electrum. Additionally, Ag-, As-, Sb-, and Sn-bearing sulfosalts are frequently observed and usually close to electrum. These textural relations strongly favor a syngenetic/magmatic origin for the 1806 zone, despite having a metamorphic overprint.

Jan 1, 2011

By Bob Butler

Brunswick Mine has been involved in a comprehensive research program investigating site specific aspects of thiosalt management to eliminate its adverse environmental effects. Minimum annual reagent cost estimates for thiosalt treatment using hydrogen peroxide and sodium hypochlorite are $400K and $1.5 million respectively. Also, minimum costs for the use of bicarbonate to buffer the pH depression associated with thiosalt oxidation in the receiving environment is in the order of $400K annually. A design of experiment (DOE) research program identified that natural UV radiation, temperature, DO and water chemistry are key factors influencing the natural oxidation rate of thiosalts within Brunswick?s water management system. A DOE surface response model was used to describe the thiosalt oxidation kinetics, which were then used to develop a predictive oxidation model for thiosalt and pH control of the mill?s reclaim water system.

Nov 1, 2002

By S. Balideh

A good understanding of the behavior of rock helps us to make more informed decisions regarding geo-structures. Engineers need accurate equations to calculate the strength and deformation of rock before and after failure. Previous studies explain the failure of rock to ultimate strength, and laboratory tests adequately determine the ultimate strength and deformation modulus of rock. However, there are few comprehensive equations to determine the post-failure strength and deformation of rock. Previous work shows that the post-failure behavior of rock depends on the behavior of the broken rock particles after failure. The following question is then posed: How can the post-failure behavior of rock be determined by the behavior of broken rock particles? In order to answer the question, this study pursues three objectives: (i) to explain the behavior of broken rock at low confining pressure; (ii) to estimate the behavior of broken rock via the extrapolation of scaled laboratory testing; and to suggest a procedure (iii) to outline the post-failure behavior of a rock mass at low confining pressure commensurate with the behavior of broken rock in a rock mass.

Aug 1, 2013

By Tao Cheng

Previous research and applications in construction resource optimization have focused on tracking the location of material and equipment. There is a lack of studies on automated monitoring of the interaction between workers and equipment for safety purposes. This paper presents a new approach for measuring the safety performance of construction personnel particularly when they work in very close proximity to moving equipment as well as static hazards such as chemical and flammable substances. A method of generating hazardous zones according to the geometric and kinematic characteristics of the considered hazard is introduced. The spatio-temporal relationships between the hazardous zones and workers? positioning data collected by real-time location sensing technology are automatically analyzed. This approach has been validated in a controlled test bed environment that simulates a construction site. Results indicate that worker?s safety performance of selected activities can be automatically and reliably measured using the developed approach. Furthermore, a heat map is generated for visualizing proximity related issues in the test bed using the computed results.

Aug 1, 2013

By C. Andrews

Fuel cell testing requires fully automated operation, on-site configuration of tests, and real-time monitoring for performance and failures. Balancing the flexibility and programmability of a test station with reliability, cost, and user interface can be a daunting challenge to the test equipment engineer. Endurance testing of fuel cells requires the highest level of reliability for test stand hardware and software without compromising automation capabilities or users interface. Techniques for implementing an ultra-reliable test platform addressing hardware limitations, sophisticated watchdog monitoring to prevent inadvertent shutdowns, and software limitations (e.g., balancing a highly-functional graphical users interface with reliability) are presented.

Jan 1, 2005

By F. E. Goodwin

Since the last CIM Zinc and Lead Conference ten years ago, significant technical and market forces have influenced how these metals are used, and the geographic distribution of their uses. Unprecedented price fluctuations have opened competitiveness issues, while the rapid growth of the Chinese market has created challenges both inside and outside China. Recent technical developments in battery energy storage, coatings, castings and chemical applications of lead and zinc will be reviewed together with the influence of these trends on end use markets.

Jan 1, 2008

By J. S. Redpath

Eighty feet of overburden, thirty feet consisting of fine, water-bearing sands, was encountered during the construction of a shaft collar for Chimo Gold Mines Limited at its Louvicourt, Quebec, property. This paper describes the excavation and construction methods used on the project. Open-cut methods, a sheet pile cofferdam, chemical grouting and special blasting methods were used during excavation. Concrete placement was hampered in the lower portion by a heavy water flow, and aided in the upper portion by an unusual method of form bracing. Plant and • pum11ing facilities are also described.

Jan 1, 1966

By J. E. Udd, S. Bharti

"ABSTRACTMonitoring of stability conditions in underground mines permits management to assess the response of the rock mass to mining strategies. Monitoring of movements, if sufficiently early, may also permit operators either to avert potential failures or to develop alternative approaches to extraction.The Falconbridge organization has been a leader both in the uses of rock mass stability monitoring techniques and in the development of instrumentation.In this paper, the authors review the Falconbridge approaches to monitoring, and present case history examples to illustrate the application of the various instruments used.RESUMELa surveillance des conditions de stabilité dans les mines souter-raines permet aux chefs d'enterprises d'évaluer les réactions de la masse rocheuse aux méthodes d'extraction minière. Si le contrôle des mouvements du terrain est effectué assez tot, l'exploitant pourra prendre les mesures qui s'imposent, soit pour éviter les détériorations possibles ou pour mettre au point de nouvelles méthodes d'extraction.Le groupe de la Falconbridge a ére le premier a utiliser des techniques de vérification des conditions de stabilité de la masse rocheuse et a mettre au point l'appareillage requis.Ce document présente une revue des méthodes employées par la Falconbridge pour assurer la surveillance active de la stabilité de la masse rocheuse et illustre au moyen de cas concrets la manière d'utiliser les divers appareils."

Jan 1, 1987

By C. Cekerevac

The paper addresses some geotechnical issues related to the construction of the Deriner dam and HEPP. Design considerations and rock stabilization measures are presented for the excavations which took place in a highly fractured and weathered rock mass prevailing on site. Particularly, the shallow excavations for the overflow spillways tunnels are discussed. These present huge openings that are 12 m wide and 18 m high in portal areas, with an overburden of approximately 20 m, for which numerical finite element analysis and structural discontinuity analysis have been performed to ensure safe excavation process and future operation.

May 1, 2009