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By A. Otsuki

"This paper discusses the primary collector adsorption onto a sulphide mineral in mixed collector systems to understand its adsorption mechanism. UV-vis measurements were performed to identify the primary collector concentration adsorbed on pyrite, and the adsorption kinetics under different conditions were compared to distinguish their difference between single and mixed collector systems. Small amount of secondary collector addition prior to the primary collector addition significantly improved the adsorption kinetics of primary one. The result was explained by the combination of two previously proposed mechanisms (i.e., different adsorption site mechanism and multi-layer product mechanism). This study showed UV-vis measurement as an effective tool to study mixed collector adsorption behaviour.INTRODUCTIONCollectors are surfactants composed of heteropolar molecules with a non-polar and a polar group (Lotter & Bradshaw, 2010). In a froth flotation process, the function of collector is to improve the hydrophobicity of target minerals and selectively float them with the aid of gas bubbles. Because of the chemical or physical attraction between the polar group and the mineral surfaces sites, collector molecules adsorb on the particle surface with the non-polar group assigned towards the bulk solution (i.e., water), thus the mineral particle surface becomes hydrophobic (Wills & Napier-Munn, 2006).Thiol collectors are major collectors widely used in sulphide mineral flotation. Potassium amyl xanthate (PAX), dithiocarbamate (DTC), dithiophosphate (DTP), mecaptobenzothiazole (MBT) are some common thiol collectors. Previous studies reported that some mixed collectors systems enhanced the flotation performance (e.g., Bradshaw, 1997; Bradshaw et al., 1998; Rao & Forssberg, 1997). Thiol collector mixtures are often used in the flotation of sulphide ores, and discussed with the synergistic benefits (Bradshaw et al., 1998) which include lowering the total collector dosage requirements, improving the sulphide recovery and the rate of flotation as well as the improving the froth characteristics. The current paper mainly considered the mixture between two thiol collectors (PAX and DTC, considered as a weaker and selective collector, and stronger and less selective collector, respectively (Bradshaw, 1997)) to further understand their adsorption mechanism that should assist in improving the flotation performance of refractory gold ore."

Jan 1, 2016

By Nabeel Khan

Annual oil production from the Canadian Oil Sands in Northern Alberta has been rising for several decades, and more ore and overburden are excavated each year from an increasing number of open pit mines. Overburden meeting certain specifications will be used to dam tailings and fill open pits, but the remaining material must be stored in overburden storage structures (OBSS). Well-designed overburden storage structures are more stable and cost less in the short- and long-term. The purpose of this paper is to explore OBSS designs that will be stable yet economical in the short- and long-term. The geological background of the site is briefly discussed, including the effect of each of the main geologic layers (recently deposited till and muskeg, Clearwater Formation clay shales, McMurray Formation oil sands, and the Devonian limestone) on the slope stability of the OBSS. Cost is considered in the analysis when balancing between minimizing costs (steeper slopes) and acceptable factors of safety (flatter slopes), all the while considering the financial consequences of failure. Potential failure planes are identified and probabilistic analysis is conducted on the critical failure surface. The variations in the factor of safety caused by varying pore water pressure, friction angle, and cohesion, are plotted and discussed.

Jun 1, 2012

By G. Kollberg

"IntroductionThe SALA Caravan Mill system represents a proven concept for the design and operation of mobile and semi-mobile ore dressing plants.The Caravan Mill has been developed to meet the demand for a flexible processing plant to be used for small and medium-sized orebodies or for pilot investigations of deposits directly at the mine site e •The first Caravan Mill installation was put into operation in 1970 and a number of plants have been delivered world-wide since then.The Caravan Mill system has great flexibility both in capacity, ranging from 50 to 1000 tons per day, and in process combinations. The process modules available are:• crushing by jaw and cone crushers;• pre-concentration by the Dyna Whirl Pool dense media system;• grinding by wet rod or ball mills;• separation by gravity, magnetic, flotation or leaching-CVP adsorption methods;• dewatering by lamella or conventional thickeners and vacuum filters.To form complete plants, auxiliary equipment is also available, such as:• bins, feeders and conveying systems;• power generator units;• water tank and pump for process water;• interconnecting piping and cables;• erection and service tool kits;• set of spare and wear parts.For mine sites with rainy or winter conditions, a plastic tent with air heater can be supplied to cover the ore dressing equipment. Each module is workshop assembled complete with slurry pumps, internal pipe work, electric wiring with plug-in connections, hoses, etc., all arranged for quick and simple connection between the units. Before delivery, each unit is tested in the workshop."

Jan 1, 1982

By V. F. Kozyrev, L. B. Tsymbulov, L. Sh. Tsemekhman, A. N. Golov

Gipronickel Institute, JS has developed a new process and equipment for melting copper raw material in a two-zone Vaniukov furnace resulting in the production of white matte and low-grade slag in terms of copper content. Tests on processing copper nickelcontaining ore from Norilsk (Cu - 17 %), Ni - 3 %) were conducted in Vaniukov pilot furnace (total area 11.4m2) of Severonickel Combine. The amount of the processed material was about 11 thousand tons. Principal results of pilot testing are presented.

Jan 1, 2007

By Thomas J. Ferree

"IntroductionThe objective of this chapter is to provide important criteria relating to the operation and maintenance of spiral concentrators and Reichert cones, so that optimum performance can be achieved and maintained in a mill circuit. Little space will be devoted to the theory of the forces of separation or the technical details of the devices, as that in(ormation is available from other sources. The discussions in this chapter will be presented in a manner that should be interesting and useful to anyone who may be exposed to these methods of gravity separation. It is most important for the reader to understand that each application of the equipment should be considered on its own merit, as no two suites of minerals respond exactly alike in mineral processing circuits. The information herein should be useful as a guide toward increasing the metallurgical efficiency of the processes, irrespective of the type of minerals being concentrated.It is highly recommended that certain tools be made available to the personnel responsible for metallurgical performance of the spirals and cones; these include a set of standard type laboratory screens, a medium quality petrographic microscope, and a vanning plaque or gold pan. These devices, when used in conjunction with a basic understanding of the mill circuit, provide immediate knowledge on the characteristics of any sample in the mill circuit. The information gained by visual evaluation of sized fractions of products can solve many of the basic problems of mineral beneficiation, and at the same time increase the interest of the non-technical personnel associated with the plant operation. There are many problems associated with obtaining satisfactory performance from a mill operation. Many of the problems have to be solved using a technical approach. Some of the problems, however, can be solved with practical knowledge and common sense. It is hoped this chapter can provide a guide to both techniques."

Jan 1, 1989

By N. Romani, R. Provost

"Commissioning of a circulating dry scrubber plant was recently completed at an existing facility, in order to treat the sulphur dioxide off-gas emitted from rotary kilns. Proper planning of the different commissioning stages and staffing an integrated team are the most important factors required for a successful plant start-up. A strong operational readiness plan must be in place as early as the start of construction in order to ensure a smooth transition from commissioning to operations. Plant performance can meet or exceed performance criteria within the required timeframe if the proper group dynamic and good communication is established between construction, commissioning and operations teams.INTRODUCTIONCommissioning of a circulating dry scrubber (CDS) plant was recently completed at an existing facility in Quebec, Canada. The CDS plant treats the sulphur dioxide off-gas emitted from rotary kilns in order to meet increasingly stringent environmental requirements. This installation enables the existing facility to reduce their sulphur emissions by over 90%.The CDS ProcessA general overview of the CDS process is presented in Figure 1 below. The combined, de-dusted off-gas from multiple kilns is sent to the CDS, which acts as an entrained fluid bed, where the gas is contacted with a water mist, re-circulated solids and hydrated lime. The SO2 from the gas stream and the available calcium hydroxide (Ca(OH)2) from the hydrated lime dissolve in the water and react to ultimately form calcium sulphites and gypsum. The solid residue (referred to as CDS residue), is the primary byproductof the process.Fresh hydrated lime and CDS residue is captured by the dust collection system and is re-circulated to the CDS via a fluidised transport system. Clean off-gas passes through the dust-collection system and is then sent to the atmosphere by a single exhaust fan.The CDS residue purged from the system is combined with the dust collected from the kiln offgas system and this mixture is wetted in the already exiting agglomeration system, to minimize dust generation during handling, and then sent to disposal."

Jan 1, 2016

By Jean-François Dorion

In an underground mine rock reinforcement elements and surface support units are often exposed to conditions that make them susceptible to corrosion. These unfavourable conditions include high relative humidity, the presence of dust and various other particles in the atmosphere, splashing of water and gases from blasting and diesel equipment. The corrosion of support systems is often associated with a loss in capacity that can be a major safety and economic concern in underground mines. A support system is composed of several components such as bolts, mesh, plate, retaining nut, cable ties. Every individual component can deteriorate due to atmospheric or aqueous corrosion and consequently can damage the integrity of the support system. This paper reports the results of a 5-yr study on the loss in capacity of individual support and reinforcement components at selected underground hard rock mines. As part of this investigation corrosion coupons were installed at selected locations at participating mines. A number of these coupons were recovered at regular time intervals and analysed for any signs of corrosion and subsequently tested to quantify any loss in capacity. The testing of the corrosion coupons was complemented by similar tests on recovered mesh and friction bolt specimens from the site. The collected data have provided useful insights on the factors that contribute to the corrosion of support systems. This knowledge can aid in the selection of appropriate support strategies and a reliable assessment of the predicted useful life of a support system and the need for rehabilitation.

Jun 1, 2012

By Paul T. Fitzgerald

Risk financing solutions are emerging to fully address environmental liabilities for mining operations. Supported by specialized insurance and alternative risk transfer (ART) products, mine owners can fund, cap and guarantee the environmental liabilities and closure obligations of a mine within a financial structure that will be acceptable to regulators. An environmental risk financing program will permit an owner to transfer the liabilities and indeed the ownership of a site to a third party that has the ability and resources to responsibly execute the closure plan. A properly structured program will be financially viable for the owner and will also respond to community and environmental opposition concerns about sustainable development and the environmental legacies associated with mining activities.

Apr 1, 2005

By Michael Hopp

The beginning of the electroforming technology dates itself on the beginning of the industrial revolution 1800 to 1820 approximately. Basis was the existence of electricity in order to be able to drive the electro-form-process. With the development of the electroforming, big names of the science-history, like Michael Faraday (1791? 1867), Sir Humphry Davy (1778?1829), Max Schlöter (1878?1946), Werner von Siemens (1816?1892), and many others. Already about 1840, the first monograph originated to electroforming (38). While in the first years the electro-forming most extensive only to the coating of art - or other usefulness-objects was used. At the beginning of the 20th century the formation of objects from pure metals became more and more, later also from alloys to application. One of the first bigger electroforming factory, the ?Württembergische Metallwarenfabrik? was working 1894 in Geislingen / Steige, Germany. In the industrial application, the electroforming-technology is to be imagined away for miscellaneous coatingtasks and the form-body-preparation no longer today (18). A little bit confusing is the german name ?galvano-technology?. It based on the Italian physiologist and naturalist Luigi Galvani (1737 ? 1798). This technically seen is however wrong, right, the name is electroforming. The physical bases were founded mainly by Michael Faraday and Sir Humphry Davy.

Oct 1, 2003

By Isabel F. Barton, Matthew J. Gabriel, Mark D. Barton

Process control, mine-to-mill optimization, and other mining operations depend on having robust, comprehensive mineralogical and chemical characterization. However, current characterization methods rely primarily on analyzing samples from trenches, channels, blast holes, and drill holes and interpolating between them, and are not always sensitive to some minerals (such as clays) that cause major problems for mining and mineral processing. Continuous characterization is possible with techniques such as hyperspectral remote sensing, which measures reflectance or absorption of light in the visible to near infrared (VNIR) and short-wave infrared (SWIR) regions of the electromagnetic spectrum. Absorption and reflectance features are characteristic of different chemical bond types, so each spectrum corresponds to a different mineral or material. In remote sensing, each pixel in the scanned area has both a location and a spectrum. This makes hyperspectral remote sensing potentially useful for characterizing mine site materials. In this study, we tested a hyperspectral remote sensing system as a method of characterizing the mineralogy and material types at mine and metallurgical sites. Our test site was a small open-pit copper mine and leach operation in the southwestern U.S. We scanned mine highwalls, dump piles, leach pads, and nearby rock outcrops with drone- and tripod-mounted VNIR-SWIR spectrometers. We collected ground-truth data through geologic mapping, sampling, and spot analyses with a portable short-wave SWIR instrument. The results show that the hyperspectral remote sensing system that we tested is capable of distinguishing the types and distribution of spectrally active minerals and other materials in diverse mining settings, including showing wet and dry areas of leach pads; clay and carbonate type and distribution on mine highwalls, leach pads, dumps, and rock outcrops; plant type and distribution; fault zones, bedding planes, and other geological features; and qualitative spectral matches between dump piles and areas of the mine highwalls. Hyperspectral sensing proved particularly sensitive to the presence and type of clay and carbonate minerals, which cause geotechnical and metallurgical problems such as highwall failure, gangue acid consumption, and flotation sliming. Examples will be presented and discussed at the conference. Areas of continuing research include automating and streamlining the data reduction process, integrating hyperspectral data with block modeling and mine planning software, and testing the results of hyperspectral sensing in different geological environments.

Jan 1, 2019

By E. Busse, J. E. Burgener, J. G. Eacott, M. C. Robinson, P. E. Burgener

"This paper presents a preliminary assessment of the technical and economic feasibility of a caustic leach - electrowinning process for the recovery of zinc and lead from electric arc furnace baghouse dust at a mini-steelplant. Recent studies and literature are referenced briefly as they pertain to the formation and characterization of dust, toxicity considerations and alternative dust treatment and disposal options.Laboratory testwork results, published data, pilot plant experience and anticipated influences resulting from recycling residues are used for the purpose of developing a conceptual design for a caustic leach - electrowinning plant to treat 15,000 tonnes/year of dust at a one million tonnes /year capacity steelplant in Canada.Target economic studies, comprising preliminary estimates of capital and operating costs, revenues and rate of return are presented. Economic and commercial considerations concerning the relative merits of dust treatment at a centralized facility compared with an on-site plant are discussed.IntroductionThe treatment or disposal of mini-steelplant electric arc furnace (EAF) baghouse dust has been given increasing attention in recent years for two principal reasons. Firstly, the dust is now classed as a hazardous waste material under V.S. EPA regulations which prohibit its disposal in dumps other than controlled landfill sites. Secondly, the dust contains certain metal values, notably zinc and lead, which may be economically recoverable, depending on the costs associated with disposal resulting from enforcement of the EPA regulations. Other metallurgical dusts and waste materials, from both ferrous and non-ferrous operations, may require the same considerations as EAF baghouse dust.Several studies have been carried out to examine various aspects of dust treatment but few commercial plants are in operation. Technology employed uses pyrometallurgical techniques. Commercial-scale hydrometallurgical plants are not known to exist although small-scale plants are frequently more economically attractive than their pyrometallurgical counterparts which generally require economies of scale to be viable.The concentration of mini-steelplants in northeast V.S.A. and southeast Canada merits study to determine whether or not dust treatment for metals recovery is a commercially feasible alternative to disposal.This paper examines the technical and economic feasibility of a caustic leach - electrowinning process for the recovery of zinc and lead from EAF baghouse dust at an on-site ministeel plant processing carbon steel scrap and discusses economic and commercial considerations pertaining to dust treatment at a larger, centralized facility."

Jan 1, 1984

By Y. Wang

Phosphates and fluorides are used as regulators for the removal of silicates from diasporic-bauxite both in direct and reverse flotation. While using dodecylamine chloride as a collector, micro-flotation studies showed that sodium hexametaphosphate has stronger depressing power on diaspore than on silicate minerals with increasing sodium hexametaphosphate concentration at pH 6.5, but sodium fluorosilicate shows poor depression on diaspore with increasing sodium fluorosilicate concentration at the same pH. Zeta potentials of diaspore and silicate minerals become more negative both in the presence of sodium hexametaphosphate and sodium fluorosilicate. Adsorption density studies indicated that the adsorption density of sodium hexametaphosphate on diaspore is much higher than that on silicate minerals at the concentration of 75 mg/L. FTIR spectroscopy studies show that sodium hexametaphosphate interacted with the Al atoms exposed on the diaspore and silicate minerals surfaces to form P?O?Al bonds through the P02 groups. It is possible that sodium fluorosilicate interacted through F- or [SiF6]2- with silicate minerals surfaces based on the analysis by AES.

Jan 1, 2006

By Chuan-liu Wang

The bionic non-smooth surface has the characteristics of anti-wear, and reducing resistance. Based on bionic non-smooth surface?s characteristics, a bionic drill bit was developed. When the bionic drill bit is used, a bionic non-smooth surface forms on the crown of bionic drill bit. This surface can be used to extend the life of drill bit and improve drill efficiency. The bionic unit diameter and arrangement were researched in this paper to determine the optimal bionic non-smooth surface for further improving the life and efficiency of drill bit. Four bionic samples having the same structure size, materials and arrangement were designed and manufactured. After being sintered, the abrasion ratios of the four bionic samples were tested, and the results show that the abrasion ratio of Nos. 3 and 2 were similar (only 2% difference) and higher than that of No. 1 and 4. Therefore, the optimal diameter of bionic unit is 1.5 and 2.0 mm. Small diameter bionic drill bits were designed and manufactured, and tested in the laboratory. The results show that not all bionic structure bodies are better than normal diamond bits, except the bionic unit arranged in a reasonable range. When the angle was 24° and 30°, the arrangement of bionic unit were more reasonable, which shows the superiority of the bionic coupling bit.

Aug 1, 2013

By F. Rashchi, N. Naseri Joda

Recycling of electronic wastes is an important subject both from an environmental point of view and also the recovery of valuable materials. In this research, PC board scraps were leached to recover Cu, Ag, Au and Pd. Due to the high cost of the shredding process and to avoid secondary pollution from odors and dusts, board scraps were cut into 5X5 cm2 pieces. To determine the most effective leachant, aqua regia, nitric acid, hydrochloric acid, ammonium persulfate and potassium persulfate were tested. The effect of the leaching parameters, the leachant concentration, temperature, leaching time and liquid to solid ratio were studied and optimized using response surface methodology.

Jan 1, 2011

By F. -Z. Ji, G. A. Irons, M. Barati, K. Coley

The use of oxygen in electric arc furnace steelmaking is tied to the use of fossil fuels, and slag foaming. The current work examines the kinetics of carbon injection into EAF slags especially the saturation injection rate and available reaction area in the slag foam. Based on individual rate data and experimental gasification rates of carbon in the slags, the available reaction surface area in the gas bubbles was found to be around 1900¬4700 cm2.kg-slg-1 for carbon injection into EAF like slags at appropriate injection rates and steel making temperatures. The ratio of number of bubbles to number of particles is 1 to 17 and the weights of carbon per unit reaction area are 0.001-0.008 gC-cm-2. Using the relationship between active reaction area and x supplied in this study, the gasification rates of carbon in slags can be estimated with gas-slag interfacial reaction rates.

Jan 1, 2004

By S. V. Ulianov, A. Y. Senchenko, A. A. Shvets, A. V. Aksenov

Development of an efficient technology to process complex ores containing gold and antimony as well as silver is described in the paper. The results from the testwork aimed at the valuables recovery by means of flotation are presented. A process sample of antimonite gold-bearing ore was studied in TOMS institute aiming at development of a technology to process such an ore with generation of antimony concentrate and sulphide gold-containing concentrate. Material composition study indicated that the ore included 5.3% of sulphides: arsenopyrite – 2.4%, pyrite -2.4%, and antimonite – 0.5%. Gold is present as an isomorphic dissemination in arsenopyrite. At sighter testing stage a direct selective flotation flowsheet was chosen to process the ore. Antimonite flotation was activated due to addition of lead nitrate. A single cleaning of a rougher flotation concentrate resulted in antinomy concentrate with 30% Sb content and 71% recovery. Au recovery into antimony concentrate did not exceed 1%. Sb flotation tailings were used to float the remaining sulphides and gold. The resulted sulphide concentrate was characterized by Au content of 20 g/t at about 80% recovery, arsenic content - 10% at ~80% recovery, and sulphur content - 18% at ~81% recovery. The sulphide concentrate can be forwarded to further processing aiming at gold recovery. Given that the concentrate is highly refractory it should be pretreated (bacterial or pressure oxidation, Albion process) prior to cyanidation in order to liberate gold from sulphides. The proposed technology allows one to solve the problem of precious metals recovery from antimonite ores.

Jan 1, 2016

By Jamal Jafari, Abbas Sam

"The concentration of the fourth production line at Golgohar includes 66% iron with Blaine number of 500 cm2/g. For pelletizing process, the feed iron grade should be greater than 68% with minimum Blaine number of 1800 cm2/g. In this study, the low intensity magnetic Separators, particularly the feed particle size distribution of LIMS were considered. The feed particle size distribution of the separators was optimized to prepare an appropriate concentrate (as mill pelletizing feed). The samples were performed from the LIMS feed and after grinding, four d80 (64, 103, 132, and 15 3µm) were prepared. Then, laboratory magnetic separation experiments were conducted on these samples. The best results obtained using d80 of 132µm. In this particle fraction, the iron grade and Blaine number were 70.3% and 1571 cm2/g, respectively. Therefore, it seems necessary to include a grinding and classification systems before LIMS stage. According to the presence of a high amount of -132 µm particles in the initial feed, an inverse closed circuit was selected. The hydrocyclone was designed in three units as the classification system with 62 cm (diameter), 22 cm (overflow outlet) and 11 cm (apex diameter). By simulation of hydrocyclone with USIMPAC software, the size distribution of underflow was determined. Based on these results, a ball mill with dimensions of 6.7 m (length) and 5 m (diameter) was designed as grinding system.INTRODUCTIONGole-Gohar iron ore concentration plant No.4 (Polycom Plant) in Gole-Gohar Industrial and Mining Complex was installed to increase production capacity as well as treating the circulating load from AG and SAG mills of the main concentration plant of the complex. The load from the mine is crushed using jaw and cone crushers. The crushed ore is then combined with the circulated load and the combination is then grounded using HPGR and ball mills respectively.After comminution, there is a magnetic separation plant which includes a medium intensity magnetic separator (MIMS) followed by three low intensity magnetic separators (LIMS). Final concentrate dewatering is done using three belt filters. After the primary magnetic separation, the ore is upgraded to 62% Fe content and final concentrate which is the product of LIMS has 66% Fe content."

Jan 1, 2016

By Adam Turcotte

Mining operations consume a considerable amount of energy, and while reduced energy consumption is desirable, it is not always clear how to achieve this goal. Understanding the opportunities to optimize energy consumption is crucial, and the key to understanding is visualization. One option is the Sankey diagram, which has been used for over 100 years to visualize the flow of energy, materials, or cost through various processes. However, there are drawbacks to this approach that must be addressed. In a Sankey diagram, each flow is represented by an arrow possessing a width proportional to the magnitude of the flow it represents. The diagrams show input flows, how energy is converted and into what form, and also output flows. As per the first law of thermodynamics, the total energy output is equivalent to the total energy input, so any energy that is not transferred to another process is considered to be wasted. These waste flows are depicted in Sankey diagrams and make it straightforward to associate energy sources, sinks and waste flows. Unfortunately, Sankey diagrams do not convey all information required to support practical decision making for redirecting individual energy flows. Based only on a Sankey diagram, it may become evident that a significant flow of waste heat is of the appropriate grade (temperature) and volume to meet an on-site heat demand currently being met with paid-for, possibly carbon intensive fuel. However without augmenting the Sankey diagram with 3D spatial, true geometric analysis, the practicalities of the concept or idea may not be fully appreciated. Another issue with a Sankey diagram is that the magnitude of the energy flowing between processes may have temporal fluctuation or variability on different timescales (diurnal, seasonal, interannual). Currently, Sankey diagrams only provide a static picture of energy conversion and consumption, so that, for example, 4 separate diagrams could have to be prepared for each season. A new energy flow visualization technique which we have called Sankey Trees has been developed. Process locations are defined within a 3D model of the site being studied, and the magnitude of the flow between each pair of processes considered is replaced with a time series. Branches of sustained and diminishing flows are represented through variation of the geometric properties of the branches of the trees. These branches are animated to indicate the direction of flow, and branch joints are used to indicate that a process is transporting one form of energy to multiple processes.

Aug 1, 2013

By D. Virely, M. Gasc-Barbier, J. Guittard

"The valleys of the Dordogne and the Vézère (France) have been inhabited since prehistoric times, as evidenced by the famous site of Lascaux. A few miles away, the village of La Roque-Gageac is also a very popular tourist destination (about 1.5 million tourists per year): The village is sandwiched between a massive limestone cliff and the Dordogne river. The collapse of a cave roof high above the village in January 2010 led us to characterize instability together for the cave and the whole cliff and propose a adapted instrumentation to monitor the fracture openings in the rock mass that are linked to climatic variations. Measurements have been going on and been recorded for nearly 4 years. They point out the role of thermal stress fatigue in the breakdown of the rock mass. In this paper we describe the site under study, the instrumentation and its main results. INTRODUCTIONThe phenomenon of thermal fatigue has been very little studied as far as rocks are concerned, whereas it is rather well characterized for other types of materials: Elsevier published a journal dedicated to fatigue (International Journal of fatigue). In the case of rocks, thermal phenomena and their impacts on mechanical behavior have been analyzed from a micro-structural point of view, and it is now well-known that an increase in temperature causes a dilatation of crystals (Arnould et al., 2004; Berest & Weber, 1998). This dilatation may lead to the development of inter-granular traction and compression stresses, and if those stresses are greater than fracture strength, inter-granular and intra-granular cracks may take place. On the other hand, the fatigue phenomenon (cyclic repetition of a temperature variation which is less extreme than the one that may lead to this inter-granular or intra-granular fracture) is a phenomenon which has not been much studied.The principal studies on thermal fatigue on rocks come mainly from the field of geomorphology, particularly in connection with the analysis of the evolutions of past climate that can explain the present shapes of those landforms: those studies remained essentially qualitative and not quantitative. Le Ber & Oter Duthoit (1987) proposed a thermal and thermodynamic approach to analyse the disaggregation of rock masses. This analysis is dedicated to the study of paleoclimates and was implemented to better understand the formation of slope deposits in order to propose transfer models permitting the reconstruction of the climactic conditions contemporary to their appearance. Since deterioration in the cliff only appears after several cycles, it means that it is a gradual and irreversible deterioration which leads to an increase of the « disorder ». Seen from a macroscopic system point of view, this irreversible evolution is quantified by the internal creation of entropy."

Jan 1, 2015

By Y. Feng

Perovskite structured oxide 15% Y-doped BaCeO3 (BCY15) has been evaluated for use as proton conducting electrolyte in SOFC with propane as the fuel and Pt as both electrodes. Under the fuel cell conditions, BCY15 exhibited high proton conductivity and good cell performances. Propylene was detected as product at the anode outlet, and the product distribution suggests that propane dehydrogenation underwent competition with cracking to lighter hydrocarbons. Stability during cell performance tests showed that there was no obvious degradation for BCY15 electrolyte during operation of C3H8-O2 fuel cell.

Jan 1, 2005