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Stellite-6 coatings were formulated on two Ni-base superalloys, namely Superni 75 and Superni 600, by a shrouded plasma-spray process, and the oxidation behaviour of these coatings has been investigated in air and in an aggressive environment of Na2SO4- 60%V2O5. Accelerated oxidation tests were conducted in a silicon-carbide tube furnace under cyclic conditions at an elevated temperature of 900°C for 50 cycles. Each cycle consisted of 1 h heating and 20 min cooling in air. A thermogravimetric technique was used to approximate the oxidation kinetics. The corrosion scales were characterised by XRD, SEM/EDAX and EPMA analysis. It has been observed that the coatings nearly followed the parabolic rate law of oxidation. Overall weight gain conceived in air was just 51% of that in the aggressive environment in the case of coated Superni 75, whereas in case of coated Superni 600, the cumulative weight gain in air was found to be one-third of that in the Na2SO4-60% V2O5 atmosphere. Furthermore, the coating showed very good adherence to both of the substrates during the course of air oxidation, whereas some superficial cracks were observed near the edges of the specimens during the molten salt induced oxidation. XRD analysis revealed the presence of phase-like CoO, CoCr2O4 and Cr2O3 in the oxide scales, which are reported be protective against high-temperature oxidation. The XRD results were further supported by SEM/EDAX and EPMA.

Jan 1, 2005

By A. O. Orumwense

Mill circumferential speed, the number of passes of pulp through the grinding chamber, media type, size and filling ratio were investigated in an attempt to determine how to effectively grind copper concentrates in a stirred mill. The stirred mill product fineness was enhanced to some extent by decreasing media size, high media filling, and an increased number of passes of the pulp through the grinding chamber. Shape also plays a major role in grinding media effectiveness, with spherically shaped media producing a finer size. The fineness of the product increases with increasing power consumption but the method of energy transfer is very important in energy utilization. The effect of the mill parameters on copper flotation was evaluated. Copper recovery was influenced by grinding media size, mill speed and the number of pulp passes through the grinding chamber.

Jan 1, 2006

By S. F. Guo, B. W. Zheng, X. L. Huang, S. W. Qi

"The study of mechanical characteristics of rock discontinuities under different shear deformation velocities is an important premise of rock slope dynamic response analysis. According to disposing and calculating the experimental results of previous research about peak shear strength of rock discontinuities under different shear deformation velocity of constant normal loading, the law of influence of shear velocity on the total friction angle is studied. Based on the research results, it can be found that the total friction angle of rock joint specimens varies in the form of negative logarithm with the variation of shear deformation velocity. It’s also indicated that the total friction angle of rock joints decreases with the increase of shear deformation velocity for rock joints of relative strong homogeneity and isotropy. However, the total friction angle of rock joints increases with the increase of shear deformation velocity for rock joints of relative strong heterogeneity and anisotropy and the latter amplitude of increase is less than the former amplitude of decrease. The physical property and microscopic geometry of rock joints play an important effect on the increase or decrease tendency and amplitude variation of total friction angle with the increase of shear deformation velocity.INTRODUCTIONThe rock slope dynamic response is largely restricted by rock discontinuities. Hence the study of dynamic characteristics of rock discontinuities, especially the dynamic shear characteristics is an important premise of rock slope dynamic response analysis (Qi et al., 2007). Seismic load is both dynamic load and cyclic load (Liu et al., 2011). Under the dynamic and cyclic shearing actions of seismic load, the rock slope which is stable under the condition of static load may slide along the rock discontinuities whose shear strength reduce and then the earthquake landslides occur. The strength degradation and deformation mechanism of rock discontinuities under the dynamic and cyclic shearing actions is one of the key problems to be solved in the work of earthquake prevention and control of engineering slope. Based on the above understanding, predecessors conduct some researches which focus on the shear behavior mechanical characteristics of rock joints under cyclic shearing actions (Plesha, 1987; Hutson & Dowding, 1990; Jing et al., 1992, 1993; Huang et al., 1993; Qiu et al., 1993; Homand et al., 2001; Lee et al., 2001; Jafari et al., 2003; Liu et al., 2011, 2013). However, there are a few researches about the mechanical characteristics of rock joints under different shear deformation velocities because of the restriction of shear apparatus. Crawford and Curran (1981) conducted a series of one-way cyclic direct shear tests on four kinds of natural rock joints under different shear deformation velocities varying from 0 to 200 mm/s. The tests showed that at low normal stresses the peak shear strength of soft rock joints exhibited an increase up to a certain velocity, after which it remained essentially constant. For rock joints of intermediate hardness, the peak shear strength was essentially independent of shear deformation velocity; whereas for hard rock joints, the peak shear strength of which showed a significant variation with the shear deformation velocity. Jafari et al. (2003) carried out a series of conventional triaxial tests on artificial rock joints of regular saw-tooth shape with axial loading rate from 0.05 mm/s to 0.4 mm/s."

Jan 1, 2015

By T. Lamb

There are many honor stories about aluminum in the marine environment and many are not based on facts, so they are myths. Myths must be addressed before progress can be made. This paper attempts to dispel the myths and state the facts. A common perception is that aluminum ships cost significantly more than steel ships. This paper illustrates that even though the cost of the aluminum structure is over 50% more than the steel structure, an "equivalent" aluminum naval ship can be built within 7% of the acquisition price of a steel ship. This is possible because of the cascading benefits of the aluminum ship's significantly lighter weight. Aluminum ships also have a life-cycle cost advantage over steel ships because of reduced maintenance and fuel cost savings.

Jan 1, 2011

By R. Stratton-Crawley, S. W. Wilson

"Inco's Matte Separation Plant is a unique mineral processing facility having no process tailings stream. Each product is a high-grade concentrate with strict assay specifications which are defined by the downstream refining route. The most recent column application in the flowsheet, copper scavenging in the production of a high quality nickel concentrate, is described in detail. Testwork in pilot-scale columns (0.038 m, 0.051 m and 0.10 m in diameter) was used to develop a model of the copper scavenging system. This data was then used to simulate the performance of plant-scale equipment. The relationships thus established were confirmed by a series of plant tests in a 1.8 m diameter column. Column results consistently exceeded conventional cell performance. The modelling was extended to assess full plant production requirements and, as a result, a 2.1 m diameter column was specified for this application. Engineering design for this column is currently underway and the column is scheduled to be commissioned later in 1991.INTRODUCTIONMatte SeparationINCO's Matte Separation Plant is a part of the Copper Cliff Smelter complex near Sudbury Ontario. The flowsheet and the development of column flotation within it have been described previously (Feeley et al., 1987, Wilson et al., 1989). The plant feed is a synthetic Bessemer Matte from the Nickel smelter. This matte is slow cooled to promote grain growth and typically assays 46-52% Ni, 23-27% Cu. These elements are present primarily in sulphide form (Ni3S2 and Cu2S respectively) with some metallic alloy also precipitating from the sulphur deficient matte. Minor amounts of iron, precious metals, and nuisance elements are also present.The matte separation process is, in concept, relatively simple. Following magnetic removal of the metallic alloy from the feed, the flowsheet is designed to float a high grade copper concentrate from the nickel sulphide matrix. A simplified flowsheet of the process is shown in figure 1."

Jan 1, 1991

By J. Kempken, R. Hagmann, C. -P. Reip, W. Hennig

The CSP technology symbolizes a highly productive process for the cost-effective production of steel grades with a range of sophisticated properties comprising both the inner quality of hot strip, its surface formation as well as the relating technological characteristics. Thanks to extensive development work undertaken during the last 15 years, the range of steel grades that can be produced was continuously expanded and the process technology optimized. The present paper describes the ongoing development work concerning the production of higher-strength, microalloyed pipe steels. The resulting hot strip, due to the associated thickness and the potential pipe diameters, is particularly suited for being processed to HFI-welded pipes. Based both on ferrite-pearlite as well as very fine-grained, ferrite-bainite hot-strip microstructures, strength levels of up to grade API X80 can be realized. It can be demonstrated that hot strip produced in a CSP plant has very good toughness values at temperatures down to -60°C and can even make application with required sour-gas resistance possible.

Jan 1, 2005

By D. A. Wheeler, Rémi Tremblay

"INTRODUCTIONDuring the last few years, through Column Flotation Company of Canada ltd, the Centre de Recherches minérales has worked on the column flotation of coal, phosphate, feldspar, talc, graphite, copper, lead-zinc and diamond ores. The operating companies and prospective deposits were located in Canada and in other countries. Since these projects were financed by the concerned mining companies, all results remain confidential unless we obtain permission to publish. Three companies have graciously allowed us to use their information which I will describe in this text. These are the Polkowice copper mine in Poland, the North Coast Industries ltd graphite deposit and a talc company which preferred to remain anonymous. I will also describe our 2 inch column which was used for all tests. Data is also given on how to scale-up the 2 inch column to industrial size.Figure 1 presents a schematic of a flotation column. Feed, at a controlled rate and pulp density, enters at about 1/4 of the height of the column from the top. A controlled rate of air is bubbled into the bottom of column through a fine-holed sparger. The column volume between the feed point and the top of the sparger is called the recovery zone. Tailings, at a controlled rate, always slightly greater than the feed rate, discharges from the bottom of the column. This difference in feed and tailings flowrates is called the bias. The floated mineral is carried through the recovery zone on air bubbles which rise into the cleaning zone which is that column volume between the feed point and the overflow at the top. As the bubbles rise in this zone they are washed of gangue material by wash water which enters over the top of the froth layer. The froth layer is maintained at a given depth during flotation but this depth will depend on the froth cleanliness, for quite a bit of cleaning by wash water is accomplished in this layer."

Jan 1, 1988

By Y. S. Sun, Northeastern University, W. B. Li, P. Gao, Z. Y. Zhang, J. W. Yu

"The boron-bearing iron concentrate was extracted from ludwigite ore by the process of magnetic-gravity separation. In order to fully utilize the refractory ore and meet the boron consumption of China, a novel process for separation of boron from iron in boron-bearing iron concentrate was proposed in this paper. In particular, laboratory scale experiments of improving boron reactivity were performed. Fine boron-bearing iron concentrate briquettes were reduced by bituminous coal completely at 1125 °C for 150 min. The effect of sodium carbonate, which was used as an additive in the roasting process, was investigated. The addition of sodium carbonate decreased the boron reactivity and facilitated the volatilization of boron. The influence of diverse cooling methods of the reduced samples on the boron reactivity was studied. The results indicated that boron reactivity could reach up to 80.76% when the reduced samples were cooled by rapid water quenching. In addition, the magnetic material containing 92.71 % Fe with a recovery of 95.11 % and boron-rich non-magnetic material containing 14.51% B2O3 with a recovery 88.85% could be obtained by low-intensity magnetic separation. The magnetic material and boron-rich non-magnetic material were good raw materials for steel-making and borax production, respectively.INTRODUCTION Ludwigite ore is abundant in Liaoning province of China, with 28.43 Mt B2O3 accounting for 57% of the boron resources of the country (Liu et al., 2006). However, it has not yet been utilized on an industrial scale due to its complex mineralogy and fine mineral dissemination (Wang, Wang, Ding, Ma & Xue, 2012). At present, boron-bearing iron concentrate and boron concentrate can be obtained from ludwigite ore using magnetic-gravity separation. The boron concentrate contains B2O3 12%~16%, which can be used as a high-quality raw material for the boron chemical industry after activated roasting, but the B2O3 content in the iron concentrate reaches up to 4%~6%. In order to further separate boron and iron from boron-bearing iron concentrate, a blast furnace and a solid pre-reduction followed by electric arc furnace melting have been proposed (Liu, Cui & Zhang, 1998; Wang et al., 2012). However, both of these two current routes face the same crucial problem that molten boron-rich slag has to be cooled slowly to obtain the alkali-dissolution activity of boron, which affects the yield of boron resource."

Jan 1, 2016

This paper describes basic parameters, such as surface forces and film elasticity, affecting the stability of foams (two-phase froths). We used the thin film pressure balance (TFPB) technique to measure the surface forces in foam films stabilized with various frothers such as pentanol, octanol, methyl isobutyl carbinol (MIBC), and polypropylene glycol (PPG). The results were compared with the foam stabilities measured experimentally and the film elasticities calculated using a new model developed by Wang and Yoon (2006). It was found that at low electrolyte (NaCI) concentrations foam stability is controlled by both film elasticity and surface forces (or disjoining pressure), the relative contributions from each changing with frother type and concentration. Further, the kinetics of film thinning was studied at a high electrolyte concentration. The results obtained in the present work showed that the major role of a frother is to decrease the hydrophobic force rather than to increase the film elasticity. This conclusion is drawn from the observation that at the typical frother (MIBC) concentrations employed in flotation, frother additions cause sharp decreases in hydrophobic force while causing relatively little changes in film elasticity.

Jan 1, 2006

By L. A. Ayres da Silva, J. P. G. Negri, A. L. M. Ayres da Silva

"Rock hardness is dependent on the type and quantity of the various mineral constituents of the rock and the bond strength that exists between the mineral grains. As the book “The Complete ISRM Suggested Methods For Rock Characterization, Testing and Monitoring:1974-2006” explains, hardness is a concept of material property. As such, the quantitative measure of hardness depends on the type of the test employed.Among the three types of tests that have been used to measure the hardness of rocks and minerals: 1) indentation tests; 2) dynamic and rebound tests; 3) scratch tests, the authors of this paper chose indentation tests, more specifically the Vickers test, and complementary verified the correlation between the results of the Schmidt sclerometer tests (rebound tests) and the Vickers microhardness tests in a set of the same 9 (nine) granite rocks.The objective of this research was to verif y the correlation of one created index, based on the Vickers test that can be able to represent the rock material hardness. We know that Vickers tests determine the microhardness of individual rock minerals. A pyramidal shaped diamond is applied to the surface with a specified force. The area of the permanent residual deformation divided by the applied force is a measure of the hardness. Using the relative participation of the mineral components of the rock, we established a hardness index denominated EVM (Equivalent Vickers Microhardness).The correlation of the EVM with others strength properties and application parameters like UCS (Uniaxial Compressive Strength) to study sawability of granite blocks have presented very good results. The association of equivalent microhardness with others strength parameters, allowed to find powerful algorithms for analyzes of the rock materials behavior under diversified circumstances, as the sawability of granite blocks, as we can see in Fig. 1.Other very interesting correlations were found as the EVM values and that were obtained by the use of the Schmidt impact hammer for the superficial hardness determination."

Jan 1, 2015

By V. Chatain

The environmental assessment of historical mining sites contaminated with various inorganic species, as also the determination of remediation targets require a better knowledge of pollutant-bearing phases. The objective of this paper was to investigate the operational fractionation of arsenic (As) in an As contaminated (ca. 3 wt%) soil collected from a gold mining site in France, where mining activities and smelting processes of gold ores took place until 2004. Single and sequential chemical extraction procedures were performed to evaluate the potential mobility of As according to the fractions to which it was associated in the contaminated soil, and also the part of As sorbed onto soil particles. These procedures used provided information on the nature of As fixation processes in the mining soil studied. Results showed that As appeared mainly sorbed (ca. 72%) with iron on the soil particles, in particular amorphous iron oxyhydroxides. These results confirmed a potential risk of arsenic mobilization under acidic and/or reducing conditions, which frequently occur in mining environment. This research evidenced the importance of the knowledge of As-bearing phases to better predict the mobility of this pollutant and in turn improve the management of As contaminated sites.

Aug 1, 2013

By D. Berkley

Off-gas systems often become the limiting factor in production increase and environmental projects. Any upgrade or new off-gas project needs to address control instability issues, instabilities that can result in safety hazards, significant loss of system capacity and/or emissions to the environment [1]. In addition, the design engineer must optimize system configuration and equipment size for the new operating conditions, to have a technically feasible and economically viable project. Dynamic simulations can be used for addressing both the control stability and the design optimization issues. This paper illustrates how the dynamic simulation of transient processes and of their control system can be used in "real life" situations for these purposes, presenting the example of an electric furnace off-gas system design.

Jan 1, 2005

By Dave M. Jakelski, Gerhard W. Heinrich, Peter F. Wells, Daniel F. Suarez, Jamie B. Beauchamp

"A need for increased copper concentrate production and for less nickel contamination in that concentrate at Falconbridge's Strathcona Concentrator during 1993 required the installation of a third flotation column and improvements in the operation of the existing circuit. Innovations in wash water distributor and launder design were fundamental in achieving objectives on a new 3 meter diameter column. Minnovex plug-type spargers were tested on a 2.1 meter diameter column in order to reduce maintenance requirements. The paper details the measures taken to enhance column flotation circuit performance and the results obtained.IntroductionFalconbridge's Strathcona Mill receives 10% of the ore feed from a rich copper zone in the Strathcona mine. This ore typically grades 7% copper and 1 % nickel and, because of its high copper content, it is processed in a separate circuit ('C' circuit) which consists of conventional grinding, rougher flotation with the concentrate being treated with lime to pH 12.3 and cyanide followed by column flotation. The columns are operated with mechanical flotation scavengers and the scavenger concentrate is returned to the column feed. Testwork conducted in 1991 showed that the original flotation column (Column 2) could only produce 5.5 mtph of concentrate with less than 0.5% nickel (Figure 1).Between 1991 and spring of 1993, production was increased at times by open circuiting the scavengers. Metallurgical improvements were obtained by improving the wash water distributor of Column 2 and by wash water sprays in conventional cells (1 ). However, the scavenger concentrate assayed 0. 7 -0.8% nickel and was not acceptable for long term operation. When Copper ore production targets were significantly increased for 1993, it became clear that an additional flotation column was required. The new flowsheet employs mechanical scavenger cells on the column tails as in Column 2 circuit (Figure 2). A -parallel configuration was chosen as pulp solids fraction has been shown to be a critical variable and the second column in series would receive a lower density feed."

Jan 1, 1994

By Y. M. Shneerson, V. M/ Shpaer, E. E. Zhmarin, A. Y. Lapin, E. M. Vigdorchik

This paper describes studies of zinc concentrate oxidizing pressure leaching using the method of mathematical modeling. The concept of a kinetic function was taken as a basis for mathematical modeling of the leaching process. The kinetic function describes dependence of the unreacted component share OJ on the relative time x (the relative time is the ratio of the test duration and the time of complete dissolution). This kinetic function is determined in accordance with the results of batch laboratory tests. The laboratory tests have been carried out on zinc concentrate produced from Kazakhstan zinc-copper ores. Zinc concentrate consisted mainly of three types of minerals: sphalerite (70%), pyrite (13%) and chalcopyrite (10%). Oxidation reactions of sphalerite, pyrite and chalcopyrite have been considered as principal ones. The kinetic characteristics of the process (kinetic function, reaction order, activation energy, duration of complete dissolution of the concentrate components) have been calculated in the course of laboratory tests. The mathematical model was used for estimation of the main technological leaching process parameters (such as process rate, degree of metals extraction, autoclave capacity, heat balance, etc.). Mathematical modeling based on the kinetic function concept allows safe designing of metallurgical equipment and scaling the technology to industrial capacity.

Jan 1, 2004

By Robert Yobou, Jacques Naho, Benjamin A. Allou, Jacques Carignan, Huan-Zhang Lu, Jayanta Guha, Koffi Pothin

"Résumé - Les seules productions de columbo-tantalite en Côte d'Ivoire sont effectuées dans les éluvions, colluvions et alluvions d'Issia, au Centre-Ouest de la Côte d'Ivoire. Même si un lien direct avec les roches granitiques est suspecté, aucune attention particulière n'a été accordée à l'étude de la minéralisation primaire en relation avec l'évolution de ces granites et des pegmatites associées. Ces granites, qui sont en intrusion dans les roches sédimentaires du Protérozoïque inférieur, comprennent: le granite orienté à deux micas (type Lobo), le granite orienté à muscovite dominante (type Bitapia) et le granite porphyroïde non orienté à muscovite dominante (type Issia). Les résultats de cette étude indiquent que les pegmatites à Nb-Ta-Be-Li sont liées au granite de type Issia. Les observations de terrain et les analyses sur roche totale montrent que: (1) les trois principaux granites de la région sont de type-S et peralumineux dans leur composition, (2) ils ont été formés pendant la période tardi- à post-Éburnéenne, (3) le granite de type Issia fut le dernier à se former.Les pegmatites liées au granite de type Issia ont été classées en quatre types : A- pegmatites stériles; B- pegmatites à Be; C- pegmatites zonées à Nb-Ta-Be; et D- pegmatites zonées à Be-Nb-Ta-Li. Les pegmatites zonées comprennent les zones suivantes: I- zone à aplite; II- zone graphique; III- zone à albite, microcline, béryl et columbo-tantalite; IV- zone à microcline massive; V- zone à quartztourmaline. Ces pegmatites présentent une zone d'altération métasomatique externe.La minéralisation de Ta, Nb, et Be est liée à la zone III des pegmatites de types C et D, la minéralisation de Li est associée aux greisens qui peuvent être observés n'importe où dans les pegmatites de type D. Les données de terrain et de laboratoire indiquent que le granite de type Issia est la roche parentale des pegmatites à éléments rares de la région. Les pegmatites minéralisées sont distribuées seulement autour du granite de type Issia et les patrons des terres rares des granites et ceux des pegmatites à éléments rares sont très similaires. Les analyses de la composition totale montrent un lien génétique entre le granite de type Issia et les pegmatites à éléments rares. Il est suggéré que les pegmatites ont été formées durant le transport et la cristallisation fractionnée du magma. Les éléments rares sont restés dans le liquide résiduel jusqu'à ce que les conditions favorables à leur précipitation soient atteintes.L'établissement de ce lien génétique ouvre des voies pour des nouvelles stratégies d'exploration."

Jan 1, 2005

By M. Hames, K. Larmour-Ship, B. Grinbaum, E. Buchalter, R. Hackl, B. Wassink

Sodium cyanide continues to be the lixiviant of choice for gold dissolution. Many gold ore-bodies contain a significant amount of cyanide-soluble copper which increases the cost of processing due to high cyanide consumption and high cyanide destruction and disposal costs. Several cyanide destruction processes are in use today, however, there are just a few cyanide recovery plants operating. A solvent extraction process to recover cyanide has been developed which utilizes the organophosphorous extractants Cyanex 923, di-butyl-butyl-phosphonate (DBBP) or tri-n-butyl phosphate (TBP) in Bateman Pulsed Columns. Copper cyanide species are first converted to hydrogen cyanide (HCN) by acidification, with or without sulfide addition. HCN is extracted by the organic and stripped using a suitable base (eg. NaOH) resulting in a high strength cyanide solution (eg. NaCN) for recycle to the gold recovery process. Continuous pilot plant testwork on HCN extraction using a 40 mm diameter Bateman Pulsed Column demonstrated a cyanide recovery of greater than 99% with final levels of cyanide in solution of less than 10 ppm. These results illustrate the potential of this technology to recycle cyanide and to detoxify final effluent streams.

Jan 1, 2005

By Jan E. Nesset, L. Paul Staples

"High Gradient Magnetic Separation (HGMS) technology, although developed over 2 decades ago, has not been widely applied to the separation of sulphide minerals. Under conditions of strong magnetic field gradients, weakly magnetic minerals such as chalcopyrite (CuFeS2) and marmatite (Zn(Fe)S, sphalerite with iron in solid solution) behave paramagnetically and can be effectively separated from diamagnetic minerals such as galena (PbS). The application of this technology to the separation of Cu-Pb and Zn-Pb bearing streams in the treatment of fine grained complex sulphides may in some cases be more effective than separation by flotation. A 2 TPH Sala HGMS pilot plant was operated at Brunswick for a nine month period, ending in March 1995. The testing demonstrated the mechanical reliability of the technology, the consistency of operating results and the scale up from laboratory testing. HGMS is seen as a complimentary technology to flotation, best suited to performing those separations of galena (and other diamagnetics) which flotation does not do as well.IntroductionBackgroundSince the turn of the century, the magnetic character or magnetic susceptibilities of minerals have been determined with increasing precision and accuracy. Figure 1 illustrates specific magnetic susceptibilities of some common minerals. As long as susceptibility ranges do not overlap, separation is possible.In 1937, the principle of using a magnetizable matrix material in a magnetic field to increase both magnetic flux density gradients and number of capture sites for susceptible minerals was first applied (Frantz). It was not until the 1970's, however, that the genuine development of wet high gradient magnetic separation began with the introduction of very fine matrix materials to the magnetized volume of large solenoid magnets. Today, dozens of HGMS units purify, filter and separate minerals, primarily for the removal of iron stained minerals from clays used in the paper coating and china clay industries and for the recovery of fine titanium and iron oxides in the iron ore industry. Only the Garpenburg mill in Sweden is currently applying a continuous HGMS machine to separate complex sulphide minerals; upgrading a lead concentrate since 1988."

Jan 1, 1996

By A. D. Dalvi

Economics, Resources, Environment and Technology are the major driving forces in the base metals industry. However, these factors are intertwined and together will propel the industry in the future. The demand for metals has grown with economic expansion, between 2 to 4 % p.a. The current growth cycle has been driven by economic expansion in China where the demand for base metals has risen from - 7 % of the world demand in the 90's to - 25 % of world demand today, and rising. Base metals are commodities and their demand and price are cyclical. Historically metal prices have declined in constant dollars, forcing the industry to reduce costs, increase productivity and increase the scale of operation for economies of scale. Due to resource depletion and capacity expansion the industry is driven to expand its reserve and resource base. However, in the case of sulphide deposits of copper and nickel it appears to be a losing battle. For nickel the laterites represent a vast source at this time. Their development requires development of new technologies to make these resources economic. Emission reduction is being increasingly mandated in most jurisdictions with all governments enacting progressively more stringent regulations. The industry has been responding with technological innovation. With the Kyoto protocol there is a push to reduce energy intensity in metal production. Technological innovation is driven by all the other factors and is leading to novel ways of doing exploration, mining and processing, that would maximize resource delineation and utilization, reduce costs, increase productivity, reduce energy consumption, maximize asset utilization and reduce environmental affects. Development of alternative technologies such as Pressure Acid Leach of laterite for nickel, bio-leaching, heap leaching, SX-EW etc are being adopted to achieve the aims of the industry.

Jan 1, 2005

By W. W. Rudolph, L. N. Trevani, P. R. Tremaine

UV-visible spectroscopy, Raman spectroscopy, and vibrating tube densimetry have been used in our laboratory to determine equilibrium constants of aqueous species at temperatures as high as 325 °C. The UV-visible and Raman spectra of solutions containing metal complexes and ionized acids or bases can be used to yield formation constants by applying curve fitting methods to resolve the contribution of each species. Colorimetric pH indicators identified by Johnston and coworkers at the University of Texas (Austin) provide an alternative means of determining ionization constants and the pH of complex mixtures. High precision density measurements over the same range yield standard partial molar volumes, which are key parameters for "equations of state" for aqueous species. Examples are given for the copper-ammonia system, simple carboxylic acids, and the iron-sulphate system.

Jan 1, 2004

By K. Buxmann

Climate change is a subject of growing concern. Based on the International Energy Agency, about 19% of man made greenhouse gas emissions globally are generated by the transport sector. This paper will focus on the environmental aspects of the light-weighting in transport and the resulting savings of fuel and electricity. Aluminium is an option for lightweight applications in transport, with very high benefits not only in the use stage, but also in the stage of vehicle recycling. Life cycle assessment is used to quantify the relative benefits of light-weighting specific components of cars, commercial road vehicles, buses, ships and trains. A vehicle consists of many components, which are produced by different processes and undergo different types of end-of-life operations. This document does not intend to compare a generic aluminium vehicle with a generic "heavy materials" vehicle. It rather tries to use a pragmatic approach based on specific examples of components where aluminium is used and can be used in the design of new vehicles, also taking into account future developments. The case studies in this paper are based on real cases where aluminium was used. For each component, sensitivity analyses are applied to see the impact of specific parameters such as the end-of-life recycling rate and the use stage driving distance. Significant greenhouse gas savings by the use of aluminium are demonstrated for cars and even higher ones for trucks, buses, trains and ships. In addition, the total potential benefits of light-weighting with aluminium are shown on the global level.

Jan 1, 2007