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The seam gas content at Westcliff Colliery is 12-15m3/tonne of coal.Composition ranges from 99% CH4 to 52% C02 in one area. Desorption rates are proportional to gas contents and CH4 is preferentially desorbed. A crushed zone of reduced permeability advances with the face - at Westcliff ribside crushed zones are 2.5 to 6.5m wide. Poor strata control widens crushed zones. 12 months of pre-drainage allowed 2 heading development and longer pillars to be used in a virgin area instead of 3 or more headings without drainage. Machined coal may lose as much as 1.6m3/tonne being conveyed out of Westcliff Colliery. Experience differs from mine to mine. Permeation is affected by time, strata movements, changing water content, and changing stress. Permeabilities vary from lOmd for Pittsburgh Seam to less than 1 and for the Bulli Seam. All these data and differences await further investigation.

Jan 1, 1982

By J A. Rumball

Measuring cyanide in the leach liquors associated with high copper and/or sulfide ores is a non-trivial exercise. It is well known that copper complexes with cyanide and reduces the amount of cyanide available for gold leaching. What is not so well known is that the rhodanine end point overestimates the amount of cyanide available for leaching in the presence of copper. Sulfide ions also interfere with a rhodanine end point titration, although this is less of a problem as the black silver sulfide precipitate formed clearly indicates to the operator that something is wrong. Thiosulfate, which forms readily from the alkaline oxidation of sulfides, causes an overestimation of the cyanide available for leaching due to the formation of Ag(S2O3)-. The net result of these observations is that rhodanine is rarely of value as an end point indicator in complex solutions. It generally overestimates the amount of cyanide available, providing plant metallurgists with a false sense of security. Potentiometric titrations are generally much more capable of accurately measuring cyanide in complex solutions. The interfering effect of copper can be resolved and it is even possible to estimate the copper concentration using the inflexions associated with the titration of CN- + Cu(CN)43- versus Cu(CN)32-. Using the potentiometric method sulfide ions can be determined before the cyanide measurement is made due to the formation of AgS2, although the electrode will foul with repeated measurements. Thiosulfate can also be distinguished from cyanide with a potentiometric titration. Rhodanine and potentiometric titrations are both affected by the pH of the liquor. At pH 9.2 half the cyanide will be present as CN- and half as HCN(aq) with only the CN- being titratable. This does not hold in the presence of a buffer active around pH 9. In the presence of sufficient buffer, both the CN- and HCN(aq) are titrated. Ca(OH)+ may buffer the pH when large amounts of lime have been added.

Jan 1, 2007

Builders have been very familiar with iron since ancient times, but because of its weathering characteristics it was relegated to use as a fastening material in unexposed places and bronze became the popular metal for exposed applications. It is of interest that iron nails buried deeply about A.D. 87 at a Roman fortress and carefully covered with clean beaten earth under conditions practically excluding oxygen were found to be almost unrusted 1870 years later. (1) Today, weathering steels, which contain less than 2% of alloying additions, can be used in exposed situations without protection and without experiencing continuous wastage. As we all know the steady access of atmospheric oxygen to the surface of plain steel causes continuous corrosion. Weathering steels, on the other hand, due to their alloying additions develop their own impervious surface layer which limits the access of atmospheric oxygen and effectively limits corrosion. Table 1 shows the chemical composition of a plain carbon steel and a typical weathering steel. Fig. 1 shows what we refer to as direct corrosion - time curves in which corrosion loss is plotted against time of exposure in an strial environment. The weathering steel has a high rate initially which then decreases steadily for about three years, as the stable rust film builds up. This is followed by a practically linear relation where the very low corrosion rate, according to one school (2), is due to a blocking of the rust pores by insoluble complex salts formed from interaction of the oxidation products of the separate alloying elements. The start of the linear region represents a total corrosion loss of only about 2 thousandths of an inch.

Jan 1, 1970

The creation of an accurate and precise enough database requires the collection of many representative samples, subsampling and assaying them without destroying their integrity. The selection and implementation of sampling protocols often lead to severe difficulties, making the unaware practitioner vulnerable to massive exploration, feasibility and operating failures. Therefore, there is no substitute for a good understanding of the Theory of Sampling (TOS). Either because of ignorance, or because of short-term economic reasons, failure to comply with many stringent conditions can be devastating for the validity of a feasibility study, leading to false evaluations, to the abandonment of a viable property, or to the exploitation of one that is not profitable. All these failures have something in common: insufficient duplicate sampling, subsampling and assaying were performed; very important, preliminary heterogeneity tests were never performed; for short-term economic reasons, poor sampling and subsampling protocols were selected, second-class sampling systems and weightometers were installed and poor preventive maintenance and cleaning were implemented;and sampling experts were called only when the project was obviously in trouble. The conclusion is clear: in due time, iterative auditing of sampling practices is an insurance policy against massive financial losses for the company involved. A complete, comprehensive 100 point checklist of sampling Quality Assurance and Quality Control is provided, so critically important details to ensure success are not forgotten.

Mar 1, 2010

By Z Chang, S A. Mrozek, S Windle

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. It is important to understand skarn-porphyry transitions in order to use exposed skarns to look for associated and potentially larger porphyries. For such purposes, a good start is to understand the transition between porphyry and skarn in known deposits. In this contribution, we report the transition at Antamina, Peru, where skarns occur in and around a Miocene complex comprised of more than seven porphyritic intrusions. There are three types of skarn-porphyry relationships. The earliest intrusive phase, P1A, contains both endoskarn and porphyry-style quartz veins with secondary biotite halos. The porphyry quartz veins and endoskarns formed at the same time. Locally, the intrusion contains only endoskarn without porphyry quartz veins and is surrounded by exoskarns in carbonate wall rocks. In the third scenario, later porphyry (P2) intruding into P1A porphyry and skarns related to P1A contains abundant granular quartz veins and secondary biotite alteration but does not have significant endoskarn. The granular quartz veins also extend into earlier P1A skarns. The scarcity of endoskarn associated with P2 is related to the supply of Ca. The earliest P1A intrusion intruded into carbonates that supplied abundant Ca, therefore both endoskarns and exoskarns formed. In contrast, where the wall rocks of the later P2 intrusion are P1A or skarn related to P1A, there was little free Ca, therefore only porphyry-style quartz veins formed.CITATION:Chang, Z, Mrozek, S A, Meinert, L D and Windle, S, 2015. Skarn-porphyry transition – an example from the Antamina skarn, Peru, in Proceedings PACRIM 2015 Congress, pp 409–414 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By T Goldsmith

The mining industry is cyclical, but those are more than normal business cycles. In the early 2000s the industry saw the start of China as a game changer for the mining industry which lead to catch phrases like ‘stronger for longer’ and even ‘stronger forever’. Enter the global financial crises and the more recent slow-down in the Chinese economy and confidence that the future is bright has dimmed! This paper looks at the long-term forces that are likely to impact the global mining sector and explain why the industry has an excellent future. However, the industry is not without its many challenges and while demand may be in a prolonged step change, the ability to generate profits will depend on the fitness of each asset and company.The author also discusses the hated terms of ‘boom’ and ‘bust’ and considers how the industry can reduce them, but normally exacerbates them. The ability of the junior sector to raise funds being a primary example and one that remains closed to all but the very best exploration assets. There is also consideration of Australia’s position as a mining country in the future world.CITATION:Goldsmith, T, 2014. The future of the global mining sector, in Proceedings Ninth International Mining Geology Conference 2014 , pp 15–20 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

Lateritic nickel ore occurs as a supergene or residual deposit as a result of the tropical weathering of underlying ultramafic rocks. The mineralisation may be as hydrated Ni-Mg silicates, like garnierite (silicate ore); or as hydrated Ni-Fe oxide (oxide) ore. Non-sulphide ore represents only 30% of the tonnage mined, but represents 85% of the total world's nickel reserves. A typical lateritic profile consists of 4 zones above the unweathered ultramafic parent rock: Zone 1: the "upper laterite" which is dark red-brown, porous and concentrically structured. It contains 0.2 to 0.8% Ni, 48.0 to 72.0% Fe, and 0 to 9.5% MgO. It is often capped by a ferricrete crust. Zone 2: the "middle laterite", which is red-brown to light brown and more porous than the above zone. It contains 0.8 to 1.5% Ni, 42.0 to 48.0% Fe and 0.5 to 6.0% MgO. Zone 3: the "basal laterite" which is yellow-brown to yellow-orange,

Jan 1, 1974

By Tullemans FJ

This paper describes the general approach to ore reserve estimation and mine planning used at the Kidston Gold Mine. The geological setting and exploration is briefly summarized for background information.A geostatistical study of the deposit was carried out to determine the geological ore reserve. This was confirmed using a manual polygonal technique. Optimum pits outlined by a Lerchs-Grossman open pit design algorithm were manually smoothed allowing mineable reserves to be calculated. Mine production schedules based on kriged block grades and tonnages are continuously updated using production blasthole assays. An arithmetic mean technique of block grade estimation has proved successful to date. After milling approximately 4.9Mt of ore, the mill grade of 2.13g Au/t is only 0.5% above the mine estimate of 2.12g Au/t. The difference in contained gold between "As staked" blasthole reserves and kriged mineable reserves is 3.8%. The application of blasthole kriging as a basis for ore/waste classification in erratically mineralized areas is being evaluated. Planned future developments are briefly mentioned.

Jan 1, 1986

By I M. Platten, Y Xie, B W. Cuffley, S C. Dominy

"Geometallurgical programs require the collection of representative samples for geochemical, mineralogical and metallurgical test work. Such protocols must be designed to suit the style of orebody in question. The distribution, proportion and size of gold particles have a direct impact on the effectiveness of sampling and test work protocols, and the gold recovery processes employed. Characterisation studies focusing on ore mineralogy, and gold particle deportment, size and distribution are required. High resolution X-ray computed tomography provides a non-destructive method for analysing the 3D nature of gold in rock samples. It can be used to calculate the modal abundance, particle size and distribution of gold in the sample volume. This paper presents a case study of the imaging of in situ gold particles in a high-grade gold ore. The Nick O’Time reef system comprises laminated quartz veins, which locally bear extreme grades of up to 100 oz/t gold. The mineralisation has previously been characterised from both a mineralogical and metallurgical perspective. Eight visible gold-bearing vein samples were scanned using X-ray microtomography. Microtomographic data were integrated with previous mineralogical and metallurgical test work outputs.CITATION:Dominy, S C, Platten, I M, Xie, Y, Cuffley, B W and O’Connor, L, 2016. Characterisation of Gold Ore from the Nick O’Time Shoot (Tarnagulla, Australia) Using High Resolution X-ray Computed Tomography, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 241–254 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By L. R. MURPHY

This paper gives a general description of mining operations at the Rosebery Mine and a brief account of the older Hercules Mine. The more unusual aspects of the operations, such as the sinking of the inclined shaft, blast-hole experiments, diamond drilling practice, and proposed future developments are described in detail.The following main heads are used:Roseberry- General production Data.General Description of Ore-body, and Characteristics of Ore and Country Rock.Layout of MineMining Methods, Filling, etc.Blast Hole Stoping.Sinking Main Inclined Shaft.Mining Timber. Contract System.Diamond Drilling and Sampling.Surveying.Labour Force.New Developments, Sand Filling and Pumping.Hercules-Situation of Mine.Transport-Haulage and Aerial.Ore Bodies.Stoping Methods.Ore Handling.

Jan 1, 1949

By P Louden, C Rothnie, G Showers

Tiwest employs several methods to assess the quality of heavy mineral concentrates in ore and process samples. Mineralogy is determined using a method called MA98, developed in conjunction with JKMRC over the last three years (Zhang and Whiten, 2001). A range of other techniques are also used to characterise ore, heavy mineral concentrates and mineral products. MA98 is the culmination of efforts since 1989 to determine mineralogy from chemical analysis without recourse to heavy liquid fractionation, which has traditionally been used to discriminate between light-heavy , zircon, rutile and leucoxene. The major advance with MA98 is the use of statistical mass balancing for all chemical species, as opposed to reliance on key chemical species for each mineral. Three magnetic fractions are analysed by X-ray fluorescence spectrometry, with a minerals balance performed for each. Heavy mineral concentrates processed by this method include drill samples, process samples from the wet concentrators and Dry Mill, and mineral products. TBE can be avoided for higher heavy mineral grade samples since quartz is determined from SiO2 balance. In this sense the method is sufficiently universal and robust to cope with a wide range of sample types and compositions. The MA98 algorithm provides abundant information in addition to mineralogy, including TiO2 and Fe2O3 grades of ilmenite and leucoxene, and concentrations of weakly magnetic zircon and kyanite. Information such as this is invaluable in tracking different minerals through the processing plants. Other ore assessment procedures used by Tiwest provide for modelling of orebodies by mineral sizings, Fe in zircon, and FeO and U+Th in ilmenite. Microscopy is used to provide important qualitative information such as grain shape, surface staining and degree of cementing. These quality measurements are included with mineralogy in geological ore models and are available for mine scheduling. In using the above methods to characterise heavy mineral concentrates, Tiwest is better placed to predict and monitor plant performance and product quality from any ore zone.

Jan 1, 2001

By D J Rawlings

The Palaeo- to Mesoproterozoic McArthur Basin contains a thick (-10 km) intracratonic platform cover sequence of unmetamorphosed and relatively undeformed sedimentary and volcanic rocks (Pietsch et al, 1991). It covers an area exceeding 180 000 km2 of the North Australian Craton (Figure 1), overlying segments of the older deformed basement and transitional igneous units. Volcanism in the basin (including transitional domain) followed a four-phase pattern. These phases are geologically distinct and widely distributed, and are also recognised beyond the McArthur Basin in many similar-aged tectonic provinces in northern Australia. The four phases are described briefly below. Regional and structural nomenclature used refers to Figure 1. A stratigraphic correlation diagram is presented in Figure 2.

Jan 1, 1994

By S Hapugoda, J Manuel, N Ware, A Dehghan-Manshadi

The effect of titania (TiO2 ) addition on the sintering performance of hematite iron ore has been studied by doping pure TiO2 into a sinter blend. The results of laboratory-scale compact sintering tests confirmed the considerable effect of TiO2 addition on sinter strength and mineralogy. The tumble index measurements confirmed an improvement in the strength of the sinter in response to TiO2 addition. The melting point of the sinter was also affected by increasing the TiO2 content, indicating a possible relationship between coke breeze consumption and TiO2 on industrial-scale sintering of Ti-bearing ores. Analysis of the sintered structures using optical and scanning electron microscopes confirmed a general improvement in the overall pore structure and sinter melt characteristics with the addition of TiO2 to the sinter blend. An important feature of the sinter structure was the formation of a perovskite phase (CaTiO3 ) and an increase in the proportion of this phase in the structure as TiO2 levels increase.CITATION:Dehghan-Manshadi, A, Manuel, J, Hapugoda, S, Ware, N and Donskoi, E, 2015. Effect of titania on the sintering performance of hematite iron ores, in Proceedings Iron Ore 2015, pp 29–34 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Walker G. S, Sparrow G. J

Dissolution of S02 into water-acetone mixtures results in the formation of 2-hydroxy-2-propane sulphonic acid. The pH, or acid strength, of water-carbonyl-S02 mix- tures can be controlled by varying the concen- tration of the carbonyl compound or the rate at which S02 is added to the water-carbonyl mixture during a reaction. The ease with which the acid strength of these mixtures can be controlled means that they have significant potential for use as a selective lixiviant. We have used water-acetone-S02 mixtures to selectively dissolve phosphate minerals in Christmas Island and Duchess phosphate ores and also uranium minerals in Yeelirrie uranium ore and Olympic Dam copper concentrate.

Jan 1, 1987

By Heape JM

Production from the Cattle Grid orebody commenced in August, 1974. This followed a recent discovery arising from an extensive exploration programme involving stratigraphic drilling, geochemistry and geophysics. Located some 4 km west of the original copper occurrences at Pernatty Lagoon the discovery was found to contain 4.6 million tonnes of ore averaging 2.4% copper. The ore is a "sandstone copper" type localised near the disconformity between two Precambrian (Adelaidean) stratigraphic units, the Pandurra Formation and the Whyalla Sandstone. The mineralisation roughly follows the interface between these units and occurs in fractures, vugs and along bedding planes. The mineralogical character of the ore is somewhat complex consisting of chalcocite and bornite, with associated chalcopyrite, sphalerite, pyrite and other less common sulphides. 1. Senior Geologist, Pacminex Pty. Limited, Sydney, N.S.W. 2. Mine Geologist, for Mt. Gunson Mines, Pacminex Pty. Limited, Mt. Gunson, S.A.

Jan 1, 1975

By Rogis J

The basic parameters causing outbursts are rock pressure, gas characteristics and the physico-mechanical properties of the coal. The three sets of factors are to some degree interdependent. At Collinsville, the gas characteristics coupled with the physico-mechanical properties of the coal appear to be the major factors contributing to outbursts. The relative importance of rock pressure is uncertain. The following geological parameters appear to be necessary before outbursts can occur. 1. A coal rank greater than 1.2% vitrinite reflectance. 2. Thrust faults with throws greater than 3.Om or strike- slip faults with coal gouge wider than 0.3m. 3. Seam gas emission values greater than 1.1 cm3 /g. Igneous intrusions are the likely source of the carbon dioxide seam gas. Outbursts have occurred at depths ranging from 215m to 265m. They occur at these relatively shallow depths due to: 1. the high rank of coal at the present topographic surface and the high coalification gradient; 2. the relatively high degree of tectonic deformation of the strata; 3. the seam gas characteristics; and 4. the extent of igneous intrusions.

Jan 1, 1980

By D von Horn

Mineral sand orebodies are typically mined for their TiO2 content. Increasingly over the past 30 years, the major mineral focus has shifted from natural rutile to ilmenite and an acceptance that the latter generally needs some form of upgrading for economic conversion into TiO2 pigment. This upgrading obviously has a cost, and in conjunction with diminishing mineable feed grades, results in higher cost TiO2 units for chloride route Pigment Plant feedstocks. The net cost of feedstock can be significantly influenced by the recovery and sale of accessory minerals and by-products from the processing chain to the extent that some producers have the potential to achieve a zero net cost. Whilst slagging plants typically reduce net cost from rutile, zircon and pig iron revenues, operations supporting Becher type synthetic rutile operations have been limited to revenues from rutile and zircon only. A range of alumino silicate minerals show industrial potential, as does activated carbon, iron oxide and gypsum, by-products of the synthetic rutile process. Tiwest is a good example of a company maximising revenue from the accessory minerals as well as from by-products of the synthetic rutile process.

Jan 1, 2001

By E S. B Santiago, C P. N Moreto, L V. S Monteiro, G H. C Melo, R P. Xavier

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Iron oxide-copper-gold (IOCG) systems of the Carajás mineral province (Amazon craton, Brazil) are structurally controlled by regional-scale shear zones and have formed by multiple episodes of fluid circulation and hydrothermal alteration in the Neoarchean (2.71–2.68 Ga and 2.56 Ga) and Palaeoproterozoic (1.90–1.87 Ga).Collectively, fluid inclusion, boron, oxygen and hydrogen isotope data and Cl/Br–Na/Cl ratios in fluid inclusions reveal that regional circulation of non-magmatic brines (eg evaporative fluids/evolved sea water) and mixing with other fluid sources (eg meteoric or magmatic) is an important attribute in the genesis of the Carajás IOCG systems. The ?33S and d34S compositions of sulfides from the Neoarchean and Palaeoproterozoic IOCG systems suggest that the ore-bearing fluids have assimilated sulfur from crustal reservoirs. Nevertheless, most ?33S measurements have indicated mass independent fractionation (MIF) effect for both systems which points to the possible involvement of surface sulfur sources.CITATION:Xavier, R P, Monteiro, L V S, Moreto, C P N, Melo, G H C and Santiago, E S B, 2015. Non-magmatic versus magmatic fluids in the genesis of Archean and Palaeoproterozoic iron oxide-copper-gold systems of the Carajás Mineral Province (Brazil), in Proceedings PACRIM 2015 Congress, pp 281–288 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Biswas AK, Hayes P

During the reduction of iron oxide pellets in the blast furnace it has been found that catastrophic swelling (up to 300% volume increase) can occur. Although the burden preparation conditions can be designed to avoid this phenomenon the exact reason and mechanism of the swelling has yet to be clearly identified. Swelling of the burden is undesirable since it reduces the interparticulate voidage in the blast furnace thus reducing gas flow through the stack resulting in low production rates of iron. The present study differs significantly from previous experiments in that reduction is carried out on single crystals of wustite thus the problems of control of gas composition and specimen preparation are minimised. The microstructures formed on reduction have been examined by optical and scanning microscopy. Pure wustite and wustite doped with various levels of CaO have been examined after reduction in controlled CO-CO 2 gas mixtures at 968¦C. The catastrophic swelling on reduction coincides with the formation of an unusually open iron structure in which the iron appears as whiskers or needles as previously reported. The spacing and thickness of the needles are shown to vary with impurity content and gas composition. Metallographic examination has shown in addition, however, that the whiskers do not necessarily constitute the only product form of the iron produced and in CaO containing wustites with less than - 2% CaO there is a transition from needle growth to porous growth of iron. Thus the % swelling of the oxide particles is dependent on the initial size of the oxide grains. Samples of FeO - 10% CaO exhibited a previously unreported product inorphology associated with the nucleation of 2CaO.Fe203.

Jan 1, 1980

THE slag from the blast furnaces having been granulated, a representative sample is taken to the sample mill. It is then dried, crushed through a 100-mesh screen, intimately mixed, and packeted for assay purposes.METHOD OF ANALYSISINSOLUBLEWeigh 1 grm. of the finely-pulverized slag into a 3t-in. casserole, moisten with a little water to prevent sticking, cover with a clock glass, and add 20 cc. of hot acid (1 HNOs, 3 HCI, 4 H2 0). Evaporate slowly to dryness on a hot plate and bake (without overheating) until all the gelatinous silica is dehydrated. Cool, add 20 cc. HCI (1-1), and boil gently for several minutes; filter into a 300-cc. beaker, cleaning out the casserole thoroughly with a rubber-tipped glass rod. Wash residue with hot distilled water and transfer it to a No. 1 porcelain crucible. Dry, ignite, cool in a desiccator and weigh as total insoluble matter. Dilute filtrate to 200 cc. and neutralize some of the excess HCI with NHa.OH. Warm, and pass H2S for 15 min. Filter and wash withhot water. Boil off H2 S, oxidize with 5 cc. HNOll , reduce bulk of the solution by evaporation. to about 100 cc., and transfer to a 250 cc. flask.SILICAFuse insoluble residue over a blast lamp in a platinum crucible with three or four times its weight of anhydrous carbonate of soda, for 10 to 15 minutes, or until decomposition is complete. Cool, and extract fusion in an 8-in. evaporating dish with HCI (1-1); rinse crucible and cover with distilled water, and evaporate to dryness over a water bath. Take up dry mass with 10 cc. strong HCI, and then.

Jan 1, 1922