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Supercritical fluids are gases compressed to near liquid densities and, as such, have unique properties compared to liquids: low viscosity; zero latent heat; high diffusivity and pressure-dependent, solvation characteristics. These properties are being utilised in new processes and current research is delineating areas where such processes may be applicable to extractive metallurgy. The processes and areas of interest are as follows: Supercritical Fluid Extraction in which substrates are dissolved at high pressure and fractionated at successively lower pressures. Areas of interest include extraction of organic materials for regeneration of activated carbon for the CIP process and for upgrading alumina industry products and, separation of transition metal chlorides. ò Supercritical Water Oxidation in which high pressure gaseous water acts as a medium in which substrates are oxidised while suspended or dissolved. This process may be of use for oxidation of organics in Bayer liquor and oxidation of mine waters etc. ò Supercritical Fluid Reactions where reactions occur in a supercritical fluid medium, particularly when the medium itself is a reactant. This may be of use in treating refractory or carbon-aqueous auriferous ores and in lower-temperature chlorination of transition metal oxides. Research is described which is aimed at chlorination and separation of transition metal oxides by two supercritical operations.

Jan 1, 1991

Coal seam methane (CSM) is an æunconventionalÆ gas resource that is becoming an important energy resource for Australia, especially along the eastern seaboard. It has been conventionally believed that methane in high rank coals was exclusively derived from thermocatalytic processes during decomposition of coal at elevated temperatures. However, recent re-interpretations of gas composition and isotope data have indicated that microbial methane generation may be one of the main processes responsible for the accumulation of commercially producible methane in some coals. In low rank (æbrownÆ and sub-bituminous) coals, methane (CH4) is mainly generated by microbial activity at low temperatures. The amount of this biogenic gas generated and accumulated in low rank coals depends largely on the rate of burial and depth. Most low rank coals are æunder-saturatedÆ with respect to their maximum gas sorption capacity. In contrast, high rank coals may be highly saturated due to extensive gas generation from both thermogenic and secondary biogenic processes. However, in basins where secondary biogenic gases have not replenished the thermogenic gas lost during basin uplift, the coals will be æunder-saturatedÆ. In many basins around the world, high CSM producing zones appear to contain secondary biogenic CH4 generated by microbes transported in meteoric water recharge through permeable coal seams. Biogenic CH4 generation requires the activity of a consortium of anaerobic respiring microorganisms, fermentative bacteria and acetogenic bacteria to break down complex organic molecules to simpler molecules having one or two carbon atoms, which enables methanogenic archaea to generate CH4. The two main methanogenic pathways in the generation of secondary biogenic gas from coal are aceticlastic reaction and carbon dioxide (CO2) reduction. In eastern Australian coals CO2 reduction appears to be the main process. The types of microbes that are directly involved in these processes are unknown because they have not yet been isolated from the coal seams. The CSIRO is currently investigating the processes of biogenic gas generation in Australian coals. Potential may exist to introduce appropriate microbes into deep coal seams to enhance methane saturation levels, gas sorption capacities and permeabilities.

Jan 1, 2004

By Sarracino R. S

A number of ideal detonation codes are used internationally for estimating the strength of explosives compositions. Important and far reaching decisions by explosives users are ofen based on the predictions of these codes, but since different codes can deliver very different answers for the same composition, there is a strong possibility of decision makers being misled. In order to both provide a sensible basis for comparing the theoretical energy from explosives from different manufacturers and to prevent the entire rating system from slipping into disrepute, it is in the interests of all to reach agreement on fundamental criteria used by detonation codes for detemtining strength. The problem is illustrated by a case history and basic conventions are proposed, specifically the adoption of energy of reaction as a fundamental and code independent indicator of explosive energy, and agreement on disclosure by suppliers of key non-proprietary information. These measures would assist explosives customers in assessing the true strengths of explosives from the strengths calculated by the different ideal Codes.

Jan 1, 1990

A review of ground control procedures in Western Australian underground mines is presented. Geotechnical input into initial mine design and methods of ground control is rare. As a result, the frequency of unexpected rockfalls is comparatively high, with over three quarters of the mines adopting non-specialist ground control designs experiencing unexpected falls-of-ground. In contrast, mines that provide some level of specialist input into initial ground control design experience decreased rockfall frequencies.

Jan 1, 1992

By Wightman D, Hoyle M. W H, Peters W. S

The Radio Hill nickel-copper deposit is located 30 km south of Karratha. It is a new discovery in an area where similar mineralization had been previously discovered at Mt. Scholl and Ruth Well. Radio Hill is the first massive Ni-Cu sulphide deposit of economic significance to have been located in the Western Pilbara.Preliminary studies indicate that the sulphide mineralization occurs within gabbros, pyroxenites and peridotites of a basic igneous cumulate layered sequence. Primary sulphides have been subsequently remobilized and concentrated as stringer and massive mineralization. This is tentatively attributed to the intrusion of a further gabbroic body.The deposit appears to be of the gabbroic association type with a Ni:Cu ratio varying from 1:4 in the outer parts of the mineralized envelope to 1:0.9 towards the central zones. In drill core observations, chalcopyrite surrounding pyrrhotite was noted in many instances. Drilling has so far delineated a body developed over a strike length of 600 m and a horizontal width of up to 25 m. The mineralization plunges 20° to the southwest with a southerly dip varying from 75° in the west to about 20° - 30° in the east.The deposit is a leaf-shaped ore zone, plunging southwest from a vertical depth of 17 m in the north to 300 m in the south. The massive sulphides occur as lensoid masses within this zone. A geological resource of up to 2.5 million tonnes at 1.5 per cent Ni and l.4 per cent Cu is indicated.The predominant sulphides are pyrrhotite, chalcopyrite and pentlandite, with significant cobalt, platinum group metals and gold. Tellurides of Pd, Bi and Pb were detected by scanning electron microprobe within the pyrrhotite and other trace metals include Zn and native tin. Massive magnetite is sometimes associated with the massive pyrrhotite intersections.A test on one composite massive sulphide sample showed that pyrrhotite is present mainly as the non-magnetic hexagonal variety and only 10 per cent is present as magnetic monoclinic pyrrhotite.The deposit has no surface expression and its identification was based mainly Oil drilling targets generated by geophysical methods. No secondary minerals have been observed in association with the primary sulphides, even though the deposit is only 17 m below surface in the northern part.

Jan 1, 1987

By M Stewart, J Vann, A Bu, D Frederickson

The Golden Gift is a recently discovered deep deposit below the main operating areas of the Stawell Gold Mine. At an early stage of the project, diamond drilling was used to define the mineralisation on sections approximately 100 - 150 m apart. The project economics were sensitive to both grade and tonnage. There were consequently two significant risks on resource quantification: risk on tonnage (ægeological riskÆ); and risk on grade (ægrade riskÆ). The degrees of freedom inherent in the geological model were considered to be potentially high because of wide drill spacing and likely structural complexity. To quantify geological risk three geologists familiar with Stawell mineralisation independently interpreted the deposit. This generated three plausible, different geological volume models. Conditional simulation was then used to quantify grade risk. Conditional simulation requires the user to define input statistics (histogram and variogram model) and a geological envelope. Based on global mean grade of an ordered set of simulations, æpessimisticÆ, æmedianÆ and æoptimisticÆ simulation cases were defined. The result was a 3 x 3 risk matrix with geological risk (the three interpretations) on one axis and grade risk (also three cases) on the other axis. An interesting result was that geological and grade risks were of a similar order of magnitude. Therefore a risk analysis of grade by geostatistical methods within a fixed geological model is of limited value, especially if the drill spacing is wide. After completion of this study, with additional drilling, the geological degrees of freedom at Golden Gift reduced substantially. A second Golden Gift risk study used a refined geological model to build a set of simulations to be used in preliminary mine design. A third simulation study in the deeper parts of the Magdala ore deposit, a well-drilled part of the mine with production history, demonstrates that the geostatistical simulation method used at Golden Gift is a robust and useful tool to quantify grade risk.

Jan 1, 2003

By Koh P. T L, Varnas S. R

Fluid flow, heat transfer and combustion in a nickel flash smelter have been investigated by numerical modelling and flow visualisation. The three-dimensional numerical model incorporates turbulent two-phase fluid dynamics, radiative heat transfer and combustion. The main features include the use of the k-E turbulence model, the Lagrangian tracking of particles, radiative heat transfer based on the spherical harmonics method, and chemical reactions. The predicted flow fields are in good agreement with data obtained from a series of flow visualisation experiments on a cold water model. The interaction mechanism between the fluid flow and the solid particles is examined for a range of particle sizes both with and without injected oil in a series of simulations. The heat transfer in the shaft is dominated by combustion and radiation, whereas the ignition of particles is influenced by the particle size and the added oil. Flow and temperature fields for both gas and solid particles are presented as well as the fraction of sulphur removed from the particles.

Jan 1, 1992

The paper presents an overview of the mining industry of Papua New Guinea. Although the Bougainville problem is still unresolved, new mines like Ok Tedi, Misima and Porgera, which have come on stream during recent past, have raised hopes of sustained growth period in the industry. Kutubu Oilfield is also being developed in the Southern Highlands and the oil production has commenced from July 1992. Government revenue from these mega projects will increase five-fold during 1993 and 1994. A new mine which is being planned is the fabulous Lihir Deposit, on an island renowned to be full of gold. Gold occurs within a volcano which still contains high temperature ground water because the system which created the deposit is still geothermally active.In Papua New Guinea, problems of environmental management are far easier to tackle than those of a socio-political and economic nature involving compensation payments to the landowners and the distribution of royalties and taxes between the national and provincial governments. At the socio-political level, the country has not been able to resolve the problems of land rights versus mining rights. Whenever mining starts in a big way, it raises people's expectations to a very high level, which then becomes the focal point of dispute between landowners, provincial governments, national government and mining companies. A new system called 'Forum' has been tried to bring all parties together and son out the issues. The system appears to be working well in new mines like Ok Icdi, Porgera, Misima and Kutubu Oilfields.

Jan 1, 1993

By C Glassock, P Tilyard, T Sandeman

Computer simulation is a well accepted tool for modelling the behaviour of large and complex operating systems. It is a particularly useful technique in complex operations where there are multiple interactions between the inputs and outputs of various unit operations. It can be utilised during the early stages of a project as part of the business case definition phase or the early engineering phases, or alternatively to help understand the various options available in an upgrade or expansion. With the design of a new processing plant to handle a different ore type at Lihir Gold Limited (Lihir), there was concern that the existing conveying system could separately handle the increased tonnages. A simulation model was constructed which allowed Lihir to examine the impact on the conveying system of the new process plant, as well as investigate the effect of different trucking options. As is often the case, once the simulation model was built, further understanding of the downstream bottlenecks was able to be investigated, including the sizing of critical equipment.

Jan 1, 2006

By Walton M. C

A combination of flotation and smelting technologies is proposed as a cost-effective means to maximise the revenue of base metal operations. The proposed treatment route breaks the grade - recovery nexus associated with the treatment of ores exhibiting difficult mineralogy in conventional plants. Aspects of the two technologies are reviewed and typical capital and operating costs presented. A significant improvement in revenue is demonstrated in a worked example, where a copper-lead-zinc operation is examined in terms of the conventional and proposed treatment options. For the selected ore, the net smelter return per tonne of mill feed improved 57 per cent, from US$89.70 to US$141.10 with the proposed treatment option. This represents an additional US$51.4 million in annual revenue. Metallurgical operating costs increased by US$20.12 per tonne of mill feed for an incremental capital requirement of US$30.3 million for an existing operation.

Jan 1, 1992

By R Rodriguez, S Gumo

The Lihir Gold Mine, in Papua New Guinea, is a large open pit operation within an active geothermal system inside a collapsed volcanic crater. This unique setting has a big impact on the mine operation because of the occurrence of geothermal hazards. The system for managing geothermal hazards that has been developed by Lihir Gold Mine is a pioneering effort that can be applied to future mine discoveries in a similar environment. The controls are integral to the mining operations and allow mining to proceed whereas without them mining could not be considered. Truck and shovel productivities in conventional open pit operations are constrained by diggability, equipment availabilities and utilisation. At Lihir, additional constraints are in the form of 100 m exclusion zones around working shovels and 50 m exclusion zones around working drills. Given that the mine has seven large digging units and six drills, this amounts to a lot of area that excludes the presence of people on the ground. So how are the necessary work like grade control, survey, blasthole loading, and in-pit maintenance performed safely to achieve production targets? The answer is in the highly specialised procedures that have been developed that utilise geological, geothermal and geotechnical knowledge to predict problem areas and also deal with the organisation of movement in the pit for people and mining equipment. This paper will detail how scheduled material movement can be maintained despite the challenging conditions faced at Lihir Gold Mine.

Jan 1, 2007

Brunswick Mining and Smelting Corporation Limited operates a large base metal property near Bathurst, New Brunswick in eastern Canada. Nominal capacity for the underground mining operation and concentrator is 10 250 DMT/day. Four concentrates are produced by differential flotation technology to recover minerals containing copper, lead, zinc and silver. Two characteristics of the Brunswick ores have a major impact on mineral processing operations. The mineralogy of the ore is complex with a total sulphide mineral content of 85 per cent. In addition, the ore is extremely fine-grained, and satisfactory liberation is difficult to achieve. These characteristics directly influence flotation selectivity and thereby affect metallurgical performance. Significant improvements in metallurgical performance have been achieved through the application of basic grinding and flotation principles using conventional milling equipment. Current operating practice and the metallurgical advancements are detailed.

Jan 1, 1993

The LeadtZinc Concentrator at Mount lsa treats all the lead-zinc-silver ore from the Mount Isa Mine and some of the ore from the Hilton Mine. This concentrator was commissioned in June 1966 and total lead-zinc-silver ore treatment was transferred from the Mount rsa's original No 1 Concentrator in May 1967. Plant capacity is around 5 x 106 t/y.There have been three phases of major plant modifications since commissioning:1. replacement and upgrading of the flotation section in 1979; 2. upgrading of the crushing plant and installation of a heavy medium hydrocyclone plant in 1983 for ore preconcentration, and; 3. doubling ball milling capacity and a further upgrading of the flotation section in 1992.Other developments have included the installation of flotation columns and Jameson cells.The evolution of milling practice since 1955 has been reported by Davey and Slaughter (1970), Bartrum, Dobrowolski and Schache (1977), Fiedler and Munro (1984) and Espinosa-Gomez el al (1989).Lead concentrate is smelted in Mount Isa while zinc concentrate and bulk concentrate (locally called Low Grade Middlings or LGM) are railed to Townsville and shipped to custom electrolytic zinc plants and ISP smelters.

Jan 1, 1993

The Skybolt is a new bolt concept, point anchored with resin in large diameter holes of specific sizes 38 mm and 45 mm. The new design achieves the optimum annular spacing required for mixing the resin anchor components which is essential for optimum resin bonding of the bolt to the surrounding rock. This paper explains the load transfer mechanisms between bolt/resin/rock, unique to this bolt concept. It compares the pull-out test results to those of paddle and expansion shell type bolts, and highlights the versatility of Skybolt over existing, currently used, rock support systems and the benefits mine operators can achieve when using the Skybolt.

Jan 1, 1992

By A Galli

Traditionally pit optimisation and scheduling is carried out assuming that the resources, the commodity prices and production costs are all known. Once the pit contour and the mining schedule have been determined, geostatistical simulations can be used to assess the impact of the uncertainty in the resources on the pit design and the schedule, and likewise stochastic simulations can be used to test its robustness to fluctuations in costs and prices. But it would be more interesting to have a dynamic procedure for optimising the pit as the resources become better known and as economic factors such as commodity prices and costs evolve over time. This paper presents a novel approach for doing this. Rather than working with millions of small selective mining units, it was decided to work with large blocks, called macro-blocks. Mining sequences are defined as the quantities to be extracted from each macro-block in each time period. Feasible mining sequences are mining sequences that respect the accessibility constraints, and also the geometric constraints on the amounts that can be extracted from any one block over time, or from all the active blocks at a given time. Having defined feasible mining sequences, their mathematical properties were studied. It was found that natural breakpoints occur in the sequences when one set of blocks have been completely mined out, thereby opening up access to others. It was discovered that families of sequences exist, and that they are convex and closed under certain types of row permutation operations. Convexity is an advantage when optimising. The closure property opens up the possibility of mixing and matching subsequences of rows in the sequences. Another interesting property is that the sequences form branching families, rather like the binomial and trinomial trees used to model prices in finance and in real options.It is easy to generate large numbers of feasible mining sequences randomly. A two-step procedure is used to find the best one (or the best few) using three economic criteria: expected NPV,the probability of a negative NPV, and the percentage of years when the cash flow is negative. The procedure was tested on a synthetic gold mine based on the characteristics of the Essakane mine in Burkina Faso. The results were encouraging.

Sep 26, 2011

The granulites and related "dry" igneous rocks tend to be passed over during exploration for metals. Preliminary data show that high trace concentrations of Cu, Ni and other metals of economic interest are common in orthopyroxene and some of the other granulite minerals. During retrograde metamorphism of granulites, pyroxenes are converted to amphiboles or phyllosilicates, and significant quantities of metals are released and become available for incorporat- ion into new mineral phases, or may be transported elsewhere. S--rich scapolite is the normal scapolite of granulites. Its retrogression to secondary plagioclase provides much S which scavenges Cu, Ni, etc., from pyroxenes undergoing retrogression, thus producing ore-fluids. A full analysis of a scapolite with 5.10 per cent S03 is given. Beryl is unstable in granulites but the rare Be mineral taaffeite (Al4Pf (Be,Fe)O3) with 5,50 per cent BeO occurs in central Australia as a pale green Tabular mineral easily confused for chloritoid in hand-specimen. Metamorphic differentiation and mobilization of primary ore concentrations are major factors controlling their post-granulite attitude and grade.

Jan 1, 1969

In order to satisfy environmental and mine operational requirements it is becoming increasingly important to minimise ground blast vibrations at certain locations. These locations are often in soil or on large resonant structures such as grain silos, highway bridges or even the walls of an open pit. A soil monitoring exercise was carried out to evaluate the common practice of coupling vibration detectors to the ground using spikes. At a series of locations in an operating quarry the spiked array response to single blastholes was compared with that of an accelerometer array attached to a calibrated embedded mount. The results clearly showed that the spiked arrays over-estimated the true ground vibration by 46.5 per cent on average, with a maximum observed error of 99.2 per cent. These errors are considered too large for compliance monitoring where accurate vibration levels are required for comparison with prescribed limits. Although spike coupling is convenient, its use for compliance monitoring should be viewed with caution. Unfortunately, however, many manufacturers supply their detectors as spiked arrays. A structural monitoring exercise was also carried out to evaluate the vibration response of a grain silo, highway bridge and a pit wall to the initiation of single blastholes. In this case accelerometers and standard geophones were firmly attached to the bridge which resonated at low frequencies. The results clearly show that, due to their limited low-frequency response, the geophones typically measured only half the true vibration level as measured by the accelerometers.

Jan 1, 1995

By P B. Hills, R J. Walton

Narrow vein tabular orebodies are prone to mining induced seismicity. The Tasmania Mine is a complex example of a seismically active tabular orebody, where the contrasting material properties of the host strata and of the orebody itself, serve to exacerbate the seismic response. Analysis of a continuous record of seismicity over a period of seven years has provided significant insight into the fundamental mechanics of the rock mass. Understanding seismicity to permit safe extraction of the orebody has been enhanced by instrumentation of rock mass behaviour in response to mining and mining induced seismicity. It is the purpose of this paper to explore that understanding in respect to the adoption of an alternative down-hole Avoca stoping method for use in particular circumstances.Intensive instrumentation of the Tasmania Mine over a period of four years has provided insight into the behaviour of the rock mass in response to extraction of the narrow vein orebody it encompasses. A range of instruments have been installed in clusters or single installations in order to measure changing stress conditions and the impact of those changes on the rock mass and the reinforcement system.Instruments are often installed in very close proximity to active production stoping. While it has been possible to observe the impact of the mining and mining induced seismicity at very close quarters, instruments installed in these locations are vulnerable to damage and consequently, the level of instrumentation is high. Instruments are continuously logged, typically on a six hourly basis coinciding with the end of regular blasting times. The response of the instrumentation to changed rock mass conditions is considered against the background of development and production blasting and against the seismic record to assess the viability of downhole Avoca stoping.CITATION:Hills, P B and Walton, R J, 2012. Continued observations of rock mass behaviour in response to stoping at the Tasmania mine, Beaconsfield, Tasmania, in Proceedings Narrow Vein Mining 2012 , pp 169-178 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By T Baumgartl, B Richards

Covers on waste rock and tailings remain the primary choice for closure planning where the purpose is to create an environment where water ingress into reactive material can be controlled and/or prevented. In semi-arid and arid environments, dry cover systems are the preferred option with the design intention to absorb rainfall and to prevent deep drainage. Although the average amount of rain typical for semi-arid environments is relatively low and evaporative demand is high, the seasonal and annual distribution may vary greatly. Rocky substrates are often the only choice for the construction of covers due to economic constraints or availability of suitable materials. While the water holding capacity may be suitable for the application of a dry cover design in arid and semi-arid climates, some of these covers bear the risk of preferential water flow when rain events are intensive or occurring at high frequency. The objective of this presentation is to demonstrate the occurrence of preferential flow through rock containing dry cover systems. A regional classification for the applicability of dry covers is attempted to delineate those regions of Australia where the characteristic of the rainfall pattern increases the risk of failure for dry cover designs. CITATION:Baumgartl, T and Richards, B, 2016. Rainfall patterns rather than climate classification control cover design for closure, in Proceedings Life-of-Mine 2016 Conference, pp 89–92 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 28, 2016

By Fulton B, Stewart R, Leach T

Gold mineralisation at Porgera is inferred to have been derived from a deep differentiated magmatic source which is capped by a series of (now tilted) inward dipping sills and stocks, which comprise the Porgera Intrusive Complex. An arc normal transfer structure provides a conduit, at the intersection with an arc parallel structure, into which basic magma derived from the deep melting of mantle material has been emplaced. Two phases of mineralisation display an association with late stage feldspar porphyry intrusives. Stage I carbonate-base metal-style gold mineralisation occurs as early quartz-sericite, then massive sulphide and late zoned Mn-Fe-Mg-Ca carbonate vein/breccias. Magmatic fluids derived from the deep magma source, are interpreted to have migrated along the margin of a feeder stock to the sills, and south to Waruwari. Stage II epithermal Au-Ag quartz-style gold mineralisation occurs as early fluidised breccias and carbonate veining, followed by zoned quartz-roscoelite-carbonate-gold vein/breccias, and late carbonate and/or sulphate open space infill. Magmatic fluids are interpreted to have utilised the same plumbing system as the late stage feldspar porphyry intrusive, and then migrated into the Roamane Fault which was dilated by; dextral rotation on elements of the transfer structure, normal faulting, and refraction around the competent footwall hornblende diorite. Bonanza gold is localised in a jog in the Roamane Fault, hangingwall splits and at intersections with cross structures. Bulk low grade Stage I gold has been deposited by the mixing of magmatic fluids with cool gas condensate waters, whereas high grade Stage II gold mineralisation resulted from the rapid quenching of mineralised magmatic fluids by oxygenated groundwaters.

Jan 1, 1995