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By Mery-Cecilia Gómez-Marroquín

O presente trabalho trata da formação da ferrita de zinco a partir da mistura e posterior reação solido-solido entre o óxido de zinco e óxido de ferro - Fe2O3 puros em proporções equimolares. A faixa de temperatura onde teve lugar a formação foi entre 1073 e 1373 K. Testes de redução da ferrita de zinco sintética-ZF e pós de aciaria elétrica–EAFD foram realizadas usando misturas de CO e CO2 que variaram entre 50 e 100% CO. Ambos os testes (formação e redução de ZF e EAFD) foram suportados usando técnicas de caracterização física, química, estrutural e microscópica. No caso da redução, foi observado que tanto a temperatura como a percentagem de CO, foram os fatores que, mais afetaram a redução de ferrita de zinco contida no EAFD. A máxima percentagem de redução foi 85%, para 100% CO, 1373 K e 105 min, e 52%, para 50% CO, 1373 K e 105 min. Por outro lado, atingiu o 100% para 100% CO, 1273K, em 80.75 min, 60%, para 50% CO a 1373 K durante 105 min.

Aug 16, 2017

By Mery-Cecilia Gómez-Marroquín

O presente trabalho trata da formação da ferrita de zinco a partir da mistura e posterior reação solido-solido entre o óxido de zinco e óxido de ferro - Fe2O3 puros em proporções equimolares. A faixa de temperatura onde teve lugar a formação foi entre 1073 e 1373 K. Testes de redução da ferrita da zinco sintética-ZF e pós de aciaria elétrica–EAFD foram realizadas usando misturas de CO e CO2 que variaram entre 50 e 100% CO. Ambos os testes (formação e redução de ZF e EAFD) foram suportados usando técnicas de caracterização física, química, estrutural e microscópica. No caso da redução, foi observado que tanto a temperatura como a percentagem de CO, foram os fatores que, mais afetarem a redução de ferrita de zinco contida no EAFD. A máxima percentagem de redução da ZF foi 85%, para 100% CO, 1373K e 105 min, e 52%, para 50% CO, 1373K e 105 min. Por outro lado, atingiu o 100% para 100% CO, 1273K, em 80.75 min, 60%, para 50% CO a 1373K durante 105 min. no caso da redução do EAFD

Aug 17, 2017

By Michael McDonald

The cold-rolled steel output of cold-rolling mill (CRM) complexes are sometimes constrained by their batch annealing facilities (BAF). This paper examines a cost-effective solution to increasing capacity and quality of the BAF thereby making additional capacity available for CRM output. The solution involves applying a structured system of scheduling and operation to the BAF, using a proven level-2 software model. The system presented has been applied to a wide variety of BAF with all the leading furnace brands. Whether using traditional HN atmosphere or 100% hydrogen, peak performance can be achieved when using a properly configured, on-line, physical thermodynamic model. Given that it is not practical to place a thermocouple in each coil that is being annealed, various methods have historically been used to estimate the time required to properly anneal all the coils in the charge. This paper examines how the latest technology, in wide use throughout the USA, uses a physical thermodynamic model to shorten average cycle times, thereby increasing productivity and reducing energy consumption. The paper also examines the benefit of building thermodynamically balanced charges to further optimize the BAF operation and improve quality consistency by decreasing mechanical property variations.

Jul 30, 2018

By Mathias Woydt

The tribological and mechanical properties of binderless and metal-bonded niobium carbides (8 or 12 vol.-% of Cobalt, 12 vol.-% of Fe3Al) are presented. Rotating disks made of niobium carbide bearing hard metals were mated against alumina (99.7%) under unlubricated (dry) unidirectional sliding tests (0,1 m/s to 12,0 m/s; 22°C and 400°C) as well as in oscillation tests (f= 20 Hz, ?x= 0,2 mm, 2/50/98% rel. humidity, n= 105/106 cycles). Microstructure and phase compositions were determined as well. The tribological data obtained were benchmarked with different ceramics, cermets, hard metals and thermally sprayed coatings, where NbC bonded with 8% and 12% Co presented above 8 m/s the lowest wear rates so far in such a benchmark. Binderless NbC (HP-NbC1) and the metal bonded NbCs exhibited low wear rates under dry sliding associated with high P?V load carrying capacities. NbC-based hard metal bonded with 12 vol.-% of Fe3Al resulted in a higher hardness level than for 12 vol.-% cobalt. The tribological profile established revealed a strong position of NbC bearing materials under tribological considerations and for closed tribosystems against established reference tribo-couples.

Jul 31, 2018

By Leandro Rigo Ramos, Marcelo Lucas Pereira Machado, Lumena Gloria de Souza Nunes, Mariana Valinhos Barcelos

The aim of this work was to study the influence of temperature on the grain refining process from severe plastic deformations through the simulation of Accumulative Roll Bonding (ARB) by torsion tests. The assays were performed to simulate the ARB at three different temperatures of 550 ° C, 625 ° C and 700 ° C with 5 torsion cycles with equivalent strain of 0.8 per cycle at a rate of 0.1−1 , totalizing an accumulated deformation of 4.0. Grain refining was obtained with an average size of 2μm, 5μm and 6μm for the temperatures of 550 ° C, 625 ° C and 700 ° C respectively. There was a rise in Vickers hardness by 68%, from 119HV in the annealed sample to 175HV in the deformed sample at 550 ° C. In the deformations at 625 ° C and 700 ° C the value of 130HV E and 150HV respectively was obtained. Based on the obtained results, it can be stated that the severe plastic deformations in microliged steel, carried out at temperatures lower than the end of the austenite-ferrite transformation, produce refined grains of the order of 2μm and, consequently, increase the mechanical strength of the material.

Oct 1, 2019

By Peter Grawenhof

In steel mills universal joint shafts, slipper spindles and gear spindles are used to overcome the design- and process- related offset between the axis of the motors and the work rolls. At the roll side the available space for the couplings is limited by the minimum work roll diameter. This leads to extremely high loaded components of the universal couplings especially at the roll side joints. Furthermore modern steel mills continuously strive to roll larger plates and materials with increased strength. This requires drive solutions with even higher torque capacity. For these applications conventional design joints are not sufficient anymore. Even alternative solutions such as hybrid- or offset- designs fall short. Therefore the companies Voith and BUMA Engineering developed together the new GearLink drive concept in close cooperation with the Voestalpine Grobblech GmbH. A completely new combination of universal joints and gear couplings offers an up to now unique solution enabling the use of 1,35- times bigger joint with a 2,5- times higher torque capacity and a 20- times longer lifetime. The GearLink system was first time successfully taken into operation at Voestalpine Grobblech in December 2013 and is up to now working without issue.

Aug 16, 2017

By Jens Kempken

A competitive landscape pressurizes the steel producers business, zero defect requirements from customers forces the operators for additional efforts in process control and quality management. The so called quality related cost, which include also rework, cost for downgrading or even scabbing of material is already a remarkable lever in a plants profitability breakdown. The introduction of advanced state of the art grades in the product portfolio requires already a budgeting for the expenses for R&D and quality management. PQA has been developed as a process and quality management software solution next to existing level 2 or level 3 automation systems. It is focusing on the analysis of process data, equipment information, in line quality measurement devices and trend analysis to obtain an answer whether the process is according to definition and expectation and whether the intermediate or final product can be shipped for further processing as prime material. Advanced analytics which are linked to an expert know how based configuration identifies deficiencies in the production and processing process. An intelligent, state of the art quality rating system evaluates tolerable deviations. PQA comprises the software platform including the database, data configurator and collector from the different sources in the production process and units. The core element of the platform is the knowledge based expert know how package defining process and quality determining fundamentals. The paper describes the structure of the software package, it gives insights on the expert know how package, process and quality evaluation and points out the customer benefits, cost reduction, improvement yield, customer satisfaction increase. The link to recent operational references is given.

Oct 30, 2017

By Rodrigo Sanchotene Silva

Currently the industries of paint have directed their efforts on cleaner production of products that provide effective performance in corrosion protection of metallic materials. This work search introduce a new alternative of organic coating, without the presence of hazardous metals and replace equipments commercials used method of anodic protection for protection of oxidized metals. From this it, was produced Smart Paint (SP), consisting of Paint Acrylic Commercial (PAC) mixed the 1 % of binder, compound by the conducting polymer, Polyaniline Emeraldine Base (PAni EB) and plasticizer 4-chloro-3-methylphenol. The SP and PAC were applied to plates of carbon steel AISI 1010, with the aid of dip coat technique and then were subjected to drying for 48 h. The SP was characterized by thermals and physicochemical analyzes in order to verify possible changes in chemical properties of the ink produced, beyond perform electrochemical tests of Open Circuit Potential and Electrochemical Impedance Spectroscopy, employing equipment Potentiostat/Galvanostat Autolab PGSTAT302 Ecochemie, and aqueous 2 mol.L-1 of H2SO4. The results obtained allow us to state that the plasticizer does not alter the electrochemical properties of PAni and application of binder PAni EB to PAC does not alter the physicochemical properties of commercial coating. The binder PAni EB adds to PAC the capacity to induce the formation or maintenance of protective oxides in oxidizable metals submitted to harsh environments, method known as anodic corrosion protection.

Aug 8, 2018

By Wolfgang Kern

More and more coke oven plants worldwide face the task to improve their emission reduction at their coke oven batteries. In the 90’s PROven® was invented and developed by DMT to regulate the inner pressure of a single coke oven chamber. Generally, most of the coke oven chambers can only close and open their connection to the collecting main but without the possibility to regulate the pressure during the carbonization time. Through the installation of PROven® the load on the coke oven door sealing system and the charging lids will be decreased and so does the emissions of crude COG as well. The current PROven® system, installed in the collecting main, does not only regulate the chamber pressure, it replaces the valve between the goose neck and the collecting main, too. This variable pressure control allows decreasing the leakages at the emissions sources to a minimum and allows operating the collecting main under optimum pressure. Subsequently, this will lead to enhanced emission reduction. PROven® proved its value with more than 2,100 units installed by licensee worldwide. Nevertheless, DMT is always focused on its client’s needs and therefore enhance PROven® to provide the Best Available Technique (BAT). Among the main features of the now available system is the plain arrangement with a higher reliability and the possibility to install the system outside of the collecting main without modifying it. Hence, upgrading coke oven plants during operation is possible without any noticeable impact on the plant operation.

Aug 1, 2018

By Samuel Filgueiras Rodrigues, Clodualdo Aranas Jr., Gedeon Silva Reis, Eden Santos Silva, Fulvio Siciliano

When austenite is deformed above the Ae3 temperature, partial amount of it transforms dynamically into ferrite by a displacive mechanism. After unloading, it retransforms back into the stable austenite by a diffusional process. This influences the rolling load which decreases under isothermal condition or does not increase with decreasing temperature as rapidly as expected under cooling. Plate rolling simulations under isothermal and continuous cooling conditions were carried out on a 0.09 wt.% Nb X-70 steel. Pass strains of 0.2 were employed together with interpass times of 10 s, and 30 s for the cooling conditions and 0.3 with interval of 10 s at 900 °C for the isothermal experiments; strain rate of 1 s-1 was used during the simulations. The mean-flow-stress (MFS`s) behavior of both conditions indicates that dynamic transformation and dynamic recrystallization were taking place during straining. The critical strains for the initiation of dynamic transformation fell around 0.06 while the critical strain for DRX was 0.12. It has been shown that ferrite is formed due to the applied deformation of roughing passes and increases its volume fraction throughout the finishing rolling stage. Under cooling conditions, the ferrite formation is also favored as the temperature approaches the Ae3 line. Such ferrite forms when the driving force for dynamic transformation is higher than the total free energy barrier preventing its formation. This obstacle consists of the free energy difference between austenite and ferrite as well as the lattice dilatation work and shear accommodation work. The addition of Nb retards the retransformation of the ferrite into austenite. Moreover, holding times after rolling increases the amount of austenite available for microstructure control on subsequent stages. The dynamic transformation (DT) mechanism can be used to design improved rolling schedules

Oct 1, 2019

By Vitor Guarnier Domiciano

The need to adjust the monolithic refractories to increasingly severe and unstable Blast Furnace casthouse operating conditions has been a major challenge for refractory suppliers in order to guarantee the runner’s safety and its availability for operation. This paper presents the properties of a new robust single line Al2O3-SiC-C refractory castable developed to endure the severe operating conditions that main runners are facing in today's Blast Furnace casthouse scenario. Practical results during almost one year of testing revealed a significant lower wear speed of the new refractory lining when compared to a standard product.

Aug 1, 2018

By Eric Yoshimitsu Sako

One of the main difficulties in the operation of trough and runners at Arcelor Mittal Tubarão (AMT) Blast-furnace no.02 is the reduced amount of time available for repair procedures. The consequence is that the castable installation must often be performed during hot conditions and the installed castable could easily detach from the base material during the early stage of operation, exposing the previously oxidized base material to molten iron and corrosive slag attack. When events like this happen, emergency repairs must be executed, resulting in increased refractory unit consumption and an unplanned shutdown of unit operation. Considering these targets, Nippon Crucible Co. and Saint-Gobain HPR Brazil have developed a high-performance Al2O3-SiC-C composition based on an entirely novel anti-oxidation technology. Oxidizing reactions could be attenuated by adding an oxidant inhibitor and a water reducing agent. As a result, the open porosity was significantly reduced, resulting in an improvement of campaign life in terms of pig iron throughput when compared with the regular castable. An analysis of this life improvement showed successful results for the material after 250 days of campaign. The main reason for such successful results was that the deterioration caused by the oxidation was significantly less and that this change made on the high cohesive structure of the base material was maintained for a long time. The attained results allowed Arcelor Mittal Tubarão to achieve longer trough campaigns, and avoid any unplanned stoppages with zero breakdown risks.

Oct 30, 2017

By Marco A. Ramírez-Argáez

A 2D mathematical model was developed for the plasma arc welding process. Computational simulations based on mass and momentum conservation equations as well as Maxwell equations were performed by using the commercial software PHOENICS. The model predicts the electric characteristics of the arc column, flow patterns, temperature contours and electrical potential, by varying the composition of the cover gas, in this case, argon and nitrogen. It was found that an arc of nitrogen with respect to one of argon generates more intense jets, greater voltages, and lower temperatures in the arc column for welding arcs current of 150 A and 10 mm arc length.

Oct 30, 2017

By Jefferson Lisboa Lelis, Marcos Roberto Soares da Silva, Maiara Rodrigues Gouveia

Nowadays, due the development of new hot rolled strips at USIMINAS, established the necessity of realizing studies to define new parameters for the welding machine of new pickling line, in order to improve mechanical and metallurgical properties of these materials. The aim of this study was to evaluate the weldability of high strength low-alloy steel with low boron content with tensile strength above 600MPa.The influence of energy input and preheating temperature on the mechanical properties of hot rolled strips were analyzed at three distinct thickness (2, 4 and 6 mm). To perform these evaluations were used tensile test, micro-hardness, metallography (micro and macro examination) and scanning electron microscopy analysis. In resume, a good welding performance was achieved, increasing preheating temperature and the welding energy higher than 60%.

Oct 13, 2019

By Jürgen Schanderl

Cold rolling mills by SMS Siemag are well known for their reliability and long-life cycle. They are an investment in the future. Nowadays mill owners are under considerable competitive pressure and are asked to organize production in a more and more efficient and flexible way. Doing so, a number of elevating screws have to be turned. These are: cutting of operation costs, especially by more efficient equipment and processes as well as transition to more process flexibility to fulfil future product requirements. To support owners in their effort, SMS Siemag offers convincing solutions in cold rolling technology under the brand X-Roll 2.0. Examples to be presented are: Sieflex®-HT drive technology; Redesigned DS system; New reel design: Twin Reel; Emulsion compact unit ECU Compact; TRC® threading assistance system; ECOMode and Energy ADVISOR monitoring system.

Jul 30, 2018

By Maycon de Almeida Gomes

Fiber reinforced polymeric composites have received widespread attention in the past four decades because of their high specific strength and modulus. In particular, research works have disclosed the potential advantages associated with the use of lignocellulosic fibers as the reinforcing phase in polymer composites (2-3). Among various natural fibers, pineapple leaf fibers exhibit excellent mechanical properties. The main chemical constituents of pineapple fibers are cellulose (70–82%), lignin (5- 12%) and ash (1.1%). The superior mechanical properties of pineapple leaf fibers are associated with their high cellulose content (6). This work aims to make the analysis of the Izod impact energy against volume fraction of palf fibers of epoxy composites reinforced with PALF. The fibers were incorporated into the epoxy matrix with volume fraction from 0 to 30%. After fracture the specimens were macro photograph analyzed.

Aug 16, 2017

By Karl Berger

Today we are talking about Industry 4.0, as the latest revolution of industrial processes and progress, considering that the steam engine (Industry 1.0), railways and cars, mass production in the 1920th (2.0), Industrial Automation (3.0), and finally integrated manufacturing, integrated communication, and internet (4.0) can be seen as the state-of-the-art situation in industry, nowadays. Similar to the Industry progress, we can approach the rolling process of material, which started about 150 years ago in a very basic way. Steam engine- and belt driven-mills were very operators’ intensive, brutal and risky to operate. Mechanical improvements brought throughput, safety and quantity, as also quality of the products. The rolling of steel, in particular of rails, beams, rebar, strip (focus in this paper) and plate has enabled the large scale transport and travel, the building of bridges and buildings, the manufacturing of ships and cars. From single stands to continuous rolling trains the production and quality of mills increased significantly. From ingots and blooms to slabs, we have to admit a big jump in which has changed the face of the world significantly. Thin Slab Rolling has revolutionized the output and the throughput of rolling mills (Generation 3.0 to 5.0). Finally, Endless Rolling, has boosted the quality and quantity of rolling mill processes and permitted nowadays to enter in market niches which were not thinkable a decade ago. Mastering the automation and applying reliable systems (mechanical and electronically) of drives, actuators and sensors, as also communication and information interchange to all levels of automation are the success factors of such complex mills, we call herein after “Rolling Mills of Generation 6.0”.

Aug 16, 2017

By Cristina Escudero Martinez

The purpose of the Basic Oxygen Steelmaking (BOS) is to refine the hot metal produced in the blast furnace into raw liquid steel, which may be subsequently refined in the secondary steelmaking shop. Appropriated fluxes for the BOF could require low melting point to reduce the energy consumption, to reduce the energy to fluidity the slag at lower temperature and to melt at lower temperature than steel. It is necessary a good Tumble test result and the fluxes do not generate fines which could obstruct the blowing plugs, so we would have a homogeneous flux. A homogeneous chemistry that allows to control the basicity (Si and MgO levels) and a high absorption characteristics to combine the flux with P, S, Si, etc. are necessary. PASEK Dunite is an ultramaphic rock exploited in the north of Spain with a basic chemical classification being olivine and serpentine its principal minerals. It is formed by orthopyroxene, clinopyroxene and olivine in variable proportion. Dunite is a very homogeneous and hard stone. The main characteristics are: High hot and cold resistance to mechanical stress (shatter / crushing / abrasion), softening and melting points of a flux, not a refractory material, large porosity which is increased more than 20% when dunite is heated at BOF process temperature, and high absorption level, and stable components with low melting points. PASEK Dunite is a good flux in BOF process and its use is recommended if the BOF process produces pig iron with low Si content, generates high levels of slag and it is necessary maintaining the basicity index and the MgO amount and with high value of hot metal ratio (high amount of phosphorus to remove).

Aug 16, 2017

By Alberto Tremea

In this period a great attention is put on roll cost and the differences in roll behavior in very few situations move the existing balances. Among many variables that are taken into account to evaluate the roll there is the consumption which is normally calculated according to the tonnage rolled. In this work there is a review of some approaches that are used to evaluate the roll efficiency together a description of a new method to make this. The main purpose of this calculation method is to help the comparison of roll results used in different mills. There is the need to have a clear and univocal reference when it’s time to think about innovative products. At now there are available roll grades with excellent technological properties but it’s necessary to have the right tools for a careful evaluation of roll behavior to take a good decision.

Jul 30, 2018

By Michaela Böberl

State of the art sinter coolers are working based on the cross flow cooling principle. Thus, only a part of the thermal energy can be used for heat recovery application. The other part of the cooling air is brought unused to the environment. Furthermore, environmental regulation regarding dust emission and intelligent usage of exergy are getting stronger. Therefore, Primetals Technologies developed sinter coolers based on the counter flow principle. The cooling air passes the sinter bed in counter-flow direction enabling a direct heat transfer from the hot sinter to the air. The exhaust gas temperature can be maximized by using the total heat of the hot sinter. Due to the possible usage of the total exhaust gas amount, diffusive dust emission is reduced to zero. Two types of counter flow coolers are in the portfolio of Primetals Technologies. One type is based on a stationary shaft, in which the hot sinter is charged. The flow of the hot sinter is in vertical direction from top to bottom, in counter direction than the cooling air. The second type is a circular hopper cooler. The hot sinter is charged on top of a moving bed. At the bottom of the bed the sinter is discharged. The cooling air flows also from the bottom to the top, following the counter flow principle. Depending on the requirements, one of the two counter flow cooler types can be chosen for optimized and efficient cooling of hot sinter..

Oct 30, 2017