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By Kimberly Conner-Mills

Due to increasingly stringent worldwide environmental regulations for gaseous, aqueous and solid waste emissions, conventional smelting technology cannot effectively process arsenic containing materials. Many globally significant copper properties have copper sulfide mineralogy that has a high arsenic content present as enargite with significant contained precious metals. As global copper, silver and gold demand increases while significant world resources decrease, treatment of sulfide orebodies with enargite is becoming increasingly important. Methods to selectively dissolve and fix arsenic, leaving behind clean copper and precious metals-bearing concentrates could effectively treat these ores.

By Michael A. Krstich

A soil washing pilot plant to treat soils at the U.S. Department of Energy (DOE) owned Fernald Environmental Management Project (FEMP), was designed based on extensive bench-scale testing. The system's design incorporated a combination of physical separation and' chemical extraction processes and was tested on two soils. The textural composition of the two soils was approximately 20 percent sand, 60 percent silt, and 20 percent clay. Since this grain size distribution was not considered optimum for physical separation techniques, thesoil washing pilot plant had to be designed with selected equipment to provide specific soil size fractions during processing operations. A trommel, vibrating screen deck, centrifuge, and attrition scrubber were used in the system to selectively separate specific soil size fractions at 4.75, 2, 0.3, and 0.02 millimeters (mm). The trammel used high pressure water [1000 pounds per square inch (psi)] during the initial step of the process to reduce soil aggregates to single grain composition, separate out greater than 4.75 mm gravel, and dislodge chemical contaminants from the individual soil particles. The vibrating double-screen deck provided 2 - 4.75 and 0.3 - 2 mm soil fractions that, when combined, averaged greater than 75 percent solids for both soils. The centrifuge was designed to take the less than 0.3 mm soil slurry from the screen deck and produce a particle size of 0.02 mm. The centrifuge produced a high solids stream that averaged greater than 70 percent solids for both soils. These 0.02 to 0.3 mm soil solids from the centrifuge were combined with the 0.3 to 4.75 mm soil solids from the screen deck and processed through the attrition scrubber. The data collected from the pilot-plant operation was used to aid in the design of a full-scale system and was instrumental in formulating full-scale process operations and the selection of equipment.

Jan 1, 1995

By Yurniko Nakamura

Hydriding properties and crystal structure of a Ti-V- Mn solid solution alloy have been studied by P-C isotherm measurements and neutron and X-ray powder diffraction. The absorption P-C isotherm at 298K shows two plateau regions at 0.01MPa and 1MPa. The X-ray diffraction data have demonstrated that three phases with a BCC, a pseudo-cubic FCC and an FCC structure form subsequently with increase of the hydrogen content. Crystal structure of the latter two phases has been determined by Rietveld refinement of the neutron diffraction data. The FCC phase is the di-hydride of CaF2 type with hydrogen occupation in the T sites. The pseudo-cubic FCC phase is the mono-hydride of NaCl-type with hydrogen occupation in the 0 sites, which has not been reported so far. The lattice constants of the mono-hydride (Ti1.0V1.1Mn0.9)H_2.7 are a'=0.407 nm for two axes and c'=0.390 nm for the third axis. The a'axis is shorter by 4% than the c'axis. This pseudo-cubic FCC lattice is formed by contraction of 5% of the a axis and expansion of about 30% of the c axis from the original BCC lattice.

Jan 1, 2002

By Florian Kongoli

"Lime ferrite" slag with limited silica content has proven to be a valuable choice in the modem processes of copper smelting and converting due to several advantages that this slag offers compared to classical silicate slags. Nevertheless the liquidus surface of this slag has been experimentally measured only at low oxygen potentials such as in equilibrium with iron or near it and in air. Although most of the smelting and converting processes that use this slag occur at intermediate oxygen potentials, the liquidus surface of this slag is not known at these conditions and the effect of oxygen potential and silica has not been correctly understood. This has brought some confusion in literature as well as in the industrial practice. In this work the liquidus surface of the calcium ferrite slags has been quantified by the means of a new thermophysicochemical model and a new type of liquidus surface diagrams which are very convenient for any industrial process that uses calcium ferrite slags. These diagrams can be easily used to select the lowest liquidus temperature of calcium ferrite slags at a minimum cost and can help design several fluxing strategies in copper smelting and converting processes. The effect of the oxygen potential and silica is also quantified and important industrially related conclusions are drawn.

Jan 1, 2003

By Raymond F. Dalton

Despite the ready availability of numerous zinc sources, the process of solvent extraction- electrowinning (SX-EW) has as yet found little favour in the zinc industry. It is suggested that this is largely due to the previous lack of availability of suitable selective reagents having the particular features required to enable them to fit in to a solvent extraction-electrowinning based process for zinc, particularly with regard to strength and selectivity for zinc over iron. This paper describes work on the development of new selective extractants for the recovery of zinc from both sulfate and chloride aqueous solutions and suggests how they might be integrated into new zinc processes.

Jan 1, 1994

By S. K. Varma, Miriam Regalado, Daniel Salas, Erica Corral, Erika Esquivel

"Age hardenable 2014 aluminum alloys and composites containing 0.10 and 0.15 volume fractions of alumina particles (VFAP) have been solutionized at 540 and 550°C for up to 20 hours. The solutionized samples, heat treated for 5 and 20 hours, have been subjected to room temperature rolling until cracking develops. The work hardening curves have been compared to determine the effect of solutionizing time on the rolling characteristics from both hardness and the microstructural evolution points of view. Solutionizing at two different temperatures results in differences in the extent to which the composites can be rolled until fracture. The microstructural characterization by TEM has been performed to understand the room temperature rolling behavior.IntroductionThe effect of solutionizing on the age hardening response of 6061 and 2014 aluminum alloys and composites reinforced with 0.10, 0.15 and 0.20 volume fractions of alumina particles (VFAP) have been reported in the literature [1-4]. A comparison of the monolith and composites indicates that particles promote the aging process through differences in the microstructures in solutionized condition. The first effect of solutionizing is to produce a grain growth process which follows a grain growth law (square of grain diameter as a function of solutionizing time). It appears that it is possible for vacancies to be emitted during grain growth period as they try to minimize the total grain boundary surface area by increasing their diameter. This may be common to both the monolith and the composites. However, the second effect must be exclusively considered for the composites. The particles generate dislocations during the solutionizing process due to the differences in the values of the coefficient of thermal expansion (CTE) between the particles and aluminum base metal. It has been determined [1] that the dislocation density increases with increase in solutionizing time in the composites of 6061 aluminum alloys reinforced with 0.10, 0.15 and 0.20 VFAP. The improved bonding between particles and matrix can give rise to additional generation of dislocations due to curvature effects [1] with the result that the dislocation density continues to increase with increase in solutionizing time even after the CTE effect is considered to have been stabilized."

Jan 1, 1998

By Yang Hong-ying, Yu Juan

Electrochemical behavior of natural chalcopyrite in electrolyte solution at pH value of 6.97 was studied by cyclic voltammetry, X-ray photoelectron spectroscopy and electrochemical impedance spectroscopy. The results showed that the electrochemical processes occurred on electrode surface were controlled mainly by the growth of sulfur species at lower applied potentials (<0.35Vvs.SHE), and the oxidative dissolution of sulfur species and the hydroxylation of iron at higher applied potential (>0.45V). The EIS spectra of oxide product layers could be illustrated by the equivalent circuit of Re(QdlRct(QfRf)), and the degree of hydrophilicity for chalcopyrite was higher when the value of charge transfer resistance Rct. was greater. The optimum potential range for the floatation of chalcopyrite in collectorless solution at pH value of 6.97 was between OCP (0.165V) and 0.35V.`

Jan 1, 2015

By R. David Prengaman

During the past several years a new insoluble lead anode has been developed for copper electrowinning. The new anode consists of a rolled lead-calcium-tin alloy sheet attached to a slotted copper bus bar by a soldering process which produces a complete metallurgical bond between bar and sheet. The metallurgical bond greatly reduces the resistance between the bus bar and the lead sheet and the high conductivity does not deteriorate during the life of the anode. The rolled anode thins uniformly and does not suffer preferential grain boundary or internal corrosion commonly seen in cast anodes. The lead-calcium alloy containing a high tin content corrodes slowly because the rolling process produces a uniform, fine grained structure. The wrought product is very strong and ductile; and contains no internal defects, segregation, cracks, or pores which can reduce the life of the anode. Because the anodes corrode uniformly, a high percentage of the anode thickness can be utilized thus extending the life of the wrought anodes. The anode alloy composition which is stable only in wrought form, produces exceptional resistance to passivation during current interruptions. First introduced into liberator cells, the new electrowinning anodes have been specified as the anodes of choice for every new SX-EW tankhouse constructed in the last two years. This paper describes the new anode, its method of construction, service history, and how it differs from present copper electrowinning anodes.

Jan 1, 1987

By Florian Kongoli

"Lime ferrite" slag with limited silica content has proven to be a valuable choice in the modem processes of copper smelting and converting due to several advantages that this slag offers compared to classical silicate slags. Nevertheless the liquidus surface of this slag has been experimentally measured only at low oxygen potentials such as in equilibrium with iron or hear it and in air. Although most of the smelting and converting processes that use this slag occur at intermediate oxygen potentials, the liquidus surface of this slag is not known at these conditions and the effect of oxygen potential and silica has not been correctly understood. This has brought some confusion in literature as well as in the industrial practice. In this work the liquidus surface of the calcium ferrite slags has been quantified by the means of a new thermophysicochemical model and a new type of liquidus surface diagrams which are very convenient for any industrial process that uses calcium ferrite slags. These diagrams can be easily used to select the lowest liquidus temperature of calcium ferrite slags at a minimum cost and can help design several fluxing strategies in copper smelting and converting processes. The effect of the oxygen potential and silica is also quantified and important industrially related conclusions are drawn.

Jan 1, 2003

By G. Richards

The Trail smelter of Teck Metals Ltd. produces about 90,000 tonnes of lead per year through two stages of refining following KIVCETTM smelting. Bullion from the KIVCET furnace is first treated in a pyro-refining plant in preparation for Betts electrorefining which makes 99.99% pure lead. Pyro-refining consists of number of integrated unit operations to remove primarily copper, arsenic, antimony and tin. The operation of this plant to meet the specifications for electrorefining requires attention to bullion management and selective use of reagents. The processes used for pyro-refining are reviewed in terms of chemistry and control.

By W. G. Davenport

This chapter shows how flash furnace industrial oxygen and oil requirements are affected by different: (a) product temperatures (b) conductive, convective and radiative heat losses (c) electrical energy inputs (d) hydrocarbon fuels. The calculations of the chapter are all for production of 65% Cu matte from pure CuFeS2 concentrate. Blast temperature is? 298 K throughout.

Jan 1, 2001

By Ho-Jung Shin

The influence of cooling rate from 1873 to 1473 K on the size and morphology of austenite grains was studied using a Fe-O.I5 % C-I.5 % Mn alloy. The experiments were carried out at three different cooling rates of O.33KJsec, O.67KJsec and air-cooling. The austenite grain showed an isotropy at 0.33KJsec but maximized anisotropy at O.67KJsec and become much less. anisotropic. In order to account for these phenomena, a model was developed for estimating the size and morphology of austenite grains as a function of cooling rate. The driving force for the )( phase formation from 0 phase is caused by undercooling degree due to cooling rate and energy barrier is restricted to the misfit strain energy which is caused by mismatch between )( phase and 0 phase. The )( phase from 0 phase could be formed on not random orientation index systems but specific orientation systems depending on cooling rate.

Jan 1, 2001

By Wei Liu

A new process for extracting cadmium from the electric precipitated dust produced by ISP process was studied. A leaching rate of 89.1% of cadmium was attained by leaching the dust with NH3?H2O-(NH4)2SO4 system under the best leaching conditions: ratio of liquid to solid(l:s)=2.5, c(NH3):c(NH4+)=3:5, total concentration of ammonium and ammonia=8 mol?L-1, leaching time= 1.5h, temperature=35. The most troublesome impurity of lead could be deposited from the leached out solution automatically after put it static more than 15h when the total concentration of zinc and cadmium was up to 45gL-1 , and the final concentration of lead was 0.0047 gL-1, which meant 99% of it was removed. Metallic cadmium which contained cadmium more than 99% was prepared by electrowinning under the conditions: current density=750Am-2, total concentration of Cd2+ and Zn2+>25gL-1. The current efficiency was about 87% and the energy consumption for every ton of cadmium was about 548KWht-1. Main impurities of the metallic cadmium were copper and zinc and all of they could be got rid of in the following pyrometallurgical refining step.

Jan 1, 2006

By Stein Tore Johansen, Fionn Iversen, Jon Arne Bakken

"A new marker chain front tracking method is used for modelling the meniscus movement during DC casting of aluminium ingots. Modifications have been made to an earlier method developed by Popinet and Zaleski [12] to adapt the model for simulations of meniscus dynamics in the casting process.Initial casting simulations show that wetting conditions in the mould greatly influence the meniscus stability. Controlling the wetting conditions seems to be important for improving the cast ingot surface quality.IntroductionIn conventional direct chill (DC) hot top casting of aluminium extrusion ingot with gas-slip poor surface quality of the cast ingot can be a problem. In the worst cases pronounced surface wrinkling occurs coupled with periodic zones of reduced grain size, macrosegregation and exudation at the surface. The observed surface irregularities are believed to be linked to Periodic surface oscillations or folding of the meniscus resulting in varying solidification conditions.The focus of this work is to gain a better understanding of the dynamics of the meniscus and the influence it has on the finished cast ingot surface through numerical simulations of meniscus movement during the casting process.A two phase marker chain front tracking technique[12] using cubic spline surface reconstruction is applied for modelling the meniscus movement. The advantage of this type of model is its accuracy in the calculation of surface tension forces. Also the wetting can be implemented directly as a boundary condition on the surface spline function. The method is applied in the FLUENT solver, which is based on a finite volume method using the SIMPLE algorithm."

Jan 1, 2001

By Mingchun Lu, Yunjin Yan

"This paper describes a new type of bell-less top installed on two relined blast furnaces at Tianjin Iron Works and another new-built at Echeng Steel Works in China. A compact installation was presented for existing furnace top innovation with the least reformation of existing top structure. A water cooling and sealing gearbox used for driving the chute discards completely the traditional idea about necessity of continuous supply of cooling gas for the gearbox. A multiring spreader and its dozens of selectable charging patterns enables an operator to achieve optimal burden distribution easily under the condition of a minimum investment of control equipment. Some useful conclusions have been made through a small-size model and a full-scale model tests. The excellent characteristics and the superiority of the new top have been fully proved at both works.IntroductionIt is known that there are some advantages with the bell-less top of a blast furnace: suitable for furnace to operate at high top pressure, capable of realizing optimal burden distribution, less investment and maintenance costs, etc. But why do most of blast furnaces in the world still remain using conventional bell top. One of the concerns is that current bell-less tops still have some shortcomings:1) The height of a current bell-less top might be lower than three or four-bell top or two-bell plus valve seal top, but still much higher than an ordinary two-bell top.2) The gearbox for driving the rotating chute is positioned onto the lip of the furnace. It is subject to attack by crude hot bf gas. Continuously pumping cooling gas (pressurized nitrogen or clean bf gas) into the gearbox is indispensable to withstand such a harsh working environment. Therefore, a plant furnished with blower8 and its ancillaries has to be built, It involves a large sum of investment and much expense in its annual running costs.3) Although the current bell-less charging device as a means of controlling burden distribution possesses a wide range of freedom, it is difficult to realize optimal burden distribution. There are some large blast furnaces realized better burden distribution, but sophisticated control means is indispensable so that the investment of control means is much higher."

Jan 1, 2000

By Binxu Zhaug, Mark Jolly, Xiaojun Dai

"In conventional investment casting process of aluminium alloys for the application of the aerospace industry, to assure the quality of the final casting, usually the foundry uses large runner system which results in low yield, high energy consumption and high GHGs emission. In one case of this investigation, the yield is between 5 ~ 10% which means that the current casting process wastes large amount of energy and generates lots of scraps. By applying a new casting method, the bulky runner system and the melting/holding time are significantly reduced, the quality of the casting is improved, and in the meantime the related energy consumption and GHGs emission are significantly decreased. In the investigation, the energy efficiencies and GHGs emission between the current and traditional processes are calculated and compared.1. IntroductionAs one of the conventional casting process, Investment Casting Process (ICP) and its applications can be traced to thousand years ago [l]. In current casting industry, ICP still plays an important role in the production of small and precious castings with high quality requirements in automobile and aerospace industries. Both casting quality and manufacturing costs which mainly consist of energy costs have crucial effects on the competitiveness of castings in the market. In the production of aluminium alloy castings using ICP, the energy cost and energy efficiency of a casting facility depend mainly on the efficiency of its melting and heat treating performance. In association with the two performances, more than 60 % of the total process energy costs are symbolised in a typical casting facility [2]. Additionally, in conventional ICP of aluminium alloys for the application of the aerospace, to assure the quality of the final casting, typically the foundry uses huge runner system including big risers/feeders which cause low yield, creates lots of scraps and generates high energy consumption. Consequently, there are huge opportunities for casting industry to choose the best practices for potential energy saving. Furthermore, the reasons such as the stringent limitation of environmental legislation in Europe and the pressure of the rising energy price force the casting industry to reduce the energy consumption and greenhouse gases (GHGs) em1ss10n."

Jan 1, 2012

By R. Colás, A. Salas, M. P. Guerrero Mata, R. Garza

"The use of the finite element method (FEM) for studying the plastic behavior of metals has become a common practice over the past few years, because it has been proved to be a good means of evaluating processes parameters, and predicting and improving processes, avoiding the traditional trail and error technique. FEM was used via a commercial package (Abaqus) to create two dimensional models to simulate uniaxial tensile tests for a galvanized low carbon steel. The aim of the work was to analyse the plastic behaviour of a distribution of grains on the zinc cover of a set of galvanized low carbon steel samples. A mesh with lines 2 mm apart was drawn on one of the faces of the samples that were deformed at room temperature, at constant crosshead speed, stopping the deformation at different times. Before and during the stops the deformation measurements were recorded for further calculations in an image analyser in order to compare these with computational predictions, as well as validate the numerical model. The results of this study can be extended to other testing conditions, besides the model can be used for obtaining constitutive equations of the materials.INTRODUCTIONThe use of the finite element method has been widely spread during the last two decades in most engineering areas, it is a good means of obtaining approach values at a first try [1-4]. Thanks to the software and hardware developments it is now possible to run huge problems within hours or minutes, making the technique more accessible and useful for the industry.The aim of this work is to create a finite element model for the uniaxial simple tension test, and compare the results with some experimental results, and asses the validity of the model.The plastic behaviour of the materials with FEM has been studied for a long time [5] and there is always something new to learn about this behaviour of the metals in particular, as well as to characterized new materials and alloys [6,7]. The tension test has been used since XIX century to get knowledge of the materials [5,8], it is the test that has been used the most and the only that is fully standardized, although it has the limiting of low strains, it is still the most widely used, especially in the industry.Two different finite element models in two dimensions (2D) have been developed, one called the mesh model and the other one the grain model, attention was focused on the geometry and strain prediction. The model is validated with experimental test, by using the data and directly comparing it with the numerical predictions. All the tests were carried out at the same constant crosshead speed at room temperature. An analysis of the grid distortion using FEM and analytical methods has been carried out."

Jan 1, 2001

By Xue Wang, Callie Babbitt, Chelsea Bailey, Matt Ganter, Gabrielle Gaustad, Brian Landi

"Current trends, motivated by fossil fuel dependence and unprecedented greenhouse gas (GHG) emissions, show lithium-ion batteries (LIBs) emerging as a competitive energy storage technology due to higher power and energy densities compared to Pb-acid and Ni-metal hydride chemistries. These trends may be of concern, however, as environmental impacts are not well understood for either the LIB itself, or for the nanoparticles consumed or released during the battery's production, use, or end-of-life. This study combines economic modeling, dynamic material flow analysis, and fundamental material characterization methods in order to quantify some of the economic and environmental trade-offs for LIBs at their end-of-life. As expected, results show that as chemistries transition from Li-Co based cathodes to Li based Fe, Mn, and S cathodes, LIB recovery value correlates to the value of the raw materials used. These initial results aim to inform collection policies being proposed currently as well as enable future deployment of novel recycling techniques.IntroductionGlobal fossil fuel dependence and unprecedented GHG emissions have led to increasing attention on energy alternatives, for both electricity production and personal transportation. However, development of renewable energy systems is contingent on concurrent technological development of energy storage systems, primarily batteries used for power grid load-leveling, renewable energy storage, and hybrid and battery electric vehicles. In this sector, lithium-ion batteries (LIBs) are emerging as a competitive technology due to higher power and energy densities compared to lead-acid and nickelmetal hydride chemistries[!]. LIBs represent close to 20% of the total rechargeable battery market and 75% of the portable rechargeable battery market, which is the fastest growing segment of the rechargeable battery market, with a 20% global growth in 2008 [2].This surge in production ofLIBs indicates a looming waste problem; total waste from Li-ion batteries has likely grown substantially from the 500 metric tons estimated in 2003 [3]. Figure IA shows the substantial increase in world-wide lithium production that has occurred in the last several decades with batteries making up the largest share of applications (Figure lB). California and New York state legislators have attempted to proactively address this looming waste by issuing diposal bans on rechargeable batteries in their states[4, 5]. However, quantification of the costs involved in collection, transportation, and processing of these materials has not been examined in depth."

Jan 1, 2012

By J. D. McCain

Magma&apos;s San Manuel smelter has adopted new operating techniques resulting in 21% increased productivity and 87% reduction in lost time accidents. Reverberatory furnaces were converted to coal firing from expensive natural gas and fuel oil. Slag and matte flow problems and safety were improved by implementing hydraulic slag stopping and matte tapping machines. Coordination of furnaces, converters and acid plant was improved by using a computer-aided converter controller/scheduler function. Manual mudding of converter lips after each collar pull was replaced with a gunning system for coating the mouth castings. One converter punch car was automated using robotic technology. An automatic anode take-off was installed with fewer moving parts and a mechanism for ear twisting one cell contact. Anode copper refining was improved by replacing propane/hydrogen mixtures with high pressure/velocity natural gas tuyeres. Improved converter scheduling increased acid plant production 43% with more autothermal operation time. Six dedicated computers/microprocessors are utilized for automation, data acquisition, process monitoring and on-line air quality information for the Supplementary Control System.

Jan 1, 1983

By P. L. Sibrell

The U.S. Bureau of Mines has tested cyanide leaching for recovery of palladium (Pd) from spent petroleum processing catalysts. Three different catalyst samples were supplied by a spent-catalyst processor. These catalysts consisted of a zeolite base and contained 0.4 to 0.7 pct Pd. During alkaline cyanide leaching, the catalysts exhibited ion-exchange properties due to their zeolite matrices. Hydrogen ions were released from the zeolite in exchange for sodium ions in solution, resulting in a significant decrease in solution pH. This could present a safety hazard because of the potential for release of toxic hydrogen cyanide gas. A pretreatment .step where the catalysts were contacted with a 1.0M sodium hydroxide solution was found to prevent the pH shift from occurring. Following the sodium hydroxide pretreatment, two stages of leaching at 160 °C with solution containing 1 pct sodium cyanide and 0.1M sodium hydroxide gave at least 75 and up to 95 pct Pd recovery. The Pd was quantitatively recovered from the leach solution by thermal decomposition in an autoclave at 250 °C for 1 h. The Pd content of the precipitate was over 50 pct. Thermal decomposition also decreased the total cyanide content of the barren solution to less than 0.2 mg/L. The catalyst leach residues passed the Federal Toxicity Characteristic Leaching Procedure and the California Waste Extraction Test, indicating that landfill disposal of the leach residues would be acceptable.

Jan 1, 1995