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By N. Panteleeva, E. Konoplev, I. Michailova, S. Titkov, S. Aliferova, T. Gurkova, T. Chumakova

Cationic flotation using alkylamines and their derivatives as collectors, and characterized by high selectivity of mineral particle separation, is finding ever growing industrial application. In recent years the industrial application has been initiated of new cationic collectors - alkylmorpholines. Efficiency of cationic surfactants operation as collectors is dependent upon their colloid and sorption properties and the availability of silicate .carbonate rock-forming mineral impurities in the ore, which sorb the cationic collector. Investigations have been carried out on the influence of frothers and organic depressors with various compositions upon physical-chemical and flotation properties of alkylamines and alkylmorpholines. On the basis of these investigations requirements for organic depressor were developed and new flotation reagents were proposed (V-1 frother and KS-MF depressor). The use of new reagents enables one to decrease considerably the consumption of expensive cationic collectors and to enhance the floatability of coarse mineral particles. Data of new reagents industrial application is presented. The reagents developed can be used for flotation processing of other ores.

Jan 1, 2003

By Y. J. Ferdosi

This paper presents the outcomes of the preliminary investigation focused on the potential usage of Electrochemical Impedance Spectroscopy (EIS) in minerals processing. Currently, Electrochemical Impedance Spectroscopy has been successfully employed in the characterization of multilayer structures formed as molecules adsorb on flat surfaces and is commonly used in bio-related research. Few studies have explored the application of EIS in minerals processing, particularly for mineral particles and flotation systems. In the first series of tests, the impedance response was investigated as a function of particle size, shape and hydrophobicity using model quartz particles. The particle size fractions and the shape were found to contribute to the impedance response. The more hydrophobic quartz particles resulted in a higher impedance values. Further tests involved pure sulfide minerals including chalcocite, bornite, chalcopyrite and pyrite. The AC impedance measurements were conducted as a function of collector (sodium ethyl xanthate) dosage. The AC Impedance data was modeled using the combination of reference circuits. It has been shown that adsorption of collector onto sulfide minerals surfaces results in a higher magnitude of impedance. Increasing the collector dosage resulted in an increase in AC impedance for chalcopyrite, while a decrease was observed for chalcocite. Significant variations in impedance were exhibited by bornite and pyrite with a gradual increase in collector dosage.

Sep 1, 2012

By Thenepalli Thriveni, Seong-Young Nam, Nam-Il Um, Joobeom Seo

In the present work, we report a novel microstructure of synthesized scalenohedral PCC (precipitated calcium carbonate) without any additives by a simple and ecofriendly carbonation process carried out in a liquid-gas system on the crystal growth of the scalenohedral calcite phase. Especially, the process parameters of Ca(OH)2 concentration and CO2 flow rates were investigated to enhance the sensitivity of the process. The highest average length of the scalenohedral calcite was obtained at pH 6.0, temperature 450C, Ca(OH)2 concentration 0.2M, CO2 flow rate 80mL/min, and total volume 1L. The utilization of flue gas-derived CO2 from coal fired power plants could be a form of carbon capture and storage using carbonation reaction with scalenohedral PCC. Finally, the synthesized scalenohedral PCC was used as a filer for ONP recycling. We demonstrated all these experiemnts at semi pilot plant scale.

Jan 1, 2014

By T. N. Matveeva, L. B. Lantsova, N. K. Gromova

"Multimetal gold-antimony ores are complexed processing products, since they are characterized by veindisseminatedsulfide mineralization with fine-dispersed submicroscopic gold, low content and uneven distribution ofAu, which is concentrated together with iron sulfides (pyrite, arsenopyrite, pyrrhotite). Such ores are classified asrefractory ones and characterized by low gold recovery rates during cyanation. A particular feature of gold-antimonydeposits is the presence of antimony in industrial concentrations therein, along with gold that significantly increasesthe value of these deposits. The main antimony mineral is antimony sulfide - antimonite (stibnite). Gold-antimonyores undergo flotation concentration with producing collective gold-containing concentrates or gold sulfide andantimony concentrates. The purpose of the work is an experimental study of the flotation separation mechanism ofsulfide minerals of copper, antimony and arsenic using tannin-containing modifiers during processing of multimetalgold-bearing ores. During the research it was established that for the selective separation of antimony and arsenicsulfide minerals into concentrates of different kinds, it is possible to use vegetable reagents capable to be selectivelyadsorbed on the arsenopyrite surface. Using the laser KEYENCE VK-9700 and electronic LEO-1420 VP INCA-350microscopy methods, it has been established that the film of a vegetable modifier was not washed off with water andfixed firmly enough on the surface of the polished sections of arsenopyrite. In the X-ray spectrum there are C and Obands related to the reagent structure. The vegetative reagent is fixed both on the pre-adsorbed phase of the collectorand on the areas free from the collector. On the polished sections of antimonite before and after a contact with thetannin solution, only partial adsorbed tannin phases are detected, which disappear as a result of subsequent washingwith water.The reported study was funded by RFBR according to the research project ? 16-05-00646 ?."

Jan 1, 2018

By Zoran S. Markovic

The extensive laboratory investigations were carried out in order to determinate behavior of sulphide and nonsulphide copper bearing particles during the flotation. The present ore sample were contained 0.55% Cu with 20.1% of nonsulphide copper in it and gangue material with higher contents of alumina about 19.07%. In this paper will be presented some results such as: effect of particle size, pH and applied collectors. The main goal was in application of collectors S-7518, as well as mixture of KEX and Z-96. Z-96 is a product from Chemical Industry Zupa Krusevac which was used as auxiliary collector in mixture with xanthates. The best results were done with this mixture in ratio KEX / Z-96 as 77/23 % in area of oxidized minerals flotation, but the collector S-7518 was achieved better results in sulphide mineral flotation. The S-7518 has better selectivity between copper minerals and pyrite comparing to mixture of KEX/Z-96 in mentioned optimal ratio. Flotation recovery and copper grade in concentrate were studied by flotation kinetics tests.

Sep 1, 2012

By S. K. Chaurasiya

o meet the ever increasing demand of iron oxide feed stock for rapidly growing domestic steel industries and to effectively manage the depleting reserve of high grade lumpy iron ore, Pelletization of iron ore fines/slimes are expected to play a dominant role in the near future. Use of pellets will also enable the blast furnace operator to achieve higher levels of productivity with lowering of operating cost. The effective utilization of Iron Ore Slimes is important not only from the point of view of optimum utilization of Iron values in the mined ore but also for preventing environmental pollution. A significant amount of slime is being accumulated at the tailing dam of one of the iron ore mines and with the present scale of operation the tailing dam will be filled in another 10 years. Hence to increase the life of tailing dam and for better utilization of the iron values a study has been carried out for the suitability of pellet manufacturing with slimes and fines at our laboratory. The pelletization studies are aimed for optimization of various parameters for production of Blast furnace/ DR grade pellets from beneficiated slimes and Fines. This paper attempts to describe the production of blast furnace grade pellets from beneficiated slime and fines and its characterizations.

Sep 1, 2012

By József Faitli, Barnabás Csoke, Károly Solymár, Zoltán Hatvani, Dimitri Papanastassiou

"Grinding has a significant economic impact on ore dressing/processing, therefore the sizing of mills has an outstanding role.In most cases, the sizing of dry or wet mills for ore processing is primarily based on the determination of the Bond grindability index, using the Bond-Kjos-Rowland relations. In several cases, grinding takes place under conditions different from these and the grinding conditions have a great influence on the post-grinding process. This is particularly true for the grinding of bauxites where grinding takes place in alkali, often in higher temperature (up to 100 ºC) in alkali Liquor. So it is necessary to develop a testing method providing a reliable grindability index even under these special circumstances (grinding in alkalis medium at different temperatures) and allowing a more precise mill sizing. The new heated mill is suitable to determine the grindability index under temperature-controlled circumstances, in liquids with different temperatures (water, alkali). This paper presents in detail the equipment, the conditions (parameters) of the testing process for wet and alkaline grinding, the measuring results and the conclusions."

Jan 1, 2003

By Jochen Petersen, Steven Bradshaw, Guven Akdogan, Ngoie Mpinga, James Mwase, Jacques Eksteen, Cornelius Snyders

"The platinum group metals (PGMs) and associated minerals are particularly refractory to most traditional direct leach processes. However, the remoteness of many new ore deposits, socio-political risks, the scarcity of skilled labor and constraints on the availability of water and electrical power makes it increasingly more difficult to implement the conventional mill-float-smelt-refine process routes to extract and refine PGMs in remote areas. This paper discusses a process to extract PGM’s from low grade ore and concentrate using a sequential stage heap leach process entailing heap bioleaching and high temperature cyanide leaching, and evaluates the feasibility of implementing a carbon-in-pulp process to recover the PGMs from the pregnant leach solution. The heap bioleaching extracts the base metals in an acidic sulfate medium using a mixed culture of thermophiles. After heap bioleaching the heap is reclaimed, rinsed, agglomerated and restacked for high temperature cyanide leaching where the cyanide liquor is directly heated via solar energy in panels. Palladium, gold and platinum are recovered during the cyanide leaching stage. The pregnant leach solution was evaluated for potential carbon-in-pulp adsorption and subsequent elution similar to gold processing. The kinetics of adsorption and elution compared well with gold adsorption and elution."

Jan 1, 2014

By M. Panayotova

Most of the quantity of the water soluble xanthates, used in mineral flotation, is consumed in the process. However, the residue amounts are water contaminants downstream the mineral processing operations and can be toxic to aquatic biota at concentrations of 1 mg/L. In order to be able to discharge water from tailing ponds to natural water bodies the concentration of xanthates has to be decreased. The present paper studies the uptake of potassium ethyl xanthate by directly modified with copper and lead ions natural zeolitic rock, without passing through zeolite transformation into homoionic form. Modified zeolite exhibits high, comparable with powdered activated carbon of chemical purity grade, capacity to remove potassium ethyl xanthate from model wastewater, with pH in the range of 7?9 and pollutant concentration in the range of 10-150 mg/L. The pollutant immobilization is fast. Both Cu and Pb modified zeolite behave as selective with respect to xanthate in the model wastewater, and Cu-modified zeolite possesses higher selectivity. The equilibrium is best described by the Freundlich equation. Keywords: xanthate, wastewater, modified zeolite

Sep 1, 2012

By Darryel Boucher, Raymond Langlois, Neil Rowson, Kristian Waters

The Knelson Concentrator is a centrifugal gravity concentrator composed of a high speed rotating bowl into which a mineral slurry is fed. The rotational motion creates a centrifugal acceleration up to an equivalent of 200 G. Under this acceleration, particles enter fluidised riffles along the side of the bowl, with the fluidisation allowing for the substitution of dense material for less dense. The separation mechanism is not fully understood and questions remain on the optimal residence time, slurry feed parameters and bowl surface profile to achieve a better separation. The positron emission particle tracking (PEPT) technique has been applied to record the motion of a -1700+1180 µm particle of a quartz-gold matrix, labelled with 18F radioisotope while it undergoes concentration inside a 3" laboratory scale Knelson Concentrator (KC-MD3) operated at 60 G. The slurry used was composed of quartz and magnetite. Particle trajectories during the first stage of the concentration process where the heavier particles centrifuge through the increasingly dense slurry towards the riffles of the bowl are shown with respect to time. This work reveals new information on particle motion inside the Knelson Concentrator and the results will be used for validation of developed separation model as well as optimisation of a centrifugal concentrator’s performance.

Jan 1, 2014

By G. Pahomova

"It developed an alternative to traditional flotation enrichment refractory of complex lead-zinc ores to obtain conditional lead and zinc products. The scheme involves the use of the processing method of gravitational enrichment of the primary cycle and the combined gravity-flotation-hydrometallurgical in finishing. The method has a high level of comprehensive utilization of mineral raw materials in relation to the elements that are extracted in the process of enrichment in lead concentrate, and the increase in recoverable value of processed ores. INTRODUCTION The primary source of lead are complex sulphide lead-zinc ore, lead ore actually rarer. The value of lead and zinc ores (except lead and zinc) is determined by the presence in them of a wide range of associated components: silver, contained mainly in galena; gold; bismuth in the form of its own minerals, but is associated with galena; cadmium contained mainly in the sphalerite; indium, thallium and gallium contained in sphalerite and galena; selenium and tellurium are present as impurities in the sulfide, tellurium is also found in the form of its own minerals. Of note harmful impurities antimony, which is often associated with lead sulphosalts and arsenic, having a substantially own minerals. By quality (content of lead, or the total content of lead and zinc) lead-zinc ores are divided into rich, ordinary and poor; by oxidation - to sulfide (with a lead oxides content less than 15% and zinc oxide content less than 10%), mixed and oxidized (50% oxide); the latter have a subordinate importance as a source of zinc and lead. Traditionally, the most contrasting technological properties of sulfide ores of nonferrous metals considered flotation properties, which determines the priority in the selection of flotation technology of their enrichment. Other methods of enrichment - gravity (jigging and enrichment in heavy suspensions), radiometric sorting (separation) are used as preliminary operations whose main purpose is to increase the content of lead and zinc in the ore sent to flotation, as well as the removing of part of empty rock in dumping tails prior to flotation. Effective implementation of these methods is possible at large size emphasizing in the ore of lead and zinc minerals, which is typical of the rich ores and which so far mainly worked. At the same time, non-ferrous metal ores (polymetallic, lead-zinc, copper-zinc, etc.) have a sufficiently high contrast to gravitational properties since ore minerals have a higher density compared with a rock minerals. But the gravity of the practice of non-ferrous ores enrichment is not widely used, despite its high degree of environmental safety and lower cost expensive."

Jan 1, 2018

By G. Mucsi

This paper deals with the laboratory investigation of cathode ray tube (CRT) glass based glass foam, a relatively new product so called ?Geofil bubbles?. The main process engineering material properties of raw materials, such as particle size distribution, moisture content, density and specific surface area are shown. Then the preparation of raw cathode ray tube glass waste is presented including the following steps: crushing in impact crusher, grinding in laboratory scale ball mill, mixing, pelleting and sintering. We found that it was possible to produce foam glass (with proper mechanical stability and particle density) from the investigated waste CRT glass. The material characteristics of the final product strongly depend on the sintering conditions. Optimum conditions were determined particle size fraction was found to be 4-6 mm, temperature 800 0C, residence time 7.5 min. Keywords: waste CRT glass, grinding, pelleting, sintering, glass foam

Sep 1, 2012

By S. V. Balikov

A close association of fine gold with pyrite and arsenopyrite is observed at many gold ore deposits. Gold forms and gold distribution in sulfides of different deposits were studied. A comprehensive method including optical spectrum analysis, X-ray diffraction analysis, high-temperature X-ray diffraction analysis, scanning electron microscopy and X-ray microanalysis was used for the de-tailed investigation of the defectiveness of the structure of pyrites from different deposits. It was shown that gold content in pyrites varied from 1.5 g/t to 100 g/t compared with 30 g/t to 230 g/t in arsenopyrites. The nature and arrangement of inner inclusions of foreign minerals in pyrites as well as occurrence of fractures and macro- and microdefects were examined. Iron, sulfur and arsenic contents in all pyrite samples were determined. Chemical composition of the detected inclusions was defined. Parameters of submicroscopic structure of pyrite were estimated using X-ray Fourier line shape analysis. Estimation of real structure characteristics with calculation of submicroscopic D-blocks and root-mean-square lattice deformation 2()evalues was performed. Defectiveness of the pyrite structure can be defined by the following parameters: K?1 and K?2 reflection resolution and its intensity within high Bragg angles; S content to Fe content ratio; the arsenic content and the local variation in its concentration within the pyrite grain; the size of submicroscopic blocks and the crystal lattice disturbance value. The performed analysis showed some relationships between these parameters and refractoriness of the pyrite concentrates. It was observed that at S/Fe ratio close to or higher than stoichiometry and at a low arsenic content (less than one per cent) pyrite concentrates were not refractory. The analysis results showed that concentrates of the Beryozovskaya gold plant (0.02~0.07 As%) and concentrates of the Kommunarovskaya gold plant (less than 0.05 As%) as well as some pyrites from the Sukhoi Log gold deposit had the same characteristics. It was found that average arsenic content did not excess 0.2 per cent. Arsenic distribution within the grain of all these pyrites was uniform. At S/Fe ratio lower than or close to stoichiometry and at high arsenic content (more than one per cent) and significant variation in its distribution within a pyrite grain the pyrite concentrates are refractory. Such pyrites are typical for the Sukhoi Log, the Bakyrchik and the Mardzhanbulak gold deposits. Direct correlation between arsenic and gold contents, in particular, in fine grains of pyrite was observed by many researches. This correlation was explained by impregnation of arsenopyrite which normally contains more gold than arsenic pyrites. The analyses results showed that no arsenopyrite impregnation was found: arsenic distribution within the grain was uniform but its concentration varied greatly. Such pyrite concentrates are more refractory. This paper presents the results of analyses of sulfides to determine the amenability of the associated gold recovery by hydro- and pyrometallurgy.

Jan 1, 2014

The challenges of nature for the recovery of metals for a sustainable future continue to present in diverse ways. Base metal deposits are becoming lower grade and more complex. Rare earth metal demand is soaring and must certainly be met from new sources outside of China. Precious metals have soared in value due to increased industrial usage and the importance of these metals as financial instruments. Many of the future sources of precious metals are complex and difficult to process. The field of hydrometallurgy plays an important role in providing technology for extraction of these metals for a sustainable future. Selected examples from the base, rare and precious metals fields will be used to illustrate how current developments are providing metals for our future. The recovery of rare earths by beneficiation, leaching, purification, precipitation will be described from a multi-mineral deposit in Canada. The recovery of metals from complex base and precious metal ores may be accomplished using chloride ? assisted high temperature pressure leaching. Finally, by way of example, the enhanced Galvanox? process for treatment of chalcopyrite concentrates using silver-activated pyrite as a catalyst will be illustrated. This process offers a viable alternative to the conventional smelting of chalcopyrite copper concentrates.

Sep 1, 2012

By Girolamo Belardi, Silvia Serranti, Giuseppe Bonifazi, Roberta Palmieri

Ore textural and structural characterizations play a fundamental role in any preliminary study (i.e. comminution, classification, separation) addressed to the design and set up of beneficiation flow sheets. The possibility to utilise automatic tools able to perform a classification, and a quantitative description, of the mineralogical and petrographical characteristics of raw ore samples thus represents an important step to define, to control and to verify the entire set of parameters, ore-texture-related, that can affect the final beneficiation results. The procedure usually adopted is based on the analysis of polished sections and more in details the recognition of the different mineralogical species and associations and the measurements of some quantitative parameters estimating both the geometrical characteristics of each species and the possible spatial relationships between them. This approach, originally carried out by experts, utilising optical and/or electronic microscopy, was ‚replaced? during the years by more and more sophisticated devices integrating analytical facilities and acquired data processing. Such integrated analytical devices formed the breakthrough platforms into what is now known as modern Process Mineralogy. In this paper the possibilities offered by chemical imaging based devices and techniques, to perform ore minerals recognition/classification, and to perform their topological assessment, are presented. Tests have been carried out and are discussed in order to analyze the problems related to the development of suitable and low cost strategies addressed: i) to realize a full mapping of ore minerals/gangue inside selected samples, ii) to define the optimal data-flow handling to optimize the speed of processing versus the quality of the results and iii) to start to define logics and procedures finalized to implement innovative smart detection engines, chemical imaging based, for mineral processing addressed to perform both a preliminary characterization of the ore, at laboratory scale, and a further possible control of the different processed minerals flow streams.

Jan 1, 2014

By M. Kanuchová, J. Briancin, M. Achimovicová

"Faculty of Mining, Ecology, Process Control and Geotechnology, Technical University, Košice, Slovakia An industrial eccentric vibratory mill was used for direct and short-time mechanochemical reduction of ilmenite concentrate (FeTiO3) and anatase (TiO2) with magnesium metal powder in order to reduce Fe and Ti resp. and hereby to convert them to the more soluble phases suitable for further hydrometallurgical processing. X-ray diffraction analysis of FeTiO3 after 60 min of milling with Mg confirmed the presence of Fe0 and Mg2TiO4 phases and for TiO2 after 180 min of milling the new TiO and MgO phases have appeared. X-ray photoelectron spectroscopy has detected Fe0 (metal) and Mg2+ species which are corresponding to the product of FeTiO3 mechanochemical reduction. The product of TiO2 mechanochemical reduction has revealed XPS spectral lines corresponding to Ti2+, Ti4+ and Mg2+ species on its surface. Morphology of mechanochemically reduced samples was studied by scanning electron microscopy analysis. Subsequent leaching of mechanochemically reduced FeTiO3 and TiO2 was performed in dilute HCl and H2SO4 at 80oC and compared with mechanically activated samples. The recovery of Ti has reached 100% for FeTiO3 and 79% for TiO2 after 60 min of leaching. Based on this study the flowsheet for possible processing of natural refractory titanium ores patented by author was adapted and documented. INTRODUCTION Ilmenite (FeTiO3), along with rutile (TiO2) represents the most important titanium resource necessary for titanium industry, for production of titanium metal, alloys and pigment grade TiO2 which are becoming more important and versatile for various industries such as an aircraft and aerospace, navy, chemical, automotive, medical and offshore wind industries, for machine and plant engineering and architecture as well, mainly due to high corrosion resistance. Pigment grade TiO2 is utilizing in pigment, plastic, glass, paper and rubber industries (Zhang, 2011). There are obvious research efforts for development of the potential alternatives to the expensive thermo-chemical commercial processes of titanium raw materials processing. Zhang (2011) has summarized conventional thermo- a electrochemical processes which involved a combination of pyrometallurgical, hydrometallurgical and electrometallurgical technologies and highlighted the improved hydrometallurgical routes promising for commercial application in the future. Such improvement could also be mechanical activation of FeTiO3, TiO2 by high-energy milling which causes their structural disordering, the changes of physical and chemical properties, consequently and has a positive effect on the dissolution kinetics (Achimovicová et al., 2014a, 2017, Baláž, 2008). The various types of mills such as a planetary ball mill, a vertical ball mill, a drum mill, an attritor were used for mechanical activation of FeTiO3 as a pretreatment process for subsequent leaching (Achimovicová et al., 2014)."

Jan 1, 2018

By L. Ya Agapova

Emissions from pyrometallurgical processing of copper concentrates are usually subjected to wet scrubbing. The washing sulphuric acid so produced contains up to 0.2 g/L of rhenium, which is recovered by solvent extraction in the form of crude ammonia permeate (NH4ReO4). The mother liquor, obtained from the sulfuric acid wash, contains up to 35 g/L of rhenium and significant amounts of impurities. Crude rhenium salt is commonly processed by double recrystallization to produce marketable salt. A ton of high grade NH4ReO4 can be produced using 3.0-3.5 m3 of mother liquor. We propose an efficient technology of mother liquor pre-treatment aimed at removal of water-soluble organics with subsequent electrodialysis. Electrodialysis of mother liquor in a multichamber electrodialyzer resulted in the production of pure rhenium acid, from which a marketable NH4ReO4 is precipitated using ammonia solution. Multiple steps of recycling consisting of dissolution of NH4ReO4 salt, rhenium acid production from NH4ReO4 salt by electrodialysis and precipitation of NH4ReO4 from rhenium acid made it possible to upgrade the purity of obtained rhenium compounds by 1-2 orders of magnitude. A rhenium metal powder of 99.997% purity was produced by high-temperature reduction of high-purity NH4ReO4 with gaseous hydrogen. Rhenium metal powder of high purity can be produced from sulfate solutions of NH4ReO4 by non-platinum anode-based membrane electrolysis processes also. Keywords: rhenium, mother liquors, membranes, electrodialysis, rhenium acid, ammonia perrhenate, reduction, powder, electrolysis

Sep 1, 2012

By Lei Pan, Roe-Hoan Yoon

"Direct force measurement for bubble-particle interaction has been difficult due to bubble deformation, which makes it difficult to know the separation distances between the two macroscopic surfaces. In the present work, we have developed a method of monitoring the deformation accurately, while directly measuring the interaction forces. In effect, we can ‘see’ bubbles interacting with mineral surfaces under different hydrodynamic and chemical conditions and determine both the hydrodynamic and surface forces involved. In the present work, a high-speed camera has been used to record the optical interference fringes of a thin liquid film (TLF) of water formed on a mineral surface. The recorded fringes are then used to reconstruct the spatiotemporal profiles, from which one can determine the hydrodynamic pressure using the Reynolds lubrications theory. From the forces directly measured in the present work and the hydrodynamic pressures obtained from the fringes, we have determined the disjoining pressure. The results show that air bubbles interacting with hydrophilic surfaces form stable TLFs with zero contact angles. The TLF formed on a hydrophobic surface thins fast, form a ‘pimpled’ film, and ruptures to form a finite contact angle. The new information obtained in the present work may be useful to better understand the role of hydrodynamic and surface forces affecting bubble-particle interactions."

Jan 1, 2014

By Mohan Ram

Structural impurities in the crystal lattice of rock phosphate of Indian origin is a great challenge for beneficiation and practically possesses remote scope of upgradation to the desired level for industrial utilization. There is a wide occurrence of rock phosphate in different parts of India with different characteristics viz. siliceous, carbonaceous and ferruginous. The structural cationic replacement in the composition of apatite is due to the exchangeable cations present in the external impurities associated with the rock phosphate ore. The Indian rock phosphate ore from Purulia district, West Bengal is characterized as unusual structural composition due to the exchangeable cation in its composition. The elemental distribution of ore exhibits the disproportionate ratio of P2O5 and CaO which is 5.88: 3.31 in reference to the theoretical composition of P2O5: CaO in apatite which is 4.23: 5.55. The substitution by trivalent Al+++ cations within the structure of apatite in place of divalent Ca++ is found upto 18% and substitution of exchangeable cation in place of PO4 and F ion by CO3/SO4 is found upto 0.1% and OH ions upto 0.2% respectively in a lattice of apatite thereby diluting the grade of rock phosphate and restricting its industrial use even after beneficiation. This paper reveals the unusual compositional features of rock phosphate under study and is a guideline to the mineral industries using such rock phosphate. Keywords: external impurities, exchangeable cation substitution, structural compositional features, electron probe micro analyzer

Sep 1, 2012

By L. A. Nemchinova, M. A. Arustamian

"For a long time tailings piles of mining and smelting complexes have met the eye being a prospecting feedstock source for many industries. Nowadays, 6.5 million tons of copper and cooper-zinc processing tailings are stockpiled in the Urals annually, as there is no technology of its processing to provide a full and complex metal extraction within mining and processing operations. In spite of large volumes of mining wastes, not more than 20% of annual overburden, approx. 10% of processing wastes, approx. 40% slags (1) are involved into processing.Based on today’s complex of economic, environmental and social challenges of ore processing, waste processing technology using existing capacities is a burning issue. Mining wastes characteristics (including fine dissemination, variability of physical and chemical properties of mineral surfaces under impact of oxidizing, leaching, etc.) predetermine challenges arising out of its involving into processing and justify high capital intensity of new construction or reconstruction projects followed by replacement of existing processing lines with new ones.In this paper, the authors propose flotation technology for mature tailings of copper, copper-zinc and polymetallic ore processing. The technology developed provides for upgrade of existing process flowsheet diagrams at minimum costs to produce additional saleable products including low-grade copper concentrate, saleable zinc concentrate and gold concentrate thus facilitates sustainable use of depleting minerals and operational efficiency due to cost-efficient processing of already mined materials, being in fact, final semi-products located near existing operations. This is particularly important for operations with standby capacities and not engaged workforce."

Jan 1, 2018