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By Yong Liu, Peng Qian, Shu-Feng Ye, Shao-Jun Chu, Pei-Wei Han

"Chromite with a low mass ratio of Cr to Fe (Cr/Fe ratio) was treated by the carbochlorination method using solid chlorinating agent (MgCl2 and CaCl2) and carbon in the present paper. The results showed that iron could be selective removed mainly in the form of FeCl2. The removal of iron was indirectly, which consisted of the decomposition of solid chlorinating agent to release Cl2/HCl and the carbochlorination of FeO•Cr2O3 by Cl2/HCl and C. The Cr/Fe ratio increased as increasing temperature from 700 ? to 900 ? in air atmosphere, while the tendency was opposite in N2 atmosphere. The removal efficiency of iron by CaCl2 was better than that by MgCl2. At last, a new pelletizing process was proposed to treat fine chromite with a low Cr/Fe ratio based on carbochlorination method, which could produce the high quality roasted chromite pellets with higher Cr/Fe ratio and compressive strength. INTRODUCTION Chromite is mainly used for the production of ferrochromium. A high Cr/Fe ratio (>2) of chromite is usually required to meet the technical specification of ferrochromium.(Gasik, 2013) Attentions have been attracted to the economic and efficient methods for the recovery of chromium from lower-grade ores as the higher-grade ores become depleted. However, the Cr/Fe ratio is difficult to improve through the conventional beneficiation methods (such as gravity concentration, flotation) due to the spinel composition, although beneficiation methods could increase the metal content of chromite ores by removing gangues.(Nafziger, 1982) The main industrial mineral of chromite is (Fe,Mg)O•(Cr,Al,Fe)2O3, which belongs to spinel magnetite.(Liu, 2013) Iron should be selectively removed through the structural dissociation of spinel to increase Cr/Fe ratio.(Nafziger, 1982)"

Jan 1, 2018

By Gabriela Pino, Maurício Torem, Diego Veneu

Because of its simplicity, economy and biocompatibility, research regarding the use of microorganism for decontaminating heavy metals produced by many industries is an area of growing interest. Also, there is a stringent need for the control of toxic metals produced during various production processes and released into the aqueous environment in order to avoid damage relevant to soil or groundwater contamination. Among the available treatment technologies, sorptive flotation has been considered as a promising alternative for the wastewater treatment. In the present study Streptomyces lunalinharesii strain was applied as bioreagent for the removal of copper, cadmium and zinc. The removal of those metal ions depends mainly on the respective pH value, influencing the aquatic speciation during the process, as well as the zeta potential of the system and biomass concentration. Langmuir and Freundlich isotherms have been depicted. Dispersed air flotation was applied as the subsequent separation method for harvesting the suspended metal laden microorganisms, following the biosorption of copper, zinc and cadmium. The investigated parameters (in batch mode, laboratory scale) were in this case the saturator pressure, the coagulant concentration and the recycled flow. Applying the optimum defined conditions, over 60% removal of metal ions have been achieved in one stage and simultaneously, quantitative separation of the used (metal-loaded) biomass has been obtained.

Jan 1, 2014

By C. Y. Sun

Flotation of chalcopyrite and unactivated malachite with xanthates (ethylxanthate, butylxanthate, octylxanthate and dodecylxanthate) is studied in this paper. Minerals interacted with xanthates are detected by FTIR, and simulated by molecular mechanics. It shows that chalcopyrite can be floated with 4 kinds of xanthates, and unactivated malachite can?t be floated with ethylxanthate but can be floated directly with later 3 kinds of xanthates while characteristic absorption peaks of those four kinds of xanthates are all detected by FTIR on chalcopyrite and malachite surface. After simulating the interaction between xanthate and mineral, it shows that H2O and OH-can interact with chalcopyrite and malachite, and their interaction energy may be so called energy bulwark which must be overcome by collector when collector interacts on minerals; the two sulfur atoms in xanthate group interact with copper and neighbor iron atoms on chalcopyrite. It also shows that molecular mechanics results with logP of collectors can interpret the mechanism of xanthate-mineral on atom scale.

Jan 1, 2014

By F. O. Milovich, V. A. Ignatkina, L. A. Samatova, E. D. Shepeta

"The aim of the research was to increase technological parameters of the flotation of finely disseminated scheelitecarbonate ore using selective reagent regime.In the studies the monomineral fractions of scheelite and calcite; samples of the scheelite-carbonate ore of the Primorsky deposit with the range of the carbonate module 3-65 were used. A carbonate module of ore is the ratio an initial assay of calcite to an initial assay of scheelite. Sodium oleate, iso-decyl alcohol, water glass, calcium chloride, soda or sodium hydroxide as flotation reagents were used. The flotation method in the Hallimond tube and in a mechanical cell, an adsorption method for study the kinetics of adsorption of oleate and isodecyl alcohol and its combinations on scheelite and calcite, IR spectroscopy including ATR to study the composition of surfacecompounds were applied. Selective reagent regime may include two ways - a combination of collectors or a modification of depressants of calcite and other gangue minerals. On one hand the combination of sodium oleate and higher fatty iso-alcohols of fractions C12-C16 in the rough scheelite flotation to reduce the flotation activity of calcite has been studied. On the other hand depression of calcite flotation by calcium chloride with water glass into rough flotation was used; modified the steaming cycle by Petrov's method applying change the concentration of water glass and other. Fatty iso-alcohols can adsorb on the surface of the calcite that reducing the adsorption of sodium oleate and floatability of calcite has been fallen. Their co-adsorbing with oleat on the scheelite surface were support the hydrophobization and flocculation of slime particles of scheelite. Flocculation of the particles of scheelite leads to increased up 3 times of the recovery of scheelite from the slime class, and calcite change up only 1.4-1.1 times it’s recovery.The growth of the carbonate module more than 11 is decreased the assay of WO3 in the scheelite concentrate of selection cycle."

Jan 1, 2018

By A. V. Bauman

"Important for thickening processes is the ability of slurries to form under certain conditions aggregation and sedimentation stable systems. Substantial part of difficult to sediment solid particles in such systems may be in colloidal state. The technique to study the sedimentation and aggregative stability of the slurry developed by the author with co-authors makes possible to define kinetics of changes in the aggregative stability of the system with solid phase varying concentration in it and produce data on sedimentation stability of the system in preliminary investigation of the thickening process. Research of aggregative and sedimentation stability of the slurry complement standard methods of laboratory studies to prevent errors in development of water-slime thickening balance and water circulation to design new and upgrade existing processing plants. Statistical analysis of process audits of more than one hundred upgraded and newly commissioned processing plants carried out in recent fifteen years showed that more than two-thirds of problems arising in commissioning the processing plants are associated with misdesign and errors in thickening and water circulation system. Among the main reasons of process design failures are: non-conformity of actual characteristics of the raw material to design characteristics, low quality of preliminary studies at the stage of sedimentation process simulation, design failures, wrongly selected equipment for the thickening and water circulations systems. As of today a number of problems associated with laboratory studies of sedimentation process, first of all, with interpretation of precipitation curves produced at the stage of laboratory refinement of the thickening process have been pinpointed. (Bauman A.V. Outstanding issues in design of thickening and water circulation diagrams in processing plants // Ore processing. 2016. ?3 P. 58-62) ?????? ?.?. ?????????? ??????? ?????????????? ???? ???????? ? ??????????? ?????????????? ??????. // ?????????? ???. 2016. ?3. ?. 58-62))"

Jan 1, 2018

By M. L. Torem, R. H. Rojas, A. G. Merma

"Fine particle recovery by conventional flotation processes is very low mainly due to the low probability of bubble/particle collision and adhesion. In order to solve the problem of low particle recovery, several flotation technologies have been developed to increase bubble/particle collision efficiency. Among these technologies, the electroflotation process stands out. This process has advantages in the generation of microbubbles (<100 µm) and in the production of different amounts of hydrogen and oxygen microbubbles. These advantages favorably influence the fine particle floatability, due to the greater probability of particle/bubble collision and adhesion. The electroflotation tests were conducted for a hematite/sodium oleate system in a Partridge-Smith modified electroflotation binary cell of 0.38 L usable volume. The sodium oleate concentration, particle size, pH and current density were evaluated. Satisfactory results in the recovery of hematite were found at pH values of 7, reaching hematite floatability of 99% and 90% with hydrogen and oxygen bubbles, respectively.INTRODUCTIONThe flotation recovery of fine and ultrafine particles is normally very low and is caused by several factors, among them, the low probability of collision and adhesion bubble-particle, the difficulty to overcome the energy barrier (entrainment and entrapment), low selectivity, surface oxidation and mineralogical changes (Schulze et al., 1989; Waters et al., 2008; Shahbazi et al., 2010). This problem can be overcome by decreasing the bubble size or by increasing the apparent particle size. However, it is worth noting that the use of small bubbles or micro bubbles also involves some disadvantages such as their low momentum resulting in a slower process comparing with conventional flotation. Electroflotation is an attractive alternative for treating fine particles with small bubbles less than 100 µm, generated by the electrolysis of water. Electroflotation is one of the variants of the flotation process, where the gaseous phase is produced by electrolysis of an aqueous solution, generating oxygen and hydrogen bubbles (Sarkar, 2010; Gupta and Ali, 2012). These smaller size bubbles allow the recovery of fine particles by increasing the collision efficiency. This process is versatile and competitive in relation to other techniques such as dissolved air flotation and dispersed air flotation because the electroflotation units are smaller, more compact and require less maintenance and less operating cost than other flotation units (Zouboulis and Matis, 1995,). In addition, the electroflotation process is a clean technique and provides results in a short time, requiring only the investment in the electroflotation cell construction stage and the choice of the electrodes (Ketkar et al., 1991; Sarkar et al., 2010; Sun et al., 2011). In this sense, this study assesses the effect of pH, particle size and sodium oleate concentration on electroflotation of hematite fines."

Jan 1, 2018

By L. X. Zhang

It is very important to improve the A/S of the bauxite to keep sustaining development of Chinese alumina industry. This article summarized the issues of several desilication technologies, which are named as normal flotation, reverse flotation and bi-flotation. Normal flotation has been got industrialization because of technologic advantages. The campaign experiment of reverse flotation which has principle advantage was carried out in 2004, and bi-flotation which is combined the advantages of both the normal flotation & reverse flotation has the most attractive future. The development of bauxite flotation will be focused on multi-utilization of bauxite by mineral process technology and corresponding equipment which satisfied with the flotation technology and reagent.

Jan 1, 2014

By Egbert Burchardt

"Some of the challenges faced by the mineral industry in the future are the need to process low grade ores at the lowest operating cost, to deal with elevated energy cost and to address scarce water resources in some regions of the world. These challenges will increase the demand to develop highly energy-efficient and less water-consuming mineral processing systems. Experience from other industries suggests that HPGRs could help to achieve these goals, due to their high energy efficiency and their ability to be used as dry grinding systems. Historically, HPGRs have been used mainly as tertiary crushers in mineral applications for the production of ball mill feed. In the cement industry, however, HPGR systems have been successfully applied for grinding limestone, clinker and slag to a final product fineness (p80) of between 30 and 90 µm without the need of downstream ball milling. The total energy consumption of HPGR finish grinding systems in the cement industry has been found to be 30 to 50 % lower than in ball mill systems. This leads to the question of whether the same methodology can be adopted in the mineral industry. Such a step would require the use of dry rather than wet grinding systems. Traditionally, dry grinding systems have been only an exception in mineral processing, since most post grinding processes are wet. However, there are successful - mainly ball mill based - dry grinding examples in gold, nickel or iron ore. Experience from some of these dry grinding references are summarized in this paper. In addition, this paper explores two future-orientated questions: What opportunities does HPGR finish grinding offer the mineral industry? What are general conditions and challenges for adopting this technology for mineral applications?"

Jan 1, 2014

By I. Yu. Rasskazov, A. V. Rasskazova, N. M. Litvinova, N. A. Lavrik, V. G. Kryukov

The possibility of the intensification of the gravity processing of complex iron-manganese ore, which contains the finely dispersed inclusions of gold and platinum is shown. Clear mineral fractions of precious metals were sorted out of the different types of ores (quartz-braunite and carbonate- magnetite ore, ferruginous quartzite, carbon-containing shale, breccia-limestone and dolomite breccia). Composition and structures of precious-metals particles was detailed. The industrial content of platinum and gold was found. Precious-metals mineralization is character for all types of ores. High content of platinum is indicated in the carbonate-magnetite (up to 11.3 mg/kg) and quartz –braunite (up to 10 mg/kg) types of ore. Gold is presented in the ferruginous quartzite (up to 1.29 mg/kg) according to the data of the reduced mineralogical analysis. The composition of native platinum depends on the type of the ores: 1) quartz-braunite type contains isoferroplatinum (Pt3Fe) with Cu, Rh, Ir, Ru; 2) carbonate-magnetite type contains isoferroplatinum with Cu, Sn, Ni, Rh, Ir, Os; 3) pyritic-carbon ore contains isoferroplatinum with Sn, Ni; 4) ferruginous quartzite contains isoferroplatinum without admixtures. The ultrasonic treatment of mineral aggregates (P = 41.5 Watt, I = 15 W/cm2) made possible the liberation of fine particles of precious metals. Smooth-shaped or crystalline mineral aggregates are effectively liberated after acoustic treatment. Their surface is freed from impurities. The aggregates with the complex form and structure, which consist of the numerous plates and the grains, are not effectively liberated from impurities. It is shown that the ultrasonic treatment of aggregates with the fine inclusions of precious metals contributes to the liberation of the particles of platinum and gold and intensification of the gravity processing of refractory ore. This approach contributes the increase of the raw-material base of precious metals.

Jan 1, 2018

By Bern Klein, Givemore Sakuhuni

Flotation is the dominant base metal extraction technique and it requires ore to be ground below the liberation size for effective recovery due to its dependence on mineral surface properties. For a poly-metallic ore, differential hardness of constituent minerals leads to over grinding of softer minerals before the harder minerals are fully liberated, which makes selection of a target grind size complex, and the complexity increases when treating leaner ores. Flotation recovery deteriorates above 100 and below 10 microns causing significant loses of valuable minerals in most flotation circuits. Although enhanced gravity concentration is known to be effective at recovering particles above 100 microns, which are difficult to hydro-dynamically transport, exploiting differential specific gravity for base metal separation was not an option in the past. This was partly due to the absence of high mass yield gravity techniques. The advent of continuous gravity concentrators with flexible mass yields, in the past two decades, has necessitated investigation of possible base metal applications. The Knelson CVD, one of the continuous discharge centrifugal concentrators, has an established application niche for sulphides associated with gold. However, its base metal applications have never been rigorously tested. Considering the dependence of flotation recovery on particle size, continuous discharge centrifugal concentration can be integrated in flotation circuits to capture flotation non-recoverable coarse particles. This paper explores how particle size, liberation and mineral hardness influence application of continuous centrifugal technology to regulate galena deportment in a polymetallic base metal plant. The results show that particle size affects galena recovery more than liberation. In view of these results, the CVD can be integrated in the primary grinding circuit to pre-concentrate the heavy sulphides at a coarser grind size with potential grinding energy savings.

Jan 1, 2014

By K. Hori

In this study, the determination of optimal conditions for jig separation has been investigated with a TACUB jig separator. The TACUB jig, from which a Batac jig originated, is a useful gravity separator that is effective to separate crushed solid wastes as well as coarse ores. A mixture of crushed polyethylene (specific gravity 1.3) and polyvinyl chloride (specific gravity 1.5) was separated by a batch TACUB jig by varying the frequency (wavelength) and the amplitude (pulse stroke length). It was found that the sample particle layer in the separation chamber was fluidized without turbulence by the rising water pulse resulting in the separation. However, a too strong water pulse reduced the efficiency of the separation of the particles. The results indicate that the specific velocity of the rising water is necessary to fluidize the particle layer without turbulence to separate the particles. The expansion ratios of the thickness of the particle layer in rising flows were measured in a cylindrical column. The pressure losses by the particle layer were calculated from the expansion ratios and the velocity of the rising flows by Ergun?s equation. The curve of the pressure loss vs. the velocity of rising flow showed a maximum point corresponded to the point of fluidization. The velocity of a rising flow on the point of fluidization provided the optimal separation condition.

Jan 1, 2014

By S. A. Bogidaev, M. Yu. Tiunov

"The paper describes the results of the flotation tests with complex rare metal ores from deposits in the Trans-Baikal Territory. Correlations between the quality of produced wolframite, hubnerite and mica concentrates with or without the presence of various alkaline modifiers are determined. Commonly, rare metal ores contain minerals of comparable value to main elements recovered in processing plants using gravitational methods. The paper describes the results of flotation recovery of valuable minerals – main and associated – from gravity tailings of deposits in the Trans-Baikal Territory. It was found that gravity tailings from the first deposit contained fine-grained wolframite, mica (muscovite, lepidolite etc.), feldspar; hubnerite, scheelite, beryl, fluorite, rubidium-containing muscovite from the second deposit, correspondingly. This paper presents the results of the stage flotation tests with the production of tungsten (wolframite, hubnerite), fluorite and mica concentrates from gravity tailings. Figure 1 demonstrates the flowsheet of tungsten ore minerals and mica stage flotation from gravity tailings of the first deposit.Wolframite can be floated using oleic acid with the presence of soda ash, a complexing collector (IM-50), under slightly alkaline conditions in combination with a nonpolar collector [1, 2, 3, 4]. The study included wolframite flotation using the combination of two alkaline modifiers. Flotation of wolframite was performed after pulp desliming, using tall oil saponified with soda ash. The recovery of wolframite in the concentrate of rougher flotation reached 80-85%; the concentrate contained up to 1% of tungsten oxide that can be upgraded to a saleable product using gravitational methods. This procedure was tested during flotation of wolframite, tantalite-columbite and pyrochlore, and provided high performance regardless of a season, at pulp temperatures of 8-10°C, though fattyacid collectors are significantly inefficient at such low temperatures due to low solubility, dispersion and increased collector consumption, consequently. The introduction of two alkaline modifiers in pulp appears to improve these characteristics.The first stage of the tests was focused on increase of iron-bearing tungsten ore minerals recovery from gravity tailings and stabilization of the cold pulp flotation process."

Jan 1, 2018

By Alexey P. Tatarinov

Under modern economic conditions in Russia, gold heap leaching is the most effective way of investing into gold-mining industry. Gold is recoverable from small-size deposits, low-grade ores from oxidation zone, cut-off grades, and overburden rocks using heap leaching. This technology is cost-effective and allows a saleable metal to be obtained within the first year of operation. The investments for heap leaching are lower than those of for a traditional plant technology. Production cost per one gram of Au is 5-7 times lower than that of during a plant flow sheet. A seasonal development of mines can be possible. With reference to this, heap leaching resembles the technology of placer deposits development. One of the major advantages of heap leaching is the form of the product. Gold can be obtained as dissolved in a clarified PLS, which allows the further quick treatment. The amenability of ores to heap leaching depends on their mineralogical composition. Oxidized porous ores with a good access of a lixiviant to valuable particles can be treated without pre-crushing. Clayish minerals are often found in oxidized ores with free gold. In order to build ground for heap, several major methods combined with various pad materials are used. These methods have been used at many plants and are reliable. The development of heap leaching technology for gold ores for the deposits from Yakutia, Zabaikalsky region, Primorye region, Uzbekistan, Tadjikistan, and Kazakhstan began in the 70s. However, it has been commercially used only since 1990. The first heap leach plants were built and commissioned in the USSR in 1991 at Vassilkovsloye deposit (Kazakhstan) and at Maiskoye deposit in Russia in 1994. Pilot plant testing was conducted in 1996 using ores from Kuranakh ore field, deposits Phiskulturnaya-Kholodnaya and Lopukhovskoye from the Aldan region. After the first successful commissioning of heap leaching plant in Russia, this technology has been commercially applied for deposits. Every year 1-2 heap-leaching plants were commissioned. More than 30 heap-leaching plants have been commissioned both in Russia and in the former Soviet Union using technologies developed by IRGIREDMET. Keywords: cyanide leaching, heap leaching, ore, percolation, solutions, lime technology

Sep 1, 2012

By F. Waanders, Campbell. Q.

This project was specifically aimed at using increased acceleration separation, as a method to optimize the recovery of gold in an ore body mainly consisting of hematite where the specific gravity of gold is much higher in comparison to the carrying material, making it possible to separate gold from other materials like silica, base metals and their oxides, usually associated with gravitation-gold-recovery-processes. The ore body investigated in this project originated from a gold reef containing a large portion of gold locked inside the gold pyrite complexes, which was mined and treated in a conventional way. After gold extraction, the material was pumped to a tailings dump and the gold extraction of this dump was investigated. In order to assemble a concentration plant setup, the head grade and size distribution of the dump and bulk sample were determined accurately. Chemical analysis and mineralogical examination were done on a representative sample of the bulk sample, to determine the chemical composition of the material. The results obtained thereof were evaluated and a pilot plant was configured. A bulk sample was processed in the pilot plant and the results were evaluated. The results at optimum acceleration forces applied, resulted in a recovery of 5% of the mass, with a gold concentrate of 90 g/t Au, which represented 58% recovery of the gold. The hematite with high specific gravity as main phase positively influenced the high acceleration separation process. It proved that if the specific gravity of particles in a suspension were increased, high acceleration separation could be applied effectively to separate much smaller particle sizes.

Jan 1, 2014

By K. Malysa

Bubble collisions with ore grains and a selective formation of the bubble-grain aggregates are necessary steps for flotation separation of useful and gangue components of an ore. For the attachment of valuable mineral grain to the colliding bubble a liquid film, separating the bubble and the grain needs to rupture during short time of their collision. High hydrophobicity of the grain surface is favorable because stability of the separating (wetting) film is much lower at such surfaces, that is, the film ruptures faster and at greater thickness. Simultaneously, it needs to be kept in mind and taken into consideration that high affinity to air is a typical feature of hydrophobic surfaces. Thus, when the hydrophobic surface is immersed into aqueous phase the air can stay attached to such surfaces and affect kinetics of the bubble attachment. The paper presents results and analysis of dynamic phenomena occurring upon the collision of the rising bubble followed by its attachment to hydrophobic (Teflon) plates of different roughness. The influence of the Teflon surface roughness, solution concentration, bubble size and impact velocity on bouncing of the colliding bubble, time of the three phase contact (TPC) formation and drainage time of the liquid film, formed between the solid and bubble surfaces, is described. High hydrophobicity, as showed earlier (Malysa et al, 2005), does not assure that each collision leads to the TPC formation and attachment of the colliding bubble. Roughness is the parameter of crucial importance for kinetics of the bubble attachment to hydrophobic surfaces (Krasowska and Malysa, 2007; Krasowska et al, 2009; Kosior et al, 2011). Enlarged roughness of the Teflon plate, from ca. 1 to 80µm, results in shortening the time of the TPC formation (bubble attachment) by over an order of magnitude - from 105 to a few milliseconds only. Higher surface roughness means that larger amount of air can be entrapped in bigger scratches and cavities of the Teflon plate during its immersion into aqueous phase. Results documenting importance of the air presence are showed and mechanism of the air facilitated TPC formation and bubble attachment to hydrophobic surfaces is described. Keywords: bubble collisions, hydrophobic surfaces, teflon plate roughness, TPC formation

Sep 1, 2012

By Kilian Neubert, Hermann Wotruba, Henning Knapp

Sensor-based sorting has been integrated into more and more applications in mineral processing over the past decades. Various sensor types, such as line scan cameras, near infrared sensors and X-ray transmission sensors, allow the separation of a vast variety of raw materials. Sensor-based sorting has several economic benefits which can make the difference between an uneconomic operation and a profitable mine. Sensor-based sorters can be applied to fulfill various sorting tasks, such as waste rejection, product quality improvement and ore type diversion, and have a significant impact on the layout of the processing plant. Therefore, it is important to include sensor-based sorting into the planning of a processing plant at an early stage. To evaluate the applicability of sensor-based sorting for any specific ore type, it is currently necessary to provide several hundred kilograms of material for subsequent bulk tests. In exploration, ore samples are usually rare and only available in form of drill cores. The acquisition of drill cores is time-consuming and expensive especially for deposits in great depth. Hence, it is unfavorable to spoil valuable drill cores for bulk tests. This paper describes a methodology to evaluate the applicability of sensor-based sorting based on drill core analysis. That methodology offers the possibility to calculate the achievable performances of different sensor types for various grain sizes without comminution of drill cores. The general methodology is shown on basis of an exemplary test work on drill cores from a currently conducted exploration.

Jan 1, 2014

By M. Ghiani, R. Peretti, S. di Giovanni, G. Zonnedda, A. Serci

"An interesting occurrence of gold bearing ores of economic interest has recently been discovered in the Serrenti- Furtei district, central-southern Sardinia (Italy). The upper part of the orebodies are leaner and fairly porous, and are undergoing intense oxidation processes. In the lower parts sulphide ores predominate, chiefly enargite-luzonite and pyrite and these have a more compact structure. The passage from the oxidized to the sulphide zones, is rather irregular and difficult to delineate. The gold, generally occurring in its native form, is found in small grains. Mineral reserves in the area concerned were originally estimated to total 2.77 Mt: 0.63 Mt of oxide minerals with average gold content of 2.75 g/t and 2.14 Mt of sulphide ores with average gold grade of 3.18 g/t.Recovery of the valuable metals is a complex problem.The effectiveness of a variety of gold extraction techniques has been evaluated conducting tests on batches of ore representative of the different orebody depths obtained from core samples.The techniques investigated were: heap and vat leaching; flotation and flotation followed by leaching of the flotation tailings. The findings indicate that:• the gold contained in the ores in the upper oxidized zones of the deposit can be efficiently recovered by direct cyanidation via heap or vat leaching;• the sulphide ores in the deeper portions, that are not amenable to direct cyanidation but contain enargite concentrations of potential economic interest can be processed by means of flotation to produce a gold/copper bulk concentrate;• beneficiation of the difficult-to-treat minerals contained in the transition zone requires some knowledge of their intrinsic properties. A distinction should be made between the ores containing minor amounts of enargite which appear to be amenable to vat leaching and those with relatively higher enargite content which are processed using bulk flotation of the gold and copper minerals followed by vat leaching of the resultant tailings."

Jan 1, 2003

By M. Pischtschan, S. Belz, M. Perrucci

In High Pressure Grinding Rolls (HPGR), the material grinding takes place between the fixed and floating rollers. In this regard, the rollers start to wear over a period of time, which is impacted by for e.g.: ore characteristics, operating pressure, feed material size and non-uniform feed presentation across the roller width. HPGR operational experiences have shown that the rollers do not wear at the same rate. This differential wear rate over time leads to differences in the tangential speeds of the rollers, causing an uneven gap between the fixed and floating rollers in relation to the material. This unwanted but extremely common situation results in a less effective grinding process due to the fact that the slip between rollers is not optimal. As the rollers wear profile increases, the roller with smaller diameter starts to wear further, deteriorating the comminution efficiency up to a point where operators have to stop the HPGR to replace the rollers. Since the wear rate of the rollers is not equal, the replacement of the same cannot be properly planned so that their life-time are fully utilized. In this paper, a dynamic load share control with the use of ABB’s variable speed drive system is proposed, which provides the possibility to the HPGR operator to impact the roller wear in such a way that it equalizes the wear rate to a certain extent and extends the roller life time. Called RollXtend™, this solution includes a load share factor which can be parameterized based on the wear measurement performed manually during maintenance procedure. Additionally, this paper describes an automated load sharing concept based on a non-invasive wear measurement method. The partial results of the technology trial in a copper/gold mine are presented, which aimed at detecting stud damage and estimating the real rollers profile throughout their life time. The final objective of the pilot project was reduce the amount of planned and unplanned downtimes of the HPGR by increasing the rollers life time and avoiding catastrophic stud damages.

Jan 1, 2018

By D. Bastin, J. Frenay, J. Dassas

"The Luiswishi deposit belongs to the Cu-Co deposits of the Southern Group of the Katangian Copper Belt and is operated by a joint venture between EGMF (Entreprises Générales Malta Forrest) and Gecamines (Générale des Carrières et des Mines). The Cu-Co ore is beneficiated by the sulphidization process at the NCK (New Concentrator of Kipushi) at Kipushi.Sulphidization followed by flotation with sulphydryl collectors is a common practice for the treatment of oxidized base metals ores. This process is complex and its application at the industrial scale is quite sensitive. In Central Africa it is also a cost intensive treatment as the sulphidizing agent has to be imported. In order to improve the metallurgical performances and to optimise the economics of the process, a laboratory research program was carried out by the Laboratory of Metallurgy and Mineral Processing (MTM) of the University of Liège in close collaboration with EGMF and Gecamines. This program included the study of various flotation reagents as dispersing, depressing and activating agents.This paper presents the results obtained with the use of ammonium sulphate as activator of the sulphidized xanthate flotation. Although ammonium sulphate has been mentioned in the literature as a promoting agent of the sulphidized xanthate flotation of malachite, its effects on the flotation of cobalt oxides was not known.The testworks were carried out on various oxidized siliceous ore types from the Luiswishi deposit. A 1.7 l Agitair laboratory flotation cell was used. NaHS and potassium amylxanthate were respectively choosen as sulphidizer and collector. A mixture of gasoil and tall oil (90/10) was used as secondary collector. A multistage sulphidization was realised. Values of pH were followed during the different tests and an ion selective electrode Ag/Ag2S was used to control the Es potentiel evolution during the stepwise addition of the sulphidizer."

Jan 1, 2003

By J. Gebhardt, D. McBride, M. Cross, S. Gilbert

Heap leaching of ores containing chalcopyrite offers a low cost option to treat low grade complex copper sulfide ore bodies. However, the slow leach kinetics of chalcopyrite at ambient conditions typically results in unacceptably low recoveries. As the mineralogy of new ore deposits becomes more complex and the effects of gangue chemistry exert a greater influence on copper sulfide leach behavior, the control of leach reaction chemistry becomes more critical. Computational fluid dynamics (CFD) technology has been useful in the capture of multi-phase interactions and provides a path to simulate complex fluid flow, gas and liquid phases, through the heap, along with species transport. Coupling the flow models with the reactive mineral dissolution, and the sometimes competing aqueous chemical and solid-liquid reactions, yields a comprehensive model of the heap leach process. The leach kinetics of chalcopyrite dissolution in heap conditions is examined, and the incorporation of chalcopyrite leach kinetics in the CFD model is described. The application of the model to investigate optimization of the heap is discussed.

Jan 1, 2014