Search Documents

By V. Shumila, T. Butler

Microseismic monitoring systems listen to a rockmass and record ground vibrations associated with brittle rock fracture. Modern systems record continuously and can identify as many as one thousand small and possibly larger magnitude events occurring each day from induced stress change and redistribution. This paper presents examples of the real time use of microseismic information in mining applications. It shows how alerts can quickly identify large magnitude events or unexpected clusters of seismicity and how seismic re-entry protocol can help to improve safety decisions. Additionally, newly developed advanced analysis techniques applied to mine seismic data sets are shown including the use of clustering methods to see into a cloud of seismic data to identify significant activity and quantify possible planar features. The use of source parameter trend analysis is shown to be a beneficial method for interpreting changes in relative stress levels. Seismic moment magnitude distributions are analyzed using the TGR (Truncated Gutenberg Richter) and TMD (Tapered Moment Distribution) methods to estimate bvalue and expected maximum magnitude. Seismic hazard analysis is shown as a useful way to simplify a dataset and highlight seismic hot spots. The rockmass response to excavation is a complicated spatial and temporal process and microseismic monitoring is a method that can be used to help understand the location and mechanics of failure occurring in the rock ultimately helping to improve safety and productivity at a mine site.

Jan 1, 2015

By H. Sahay

"DISCLAIMER NOTICEThe views and conclusions contained in this presentation are those of the author and should not be interpreted as necessarily representing the official policies or recommendations of the Department of Mines and Energy, Government of Newfoundland and Labrador. ABSTRACTThis paper describes the main testing procedures that should be carried out to evaluate the capacity and capability of the service brakes on the large-size diesel-electric trucks now in common use at open-pit mining operations. Brake testing programs in general are described, and then consideration is given to different techniques of service brake testing, brake performance evaluation, braking energy and typical performance characteristics.IntroductionThe first diesel-electric truck with a capacity of about 85 tons was introduced in 1963 by Unit Rig and Equipment Company of Tulsa in cooperation with General Electric Company, who successfully developed and supplied the most important component- motorized wheels. Since then, its popularity and numbers have continued to grow, and now more than 3700 such units are in operation in mines around the world. In Canada alone, their number is more than 700, including about 150 in the Province of Newfoundland and Labrador. Similarly, their size has also grown from that initial capacity of 85 tons to 350 tons.Although the introduction of the electric trucks proved to be invariably economical, their indiscriminate use was not without severe consequences. Many runaways and even fatalities occurred when the dynamic retarder failed while the truck was travelling loaded down severe grades. The service brakes in such cases proved incapable of stopping runaway trucks, mainly due to their limited capability and the fading caused by excessive heat produced during the act of braking itself. This eventually led the various governments, the open-pit operators and the manufacturers to seriously question the braking capability as well as function of both service brakes and dynamic retarders. Extensive testing"

Jan 1, 1980

By Hooman Askari-Nasab

Open pit mine plans define the complex strategy of displacement of ore and waste over the mine life. The objective of the mine plan is to maximize the future cash flows within the technical and physical constraints. Various mixed integer linear programming (MILP) formulations have been used for production scheduling of open pit mines. In the MILP formulation the slope constraints guarantee that all the overlying blocks are mined prior to mining a given block. Traditionally, the slope constraints have been modeled with cone templates representing the required wall slopes of the open pit mine. The overall pit slopes constructed by these templates are a function of the width and height of the geological block model. Therefore, the overall slopes are fixed in one bearing. This paper presents a general MILP model for open pit mine scheduling with variable slopes constraints. The methodology utilizes a directed graph to capture the precedence of extraction of blocks and pit slopes in different bearings. Depth-first-search algorithm was used to traverse the graph for constructing the slope constraints in the MILP problem. TOMLAB/CPLEX was used as the implementation platform to efficiently integrate the mathematical solver package CPLEX with MATLAB. A case study on intermediate scheduling of an iron ore mine over twelve periods was carried out to validate the models.

Oct 1, 2009

By Arnfinn Prugger

"The construction of the new Scissors Creek shaft at the Rocanville mine, the first potash shaft successfully completed in Saskatchewan Canada since 1979, is summarized here. Located 15km from the existing Rocanville surface plant, this new 6 m inside-diameter, 1121 m deep service shaft was built for fresh-air ventilation and access. Shaft construction in the Saskatchewan sedimentary basin involves sinking through five different rock-types: glacial tills, shales, sandstones, carbonates and salts. The first four rock- types are all water-bearing, and the salts will dissolve in water. This results in five different sinking challenges and requires five different shaft lining designs. The upper 580 m of rock (the till – shale – sands sequence) was frozen before sinking, and grouting methods were used for water control through deeper carbonate levels. Challenges that were faced and overcome during shaft sinking are reviewed, and ideas that future operators working in sedimentary basin environments might consider in order to avoid these difficulties are discussed.INTRODUCTIONThe Nutrien Inc. (formerly Potash Corporation of Saskatchewan Inc. / PotashCorp) Rocanville potash mine in southeast Saskatchewan, Canada has been in continuous production since 1971. Devonian potash, formed approximately 380 Mybp, is mined in a sedimentary basin environment at approximately 1000 m depth below surface in this area of Saskatchewan. The predominant use for finished potash products is fertilizer: potash fertilizer is concentrated and nearly pure KCl (i.e. greater than 95% pure KCl). Currently 10 potash mines are in operation in Canada, all in Saskatchewan. In 2018 Saskatchewan mines produced ˜ 23 million tonnes of finished potash products, which is approximately 35% of World demand of ˜ 66 million tonnes for the year (e.g. Nutrien Inc., 2019).In November, 2007 it was announced that the Rocanville potash mine would be expanded to increase production from 3.0 Million tonnes per year (Mtpy) to approximately 6.0 Mtpy of finished potash products, requiring an increase in hoisting capability from approximately 9.0 Mtpy to over 18.0 Mtpy. The Rocanville potash mine has historically been accessed through two shafts: a production and ventilation exhaust shaft, and a service and ventilation fresh-air shaft located approximately 200 m from each other. All surface offices, processing facilities, etc. are situated near these original shafts.A very important part of the recent Rocanville expansion involved the construction of a new service shaft (6 m diameter, 1121 m deep) for fresh-air ventilation and access, approximately 15km west of the existing surface plant. Once this third shaft was completed in 2015, the historical service shaft was converted to a second exhaust and production shaft. Three shafts are now available for mine access, ventilation and ore hoisting at Rocanville. As of December 31, 2017, annual nameplate capacity for Rocanville was 6.5 million"

Jan 1, 2019

By G. C. Hodgson

Specification and Tests of Rope Wire Chemical Analysis: The range in composition of steel used in the manufacture of wire rope is as follows: Carbon 0 4 to 0.9 per cent Manganese 0 4 to 0.8 Sulphur Not above 0.04 Phosphorus Not above 0.04 The carbon and manganese content are varied according to the gauge of wire to be drawn and the tensile strength required. Generally speaking, best results are obtained from heats where the melt is not of too large a tonnage. The amount of reduction and patenting of the wire is left to the wire maker, who thus has a free hand in meeting the balance of the specification.

Jan 1, 1931

By Kamran Esmaieli

This paper investigates the behavior of ore pass walls under impact loads caused by material transiting through an ore pass. In particular it considers the influence of foliation in the rock mass surrounding an ore pass as both a triggering and accentuating cause of degradation. Based on empirical observations in several underground mines a numerical experiment was designed to understand the influence of rock mass foliation on impact-induced damage on ore pass walls. The distinct element method, and in particular the Particle Flow Code (PFC2D) was used to simulate three different rock masses surrounding an ore pass. Each simulated rock mass has similar properties but was defined by distinct dominant foliation (70o, 80o, 90o) along the foot wall. The numerical experiments investigated different scenarios whereby the walls were loaded by a projected rock fragment striking the foliated walls at a constant impact angle and velocity. The damage inflicted by the projectile rock fragment, on the foliated rock mass, was quantified using the number of impact-induced micro-cracks initiated on the ore pass wall. The results of the numerical analysis indicated that the presence of foliation resulted in greater damage zones in the surrounding rock mass. In addition, the extent of impact-induced damage to the ore pass wall increased as the angle of interception between the ore pass wall and the rock mass foliations decreases. This is in agreement with qualitative field observations.

Jun 1, 2012

By A. L. Mackie

Arsenic is a highly toxic element and a known human carcinogen. It is often a contaminant in mine water discharges, particularly from gold mining and roasting operations, and has been found at concentrations as high as 4 g/L. Increasingly stringent controls on the concentration of arsenic allowed to be discharged into the environment cannot always be met by current treatment processes and thus enhanced technologies are required to achieve low treated effluent concentrations at reasonable costs. A novel two-step physicochemical treatment process was developed and tested at the bench-scale using synthetic mine water solutions (SMWs) in order to reduce arsenic concentrations in treated effluent to exceed current discharge regulations. The process includes chemical coagulation with ferric sulphate and ballasted flocculation for enhanced solid-liquid separation. The SMW contained 59 ± 2 mg/L arsenic with a slightly alkaline pH. The effect of arsenic speciation on the process was tested by using either arsenite, As(III), or arsenate, As(V), in the SMW solutions. Tests were performed at cold temperature (3 ± 1 °C) to ensure the process? efficacy year-round in northern climates. Arsenic in As(V) SMW solutions was removed to a final total concentration of 0.0054 ± 0.002 mg/L, almost half the current recommended allowable drinking water concentration of 0.010 mg/L. As(III) was removed to a concentration below the Metal Mining Effluent Regulations? (MMER) current limit of 0.50 mg/L, to 0.32 ± 0.06 mg/L, with double the coagulant dose used in Stage 1 for As(V) removal. Oxidant addition at a concentration of 5 mg KMnO4/L in Stage 2 resulted in final total arsenic concentrations of 0.017 ± 0.002 mg/L and pH adjustment with lime in Stage 2 resulted in 0.0415 ± 0.0007 mg As/L in treated As(III) SMW. Both of these modifications to the process reduced arsenic concentrations to below proposed new MMER limits (i.e., 0.10 mg/L). This two-stage treatment process was shown to reduce arsenic concentrations to well below current treatment guidelines while reducing or eliminating chemical oxidant demand.

Aug 1, 2013

By James K. Gowans

"Cominco Ltd's Polaris Mine, located on Little Cornwallis Island, Northwest Territories (latitude 75degrees 30') went into production in late 1981, becoming the world's most northerly base metal mine. The concentrator, powerhouse, shops, offices, dry and warehouse, were uniquely designed and constructed on a 100f t wide by 400 ft long by 65 ft high barge. This process barge was constructed in southern Canada at Trois Rivières, then towed 3,500 miles into the High Arctic Islands and beached on Little Cornwallis Island.The paper deals with the original design philosophy, flowsheet and the initial year's operation of the Polaris process barge.IntroductionTo bring a mining property into production in the Canadian High Arctic, a company must deal with the harsh environment, the short shipping season and the high cost of labour. In trying to minimize the effect of these fact or s, the concept of a barge-mounted process plant was investigated as an alternative to the conventionally built concentrator. Cominco's previous experience gamed at the Black Angel Min e on Greenland's west coast suggested that this would be a practical alternative.The normal shipping season at Little Cornwallis Island is approximately six weeks long, from mid-August to the end of September. All equipment and materials must be delivered during the ""shipping window"". The logistics problems are enormous; if the conventional approach had been used the major process equipment would have been delivered to Little Cornwallis Island at the same time as the completed barge actually was! Construction would also be starting at the start of the worst climatic conditions, the Arctic winter. Nine months' production was gained by opting for the ""barge"" approach."

Jan 1, 1983

By David deVries, James Rajith, Paul Mascrenhas, Nurzhan Dyussekenov, Lawrence Hanschar

Kansanshi Copper Smelter commenced operation in March 2015. The smelter features four Peirce- Smith Converters (PSCs) operated in a three hot, two blowing configuration. This paper describes some of the process automation and design features implemented to maximize operational and environmental performance. To ensure that the converters were easy to operate, efficient, and were protected in emergency situations such as power failures or loss of tuyere air supply a significant focus was placed on automated sequences initiated by “one button” operator commands or otherwise automatically by the Distributed Control System (DCS). Examples include: main converter roll-in and roll-out sequences; emergency roll-out in the event of power failure; and the charging sequences for reagents (silica and reverts). Other automated features configured for the PSCs were specifically aimed at maximizing converter capacity and reducing the environmental impact from fugitive emissions. These features include: “one button” in-stack charging; automated restriction of blowing rate based on the available acid plant capacity; and fully-automated control logic for the Secondary Ventilation System. In-stack charging allows anode furnace oxide slag to be poured into the PSCs while the converters are still blowing and still sending off-gas to the acid plant. PSC Secondary Ventilation control logic was configured to require minimum input from the operators while ensuring maximum utilization of the available draft from the ventilation system. Highly automated PSC controls contribute to high utilization, averaging 41.2 in-stack hours per day. INTRODUCTION Kansanshi Copper Smelter (KCS) is located near Solwezi at Kansanshi copper mine in Zambia's Northwestern province. The smelter treats concentrate produced at Kansanshi mine as well as Sentinel mine located 150 km west of Solwezi. Four Peirce-Smith Converters (PSCs) are installed at KCS. The nominal capacity of each converter is to treat 350 t of copper matte and produce up to 250 t of blister copper per batch. Normally three PSCs are hot, with two able to operate (produce off-gas), and the third converter on hot standby. The fourth converter is normally under cold repairs. The blister charge size is relatively low for the matte charged due to the unavailability of tank house or other high copper scrap.

Jan 1, 2019

By Hoeve. J.

"In the unconformity-type uranium deposit at Midwest Lake, mineralization is associated with extensive host rock alteration, which affects the metamorphic basement as well as the overlying Athabasca Group sandstones. Host rock alteration is manifested by (I) transformation of clay minerals [kaolinite into illite and chlorite (sudoile)]; (2) bleaching due to removal of hematite from the lateritic paleoweathering profile and the overlying red bed, Athabasca Group sandstones; (3) loss of coherence of the sandstone resulting from corrosion of quartz cement; and (4) in the immediate vicinity of high-grade ore, development of a clay envelope due to residual enrichment of clay minerals caused by massive dissolution of quartz. Clay mineral transformation and bleaching are the most prominent and the most widespread alteration effects, forming haloes that extend for several kilometres along the strike of the mineralized structure and also constitute distinct alteration pipes that rise f or several hundred metres above the unconformity to be truncated at the present top of the bedrock.Although the two haloes are largely congruent features, cross-culling relationship s indicate that clay mineral alteration represents an earlier phase in the history of the deposit than the large-scale bleaching that gave rise to the superimposed bleaching halo.Because clay mineral alteration and bleaching are intimately tied to the mineralization and extend well beyond the limits of the actual orebodies, host rock alteration may be used as an ore guide in exploration and drill-hole evaluation. In this application a third hydrothermal discharge centre was identified, as yet untested for are, which is located between the hydrothermal centres associated with the two known orebodies of the deposit.It is estimated that host rock alteration may enlarge a potential drill-target by a factor 10 - 20X. Information on the configuration of bleaching haloes can be obtained from systematic core logging, whereas diagnostic clay mineral alteration is readily identified by means of automated, quantitative XRD techniques."

Jan 1, 1984

By A. Dahi Taleghani, Amir Shojaei

A continuum damage mechanics (CDM) based constitutive model has been developed to describe elastic, plastic and damage behavior of rock during drilling. In addition to inelastic deformations, this model incorporates rock anisotropies like toughness anisotropy due to the bedding planes orientation that is a common observation in soft Shales. The pressure sensitive inelastic deformation of porous rocks together with their damage mechanisms are studied for drained and undrained conditions. Fracture mechanics of microcrack and micro-void nucleation and their coalescence are incorporated into the formulation of the CDM models to accurately capture different rock failure modes. The performance of the developed elastoplastic and CDM models are compared with the available single cutter test data of a specific shale play and then the models are introduced into a commercial finite element package through user-defined subroutines. A workflow to derive the required model parameters is presented through inverse modelling of the single cutter test data. The developed CDM model outperforms the traditional discrete element and fracture mechanics approaches by removing stress singularities at the fracture tips and simulation of progressive fractures like formation of the cuttings ribbon without any essential need for remeshing. This model would provide a robust tool for modeling bit performance and rate of penetration using conventional elements of FEA with a reliable results and a computational cost less than similar computational techniques like discrete element methods.

Jan 1, 2015

By I. Imris

The chemical industries are using different type of catalysts, which after application usually produced many tons heap of residues. One of them is cupric oxide catalyst with high content of copper and silica. The recovery of copper from the waste has become major interest from a viewpoint of environmental protection and recycling of resources. The thermodynamic analysis and experimental results suggest that the copper from cupric oxide catalyst can be extracted by plasma reduction process. By plasma reduction process the inert slag and copper with following chemical composition: 99.04 % Cu, 0,042 % Fe could be obtained.

Jan 1, 2007

By H. Warren Newcomen, Dennis C. Martin

"This paper describes the investigation of a large, progressive slope failure on the southeast wall of the east pit at Highmont Mine, British Columbia Geotechnical investigation s consisted of geological and structural mapping, assessment of blasthole drilling records, review of rock core information, slope movement monitoring and back analysis of various possible failure modes. Climate records and mining history were also assessed to determine their relationship to slope movement .Analysis of movement monitoring records and geotechnical information indicates that the failure is deep seated. The upper portion of the failure surf ace occurs along clay filled discontinuities. The lower portion of the failure surf ace appears to occur through the highly altered rock mass. High groundwater pressures and mining at the toe of the slope are documented to have had a major influence on stability at various times during the failure. Stability analyses results are presented and possible remedial measures are discussed.IntroductionHighmont Mine is located near Logan Lake in the Highland Valley approximately 50 km southwest of Karnloops, British Columbia (Fig. I). Mining of the porphyry copper and molydenum ore bodies began in 1980. In May, 1983, when mining in the east pit had progressed to a depth of about 60 m (200 feet) , a failure (designated the Southeast Failure) began to develop in the southeast corner of the east pit. Subsequent mining to a depth of 110m (360 feet) was accompanied by frequent and substantial slope movements involving between 500000 and I 000 000 m3 of rock . The slope was monitored extensively to assess short-term movement trends for operational safety. Geological mapping, core logging and rock mechanics testing were used in conjunction with the long-term monitoring information to determine the failure mechanism, conduct stability analyses, assess the effects of instability on pit design and enable design and installation of remedial measures."

Jan 1, 1988

By G. W. Clark

"The mining of the ore bodies at Rabbit Lake has in the past been by the open pit method. This method is presently being used to develop the B-zone and will continue into the future with the development of two smaller ore bodies, the A-zone and D-zone. The Eagle Point orebody will be developed by an underground method which will provide production and employment into the next century.The ore bodies at B-zone, A-zone and D-zone are unique in that they are located under Wollaston Lake. To permit mining by the open pit method a steel-celled dyke has been constructed around the north end of the B-zone. This same dyking method will be used for the A -zone and D-zone. INTRODUCTIONMine development at Rabbit Lake commenced in 1970when a detailed engineering feasibility study established the viability of the Rabbit Lake deposit. In 1972 construction of the mill and camp site began. Construction materials were seasonally hauled to the site over a winter road until November 1973when the government of Saskatchewan completed an all-weather road to within six miles of the operation.In October 1974, stripping of the Rabbit Lake open pit began with the removal of overburden and lake bottom sediments from the previously drained Rabbit Lake. The first ore was processed by the mill in June 1975and by October the mill was producing three million pounds per year. The design capacity of five million pounds annually was first achieved in 1977 and maintained until 1981, when lower ore grades resulted in lower production rates .It was clear when mining at Rabbit Lake began that, without additional reserves, the Rabbit Lake operation had a life of less than 10 years. Exploration, therefore, continued in the immediate area in an attempt to discover additional uranium mineralization."

Jan 1, 1989

By B. M. Das, F. Claridge, V. K. Garga

Coal, as well as a large part of other minerals in Canada, is produced by surface mining methods. This has resulted in short and long-term accumulation of waste rock in dumps. Two main problems arise from the flow of water through these dumps: stability of dumps and the impact on stream flows. In recent years, a number of mines have started placing waste rock in valleys for general disposal or far constructing mine access road ways. All these have created challenges in the following areas: effective design of dumps and flow-through dams; stability monitoring of the structures; environmental impacts downstream by way of increased amount of fines in suspension, sedimentation, and toxic substances; and long-term status of flow and flood. Similar situations also exist in many civil engineering structures. This paper discusses the status of rock drains and the immediate and future research needs.

Jan 1, 1990

By Young Hyun Paik, Hyung Sup Choi, Yeun Sik Kim

The basic studies on the surface properties and flotation characteristics of ilmenite were made by electrophoretic, adsorption, contact-angle and floatability measurements. The isoelectric point of ilmenite is found to be at pH 5.6. By combining the results of electrokinetic studies and adsorption measurements, a clearer picture of the ilmenite-solution interface was observed. These findings were correlated with the floatability of ilmenite obtained by Hallimond tube tests. The general flotation characteristics of ilmenite are compared with those obtained for magnetite and rutile. It is indicated that the above three minerals, namely, ilmenite, magnetite and rutile, have very similar surface properties and flotation characteristics. Therefore, it is difficult to make an effective separation of these minerals by flotation. However, it is found that sodium orthophosphate acts as a selective depressant for magnetite in anionic flotation. Therefore, close pH control of the pulp in the presence of the phosphate ion enhances the possibility for a successful separation of these minerals.

Jan 1, 1967

By K. Shikaze

"For the last three years (1967-9) the value of the output of mineral resources in the Province of Ontario exceeded one billion dollars per year. To produce this great wealth, it was necessary for the mining industry in Ontario to dispose of an estimated 80 million tons of waste mill tailings. Some of these tailings were returned underground but the greater proportion was disposed of above ground in lakes, watercourses, marshy areas and in engineered impoundment basins. This volume of tailings, if accumulated in one location would cover an area of 1000 acres to a height of almost thirty feet. The provision of proper disposal of the waste mill tailings in a manner such that they will not create problems in the environment is one of the costs which must be borne from the extraction of such a wealth from our mineral resources. It is principally the potential water pollution which may occur as a result of the indiscriminate discharges of waste mill tailings which is of concern to the Ontario Water Resources Commission.ONTARIO WATER RESOURCES COMMISSIONThe Ontario Water Resources Commission was formed in 1956 and operates under the Ontario Water Resources Commission Act. The Act has been broadened and amended many times by amendments."

Jan 1, 1970

By S. Ando

The fatigue crack growth behavior of magnesium single crystal has been investigated, CT (compact tension) type specimens with different notch orientations were prepared. In the case of notch plane and direction are (1-210) and [10-10], fatigue crack propagates parallel to notch, From TEM observation, it is found that pyramial slips occures at the crack tip. When notch is normal to basal plane, a fatigue crack propagates [0001] and parallel to basal plane depending on stress intensity factor range, In the case of notch parallel to basal plane, a fatigue crack propagates through straight route with some {10-12} twin, Fatigue crack growth rate, da/dN of A- and B- specimen is lower than F-specimen with crack parallel to basal plane.

Jan 1, 2004

By R. J. Mitchell

"The use of hydraulically delivered classified tailings sands to provide ground support in large mining operations is still widespread despite recent developments of alternate backfilling methods and materials. The major disadvantages of the use of hydraulic fill are the costs and risks associated with slurry delivery. The main risk is that of bulkhead failure resulting from sand liquefaction due to insufficient operational control or due to dynamic loading from earthquake or rockburst. That risk may be eliminated by the pouring of a stiff cemented sand plug in the base of each stope prior to continuous fill pouring in that stope. An additional advantage of cemented plugs is that massive bulkheads are not needed. Instead, a temporary (removable and reusable) bulkhead can be used for plug forming.Physical model studies of fill pressures on a temporary bulkhead were carried out in a 3 m radius centrifuge facility. Fill pouring in-flight was carried out in order to model prototype stress paths. The results indicate that the average bulkhead pressure is likely to be less than 10 kPa under normal operating conditions and less than 20 kPa under the poorest anticipated operating conditions which include smooth walls, high slimes content and high water-content slurries. A portable bulkhead consisting of a central core and a surrounding sealing bladder was modelled and found to be effective. The use of different sizes of cores allowed the stress distribution adjacent to these bulkheads to be evaluated."

Jan 1, 1992

By H. N. Tran, D. Barham

"A systematic survey of the appropriate literature in terms of phase equilibria and possible reactions involving deposits in Municipal Solid Waste (MSW) incinerators are analyzed particularly with respect to the theoretical first melting points of typical ashes and the possible presence of a liquid phase at the temperature of ash-metal interface. Conclusions are drawn on the basis of the possible presence or absence of various metal chlorides and sulphates in such situations, and their effects on the problems of fouling and metal corrosion. From preliminary results, it would appear that ZnCl2 is unlikely to be present in any molten phase which causes corrosion because it evaporates rapidly from such liquids. It would also appear that PbCl2 and, by inference, ZnCl2 will sulphate at relatively low temperatures if the flue gas contains SO2 and O2.IntroductionMunicipal Solid Waste (MSW) incinerators produce fly ash which deposits on heat transfer surfaces throughout the furnace, leading to corrosion and loss of energy recovery efficiency. Despite a massive amount of research carried out on the subject of corrosion in MSW incinerators, the problem of corrosion of heat transfer metal is still with us, and no definite over-all cause and effect relationship has yet been identified. In order to make a contribution to the eventual solution of this problem, the authors have examined the problem from the beginning, using their knowledge of fouling and corrosion problems in black liquor recovery boilers as a starting point.The incineration of MSW has been used for many years to reduce the volume of material sent to landfill (ash volume compared to raw waste volume), and, in most cases, to recover energy at the same time by raising steam The steam may be ""low- or high pressure/ temperature"" depending on its end use. The higher the steam pressure and temperature, the greater seem to be the problems with corrosion of heat exchanger metal, presumably because the metal must withstand higher surface temperatures.The chemical and physical composition of MSW is extremely variable, not only on a regional basis, seasonal basis, and day-today basis, but also on a minute-by-minute basis, due to the inhomogeneity of MSW. This makes it extremely difficult to define cause and effect relationships, because both cause and effect are transient in nature."

Jan 1, 1991