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By Elaine R. Goetz

The eastern and southeastern regions of Ohio are part of Appalachian coal country, with a documented 1,300 miles of streams impacted by acid mine drainage. Since 1995, partnerships of local watershed groups, government agencies, private industries and universities have focused on the remediation of the affected waterways. The partnerships have spent $2.4 million annually in constructing and operating treatment systems such as wetlands, anoxic limestone drains, successive alkalinity production systems, steel slag leach beds, and lime dosers. These systems have been partially successful, and water quality has improved in the region, but no treatment has yet met the ultimate objectives of low cost, continual remediation. Our research group has investigated an alternative system for acid mine drainage treatment: electrolysis combined with pH adjustment to selectively precipitate recoverable, saleable metal products to offset the cost of treatment. We utilized a $0.2 million pilot facility constructed by the Wayne National Forest, in Nelsonville, Ohio, to process approximately 40 L/min of mine drainage from surrounding seeps. The pilot facility has multipurpose tanks that can be adapted to process acid mine drainage with different characteristics, such as high or low aluminum content or high or low carbonate concentrations. Sodium hydroxide was used for pH adjustment. Results indicate that saleable product can be generated with this treatment technology. In an initial, not optimized trial, one seep yielded 4.7 kg of dried 69 % iron oxide product from 10 hours of pilot facility operation, treating 23,000 L with electricity costs of $4.68. Dissolved iron concentrations in the water were reduced from 242 ± 18 mg/L to 2.8 ± 2.0 mg/L (99.0 % removal) while the initial acidity of 443 mg/L as CaCO3 was neutralized to an alkalinity of 160 mg/L as CaCO3. Iron oxide can be sold as pigment for an average of $1.47 per kg in the United States. Currently, approximately 80 % of all pigment used in the United States is imported, and there is incentive to purchase domestically recovered pigment. If the iron oxide from the pilot facility could be sold as pigment for $1.47 per kg, 43 % of the operating cost (raw materials, electricity and construction costs) of treatment could be offset by the sale of the product. Considering the cost offset, the electrolysis process shows potential as a sustainable low cost alternative for treating acid mine drainage.

Aug 1, 2013

By S. McPhail, D. Richardson, G. J. Simandl, C. Akam, S. Paradis, M. Yakimoski, A. Teucher, Y. Cui, F. Ferri

Historically, extracting dissolved solids from formation water was economically motivated. Today, main drivers are environmental benefits and regulations, as large volumes of water needed for hydraulic fracturing require treatment before reuse or disposal. The concentration of dissolved solids in flowback water increases with each use and may require treatment prior to disposal. Element recovery from produced water is not profitable unless market conditions are favourable, recoverable elements are abundant, and economical recovery methods are established. Sale of recovered materials could offset recycling and disposal costs. This paper describes markets for Cl, Na, Ca, K, Sr, Mg, Br, Ba, I, B, and Li, and their concentrations in produced water from oil and gas wells in British Columbia. It recommends revising sampling protocol for produced water.

Jan 1, 2018

By Damien Gaboury

"Two practical methods for correlating two or more diamond-drill core intersections, using a stereographic projection software are presented. The first may be used to establish if two or more vein intersections are correlative, based on their core angles and diamond-drillhole attitudes. The second method allows prediction of main vein attitudes from numerous intersections, based on a spherical density contouring projection. The methods are suitable for: (1) correlating veins in complex orebodies; (2) ascertaining lateral continuity of ore for reserve estimations; (3) demonstrating the hidden complexity of an orebody; and (4) correlating and interpreting various planar elements.IntroductionModern mineral exploration relies on diamond- drill core data and on the ability of geologists to interpret them. Drill core generally yields unoriented information, unless an expensive orientation device is used. As a consequence, strike and dip of planar elements such as lithological contacts or mineralized veins cannot be determined easily. This is particularly true for blind deposits (covered by thick overburden) and complex orebodies, where field data cannot support drilling interpretations. Such a problem has been addressed previously using two and three diamond drillholes and several solutions were proposed based on trigonometry, and geometric and stereographic projections (Mead, 1921; Wisser, 1932; Fischer, 1941; Stein, 1941; Bucher, 1943; Gilluly, 1944; Addie, 1962; Mills, 1963; Lyons, 1964). However, these solutions are time consuming and not relevant to present day computerized data plots."

Jan 1, 1997

By A. McLean, W. Q. Chen, W. Yan, M. Barati, Y. D. Yang

In order to maximally remove the harmful impurities phosphorus and reduce the loss of valuable elements from Si-based alloy for production of solar-grade silicon, thermodynamic properties of the Si-based alloy were studied. In this work a new model, the Molecular Interaction Volume Model (MIVM) derived from statistical thermodynamics, was successfully used in the Si-based and Si-Fe-based alloy. The calculation started from binary Si-Fe, Si-P and Fe-P systems, then the thermodynamic parameters of ternary systems could be derived based sub-binary systems. Using the activity coefficients of the elements in the Si-based alloys and the saturated vapor pressure of the pure substance of the components, mass fraction of P during vapor-liquid equilibrium can be calculated. The calculated thermodynamic parameters were compared with experimental data available in different publications, and it is found that the thermodynamic parameters calculated using MIVM model are in good agreement with the measured results. The calculated result shows that the mass fraction of phosphorus during vapor-liquid equilibrium of Si-Fe-P melt increases with the increasing phosphorus content and decreasing temperature. This is an important direction for experimental practice in vacuum or low-pressure EML refining of ferrosilicon for potential production of solar-grade silicon without significant vaporization loss of valuable element.

Jan 1, 2015

By N. Bahrani

Photogrammetry surveys were used to document a footwall slab failure that occurred at a surface coal mine located on the eastern slope of the Rocky Mountains. Photographs taken before and after the failure provided the pre- and post-failure geometry of the slope and the failed slab. A 2D finite element model was constructed using slope profiles. The model contained joint elements that represented the bedding surface upon which the slab slid and the model was used to analyze the footwall slope. The in situ stresses, rock properties and the bedding surface shear strength and stiffness properties are discussed. The process of mining out a valley and exposing a highwall was modelled. As expected, elastic valley rebound occurred in the model, but shear stress and shear displacement reversals along the slip surface were also observed. The modelling results provided new insight into shear strength degradation that occurs when the pit floor approaches and then passes a specific point in the highwall.

Jan 1, 2009

By Longjiang Li, Song Mao, Zhengyang Qiao, Qin Zhang, Guizhou University, Ling Wang

"After a study on the advantages and disadvantages of flotation column, according to the limitation of ordinary flotation column only is used for a flotation of microgranular minerals, the paper designed a new kind of layered convection coarse particle flotation column.Using a bauxite to test the rationality of the flotation column.The test results show that the new layered convection coarse particle flotation column is feasible.It has certain advantages about coarse particles flotation.INTRODUCTIONFlotation column has many advantages, for example,a simple structure, high efficiency and energy saving, the obvious advantage of fine particles flotation , the index superior and so on. The advantages gradually getting people's recognition. Research of flotation column has been a breakthrough, however, due to it only is used for the flotation of microgranular minerals, and the microgranular mineral particles will lead to a series of problems, and makes the processing cost is increased. Due to increase grinding fineness can save the grinding time and reduce the cost of grinding, also can avoid the disadvantage of fairly granular mineral particles cause a deterioration in the flotation. So it is necessary to research a kind of coarse particle flotation column.After a research on the advantages and disadvantages of flotation column, the authors designed and manufactured a new layered convection coarse particle flotation column, the flotation column both in theory and operation is better than flotation machine.DESIGN OF THE LAYERED CONVECTION COARSE PARTICLE FLOTATION COLUMNAdvantages and Disadvantages of the Traditional Flotation ColumnIn the field of mineral processing, as the increasing proportion of ore that has low grade, fine dissemination size, complex mineral composition characteristics. The limitations of traditional flotation machine is increasing[1],for instance, the high energy consumption, severe wear, inconvenient configuration , large amount of maintenance and so on. Compared with flotation machine, the flotation column with high separation efficiency, low investment and production cost, covers a less area low installation cost, less reagent dosage, more suitable for separation of fine particles and can automatically control, etc[2]. At present, the ore is facing the world energy crisis situation, and becoming increasingly difficult to flotation. So it is important to invent a coarse particle flotation column."

Jan 1, 2016

By M. Lindgren

"Hydrometallurgical processing involves process stages, like leaching, that create harsh environment for stainless steels. High acidity, the presence of chlorides and oxidizing ions combined with relatively high temperature create risk for both uniform and localized corrosion. Advanced electrochemical techniques were employed to study uniform and pitting corrosion of two stainless steel grades 316L and 2205. Results obtained with the linear polarization resistance technique combined with the harmonics distortion analysis, electrochemical noise and coupled multielectrode array systems are compared to the results of conventional electrochemical techniques and immersion tests.INTRODUCTIONHydrometallurgical processing has become favoured in metals production in recent years due to energy costs, leaner ore bodies and environmental factors. Because the hydrometallurgical processing route is flexible, various types of secondary raw materials, like flotation tailings, dusts, sludges and slimes can also be treated in addition to conventional mineral concentrates (Sarveswara Rao & Acharya, 2008).Hydrometallurgical processing relies on aqueous chemistry, usually acids, at temperatures around 100°C for the recovery of metals from ores, concentrates, recycled or residual materials. The processing route can typically be divided into three stages: leaching, solution concentration/purification and metal recovery. The processing environment is aggressive, especially in leaching. High acidity, relatively high temperature together with impurities, like chloride ions, place high demands on the corrosion resistance of construction materials. The dominant corrosion mechanism may be uniform corrosion or localized corrosion depending on the process conditions (Ekman & Torsner, 2010). This complicates the prediction of corrosion rates and, consequently, cost effective material selection.Traditional means to evaluate uniform corrosion resistance of stainless steels are immersion tests and the results are published in the form of iso-corrosion diagrams (Outokumpu Stainless, 2010). For the localized corrosion, namely pitting and crevice corrosion, immersion tests can be used but the duration of the test is rather long because an incubation period takes place prior to the occurrence of the actual localized corrosion damage. Electrochemical techniques, traditionally in the form of cyclic polarization scans, have been employed to assess the susceptibility of a material to pitting corrosion (Papavinasam, 2008). They cannot, however, give any indication of the pitting corrosion rate and lack potential for on-line measurements."

Jan 1, 2012

By R. G. Helberg, S. M. Rebelo

"Copper and cadmium are removed from the zinc sulphate solution in primary purification by cementation reaction followed by filtration. The solids are sent to the cake leach section where zinc and cadmium are recovered from the copper rich slurry. The copper solids from cake leach are filtered, bagged and sold. In order to achieve a lower cadmium copper cake, an altered process flow is suggested. It is proposed the primary purification be split into two steps for individual removal of copper and cadmium. INTRODUCTIONCopper cake is a product of primary purification, also known as copper and cadmium removal. Copper and cadmium are removed by cementation reaction in four stirred reaction tanks. The slurry is then filtered through Shriver manual plate and frame presses with the solution advancing to the next stage of purification, hot zinc purification (HZP). The solids from primary purification are further processed at the cake leach section where zinc and cadmium are separated from the copper rich slurry. Cadmium and zinc are dissolved in the cold cake leach tanks using spent electrolyte. Cadmium is recovered from this cadmium rich solution by cadmium sponging, leaching and electro-winning circuits. The residue from this cold leach step is further leached using spent electrolyte at a temperature of 85°C. The copper rich solids from hot cake leach are filtered on a drum filter and bagged in 1 ton bulk bags for shipping to buyers.Current assays of copper cake are shown in Table 1. The goal is to produce a copper cake product that is below 0.5% cadmium."

Jan 1, 2012

By Dawei Yu, Kinnor Chattopadhyay

In the nickel industry, molten slags produced from a Pierce-Smith converter contain significant amounts of valuable metals in the forms of oxides and physically entrained matte droplets. A slag cleaning step, which takes places in an electrical slag-cleaning furnace, is therefore required to recover the valuable metals as a common practice. Utilization of a waste material from aluminum industry (i.e. spent potlining) as a flux to improve the slag cleaning in terms of both the metal recovery and the operation efficiency was studied by simulation with FactSage program. Results show that the addition of SPL could substantially reduce the slag viscosity due to its fluoride values, thus accelerating the settling of matte droplets. The carbon value in the SPL could also help increase the metal recovery by reducing the valuable metal oxides followed by settling.

Jan 1, 2015

By S. X. Shi, M. Tan, Y. Q. Li, D. F. Han, Z. B. Han

Bauxite resources in China are mainly diaspore ore with the characteristics of low ratio silicon to aluminum. In order to obtain high quality of alumina product, flotation process is generally used to extract the aluminum from diaspore ore. Small aeration rate is needed for bauxite flotation, which requires air to be controlled accuracy. In addition, productive froth from bauxite flotation is too sticky to effects froth transportation. Air-forced XCF/KYF flotation machines are helpful for aeration control, while self-suction GF flotation machines benefits froth transportation. Zhongzhou aluminum plant of China Aluminum Group (Chinalco) uses 7 series of XCF/KYF /GF combined flotation machines to process bauxite. Air distribution, suspension characteristics, froth flow velocity and Al2O3 recovery were investigated, to evaluate the performance of flotation machines in one series and determine recovery contribution of each cell to the entire flotation circuit.The air distribution degree varies from 3 to 4, which is enough for bauxite floatation process. Froth in the tank could flow smoothly with a flow velocity of 2.4m/min. The recovery of the first KYF-40 flotation cell is the largest. Flotation concentrate of Al2O3 is up to 64.29%, the total recovery is about 75%, and the ratio of Al/Si has reached 10.4.

Jan 1, 2015

By D. W. Davis, P. Landais, L. J. Robb

Abstract -Nodules of carbonaceous matter have been observed in several Archaean peraluminous granites adjoining the gold- and uranium-bearing Witwatersrand Basin. These nodules, which resemble solid bitumen, usually replace uraninite or uranothorite and are paragenetically late. They show many similarities to kerogen seams and nodules associated with the conglomerate horizons in the Witwatersrand Basin, including composition, maturation, intimate association with uraninite, and a late paragenesis. U-Pb isotope ratios for granite-hosted and Witwatersrand kerogens define a single, albeit somewhat diffuse, Pb-loss discordia suggesting an upper intercept age of circa 2300 Ma. Carbon isotope analysis indicates lighter ?13C values for the granite-hosted nodules than for the sediment-hosted kerogen seams. Raman spectroscopy indicates that granite-hosted kerogen is more highly ordered than Witwatersrand seam kerogen. A model is presented which links the granitoid­ and sediment-hosted organic matter to an event of oil generation in the Witwatersrand Basin circa 2300 Ma ago. Light hydrocarbons migrated through the sediments and into underlying/adjacent granitic rocks, undergoing polymerization and accumulation in response to radiation accompanying the presence of high-uranium phases.

Jan 1, 1994

By John D. Campbell

Alberta Plains coals exhibit an almost rectilinear system of vertical fracturing called "cleat", which is best traced by mapping true bearings of underground coal mine rooms. The cleat pattern is approximately conformable with a pattern of surficial features and a pattern of bedrock jointing in the Alberta Plains, and with the trend of the Rocky Mountain Trench, but not with the distribution pattern of coal rank nor with the trend of the eastern boundary of the Rocky Mountains and Foothills physiographic province. The processes resulting in cleat remain in doubt, but cleat is always of practical importance in extracting coal from deeply buried deposits.

Jan 1, 1979

By M. Fiset, D. Belley

"To better understand the wear process of various materials that may be used as blades on snow removal equipment, the first step is to evaluate the influence of the load applied and the moving speed on road wear rates of one type of steel and three types of polymers. While the behavior of steel conforms to Archard's law, wear rates of polymers increase to a power of ex of the load applied according to a model implying that the wear of these materials is due to fatigue. The wear rate of some of the polymers varies considerably in terms of speed, unlike the steel. The wear resistance of some of these polymers outclasses the steel tested as long as the speed is not too great. They, therefore, present interesting alternatives for snow removal on more fragile surfaces such as sidewalks and zone made of inter-block slabs.IntroductionSince the dawn of the Industrial Revolution, the massive use of machines has brought with it a number of different problems regarding wear. Snowplowing roads, parking lots and sidewalks is an activity that generates enormous expense in a country such as Canada. To better understand these wear processes and in the hope of stimulating new approaches designed to reduce the costs related to this sector of activity, this paper presents the behaviour of several materials (steel, polymer and rubber) as they wear on an asphalt-fines matrix surface lubricated with water. Also discussed is the effect of various parameters such as the load applied and speed."

Jan 1, 1990

By R. A. Campbell

The electric smelting of five lowgrade Canadian manganese ores has been investigated at the Mines Branch, Department of Mines and Technical Surveys, Ottawa. Ferromanganese, silkomanganese, and spiegeleisen were produced 1by special smelting processes from these ores since the latter were too low grade to be treated by conventional smelting methods. In one case the results were considered to be sufficiently promising to justify the construction of a pilot plant, by the Company concerned, for the further development of the process.

Jan 1, 1956

By Eugene Barsky

"At present, theoretical concepts of gravitational separation processes are mainly limited by the study of the interaction between a flow and a solitary particle. Then the main conclusions of this analysis are applied to a mass process. However, this analysis is absolutely insufficient, because some elementary phenomena such as the ingress of coarse particles into the fine product output and vice versa cannot be interpreted from its standpoint. It is also impossible to predict the results of the classification of a material with a specific granulometric composition on a specific apparatus on its basis.In the present paper, an extended model of the process is suggested. The model is based on the behavior of all the particles of a specific narrow size class, and not on that of an individual particle. Similarity criteria of the process, which were empirically derived previously, are obtained from the analysis of this model.INTRODUCTIONIn case of gravitational separation, a part of solid phase moves, as a rule, vertically upwards with the flow, while another part settles against the flow. This flow is extremely complicated and chaotic due to various random factors. Among these factors are mass interactions of particles with each other and with the apparatus walls, non-uniform character of concentration and velocity fields, turbulent vortices and local fluctuations, real particles shape difference from spherical one, etc.Particles rotation results in a transverse force (Magnus' effect). At the motion of a non-rotating particle in a non-uniform velocity field, a transverse force also arises (Saffman's effect).A great number of publications have been devoted to the account for all these factors in two-phase flows in recent decades. Very complicated models have been developed, but the problem has not been completely solved as yet [1, 3].At the same time, simplified models of the behavior of a solitary particle in a flow are being developed. Despite their schematic nature, such models often prove to be useful for establishing general laws of the process and its similarity criteria [1]."

Jan 1, 2016

By Jerry M. Whiting, Neil J. Duncan

"Does Canada need a mining industry? Isn't it a chronically depressed collection of businesses that pollute the air and water and tear up the countryside? Wouldn't it be better if Canada's investors devoted their attention to high-technology endeavours, tourism, and other relatively pleasant tasks?Probably the answer to whether Canada needs a mining industry in the 21st century is to look at the real mining industry that is in operation today. The facts indicate that mining is a very important contributor to Canada. It has certainly encountered some challenging times during periods of recession, and it face s severe and continuing problems of cost and competition in world markets. However, uneconomic mines have been closed, others suspended, and productivity has risen dramatically with employment at 77 000, down from 101 000 in 1981. The country's metal and non-metal mines, metallurgical plants and semi-fabricated metals industries employed an estimated 378000 workers in 1986, and paid wages than any other sector of the Canadian economy. This effort resulted in the production of 60 different metals, non-metals and structural minerals valued at $13.5 billion.The trade aspects of the mining industry are of paramount importance. If there is a reason for this situation to change during the next century. it eludes the authors. Canada has the well-developed expertise to discover, evaluate, develop, operate and profit from existing and new businesses based in an enormous area endowed with a nearly unbelievable variety of mineral resources. Many countries throughout the world must rely on producers like Canada, if they are to maintain and/or improve their standard of living."

Jan 1, 1988

By W. L. Sherwood

Present conventional techniques for primary steelmaking in both integrated and non-integrated plants are outlined. 'Direct reduction' alternatives are reviewed and categorized according to the nature of the product produced, with particular emphasis on the limited number designed to yield steel as the end product. A proposed new technique, referred to as the Sherwood Process, is described in some detail as a new combination of selected features from the prior technology. This process is in-tended to realize, in integrated operations, the result of continuons steelmaking directly from the ore in a single plant and, in non-integrated operations, continuons steel-making from a metallic charge of scrap, sponge iron or pig iron. Prominent features are continuons processing in elongated, horizontal, rotary furnace equipment, controlled direct heating of each process stage and, for the over-all integrated process, a size separation for removal of excess solid reductant and other waste just prior to the melting step. Material and energy balances are presented as well as exemplary cost data. Reasons for selecting this particular combination of process elements are dis-cussed.

Jan 1, 1968

By N. H. Grace

"IntroductionDURING the past half century, the economy of Western Canada was largely centred on agriculture. However, the impact of World War II has led to an acceleration in the development of a variety of natural resources so that, today, Western Canada is experiencing great industrial development. Consequently, the availability •of low-cost energy assumes prime importance. In the final analysis, industrial growth and expansion are intimately linked to the energy resources.Coal ReservesHas Western Canada adequate coal reserves to meet the present accelerating demand for power in the days that lie ahead? This question must be answered before detailed consideration can be given to the probable patterns •by which various energy sources in Western Canada may be expected to meet the expanding demand. Figure 1 indicates the extent and distribution of the Canadian coal reserves, the data having been prepared by Dr. B. R. MacKay for the Royal Commission on Coal in 1946 (1). The amount of readily recoverable coal is listed as one-half the quantities shown on the chart. It is interesting-to note that upwards of 90 per cent •of the Canadian coal reserves .are located in the three most westerly Canadian provinces. It has been estimated that the coal reserves, at the present rate of mining, would be adequate for about 3,000 years. Consequently, it may be concluded that the coal •reserves in Western Canada •are indeed adequate to meet tremendous energy demands for many centuries. When the oil and natural gas have been exhausted, the great coal reserves will still be available."

Jan 1, 1953

By Jas. G. Ross

Introduction Asbestos, a mineral known and used in ancient times, has become an article of commerce only during the life of the older asbestos miners in Quebec. The diversified uses of this adaptable substance are now numbered by the hundreds. Wherever insulation or resistance to heat may be required, asbestos, either by itself or mixed with some other material, may be employed to advantage. Regarded as a curiosity for centuries, it is now in such common use that it is familiar to all. The demand for long fibre for use in the manufacture of textiles and brake-lining, and for shorter fibre for making shingles, paper, and insulation materials, serves to support the industry of mining asbestos-bearing rock and milling the fibre from it in Canada, South Africa, Russia, Cyprus, and the United States. The commercial use of asbestos dates only from 1876, in which year large deposits were discovered in the Province of Quebec, Canada. Prior to that year a small amount of long fibre amphibole asbestos was produced in Italy. Occurrence In Canada In the Eastern Townships of Quebec, along the line of the Quebec Central railway, is an area of serpentine rock. It extends westerly into Vermont and easterly to Gaspe. A part of it, the section from Danville to East Broughton, contains areas in which occur deposits of commercial asbestos fibre of the chrysotile variety. Pits have been opened on some of these deposits at Danville, Coleraine, Black Lake, Thetford Mines, Robertson, and East Broughton. Thetford is distant 68 miles from Quebec city, East Broughton lies 25 miles to the northeast of Thetford, while Danville is 45 miles to the southwest of Thetford.

Jan 1, 1927

By D. S. Case

"Following a brief explanation of the land arrangements under the Alaska Native Claims Settlement Act, this paper will examine both a mineral exploration agreement and a mining development agreement negotiated between two large mining companies and two different Alaska Native institutions. One of the institutions is a village corporation involved with an exploration agreement and the other is one of the Alaska Native regional corporations, which is party to a mining and development agreement with Cominco Alaska for the development of the Red Dog lead and zinc mine.Special attention will be given to the factors to be considered when dealing with small aboriginal owners with few resources in the context of an exploration agreement, including development issues which must be considered early in the process. The paper will also discuss the unique royalty and taxation structures developed for the Red Dog Mine Agreement as well as environmental issues. The paper will also consider the ways in which the cultural and differing economic interests of an aboriginal owner and a large mining company have been accommodated in the both the exploration and development agreements"

Jan 1, 1998