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By H R. Watling, W van Bronswijk

Of the various copper sulfides in the EarthÆs crust, chalcopyrite is by far the most common. This mineral is also the most difficult to leach, with hydrometallurgical extraction processes characterised by prohibitively slow kinetics. While a number of processes, including leaching at atmospheric pressure and temperature, pressure leaching at higher temperature, and bioleaching of concentrates in stirred tanks and whole ores in heaps have been demonstrated to some extent, there is currently no full-scale unit process for the hydrometallurgical extraction of copper from chalcopyrite ores. Titan Resources NL operated a test bacterial heap leach at Radio Hill, Western Australia in 2001, to extract nickel and copper from a mixed sulfide ore that contained significant amounts of chalcopyrite, pentlandite and pyrrhotite. A proprietary mixed bacterial culture was used to inoculate the heap, and the nickel and copper were precipitated from the resultant solution as mixed hydroxides. Although 65 per cent of the copper from the Radio Hill heap was eventually recovered, the rate of extraction followed an unexpected trend, as the initial rates of copper recovery were much slower than column tests had suggested. It was postulated that this was due to dissolved copper precipitating as covellite or chalcocite in the most poorly aerated zones within the heap, ie furthest from the aeration pipes at the base. It was further hypothesised that the lack of oxidants (oxygen, ferric iron) and the likely inactivity of bacteria in these areas limited the re-dissolution of such secondary copper precipitates. In this study the above hypothesis was tested in column experiments using the same mixed sulfide ore and a synthetic leach solution. One set of columns was aerated and another set was operated without aeration. Results showed that precipitation of copper occurred regardless of whether the column was aerated or not. The results suggested that pH of the leach solution played a significant part in the precipitation of the copper. Further column tests revealed this to be the case. These results are described here in detail.

Jan 1, 2004

Portman Mining Pty Ltd very successfully operated the Ferro GullyNorth Mine in the Hamersley Province of Western Australia to satisfy a contract for the delivery of six million tonnes of iron ore in less than two years to the Mount Newman Mining Co Pty Ltd. The high-grade ore extracted from Ferro Gully North Mine was unusual in that, not only was it within the Joffre Member of the Brockman Formation, but it was rich in red ochreous hematite and martite and very low in phosphorus.

Jan 1, 2001

IN the ordinary course of treatment of pyritic ores or concentrates, whether for the recovery of copper, tin, gold, or any other contents, the removal of some or all of the sulphur contents is almost invariably the first step. The practice is to roast the ore in a current of air so that the sulphur is oxidized to sulphur dioxide and the metal constituents are changed from sulphides to oxides. If it is feasible to produce sulphuric acid in conjunction with the treatment process, the sulphur can be usefully employed; but if this is not possible, then the sulphur contents not only become a dead loss, but tend to be a nuisance as well in the surrounding neighbourhood.The problem of avoiding this disadvantage and making economic use of the sulphur has had attention from the early days of scientific metallurgy, and in the past few years very special efforts have been made both to drive part of the sulphur as such from pyrites and recover it, and to replace the sulphur in the S02 by carbon, with the production of carbon dioxide and precipitation of the sulphur. So far economic success does not appear to have crowned these efforts. In the case of pyrites, of the two atoms of sulphur which go to make the FeS2, the first is very lightly held. Dissociation is effected by heat alone at a temperature which is given by Peters as 5160 C.Now, sulphur and hydrogen will unite or burn together, with the production of sulphuretted hydrogen. It occurred to the writer that, if hydrogen was passed over pyrites heated to the above temperature, this first atom would be snatched away by the hydrogen, and could possibly be economically recovered.The first step consisted of some simple laboratory experiments. From these it was found that this first atom was readily removed, and that the extraction was practically complete. Further, the reaction took place at a low temperature, a dull red heat being sufficient.

Jan 1, 1923

By Xin J

In China, the State-run mines are currently practising an information card management system, to collect data about mine production and safety condition. Since large volumes of data will be obtained every day, efficiently and effectively processing data and sorting out valuable information will take enormous resources of manpower, if by hand. Therefore, an intelligent database system with easy data inputting was developed to assist information processors in data classifying, filing and retrieving. For analyzing and improving production performances, reliability models and production functions were embodied. The system was implemented on AST-286 in DBASE M. Preliminary applications have proved effective and successful.

Jan 1, 1991

By Adamiak Z. P

A study has been made of the influence of bentonite type on the wet strengths, dry strengths and drying rates of pressed iron ore pellets. Measurements of the influence of bentonite on the kinetics of growth of pellets are also reported. The results show that bentonite decreases the rate of growth of pellets and the drying rates of pellets while increases are observed in both wet and dry strengths. The results have been interpreted in terms of the physical and chemical charact- istics of the bentonite and the suitability of a given bentonite for particular pelletising operations has been discussed.

Jan 1, 1973

By Seedsman R

The fundamentals concepts of roof support are similar between coal mining, metal mining and tunnelling and yet there are different design approaches, different hardware, and different levels of site investigation. This should not be the case and this paper discusses the key geotechnical issues that should underlie all roof support design - the need to reinforce defects. A design method to build a beam in laminated rock under high horizontal stresses is presented. The method allows for changing rock strengths, defect properties and varying horizontal stresses. At one level the design can be implemented with design charts and tables. Lessons learnt during the implementation of the designs at 5 different mine sites are Discussed.

Jan 1, 1998

A blast is designed to completely break competent rock such that it can be economically extracted, and efficiently handled or processed. Efficient breakage of the rock is critical to the success of an operation, and in many operations blast design is optimised to achieve fragmentation, muckpile profiles, and material that is easily excavated. There are inevitably other issues, such as damage to adjacent rock, that should be taken into account when designing a blast to achieve overall optimisation. Some of the key issues with respect to the integrity of the in situ materials adjacent to a blast are identified and briefly discussed in this paper. The potential for damage and the effects of a blast will be strongly influenced by the rock mass properties. This makes it important that site specific conditions and their response to blasting are known. Practical techniques that allow the disturbance adjacent to a blast to be measured with minimum disturbance to operations are described in the paper. Experience shows that, during the blasting process, there is considerable potential to disturb the in situ rock mass adjacent to the blast. In some circumstances a very important objective must be to minimise disturbance outside of the immediate blast area. Measured and observed disturbances caused by blasting to adjacent rock, for various common types of blasting, are discussed in this paper. Blast induced disturbances to the rock mass have been observed in both the near and far fields. These disturbances have the potential to impact on geotechnical design. The geotechnical significance of blast disturbance on a rock mass that is to remain in situ is explored and suggestions with respect to design are given.

Jan 1, 2004

By Davey KJ

Complex sulphide ores are characterised by complex texture of the valuable minerals. Any assessment of the performance of differential flotation circuits treating such ore should include analysis of the effects of poor liberation of the valuable minerals. Selected samples were taken from balanced size by size surveys of the flotation section of a concentrator treating an ore body containing fine grained galena and sphalerite in a matrix of iron sulphides which is mostly pyrite. liberation measurements were made using the QEM*SEM system on four or seven size fractions. The measurements indicated that less than 40 per cent of the galena and less than 60 per cent of the sphalerite in the flotation feed was liberated. The final concentrates were largely composed of composites of valuable minerals and iron sulphide however there was a small but significant fraction of liberated iron sulphide. Using the sized mineral flows obtained from the original balances and the liberation measurements, a satisfactory liberation balance was obtained. This enabled the effect of liberation on the flotation performance to be examined; not only for the entire circuit but also in the rougher, scavenger and cleaning sections. In the zinc circuit the effect of a regrind mill could be assessed. Recovery of galena in the lead circuit was limited by the recovery of composite lead particles. Recovery of liberated galena exceeded 95 per cent in all size fractions while the recovery of composite galena exceeded 85 per cent below 38 ¦m but fell sharply above 38 ¦m. Examination of the behaviour of the liberated and composite galena in the various sections of the lead flotation circuit revealed high recoveries of both liberated and composite galena particles in the roughing and scavenging sections but very low recoveries in the final two cleaning stages. Similar trends to those observed in the lead circuit applied in the zinc circuit although the performance of the liberated sphalerite also fell off at sizes greater than 38 pm in this case. Thus the zinc recovery was limited by the flotation of both the liberated and the composite sphalerite. The effect of regrinding was to increase the recovery of sphalerite mainly by reducing the amounts of sphalerite in less liberated sizes rather than by increasing the liberation of the sphalerite within a given size Fraction.

Jan 1, 1993

This work provides a comparison between the most commonly used classification equipment in the treatment of minerals - hydrocyclones and spiral classifiers - considering their applications and costs. Although in use for decades in the mining industry, spiral classifiers have lost a lot of their importance due to the development of cyclones. This trend, however, is now being reversed, and in the last few years there has been an increasing interest in spiral classifiers, in view of their advantages over cyclones, such as: ò possibility of obtaining more thickened solids; ò less by-pass; ò great durability; ò lower operating cost. This work approaches the different aspects related to the installation, operation and costs of maintenance of these machines, giving a critical comparison of the involved costs.

Jan 1, 1993

The word `environment' may have many different meanings but, for the purposes of this paper, I have assumed the definition included in the Environmental Protection Act 1986 (Western Australia). This Act defines `environment' as `... living things, their physical, biological and social surroundings, and interactions between all of these'. The Act further defines the `social surroundings of man' as `... his aesthetic, cultural, economic and social surroundings to the extent that those surroundings directly affect or are affected by his physical or biological surroundings'. This gives a very broad meaning to the idea of environment and environmental issues, and it is therefore understandable that the influence that environmental issues have on mining activity can vary so much from state to state, and even within states, and why the degree of influence can change so much with time.

Jan 1, 1990

By Angove JE, Johnson GD

Sulphide concentrates are produced in a wide range of mineral processing operations. In the case of base metals they are further treated by smelting and/or hydrometallurgical techniques. In the case of refractory gold ores, sulphide concentrates containing gold are roasted or oxidised by various hydrometallurgical processes. This paper discusses the development of the Activox(R) Process which can provide an alternative method for treating sulphide concentrates. This process consists of fine or ultra-fine milling, followed by mild pressure oxidation to produce solutions of base metals or to liberate refractory gold. Base metal solutions (eg of nickel and cobalt) can be further processed by solvent extraction and electrowinning, while refractory gold can be recovered by cyanidation. The economics of the Activox(R) Process are often better than alternative oxidation techniques.

Jan 1, 1993

Taxes have an impact on mineral resource availability in several ways. There is the obvious effect on the grades needed for mineral deposits to become economic orebodies. There are also indirect effects which can have equally significant impacts. The paper examines the appropriateness of different types of taxes in the mining industry. The effects of discriminatory taxes such as price-based royalties are described. There is a discussion on the feasibility of introducing a single resources tax to replace completely the various forms of taxes presently applied to the industry. The subtle impacts of taxes are described in a section covering the way in which apprehension over future possible changes to both the level and diversity of taxes is reflected in industry confidence. It is concluded that taxation can significantly limit the economic availability of mineral resources.

Jan 1, 1978

By Parker GJ

The financing of smaller resource projects has proven to be a difficult problem for promoters and financiers alike as very often such projects have not met the requirements of available financing methods and promoters have equally found it difficult to establish credibility, management and technical ability with potential financing sources. Solutions to the dilemma in which many of these projects find themselves are not readily apparent but will need to be found if the full potential of Australia's resources is to be realised. INTRODUCTION The growth of so called project financing in its present form is normally considered to be a phenomenon of very recent times, however, paradoxically there are references to what could be called financing in the old testament. To confuse the issue further financing small resource projects may not, and very often are not undertaken on a project financing basis. It is therefore quite apparent that one should be completely clear on:

Jan 1, 1982

In this paper the reactions which may lead to particle hydrophobicity/hydrophilicity as a function of grinding environment-are reviewed. The results of pulp chemical investigations related to a Cu-Pb-Zn ore on a pilot plant scale and laboratory tests with a Pb-Zn ore to evaluate the effect of some inhibitors on grinding/flotation are presented. The flotation recoveries of the ores treated by conventional and autogenous grinding methods show only a marginal difference and the results favour autogenous grinding. Iron originating from several sources manifests in the form of insoluble hydroxy complexes in the pulps. Such metal hydroxy complexes are hydrophilic and coat the mineral surfaces indiscriminately. On the other hand, selectivity is a problem for pulps ground by autogenous milling. Some corrosion inhibitors used in the laboratory grinding/flotation tests on a Pb-Zn ore showed maximum reduction in the wear of the grinding media ranging from 25 - 36 per cent, depending on the type and concentration of the inhibitor.

Jan 1, 1993

The ER&S Company operates a copper sinter plant, blast furnace and converter smelting complex at Port Kembla. Eighty percent of the smelter feed is dirty copper concentrates that contain some lead and zinc. The remaining twenty percent of the smelter feed is copper bearing secondary materials, some of which contain lead, zinc and tin. A predominately lead/zinc fume is produced during the smelting and converting of this feed mix. The composition and tonnage of fume produced at Port Kembla has varied over the years as the smelter feed sources have changed. The economic processing of the fume has always been dependent on the value of the metals contained in the fume and on the fume composition. Both pyrometallurgical and hydrometallurgical methods have been used to treat the fume for the recovery of some or all of the following metals - lead, zinc, tin, copper, cadmium, silver and bismuth. A detailed description of the treatment methods that have been investigated and used to process ER&S fume is given.

Jan 1, 1984

By S McKnight, S Hall

Much of the research regarding the use of bacteria for the oxidation of sulfide minerals has been conducted using pure bacterial strains or synthetic minerals, often under ideal conditions, which does not reflect the conditions commonly encountered in commercially operating plants. This has also led to much conjecture as to the exact mechanism by which bacteria are able to enhance sulfide oxidation and as to which species of bacterial microflora are the most dominant. Recent advances in 16S rNA sequencing has confirmed that many of the bacterial species once thought to dominate commercial oxidation circuits were simply more willing to grow under the culturing conditions used and may only play a minor role in the oxidation process (Rawlings, 2002). Consequently this research will look at bacterial oxidation under conditions more reflective of commercial operations, focusing on the presence of organic carbonaceous material within a refractory sulfide orebody to be sourced from the Fosterville deposit of Perseverance Corporation Limited.

Jan 1, 2004

By Gutsche O, Kapur PC

Experimental data on the production of fines as a function of specific grinding energy consumption show that in general the energy utilisation in a choke fed high-pressure roll mill is higher than in a ball mill, but lower than in the single-particle mode of comminution under slow compressive loading. There is some evidence to suggest that the presence of water in feeds improves the energy efficiency of pressurised roll milling somewhat. Within a wide range of energy input, the size distributions of the ground product are self-similar, the logarithmic median size decreases linearly with the amount of fines produced and the inverse of the median size increases linearly with the energy spent. The production of fines as a function of energy expended follows essentially the same pattern as the one frequently encountered in media mills. The kinetics of grinding in the high-pressure roll mill can be simulated satisfactorily by modifying the standard particle population balance equation in order to account for energy dissipation in the tightly compressed bed. Common characteristics and important differences in grinding by the media mill and the high-pressure roll mill are highlighted.

Jan 1, 1993

By V S. T Ciminelli

This work aimed at evaluating the acid rock drainage (ARD) potential of five samples of a Brazilian gold sulfide mine in a decommissioning process. Three of the most traditional ARD prediction techniques, Standard Acid Base Accounting (Std ABA), Modified Acid Base Accounting (Modified ABA), as static methods, and humidity cells as a kinetic method were tested. Both the Std ABA and the Modified ABA results indicated an acid generation potential for some of the studied samples. In the other cases the results were inconclusive. The five samples were then submitted to humidity cell tests during 27 to 30 weeks. At the end of the period, the leachate pH was stabilised in a range from 3.4 - 4.1 (four samples) to 5 (one sample). The presence of relatively high levels of sulfate and dissolved metals was detected throughout the operation, specifically, Ni and Zn, and less frequently, As. These findings are discussed with the help of the samples mineralogy and Eh-pH diagrams. The results obtained in this investigation indicated potential environmental risks of this mining area. In this particular case, the kinetic tests were shown to be essential to the identification of the samples ARD potential.

Jan 1, 2003

By Reynolds JO

This contribution by. The Australasian Institute of Mining and Metallurgy has three main thrusts. First, an Institute (and industry) view on academia and the need for more entrepreneurship at top academic levels, second the need to lift our technological game, and third, professionalism and the perceived role of mineral industry education. While I will deal with each of these separately they are of course inter- related and can be brought together under the frequently used, but insufficiently practised title, "communications". First then, The Institute and industry view of academia. There are some academics in the audience and I imagine they may wish to reply to my remarks with an academic view of industry. That is not unreasonable. Like all human institutions, academic institutions vary in quality and characteristics. Some are successful and some less so. Some historically are well renowned. Others that were once successful schools have declined. Lesser known schools have grown into prominence. What is it that sets apart 'good' highly regarded schools from those that are not so well regarded? It comes down to one main ingredient - "leadership". The strong mining schools in the past 100 years have been strong because they have had outstanding and clearly identified leaders. Strong clearly identified leadership has always had rapport with, and the support of the industry. The two go hand- in-hand, each nourishing and supporting the Other.

Jan 1, 1986

Criteria for the manipulation of commodity markets are discussed. Against the economic background of the past twenty five years actual attempts to manipulate markets are evaluated.

Jan 1, 1985