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By E Jak, G Khartcyzov, M Shevchenko

The increasing complexity of ore resources and recycled materials in the feed of pyrometallurgical processes present a technical challenge to the metallurgical engineers working on maximising the recovery of the valuable elements and minimising the environmental impact of the processes. To address this challenge, the availability of computational tools that can predict the mass and energy balance in complex systems is required. Then the accurate description of phase equilibria in the complex multicomponent systems describing the chemistry of the pyrometallurgical processes becomes critical for the correct implementation of the indicated tools and facing the outlined industrial challenges. In the present study the distribution of selected elements (Pb, Zn, Fe, As, Sn, Sb, Bi and Ni) between oxide liquid and metal in the ‘CuO0.5’-CaO-AlO1.5 system in equilibrium with Cu metal at 1400°C (liquidus of CaAl2O4) was experimentally studied using the equilibration and quenching technique followed by the electron probe X-ray microanalysis of the resulted samples. The study covered a wide range of effective p(O2) over the system from 10-11 to 10-3.5 (corresponding to formation of immiscible CuO0.5-rich slag). To avoid loss of volatile elements (Pb, Zn, As, Sn, Sb and Bi), a correlation between ‘CuO0.5’ in oxide liquid and p(O2) in open system was obtained first, followed by studying the volatile elements distribution in closed conditions (Al2O3 crucible sealed in SiO2 ampoule), where ‘CuO0.5’ concentration was used as a marker to evaluate the effective p(O2) over the system. The experimental results were then used for the optimisation of the thermodynamic model parameters of the system as part of the integrated experimental and self-consisting thermodynamic modelling research program of phase equilibria in the Cu-Pb-Zn-Fe-Ca-Si-Al-Mg-O-S-(As, Sn, Sb, Bi, Ag, Au, Ni, Cr, Co and Na) gas/oxide liquid/matte/speiss/metal/solids system.

Jun 19, 2024

This paper describes the new iron and steelmaking process recently commissioned at NZ Steel. Ironsand mined and concentrated at Waikato North head is slurry pumped 18 km to the company's Glenbrook works. Ironmaking includes the direct reduction process pioneered at Glenbrook in the 1970s and a new continuous electric melter. The molten, high carbon pig iron produced is then fed to a vanadium recovery unit and on to the KOBM oxygen steelmaking vessel. Steel is cast into billets or slabs. The new plant, which is the first stage of a fully integrated works at Glenbrook, raises New Zealand Steel's production capacity from 150 000 t/y to 750 000 t/y.

Jan 1, 1986

By M G. Shaw, M A. Rhamdhani, S P. Singh, A R. Duffy, B Eisenbart, A K. Shukla, G A. Brooks

The field of astrometallurgy is a growing area of study. Metal production on the Moon is likely to begin in less than a decade as major space agencies such as NASA (National Aeronautics and Space Administration) and CNSA (China National Space Administration) are preparing to construct permanent lunar bases. The utilisation of regolith to generate oxygen and metals is expected to be important in the development of a sustainable lunar habitat. This paper provides an overview of potential metallurgical processing methods for lunar conditions, emphasising the impact of lunar factors on slag chemistry. The interaction between regolith and the extracted metals, as well as their impact on slag composition and refractory performance, are critical considerations in metal production on the lunar surface. The initial research on lunar metallurgical technologies is focused on oxygen extraction and Fe-Si alloys are reported as the by-products of these processes. This paper delves into the fundamental thermodynamics associated with the carbothermic reduction of lunar regolith. Thermodynamic analysis using the FactSage™ ver 8.2 software package indicates that the Fe-Si alloy can be produced as a metallic product from the lunar regolith at temperatures ranging from 1400°C to 1600°C under terrestrial conditions. However, under ultra-high vacuum conditions (3 × 10-15 bar) on the Moon, the required operating temperature for producing ferrosilicon would be significantly reduced. Thermodynamic modelling results indicate that under lunar vacuum conditions, Fe-Si alloys only exist as solid phases at lower temperatures below 650°C. At higher temperatures, both Fe and Si are expected to be present in the gas phase. In this work, the carbothermic reduction of the Lunar Mare Simulant (LMS-1) is conducted under terrestrial conditions. The findings indicate that the process can readily yield Fe-Si alloys with 7–10 wt per cent Si at 1600°C. Additionally, energy dispersive spectroscopy (EDS) analysis of the resulting Fe-Si alloy indicates the presence of phosphorus up to 1 wt per cent.

Aug 21, 2024

Many volcanoes in western Melanesia have tectonic settings and rock compositions that do not conform to conventional models of arc- trench systems. Part of the reason for this may be that in an environment of rapid tectonic change mantle source regions bear the imprint of former subduction even though subduction has now ceased. Results bearing on this concept and on other important aspects of Plelit nesian v ican ism and tectonics, were obtained in 1982-1986 from >e,:eral marine - geoscience studies in the re,,ii n

Jan 1, 1987

By A Mokhtari, S Gatehouse, N Rutherford

Geochemical exploration continues to play a significant role in new mineral discoveries inAustralia and elsewhere, including terrains where mineralisation is buried or otherwise obscured by regolith cover of various types. Transported regolith commonly restricts the migration of trace elements to surface, especially in arid terrains, presenting a range of problems for traditional geochemical exploration methods that employ surface samples. Regions dominated by transported cover include the northern parts of the Tasmanides in eastern Australia and the Yilgarn Craton which are variably covered by thick alluvium and Mesozoic to Cainozoic sedimentary rocks (Anand and Paine, 2002). An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By J Cortinez, P Vallejos, J Yianatos, M Rodriguez

Nowadays, one of the main problems in current flotation plants and new projects is the significant decrease in feed grades and changes in the mineral composition, which has an important effect on the mineral liberation and associations. Additionally, flotation plants usually operate with feed throughput higher than the original design, which has a significant impact on the feed particle size. All these conditions affect metallurgical performance, and must be evaluated and addressed, by improving control strategies for banks optimisation. For this purpose, the flotation of valuable minerals along the circuits requires better understanding, considering the compromise between performance and selectivity in flotation circuits. This paper presents a characterisation of the different minerals recovered along industrial flotation circuits. Plant sampling campaigns, performed in a copper industrial concentrator in Chile, provided the data for the study. Two rougher flotation banks consisting of cells of 130 m3 and 300 m3 were analysed. All the samples from the industrial surveys were analysed by screening and mineralogy, and the mineral recovery along the circuits was evaluated per particle size class, liberation class, type of associations, and others. Additionally, operating data on froth depth profiles complemented the evaluation of the mineral composition of concentrate streams, along the circuit. The results allowed for identifying and quantifying the main factors that affect the copper recovery and concentrate grade along the flotation banks. It was found that minerals with liberation lower than 50 per cent have a significant impact on the recovery. On the other hand, the decrease in the Cu grade in concentrates along the flotation circuits is mainly due to the relative increase of middling minerals (less liberated), non-valuable floatable minerals, such as free pyrite, and gangue entrainment. The characterisation of the gangue entrainment flow rate along the flotation banks showed a strong relationship with froth depth, which becomes more critical towards the last cells of the banks.

Aug 24, 2022

Cretaceous volcanic activity (Hauterivian Albian) in the Peruvian Andes can be found along the coast of Peru and the western edge of the Andes mountains between 15o30'S and 5o30'S, extending discontinuously in south to Chile and north to Ecuador and Colombia. This volcanic activity formed in three aborted marginal basins; the NNW-trending volcanic Ca±ete and Huarmey, and NNE-trending Lancones basins. These volcanic rocks are predominantly andesitic and basaltic in composition, of calc-alkaline and tholeiite affinity with subordinate dacitic and rhyolitic rocks. One notable feature is the appearance of æocoitasÆ from Ica (14oS) south to Santiago de Chile. These rocks have a calc-alkaline to alkaline affinity. From south to north, the continental crust gradually becomes thinner, allowing mantle material to rise towards the surface. Ophiolitic sequences of this type form a marginal basin in Colombia. Very low-grade regional metamorphism which affects the volcanic rocks also varies gradually from south to north. Between Santiago de Chile and Ica this takes the form of burial metamorphism, with moderate geothermal gradients (20o-30oC/km). Metamorphism in the Huarmey basin is transitional between burial and ocean-floor metamorphism, with very high geothermal gradients (>3000C/km). High geothermal gradients are also apparent in metamorphism of the Lancones basin, though less than the other basins. Ocean-floor metamorphism is present in the ophiolitic sequence in Colombia. Associated mineral deposits in the Huarmey and Lancones basins, and in the north, are of the volcanic massive sulphide-type (VMS). The principal deposits in Peru are Leonila Graciela (20 Mt Zn and Pb) and Tambogrande (40 Mt Cu and Zn). There are also smaller mines and prospects. To the south of Lima, manto-type Cu deposits (CuMT) are found with a mineralogy of chalcopyrites, pyrites, magnetite, actinolite and apatite. The main example is Raul Condestable (10 Mt Cu). Other prospects are present to the south and Chile has some very large mines of this type (El Soldado, Lo Aguirre). The notable differences between the CuMT and the VSM deposits are thought to be the result of the prevailing conditions in the earthÆs crust during the Hauterivian Albian. To the south, calc-alkaline and alkaline volcanic activity in aborted marginal basins, with thicker crust, was thick, produced moderate geothermal gradients associated with burial-type regional metamorphism and deposits of CuMT. In the north aborted marginal basins associated with calc-alkaline to tholeiitic volcanic activity and a gradually thinning crust, produced transitional regional metamorphism between burial-type and ocean-floor type, associated with high to very high geothermal gradients and VMS deposits. In Colombia these conditions led to ophiolite extrusive rocks, ocean-floor metamorphism and also VMS deposits.

Jan 1, 1999

The Abra mineralized body is regarded as a significant new style of mineralization for its environment. It is a blind polymetallic deposit, located in the Bangemall Basin of Western Australia. It was discovered by Geopeko in 1981 by diamond drilling a coincident magnetic gravity target, which revealed a large low grade epithermal Fe-Ba-Pb-Ag-Cu-(AuW) deposit, hosted by chemogenic and clastic sedimentary rocks, overlain by 200-500 m of clastic sedimentary rocks, of Middle Proterozoic age. The mineralization occurs as an upper stratabound phase, and a lower vein "stringer" style phase within a pervasive chlorite alteration envelope.

Jan 1, 1987

By C Sellens, L D. Fabbro, S Vink

The Fitzroy River Aqua-Eco Health Project is a collaborative research project between the Central Queensland University, the University of Queensland and BMA. It is designed to assess the aquatic ecology and health of the streams within the Fitzroy catchment located adjacent to mine sites. The universities are conducting an independent sampling program expected to yield the most comprehensive monitoring to date. The project design incorporates in situ testing of water quality variables including temperature, dissolved oxygen, conductivity, oxidation reduction potential, pH and turbidity. Water and sediment chemistry incorporate testing for sulfate, suspended solids, nutrients and metals. This sampling is complemented by quantifying changes in the abundance and diversity of a wide range of biota, including microbial, macro invertebrates and fish.This paper will detail the program and highlight some of the particular difficulties in conducting this type of research in ephemeral stream systems. Case study examples will be used to illustrate insights being gained from the program. CITATION:Fabbro, L D, Vink, S and Sellens, C, 2013. The Fitzroy Aqua-Eco Health Project, in Proceedings Water in Mining 2013, pp 117-120 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By Abdulhadi H. M, Soliman S. A

The Western Desert of Egypt is a part of the arid Great Sahara of Africa which extends from the Nile Valley in the east to the Atlantic Ocean in the west. It is covered by a sedimentary sequence of Mezozoic and Teriary rocks. Recently this part of the country (about 65% of its surface area) has attracted an increasing attention in the plan of finding new agricultural and industrial communities outside the crowded Nile Valley. The plan aims to reduce the high population density in the narrow Nile Valley and to cover a considerable part of the increasing food demands in the country of Egypt. Accordingly, the groundwater exploration work in the Western Desert has been remarkably increased in the last decade, however it is still limited compared with the vast area of the Desert. The present work is a part of the groundwater exploration in the 6th October City, a new community located at 40kms west of Cairo. The rock exposures belong to a sedimentary stratigraphic section starting from the Cretaceous in the east to the Pliocene in the west. The Cretaceous outcrops due east are attributed to an almost N-S uplift and forms a thick massive limestone plateau which separates the present area from the Nile Valley. The Teriary section in the west have alternations of different porous formations such as the sands and sandstones which may acquire a good potentiality of groundwater resources. The previous groundwater exploration work included combined geological and geophysical investigations followed by exploration drilling. Although the area lies directly to the west of the Nile Valley, the discovered groundwater is saline and located at deeper reserviores compared with the groundwater in the Nile Valley. This groundwater was described as marine fossile water by the oil companies working in the Western Desert. From the geological point of view, it is believed that the Cretacious massive limestone plateau, in the east, roots to a depth which far exceeds the groundwater levels in the Nile Valley and acts as an impervious barrier between the aquifers in the Nile Valley and the area under investigations.

Jan 1, 1988

In October 1993 it was decided to undertake the fourth phase of mining at Big Bell. This decision followed the exhaustion of open pit reserves in January 1993. Two stages of mining were proposed for the new underground mine. The initial stage would mine the remnant ore, consisting of the rib and crown pillars and lower grade ore on the hangingwall and footwall side of the old open stopes, which were mined from the 1930s to 1950s. Most of the old open stopes were backfilled with either deslimed mill tailings or development mullock, both of which were economic to recover. However, the mineable ore from this resource was difficult to evaluate. The second stage focused on mining ore outside the remnant areas and was initially proposed as a Core and Shell method under a caving hangingwall. This method has since been superseded with sublevel caving, in part due to the very high and deviatoric stress conditions encountered at Big Bell and the relatively long mining cycle required for open stoping. The problems and challenges discussed in this paper will cover the identification of remnant ore reserves, dewatering the old workings, and remnant mining.

Jan 1, 1998

By D Bradshaw, J R. R de Villiers

The non-stoichiometric sulfide mineral pyrrhotite (Fe(1-x)S), common to many nickel and platinum group element (PGE) ore deposits, occurs in varying crystallographic forms with the different types exhibiting subtly different physical and chemical properties. These differing properties are likely to influence the flotation performance of pyrrhotite, which in the case of PGE operations is actively recovered, whereas in nickel operations pyrrhotite is depressed. In this study, examination of natural pyrrhotite samples from Southern African and Canadian nickel and PGE ore deposits revealed a variety of pyrrhotite compositions in terms of iron content (Fe7S8, Fe9S10, Fe11S12) and solid solution nickel concentration. Pyrrhotite composition was correlated with its mineral association depending on whether non-magnetic pyrrhotite occurred in conjunction with troilite, non-magnetic pyrrhotite occurred as single phase pyrrhotite, magnetic pyrrhotite occurred as single phase pyrrhotite or whether the two phases; magnetic and non-magnetic pyrrhotite co-exist. Subsequent microflotation tests of selected single phase pyrrhotite samples revealed that the non-magnetic pyrrhotite is slightly more floatable than magnetic pyrrhotite. Microflotation tests also showed that varying flotation responses occur between differing magnetic pyrrhotite samples. These differences in flotation performance are postulated to be a result of the effects of varying pyrrhotite crystallography, trace metal content and mineral association on pyrrhotite oxidation, formation of surface species and subsequent adsorption with xanthate collector.

Jan 1, 2008

By K B. Quast

During the prefeasibility stage of the mining cycle for a gold deposit, an evaluation of the ore leaching characteristics from various defined areas is essential prior to plant design. There are a number of simple laboratory tests which have proven successful in establishing gold and silver leaching kinetics, carbon adsorption and fouling, as well as elution characteristics. A number of case studies of carbon-in-pulp (CIP) simulation are presented which show excellent agreement between calculated and assayed gold and silver grades in feed and adsorbed on carbon which validate the methods used.

Jan 1, 1998

By E Giles

Pike River Coal Limited (PRCL) is opening a new underground coal mine in the Paparoa Ranges north-east of Greymouth. To access the coal reserves, PRCL have had to build a 13 km access road through regrowth and virgin forest, and appointed McConnell Dowell Constructors Limited, with URS New Zealand Limited as their consulting engineers, to construct the final access link: a 2.3 km long, 5.5 m wide and 4.5 m high incline tunnel. This paper discusses the logistical issues of construction in an isolated pristine forest in mountain land and how they were addressed. It provides an overview of the 90 per cent complete tunnel and how challenging rock conditions have been mastered. It outlines briefly the remaining work which is construction of pit bottom workings where the mine infrastructure will be housed and construction of a 110 m deep, 4.0 m diameter, vertical ventilation shaft.

Jan 1, 2008

By D J. Williams, S Islam

Fine-grained coal tailings slurry undergoes only limited settling and self-weight consolidation, and tends to remain slurry-like and unsuitable for conventional laboratory consolidation testing. In addition, constant rate of loading consolidation testing is more representative of the continuous disposal of tailings slurry into a tailings storage facility (TSF) than conventional step loading. The laboratory consolidation testing of coal tailings slurry under a constant rate of loading has been carried out in a purpose-built, large-scale, slurry consolidometer, instrumented with load cells and pore water pressure (PWP) transducers. In the slurry consolidometer, the rate of loading may be varied to represent the actual rate of rise of the tailings in the TSF. A slow rate of loading increases the test duration, while too fast a rate of loading may build up very high excess PWP, without achieving significant consolidation. For the particular fine-grained coal tailings slurry tested, the rate of loading in the slurry consolidometer is varied to access its effect on the development and dissipation of excess PWP. The resulting consolidation parameters are evaluated and explained using the recorded settlement and PWP data.CITATION:Islam, S and Williams, D J, 2018. Optimisation of constant rate of loading slurry consolidometer testing of fine-grained coal tailings, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 72–80 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By L W. Palmer

"Evaluating the geological risk associated with ore deposits is becoming common practice in the mining industry. While geostatistical simulation is a useful tool for evaluating this risk, the effect of applying different types of simulation is less understood. For simulation of categorical variables like rock types, available methods perform simulation in fundamentally different ways. In this study, the geological risk relevant for informed mine planning is studied with two categorical simulation methods, PluriGaussian Simulation (PGS) and Sequential Indicator Simulation (SIS). Risk is expressed as a probability of repeated occurrence of lithological units in the same location across simulations. Significant differences are observed between the methods in terms of spatial distribution of risk. To identify the most plausible risk model, the input parameters at every step of both techniques are scrutinised. PGS and SIS inputs are classified as four parameters that are: fundamental to implementation of the methodfixed to enable comparison of PGS and SISdetermined by user interpretation, hence variablenormally optimised during application of PGS and SIS. The effect of parameter selection from categories 1 and 4 on the risk model is investigated using drill core data from a leucogranite deposit. A corresponding block model is created for assigning outputs from PGS and SIS. Risk models produced by either method are illustrated in a cut-out from the block model to enable bench-by-bench comparison. For PGS, risk associated with relatively rare lithologies is relatively sensitive to variation of parameters. Independent of the abundance of lithology, a location-dependent effect of variogram and vertical proportion curve parameter selection is observed, with risk increasing towards the deposit edge. Although SIS requires fewer inputs, single lithologies must be modelled in turn. Using small numbers of samples in the search neighbourhood, all risk models differ substantially. For larger numbers of samples, the risk models are similar. Overall it appears that the risk model produced using SIS is less sensitive to changes than PGS but further work is required to confirm this.CITATION:Palmer, L W and Glass, H J, 2014. Risk associated with rock type prediction using simulation techniques, in Proceedings Ninth International Mining Geology Conference 2014 , pp 217–228 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 18, 2014

By L Abrahamsson

The aim with this paper is to discuss experiences from the ongoing research project ‘Attract: A roadmap to attractive, inclusive, and safe mining workplaces’. The project’s aim is to analyse possibilities, effects, and consequences of the green and digital transformation in the Swedish mining industry from workplace, socio-technical and gender equality perspectives. The research project (2022–2025) at Human Work Science at Luleå University of Technology is financed by the strategic innovation program Swedish Mining Innovation (a joint venture by the national research funds Vinnova, Formas and the Swedish Energy Agency). The project includes a multidisciplinary research group of five senior researchers and five PhDstudents and a broad repertoire of methods, eg literature reviews, qualitative interviews with both managers and workers, workplace observations, workshops, surveys, and project seminars where the researchers and the company representatives together analyse the results. One important part of the project is the applied approach where the researchers work together with two mining companies and one subcontractor company. The project has two parallel main subprojects.

Sep 1, 2024

By G R. Hancock, W D. D P Welivitiya

is placed in a waste rock dump, which is usually later reshaped to be erosionally stable, initiate and sustain vegetation and ultimately integrate with the surrounding undisturbed landscape. However, it is unclear how this exhumed material will weather and evolve for most sites. Also, there is a lack of data on the weathering of post-mining materials. If weathering is better understood, then there is the potential to improve rehabilitation outcomes. To improve predictions of the evolution of soil properties and weathering-limited erosion, estimating the rate at which fine, transportable material is produced from the weathering of larger, non-transportable particles and the resultant fragment size distribution and how that distribution evolves over time is necessary. This study examines the weathering process for four different coalmine waste rock materials for a Bowen Basin, Queensland site. Materials obtained from various areas of the coalmine were subjected to cyclic wetting and drying and heating and cooling. Particle size distribution and other material properties were explored after each experimental cycle to ascertain how the material changes during the experimental cycles. The particle size distribution data of wet and dry cycles were used as input data in a numerical weathering model to explore the dynamics of the weathering process for each material sample. A Monte Carlo framework was employed to assess the geometry of the weathering products, weathering rate and the number of daughter particles produced within a weathering cycle. Then the SSSPAM Landscape Evolution Model was used to evaluate the influence of weathering on erosion and landscape evolution of a post mining landform. SSSPAM simulations with: (i) active weathering and (ii) without weathering were run for each material. The erosion rate and the overall landform structure were then compared between weathering and non-weathering simulations.

Aug 2, 2023

By M I. Pownceby, N Karimian, J R. Manuel, M J. Peterson

The CSIRO ore classification scheme for Pilbara ores was used as a reference frame to target recognisable ore types/textures with potentially elevated phosphorus content for detailed analysis. Particles of each individual ore texture were separated from a Brockman high-P ore and each class was characterised using methods including XRF, XRD, EPMA and synchrotron-based XAS. Results were then correlated with optical microscopy and hand specimen identification to establish any relevant associated mineralogical phases and/or textures. This represents a more systematic approach to identification of high-P ore components based on particle and goethite type and texture. The information can then provide the basis for more targeted P-removal strategies factoring in the relationship between particle/ore texture and phosphorus deportment

Sep 18, 2023

By Sano S, Ishikawa T, Nagaoka H, Hayashi Y, Hasegawa M

The stirred mill is regarded as one of the most efficient devices for micronising materials and has come to be actively used for preparation of fine particles. Recently, the demand for ultrafine particles was increased in many kinds of industries. In this paper, autogenous grinding to get submicron particles based on mutual friction feed material has been carried out using a stirred mill. The mill used was made of stainless steel and its volume was about 5.5 litres, and has 12 impeller blades. Sample used was limestone. In the present work, two operating parameters such as stirring speed and feed size of limestone were considered. The ground products were sieved in the size range from feed size to 325 mesh (45 lun), and from 45 to 0.17 pm the size distributions were measured by a laser diffraction and scattering method. The progress of grinding was evaluated by the increasing amount of submicron particles in products. As a result, the rotational speed of impeller with the minimum energy consumption to produce submicron particles was observed. It was found that the autogenous grinding with a stirred mill is an effective method for producing submicronized limestone.

Jan 1, 1993