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By Ruddle R. W.

The slags produced in copper smelting are largely composed of silica and ferrous oxide and may therefore be regarded as essentially ferrous silicates. A fair amount of information is available on the constitutions of the liquid slags used in copper smelting and, in this connection, the large volume of work being carried out on steelmaking slags should be helpful. Constitutional diagrams are available for most of the principal systems involved (SiO2-FeO; SiO2-FeO-Al2O 3; SiO2-FeO-CaO; SiO2-FeO- MgO; and SiO2-FeO-CaO-Al2O3) and these show that additions of Al2O3 and CaO reduce the freezing points of SiO2-FeO slags but that additions of MgO increase the freezing point. A certain amount of information is available on the thermodynamics of slags, but much further work on this subject is required. Modern theories of the constitution of liquid slags deny the existence of molecular compounds but consider that liquid slags are mixtures of various ions such as, Fe2+. O2- and SiO4(4-). Little appears to be known of the reactions between matte and minor constituents dissolved in the slag

Jan 1, 1953

By D. J. Allan, W. R. Wilson

For conventional aerospace aluminium alloys of the 2000 (copper) and 7000 (zinc, magnesium) series the recycling of process scrap from both metal suppliers and aircraft manufacturers is a well-established, worldwide industry. The recent introduction of a new family of alloys that incorporates lithium has posed a new challenge to the recycling industry owing to the high cost of lithium, its high reactivity to the atmosphere and to refractories and its absence from the specifications of all other registered alloys. Various process options for recycling have been identified, but vacuum distillation has been selected as the most cost-effective and technically feasible solution. Experimental work established that the separation of Li from AI-Li scrap is feasible and an industrial process has been designed. The economics of Li recovery are very sensitive to the AI-Li content of the feed material. Owing to the design of aerospace vehicle manufacturing plants it is expected that the swarf will be mixed with other alloys. A method of enriching this feed has been developed that is based on the control of swarf morphology by thermal and mechanical treatments as a precursor to eddy-current separation. After eddy-current separation and vacuum distillation small proportions of Li are retained in the AI residue. The effects of this on the properties of conventional AI-Si shape-casting alloys were investigated and safe threshold levels have been established.

Jan 4, 1993

By D. J. Fray, F. Tailoka

Microporous ceramic tubes (15 micrometre pore diameter) and PVC membranes (10 micrometre diameter) have been used as spargers in the electrowinning of copper from concentrated and dilute chloride electrolytes. At a current density of 600 A/m2 and a nitrogen gas sparging flow rate (at NTP) of 1.53 cm3/s per unit electrode length, it was possible to electrowin planar rather than powdery deposits with copper concentrations as low as 0.157 M. To obtain a planar deposit at higher concentrations of cupric chloride the most realistic optimum current density appears to be between 1 000 and 1 500 A/m2.

Jan 4, 1993

By Z. Sawlowicz

Finely dispersed, primary sulphide mineralisation in the Cu-Fe sulphide zones of copper-bearing shale of the Polish part of the Permian Kupferschiefer is mainly present in the form of framboids and spherules. This type of mineralisation is especially well preserved in organic-rich shale, where it often dominates over a later diagenetic mineralisation that consists of large grains and veins. In microscopic observations special attention was paid to composite grains of copper and iron sulphides. The results suggest that the Cu-Fe and Cu sulphides precipitated in the Kupferschiefer sediment before pyritisation of the framboids had ceased and that they replaced metastable precursors of pyrite. The precipitation of copper sulphides could have been delayed owing to the formation of Cu-organic complexes.

Jan 4, 1992

By L. T. Matthews, C. E. Loo

During sintering, porous ore particles are easily assimilated by liquid melt. Two simple models of the process are considered: the dissolution of a solid by a liquid and the penetration of a liquid into a porous solid. Laboratory sintering studies covering a range of experimental conditions were undertaken to characterise the assimilation of large particles of ore and flux by melts formed from different mixes of fines. For ores, the process appeared to be complicated by the detachment of fines from the ore surface prior to melt formation, according to the mass of adhering fines and surface roughness of the particle. This delayed the onset of assimilation and sometimes reduced it, although melt penetration was fast and effective. Studies using different temperature profiles suggested that the assimilation of haematite was controlled by the transport of Fe2O3 away from the surface of ore particles. The assimilation of limestone depended more on thermal conditions than on the three magnesia-bearing minerals considered. Changing the composition of the initial melt significantly altered the extent of assimilation of ores and limestone, but again had a less marked effect on the magnesia-bearing fluxes.

Jan 8, 1992

By O. Dojcar

Equations for calculating the parameters of controlled blasting (burden and spacing of boreholes and weight of the bottom charge) are derived and analysed on the basis of empirical values and made more precise through incorporation of the properties of the rock being blasted and explosive applied. For the success of controlled blasting the correct choice of the blasthole diameter/charge diameter ratio is critical. This relation is defined as the coefficient of radial decoupling of the charge; it is recommended that it is chosen to be between 3 and 3.5. Analysis of smooth blasting, cushion blasting and presplitting indicates that cushion blasting is a less destructive alternative to smooth blasting, but it has a slightly higher blasthole consumption and limited possibilities of use. There are definite economic advantages to controlled blasting, especially in rock masses of low and medium strength

Dec 1, 1996

By J. Drzymala, K. L. Wolters, T. Chmielewski, T. D. Wheelock, D. H. Birlingmair

Microflotation tests were conducted with a modified Hallimond tube equipped with a fritted glass disk and magnetic stirrer to determine whether the results would support an equation that predicts a linear relationship between particle size and the reciprocal of particle density in water for a specified flotation recovery in a given time. Data obtained with the tube for either hydrophilic or hydrophobic solids fit the equation satisfactorily. It was also shown that the natural flotability of molybdenite is somewhat less than that of elemental sulphur and that sodium dithionite is a good depressant for sulphurised pyrite. In addition, it was found that the untreated pyrite and galena used in the study were hydrophilic and did not float by particle-bubble attachment.

Jan 4, 1992

By R. E. T. Hill

"A laboratory study was undertaken to determine the condensed equilibrium phase relations at 600°C in that portion of the quaternary Fe-Ni-Cu-S system which lies in the neighbourhood of the monosulphide solid solution (MSS). The study sought to determine to w hat extent copper affects the temperatures of stability and compositions of iron-nickel sulphides in bulk compositions similar to those of massive Fe-Ni-Cu ores. Experimental data, including stable phase assemblages and phase compositions, are presented.In the quaternary system at 600°C MSS forms stable phase assemblages with pentlandite, chalcopyrite solid solution, pyrite and vaesite. Over the range of bulk compositions displayed by natural ores copper as well as metal/sulphur ratio have a significant effect on the thermal stability of pyrite and pentlandite. Errors therefore accompany the widespread practice of ignoring copper or chalcopyrite when the mineralogical and compositional changes that have accompanied the initial cooling of primary magmatic sulphides or their subsequent homogenization during isochemical metamorphism are being deciphered. These errors are most significant for ores the bulk compositions of which lie tow ard the sulphur-deficient side of the cupriferous MSS. Temperatures as much as 300°C above the copper-absent value are possible for the interpreted upper stability limits of pentlandite in these ores.The experimental data show that up to 2.0 at% copper can occur in pentlandite stable at 600°C in a bulk composition equivalent to natural magmatic ores. This is equivalent to nearly 10 vol% chalcopyrite. Pentlandite contains more copper than coexisting MSS and the copper content of both phases increases with increasing iron."

Jan 1, 1984

By J. H. E. Jeffes, K. T. Jacob

Solid oxide galvanic cells, of the type: Pt,Ni-NiO | Solid electrolyte | O(metal),Cermet,Pt, were used to measure the activity coefficient of oxygen in liquid Cu at 1 100 and 1 300°C and in Pb at 1 100°C. Similar cells were used to study the activity coefficient of oxygen in the whole range of Cu + Pb alloys at 1 100°C and in Pb-rich alloys at 900 and 750°C. The results obtained are discussed in terms of proposed solution models. An equation based on the formation of 'species' of the form M(2)O in solutions of oxygen in binary alloys is shown to fit the experimental data

Dec 1, 1971

By Ruddle R. W.

Magnetite occurs in the reverberatory furnaces, blast furnace and converter (a) as the result of its presence in the materials charged, and (b) as the result of oxidation of the FeS in the charge in the absence of sufficient SiO2 to slag the FeO as it is produced and thus prevent its subsequent further oxidation. Magnetite is reduced by FeS according to FeS+3Fe3O4=10FeO+SO2 and similar reactions. This reaction is markedly affected by temperature and does not proceed to any important extent below about 1200°C. To ensure comparative freedom from magnetite it is therefore necessary to raise the temperature of the furnace to the highest practicable figure and to use plenty of siliceous flux. Since the maximum operating temperature is likely to be limited by the resistance of the refractories to attack by the slag, investigation of the factors affecting this attack should be helpful. It is reasonable to suppose that the formation of magnetite might be minimized by ensuring intimate admixture of matte and slag during conversion so that silica is readily available for combination with ferrous oxide as the latter is formed. The literature gives no clue to the importance of this factor and some experimental work on this aspect might be fruitful

Jan 1, 1953

By T. Guyaguler

An analytical technique using computer-based multiple-regression methods was employed to determine the relation between the dust-producing index and inherent rock properties of typical samples from a coal-producing area, one of the aims being to provide a preliminary predictive tool for practical use. The investigation demonstrated that factors varied in their influence under different conditions, the brittleness:toughness ratio and the hardness being the most significant inherent properties with hardness showing the highest positive correlation coefficient

Jun 13, 1905

Discussion of the paper presented at the North Staffordshire Institute of Mining and Mechanical Engineers' general meeting held in Stoke-on-Trent, March 27th 1916, with Mr. John Gregory, President, in the chair, included contributions by Gregory J., Cadman J., Hartley J.W., Wain E.B. and Henshaw A.M., followed by the author's reply

Dec 1, 1916

By D. G. Skinner, J. H. Griffiths, F. T. Williams, A. G. Withers

"The absence of homogeneity, in dust-clouds underground indicates the use of a method in which the volume of air sampled is an appreciable proportion of the total volume under consideration. Of the available methods, only the impinger and gravimetric techniques seem to comply with this requirement. In practice, greater efficiency of collection of the smaller particles is possible by the use of a gravimetric filter than with the impinger. For this reason if, as seems desirable, a standard method of sampling be sought, the adoption of a gravimetric technique is to be recommended.Provided that the amount of dust collected is reasonably large, the paper filter would seem to be preferable to the solid crystal type of filter on account of its greater convenience in use.Alternative methods of sampling are desirable to cover the wide range of practical conditions."

Jan 1, 1947

By D. J. Buchanan

British Coal's mining research programme is directed towards the strategic objectives of reducing production costs, improving product quality and resolving health, safety and environmental issues. The strategy for R&D is described and selected parts of the programme are reviewed. Two major initiatives are directed towards reducing production costs: geotechnics and automation. Integrated exploration techniques are used to delineate geological structures as an aid to mine planning. Rockbolting is being rapidly introduced and the in situ stress field has been found to be of significant influence. Automation is the subject of a major programme. A strategy for coal quality has been devised. The health, safety and environmental programme concentrates on the traditional hazards together with surface environmental problems.

Jan 12, 1992

By R. Vikram

IMAGES (Integrated Mapping Applications Graphical Evaluation System) is a computer graphics system developed by British Coal for mine planning. The objectives of the system are to increase the profitability of mined coal through a combination of direct and indirect benefits. The system is flexible and can be used in part or in full at a mine as a stand-alone system or as a remote location of a central corporate system.

Jan 12, 1992

By K. El-Barawi, Hussein M. Kamal

Chlorination was performed of iron-rich chromite ore from Barramyia, United Arab Republic (UAR), together with its concentrate. The effects of change of grain size, chlorine gas flow rate, time and temperature were studied. The extent and mechanism of chlorination were followed through chemical and structural analyses of the feeds and complete chemical analysis of the chlorination products. By conducting the chlorination process for short periods at 600°C or lower temperatures, products having high Cr-Fe ratios suitable for ferrochrome production can be obtained.

Dec 1, 1971

By A. C. Dunham, Y. D. Drakapoulos, P. W. Scott

The Pt and Pd occur alloyed with copper in small, irregularly-shaped grains, 0.25-5.0 micrometers in maximum dimensions. Grains of unalloyed native copper are also present. The grains are completely surrounded by or marginal to magnetite with inclusions of Ni-Fe-Co sulphides and native Ni-Fe, which is apparently a product of the serpentinisation process. Crystallisation of the Pt-Pd-enriched copper probably occurred at the same time, at low temperature, but the previous form of the Pt and Pd is unknown as no earlier PGE phases have been found. While Pt and Pd minerals are usually important in early-magmatic base-metal sulphides, Pt alloyed with Cu is extremely rare and apparently occurs only very late in the paragenetic sequence. A Cu alloy with Pd dominant over Pt and only minor amounts of other elements appears not to have been reported

Jun 14, 1905

By NA NA

Listing safety award winners, £I43M has been added to proceeds from coal privatisation in the year to March 1997, bringing total revenues to over £1.3bn, some company news in brief.

Jan 8, 1997

By D G. Oldfield

Pall has developed and supplied to several airlines cabin air libers to provide clean air for passengers and crew in flight, while reducing airline operating costs. Most of today's modern commercial passenger aircrafts employ cabin air recirculation as a means of reducing operating costs. With large numbers of passengers being subject to an increasing proportion of recirculated air for hours at a time, the matter of cabin air quality, with particular respect to the health effects on passengers and crew, has to be addressed. Commercial pressure will ensure that the airlines and aircraft manufacturers will not revert back to the total fresh air systems of the 1960s and 1970s. In fact, feasibility studies are already being undertaken to look at increasing the proportion of recirculated air to 80% and above. With the application of specialist nitration technologies. Pall is able to ensure that the requirements for economy are met whilst ensuring that the air is effectively rendered as 'fresh air’ each time it is recirculated.

Jan 9, 1996

The mineralogical composition of the ore was determined and the mineral phases with which nickel is associated were identified. The ore was prepared by grinding to -420 micrometres and classification into granulometric fractions. Prior to the main series of experiments the effect of agitation rate on nickel recovery was investigated. The influence of sulphuric acid concentration, temperature and particle size on the kinetics of nickel extraction was then studied, both quantitatively and qualitatively, over fixed value intervals. Application of the initial rate method enabled determination both of the order of reaction with respect to sulphuric acid concentration and the activation energy for the dissolution of nickel. The results indicate that a physical mechanism can be ruled out as the rate-determining step in the extraction of nickel from the ore and that a chemical mechanism is more likely

Dec 1, 1991