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By Longjiang Li, Mao Jiang, Zhihui Shen, Guizhou University, Yin Pan

This paper aims to study the influence and action mechanism of collector Y-89 on the flotation of auriferous pyrite. The measurement to identify adsorption quantity, IR and XPS spectrum analysis and flotation experiment made on the pure mineral were conducted. The research results show that when the dosage of MIBC is 20 mg/L, and pH of 8, the dosage of Y-89 over 60 mg/L, the pyrite recovery rate is greater than 80%.And when the dosage of Y-89is 60 mg/L, dosage of MIBC 20 mg/L, the pH in a wider range (pH=4~9), the recovery is greater than 75%. When the pH is above 10, the pyrite is depressed and its recovery rate is found to be dramatically dropping. Adsorption quantity measurement also shows that the strong alkaline conditions inhibit the adsorption of Y-89 on the surface of auriferous pyrite. IR measurement indicates that chemisorption of Y-89 occurs on the surface of auriferous pyrite. XPS spectrum analysis indicates that without adding Y-89, oxidation reaction occurs on the surface of pyrite. But when Y-89 is added, the chemical environment of Fe on the surface of pyrite has changed. Such findings indicate that with Y-89, chemisorption occurs on the surface of auriferous pyrite.

Jan 1, 2014

By V. A. Luganov

The processing of pyrite concentrates may be accomplished with a preliminary enrichment due to withdrawal of iron sulfides from initial concentrate. The withdrawal of iron sulfides is possible with the help of magnetic separation when the magnetic iron sulfides (pyrrhotites) separate from non-magnetic fraction?the sulfides of non-ferrous metals. The conversion of non-magnetic pyrite to magnetic pyrrhotites of adjusted structure occurs because of roasting with the withdrawal a part of sulfur. The resultant pyrrhotites are strong ferromagnetic with hexagonal structure. This paper contains results of studying magnetic properties of pyrrhotites, findings of the de-composition of initial pyrite with the consequence homogenizing of product and hardening of product of decomposition in liquid nitrogen. Define the type of pyrrhotites super lattice structure, was established that at increasing of sulfur contention the magnetic properties of pyrrhotites are change ? pyrrhotite begin evince the properties of antiferromagnetic material and magnetic susceptibility of material is interruptive changing from 0 to 1.7×10-3~1.9×10-3 SI units/g system. The paper contains results of technological researching of pyrrhotizing-magnetizing roasting of pyrite concentrates in different condition: in unoxidizing, with the decreasing contention of oxygen and in autogenous regime in air atmosphere. Established that the magnetic susceptibility of products depend of pyrite degree dissociation and achieve 2×10-3~3×10-3 SI units/g system at 40%~45% desulphurization. Defined the conditions of steady regime autogenous roasting, at resultant products possess coefficient of magnetization, and this can be used magnetic separation for separating ferromagnetic pyrrhotites from gangues and non-magnetic sulfides of non-ferrous metals. This technology of pyrrhotizing roasting is recommended for effecting in industrial condition. The initial materials and products of roasting subjected to chemical, thermogravimetric, Moss-bauer spectroscopy and X-ray analysis, defined the magnetic properties.

Jan 1, 2014

By L. Burdukova

"In flotation, depressants are used to reduce the amount of gangue that reports to the concentrate and hence increase the selectivity of the flotation process. At the University of Cape Town extensive batch flotation tests are carried out to evaluate industrial depressants and standard procedures have been developed over the years.This study was conducted in order to develop an improved method for comparing depressants using machine vision as an aid. The modified method of batch flotation involved a test with prolonged intervals between scraping to allow more time for the froth to build up and mature.This method of testing showed increased differences between the flotation performance obtained as represented by grade recovery curves for carboxymethyl cellulose and guar depressants when compared to the standard method of testing with shorter scraping intervals. The improvement was attributed to reduced entrainment resulting from longer drainage time in the froth and therefore yielded a better test for comparing depressants on the basis of true gangue flotation with minimized entrainment. As expected, the sulphide recoveries were unaffected by the change in method. The machine vision system also added to the information obtained during these tests by recording bubble size trends throughout the tests which were later analyzed and related to the amount of flotable gangue in the froth. Modifications are recommended to improve the usefulness of machine vision in batch flotation."

Jan 1, 2003

By J. Finch, F. Rosenblum, McGill University

The self-heating of sulphides can be a major hazard in mining operations and concentrate handling, particularly during transportation and associated storage. Self-heating results from the oxidation of sulphide minerals and can vary from being insignificant to potentially hazardous to life and infrastructure. It is essential that there be a reliable test methodology that can categorize a given sulphide material as to its self-heating potential. By their nature, sulphide ores and concentrates are complex and variable mineral combinations making it difficult to predict their self-heating behavior a-priori based on mineralogy or with a simple "snapshot" test. Furthermore, self-heating behavior will depend on the state of oxidation of the sulphides as well as time, temperature and humidity. A review of available testing apparatuses and protocols that can be used to assess self-heating potential is presented. Each of these methodologies was examined in relation to its ability to predict the latent self-heating hazard of a sulphide material. Several of the methods were compared to illustrate their strengths and weakness. The results indicated that a number of the test protocols may produce false negative indications of self-heating potential, constituting an obvious concern to the industry.

Jan 1, 2014

By U. M. J. Boin, E. V. Verhoef

Pyrometallurgical reactors constitute a key processing component in the total primary and industrial/recycling resource cycle, being involved both in primary smelting, converting and extraction, as well as the reprocessing of scrap, from aluminium cans to end-of-life automobiles. Therefore the pyrometallurgical reactor?s role in achieving sustainability is the central theme discussed in this paper since optimising their operation minimises waste, residue and offgas (NOx, dioxin, CO2) and maximises product quality and therefore efficiency. To effectively control the overall resource cycle, one needs to take a systems modelling approach of the whole cycle, seeking to also understand the dynamic process behaviour of the individual components of the cycle, and then especially the part that contributes most to the chemical conversion, namely the pyrometallurgical reactor. This paper highlights the role of pyrometallurgical thermodynamics in the whole resource cycle and specifically places equilibrium thermochemistry in the context of process dynamics where large, variable inventories are recycled or maintained within the system. This paper will therefore review the semi-empirical dynamic modelling tools, which are used to model complex systems with the specific goal of developing dynamic predictive models, which also include slag-alloy chemistry, towards controlling the recycling in a feed forward manner. To illustrate the primary production of metals, high carbon ferrochrome and Ni-Cu-matte smelting will be presented as a brief case study. Also fundamental studies in blast furnace and waste incineration kilns will be given. It also will show how the distributed nature of the chemistry of melts in the case of primary extraction, and industrial (recycling) materials such as recycled end-of-life vehicles, have a significant impact on the process outcomes and model predictions. It is therefore argued that the fundamental thermodynamics and kinetics in metallurgical reactors play a final crucial role in modelling the closed material cycle, but only when it is used in conjunction with process systems theory based on reconciled data for parameter estimation and model calibration. System models for aluminium and car recycling will be given as well as a dynamical system model that describes the interconnected material flows for Ag, Au, Bi, Cu, Fe, Ni, Pb, PGM, Sn and Zn for a study on lead-free solder.

Jan 1, 2003

By N. D. Ilankoon

"The use of thiosulfate as an alternative lixiviant for cyanide to treat complex refractory ores followed by the use of ion exchange resins (IX resins) for gold recovery has become an industrial reality. In this study, polyethylenimine (PEI) coated iron oxide magnetic nanoparticles (MNPs) were used to recover gold from the leaching solutions that consist of calcium thiosulfate, copper and gold. The gold loaded MNPs were easily separated from the solution using an external magnetic field. Proposing a novel adsorbent with characteristically easy solid-liquid separation, to recover gold from synthetic thiosulfate leaching solutions and gold elution and reuse of MNPs were the main objectives of this study. Adsorption isotherm studies revealed that the data fitted both Langmuir and Freundlich isotherm models equally well. The maximum adsorption capacity was 18.5 mg/g at pH 8 and 50?C. According to thermodynamic studies the physisorption process was exothermic and spontaneous. Gold and copper elution, and the regeneration and reuse of the nanoparticles were investigated and promising results were obtained. Different elution systems comprising sulfites, chlorides, glycine, EDTA (ethylenediaminetetraacetic acid) and sodium hydroxide were considered. Among them, EDTA for copper elution and NaOH for gold elution were the most efficient eluants. Regeneration and reuse studies revealed that the MNPs can be used for several cycles without significant performance loss. INTRODUCTION Although cyanidation has been used for gold leaching for more than 100 years, some major drawbacks associated with cyanidation have led to a quest for alternative lixiviants for gold leaching. Cyanide is ineffective in treating carbonaceous refractory ores as gold cyanide complex is adsorbed onto the native carbon in the ore itself known as preg-robbing. On the other hand environmental concerns associated with cyanidation drives the need for environmental friendly alternatives for cyanide. As of today, thiosulfate is known to be the most extensively studied and most promising alternative lixiviant for cyanide in both technical and environmental perspectives (Aylmore and Muir 2001, Oraby 2009)."

Jan 1, 2018

By E. V. Koporulina, I. Zh. Bunin, M. V. Ryazantseva

"We studied the mechanism of structural and chemical transformations of columbite, tantalite, zircon and feldspar surface during the treatment by high – power electromagnetic pulses (HPEMP) using the methods of X - ray photoelectron spectroscopy (XPS), analytical electron microscopy (SEM - EDX), Kelvin probe force microscopy and flotation experiments. According to XPS and SEM - EDX data, major changes in the atoms chemical state of investigated minerals surface are related with formation and modification of functional cover and changing in concentration (% at.) of hydroxyl groups on the mineral surface, leading to increase in the contrast of technological properties of the rare metals minerals. Research has identified the optimal parameters of HPEMP - treatment of rare - earth minerals Npuls ??104, Ttreatment ??100 sec. improving the selectivity of the flotation separation of columbite and zircon. The difference in mineral recovery into the froth (? e) before and after HPEMP - treatment was about 11 % and 24.5 %, respectively. No significant increase was observed in the flotation activity of feldspar. This study's findings demonstrate the effectiveness of HPEMP - treatment in inducing a controlled change in the structural and chemical properties of rare - earth minerals and improving the process efficiency for the processing of rougher tantalum - niobium gravity concentrates.INTRODUCTIONThe importance of improving the processing methods of tantalum-niobium ores and concentrates is explained by the mineralogical properties of rare - earth ores. These are properties such as the variable mineral, chemical, and grain size composition, complex morphometric properties, and the dissemination of ore mineral grains of micro - and nanometric size. Iron oxide and hydroxide films on the mineral surfaces neutralize the surface physicochemical and absorption properties of the minerals. Both in Russia and globally, nonconventional (non - mechanical) methods are being developed based on physicochemical, electrochemical, and pulsed energy impacts to improve the efficiency of disintegration and liberation processes of disseminated mineral complexes and to enhance the contrast of the structural, chemical, and technological (floatability) properties of refractory ores. This study is devoted to the investigation of the applicability of high – power electromagnetic pulses (HPEMP – treatment) for the change in the structural and chemical properties of rare - earth minerals and improving of the flotation properties contrast."

Jan 1, 2018

By G. Bulut, Ü. Yenial

"Heavy metals contamination in aqueous systems can be found in a variety of industries, in particularly mining, metal processing, finishing and plating. Water containing more than 0.5 ppm heavy metal considered as a toxic due to harmful effects on health. The major techniques employed for heavy metal removal from industrial wastewaters include precipitation, reduction, ion-exchange, and adsorption. Adsorption is a heavy metal removal method for aqueous systems. As a common adsorbent, activated carbon has been used in treatment but it is ineffective on some elements. Thus, there has been a research for developing highly effective and selective adsorbents. In this study the adsorption of lead and arsenic ions on to coal waste and red mud waste was studied. The experimental parameters were determined as pH, equilibrium time and the initial concentrations, activation by heat treatment and the blend of adsorbents. According to their adsorption capabilities, red mud was found to adsorb lead and arsenic ion with high efficiency but coal waste did not adsorb arsenic ion. However the binary adsorptions of these ions were enhanced the adsorption efficiencies. In addition the blend of coal waste and red mud affected the adsorption efficiency. INTRODUCTION As a result of rapidly developing industry and excessive use of water resources, the need of clean water and wastewater management appear as a problem. Wastewater recycling activities and researches come to the fore for an effective use of wastewater. Recycling of wastewater, which contains heavy metals harmful to the environment and human, is a difficult process. Heavy metals are generally divided into three categories: toxic metals, precious metals, radionuclides. Wastewaters from various industries, containing heavy metals, are the main polluters of water and soil. Although their toxic structures, heavy metals are used extensively in industry as they have technological significance. Usually mining industry, metal industry and industrial organizations produce heavy metal containing wastewaters (Volesky 1990, Ting and Lawson 1991, Bishop 2002)."

Jan 1, 2018

By E. V. Koporulina, I. Zh. Bunin, M. V. Ryazantseva

"We studied the mechanism of structural and chemical transformations of columbite, tantalite, zircon and feldspar surface during the treatment by high – power electromagnetic pulses (HPEMP) using the methods of X - ray photoelectron spectroscopy (XPS), analytical electron microscopy (SEM - EDX), Kelvin probe force microscopy and flotation experiments. According to XPS and SEM - EDX data, major changes in the atoms chemical state of investigated minerals surface are related with formation and modification of functional cover and changing in concentration (% at.) of hydroxyl groups on the mineral surface, leading to increase in the contrast of technological properties of the rare metals minerals. Research has identified the optimal parameters of HPEMP - treatment of rare - earth minerals Npuls ? 104, Ttreatment ? 100 sec. improving the selectivity of the flotation separation of columbite and zircon. The difference in mineral recovery into the froth (? e) before and after HPEMP - treatment was about 11 % and 24.5 %, respectively. No significant increase was observed in the flotation activity of feldspar. This study's findings demonstrate the effectiveness of HPEMP - treatment in inducing a controlled change in the structural and chemical properties of rare - earth minerals and improving the process efficiency for the processing of rougher tantalum - niobium gravity concentrates.INTRODUCTIONThe importance of improving the processing methods of tantalum-niobium ores and concentrates is explained by the mineralogical properties of rare - earth ores. These are properties such as the variable mineral, chemical, and grain size composition, complex morphometric properties, and the dissemination of ore mineral grains of micro - and nanometric size. Iron oxide and hydroxide films on the mineral surfaces neutralize the surface physicochemical and absorption properties of the minerals. Both in Russia and globally, nonconventional (non - mechanical) methods are being developed based on physicochemical, electrochemical, and pulsed energy impacts to improve the efficiency of disintegration and liberation processes of disseminated mineral complexes and to enhance the contrast of the structural, chemical, and technological (floatability) properties of refractory ores. This study is devoted to the investigation of the applicability of high – power electromagnetic pulses (HPEMP – treatment) for the change in the structural and chemical properties of rare - earth minerals and improving of the flotation properties contrast."

Jan 1, 2018

By Haragobinda Srichandan

The present study aimed to investigate the bioleaching efficiency of moderate thermophilic microorganism in a growth medium without Fe supplement on three different size fractions of spent catalyst obtained from petroleum refinery. All the experiments were conducted on shake flasks at a temperature of 65 °C and a pulp density of 10% (w/v) on three size fractions viz. 45-106 µm, 106-212 µm and >212 µm and a working volume of 100 ml comprising of 10 ml of microbial inoculums and 90 ml of Modified Kelly medium. The parameters like pH, redox potential, viable planktonic cell count and the amount of acid addition was measured and quantified on regular basis to follow the progress of the bioleaching. The pH varied much in the lag and logarithmic phase of the experiments but stabilized toward the stationary phase. The total acid additions in each batch experiment were determined the amount of Conc. H2SO4 requirement, which ranged between 683-757 kg/ton of spent catalyst. The redox potential values ranged between 625-650 mV, Ag/AgCl, but were very low ranging between 350-450 mV during initial period. The planktonic viable cell count ranged between 108-109 cells/ml active in the bioleaching system, without any toxic influence of the spent catalyst, but initially due to fall in redox potential and new environment for the microbes, their population was low. The leaching yield of Ni was found to be promising with very high leaching yield of 92-96% followed by Al as 61-62%, which means both Ni and Al leaching were favored by the moderate thermophilic bioleaching compared to the mesophilic bioleaching. There was very little difference in the leaching yield, when compared with different size fractions and hence grinding can be avoided prior to leaching. This process seems to be economical as no Fe source is supplemented together with no requirement of grinding and over all a biological process resulting for an eco-friendly process for future optimization of the metal recovery from petroleum refinery spent catalysts. Keywords: bioleaching, spent catalyst, thermophile, 9K medium

Sep 1, 2012

By M. A. Wei

Effects due to some metal cations, such as Ca2+, Mg2+,Fe2+, Fe3+, Cu+, Cu2+, Zn2+ and Al3+ etc., which are produced in the pulp when the complicated ore is dipped in the deioned water, on the flotation of chalcopyrite and galena with the isopropyl thionocarbamate as collector have been studied. It is found that chalcopyrite floatability is not influenced by these cations, and the cations can be di-vided into three types according to their effects on the purified galena?s floatability with the same conditions, as activator such as Cu+; as depressant such as Al3+, Fe3+, Fe2+, Zn2+ and Cu2+ , unaffective such as Mg2+ and Ca2+.

Jan 1, 2014

Producing robust agglomerates with desirable structural properties is the key to success of the heap leaching of complex, low-grade nickel laterite ores. Mechanically strong but porous agglomerates with narrow size distribution (e.g., 5 ? 40 mm) are required to build permeable and perennially stable heaps of 4 ? 10 m height. The characterization of granules? microstructure is essential for greater understanding and correlation with the concomitant mechanical properties and robustness. In this study, we used non-destructive, computed X-Ray tomography analyses and scanning electron microscopy (SEM) in tandem with conventional compressive strength,and integrity/stability tests to draw links between nickel (Ni) laterite agglomerate strength/stability, internal microstructure (e.g.,porosity, inter-particle bridges) and binder type. It is shown that binder composition (e.g., tap water vs. 30% w/w H2SO4) and post-agglomeration drying both significantly impact on granules? physicochemical and microstructural properties. Acidic binder, in contrast with tap water, leads to significant incongruent leaching of different species from particles during ore-binder mixing and agglomeration. Upon wet agglomerate curing, solidified/recrystallized leached species form strong intra-granular solid bridges which, lead to greater compressive strength of dry agglomerates. Structural stability/integrity of cured agglomerates in acidic solution, however, decreases dramatically due to greater porosity and acid solubility of intra-granular solid bridges. These findings are useful in shedding more light on agglomerate structure characteristics and their optimization for enhanced column and heap leaching with concentrated sulphuric acid.

Sep 1, 2012

By A. Chattopadhyay

Porphyry copper deposits are the most important source of copper and also gold within the orogenic belts. These deposits are characterized by low grade copper ore (0.2% to 1% copper) and host precious metals like gold, silver and platinum. A characterization tool has been developed for complex porphyry type copper-gold deposits with an aim to quantify copper and precious metal deportment. This quantification is a challenging task due to low grades and also due to the presence of both visible and invisible precious metal content in different sulphide and non-sulphide phases. Studies were initiated on various complex, ore deposits and also on samples representing various processing streams such as flotation and leach products. This paper presents the development of a systematic approach to diagnostic metallurgy using state-of-the-art optical and automated mineralogy, micro-probe, dynamic SIMS and TOF-SIMS analysis for quantification of invisible and visible precious metals content in various species. The relevance of this characterization to metallurgy will also be briefly discussed in this paper.

Sep 1, 2012

By I. A. Khabarova

The paper presents the results of experimental investigations of the effect by high-power nano-second electromagnetic pulses (HPEMP) on change of surface composition, physical-chemical and flotation properties of pyrrhotite, and search of optimal combination of flotation reactants providing increase of metal extraction from disseminated copper-nickel ores. Preliminary electropulse effect on products before flotation allows to create optimal conditions for flotation separation of pentlandite and pyrrhotite owing to forming the new phases and defects on the surface of sulphides. It was established, that the yield of monomineral fractions of pyrite, pyrrhotite and chalkopyrite increases by 5%~15 %, compared with flotation with one butyl xanthenes (BX), during usage of combination of thionic carbamate (isopropylmethylthionocarbamate (ITC) or isopropylethyl- thionocarbamate (Z-200) with butyl xanthate (BX). Sorption of investigated reactants and strength of their fixing on the surface of minerals are examined; it helped to reveal the cause of rise of floatability of sulphide minerals for the case of combination of reactants. Preliminary high-pulse processing and reactant conditions with usage of combination of thionic carbamate and xanthate have been tested on the sample of disseminated copper-nickel ore from Norilsk region.

Jan 1, 2014

By Azin Zangooi, Cesar Gomez, James Finch

Frother concentration is a variable which significantly affects the flotation performance by decreasing bubble size and helping froth stabilization. Variations in frother concentration, which mostly go unnoticed in industrial operations, may affect these functions. Some factors that can cause variations include the fact that frothers are normally dosed based on feed tonnage and not solution concentration, unstable frother delivery, incomplete dissolution for low solubility frothers, addition of frother-free wash water, remnant frother in recycle waters and frother partitioning to the froth. A colorimetric technique developed for determining frother concentration on site makes it possible to detect the occurrence of these problems and to establish their magnitude, allowing conditions to be adjusted to reduce frother concentration variations. By sampling and analysis, frother distribution throughout a circuit can be established, referred to as ‘frother distribution mapping’. Experiences at several concentrators processing sulphide ores are used to illustrate time restrictions for sample analysis, and to demonstrate temporal and spatial frother concentration changes as a consequence of variations in the grinding stage, recycled waters containing frother, and frother partitioning.

Jan 1, 2014

By Gerke Gilian, Pretz Thomas, Pehlken Alexandra

"The evaluation of health hazards within the treatment of mineral and waste materials is gaining more and more importance in industrial countries. The need to control occupational health and safety has been recognised, and regulations which describe general protective measurements for personnel provide a tool to protect their health. It is the aim of the paper to give an outlook for practical approaches to risk assessment and to present measures for exposure reduction in accordance with the state of the art in Germany.Both the treatment of minerals and of waste materials are described in relation to the risk assessment. The method of evaluating health hazards in the two industries is similar and therefore both examples are presented next to each other.The example presented in the paper is the German “Biostoffverordnung” (the regulation for biological materials) which is important for the waste treatment industry. All kinds of waste treatment facilities (like composting facilities, waste dumps, sorting facilities for packaging materials) are obliged to carry out an assessment of health hazards for a variety of working areas and working places. The possible safety requirements deriving from this regulation are presented and discussed under the aspect of biological hazards."

Jan 1, 2003

By Sanjay Chaudhuri, V. K. Kalyani, Pradeep Kumar Singh, T. Gouri Charan

"Indian coal industry is the world's third largest in terms of production and fourth largest in terms of proven coal resources. Indian coal deposits are generally of high ash content varying from 24 to 50%. The coking coal reserves of India constitute about 12% of the total coal inventory, and the coals are washed in washeries, before being used for metallurgical purposes. The processes used for washing coking coal is Jigs, Heavy medium bath and Cyclones for the sizes upto 0.5mm, while the coal fines are washed in spirals and conventional flotation cells. Extensive studies were carried out for understanding the performance of an operating conventional flotation plant. The performance studies revealed that appreciable quantity of clean coal is being lost in the tailings due to varied reasons and the required quantity and quality was not achieved. In this study, laboratory Flotation experiments were carried out to examine the cleaning characteristics of the said tailing and to determine the effective process parameters for recovery of clean coal at desired ash level ( 16-17%). Response Surface Methodology was applied to investigate the operating conditions of the Froth Flotation for modeling and optimization. Primary study reflects that there is a possibility to recover clean coal at 16-17% ash level with a yield of about 60-70% from that Flotation tailing of feed ash about 28%.INTRODUCTIONMost of the Indian coking coals are difficult in cleaning characteristics and high ash content due to its drift origin and its age of formation for more than 225 million years. Indian coking coal reserve is limited about 12% of total coal reserve. The minerals are homogeneously mixed with the coal macerals. The open cast mining practice and mechanized mining methods are being adopted to meet the increasing demands of coals resulting in generation of more coal fines and subsequently the quality is deteriorated. Indian good quality coking coal reserves of higher seams are fast depleting and hence coking coals of difficult cleaning characteristics of lower seams (LVC) are being now explored. Due to increased mechanization of coal mines to cope up the increased demand and followed by size reduction of lower seam coals in search of better liberation , the coal fines are increasing by leaps and bounds. The processes used for washing coking coal is Jigs, Heavy medium bath and Cyclones for the sizes upto 0.5mm, while the coal fines are washed in spirals and conventional flotation cells."

Jan 1, 2018

By Volker Vogt, Wolfgang Sand, Eberhard Gock

"It was discovered that the selective activity of bacteria during the extraction of raw material concentrates by means of flotation could also be achieved with extracellular polymeric substances (EPS) excreted by bacteria. EPS, which is extracted by means of centrifuging bacterial cultures, can help to significantly reduce the use of cyanides, approximately 200,000 t/a of which are used for ore dressing today.The bacterium used was Acidithiobacillus ferrooxidans. In order to identify the bandwidth of the oxidation activity, 20 bacterial strains of the strain collection of the University of Hamburg were attracted to iron(II) sulfate and pyrite under defined conditions. All strains oxidized iron(II) sulfate ten times faster than pyrite.EPS has so far been derived from four strains. In general, EPS extracts are divided into a hydrophilic and a hydrophobic fraction. The hydrophilic fraction is composed of e.g. fucose, rhamnose and glucose; fatty acids such as dodecanoic acid, hexadecanoic acid, octadecanoic acid and nonadecanoic acid were found in the hydrophobic fraction.Pure mineral phases and mineral mixtures were used for the flotation tests. As opposed to current knowledge, the results were reproducible with technical flotation machines."

Jan 1, 2003

By Sergey S. Gudkov

In the current climate of changing the approach to mining and treatment of mineral resources, processing technologies are being developed that require little maintenance and are economically as well as ecologically sustainable. This may also involve the development of entirely new ways of ore processing. One promising approach is to use bioleaching for the pretreatment of gold refractory ores to cyanidation. Capital costs for vat bioleaching of concentrates and ores are very high and cannot be applied for small or medium-size deposits. IRGIREDMET JSC carried out bio heap leaching test work on refractory ore samples from three Russian deposits. Following this biological treatment a combination of flotation, vat bioleaching, and cyanidation are used to recover gold. After heap bioleaching, gold recovery was 75-80 per cent. It was found that efficiency of heap bioleaching process depends on ore feed size. High duration of this process is another feature and it lasts for about a year. This process can be also used for carbonates in the combination with other process during which acid generation occurs. The results of our studies have shown that this technology is amenable for refractory gold ores. Its introduction allows an increase gold recovery and to solve a number of environmental problems. Keywords: heap biooxidaton, the refractory of the ores, the degree of oxidation, arsenopyrite, pyrite, CIL

Sep 1, 2012

Nowadays, the more successful plants are those who have adopted effective and efficient strategies to optimise their plant operation. As the ?heart of the plant? could be viewed as the mil-ling/grinding area, one of the key steps in plant optimisation is, therefore, ensuring the mill is operating properly. In the past, when primary, secondary and tertiary crushers fed material directly to large ball mills, the energy efficiency of the concentrator was determined for the most part by the ball mill operation, whereas now the energy efficiency of a plant often rests largely on the semiau-togenous grinding (SAG) mill operation. As a result, mines have shifted their emphasis in optimization from ball mills to SAG mills. The grinding mill?s energy efficiency essentially depends on ore characteristics and the discharge rate of broken particles, which in turn depends on how efficiently the discharge pump (grate and pulp lifters) operates. The essential function of pulp lifter being to transport the broken material and slurry out of the mill, its design optimization therefore affects the discharge capacity (or mill throughput) of AG and SAG grinding mills. This paper will discuss how the optimised design of the pulp lifter/ discharger has helped to eliminate material transport issues such as flow-back and carry-over of slurry and pebbles to in-crease the energy efficiency of SAG mill using the actual operational data.

Jan 1, 2014