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By P. Saha, D. M. Chakrabarti, J. P. Srivastavam, P. Bhattacharyya, B. R. Sarkhel, Banerjeem B.

The phosphatic soil deposit at the Sukulu hills region of Uganda contains 10-12% P2O5. The ore occurs as a naturally degraded soil deposit containing a very sticky slime composed of earthy lateritic minerals. Desliming of the ore, which is imperative for its further beneficiation, is an extremely difficult hurdle to overcome for its commercial utilisation. Earlier studies on samples of the same ore at the National Metallurgical Laboratory (NML) and abroad established that it was necessary to pass the ore through a series of three stages of desliming, each consisting of a step of vigorous attrition scrubbing followed by hydrocycloning, for effective elimination of the sticky slime. In the present paper an innovative use of the very strong shear-fields created inside a hydrocyclone has been discussed, that could effectively eliminate the stubborn slime from the ore. The standard design of the hydrocyclone was suitably modified to increase the shearing effect on the slurry. It was possible, through the application of this modified hydrocyclone, to not only totally eliminate all the stages of attrition scrubbing, but also to reduce the subsequent stages of hydrocycloning. The modified technique yielded a concentrate of grade comparable to that obtained by employing the earlier more complex flow sheet, with about 25% higher P2O5 recovery.

Jan 1, 2003

By Kazutoshi Haga, Atsushi Shibayama, Altansukh Batnasan

"The aim of this study was to develop a hydromellurgical processing for removal of arsenic from high-arsenic copper sulfide ores and concentrates, providing increase in copper recovery. In this study, three different enargite ore samples containing 28.2–46.7% copper, 1.9–15.0% arsenic and 10.6–27.5% iron were used to determine optimum conditions for the extraction of copper and removal of arsenic. High pressure oxidative leaching process was preformed using various leaching reagents such as sulfuric acid (H2SO4), ferric sulfate (Fe2(SO4)3), hydrochloric acid (HCl), ferric chloride (FeCl3), sodium sulfate (Na2SO4), sodium chloride (NaCl) solutions and distilled water (DW), respectively, under the fixed conditions which were selected to be as follows: NaCl concentration, 0.34 M; concentrations of other leaching reagents, 0.1 M; particle size, -45 ?m; pulp density, 100 g/L; agitation speed, 750 rpm; leaching temperature, 160 ?C; leaching time, 60 min and total pressure (oxygen gas and vapor pressure) into an autoclave, 1 MPa. Results show that under the leaching conditions, more than 90% of copper leaching was achieved with lower than 2% arsenic content as a consequence of the formation of arsenic precipitates in a solution of Fe2(SO4)3–NaCl. It was determined that copper, arsenic and iron concentrations in the pregnant leach solution were 42 g/L, 0.3 g/L and 0.3 g/L, respectively. As a result, it can be concluded that the Fe2(SO4)3 solution in the presence of NaCl or FeCl3 are more efficient leaching media compared to other leaching agents under the high pressure oxidation conditions, because of their high copper recovery and lower arsenic level in the pregnant leach solution.INTRODUCTION Generally, copper is usually produced from copper sulfide ores by a combination of several processes which are flotation and smelting followed by refining [1-3]. Arsenic content in copper sulfide ores tends to increase due to the depletion of high grade copper deposits, hence conventional mineral processing and metallurgical processes cannot effectively treat these ores containing high levels of arsenic to obtain consistently high purity copper concentrates. Because high levels of arsenic in copper ores/flotation concentrates reduces the value of concentrates due to the restriction of smelting process and causes it to be a source of environmental pollution [4-6]. From this point of view, the known way of prevention against high-arsenic copper sulfide concentrates in further metallurgical treatments is to develop economically and environmentally competitive technologies for removal of arsenic impurity from copper sulfide ores before treating the ores/flotation concentrates by the pyrometallurgical routes."

Jan 1, 2018

By Ramon V. V de Araújo, Roberto B. E Trindade, Pablo R. Fica-Piras

"Lead has been reported to affect blood vessels and kidneys. It also produces adverse effects in the mental and physical development of children and nervous system of adults. It is also considered as a possible cause of cancer. Because of all these threats to the human life, the reduction of its environmental occurrence, by means of recycling, is an important additional advantage to the usual ones derived of the procedures of the secondary metallurgy: lead can be recycled several times maintaining its characteristics equivalent to the primary one.Furthermore, this way of producing the metal avoids the environmental impacts of primary lead melting. Also, as an additional advantage, it triggers the metallurgical process with a raw material in what we observe higher lead content than in the natural ores. Some of the potential sources for these purposes are: ashes, slags, electrode residues, anodic muds, spent electrolytes, solid and liquid wastes, industrial or automotive catalysts, worn-out or obsolete equipment components and/or final consumption products.About 40% of world’s lead production comes from automotive batteries, mainly composed of four parts: plastic box, electrolyte (diluted sulphuric acid), contacts and connectors of Pd-Sb and plates (PbSO4, PbO2 and PbO). The plates represent 75% of the total mass. Metallic parts can be melted at moderate temperatures and then refined. The remaining fraction, constituted by the non-metallic portions, can be recovered by hydro and electro-metallurgical routes. These routes are preferred instead of pyrometallurgical ones due to the ultimate emissions of lead particulates and sulphur dioxide.The principal constituent of the residual paste of batteries is the lead sulphate. In this process, the paste is treated in two stages: in the first, lixiviating with Na2CO3 (desulphurization of the paste), obtaining PbCO3 and Na2SO4; in the second, the lead carbonate is lixiviated with HNO3, producing Pb(NO3)2, soluble, that can be converted to metallic lead by electrolysis. The reaction of PbSO4 with Na2CO3 in aqueous solutions is fast: the global rate is limited by the diffusion of the carbonate ions inside the reaction medium."

Jan 1, 2003

By R. Hejazi, Saghaeian. M., H. Abedini

Continuous vacuum belt filters mainly carry out an important duty in the solid-liquid separation processes such as iron ore concentrate dewatering. However as the particles become finer, the resistance to filtration and dewatering would increase and as the result cake moisture content tends to increase. So in recent decades, using additives in order to improve the filtration performance has been considered by many researchers. In the present study, the effect of several surfactants on the filtration rate and cake moisture content of Chadormalu iron ore concentrate (80% =40 micron) was investigated using a laboratory scale vacuum filter. The results of several tests indicated that a non-ionic surfactant (Lauryl Alcohol Ethoxylated, LAE) has the best performance on reducing the moisture content of the cake and reducing the cake formation time. The optimum dose of LAE was found to be 300 g/ton which reduced the concentrate cake moisture content from 13.76 to 11.28% (wet weight base). Some industrial filtration tests were performed in Chadormalu iron ore concentrate plant to prove the effectiveness of this surfactant. The surfactant is mixed with water and added to the concentrate slurry before distributing on the vacuum belt filter. The industrial and experimental results were almost similar, so that adding about 300 g/ton of LAE would reduce the final cake moisture content from 12.87 to 10.76%.

Jan 1, 2014

By Danuta Szyszka

This paper presents results of tests performed to determine minimum concentration of a surfactant used at which coalescence of air bubbles during flotation has low probability to occur. The measurements of the critical coalescence concentration, also known as CCC, were carried out in a device consisting of glass cell into which air was pumped by peristaltic pump through capillaries. The flotation foam was recorded with a high resolution digital camera. Basing on the video records, average diameters of the air bubbles were measured and the values obtained were subsequently used to determine the CCC values. The author of paper determined the CCC values of surfactants tested using the linear regression method, and subsequently analyzed the results obtained. To define initially the capability of a tested surfactant to flotation, efficiency of multiparticle model flotation and flotation of individual size fractions were determined in a flotation apparatus for laboratory use in the presence of only foam making agent at CCC value pre-determined during the tests previously carried out. The tests of coalescence phenomenon were carried out with use of selected flotation frothing agents.

Jan 1, 2014

By P. Basarova

The attachment of bubbles onto a collecting surface is an ubiquitous natural phenomenon, playing a critical role in numerous practical processes. The goal of the project is to broaden the knowledge about hydrodynamic interactions between small bubbles and large solids that occur in nature and industrial processes. Focusing on collision processes between a single rising bubble (Db<1 mm) and a larger falling spherical particle in stagnant liquid, the theoretical model describing the bubble trajectory is given here. The model is based on analysis of forces acting on the bubble, and utilizes equation for the bubble motion. Mobile and immobile type of bubble surface mobility are considered. The calculated results are compared with the experimental data; here a high-speed video camera was used to capture the bubble motion and bubble-particle interaction. Very good agreement between experimental and calculated data was found. For both types of surface mobilities, the bubble deviation in the horizontal direction is nearly linear. The proportion constant is bigger for immobile bubble surface and increases with the bubble size. Furthermore, particular forces acting on bubble were studied. A similar course of relative bubble velocity and force impact was observed for identical bubble position. For cases when the bubble centre is close to the particle axis, only deflection in one direction is observed. When the bubble is reaching the maximum trajectory, the force ratio is changed. The bubble is firstly pushed away from the particle, but when it is within close distance from the particle, the bubble is pushed towards the particle.

Sep 1, 2012

By Erico Tabosa, Meng. Jun, Kym Runge, Matthew Brennan, Weiguo Xie, Dee Bradshaw

Turbulence and its distribution are of great importance in flotation cell design as they affect suspension of particles, air dispersion and particle-bubble collision rates, which in turn determine flotation performance. However, there is no mature technique to measure turbulence in three phase (liquid-solid-gas) systems such as in flotation cells. In this article, the authors present two new approaches that are suitable for measuring turbulence distribution in three phase systems and validate their applicability. The first technique uses a piezoelectric vibration sensor (PVS) to measure fluid kinetic energy standard deviation and the second technique applies electrical resistance tomography (ERT) to measure conductivity variation at a measurement position in a flotation cell. For the PVS technique, calibration of the sensor was performed to determine the values of parameters that were needed to calculate the force applied to the sensor. Then measurement was conducted in a 60L batch flotation cell and the results were compared with LDA measurement. This demonstrated that the piezoelectric sensor signal provides a good representation of fluid kinetic energy standard deviation at the position of measurement. For the ERT technique, conductivity distribution data was processed to give conductivity variations, which were then used to calculate fluid kinetic energy standard deviation at the measurement position. The spatial distribution of turbulence obtained by performing multiple measurements at different positions in the 60 litre batch flotation cell was found to agree with the PVS measurement results. These two techniques are potentially powerful tools for turbulence measurement in flotation environments, enabling a clearer understanding of turbulence’s influence on flotation performance to be determined.

Jan 1, 2014

By Filippov. L. O.

Metallurgical results for the copper-nickel disseminated ores were improved by using ultrasonic treatment. This has been demonstrated by processing of bubble-pulp flow in the reactor zone of a reactor-separator flotation machine. It can be explained by changes in mineral and size composition of the concentrates. Thus, the selectivity of Cu/Ni flotation for different values of the hydrodynamic parameter increases considerably. Additional effect of the ultrasound treatment has been noticed under conditions when the detachment of the gangue minerals from bubbles can be controlled. Reactor-separator has advantages over other types of flotation cells for this purpose. In fact, the weak diameter of reactors make more efficient the ultrasound effect than in conventional impeller or column flotation machines. A combination of ultrasonic treatment with original organization of gas pulp flux in the reactor-separator allows to obtain significant effects in the flotation attachment/detachment subprocesses, enhancing the process selectivity and/or recovery of substances. Increase of total recovery of copper and nickel into bulk concentrate at constant grade is 8.5% for coarse disseminated ores. For copper ore, copper recovery increased by 10% at unchanged grade of 11.7% and nickel recovery gained 17% at the constant grade of 2%.

Sep 1, 2012

By Ming’an Wei, Chuanyao Sun, Zhenguo Song, Zengwen Dou, Yangge Zhu

"The effects of pH value and dissolved oxygen(DO) in the pulp to the Eh and flotation recovery of pyrite were investigated using potential online detection system. The effects of DO on the Eh and flotation recovery were tested which DO changed from 0.5mg/L to 19.5mg/L in six different pH buffer flotation systems (pH: 4.00, 5.62, 6.86, 9.18, 10.01 and 10.96 respectively). Results of potential detected online demonstrated that the pyrite electrode has nearly the same response to potential as with platinum electrode for the FeS2-xanthate-H2O flotation system under the study conditions. Pulp potential and recovery of pyrite were remarkably influenced by pH, both of them decreased with the increasing of pH and, especially, sharp decreased after pH above 9. As the concentration of DO was increased, the Eh was also increased in all the six different buffer solution, while the flotation recovery was decreased. And the amplitude of variation for Eh was not obvious in acidic and neutral solutions, but on the contrary, the change for flotation recovery was remarkable in neutral and alkaline conditions. This may indicate that the flotation of pyrite will be deteriorated in alkaline and high DO concentration conditions."

Jan 1, 2014

By P. Somasundaran, Tarun Bhambhani, D. R. Nagaraj, P. Patra

"Certain non-sulfide gangue minerals are known to have a detrimental impact on flotation performance. When present in large amounts, they can negatively affect recoveries, grades and throughput at current operations, and dictate the viability and economics of a greenfield project. While the problem has been investigated for a long period of time, a scientific understanding of the mechanisms by which these minerals affect performance has not been obtained, and no acceptable solutions have been developed. This study focused on the role of physical aspects (e.g. shape, size and morphology) of these minerals as the underlying factors for poor performance. Flotation tests were conducted using model mineral systems to understand the impact of one phyllosilicate mineral (muscovite) on flotation kinetics, recoveries and grades. The study reveals that there is minimal impact on flotation kinetics, no impact on recoveries, but a very strong detrimental impact on concentrate grade. The traditional mechanisms of transport such as true flotation and entrainment are not sufficient in describing the extent of transport. The transport is attributed to the unique platy morphology of muscovite, which allows for action of buoyancy forces. Data also shows that the muscovite transport to the froth phase depends on particle size; coarser sized muscovite (100-150@) report to the froth phase in much larger amounts than medium sized muscovite (50-100@). At finer size fractions (<50@) the transport is also increased, and this is likely due to entrainment."

Jan 1, 2014

By V. G. Prikhodko, G. I. Sukhinin, I. V. Yarygin, A. V. Fedoseev, S. A. Novopashin

"The first experiments on the vacuum drying of spherical clay sample are presented and the theoretical model of the process is considered. The model is based on the solution of the heat and the moisture transfer equations with the effective thermal conductivity and water diffusion coefficients for wet porous clay-like medium. The time and radial dependence of the temperature and the moisture were calculated for different initial conditions. The results obtained for the time dependence of the moisture content are in good agreement with the experimental results obtained in the initial period, when all the moisture in the sample did not freeze to form an ice crust. INTRODUCTION Capillary-porous materials very often occur in nature and in industry. A porous medium is a solid matrix with voids, or pores, which are continuously connected. These pores are usually filled with fluids or moisture, water vapor and air that can pass through the medium because the voids are interconnected. The void fraction in the solid matrix is referred to as the porosity. Porosity or void fraction is a measure of the void (i.e. ""empty"") spaces in a material, and is a fraction of the volume of voids over the total volume. The moisture content in porous media determines the properties of the porous body, its mechanical and thermo-physical properties, such as density, plasticity, viscoelasticity, swelling, cracking, and so on. Complex processes of heat and mass transfer occur in porous bodies when they are heated or cooled, during drying or freezing (Luikov,1966). The course of these processes depends essentially on the physical-chemical composition of the solid matrix of the porous body, on its fractal dimension, porosity and morphology. The clay and clay minerals are the most important porous materials in the history of the mankind (Mukherjee, 2013). Clay is a very fine grained, unconsolidated rock matter, which is plastic when wet, but becomes hard and stony when heated. It has its origin in natural processes, mostly complex weathering, transported and deposited by sedimentation within geological periods. Clay is composed of silica {SiO2), Alumina (Al2O3) and water (H2O) plus appreciable concentrations of oxides of iron, alkali and alkaline earth, and contains groups of crystalline substances such as quartz, feldspar, and mica. Building materials, bricks, and tiles, pottery, porcelain and faience are made from clay. Clay is used in the food and medical industry, and, not least, in the mining industry as a carrier containing aluminum, silicon and other valuable elements, as well as metals (copper, gold) as constituents, contained in the pores in the form of micro- and nano-particles or grains."

Jan 1, 2018

By Elzbieta Mielczarski, Jerzy Mielczarski, Jan Drzymala, Yann Duvalm

Polyethylene glycol monoalkyl ethers (CnEm) render quartz hydrophobic while feldspar remains hydrophilic. As a result quartz can be separated from feldspar in small frothless flotation devices such as the Hallimond tube. The separation can be accomplished at room temperature at pH < 7 and C16E33 concentrations between 10-5 and 10-4 M for quartz particles smaller than 0.4 mm. No separation is observed when feldspar ore containing about 60 % of feldspar and 40% of quartz is subjected to flotation in a laboratory flotation machine. The reason for the lack of separation is a low hydrophobicity of quartz in the presence of polyethylene glycol monoalkyl ethers and high intensity of mixing in the flotation machine. The flotometric tests showed that the contact angle of quartz in monoalkyl ethers of polyethylene glycol solutions is less than about 18 degrees and depends on the structure and concentration of the ether and the pH of the system.

Jan 1, 2003

By S. S. Indi, D. Santhiya, S. Subramanian, K. A. Natarajan

The interaction of sphalerite- and galena-adapted Bacillus polymyxa (B. polymyxa) cells with sphalerite and galena has been investigated through adsorption, electrokinetic and flotation studies. The amount of sphalerite-adapted cells adsorbed onto sphalerite and galena is found to decrease with increase in pH. On the other hand, the adsorption density of galena-adapted cells onto galena shows a feeble maximum around pH 8, and the amount adsorbed is marginally higher in the pH range of 8 . 11.5. In the case of sphalerite the amount adsorbed is higher in the pH range of 5 to 7. The adsorption density of both the adapted cells is higher for galena vis-à-vis sphalerite. Electrokinetic studies indicate significant surface chemical changes on the chosen sulphide minerals and the bacterial cells, consequent to microbe-mineral interactions. Selective flotation tests on a synthetic mixture of galena and sphalerite confirm that sphalerite could be preferentially floated from galena, using galena-adapted cells, but not with the sphalerite-adapted cells. The cells adapted to galena assay a higher polysaccharide content and are more hydrophilic, while the sphalerite-adapted cells have a higher protein content and possess greater hydrophobicity. Transmission electron microscopic studies have provided evidence in support of the differences between the cell surface characteristics of sphaleriteand galena-adapted cells. Possible mechanisms of interaction between the minerals and the bacterial cells are discussed.

Jan 1, 2003

By Glaser. C., J. Balz, F. Logsch, R. Heiduschke, M. Leiker, P. Ay

The treatment of iron-hydroxide-containing water from ground water and surface water is achieved by a combination of the process steps of flocculation and subsequent mechanical dewatering. The aim is to create solid pellet structures by extending the structure forming flocculation process with a build-up pelletizing process which can be transferred directly into a drying unit. A Taylor-Couette-reactor (diameter of the inner cylinder – 40 mm, gap width – 5 mm) was used for these experimental studies. To produce the necessary flow profile the inner cylinder was rotated at a speed of 230 rpm. The iron hydroxide-containing suspension (dry matter content: 2 mass %) was added simultaneously with the addition of a cationic high-molecular flocculant in various flocculant dosages and residence times of 5 to 15 min. The pellets were examined for parameters such as geometric dimensions, dry substance content and dewatering behaviour. As the results show, there is a direct relationship between the residence time and the geometric dimensions of the pellets. After a residence time of 5 min, round pellets with an average diameter of 6 mm were formed. With an increase in the residence time up to 15 min, a compaction of the pellets could be observed, which resulted in an increase in the dry substance content of 8.0 to 11.2 mass % on average. After completion of the pelletizing process, the pellets were mechanically dewatered by filtration. By applying this innovative wet pelletizing of iron-hydroxide containing suspensions in a Taylor-Couette-reactor, it is possible to carry out the process of flocculation combined with the pellet formation with simultaneous pellet compaction in a single process step. The resulting pellet structures are distinguished from conventional floc structures by an improved water discharge capacity. After classification the pellets can be marked directly as easy-to-handle bulk material, suitable as feedstock in percolation columns for the purification of contaminated fluid streams

Jan 1, 2018

By R. Prakash

Column flotation has now gained wide application in the recovery of various minerals. The performance of the flotation device depends on the mixing characteristics of the phases inside the devices. In this work, quality of mixing in a flotation column has been analyzed by using information entropy theory. Empirical models have been developed for flotation column with the parameters which affect the quality of mixing. The efficiency of the particle separation in the flotation column has been enunciated based on the quality of mixing. The present analysis on the quality of mixing in flotation column may give insight into a further understanding and modeling of flotation devices in industrial applications.

Sep 1, 2012

By Trevor Saldanha, Stephen Grano

A key uncertainty in flotation modelling is determining, a priori, the proportion of each mineral which will develop a certain rate constant for different feeds of variable liberation and hydrophobicity. First and foremost is the ability to predict the proportion of minerals that will not be recovered, even at very long flotation times, and which therefore report to the tailing stream as the non-floatable fraction (i.e., having a zero rate constant). Recent empirical evidence has shown there are at least two factors which contribute to heterogeneity in flotation rates and, in particular, the appearance of a non-floatable fraction - heterogeneity in the distribution of adsorbed collector amount on a particle-by-particle basis, even for the same liberated mineral in the same size fraction, and the existence of a critical contact angle below which the bubble-particle union is unstable. In this paper, inferred measures of the critical contact angle for liberated particles are compared with stability model calculations. This has demonstrated that the dependency of the critical contact angle with particle size and mineral specific gravity are explicable by bubble-particle stability considerations. This argument is further extended to the flotation behaviour of composite particles, as a function of liberation class, in which the wetting perimeter of the attached bubble on the composite particle surface is constrained by the presence of a surrounding hydrophilic domain for the case of simple binary composites. Reasons for the different flotation behaviour of composite particles having different textures, as noted in the literature, are also discussed in terms of the stability of the bubble-particle union.

Jan 1, 2014

By Rod Hocking, Nenad Djordjevic, Randolph Pax

"Semi Autogenous (SAG) mills exhibit complex interactions between the competing processes occurring inside them. Traditional practice is to measure the operation of the SAG mill at an operating point in terms of its load, power draw, steel load, ore throughput rate, water addition rate and more recently the feed size distribution. However significant departures of operating conditions can occur due to changes, for example, in ore hardness, the quest for higher throughputs and mill internal geometry.Fundamental to SAG mill operation are the internal processes that ensure that a given ore throughput and discharge grind size are obtained and maintained. These processes can be measured using non-contact acoustic emissions from the SAG mills which utilise the information rich noise that is generated by the grinding, flow and charge movement inside a mill.Non-contact acoustic in-mill measurements can be used for the validation of discrete element modelling (DEM). The approach being reported in this paper is to model the individual physical processes and then to simulated the assemblage of a physical mill."

Jan 1, 2003

By T. Kalliomäki, B. P. Wilson, M. Lundström, J. Aromaa

"The diffusion rate of cupric ions and limiting current density are important factors that determine the rate of copper mass transport in electrolytes proximal to the electrodes used in electrorefining. As a result, diffusion can critically affect both the rate and morphology of cathodic copper deposition thus it is crucial that it be optimized to improve production. The diffusion coefficient of cupric ion (DCu(II)) in copper electrolytes has been previously researched but the values detailed in the literature show significant variations and moreover arsenic - a common impurity - is generally excluded. Furthermore, in previous studies the models have only been validated with model solutions rather than real industrial electrolytes. In this study, the limiting current density and diffusion coefficient of cupric ion were defined for synthetic electrolytes containing copper (40–60 g/dm3), nickel (0–20 g/dm3), sulfuric acid (130–220 g/dm3) and arsenic (0–45 g/dm3). The cathodic limiting current densities were measured at three temperatures (50, 60, 70 °C) with linear sweep voltammetry using the rotating disc electrode (RDE) as the cathode. By utilizing the limiting current density, models for the DCu(II) were constructed using Levich equation. The validity of the DCu(II) model for technical use was confirmed through their application to industrial electrorefining electrolytes with known element concentrations. Consequently, this study provides improved models for limiting current density and diffusion coefficient of cupric ion that can be utilized for industrial process optimization.INTRODUCTION For an efficient copper electrolysis process, the mass transport of copper ions has to be effective. The main mass transport types of copper ions in copper electrorefining are diffusion and convection while the effect of migration is negligible. In order to maintain good mass transport, it is beneficial to keep both diffusion and convection high to maximize the limiting current density (jlim) (Bard and Faulkner, 2001). jlim is the highest current density that can flow in the cell, thus by maximizing jlim the deposition time can be minimized and the good quality of cathodic copper can be ensured. Thus, it is important to research possibilities that increase and optimize diffusion since slow diffusion in the electrolyte limits the rate of the process (Levich, 1947; Moats et al., 2000; Subbaiah and Das, 1989)."

Jan 1, 2018

By Komar Kawatra, Joseph Halt

"Bentonite clay has been the traditional binder for iron ore pellets. However, bentonite increases pellets’ silica contents and is expensive. Researchers have proposed lowering bentonite doses by mixing it with other common binders. These mixtures may only be successful if the fundamental bonding mechanisms are understood. For example, what happens when bentonite (physical bonding) is mixed with fly-ash (chemical bonding)? What happens when bentonite is mixed with cornstarch (physical bonding)? In this paper, experiments are described where bentonite was mixed with various ratios of cornstarch and fly-ash, and pellets were agglomerated using 0.66 % w/w binder. Ca(OH)2 and CaCl2 were added as activator and accelerator, respectively, to the bentonite-fly ash mixture. Curves of pellet dry strength vs. bentonite-starch ratio were linear, suggesting the physical-physical bonding mechanisms were compatible - acceptable strengths (> 22 N) were produced at all bentonite-to-starch ratios. This was contrary to bentonite-fly ash mixtures, which displayed dry strength curves with a noticeable minimum due to competing binding mechanisms. Bentonite alone and fly ash alone produced acceptable strengths (> 22 N), but their mixtures resulted in weak pellets. Due to the positive results using cornstarch (CS) binders, the effects of CS solubility in water were investigated using two CS with high and low solubility (60 and 7.5 %). CS was premixed with bentonite at various ratios (0, 20, 40, 60, 80, 100 %). Pellets were agglomerated using 0.66 % w/w binder. The dry strength of pellets ranged from 50-300 N using the high solubility CS mixtures, and from 50-85 N using the low solubility CS mixtures. Fired strengths exceeded 2200 N/pellet at all bentonite-cornstarch ratios. This research showed that cornstarch solubility is an important factor in determining its effectiveness as a binder for iron ore concentrates, but significant work is still necessary before it can be used as a bentonite replacement."

Jan 1, 2014

By Paul W. Cleary

"DEM application in mineral processing has for many years been heavily focused on simulating mills of various types. This method can be used to simulate many other aspects of mineral processing operations and can be used both to enhance understanding of the underlying flows and of issues such a breakage, wear, blockage, product degradation, segregation and mixing. The application of DEM to four important classes of non-comminution problems and equipment commonly found in or near mineral processing plants are described. These are:- Particle transport (examples include a conveyor belt and an inclined screw conveyor)- Sampling (assessment of sample bias for cross-stream samplers)- Separation (the efficiency of vibrating screens)- Storage and reclaim (discharge from a multi-port hopper and segregation in a splitter bin with asymmetric ingoing and outgoing conveyor belts, apron feeders and impact plate)."

Jan 1, 2003