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By H. Wotruba, L. von Ketelhodt, M. Kowalzcyk, M. Robben

ABSTRACT Decreasing reserves, water shortages, increasing energy costs, and environmental and social constraints are challenges to the gold mining industry that must be met with innovative machines and methods. This paper introduces the principles of sensor-based sorting and installations that demonstrate the technical and financial viability of the method. The scenarios discussed highlight the potential and advantages of this dry processing technology that requires little infrastructure. Case studies are presented for different ore types using optical- and X-ray transmission–based sorting. Current research is discussed in terms of the potential of near-infrared spectroscopy and X-ray fluorescence sorting for gold applications.

Jan 1, 2013

By L. C. Stevens

The particular purpose of this paper is to direct attention to the development of underground conveying as applied to methods of working coal in the mines of Alberta. Historical A retrospective view of coal mining discloses a continuous effort, on the part of those interested, to substitute mechanical contrivances for hand labour. A patent for a coal-cutting machine was granted to Michael Menzies in 1761, at which time much of the transportation of coal underground was accomplished by means of sledges. Early forms of cutting machines attempted to duplicate the action of a miner's pick, and one hundred years lacer than Menzies? patent we still find this class of machine, driven by water power or compressed air, in use to a limited extent. A coal-cutter using the principle of a circular saw and worked by hand was exhibited in London in 1851, and from these crude beginnings the machines of today have been evolved. Transportation of coal underground has similarly been subject to considerable improvement. The above mentioned Michael Menzies took out a patent in 1750 covering the use of a self-acting incline plane, which is probably the earliest record of any system devised to lighten the load of the crammer or car-pusher of those days. In the year 1868 the Gillot & Copley machine was patented, this being a compressed-air-driven disc coal-cutter which proved highly successful. The chain cutters were a natural development from this type, and for a number of reasons they have been even more successful in the majority of cases.

Jan 1, 1930

By G. Clarkson, M. Hitch, R. Clarkson

"A novel reagent-free method of extracting gold from gravity middling concentrates in the Yukon placer fields is presented in this paper. This method exploits the malleability of gold by submitting concentrates to grinding in a rod mill. Brittle waste minerals are effectively reduced, whereas malleable gold particles are flattened and are then extracted by classification through sieves. Recoveries in the field using a laboratory-sized rod mill regularly exceeded 90%, whereas correlation laboratory tests indicated recovery to be most sensitive to the mill charge size. This method has broad potential, including application to the gravity circuits of large hard-rock processing circuits.RÉSUMÉ Cet article présente une nouvelle méthode sans agents réactifs d’extraction de l’or dans les concentrés gravimétriques mixtes que l’on trouve dans les districts placériens du Yukon. Cette méthode exploite la malléabilité de l’or en broyant des concentrés dans un broyeur à barres. Les déchets miniers cassants sont bien réduits, alors que les particules d’or malléables sont écrasées puis extraites par classification au travers de cribles. Si les récupérations sur le site à l’aide d’un broyeur à barres de laboratoire excèdent 90 %, les essais de concordance en laboratoire indiquent que la récupération est très sensible à la taille de la charge du broyeur. Cette méthode présente un grand potentiel, notamment une application possible aux circuits gravimétriques des grands circuits de traitement des roches dures.INTRODUCTIONExploiting the high density of gold to separate it from waste materials is the oldest known mineral processing technique. This basic technique is still widely used in gravity concentration circuits today; however, gravity processing invariably results in high-value middlings, especially in the Yukon placer gold fields. In addition to having a uniquely high density, gold is also the most malleable metal. This unique malleability can be exploited to extract gold from otherwise inaccessible gravity middlings.The Yukon placer gold industry has been continuously ongoing since the 1860s, and today produces approximately 60,000 oz t (1.87 million grams) of crude gold annually, most of which is from the Klondike region near Dawson City (Van Loon & Bond, 2014). It is important to note that Yukon placer miners do not use any chemical extraction methods; rather, gravity upgrading methods are the sole processing techniques used. Placer deposits are typically coarse, well liberated, and naturally gravity concentrated and recoverable, thus making more expensive chemical extraction unnecessary (Mitchell, Evans, & Styles, 1997). Furthermore, a strict permitting regime, environmental concerns, lack of expertise, and fear of repercussions from regulators prevent miners from attempting more advanced processing methods, such as flotation or cyanidation. Even simple chemical extractions like mercury amalgamation have not been implemented for decades, with one observer noting that, as many as 30 years ago, “the art of mercury for amalgamating appear[ed] to be dying [in the Yukon]” (Osler, 1983)."

Jan 1, 2017

By W. A. Gow, G. M. Ritcey, M. C. Campbell

"Uranium is a unique commodity. It is both a metal and a fuel, It has both commercial and military uses. It yields ""clean energy "" but presents environmental concerns. All of these factors have an impact on the commerce of uranium.Being a metal, uranium is extracted from ore like many other metallic minerals. As a fuel, it is subject to the vagaries of energy commodity market forces. The history of uranium in the first nuclear weapons has led to nation al governments carefully controlling production and sale of uranium. The spectre of radioactive contamination of the environment adds further to the public concern over the disposal of low-level radioactive wastes from uranium processing and use.There have been a number of excellent reviews on the commercial aspects of the uranium industry. In this discussion, these aspects will be briefly summarized to provide a general picture of the strengths of the Canadian uranium industry and the pressures to which it is being subjected currently. The principal thrust of this paper will be to outline Canada's resource strength and to identify some factors which will affect Canada's ability to continue holding a sizeable share of the world uranium market."

Jan 1, 1985

By Fei Dai

Musculoskeletal disorders (MSDs) are a group of painful disorders that affect muscles, tendons, nerves, joints, cartilage, and ligaments. They are a serious problem among the workforce in the United States. In the construction industry, high physically demanding tasks expose construction workers to a number of well recognized MSDs risk factors such as repetitive motion, high force exertion, and awkward body posture. Finding ways to effectively identify and evaluate risks of MSDs can significantly alleviate this problem. To this end, this paper reviews state of practice and research in the assessment of risks of MSDs among construction workers, in which a number of biomechanical models have been developed to evaluate joint and tissue loading with the aid of state-of-the-art remote sensing technologies. Findings from the review reveal that despite the advances in tracking human motion and muscle activities, current remote sensing approaches still involve sophisticated instrumentation and expensive experiment setup. These factors greatly limited the applicability of such approaches in real construction settings. How can we detect and evaluate the construction worker?s MSDs risk in real work environments? In this paper, strategies by utilizing video surveillance systems are presented, to set the stage for addressing the above question and discussing future research in real-time, marker-less, and costeffective MSDs risk assessment.

Aug 1, 2013

By V. Panayotov, M. Panayotova, R. Villas-Bôas

The "United Nations Framework Classification (UNFC-2009) for Fossil Energy and Mineral Resources 2009” is the international system designed to meet (to the extent possible) the needs and to support the decision making and resources management of private industry investment, governments, policymakers, bank investment, scientists. There are different international and national systems classifying commodities (resources, reserves, possibility and feasibility to extract them, etc.) with their own definitions and reporting terminology which often do not overlap entirely or even differ significantly - thus creating difficulties and problems among stakeholders to understand each other. The UNFC-2009 is developed to allow “speaking in one language”. The paper presents briefly the UNFC-2009. The UNFC-2009 applies simultaneously three fundamental criteria to classify projects: economic and social viability, field project status and feasibility, and geological knowledge (so called E, F and G axes), thus creating a visualized, easily understandable three dimensional system. The E, F and G axis categories are divided to subcategories, using additional criteria. The UNFC-2009 is already applicable to solid minerals, nuclear fuel resources, petroleum. The amounts of solid waste generated by metals production from ores (mining, minerals beneficiation, extraction metallurgy) and its metals content are discussed from the viewpoint of using the waste as resource. An attempt is made to apply the UNFC-2009 to technogenic waste from metals production from ores - both to old engineering constructions (historic mining dumps and reclaimed beneficiation tailings ponds) and new (currently in use) dumps and ponds.

Jan 1, 2016

By M. Courtin, D. Berthelot, M. Haggis, D. McClarty, R. Payne

Over forty years of uranium mining in the Elliot Lake region of Ontario (1956–1996) has resulted in the production of over 300 million pounds of uranium. With the completion of mining activity, Rio Algom Limited and Denison Mines Limited are utilizing progressive environmental technologies and management systems to reduce and manage the environmental risks associated with the 150 million tonnes of potentially acid-generating tailings in nine regional waste management areas. Water covers designed to reduce oxygen entry and, thereby, significantly inhibit acid generation, have been applied at six of the sites with the Quirke site serving as a demonstration site for the Mine Environmental Neutral Drainage program. All five of Rio Algom Limited’s effluent treatment plants are monitored and controlled from a central control station utilizing a Supervisory Control and Data Acquisition (SCADA) system based on “Fix Dmacs” technology. Scheduling, auditing and reporting of plant operating and environmental monitoring programs for the entire watershed are controlled utilizing the Regional Environmental Information Management System (REIMS). Proper application of these technologies and management systems facilitates delivery of cost-effective environmental monitoring, care and maintenance programs at these sites and provides tools to demonstrate compliance with all environmental performance criteria.

Jan 1, 1999

By Rick Valenta

Is the Labrador Central Mineral Belt part of the IOCGU Club? ?I sent the club a wire stating, PLEASE ACCEPT MY RESIGNATION. I DON'T WANT TO BELONG TO ANY CLUB THAT WILL ACCEPT ME AS A MEMBER.? GrouchoMarx Acknowledgements ?Ian Dunlop, Matt Lennox-King, Mark O?Dea, Dave Barbour, Derek Wilton, Lucas Marshall, Roland Butler, Mark King, Sally Howson,

May 1, 2006

By Derek Perkins

"Brenda Mines Ltd. operates an open pit copper and molybdenum mine located in south central British Columbia. The main economic mineralization is chalcopyrite and molybdenite. Pyrite, galena and sphalerite are also present in varying quantities. The mineralization is present in small veins and fractures in a porphyritic quartz diorite host rock.The mill processes approximately 30,000 tonnes of ore daily. The ore is crushed in three stages and then ground in conventional rod mill - ball mill circuits with cyclone classification. The cyclone overflow is fed to the bulk flotation circuit as a pulp with a density of 50% solids. The particle size distribution is approximately 35% plus 65 mesh. Bulk rougher and cleaning flotation produce a concentrate grading approximately 20% copper and 4% molybdenum. This concentrate is fed to the separation circuit, where the copper is depressed with sodium hydrosulphide and the molybdenum is floated. These products are further ground and then upgraded by column flotation. The molybdenum concentrate is pumped to the leach plant to reduce concentration of lead and copper. It is then washed, filtered, dried and packed for shipment to Europe. The copper concentrate is filtered, dried and subsequently shipped to Japan.Prior to November 1977, the mill flotation control was carried out by the assay laboratory using a Philips PW 1540 sequential x-ray spectrograph. The assay set consisted of twelve samples, analysed on a two hourly basis for copper, molybdenum, lead, iron and silica.In order to provide elemental composition information on a much shorter sampling interval and to produce speedier control analysis for automating process control, an Applied Research Laboratories PCXQ on stream analyser was purchased. The installation of this analyser, reduced the turnaround time of the control analyses from (2) hours to (20) minutes. At Brenda, the following assays are used in the mill control strategies."

Jan 1, 1989

By Fan Delian, Ye Jie, Lui Tiebing

The lower and the upper parts of the Doushantuo Fonnation, Hubei Province, China, contain silicate-type K-rich beds (illite and feldspar), and intraclastic phosphorites, as well as Ag-V and V deposits in a "Black Shale Series". The K-rich beds fonned in an anoxic basin whereas the phosphorites fonned in a more oxic and higher energy depositional environment. The Black Shale Series occurs in the lower and upper parts of the Doushantuo Fonnation; that in the upper part consists of black illite shale and dark gray dolostone, and contains Se-rich Ag and V deposits. These deposits are of more industrial significance than the previously discovered Ni-Mo polyelement sulfide deposits which occur in the Lower Cambrian Black Shales Series of South China. Studies of lithotype, sedimentary sequence, and geochemistry of the Doushantuo Fonnation have led to more attention being focused on the uppennost Black Shale Series and its Ag-V and V deposits. There are three ore types: black, Ag-V-rich, illite shale; black, V-rich, illite shale; and dark gray, Ag-Vrich, fmely crystalline dolostone. The first two ore types contain 3070 to 5% Corg and the last, 1.25%. The Ag-bearing minerals are naumannite, argyrodite, aguilarite, acanthite, and native silver that occur as inclusions in pyrite associated with barite. Vanadium substitutes for AI in illite and is also related to organic-matter contents. Because (1) the pre-Sinian Kongling Group contains one to three times greater than the Clark Ag value; (2) black, illite shale has a negative Ce anomaly; and (3) there are large occurrences of black, K-rich, tuffaceous, fme siltstone, the sources of Ag are thought to include subaerial and submarine volcanic materials. It is proposed that Ag, V, and Se were absorbed by clay particles and organic matter during syngenetic deposition in an anoxic environment; Ag subsequently was reconcentrated into sulfides and selenides, whereas V was incorporated structurally into illite during early and late diagenesis. These types of Black Shale Series-hosted Ag-V and V deposits are, therefore, considered to be sedimentary-diagenetic in origin.

Jan 1, 1992

By Limao Zhang

This paper presents a BIM-based Risk Identification Expert System (B-RIES) for metro construction, composed of three main built-in subsystems: BIM extraction, knowledge base management, and risk identification subsystems. The engineering parameter information related to risk factors is extracted from the BIM of a specific project where the IFC standard plays a bridge role between the BIM data and metro construction safety risks. An integrated knowledge base, consisting of fact base, rule base and case base, is established to systematize the fragmented explicit and tacit knowledge. A hybrid inference approach, with case-based reasoning and rule-based reasoning included, is developed to improve the flexibility and comprehensiveness of the system reasoning capacity. During the safety risk identification process, B-RIES is able to improve the inefficiencies in engineering information extraction, reduce the dependence on domain experts, and facilitate knowledge sharing and communication among dispersed clients and domain experts. A typical safety hazard identification in the Mingdu station, located in the Wuhan Metro Line Two, is presented in a case study. The results demonstrate the feasibility of B-RIES, and its application potential. B-RIES can be used as a decision support tool to provide guidelines for safety management in metro construction, and thus increase the likelihood of a successful project in a complex environment.

Aug 1, 2013

By B. Meddings, O. J. I. Evans

"This paper is mainly concerned with the present and probable future role of hydrometallurgy in the production of base metals.The economic and technological bases of the hydro-metallurgical plants built and operative in the mid-fifties are compared to those in production in the mid-sixties. The trends observed are extrapolated and some estimates made concerning the probable size and type of hydrometallurgical plants which will be operative in the mid-seventies.The impact of emerging socio-economic factors such as pollution control and the market demand for specialized metal products which favour hydrometallurgical recovery processes are also discussed."

Jan 1, 1971

By Roland B. Hoag, Roger G. Webber

Sulphate concentration in groundwater is a good measure of the extent of oxidation of sulphides, provided that sulphide minerals are the primary source of the sulphate. A study was conducted near the Eustis Mine in Quebec to determine where and how the sulphate in groundwaters originated. Atmospheric precipitation is the only source of sulphate other than oxidation of sulphides, and in this study area it is equal to 0.01,. millimole per litre. The oxidation of sulphides can be divided into subsurface oxidation (mainly inorganic processes) and surface oxidation (including both organic and inorganic processes) . The maximum sulphate concentration due to subsurface oxidation of sulphides depends on the solubility of 0 2 in water and is 0.25 millimole per litre. Surface oxidation is, therefore, responsible for any amount greater than atmospheric plus subsurface contributions (0.29 millimole per litre). Surface inorganic oxidation occurs in waters with a pH greater than 15 and is controlled by the kinetics of the oxidation processes. Organic (bacterial) surface oxidation is dominant only in acid (pH< 1.5) waters. The bacterial action accelerates the oxidation of sulphides, and large quanttties of sulphate may be introduced into solution.

Jan 1, 1976

By V. S. Papezik

Pyrophyllite, an AI silicate used in the production of ceramic materials, is formed mainly by alteration of felsic to intermediate volcanic rocks, either directly (at temperatures of 250-300°C and pressures of 1-2 kbar) or by subsequent low-grade metamorphism of aluminous protoliths produced by thermal fluids or even by prolonged weathering. Most pyrophyllite deposits in North America are concentrated in a belt of Late Precambrian volcanic and sedimentary rocks, the "Avalon Zone ", which extends along the eastern flank of the Appalachian mountain system from Newfoundland to the southeastern U.S.A. The only producing pyrophyllite mine in Canada is an open pit located near the settlement of Foxtrap on the Avalon Peninsula of Newfoundland. It lies in a belt of rhyolitic flows and pyroclastics intruded by a granitoid pluton. The rocks have been leached along a shear- or fracture zone, depleted in silica, alkalies, Ca, Mg and Fe by the action of hydrothermal fluids, and recrystallized to a very fine-grained massive assemblage of pyrophyllite, muscovite ("sericite") and quartz. High-grade pyrophyllite lenses contain small nodules of diaspore with minor barite; rutile is present in trace amounts. The close proximity of all pyrophyllitized zones on the peninsula to the granite contact suggests that the alteration was produced by thermal fluids genetically connected with the granitoid pluton. The fine-grained pyrophyllite-bearing rocks, with their simple mineralogy, are suitable for quantitative modal analysis by X-ray diffraction. Chemically analyzed samples from the alteration zone were used for the construction of working curves by plotting calculated mineral content against the intensity of selected diffraction peaks. The accuracy of the resulting curves is ±4.5% for quartz, ±3.6% for pyrophyllite and ±2.7% for muscovite. Pelletized samples give best results. The XRD method is suitable for a rapid analysis of a large number of grab or core samples to outline higher-grade areas for more detailed sampling.

Jan 1, 1978

By A. Ducastel, S. Connemann, A. Stark, F. Bouillot, C. Fricke-Begemann, LSA, H. Knapp, L. Horckmans

"Refractory materials are essential for all high-temperature applications in industry. Depending on the position in the furnace and specific process requirements, refractories are produced from several raw materials, such as dolomite, magnesite, bauxite, graphite or chromite. Most of these raw materials are not rare but strict quality requirements limit the producers of refractories to only a few deposits in the world. Thus, raw material supply is a critical factor for the production of refractories and accounts for 40-50 % of the total costs of refractories.A possible way to lower dependency on raw material supply is recycling of spent refractories. Main challenge in recycling is the separation of different brick types from each other and the removal of impurities, such as steel or slag. The European FP7 project REFRASORT aims to apply sensor-based sorting for separation of spent refractories. Sensor-based sorting is known from food industry, recycling and mineral processing and has proven its reliability. Nevertheless, some adjustments are necessary compared to applications in mineral processing because of other sensor-types and a higher number of products in one sorting step. This paper presents the results of feasibility tests for sensor-based sorting of refractories with near infrared spectroscopy and laser-induced breakdown spectroscopy (LIBS). Both sensors showed the potential to identify different brick types but the most promising results were obtained using LIBS technology. INTRODUCTIONRefractories are solid, ceramic products, which can sustain temperatures of more than 1500°C, without losing their stability or shape. Bricks of refractories have to withstand corrosion in contact with liquid steel or slag. Various high temperature applications, such as the production of glass, steel, copper or cement, require high quality refractories. The quality requirements of refractory bricks are strict, because small impurities can lower the thermal strength significantly."

Jan 1, 2016

By J. J. . BRUMMER

Kimber/ires are intrusive rocks whose main constituenr, olivine, has been altered entirely or almosr enrirely ro serpentine. Texture usually is porphyritic, superimposed upon a brecciared one. Diamonds are found only in kimberlites, and are present in economic quantities only in about I% of all kimberlites known. Two glacial drift diamonds, one near Peterborough and one near Timmins, both in Ontario, have been found in Canada and are believed to have been eroded and rransporred from their original source by glaciers. Many more glacial drift diamonds have been found sourh of rhe Great Lakes in the United States, parricularly in Indiana, Illinois and Wisconsin . There are nine known kimberlire occurrences in Canada. Diamonds have been located in rwo of rhem: on lie Bizard near Monrreal and on Somerset Island in the Northwesr Terrirories. The lie Bizard occurrence comprises three kimberlire diarremes; samples of rhe largest one revealed JO riny diamonds totalling 0.0537 carars. The Somerset Island kimberlites are rhe mosr significant yet discovered in Canada. Ar leasr 19 separare kimberlite occurrences are known on rhe island. Testing by Diapros Canada Lim ired, however, revealed only "a few small diamonds". fr is likely rhar, wirh enough time and funds, additional kimberlires, possibly bearing economic quanriries of diamonds, will be found in Canada.

Jan 1, 1984

By N. A. Beier, R. Amos, Smith. L., C. Atherton, D. R. Barsi, D. Blowes, D. C. Sego

"Waste rock is one of the most abundant materials at mine sites and must be properly characterized and managed to limit acid rock drainage and other harmful byproducts. An experimental waste rock pile—part of the test piles research program—located at the Diavik diamond mine (Northwest Territories, Canada) was deconstructed and sampled to study the spatial variability of material properties. Bulk samples were classified based on the amount of material finer than 4.75 mm. Hydraulic properties of each sample were estimated and particle size distribution analysis was completed. These datasets and classification methods might be used to improve the understanding of hydraulic and geochemical behaviour of the material and to study waste rock at other sites. ¦ KEYWORDS Acid rock drainage (ARD), Material classification, Particle size distribution (PSD), Waste rock RÉSUMÉ Les stériles font partie des matériaux les plus abondants sur les sites miniers et, en tant que tels, doivent être correctement caractérisés et gérés afin de limiter le drainage rocheux acide (DRA) et la pré¬sence d’autres sous-produits nocifs. Dans le cadre du programme Test Piles Research Program, un amas de roches stériles expérimental situé à la mine de diamant Diavik (Territoires du Nord-Ouest, Canada) a été décomposé et mis à l’essai afin d’étudier la variabilité spatiale des propriétés des matériaux. Les échan¬tillons en vrac ont été classés en fonction de la quantité de matériaux plus fins que 4,75 mm. Les propriétés hydrauliques de chaque échantillon ont été estimées et l’analyse de la composition granulométrique effectuée. Ces ensembles de données et méthodes de classement serviront à mieux comprendre le com¬portement hydraulique et géochimique du matériau et à étudier les stériles sur d’autres sites. ¦ MOTS CLÉS classement des matériaux, composition granulométrique, drainage rocheux acide (DRA), stérilesINTRODUCTION Statement of problem The characterization of mine waste rock remains a challenge in active mining sites. The large volume of material and the large size of particles make it difficult to collect representative samples. Sampling techniques are often dis-ruptive to mining operations because they alter the structure of the waste rock pile or interfere with mine traffic. The convention at most mine sites to collect little to no information on waste rock material means that models and predictions of how waste material will behave and interact with the surrounding environment are based on general information that might not be site specific. This could lead to environmental damage or higher costs if environmental effects are underestimated during the construction of waste rock structures."

Jan 1, 2019

By A. Idegami, M. Imamura, S. Heguri, Y. Ozaki

"Nickel powder can be produced by the reduction of a nickel ammine complex solution by hydrogen at high temperature and pressure. To minimize the deposition of fine nickel on the surface of the reactor and other equipment, seed crystals are added to the initial solution to promote nucleation of the nickel powder. Such seed crystals catalyze the precipitation of the nickel particles on the surface of the seed and enhance grain growth. In this study, nickel nuclei were precipitated by the addition of a polymer to the nickel ammine complex solution, resulting in the production of nickel powder. Thus, we herein propose a model that explains the effect of the polymer in the precipitation of nickel nuclei.INTRODUCTIONNickel powder is commonly produced via a hydrometallurgical process from the hydrogen reduction of a solution containing a nickel ammine complex at high temperatures and pressures, and this process was commercialized in the 1950s by Sherritt Gordon (Sherritt International, Canada, Benson & Colvin,1973; The Staff, Research and Development Division, Sherritt Gordon Mines, Ltd., 1958).In the above transformation, upon the injection of hydrogen gas into the solution, nickel is reduced as outlined in Equation(1), ultimately resulting in the production of nickel powder.Ni(NH3)nSO4+ H2?Ni+ (NH4)2SO4+ (n-2)NH3(n:2–6)(1)In this process, seed crystals are added to the reactor to suppress the precipitation of fine nickel (scaling) and to enhance nickel reduction (Benson & Colvin, 1973; Mackiw, Lin & Kunda, 1957). More specifically, iron sulfate and a small amount of dispersant polymer are added, which leads to the formation of nuclei. Upon subsequent hydrogen reduction, the reduced nickel can then be deposited on the nuclei, allowing nickel particle growth to take place. However, this results in iron contamination in the final nickel product, and so the use of pure nickel as a seed crystal is desirable to produce high quality nickel powders."

Jan 1, 2017

By A. McLean, W. Q. Chen, W. Yan, M. Barati, Y. D. Yang

In order to maximally remove the harmful impurities phosphorus and reduce the loss of valuable elements from Si-based alloy for production of solar-grade silicon, thermodynamic properties of the Si-based alloy were studied. In this work a new model, the Molecular Interaction Volume Model (MIVM) derived from statistical thermodynamics, was successfully used in the Si-based and Si-Fe-based alloy. The calculation started from binary Si-Fe, Si-P and Fe-P systems, then the thermodynamic parameters of ternary systems could be derived based sub-binary systems. Using the activity coefficients of the elements in the Si-based alloys and the saturated vapor pressure of the pure substance of the components, mass fraction of P during vapor-liquid equilibrium can be calculated. The calculated thermodynamic parameters were compared with experimental data available in different publications, and it is found that the thermodynamic parameters calculated using MIVM model are in good agreement with the measured results. The calculated result shows that the mass fraction of phosphorus during vapor-liquid equilibrium of Si-Fe-P melt increases with the increasing phosphorus content and decreasing temperature. This is an important direction for experimental practice in vacuum or low-pressure EML refining of ferrosilicon for potential production of solar-grade silicon without significant vaporization loss of valuable element.

Jan 1, 2015

By J. Peterson

A review of blast designs and improved blasting practices at the Ekati??Diamond Mine is presented along with the results of three blast-monitoring experiments. Blast monitoring was undertaken to investigate blast damage mechanisms in the mine&apos;s well jointed rock mass. Rock mass damage caused by production, pre-shear and wall control blasts was measured. Ekati??uses 270mm holes for production blasting, and 165mm holes loaded with a decoupled charge for pre-shearing. The production blasts are loaded with bulk emulsion / ANFO blends. The mine plan involves using 30m double benches. A 30m high pre-shear is drilled and blasted prior to the production blasting that is done with sequential 15m benches. This paper summarizes the monitoring equipment and data gathered to date.

May 1, 2001