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By Jilai Xue, Jun Zhu, Germain Kouma Ndong, Qiaochu Liu, Luxing Feng

"High-temperature oxidation and corrosion behaviors of Ni-Fe-Cr alloy as inert anodes for aluminum electrolysis have been studied in oxygen and molten electrolyte. The oxidation and corrosion scales on the anodes tested were analyzed using XRD and SEM-EDS. The oxidation rate is found to increase with increasing temperature from 700 °C to 950 °C, which can be approximately described by an inverse power rate function. The oxidation scales at 750 °C, 920 °C and 950 °C contain Cr-rich phase along with FeCr204 and (Feo.6Cro4)203. The corrosion extent of Ni-Fe-Cr anodes in electrolyte is dominated by temperature, which can make the scales thickness double from 700 °C to 750 °C or from 920 °C to 950 °C. Cr and Fe in the scales on the anode in electrolysis corrode preferentially into the molten electrolyte, while the nickel oxides could better sustain the corrosive environment in electrolysis. The results can be useful for developing inert anode material for potential application in aluminum electrolysis.IntroductionThe development of an inert anode for aluminum electrolysis has been a long term goal for aluminum industry. The present process for primary aluminum production involves the reduction of alumina with carbon anodes, forming carbon dioxide:"

Jan 1, 2013

By A. Butler

This paper explains the politics of mine nationalization in contemporary South Africa. Nationalization and privatization typically occur in the oil, mineral resources, and state utilities sectors, and they tend to follow one another in a long-term cyclical pattern. The paper explains why the current international environment has encouraged demands for nationalization and other forms of ?resource nationalism? in the South African minerals sector. It goes on to describe how the resurgence of resource nationalism has been influenced by internal factional politics in the African National Congress. It concludes that nationalization is unlikely to be the outcome of current policy deliberations within the ANC.

Jan 1, 2013

By Binxu Zeng, Mark Jolly, Xiaojun Dai

"The traditional investment casting foundries use batch melting and chunky running systems to produce casting components. This method leaves the energy saving issue as subsidiary one. In our research project, one of the partners, the AEROMET international PLC provides the thin wall aluminium component ""filter housing"" for test. The AERO MET uses traditional casting route to produce the filter housing, which only gives 5% --10% yield. In this paper, numerical simulation method is used to analyse filling and solidification of the casting running system. The CRIMSON running system of the filter housing is designed by using casting simulation software, MAGMAS and Flow3D. By working with AEROMET, various configurations of the casting running systems were tested and analysed. Using them ultiple life cycle approach, the energy content of new process is compared with traditional one. It indicates that the CRIMSON process only uses 36% of energy consumed by the traditional route.IntroductionThe investrnent casting is a metal for ming process using expendable patterns, which is a standard casting technique and is widely used to produce quality parts. Its accuracy, versatility and integrity tie itself to important and precious engineering components in Aerospace industry. However, traditional investrnent casting process usually uses chunky runner system and gravity filling method. It not only reduces the casting yield of the product but also causes the pouring defect during the casting. As author's previous research showed that gravity filling method pouring basin and down sprue are two main resources of entraimnent defects generation. No matter how good the running system is, entraimnent defects such as double oxide films (DOF) and bubbles will I get into the casting to cause problem."

Jan 1, 2013

Decision-making regarding plant-scale reagent dosage regimes and air rates is a topic of ongoing investigation and high importance. The current work explains some techniques that have proven useful in deciding on plant-scale flotation operating regimes. Specific focus has been placed on the reagents: frother and depressant, as well as some discussion around the control of air rate and froth depth. Air rate has been selected based on its effects on the froth phase. Froth velocity and froth height above the cell lip are the two variables measured and used to select the operating air rate. Pulp level is then adjusted to increase or decrease mass pull. A technique has been developed using the Anglo Platinum Bubble Sizer on an industrial flotation cell to determine the relationship between bubble size and frother concentration. This technique has been extended to measure the equivalent frother concentration or frothabilities of various streams on a rougher bank. A mass balance for frother was performed successfully, and this provided a better understanding of the way frother moved in the rougher bank. With this knowledge, more informed decisions can be made about frother addition required in subsequent flotation stages. For depressant, a new protocol for deciding on dosage rate has been developed. The depressant dosage should be based on the amount of fresh feed material reporting to a bank. Currently 400 g per ton of fresh feed has been assumed a reasonable starting point, with promising results. Improved froth stability and grades were observed. There is scope for more accurately defining the optimal dosage rate. Importantly, the combined effect of changing the chemistry and the hydrodynamics together has been demonstrated. A significant upward shift in the grade-recovery relationship for a cleaner bank was observed.

Jan 1, 2013

Mine planners must select a single pit for design with the knowledge that the grades on which this selection is made are uncertain. This uncertainty is often ignored through the use of deterministic models of grade. This makes the mine planner?s job simpler but does not necessarily lead to the ?correct? or ?best? selection. Grade uncertainty is typically modeled with conditional simulation, which generates multiple possible realizations of grade that are equally probable (or improbable). M ethods for incorporating grade uncertainty into mine planning to date have either been perceived as being too complicated, not accessible or too time-consuming. This paper proposes a simple and efficient modeling approach to incorporating conditional simulation into pit optimization, which would be able to be applied in currently commercially available software. An example for R esolute M ining Ltd.?s Syama gold project in M ali shows the range of ore, grade and value outcomes associated with generating pits through a variety of methods.

Jan 1, 2013

By Sen-xiang Yang, Xin-teng Liang, Gui-jun Li, Jian-hua Zeng, Yong Chen

"This research is based on PANSTEEL 120t steelmaking converter technology to have the quantitative description of the time needed in uniform mixing of molten steel in the converter with the computer. In present work, the numerical simulation approach is used to analyze oxygen lance nozzle, the flow condition of oxygen and flow status of molten steel in the converter. The various oxygen jet flows that come out from different angles and the flow status of all kinds of jet flows in the converter have also been simulated. All of the simulation parameters are based on the specifically practical conditions according to the physical conditions of PANSTEEL 120 t steelmaking converter. Through numerical simulation, the angle parameter of the oxygen lance nozzle is 16 °. The optimized oxygen lance 536-16 has a good performance in industrial application. This kind of phenomenon shows that the ways and processes of numerical simulation in this research are right.IntroductionThe oxygen lance system is the significant process in semi-steel making converter. It's related to whether the converter or even the whole system can function well. While in actual production, many problems emerge in the process of using the former oxygen lance, such as re-drying, slopping, high lance position, dead burning and even blowing out. In continuous fast-paced process, the unstableness of oxygen lance will lead to speed droop or even stop pouring. Analysis shows that all these problems are not only related to the raw materials but also the design of oxygen lance. Bad oxygen lance's scorification kinetics condition and low content of FeOn in early slag are the direct factors that we cannot easily control in steelmaking at present [l]. Therefore, the good scorification kinetics condition which is related to nozzle has good influence on BOF steel making."

Jan 1, 2013

By Ronald C. Severson

Crystals of native gold occur in placer-type deposits. Gold, as a pure metal, is the most malleable metal known; therefore, delicate gold crystal forms should not survive mechanical transport and concentration processes involved in placer formation. To test the hypothesis that the crystalline gold is currently forming in place, two active gold-placer operations and an unmineralized background area in Alaska were examined. At these sites, rock outcrops, soil profiles, and native vegetation were sampled. At one sampling site, the soil was panned and yielded crystalline gold, as well as the more common rounded nuggets. The plants and soils were analyzed for their major, minor, and trace-element contents, especially gold. Two procedures, one a simple demineralized water leach and the other a partial digestion with acetic acid and hydrogen peroxide, were also used to extract gold and various anions from soils. The water-extractable gold ranged from <0.02 to 15.0 ppb Au in the extracting solution. This represents as much as a 104 enrichment in gold over average river water. This extractable gold is probably available to the native vegetation. Gold concentrations in the unashed dry plants from the two placer sites ranged between 0.4 and 106 ppb compared to a background range of <1 to <4 ppb Au. The presence of dissolved organic matter in the soils is thought to be responsible for the dissolution, transportation, and precipitation of gold in these placer soils, and this process is presently active in these soil profiles.

Jan 1, 2013

By Patrick G. Hatcher

Studies of sedimentary humic acids by nuclear magnetic resonance (NMR), stable isotopes, and elemental analysis show they are derived by oxidative degradation of complex plant macromolecules that are insoluble in aqueous or organic solvents. The mechanism by which humic acids originate is fundamental to our understanding of the role of organic matter in ore deposition, because these substances can complex and mobilize a number of metal ions. The organic matter associated with uranium ores of the San Juan Basin, New Mexico and Carlin-type disseminated gold deposits of Nevada has certain organic geochemical characteristics that suggest an origin from humic acids.

Jan 1, 2013

By Mark Alan Marlkos

Blebs of solid bitumen from the Magmont West orebody of the Viburnum Trend were examined and analyzed in an attempt to relate hydrocarbon distribution and origin to ore genesis. The bitumen was calculated to be approximately 48 to 63 percent aliphatic and is considered to be a polymerized normal crude oil. Polymerization, which was probably caused by water-washing, hardened the bleb surfaces and appears to have "frozen" the blebs during primary migration from local source beds. Comparison of the bitumen to kerogen in local shaly partings strongly Indicates that the oil was derived locally. The polymerized oil blebs are considered to have been derived from a type II (marine) kerogen. Textural analyses indicate that oil migration occurred after lead-zinc mineralization and at temperatures that exceed normal ancient or present geothermal gradients. The following sequence of events is postulated for the Magmont West orebody: 1 Generation of hydrogen sulfide during diagenesis of a normal organic-rich carbonate sequence. 2 Introduction of pulses of hot, metal-rich fluids that resulted in: a Lead-zinc mineralization by the following reaction: Me++ + H2S ? MeS + 2H+ b Solution of carbonates by excess acid produced during the above reaction. c Brecciation of host rock in some cases. 3 Passages of the pulse resulted in: a Carbonate buffering of fluid system to more alkaline conditions. b Precipitation of dolomite c Slight temperature drop. 4 Eventually the high temperatures Introduced by heated brine caused oil generation and initiated primary migration. 5 Water-washing and mild biodegradation altered the hydrocarbon blebs to their present composition.

Jan 1, 2013

By Andrzej Walentek

In polish coal mining due to specificity of seams lying the multiple extraction is used. In this kind of mining, it is essential to take into account all geological and mining conditions which have an influence on stability and functionality of workings during their using. In view of above, for one of polish coalmines, by mean of Phase2 program, the numerical calculation were made for assessment of the influence of advancing excavation front on convergence of roadway located 30 meters above longwall was analysed. In order to verify developed prognosis, in analyzed roadway the underground investigations in scope of convergence measurement and changes of load exerted on working support were carried. As a result of these investigations it was found that real convergence on certain part of roadway was significantly larger then determined in prognosis. Additional calculations and analysis showed that the main cause of differences was underestimation of influence of dynamic load, which was an effect of numerous low energetic rockmass tremors. These tremors, related to excavated longwall, were located in close proximity of roadway in its part where the biggest convergence occurred. In current practice, in this type of convergence prognosis, the maximal value of dynamic load exerted on roadway resulted from single rockmass tremor is taken into consideration. Quantitative consideration of all tremors including their location is impossible at the stage of convergence prognosis because of lack of this type of data. This paper presents results of roadway convergence prognosis compared to results of underground investigation. Conclusions formulated on that base allow in future similar designing works for obtaining more accurate results.

Jan 1, 2013

By N. Shi, T. G. Joseph

ABSTRACT Before any large plant is moved onto an oil sands dominated surface, particularly those surfaces encountered in-pit, it is imperative that the ground be evaluated for bearing capacity. A 2230 tonne mobile in-pit hopper/crusher facility designed for operation in the Canadian oil sands was modeled. This evaluation focused on track and outrigger pad versus ground interactions as the key performance indicators of appropriate ground performance below the unit in both operating and repositioning propel modes. A study of cyclic oil sand behaviour was also inferred from laboratory cyclic plate load data as an extension of the simulation model indications.

Jan 1, 2013

By Onuralp Yiicel, Ozlem Okur, Murat Alkan

"In this study, Co-Cr-Mo alloys were produced using a mixture of Co304, Cr203 and Mo03 powders with Al powders by a Self-propagating high temperature synthesis process. SHS is a process of material synthesis that has revealed a number of reactants combinations capable of much higher energy release than conventional explosives. Al203 is added to the mixture to decrease the adiabatic temperature of the system. The thermodynamic simulations and the calculations of adiabatic temperature were examined with FactSage 6.2. In the SHS experiments, different Co304/ Cr203/Mo03 ratios were examined, and their effects on the metal recovery and alloy compositions were carried out. The samples were characterized by using chemical analysis, XRD, XRF and SEM/EDS techniques.IntroductionSelf Propagating High Temperature Synthesis (SHS) has significant advantages compared to the high technology furnace applications, such as very short processing time, simple operation, low energy requirement and low cost [l, 2]. In a SHS process, the ignition starts the combustion and propagates throughout the reactant mixture yielding the desired product. However, the disadvantages of the process such as inhomogeneous or unreacted products due to undesirable reaction rates needs to be overcome by changing some parameters such as ignition temperature, particle size, additive, atmosphere etc. [3, 4]. This work aims to establish a scientific and engineering background in the production of some cast Co-Cr-Mo master alloys via SHS (Self Propagating High Temperature Synthesis) metallurgy which is attractive process technique regarding fast and low-cost production ability of cast alloys."

Jan 1, 2013

By Kimberlee Falkenstein, Volha Kibitkina, Jessica Steeves

A series of experiments were conducted to obtain site specific constants for the vibration produced by a single charge and by more charges detonating in sequence, using short delay intervals. All charges were placed in relatively long boreholes in granite without a free face other than the ground surface. The boreholes were filled with water to provide good coupling with the rock and to provide identical confinement for all the blasts. Vibrations were recorded close to each blast in the vertical direction by uniaxial high frequency geophones and far field using a triaxial geophone.

Jan 1, 2013

By R. Venugopal, Saxena. V. K., U. Sankrityayan

"There is a dire need of a technology which can break the mineral interfaces to enhance liberation with minimum energy consumption in mineral beneficiation processes. Understanding of mineral crystal system and interfaces is essential to develop such methodology. So, this study is carried out to find out the role of mineral crystallography in milling and liberation. Data related of mineral crystallography, Vickers Hardness Number, Bond Work Index and beneficiation processes were collected from literature and detailed statistical analysis has been carried out to establish a correlation among these parameters. It was found that atomic weight and cell parameters shown statistically significant relationship with Vickers Hardness Number of minerals, which controls the milling characteristics of ores. Liberation characteristics of five different kinds of ores were analyzed considering the types of interfaces between valuable and gangue minerals. It was found that phase interfaces play vita role in liberation and coarser liberation can be achieved in the minerals of incoherent crystal systems like manganese and zinc ores. Study of this subject can help us to understand the effect of stress wave propagation in solids and its effect on crystal interfaces. It can also help us to design a technology of future to break the mineral interfaces.INTRODUCTIONCommunition is energy intensive mineral processing operation and consumes up to 2% of the total electric power generated in the world. Energy consumption due to comminution is increasing every year as there is growing needs to exploit lower grade ore bodies and process rejects (Blazy et al., 1994; DOE, 2005). Low grade ores require crushing and grinding to liberate the valuable minerals which are further separated from gangues by various beneficiation methods like gravity separation, floatation, leaching etc. Currently, comminution methods are selected based on the reduction ratio and energy consumption but effect of grinding methods on subsequent processing methods specially on liberation also need to be studied to optimize the entire beneficiation process. Most of the attempts made in past to minimize the energy consumption in milling to enhance the mineral liberation were focused on compression mechanism, chemical additives, thermal treatment, microwave treatment and electric disintegration (Kilpelm and Austin, 1982; Norgate and Weller et al, 1994; Bearman et al., 1997; Kumar et al., 2010; Wang el al., 2011; Singh et al., 2012). But the role of mineral crystallography on milling and liberation behavior of minerals not fully explored yet."

Jan 1, 2013

By Chao Li, Qian Li, Yong-bin Yang, Kai Li, Qiang Xie, Yuan-yuan Zhu, Dong-ye Li, Qi-bing Tan

"The permeability of sintering mix is a vital technological property in sintering process. However, it can only be measured by off-line method on samples picked from the production. In order to acquire the properties of sintering mix accurately, on-line measuring of permeability is urgently required. Based on the reflection characteristics of bed permeability on pipe flowing parameters, a new method is presented in this paper for on-line measuring of sintering mix permeability. The measurement can be performed by blowing gas flow in the bed with the measuring pipe. Measuring results are obtained by picking the data on flowing rate and pressure in the pipe. The function of flowing rate to pressure may be certain for samples with the same permeability. Thus, the permeability was determined by contrasting this function to the result of off-line measuring, and the relative coefficient or R2 value was more than 99%.IntroductionThe permeability of sintering mix is a vital technological property in sintering process, which directly determines production and quality of sinter, or even determines whether the sinter production is carried out smoothly [1,3].The permeability have more obvious influence on vertical sintering speed, which is mainly related to air quantity passing through material bed. Under certain inducing capacity and negative pressure, the vertical sintering speed mainly depends on the permeability of sintering mix. Low permeability may make burning through point of sintering move back, and the sinter mix cannot be burnt through. High permeability may make burning through point of sintering move forward, improving production efficiency by increasing the speed of sintering machine [4] Good permeability means a small resistance of fan ,reduction of negative pressure of sintering machine, and full contact between air and sulfide, which can strengthen physical-chemical reaction during sintering process and increase desulphurization rate. In gas well through material layer process, gas-solid desulfurization reaction and gas-solid-liquid heat exchange are completed and hot gas through the combustion zone supplies the sintering process with heat. Finally uniform sintering of the material layer in height and width direction is achieved [5] While high permeability index leads to weak sinter strength, fast sintering speed, short residence time of high temperature region and little liquid phase. Moreover, liquid phase in the fast cooling process is too late to fully crystallize but forming glass phase which is harmful to sinter strength as well. Bad permeability means a big fan resistance and increase of negative pressure of sintering machine, which make the air pass through material layer difficultly. When air and mix contact difficultly, removal of sulfide reduces so that desulfurization is incomplete. Meanwhile, low caking efficiency, slow sintering speed and easily burnt sinter , reduce sinter output. Therefore appropriate permeability of sintering mix is the premise of stable burning through point and satisfactory sinter output and quality."

Jan 1, 2013

By Guiming Yang, Xiaoxian Huang, Zhiyun Ji, Min Gan, Lishun Yuan, Xiaohui Fan, Zhiyuan Yu

"The roasting characteristics of hematite pellets containing MgO were studied where magnesia powder, serpentine and magnesite were used as magnesium-additives respectively. The mechanical strength of both preheated and roasted pellets decreased when MgO content increased, which implied the addition of MgO had an adverse effect on pellet consolidation. By adding flux containing CaO, the mechanical strength of both preheated and roasted pellets were improved. The addition of calcium flux facilitated the formation of calcium ferrite and provided a certain amount of liquid phase, resulting in faster diffusion ofMg2+ and Fe3+. The result showed that diffusing speed of Mg2+ was enhanced by 1.48 times, and rate constant of Fe203 crystalline growth was enhanced by 62% when basicity was around 0.4. Improvement of mineralization degree and recrystallization of Fe203 assisted in consolidation of hematite pellets containing MgO.IntroductionOxidized pellets are ideal iron-bearing burdens in blast furnace. At present, magnetite is the main raw material for oxidized pellet production in China. However, as the rapid development of iron and steel industry, resources of magnetite have been depleted and cannot satisfy the requirement of pellet production. Using hematite concentrates to produce oxidized pellets has become a trend [1, 2]. Many pellet enterprises abroad nowadays have adopted high proportions of hematite concentrates when producing oxidized pellets, e.g. the percentage is 100% in a lot of Brazilian factories [3, 4]. But high proportion of hematite concentrates will lead to low mechanical strength and high reduction swelling index of pellets. Some studies show that Mg-bearing pellets have excellent metallurgical properties, and the reduction swelling phenomenon can be solved by adding fluxes containing MgO [5, 7]. However, there are problems such as low pellet strength and bad roasting characteristics for MgO-bearing pellets, which remains an obstacle in pellet industry. Hence, it's vital to undertake the study on strengthening measures for indurations of Mg-bearing hematite pellets."

Jan 1, 2013

The authors provide a discussion of the paper, ?Coal workers? pneumoconiosis prevalence disparity between australia and the united States,? a peer-reviewed paper that appeared in the technical papers section of the July 2012 issue of Mining Engineering magazine. The original authors, G.J. Joy (gjoy@cdc.gov), J.F. Colinet (jcolinet@cdc.gov) and D.D. Landen (dlanden@cdc.gov), respond.

Jan 1, 2013

By Shu Bin, Lin Chen, Tian-zu Yang, Wei-feng Liu, Wan-da Bin

"Antimony resources are rich in china, its reserves and productions are ranking the first in the world. The Chinese antimony mineral resources are mainly existed in the form of three types, such as stibnite, antimony-gold ores andjamesonite. The antimonial dust that produced from lead smelting process is an important secondary antimony resource. The different process that was adopted to extract antimony depends on the different raw materials. The process of blast furnace volatilization smelting is mainly used to treat stibnite and antimony-gold ores. But jamesonite is treated by the process of roasting-sintering-blast furnace smelting. And antimonial dust is treated in the reverberatory furnace. Many new technologies that are applied in these traditional antimony smelting processes play important roles, such as deleading agent, antimony white production, air-oxidation method, direct-blowing method, bath smelting technology, and so on. At the same time, the development of antimony smelting technology in china is prospected according to the requirement of the state environmental protection.IntroductionThere are five countries that produce antimony in the world, such as china, Tajikistan, Bolivia, Russia, and South africa, but China is the largest country of antimony production in the world. In the world, the antimony productions of 2008, 2009, and 2010 are 182,000 tons, 154,000 tons, and 167.000 tons respectively, but Chinese antimony productions are 166.000 tons, 140,000 tons, and 150,000 tons respectively. So Chinese antimony production was accounted for more than 89% of the world in 2010. It indicates that China have irreplaceable advantages in antimony resource and production all over the world."

Jan 1, 2013

By G. R. Lane

A large opencast gold mining company in Africa had just completed a feasibility study for an expansion of the operations. A traditional net present value project valuation methodology had been used that showed a very positive net present value (NPV). The project team had conducted a qualitative risk assessment that identified and logged all potential project risks and had subjectively incorporated &apos;risk&apos; via the discount rate and other assumption contingencies around gold price expectations, operating parameters, etc. Management requested that an independent quantitative risk modelling approach be adopted to obtain a better understanding of the impact of risk on the overall project valuation and confidence level in the final valuation. A detailed project valuation model was configured in the Cyest Carbon Modelling Technology platform, and the stochastic modelling module used to perform the Monte Carlo simulations. Analysis of historical operational performance data relating to actual achievements versus planned and budget determined the historical variability of the underlying parameters as well as variance to budget. This was done at a detailed level for mining rates and costs, processing rate, costs and recovery, and other operational efficiency measures. External market assumptions relating to gold price, exchange rate, and inflation were modelled and the dependency between them modelled using a copula. This case study will demonstrate the approach taken to building and populating the quantitative risk model and the overall results of the Monte Carlo simulation. The final valuation demonstrated that the project had a 44 percent probability of an NPV less than zero i.e. a 44 percent chance of project finance loss.

Jan 1, 2013

By Paul J. Lewis

Estimation of the axial side shear resistance of drilled shaft rock sockets is directly related to the unconfined compressive strength of the bedrock. Commonly, the mean unconfined compressive strength value is calculated from a range of laboratory test results and is used to estimate the side shear of the bedrock. This paper presents the results from a full scale axial load test performed on an 8.5-feet-diameter drilled shaft rock socket, and compares measured side shear values to estimated values for two different rock strata. Measured side shear values correlated well with the design value calculated for the ?strong? rock stratum, but did not correlate well with the design value calculated for the ?weak? rock stratum. The mean unconfined compressive strength was used to calculate the side shear in both strata, but review of the laboratory data indicates that this value may not have been appropriate for the weak stratum due to a large variation in the laboratory test results. Also included in this paper is a discussion of the subsurface conditions, the laboratory test results, and the methodology used to design the drilled shaft rock sockets for axial and lateral resistance.

Jan 1, 2013