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By Xiang-dong XING, Zhen-yang wang, Xing-le LIU, Jian-Liang Zhang

Experiments were carried out by adding CaF2 as catalyst in a Ar atmosphere to study the isothermal reduction kinetics of vanadium titano-magnetite carbon composite pellets under high temperature in the range from1473 to 1673K. By analyzing reduction mechanism, it was found that the rate controlling step was gas diffusion, and the activation energy was 178.39kJ•mol-1 without adding any catalysts. Adding CaF2 of 3% to vanadium titano-magnetite carbon composite pellets can decrease the apparent activation energy of reduction, and the decrease extent was 14.95kJ•mol-1. In addition, temperature is an important factor influencing on reaction rate.

Jan 1, 2015

By Ting Liu, Qian Li, Peng Deng

The wastewater containing Hg2+ and Pb2+ does great harm to the environment and human bodies. Traditional wastewater treatment cannot fundamentally put a stop to heavy metals pollution for producing secondary pollution. In this paper, Hg2+ and Pb2+ in wastewater were removed and recovered by sulfide precipitation- flotation. Sodium sulfide was used as precipitant and butyl ammonium aerofloat was used as collector. Results indicated that Hg2+ and Pb2+ could be reduce to less than 0.03mg/L and 0.16mg/L respectively by both coprecipitation- floatation and fractional precipitation- floatation. In these two methods, fractional precipitation flotation could not only remove Hg2+ and Pb2+ from wastewater, but also could recover mercury and lead effectively. The infrared spectrograms showed that the adsorption between butyl ammonium aerofloat and mercury precipitate or lead precipitate is chemisorption.

Jan 1, 2015

By B. K. Chakrabarti

Modeling and a screening design of experiment (DOE) was performed with the process variables to identify the greatest effect of variables on the response quality in the dead burning of magnesite refractory in a rotary kiln. Among various interdependent variable factors, the design variables chosen were raw magnesite (RM) feed rate, kiln rotation time i,e, seconds per rotation(SPM) and burning zone temperature (BZT). The response variables chosen were exit gas temperature and density of dead burnt magnesite(DBM). ANOVA and normal plots were used to evaluate the effects.This work had enabled to correlate the BZT, RPM, RM feed with the exit gas temp and density of magnesite produced. The result opens up an avenue to look into the optimum region of operations within the ranges of variables considered in order to conserve energy and to minimize the exhaust gas temperature and to maximize the density of the DBM produced

Jan 1, 2015

By Yuzhe Zhang, Xiaodi Huang, Xinli Wang, Bowen Li, Matthew Andriese, Jiann-Yang Hwang, Zhiwei Peng

The recycling of waste tires has been a big environmental problem. About 280 million waste tires are produced annually in the United States and more than 2 billion tires are stockpiled, which cause fire hazards and health issues. Tire rubbers are insoluble elastic high polymer materials. They are not biodegradable and may take hundreds of years to decompose in the natural environment. Microwave irradiation can be a thermal processing method for the decomposition of tire rubbers. In this study, the microwave absorption properties of waste tire at various temperatures are characterized to determine the conditions favorable for the microwave heating of waste tires.

Jan 1, 2015

By Xinlei Jia, Wenming Guo, Yanling Zhang

A large amount of stainless steel dust rich in Fe, Cr, and Ni has been being generated in China. Smelting treatment is accepted as a practical method for the recovery/reutilization of these second resources, during which Fe, Cr, and Ni is reduced into one metal phase and then separated from the residue slag. Based on the typical compositions of stainless steel dust, the residual slag can be termed as CaO-SiO2-MgO-Al2O3 system. In this paper, the activity coefficients of Cr in Fe-Cr-Ni-C (-Si/Al) melt and the properties of CaO-SiO2-MgO-Al2O3- 1%CrO system thermodynamically approached. Then, in laboratory experiments, the recovery ratios of Cr and its distribution behaviors between Fe-Cr-Ni-C melt and CaO-SiO2-MgO-Al2O3 slag system were examined.

Jan 1, 2015

By Jing Zhan, Tian-zu Yang, Wei-feng Li, Li-Hua Jiang, Shi-yan Xu, Jian-yang Huang, Chuan-fu Zhang, Yan-qing Fan

The amount and activity of coal, reduction temperature and other parameters of the process of bottom-blown reduction of liquid high lead slag were investigated in laboratory. Methods to strengthen the bottom-blown reduction process were studied by industrial production. The results were in the follows: the reduction temperature was 1150℃; reduction time was 1.5h; the reductant was anthracite; lead content in slag was controlled to 2%; the rate of coal was 7% and gasification loss of coal in high temperature was severe; liquid lead slag reduction rate was faster with coal; prolonging the reaction size had little effect on reducing lead in slag; the size of the reactor can be further reduced.

Jan 1, 2015

By Saynbaatar, Gangping Ma, Jianhua Fu, Qiqige, Jinghua Wang

The influence on the performance of foam concrete made by replacing cement with some industrial waste residues was researched in this paper. The result shows that the 7d and 28d compressive strength of foam concrete increases firstly and then decreases with the increasing amount of industrial waste residue. The proper added range is 10%-20% for steel slag, blast furnace slag and coal ash, but, 8% for desulfurized fly ash. With the proper adding ratio, the compressive strength of foam concrete always increased comparing with the pure cement foam concrete. When adding 48% of the compound industrial waste residues, the 28d compressive strength of the foam concrete reached the 2.9MPa which could match the pure cement foam concrete. The results indicates that there is a synergistic effect among the compound industrial waste residue, and this effect is benefit to improving the compressive strength of foam concrete.

Jan 1, 2015

By Cong Wang, Kexin Jiao, Yongan Zhao, Haibin Zuo, Jianliang Zhang

Traditional refractory materials for blast furnace hearth lining are mainly composed of carbon bricks and the ceramic cup. However, these materials can’t meet the demands for long service life design of blast furnaces. In this paper, a new refractory called carbon composite brick (CCB) was introduced, which combined the advantages of carbon bricks and the ceramic cup. In this case, the resistance of the CCB against corrosion was equal to the ceramic cup and the thermal conductivity of the CCB was equal to carbon bricks. From the results of more than 20 blast furnaces, the CCB could be well used in small blast furnaces and large blast furnaces. In the bad condition of low grade burden and high smelting intensity, the CCB gave full play to the role of cooling system, and effectively resisted the erosion of hot metal to improve the service life of blast furnaces.

Jan 1, 2015

By I. M. Richardson, M. Janssen, I. J. Bennett, V. A. Popovich

The most critical processing step during the manufacture of screen-printed crystalline solar cells is firing aluminium and silver contacts, which generates residual stresses and solar cell bowing. In this paper, an alternative Ag contact formation mechanism is proposed and aspects related to electrical contact properties, residual stresses and layer delamination are investigated. It is found that there are two main processing parameters affecting the uniformity and delamination of the Ag/Si interface, namely the peak firing temperature and the silicon surface roughness. Silicon surface polishing gives a better wetting of the silicon surface by the glass layer, resulting in a good contact and lower incidence of large voids, compared to the case of highly textured surfaces. The non-uniformity in the glass layer and large voids at the Ag/Si interface (in the case of a textured surface) are expected to have a negative effect on the mechanical strength of the solar cell.

Jan 1, 2015

By Jesse White, Tyler Salisbury

Research projects contain many stages of development from the conception of an idea to a fullscale commercial operation. The transition from laboratory-scale research to bench-scale roasting can represent a significant increase in complexity and cost, depending on how many variables are being evaluated. Thermogravimetric analysis (TGA) can simulate roasting conditions and produce a small sample for chemical analysis or materials characterization. A simultaneous thermogravimetric and differential scanning calorimetry (TG–DSC) can identify endothermic and exothermic reaction temperatures. Using thermal analysis, some of the process variables can be tested and eliminated such as ore and reagent blends, retention times, operating temperatures, and some atmospheres.

Jan 1, 2015

By Sheng-li Wu, Guo-liang Zhang, Bo Su

The mineralogical characteristics of iron ores can influence their high temperature sintering performance. In this study, eight iron ore samples from Brazil, Australia, and South Africa were characterized by their chemical composition, mineral types, particle morphology, and gangue dispersity. Meanwhile the influence rules between the mineralogical characteristics and the high temperature characteristics were evaluated and analyzed. The results showed that the effect of SiO2 on assimilation characteristic of iron ores was relatively complex, Al2O3 and LOI of iron ores had negative correlation with assimilation temperature of iron ores, the dense slab-flaky mineral granule restrained to the assimilation characteristics of iron ores; liquid phase of iron ores with high SiO2 content and low Al2O3 content had high fluidity, and the higher dispersity of gangue minerals in iron ores was good to the fluidity of liquid phase.

Jan 1, 2015

By D. M. Fermino, C. G. Bastos Andrade, V. F. Justo, F. R. Valenzuela-Diaz, M. G. S. Valenzuela, C. Volzone

The present paper presents the study of light green smectite clay, from Paraiba, Brazil, submitted to mild acid attack under moderated conditions. Usually, clays are subjected to treatment with strong inorganic acids at temperatures near the boiling point and at high acid concentrations and then, widely used as bleaching agents. The treatment occurred under bellow boiling temperature and at short times of reaction (90°C, reaction times of 1, 6, 12, 18 and 24 hours in close reactor, concentration of the aqueous solution of hydrochloric acid 1.5 M, clay/acid solution ratio of 1g/10mL). The purpose of these attacks is to reduce the concentration of impurities providing color, with minimal change in the clay minerals structure, aiming at use in products of high value such as cosmetics and polymer/clay nanocomposites. The raw clay and the attacked samples were characterized by X-ray diffraction (XRD), cation exchange capacity (CEC), stereomicroscopy, scanning electron microscopy (SEM) and energy dispersive X-ray detector (EDS).

Jan 1, 2015

By Lei Wang, Jianjun Wang, Lingen Luo, Zhengbang Li

Dearsenication in molten steel was studied by adding Ca-Fe Alloy-based arsenic removal agent. In order to improve the utilization rate of Calcium Iron Alloy and improve arsenic removal ratio, [O] is less than 0.0005% and [S] is less than 0.0035%, Al is added into the molten steel. In the processes of adding CaO-Al2O3 based alkalinity slag for arsenic removing in molten steel (initial arsenic content is 0.0080%), arsenic removal ratio reaches 50% when Ca-Fe Alloy addition amount is 18%. During the arsenic removal experiment, adding Rare Earth promotes the arsenic removal reaction and makes the arsenic removal more effectively.

Jan 1, 2015

By Mingming Zhang, Mallikharjuna R. Bogala, Ramana G. Reddy

Steelmaking desulfurization slag samples were characterized using chemical, X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS) methods. The objective of this work is to investigate the occurrence of sulfur and phosphorus components in the slag samples and to identify their origin and associations with the iron phases. Thermodynamic calculations results confirm the presence of phosphorus and sulfur components in the slag sample at high temperatures (1400 to 1800oC). The main constituents of slag include Ca3SiO5 (28.1%), MgO (9.31%), Ca3(PO4)2 (9.18%), CaS (8.39%) and CaO (5.68%). The major phosphorus and sulfur components of the slag are Ca3PO4 (99.2%) and CaS (79.3%) respectively. Characterization studies indicate the presence of microparticles of different sizes and shapes in the slag sample. Elemental analysis of these particles confirm the presence of major elements (O, Mg, Al, Si, S, Ca and Fe) in the slag sample.

Jan 1, 2015

By Qiang Zhong, Bin Xu, Qian Li, Yongbin Yang, Tao Jiang

Viscosity of slag determines the production efficiency, energy consumption and distribution of elements between metal and slag, which is very important for pyrometallurgy. Slag of goldantimony ore blast furnace smelting has seldom been studied. In this paper, the viscosities of gold-antimony ore smelting slags of different composition have been studied by the rotating cylinder method. The results showed that, for a slag of 38.95% SiO2, 16.17% CaO, 25.97% FeO, 10.25% Al2O3, 5.17% MgO, the viscosity can be decreased by reducing 3.24%-8.5% SiO2 or increasing 3.31%-9.56% CaO content. Complex SixOy z- from SiO2 acts as the main cause for the high viscosity in a slag of high SiO2. The increasing of CaO causes the decreasing of the amount of SixOy z- and the O2- dissociated from CaO breaks the complex SixOy z-, which can decrease the viscosity. Viscosity of different composition slag in the appropriate range temperature can be calculated from the Arrhenius equation.

Jan 1, 2015

By Bhagyadhar Bhoi, Chitta Ranjan Mishra, Pravas Ranjan Behera

Red mud of Indian origin contains around 55% plus of Fe2O3 and is considered as a hazardous waste for the alumina industry. For production of one tone of alumina employing the Bayer’s Process, around two tones of red mud is generated from three tones of Bauxite. Conventional process of steel making is not devoid of environmental pollution. In the present investigation, efforts have been made to produce steel from red mud by adopting reduction roasting, magnetic separation and hydrogen plasma smelting route. Magnetic fraction, containing enriched iron oxide and minimal content of alumina, is produced following the first two stages which is then subjected to hydrogen plasma smelting process for production of steel. This novel concept follows a green path way for production of steel free from pollution and is termed as green steel. Further, the only by-product that is produced in the process, is water, which is eco-friendly and recyclable.

Jan 1, 2015

By Joe E. Bryan, John P. McDonnell

"Underground mine rib stability is an ongoing safety issue in all mining applications. Rib-related accidents present at least as many problems as roof-related ground control. Underground coal mine rib safety is continually emphasized as a primary safety concern at every mining operation. The application of rib support materials is increasing as more difficult mining conditions are experienced due to deeper cover, more variable depositional environments, thicker seam heights, and multi-seam mining effects. As the coal seams become thicker, the need for rib control increases. A variety of rib control methodologies has been documented and research continues on mine design methods and support techniques to reduce or eliminate rib-related accidents.This paper presents an alternative rib bolting technology using proven conventional rib support systems that allows mine personnel to more efficiently install rib support during development operations. This alternative rib bolting method allows for additional rib support with a single support installation.INTRODUCTIONRib control continues to garner the watchful eye of both concerned operators and government officials due to many factors: inherent safety within entries and crosscuts, actual rib stability history, safety improvement, cost control, improved mining methods, and maintaining production goals. As demonstrated through many years of actual practice, desired outcomes can be achieved by scrutiny, innovation, and combining improved practice methodologies.Rib surface control continues to be a necessary part of the production process. However, production and safety issues persist at the point of installation using current control apparatuses and methods to install rib controls. Among others, current issues of rib control are quantity of bolts required, overall time required for installation, ease of apparatus installation, flexibility of the system for appendage installation and operator exposure. A need exists to decrease the time miners spend installing rib control apparatuses, while increasing the safety of such installation processes. At present, installing rib control devices (primary rib bolts, plates, mesh, and, in most cases, secondary rib bolts and plates) is performed in a very congested area and is time-consuming process at the primary coal-winning area: the face. The MatLok system addresses these problems."

Jan 1, 2015

By J. M. Ríos

"Without conscious effort and understanding, a number of factors unique to mineral exploration often hinder building sustainability in host communities. These include the episodic and transitory presence of an exploration team in the community and the inherent uncertainty of outcomes— most projects fail from an exploration perspective. Experience in rural communities across Mesoamerica, however, has shown that it is possible to go beyond pragmatic philanthropy and infrastructure improvements to promote positive, sustainable outcomes in communities. Examples are provided of lessons learned and proven practices that improve quality of life and support a strong social license to operate.RÉSUMÉ Sans une compréhension et un effort réfléchis, de nombreux facteurs uniques à l’exploration minérale nuisent souvent à l’établissement d’un développement durable dans les communautés d’accueil. Ces facteurs comprennent la présence épisodique et transitoire d’une équipe d’exploration dans la communauté et l’incertitude inhérente des résultats – la plupart des projets échouent après l’étape de l’exploration. L’expérience dans les communautés rurales à travers la Méso-Amérique a toutefois démontré qu’il est possible de dépasser la philanthropie pragmatique et les améliorations des infrastructures pour promouvoir des résultats positifs et durables dans les communautés. Des exemples qui améliorent la qualité de vie et soutiennent un solide permis social d’exploitation sont présentés; ils sont tirés de leçons apprises et de pratiques éprouvées."

Jan 1, 2015

By K. Sakai, M. Miyaue, T. Aoki, T. Tani, S. Tanaka, N. Kudo

In the planning stage of a tunnel, due to limited technology in the geological survey and the financial restriction, tunnel supports are often designed from unsatisfactory information, and the tunnel construction is started. Therefore, "Information-oriented construction" is carried out in the construction stage, in which the design is rationally verified and modified by observations/measurements. Moreover, the ground conditions ahead of a tunnel face must be predicted for efficient and safe tunnel construction. The authors have examined effective prediction methods to the ground conditions ahead of a tunnel face under construction of mountain tunnels (Aoki et al., 2010) in view of the established method (Schubert et al., 1995). Though the prediction method of Schubert requires the displacement in the direction of tunnel axis, it is difficult to obtain its accurate data by the electronic distance meter. Then, we have proposed a method that uses tilt sensors installed at the tunnel crown near the face to obtain the slight tilting information. To measure inclination of the tunnel crown, this inclinometer was originally developed as a daily control measurement, such that the geological condition and its possible change behind the face could be detected early, and a steady advance and construction safety could be ensured. This paper describes the method of forward prediction mechanism and advantages of this suggested method. It then presents the typical results of a field verification test at a tunnel under construction and an example of evaluation of the ground conditions ahead of the face based on the 3D numerical analysis in three types of condition changes of ground deformation moduli.

Jan 1, 2015

By Akshay Sakhuja, M. S. Karthika, R. Vignesh

"The bridge across River Mandovi in Goa is a cable stay bridge structure proposed parallel, along existing bridges for regulation and reduction of vehicular traffic; the entire bridge structure is supported on pile foundation socketed in rock. This paper describes drilling related issue encountered during execution of pile where bed rock varies considerably from factual geotechnical investigation, which in turn affected the productivity of bored piles socketed in rock then chiseling is advocated for rock socketing with limited number of blows based on penetration resistance of rock encountered or equivalent energy principle to increase the productivity and also to avoid excess chiseling which otherwise would have fractured the rock mass below and around the pile tip resulting in increased settlement of pile subjected to design load. Contractor decision on socket length have been taken without compromising either quality or productivity; the paper presents various procedures and the equipment involved for installation of pile in rock along with the conclusion related to termination of pile in rock and also the lessons learned in process.INTRODUCTIONPile foundations are generally used to transfer heavy loads in deeper bearing stratum if the soil immediately beneath the base of the foundation does not have sufficient capacity. The bridge across River Mandovi, Goa is in its construction phase as a part of the development plan of Goa State Infrastructure Development Corporation Ltd (GSIDC). The project was awarded to M/s. L&T Construction, Heavy Civil Infrastructure; subsequently the geotechnical investigation was awarded to M/s L&T Geostructures.The client has specified the foundation of the bridge as rock-socketed. Rock socketing is generally done to achieve higher bearing pressure through concrete-rock shear interface which many building codes permit. The design and construction of rock socketed pile foundation entails a detailed analysis and judgement on the superstructure loads, predominant geological conditions as well as ground water levels. The termination of pile is normally based on thumb rule of half to three times the pile diameter into the rock. Quite often the criteria is based on chisel penetration rate (Gandhi,1990) In fact, this is the key factor to consider appropriate and economical depth of embedment of pile into rock stratum which necessitates enormous understanding on the type and quality of rock strata encountered which may significantly influence the selection of suitable rotary rig for pile installation. Such criteria are site specific and also applicable for the set of equipment used for the particular project."

Jan 1, 2015