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By Esa Peuraniemi, Hanna-Leena Heikkilä

Boliden Harjavalta has been operating a copper flash smelter since 1949. Thus, in 2019, the smelter is celebrating its 70th anniversary of flash smelting. Slag formation is an integral part of the smelting process; currently the processing of slag is based on froth flotation at the slag concentrator. It provides high recovery of copper but restricts slag utilization; the final copper slag is deposited in a landfill. The Harjavalta smelter commissioned a new landfill area for final slag in May 2018. This paper describes the full project from permitting to commissioning of a new landfill area. The permitting process is described comprehensively, including environmental impact assessment together with the environmental and dam safety monitoring. During the environmental impact assessment, observations on rare animals protected on European level were made as well as archaeological findings. Successful completion of the permitting allowed the construction phase to start on time. After six years of intensive work, the new landfill was commissioned in May 2018. The new landfill area provides a sustainable way to store the smelter’s slag for decades to come. INTRODUCTION Slag processing Sulphide based concentrates have always formed the main raw material stream at Harjavalta’s copper smelter. During the smelting and converting steps, the iron included in the concentrate is oxidized and fluxed using a silica-based sand. Originally, the slag was processed by using an electric slag cleaning furnace after which the final slag was water granulated. Froth flotation has been utilized for slag treatment since 1966. In the beginning, the slag was cooled in open ditches. In 1984, controlled slow cooling of slag was licenced to enhance copper recovery at the flotation plant. Today, the slag from both the smelting and converting is tapped/skimmed to slag ladles and treated in the following steps: Slag ladle transportation from the smelter to the cooling area by slag hauler Slow cooling of slag in the ladle to allow mineral precipitation Unloading the slag by tilting the ladle; causing the slag to crush as it drops from the ladle Feeding the crushed slag (-500 mm) by wheel loader to a slag concentrator’s feed funnel followed by a conveyor belt transporting the slag to the concentrator plant Crushing and grinding using lump and pebble mills Froth flotation of the valuables Recycling the slag concentrate back to the smelter feed after dewatering Pumping the final copper slag to the landfill area.

Jan 1, 2019

By K. Kryst, K. Elkayar

The increasing need to process lower grade contaminated copper concentrates and simultaneously produce higher purity copper cathodes necessitates a more diligent control in the electrorefining process. Ion exchange processes can be a powerful tool in controlling electrolyte impurities to ensure trouble free operation within the tankhouse and to help maintain cathode purity. In addition, some impurities can be recovered as a value added product. The use of a short bed ion exchange process provides a unique opportunity for impurity management in copper refineries. Several metals are discussed in this paper, including Sb, Bi, As and Ni and their methods of control and recovery within the copper electrolyte circuit. INTRODUCTION To produce a high purity copper product by electro-refining a copper electrolyte, it is important to control the concentration of impurities such as arsenic (As), bismuth (Bi), antimony (Sb), and nickel (Ni). These impurities are introduced into the electrolyte from the copper anode and can affect the copper product and the production operation. The presence of As in the copper product results in a lower electric conductivity and reduced workability of the copper. High levels of Bi in the electrolyte will result in a copper cathode product containing Bi. High Sb concentration will cause undesired floating slimes. A variety of methods have been developed to control the level of these impurities in the copper electrolyte including precipitation, liquid extraction, and ion exchange. These impurities can be recovered and used. This paper discusses novel methods that utilize short bed ion exchange technology to control these impurities. Also, the use of ion exchange to recover acid from the liberator cells bleed for reuse in the tankhouse is reviewed. SHORT BED ION EXCHANGE Short bed ion exchange technology has been employed extensively in the metal finishing industries for over forty years. Unlike conventional ion exchange, short beds are fixed beds without freeboard space. The application of short bed technology results in significant benefits when compared to conventional ion exchange. The resin used in this technology has a significantly smaller diameter than conventional ion exchange resin. As a result of the smaller resin size, exchange kinetics improves dramatically. This facilitates operation at higher flow rates and the use of smaller beds with a small mass transfer zone length. Smaller beds are especially important for applications that use chelating resins due to the high cost of the resin.

Jan 1, 2019

By M. Pelser, H. Gous, J. H. W. M. Brits, K. Voogt

The effect of impurities; iron and selenium, on current efficiency and deposit quality in copper electrowinning was investigated using an at-line cell at the Rustenburg Base Metals Refiners’ Copper Tankhouse. The tankhouse is a direct leach, starter sheet electrowinning operation with a unique electrolyte composition. The effect of iron on the current efficiency in the at-line cell was found to be less severe than reported in literature. However, the distinction between the chemical impact of iron on current efficiency and the physical impact of iron on a starter sheet operation needs to be realised. The effect of selenium on current efficiency and deposit quality is also reported. INTRODUCTION Anglo American Platinum’s Rustenburg Base Metals Refiners’ (RBMR) Copper Tankhouse serves a unique function in the refinery flowsheet in that its primary functions are the removal of copper and production of acid for the leach circuit. This function needs to be performed to specification in order to keep the leach circuit operating optimally. Current efficiency is seen as an indicator of tankhouse performance and efficient energy use. The tankhouse plates starter sheets onto titanium blanks which, after stripping and preparation, return into the production cells for further plating. Approximately 78% of tankhouses surveyed (Robinson et al., 2013) use permanent cathode technology whereas older, smaller operations still use starter sheet technology. Drawbacks of the starter sheet technology are that the starters are thin and bend easily leading to increased shorts, they need to be removed after two days of plating to be manually straightened and are then returned to the cells. In addition, the electrolyte levels in the cells need to be adjusted during the plating cycle to improve loop adhesion to the cathode and reduce loop corrosion. The starter sheet technology is therefore very labour intensive and the final quality of the product is dependent on the quality of the starter sheets produced. In comparison, permanent cathode or direct plating technology lends itself to automation, allows for higher current densities and better cathode quality due to more robust geometric stability in the cell. The present barrier to implementation of permanent cathode plating at the RBMR Copper Tankhouse is the capital cost required to convert the tankhouse, i.e. blanks and stripping machine. At present, alternatives to titanium blanks, such as LDX 2101, are being investigated for the unique electrolyte composition of this tankhouse.

Jan 1, 2019

By A. Iizuka

This study was aimed at separating and recovering arsenic, antimony, and tin from refining byproducts generated in a nonferrous smelter. The target byproduct was a silicate slag containing the above elements. The silicate structure of the slag was destroyed by alkali roasting, which then enabled leaching of arsenic, antimony and tin in solution effectively. Arsenic was selectively leached out by hot water after alkali roasting of the slag, while remained antimony and tin in the residue were leached out by a hot hydrochloric acid solution. However, when the solid-liquid ratio in the leaching solution was increased, hydrous gelatinous silica (gel-like silica) was formed during the hydrochloric acid treatment and filtration became difficult. Therefore, high temperature and high pressure leaching was attempted to improve the filterability of the silica leaching residue. In the high temperature and high pressure treatment, the hydrous gel-like silica was transformed into easily filterable aggregated silica, and thus, filtration became easy. By investigating the neutralization and sulfurization treatment for the obtained hydrochloric acid leachate (second leachate), it was possible to separate antimony and tin. INTRODUCTION This study aims to separate arsenic and recover valuable metals such as antimony and tin from refining byproducts generated in a nonferrous smelter. The target smelting byproduct is antimony-containing slag in this study. In many cases, alkali roasting was adopted as pretreatment for extraction and recovering valuable metals from smelting residues and wastes (Rao, 2006). For antimony-containing slag in this study, one effective method for separating arsenic is to convert arsenic to sodium arsenate (Na3AsO4) by roasting with a sodium compound and then to remove arsenic by hot water leaching. In addition, by alkali roasting, the silicate structure of the slag is destroyed, and effectively alkalizing tin and antimony is accomplished. Then, precipitating and recovering tin and antimony leached into the acid solution are considered possible by sulfurization and neutralization treatments. In this research, we conducted basic studies on the following. 1) Destruction of silicate structure in slag by alkali roasting and leachability of arsenic. 2) Conversion of hydrous gelatinous silica to aggregated silica by hydrochloric acid treatment of residues after arsenic leaching under high temperature and high pressure, as well as leachability of antimony and tin. 3) Separation and recovery of antimony and tin by sulfurization and neutralization treatments of hydrochloric acid leachate. These topics of investigation can support to consider the separation and recovery process of arsenic, antimony, and tin from antimony containing slag.

Jan 1, 2019

By V. Barranco, K. Yliniemi, A. Hubin, B. P. Wilson, D. Janas, M. Lundström, P. Hannula

Typical copper electrorefining electrolyte contains tens of grams of copper, some nickel and a wide variety of impurities. Some of these impurities comprise trace amounts of dissolved precious metals like Ag, Pd and Pt that currently are not fully exploited. This study presents an electrochemical method to recover precious metals via a combined electrodeposition-redox replacement (EDRR) process, where energy is used only to deposit copper during the ED-step, while the RR-step relies on the spontaneous replacement of copper by the precious metals (i.e. cementation). In order to conduct the recovery successfully, process parameters such as deposition potential (EDE), deposition time (tDE), redox replacement time (tRR) and the number of cycles (n) was adjusted. Investigations performed in synthetic electrolyte (40 g/L Cu, Ag = 10 ppm) proved the possibility to recover a high purity silver. Short deposition times (tDE) were found to result in small Cu particles that provided a suitably high surface area for silver cementation. In addition, experiments performed in real industrial electrolytes containing 44 g/L Cu and 54 ppb Ag (Boliden Harjavalta, Pori), demonstrated that EDRR could attain Ag recoveries of between 46–67% in an energy efficient, additive-free manner. INTRODUCTION The raw materials used in the state-of-art primary and secondary copper smelters contain mainly base metals, but also notable amounts of Ag, Pt and other precious metals. These valuable metals distribute mostly into the copper matte during the pyrometallurgical treatment (Tirronen et al., 2017) and end up into the cast anodes. During the electrorefining stage, metals more noble than copper such as gold and platinum, are not dissolved but enrich into the anode slimes. In contrast, silver may dissolve slightly and thus, minor chloride addition is used to retain silver in the slime as sparingly soluble AgCl. Moreover, other metals less noble than copper may also dissolve, such as nickel. Therefore the electrolytes used in electrorefining typically contain substantial amounts of copper, nickel and even arsenic as well as minor metals such as antimony and bismuth. In the Boliden electrorefinery these were reported to be in the magnitude of 51.2– 60.4 g/L of Cu, 10.9–15.8 g/L Ni, 7.2–15.9 As, 0.2–0.4 Sb and 0.1–0.4 Bi with an associated sulfuric acid concentration of 139–155 g/L (Lehtiniemi et al., 2018). Copper is the most noble of the dominating base metals in the electrolyte and is thus deposited on the cathode as 99.99% purity LME-A grade. Anode slimes are collected and subjected to precious metals treatment e.g. via pressure leaching—selenium recovery— Doré smelting—Ag refining—Au/Pt/Pd leaching and reduction process (Ludvigsson & Larsson, 2003). The Pori refinery, operating in Finland since 1941, not only produces 133 000 t Cu cathode and 2300 t nickel sulphate annually but also 66 t silver, 4.6 t gold and palladium and platinum (in year 2017).

Jan 1, 2019

By F. L. Pirkle, W. C. Bagby

The International Mineral Valuation (IMVAL) Committee, founded in 2012, develops strategies for conducting mineral valuations. These strategies have been developed into a mineral asset valuation template called the International Mineral Property Valuation Standards Template and is part of IMVAL's work to establish consistent international standards for mineral property valuation and reporting. This template is a living document that is updated from time to time and is based on three core values or pillars (Fundamental Principles): Competence, Materiality, and Transparency. Objectivity, Independence, and Reasonableness may be applied as required by national codes or standards. The Template harmonizes international standards for valuation of mineral assets as real property and represents a consensus of current good practices. It is not a stand-alone reporting code and does not supersede existing national reporting standards. The Template deals with mineral-property valuation as distinct from mineral-project evaluation. INTRODUCTION In his 1989 book, “The New Realities”, Peter F. Drucker, Clark Professor of Social Science at Claremont Graduate School, California, stated: “Information is data endowed with relevance and purpose. Converting data into information thus requires knowledge. And knowledge, by definition, is specialized.” (p. 209) The discipline of mineral valuation is knowledge-based and requires a mineral valuer to collect, analyze, and interpret data that are material to a mineral valuation assignment. In so doing, the valuer turns the data into information (data come first, followed by information as determined by the mineral valuer) for use by the client (from whom the valuer obtained the mineral valuation assignment) and other intended users. The valuer uses his or her experience and education (each valuer’s knowledge base) supported by a foundation built upon competency, materiality, and transparency, the three pillars of mineral valuation (“minerals valuation”, “mineral-property valuation”). The International Mineral Valuation Standards Template (“IMVAL Template”, IMVAL”, “Template”), third edition dated May 2018, defines mineral valuation as: “The estimation of the Value of a Mineral Property in money or monetary equivalent. The word ‘valuation’ can be used to refer to the estimated value (the Valuation conclusion) or to refer to the preparation of the estimated Value (the act of valuing).” (p. 14) Furthermore, the IMVAL Template clearly separates valuation from evaluation: “The Template deals with Valuation, which is distinct from Evaluation. The distinction inherent in these defined terms is that Valuation addresses the estimation of value of a Mineral Property, whereas Evaluation addresses the broader assessment of a Mineral Property for an investment decision.” (p. 2)

Jan 1, 2019

By F. Calizaya, S. Bhattacharyya

"This study presents the results of a set of sound level measurements carried out in three underground mines where auxiliary fans are used regularly. Sound levels as high as 100 dB(A) by the workings and 115 dB(A) by the fans were measured in these mines. These levels are quite high even for intermittent noise. Ventilation layouts and best practices used to overcome potential problems related to overexposure to fan noise in underground hard-rock mines are presented here. Factors such as fan type, rotational speed, and silencer-duct arrangements and their effects on noise attenuation are discussed. INTRODUCTION Auxiliary fans are used in hard-rock mines extensively. They are used to ventilate development headings, crusher rooms, conveyor transfer points, and underground shops. They are also used in developing long tunnels and ramps. Depending on the flow requirements and space restrictions, single or double stage axial fans with rigid or flexible ducts are used. Usually, they are high pressure (3.75 kPa) fans with flow rates ranging from 7.1 m3/s to 30 m3/s. The input power varies from 15 kW to 113 kW (Mutama, 2004; O’Connor, 2008). Typically, a 113 kW fan can produce sound levels as high a 113 dB(A) (Howes, 2005). Silencers are often omitted for cost reduction purposes or when used, they are not well maintained. Furthermore, silencers provide limited attenuation depending on their length and type. Typically, the sound attenuation ranges from 10 dB(A) for a 1 × D silencer to 14 dB(A) for a 2 × D silencer, where D is the fan diameter. In a mine, the silencer is subject to wear and tear, especially when the silencer is used in harsh environments. The interior lining can get clogged and the acoustic fill can get covered by dust and diesel soot, thus reducing the silencer performance. Periodic cleaning of the interior casing can increase the attenuation capacity of a silencer by 6 to 9 dB(A) (Dabson & Acuña, 2017). However, this requires a special silencer design in which the inner cartridge can be removed, the sound absorbing material replaced, the inner casing cleaned and the whole set retrofitted. A number of techniques can be used to reduce auxiliary fan noise in underground mines. These range from selecting the right fan for the job to installing adequate silencers. The choice depends on the air quantity requirement at the working place, cross-sectional area of the opening, duct diameter, fan type (axial or centrifugal) and local restrictions. Auxiliary ventilation layouts and best practices used to overcome potential problems related to overexposure to fan noise in underground hard rock mines are presented here. Factors such as fan type, rotational speed, duct diameter, and silencer-duct arrangements and their effects on noise attenuation are discussed."

Jan 1, 2019

By C. Beul, R. Schipper, L. Santisteban

The Garfield Mine is a legacy vanadium mine in western Colorado with multiple mine openings, waste rock piles, and adit seepages that Cyprus Climax Metals Company (a Freeport-McMoRan Inc. subsidiary) voluntarily remediated through the Colorado Voluntary Cleanup Program (VCUP). The process to obtain a No Further Action determination from the VCUP is presented. Water treatment of the adit discharge, which is not part of the VCUP, is also presented. The remedial action objectives (RAOs) included preventing direct human or biotic exposure to the waste rock and radiation emitting from the waste rock; reducing metal concentrations and radionuclide activities in adit discharge and keeping the discharge from leaving the site; maintaining the existing undeveloped character of the surrounding landscape; and eliminating the need for a stormwater permit. The design included regrading, installation of an infiltration barrier and rock cover, a diversion channel, and a biologically based passive remediation water treatment system. An initial lab-scale evaluation provided design criteria for the full-scale system, which consists of a sulfate-reducing biochemical reactor and post-treatment aerobic polishing cells. The system has been operational since construction was completed in late 2016. Results indicate that the treatment objective of 90% bulk removal of constituents of potential concern (COPCs) is largely being met. The system also provides year-round operation and non-point discharge of effluent. After 20 plus years of site investigations, the remedial action was completed in 2016 with all RAOs met and a No Further Action determination granted in 2018. INTRODUCTION The Garfield Mine is a legacy vanadium mine located approximately 11 miles north-northeast of Rifle, in Garfield County, Colorado. It was leased and operated intermittently from 1929 to 1975 but was never operated by Cyprus Climax Metals Company (Cyprus) (a Freeport-McMoRan Inc. subsidiary). Prior to reclamation, site features included: • six mine openings—five adits and a vertical opening; • two adits discharging mining-influenced water (MIW)— Adit 1 at less than 4 liters per minute (L/min) and Adit 2 at 7 to 10 L/min; • main waste rock pile (13,500 m3) and small waste rock pile (minimal volume); • debris (small structure, mattress, bottles, shells, etc.) indicating site used for recreational purposes; and, • unimproved road, which has been used to access forest fires.

Jan 1, 2019

By S. K. Mohanty, T. M. Dittrich, M. J. Allen, M. Dardona, A. C. Strzelecki, J. Hovey, Boukhalfa. H.

Rare earth elements (REEs) have many critical uses in advanced technology and the lack of a reliable domestic supply has been identified by the US DOE as a vulnerability to US economic security. Our research focuses on developing an economical process for extracting REEs from coal fly ash and power plant wastewater sludge by coupling a hydrothermal extraction process with the engineering of a ligand-associated media for concentrating REEs from the extraction liquid. Ash samples have been collected from two Detroit-area Power plants that burn 100% low sulfur coal (Trenton Channel) or fuel blends of 75% low sulfur coal and 25% high sulfur coal or 70% low sulfur coal, 15% high sulfur coal, and 15% petcoek (Monroe Power Plant). Ash samples are then subjected to hydrothermal conditions from 100-350 °C for 1-24 h at Los Alamos National Laboratory and leachate concentrations are measured by inductively coupled plasma-mass spectroscopy (ICP-MS) and compared to hydrofluoric acid digestion results. Experiments designed to aid in ligand selection and loading optimization show that di-(2-ethylhexyl)methanediphosphonic acid (H2DEH or DIPEX™) can be successfully loaded to a commercially available swellable organically modified silica (SOMS) media. Preliminary results show that DIPEX-associated SOMS surface loading can exceed 4x on a mass/mass basis and in simplified sorption experiments with Nd solutions (~pH 2), the DIPEX-SOMS media can sorb >90 mg Nd per g of media. Recovery of the sorbed Nd with low pH solutions has had low efficiency with the high (4 g DIPEX/ g dry media); however, near complete recovery was achieved with lower surface loadings (0.05 g DIPEX/ g dry media). Column experiments are being conducted to evaluate the optimal ligand/media ratio for repeated use. Completive sorption with Fe and other major cations are also being evaluated.

Jan 1, 2019

By Ting Ren, Lihai Tan, Alex Remennikov, Xiaohan Yang, Xueqiu He

"Due to recent coal bursts in Australian coalmines, research of coal bursts has attracted intensive interest from mining researchers and engineers worldwide. Previous research has shown that the sudden drop of fractal dimension may be a precursor of catastrophic failure of rock. This paper examines the fractal characteristics of temporal-spatial distribution of acoustic emission signals released during the compression loading process of coal. This research suggests the possibility of coal burst forecasting based on acoustic emission data. The concept and calculation equation of fractal dimension is introduced in this paper. Additionally, uniaxial compression experiments of Australian coal samples are conducted, and the acoustic emission waveform and 3D location are recorded simultaneously by eight sensors Express-8 AE monitoring equipment in the loading process. The experimental results indicate that the continued slowdown of fractal dimension in time sequence can be used as a precursory signal of coal sample brittle failure. The fractal dimension of the spatial distribution of acoustic emission events decreases with the evolution of coal fracturing.INTRODUCTIONCoal bursts refer to the catastrophic failure of overstressed coal subject to the dynamic and static loads. In recent years, coal bursts have occurred in major coal mining countries and this phenomenon has attracted the research interests of international mining and geotechnical scholars. A total of five coal burst accidents happened in Australian coalmines since 2014. On October 20, 2018, a coal burst occurred at Longyun Coalmine in China’s Shandong province, which led to 21 fatalities. Unfortunately, even after decades of research, it seems neither more accurate forecasting methods nor comprehensive controlling measures put forward by researchers have solved the problems posed by coal bursts.As an instantons energy releasing process, coal bursts are always associated with energy dissipation in the forms of acoustic emission, micro seismicity, and electromagnetic radiation (Yamada, Masuda, and Mizutani, 1989). It is believed by many researchers that the frequency–magnitude relationship of micro seismicity induced by rock failure satisfies Gutenberg-Richer relationship as well (Feng et al., 2017). Hence, based on the principal and theory of earthquake source locating, micro-seismicity monitoring equipment has been adopted in many coalmines to locate seismic event origins associated with coal and rock failure in an attempt to better forecast coal and rock bursts. Although many parameters such as b value (parameter of Gutenberg and Richter’s law) (Lu et al., 2015) have been adopted as indicators of risk, the forecasting of coal bursts is still of low accuracy. The same is true with earthquake prediction, as it remains as a worldwide problem even after decades of research and practice. Acoustic emission (AE) methods are now widely adopted to detect rock failure processes under an applied stress for application predicting the abrupt failure of rock in the laboratory (Li et al., 2017). Previous studies have found that significant overlap exists between research regarding AE and micro seismicity with respect to generation process (both are concerned with the generation and propagation of elastic wave) and event origin location, as geophysical signals of both are same (Lockner, 1993). That is, the frequency–magnitude relationship and early-warning indicators found by AE research in the laboratory have a potential applicability to in-field micro seismic monitoring of coal bursts. Through experimental study, Feng and Seto found that the temporal distribution of acoustic emission counts of rock have distinct fractal structures during load-increase processes (Feng and Seto, 1999). Landis and Lucie found good correlation between fracture energy and AE energy during testing of mortar specimens as well (Landis and Lucie, 2002). Based on preliminary experimental study, many schol"

Jan 1, 2019

By P. Knudsen, S. Rosenthal

INTRODUCTION In 2010, Montana Tech was gifted 65 acres of land immediately west of the campus. The parcel of land included an old silver mine called the Orphan Boy Mine. The Orphan Boy and its sister, Orphan Girl, were developed about1895 and operated until 1956. In addition to the gift of land, a significant industry gift was obtained to develop a first class training facility, which we call the Underground Mine Education Center (UMEC). The UMEC has been funded primarily by industry through donations of dollars, equipment, and supplies. The UMEC is a unique hands-on, educational environment for today’s students who are being trained to find, develop and process the worlds' natural resources. The center complements courses in mining engineering, geological engineering, environmental engineering, metallurgical engineering and occupational safety and health. It also serves as a as research facility utilized by students and faculty, and other organizations interested in doing research a hard rock underground mine. LOCATION The Orphan Boy and Orphan Girl Mine are located approximately 700 feet (ft.) apart and the Orphan Girl Mine is part of the World Museum of Mining. Underground they are connected on various levels and all levels below the 100 ft. level are currently flooded. The Orphan Boy mine was 804 ft. deep and Orphan Girl was 3200 ft. deep. The surface locations of the two mines and some of the underground workings on the 100 ft. level are shown on Figure 1 (2015). CONSTRUCTION Land ownership was gifted from BP/ARCO in 2010 and planning started immediately. In June of 2011, site development for the decline to the 100 ft. Level of the Orphan Boy began with a satisfactory portal site developed (Figure 2). We hoped to be able to start driving the decline in July. However, the portal was sited approximately 125 ft. away from a natural gas line that bisected the Montana Tech campus. While outside the right of way for the line, Northwestern Energy requested that no blasting be performed near the gas line until such time as the gas line was abandoned in the fall so decline development was put on hold. The gas line was officially abandoned in January of 2012.

Jan 1, 2019

By Jessica M. Wempen

"Differential Interferometric Synthetic Aperture Radar (DInSAR), a satellite-based remote sensing technique, has application for monitoring subsidence with high resolution over short periods. DInSAR uses radar images to measure centimeter-level surface displacements. In the images, ground resolution can be relatively high, with each data point (pixel) representing the average displacement over an area of several square meters. The image data are acquired regularly which allows subsidence to be monitored sequentially over short periods; imaging periods typically range from weeks to months.Monitoring subsidence over short periods with high spatial resolution has potential to provide insight into the dynamics of subsidence and into relationships between mine advance and subsidence. In this study, for three longwall mines in the western United States, initial subsidence occurring at the start of longwall advance is quantified over short periods (12 to 72 days). C-band interferometric wide swath Synthetic Aperture Radar (SAR) images from the Sentinel satellites are used to quantify the subsidence. Overall, the data show initial development of subsidence, expansion of the subsidence trough, and the advance of subsidence in the direction of mining.INTRODUCTIONApplied Differential Interferometric Synthetic Aperture Radar (DInSAR)Differential Interferometric Synthetic Aperture Radar (DInSAR) is a satellite-based remote sensing technique that can be used to quantify small displacements of the Earth’s surface. Using data from the Seasat satellite, which was launched in 1978 (Jet Propulsion Laboratory, 2018), studies by Goldstein, Zebker, and Werner (1988) and by Gabriel, Goldstein, and Zebker (1989) applied Synthetic Aperture Radar (SAR) interferometry to topographic mapping and displacement monitoring. These studies established the potential for broader applications of radar interferometry. Studies by Foxall, Sweeney, and Walter (1998), Wright and Stow (1999), and Carnec and Delacourt (2000) represent some of the earliest evaluations of DInSAR for mine subsidence monitoring. All three of the studies demonstrated the application of DInSAR for quantifying mine subsidence. They also demonstrated difficulty accurately measuring subsidence over long periods due to data decorrelation. DInSAR continues to be evaluated as a tool to quantify surface deformation related to active and historic mining. For example, see Vervoort and Declercq (2018), Wempen and McCarter (2017a), Chen et al. (2013), and Liu et al. (2013). Technologies associated with SAR interferometry continue to develop. Recently launched satellites have relatively high spatial and temporal resolutions, and data processing methods and data accessibility are improving."

Jan 1, 2019

By Ian Bell

This paper investigates fragmentation in an aggregate quarry using the fragmentation-energy fan concept. Six blasts were monitored, located one behind the other in the same quarry area. The rock structure was blocky, the water level and the usage of explosives were variable within and between the blasts. The powder factor above grade was between 0.28 and 0.44 kg/m3 (0.47 and 0.74 lb/yd3). Fragmentation of the plant feed was measured using an online digital image analysis system and three belt scales. The oversize material that was not directly fed to the plant after the blast corresponds to 3‒9.3 % of the total. Data from image analysis was used to build the size distribution in the coarse range (fragments above 120 mm), and the passing fractions at 120 and 25 mm (4.72 and 0.98 in) obtained from belt scales data were used in the range 120‒25 mm (4.72 ‒ 0.98 in) . The non-dimensional percentile sizes between 10 and 90 % for each blast are described through power functions of the powder factor above grade; the model coefficients are statistically significant. From them, using the principles of the fragmentation-energy fan and the Swebrec distribution properties, the fragmentation can be expressed in terms of the powder factor by means of five parameters: the fan focus coordinates and the three parameters of a function of the exponents vs. the percentage passing. The model shows a good capability to describe fragmentation.

Jan 1, 2019

By A. M. Martinez, L. Melis, R. C. Peláez, L. G. Garcia

Orovalle Minerals S. L. operates a copper/gold mine in the Asturias region of northern Spain, with the operation dating back to December 1997. The feed to the El Valle mill, consisting of oxide/sulphide (skarn) mineralization, is highly variable, even on a shift by shift basis and presents challenges to the mill operating staff on a daily basis. The mineralogical characteristics of the ore are quite complex with copper present as native copper and sulphides as well as copper minerals with deleterious elements. Gold is present as native gold and electrum. The mill circuit includes SAG/ball mill grinding, gravity recovery of native copper and gold, flotation of copper concentrate, carbon-in-leach gold recovery and SO2/air cyanide destruction. The paper will provide a description of the different unit operations and present operating data of the mill operation.

Jan 1, 2019

By Tristan Worsey, Nathan Rouse

Florida legislature allocated funding for the Florida State Fire Marshal to review the applicability of the United States Bureau of Mines (USBM) Report of Investigations (RI) 8507 blast vibration limits with respect to Florida and its soils. The study also discusses whether the current blasting vibration limits set by statute are still appropriate, including a review of measured vibration amplitudes and frequencies, structure responses, and theoretical analyses of material strength and strains.

Jan 1, 2019

By D. An, J. Withers

A nano-scale investigation has been carried out by applying an AFM (atomic force microscope) to study in situ the adsorption of various collectors, i.e., oleic acid, octanohydroxamic acid (HA), and salicylhydroxamic acid (SHA), on bastnaesite in aqueous solutions. The obtained AFM images show that the surface morphology of bastnaesite changes greatly after it contacts the solutions of the collectors, suggesting that all these collectors can effectively adsorb on bastnaesite. Increasing temperature can help increase the adsorption of oleic acid on bastnaesite. FTIR (Fourier transform infrared) results also show that all these collectors adsorb strongly on bastnaesite with a strong absorbance spectra being detected, which confirms with the results obtained with AFM imaging analysis. In general, hydroxamic acid collector (HA and SHA) adsorbs on bastnaesite mainly in the form of insoluble metal hydroxamate. This specific adsorption mechanism explains that a high selectivity with a moderate collectivity will be achieved with a hydroxamic acid collector for the flotation of bastnaesite. INTRODUCTION Rare earth metals, which are very important to modern industry, are generally extracted from numerous rare earth minerals. In practice, however, the actual extraction of rare earth is mainly from bastnaesite, monazite and xenotime. The Mountain Pass mine is one of the largest rare earth mine in the world, at which the main rare earth mineral is bastnaesite. In the past years, froth flotation has been applied to the beneficiation of Mountain Pass ore. In practice, the rare earth ore is usually crushed, milled and further separated from calcite, barite and other gangue minerals by froth flotation, in which the rare earth oxide-bearing minerals stick to aerated bubbles in the pulp and float to the surface, leaving the gangue at the bottom of the flotation cell and disposed of as tailings.(Bulatovic, 2010) In spite of the fact that froth flotation has been applied to treat the bastnaesite ore at the Mountain Pass mine, the rare earth oxide (REO) recovery is still low,(Anderson, 2015) especially compared to the one obtained with sulfide flotation. For example, the typical recovery obtained at the Mountain Pass mine was only about 70%. This may be due to the low selectivity of the collector (oleic acid). In addition, to enhance the flotation selectivity, the pulp in the mine circuit has to be heated up to 70 to 90°C and it involves a lot of energy consumption. Last but not the least, a lot of depressants have to be added to improve the selectivity of flotation process. Therefore, it is critical to re-examine the existing flotation process at the Mountain Pass mine and seek any chance of improvement. (Anderson, 2015)

Jan 1, 2019

By K. C. Corin, B. McFadzean, J. G. Wiese

The Bushveld Complex of South Africa contains almost 90% of the world’s reserves of platinum group minerals (PGMs). In the flotation of PGMs, there are significant challenges arising from the need to treat ever-decreasing grades of the relevant ore deposits. The major challenge in the flotation of these ore bodies is the control and management of the gangue minerals, particularly silicates such as orthopyroxene and plagioclase feldspar which are often rimmed with talc which makes them naturally floatable. It has been shown that various polysaccharide depressants such as CMC and guar have different properties in terms of depressing the gangue minerals. Since the PGMs are often associated with sulphides, copper sulphate is widely used as an activator in PGM flotation but can inadvertently activate the gangue minerals and reduce the recovery of PtTe2 which accounts for up to 40% of the Pt in the Platreef ore body. Depressants also reduce the mass of solids reporting to the froth and can thus destabilize the froth. This effect on the froth can be mitigated by using higher frother dosages or water of higher ionic strength. In summary due care needs to be taken to carry out site test work to develop an optimum ratio of collector, frother, activator and depressant to ensure that the highest grades and recoveries of the PGEs are obtained while reducing depressant dosage as much as possible. Chromite recoveries can be reduced through the application of gravity separation or reducing entrainment through reduced water recovery. INTRODUCTION The Bushveld Complex located in the north of South Africa contains the world’s largest deposit of Platinum Group Minerals (PGMs) (1). The so-called upper Critical Zone of the Complex hosts the largest concentration of platinum group elements (PGEs) in the world. The Zone hosts the Upper Group Chromitite No.2 (UG2) reef and Merensky Reef as well as the Platreef mineralization of the northern limb of the Bushveld Complex. The Merensky pegmatoid Zone contains the base metal sulphide grains and associated PGMs. Of particular importance to the topic of this paper is the occurrence in these reefs of various gangue minerals. The Merensky Reef consists predominantly of orthopyroxene (~60%), plagioclase feldspar (~20%), pyroxene (~15%), phlogopite (5%) and occasional olivine. Secondary minerals such as talc, serpentine, chlorite and magnetite have widespread occurrence. Of these, talc is the only mineral to show significant natural floatability (2,3). Although present in small amounts talc is closely associated with pyroxene and imparts significant floatablity to the high concentrations of pyroxene present in these ores (4). The base metal sulphides consist predominantly of pyrrohtite (~40%), pentlandite (~30%) and chalcopyrite (~15%). The major platinum group minerals are cooperite (PtS), braggite [(Pt,Pd)NiS], sperrylite (PtAs2) and PGE alloys. The UG2 consists predominantly of chromite (between 60 – 90% by volume) with lesser silicate minerals (5 – 30% pyroxene and 1 – 10% plagioclase). Other minerals present in minor concentrations, can include silicates, oxides and base metal sulphides. Total PGE varies by locality but on average range between 4 and 7 g/t. The PGMs present in the UG2 Reef are highly variable, but generally the UG2 is characterised by PGE sulphides such as laurite (RuS2), cooperite (PtS) and braggite [(Pt,Pd)NiS. The base metal sulphides consist predominantly of chalcopyrite, pentlandite and pyrrhotite. The Platreef is located in the northern limb of the Bushveld Complex. This reef consists of a complex assemblage of rock types, with pyroxenites, serpentinites and calc-silicates being the most abundant. Base metal mineralization and platinum group element (PGE) concentrations are found to be highly irregular, both in value as well as in distribution. The predominant platinum group minerals (PGM) in the mined area of the Platreef are the PGE tellurides, alloys, arsenides and sulphides. T

Jan 1, 2019

By J. Ipinza, J. P. Ibáñez, Casas J., S. Cortés

Copper powder generated during the treatment of electro-metallurgical bleeds by reactive electro- dialysis (RED) had totally reduced the content of ferric ions in acidic synthetic electrolytes (Cu (II)- Fe (III) – H2SO4). In batch and columnar experiments 100% of the ferric ions were reduced to ferrous ions with an extremely high kinetics. A preliminary conceptual design for reducing ferric ions based on an integrate RED- Column for treatment of electro-winning bleed system is discussed. This system is able to recover simultaneously sulfuric acid and copper powder, which will reduce ferric ions. INTRODUCTION It is well known the negative effect of ferric ions in the copper electro-winning process. The increase of ferric content in the electrolyte reduces the current efficiency, i.e., there is an increase in the energy consumption, and changes the surface morphology of the copper deposit (Das, Gopala & Krishna, 1996; Vargas & Parra, 2013). The increase of the specific energy consumption due to the loss of current efficiency occurs by the reduction reaction of ferric to ferrous ions in the cathode, at the anode the ferrous ions are slowly oxidized to ferric ions (Shaw, Dreisinger, Lancaster, Richmond & Tomlinson, 2004). To control the level of iron in the electrolyte, bleeds are needed; this bleed electrolyte containing copper, sulfuric acid, cobalt, iron and other impurities normally is waster, which increased the production cost of the plant (Milbourne, 2002; Mckevitt & Dreisinger, 2009). Then, permanent efforts oriented to treat those bleeds to avoid losses of valuables components are made; among them are use ion exchange resins (Shaw et al., 2004; Mackevitt et al., 2009), chemical precipitation (Izadi, Mohebbi, Amiri & Izadi, 2017) and electrodialysis (Cortés, Ipinza & Ibáñez, 2013). The last one allows to the simultaneous recovery of sulfuric acid and copper powder. If one of the valuables obtained by treating the bleed can be used to reduce ferric ion concentration in the electrolyte could be an important asset. This issue at laboratory scale is reported in this work, the use of copper powder, generated by reactive electro-dialysis when treating synthetic acidic electro-metallurgical bleeds, for reducing ferric ions in acidic electrolytes.

Jan 1, 2019

By N. A. Beier, N. Slingerland

"Oil sands tailings impoundments rank among the largest (spatially) in the world, covering a total of approximately 220 km2 of northern Alberta, Canada. A preliminary geomorphic design for an oil sands tailings storage facility (TSF) landform was completed with the goal of eventual closure and delicensing in mind. This paper outlines methods identified during the design process that streamline closure when implemented early in the mine planning and TSF design stages. With most oil sands TSFs currently in active operation (and some still in the planning stages), geotechnical engineers and mine planners have the opportunity to make operational and design decisions, such as those outlined herein, that are likely to improve the geotechnical and environmental performance of the landform post closure. ¦ KEYWORDS Alberta, Athabasca oil sands (AOS), Landform design, Reclamation, Sand dam, Tailings storage facility (TSF) RÉSUMÉ Les bassins d’accumulation des résidus issus des sables bitumineux font partie des plus grands (en termes d’espace) au monde, et couvrent au total environ 220 km2 dans le nord de l’Alberta, au Canada. Une conception géomorphologique préliminaire a été réalisée pour le modelé d’une installa¬tion de stockage des résidus (ISR) issus des sables bitumineux en gardant à l’esprit la fermeture et le retrait de permis à terme. Cet article présente les méthodes identifiées pendant le processus de conception qui simplifient la fermeture lorsqu’elles sont mises en oeuvre dès les premières étapes de planification de la mine et de conception de l’ISR. La plupart des ISR issus des sables bitumineux se trouvent dans des exploitations actives (dont certaines en sont encore aux étapes de planification), aussi les ingénieurs géo¬techniques et les planificateurs miniers ont la possibilité de prendre des décisions en termes d’exploita¬tion et de conception, telles que celles présentées ici, qui pourraient améliorer la performance géotechnique et environnementale de la phase suivant la fermeture du modelé. ¦ MOTS CLÉS Alberta, assainissement, barrage de sable, conception du modelé, installation de stockage des résidus (ISR), sables bitumineux de l’Athabasca (SBA)INTRODUCTION The Athabasca oil sands (AOS) underlie 140,200 km2 of land in northeastern Alberta, Canada. Oil sands located within 100 m of the original surface account for 4,800 km2 of the total area and are considered to be economically mineable (Figure 1; ERCB, 2009). Bitumen, the thick, tar-like substance contained in the AOS, is extracted through open-pit mining and in-situ methods. During mining, the overburden is first removed as waste and the sandy, bitumi¬nous ore (“oil sand”) is transported to processing facilities via conveyor belts and 400 t trucks. Warm and hot water, as well as process aides such as caustic soda, are mixed with the oil sand, creating a slurry from which bitumen is mobilized and extracted. The resulting slurry waste product is called “tailings” and contains mineral solids, process water, and small proportions of unrecovered bitumen (Masliyah, Zhou, Xu, Czarnecki, & Hamza, 2004; Sobkowicz & Morgenstern, 2009)."

Jan 1, 2019

By R. C. Gilmore, J. McMack, G. E. Bogin, J. F. Brune, C. DeRosa

"Researchers at the Colorado School of Mines are designing and building a 1:40 scaled physical model of a fully operational longwall coal mine. The purpose of the model is to minimize the occurrence of methane explosion hazards by testing various ventilation strategies and determining optimal methane sensor placement throughout the longwall face. Fluid scaling factors were analyzed using Computational Fluid Dynamics software Ansys FLUENT™ at both full and 1/40th scales. Researchers were able to identify key scaling factors and subsequently developed suitable flow parameters that would maintain full scale accuracy of flow patterns in the 1/40th model. KEYWORDS Coal, Longwall, Methane, Explosion, Scale Model, Ventilation, Fluid Dynamics, Richardson, Gob, Porous INTRODUCTION Mine ventilation systems are a key component for ensuring a safe working environment by introducing fresh air from the surface and diluting explosive gases and hazardous contaminants. This holds true for longwall coal mines where the emission of flammable methane gas from the longwall face as well as the gob can create explosive mixtures of methane and air. Therefore, an effective ventilation strategy can help mitigate the potential for accidents within a mine. Developing an effective mine ventilation system (MVS) requires a detailed understanding of the physics of gas transport and how this relates to specific geometries and obstructions in the face. Researching this phenomenon requires the development of computational fluid dynamics models capable of simulating fluid flow and methane species transport that can be validated through physical experimentation. Unique site conditions determine ventilation layouts for every coal mine. Researchers have designed a 1/40th scaled physical model of a longwall coal face and adjacent gob that includes movable shield supports and a movable shearer with rotating cutter drums that can be adjusted to a variety of ventilation conditions. The proposed work will address the need for an improved Mine-wide Atmospheric Monitoring System (AMS), and provide the ability to link existing MVS models with AMS in real time. By accurately representing the coal face, the gob area and the mining equipment, gate roads and bleeder entries, the scaled model accurately represents all relevant structures, geometry, and dynamic conditions. A Plexiglas cover allows full optical access for sensor equipment as well as visual inspection of the fluid flow and species transport."

Jan 1, 2019