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By S. Lubbe

South Africa and Australia are the biggest suppliers of zircon sand to the international zirconium industry. However neither South Africa nor Australia is well known for zircon beneficiation. Geratech Zirconium Beneficiation Ltd (GZB) continued with additional research on sodium hydroxide (NaOH) cracking of zircon sand during 2002-2003. In 2003 GZB started extracting zirconium from zircon sand by means of NaOH cracking on a commercial scale. Experience has shown that temperature profile and atmospheric control inside the furnace is crucial for the beneficiation of zircon sand. Silica carryover to zirconium chemicals could result if a high temperature is used. Once the sodium silicate is extracted from the sodium zirconate and dissolved in hydrochloric acid, two distinct routes can be followed to precipitate various zirconium chemicals. The most common route is to precipitate zirconium oxychloride crystals (ZOC), with subsequent purification from all contaminants (crystal route). Less known is the process (liquid route) that involves the direct precipitation of zirconium basic sulphate (ZBS). This route will yield a less pure product, with contaminants such as silica and titanium. An important factor in this route is the prevention of silica gel formation, which could hamper final product filtration. For applications like paint drying (zirconium octoate) or antiperspirants (zirconium hydroxychloride) low levels of contaminants have no effect on the final product. The advantage of the liquid route is fewer production stages compared to the crystal route. The disadvantage of the liquid route is that the market for the products will be significantly smaller. The optimum solution could be a plant design that could cater for both routes. Another example of an application of zirconium chemicals is the use of ammonium zirconium carbonate (AZC) in the paper industry. Zirconium basic carbonate (ZBC) is dissolved in ammonium carbonate to produce AZC solution. AZC is used mainly in European countries in the paper industry. For example, carton boxes were initially produced with formaldehyde as the binder, however, it has now been replaced with AZC since formaldehyde is considered toxic. AZC reacts with the cellulose fibres in the paper to act as the binder. The resulting product is not toxic, and printing ink dries very quickly due to the porous paper structure. Other applications of zirconium chemicals involve the use of acid zirconium sulphate tetrahydrate (AZST), zirconium orthosulphate (ZOS), potassium zirconium carbonate (KZC), and zirconium hydrous oxide (ZHO). Fluoride-based zirconium chemicals like zirconium tetra-fluoride (ZrF4) and hexafluoro-zirconic acid (H2ZrF6) are used in the aluminium industry. Zirconium oxide (Zr02) can be produced from any of the abovementioned precipitated chemicals via a high-temperature decomposition process. The physical properties of such oxides can differ tremendously, depending on the final application. The fired density of sanitaryware is typically 5.8 g/cm3, compared to milling media at >6.1 g/cm3. The required fired density is achieved by controlling the precipitation and decomposition conditions for these two oxides. The same applies to stabilized and mixed oxides, for example where zirconium oxide acts as an oxygen carrier in fuel cells.

Jan 1, 2012

By G. Belardi

A study has been conducted to assess a new wet beneficiation treatment for the recovery of the sulphuric-acid-soluble titanium oxide contained in the waste from an Italian TiO2-pigment facility. The waste is produced during treatment of a Ti-enriched slag and contains as main components TiO2 (54%, of which 42% acid-soluble and 12% insoluble), SiO2 (27%) and A1203 (6%). Eighty percent of the material is finer than 50pm. The first step was to ascertain the possibilities offered by size classification, wet gravity separation, froth flotation and wet high-intensity magnetic separation to improve the grade and recovery of Ti02 and reduce the SiO2 content. The next step was to optimize the operating conditions of the various separations and assemble them into a complete flow- sheet. Beneficiation ensures potentially 70% recovery of the TiO2 with a concentrate grade of 80%.

Jan 1, 1998

By Xiaoping Xu

An albitization granite type tantalum-niobium ore from Jiangxi Province, China was taken as the research object in this paper. The main valuable minerals in this ore are tantalite-columbite and uranmicrolite, and the minerals that can be comprehensively recovered include cassiterite, sulfide minerals, topaz, zinnwaldite, and quartz-feldspar. Based on the research results of process mineralogy, the roughing process of gravity separation for coarse particles combined with flotation for fine particles is proposed. The combined cleaning process of flotation-gravity-magnetic-electric-hydrometallurgical separation is adopted for the rough concentrate of gravity separation while the combined cleaning process of gravity-flotation- hydrometallurgical separation is adopted for the rough concentrate of flotation. High intensity magnetic separation is used to separate and recover zinnwaldite and quartz-feldspar from gravity tailings. By mineral processing for the crude ore containing (TaNb)cassiterite concentrate is 0.0003% with a grade of Sn 63.22% and a recovery of Sn 47.42% while the yield of sulfide concentrate is 0.0783% with a grade of Pb 33.15% and Zn 27.09% which can be separated to get lead and zinc concentrate respectively. The yield of topaz concentrate is 0.1545% and the topaz mainly distributed in the size range of -0.4+0.074mm, which can be made into abrasive products of different particle sizes after classification. The yield of zinnwaldite concentrate is 16.91% with a grade of Liwhiteness of 75%, which is a glass-ceramic material of good quality. 2O5 0.0346%, Sn 0.04%, Pb 0.10% and Zn 0.33%, the tantalum-niobium concentrate with a yield of 0.00278%,a grade of (TaNb)2O5 53.61% and a recovery of (TaNb)2O5 44.49% is obtained. And the yield of 2O 1.34% and Rb2O 0.40%. The yield of quartz-feldspar concentrate is 30.42% with a grade of K2O+Na2O 8.98% and Fe2O3 0.11% and a natural All of tantalum, niobium, cassiterite, topaz, zinnwaldite, quartz, and feldspar are recovered effectively. Keywords: tantalum-niobium ore, gravity separation for coarse particles, flotation for fine particles, comprehensive recovery

Sep 1, 2012

By Hao Zhang, Dezhou Wei, Qiang Zhao, Caie Zhang, Baoyu Cui, Xuetao Wang

"Nowadays, long periods of relatively low iron ore prices have made the steel industry get the greater pressure. To develop appropriate processing technology based on characteristics of the iron ore, so as to reduce the beneficiation costs, is crucial to the improvement of iron and steel enterprise competition. For a typical low-grade iron ore from northeast China, beneficiation process research was conducted based on the in-depth studies of ore characteristics. Results show that the iron grade of the ore was 31.56%, the content of FeO was 6.59%, the main iron minerals were hematite and magnetite with fine dissemination sizes and partly scattering in gangue; With the grinding fineness of 65% passing 0.074mm, and regrinding fineness of 90% passing 0.074mm, the concentrate with 66.80% iron and recovery of 82.90% was obtained via the combined flowsheet of stage grinding – classification – gravity concentration – low and high intensity magnetic separation – reverse flotation. Ratios of gravity concentration and low intensity magnetic separation were 70.21% and 7.57% respectively in 40.42% of total concentrate yield; The loss of micro-size fractions can be reduced by feeding spiral tailings into magnetic separation and flotation; It’s helpful in reducing the dosage of reagents and beneficiation costs by increasing the throughput of gravity concentration and outputting concentrate of low intensity magnetic separation.INTRODUCTION Iron and steel industries are facing the increasing pressures in the continued falling iron ore prices. In order to improve the competitiveness, it is extremely urgent for them to develop more appropriate separation process for the reduction in iron ore beneficiation cost. As a typical low-grade iron ore, Anshan-type iron ore is one of the most important iron ore resources in China [1-3]. The flowsheet of stage grinding and separation contained the classification of the coarse particles and the fine particles, the gravity concentration, the magnetic separation and the anionic reverse flotation has been widely applied for Anshan-type iron ore. With the appropriate separation progress as well as equipment, satisfactory separation results had been obtained, and mineral particles with different size were recovered separately [4-7]. However, the low recovery of fine mineral particles and the relatively high beneficiation costs still prevented the efficient application of the process [8]. For a Anshan-type low-grade iron ore, a typical process flowsheet, as mentioned earlier, with stage grading, classification of the coarse particles and the fine particles, gravity concentration, magnetic separation, anionic reverse flotation was adopted currently. And the concentrate with 67.10% iron and recovery of 75.50% was obtained and the gravity concentrate accounted for 39% of the total concentrate. However, a large amount of fine liberated iron ore particles were lost in the tailings."

Jan 1, 2018

By T. Saastamoinen, N. Heino

"The Olserum deposit located in Sweden hosts an indicated mineral resource of 4.5 million tonnes over 0.6 % TREO, exhibiting a relatively high proportion of HREE. Beneficiation of a composite drill core sample was studied in the flowsheet of magnetic separation of magnetite followed by REE minerals flotation. Primary testwork was performed to select an effective REE mineral collector and then the parameters of grinding size, collector and depressant dosages, slurry pH and density, conditioning time and temperature, and flotation time were tested for optimization of REE flotation. The studies of process mineralogy showed that the REE-bearing minerals monazite, xenotime and apatite were successfully enriched from the concentrations of 0.6%, 0.31% and 2.6% in the feed to those of 17.0%, 8.9% and 65.0% in the concentrate with the recoveries of 79.0%, 81.3% and 71.0%, respectively. INTRODUCTION The Olserum deposit located in Sweden comprises lower grade placer material with higher grade apatite-magnetite veins and hosts an indicated mineral resource of 4.5 million tonnes at 0.6% TREO, with 34% of that being HREO (EURARE, 2017). The mineralization was studied by Andersson et al. (2018). At early stage, high-temperature REE is characterized by abundant monazite-(Ce) and xenotime-(Y) coexisting with fluorapatite and subordinate amounts of (Y,REE,U,Fe)-(Nb,Ta) oxides. During a subsequent stage, allanite-(Ce) and ferriallanite-(Ce) formed locally, partly resulting from the breakdown of primary monazite-(Ce). Alteration of allanite-(Ce) or ferriallanite-(Ce) to bastnäsite-(Ce) and minor synchysite-(Ce) at lower temperatures represents the latest stage of REE mineral formation. The mineralogy and beneficiation were firstly studied by GTK Mintec in the EURARE project for a composite drill core sample. The Olserum is considerably smaller than the Norra Kärr deposit. However, REE are hosted by xenotime and monazite, both of which have well established processing pathways, and meanwhile, the Olserum has a high contribution of the high value critical REE (dysprosium (Dy), yttrium (Y), neodymium (Nd) and terbium (Tb)), which provide a unique advantage for its exploration (Tasman Metals Ltd., 2013). In this paper, flotation of the REE minerals in the Olserum ore was studied."

Jan 1, 2018

Beneficiation Studies of Dolomitic Rock Phosphate in Pursuit of Zero Waste Technology - A Case Study

Sep 13, 2010

By Mingfei He, Xianyang Qiu, Hongling Wang, Yude Gao, Qingbo Meng, Xiaoping Xu, Hao Bu, Guosheng Wang

"By the “HGMS-gravity separation-Flotation” combined technology, a Ta-Nb-Sn concentrates with the grades of Ta2O5 10.00%, Nb2O5 9.13% and Sn 42.62% at the recovery of 44.73% , 9.13% and 14.62% respectively , a Li concentrate with Li2O 3.11% at the recovery of 51.83% and a feldspar product are obtained. All the value elements are recovered. INTRODUCTION Tantalum and niobium widely used in electronics, atomic energy, aerospace and chemical industries with the advantages of high melting point, good ductility, low vapor pressure, strong corrosion resistance and high thermal conductivity are important strategic resources which occupy a special position in rare metals (Crockettand, 1993; GAO and Zou, 2004; LI and HUANG, 2012). China's tantalum and niobium resources are poor, and most of them are low grade, fine grain size, complex composition, and polymetallic associated with refractory mineral resources (GAO and Qiu,2013; Liang and Li, 2016). The Yifeng Lion Ore containing lithium and other rare metals (tantalum, niobium and tin) is an important lithium polymetallic deposit in China Jangxi province. While extensive previous studies have settled on the recovery of lithium minerals by flotation only for the extremely low grade of Ta, Nb and Sn. The regular gravity concentration is used, and the recovery of tantalum niobium is low. This paper sets out to investigate a combined flowsheet of “high gradient magnetic separation (HGMS),-gravity separation-flotation” to effectively comprehensively recover the Li, Ta, Nb, Sn and the feldspar resources in the Yifeng Lion Ore.ORE PROPERTIES Chemical analysis The run of mine comes from Jiangxi Yifeng Lion ore. The main elements of the ore chemical analysis results shows in Table 1. From Table 1, the grades of lithium and rubidium are relatively high, but the grades of tantalum and niobium are lower than the industrial grade; feldspar with high content of potassium and sodium and low content of iron can be used as high-quality ceramic raw materials."

Jan 1, 2018

By Khosia NK, Ravishankar SA, Sankar TAP

Alumina reduction in Rajhara iron ore slimes essentially involves separation of hematite from gibbsite in relatively coarser fraction and from kaolinite in the finer fraction. Selective dispersion flocculation studies on synthetic mixtures clearly indicated that while it was possible to achieve almost perfect separation of hematite from kaolinite using starch and PAMX (modified polyacrylamide containing hydroxamate functional groups) flocculants, no selectivity was observed in iron oxide-alumina system. A schematic flowsheet suggested on the basis of this work for the beneficiation of Indian ore slimes thus consists of classification in a hydrocyclone, followed by selective dispersion of coarse fraction (underflow) and selective flocculation of the overflow fraction. Starting with a feed assaying 46 per cent Fe and 11.6 per cent A1203, a concentrate assaying 60 per cent Fe and 4.7 per cent A1203 could be produced at an overall iron recovery of 60 per cent using conventional Reagents.

Jan 1, 1993

By D. Krebs, Tero Korhonen, X. Yang, A. Kirpala, N. Heino

At present, over 85% of the world’s rare earth oxides are produced from the bastnäsite ores, found mainly in China. Meanwhile, the ion adsorption ores are the most important sources for heavy rare earth production. As the demand for rare earth materials in the world increases, other forms of rare earth deposits will become new potential resources of rare earth production in the future. In this paper, flotation performance of a steenstrupine ore from the Kvanefjeld deposit for rare earth recovery was studied through laboratory bench testwork. The effects of various factors including grinding size and collector dosage on recovery and selectivity of the selected rare earth elements, La, Ce and Y, were investigated. A rare earth concentrate with the grades of La 2.8 wt%, Ce 5.1 wt% and Y 1.0 wt% at recoveries of 80.5% La, 79.8% Ce and 55.3% Y was obtained in optimum conditions. Further potential to improve the efficiency of REE flotation was discussed. Keywords: Rare earth elements, flotation, steenstrupine, Kvanefjeld deposit

Jan 1, 2020

The present work aimed to verify the possibility of using froth flotation to separate the constitu-ent minerals of an alaskite rock waste having as the main minerals quartz and feldspar. Three stages of tests have been carried through. In the first stage was used an amphoteric collector for flotation, diaminedioleate, at pH 2 and, after analyzing the final products, a very poor selectivity was ob-served. During the second stage of tests, different collectors that are normally used for feldspar flo-tation as amines, sulfonates and soybean oil were employed. Once more, it was not possible to reach reasonably selective results. In the third stage, a salt of etheramine was used for collecting the feldspar and hydrofluoric acid was utilized for controlling the pH. A simulation of three flotation steps (rougher, cleaner and recleaner) permitted to attain a good selectivity in the flotation process. A concentrate with a silica content of 96.6% was obtained. The low concentrate content of alkalis totalizing 0.52% and a feldspar recovery of 96.5% to the tailings, represented by the high content of Na, K, and Al2O3 in the tailings, demonstrated that the concentrate was made up mostly of quartz.

Jan 1, 2014

By W Liu, S Gao, D Wei, B Cui, Z Guan, Y Shen

Beneficiation of low-grade fine-grained hematite ores becomes increasingly important due to rapid depletion of high quality iron ore resources. However, fine particles, especially ultra-fine particles, make efficient beneficiation of these ores more difficult. Therefore, methods to reduce the influence of fine particles must be considered to achieve better beneficiation performance. Analysis and systematical beneficiation tests were carried out on an ultra-fine-grained hematite ore slime from washing a fine grained hematite ore. Ore particles were found to be presented in loose soil. While some of the ore particles were agglomerated, they were very fine and contained up to 76.5 per cent -0.023 mm material. In this paper, using a single magnetic separation flow sheet with sodium silicate (SS) as a dispersing agent, a concentrate containing 65.05 per cent Fe was obtained at an iron recovery of 68.58 per cent from the hematite ore slime of 56.65 per cent Fe. The single magnetic separation flow sheet was simple and reliable, the agent SS was effective in dispersing ultra-fine particles. The results are believed to be applicable to similar hematite ores.CITATION:Wei, D, Guan, Z, Gao, S, Liu, W, Shen, Y and Cui, B, 2013. Beneficiation study of an ultra-fine-grained hematite ore slime, in Proceedings Iron Ore 2013 , pp 495-500 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By X. Q. Cao

As the second largest phosphate resource in the world, Chinese phosphate ores generally grades with low of P2O5. The presentation of beneficiation test on the low grade of phosphate rock in this paper may be used for a reference for development and utilization of the similar reserves. The ore is a marine sedimentary phosphate rock containing low grade of P2O5 and high content of MgO and R2O3; The banded structure shows its suitability for heavy medium separation. The laboratory heavy liquid testing results indicate that as specific gravity of the heavy liquid is 2.85 g/cm3, a rougher concentrate assaying 28.71% P2O5 could be obtained while the rougher tailings contain only 4.47% P2O5. When the combined process with heavy liquid separation followed by direct & re-verse flotation is employed to treat the feed containing 21.15% P2O5, 3.79% MgO, 1.86% Fe2O3, 3.66% Al2O3, 23.75% A.I, and specific gravity of heavy liquid is 2.84 g/cm3, the optimum mesh of grind is 67.5% minus 200 mesh, a phosphate concentrate contained 32.51% P2O5, 0.48% MgO, 0.81% Fe2O3, 1.69% Al2O3 can be produced at a yield of 55.24%. The concentrate P2O5 recovery is 85% with which quality comply with the Class A specifications for production of phosphate fertilizer.

Jan 1, 2014

El presente trabajo describe el sistema y los métodos para la extracción del oro en la planta de beneficio de Andaray Gold Mines, alcanzando una productividad óptima en el campo metalúrgico. La mina está situada en San Juan de Chorunga, provincia de Condesuyos, departamento de Arequipa, donde sus yacimientos mineralizados son de dos tipos: los yacimientos descompuestos que contienen limonita y oro libre, perteneciente a la mina Mercedes , y los de mineral piritoso aurífero, que comprenden chalcopirita y ojos de galena, perteneciente a la mina San Juan. El proceso de explotación se inicia con el transporte del mineral hasta su descarga en la parrilla de apertura. E mineral que no pase por la parrilla, se deriva a la chancadora durante 10 horas. Posteriormente pasa por la molienda para luego ser clasificado. Allí se adicionan los reactivos para la flotación y su análisis de malla. Producto de la flotación se obtiene el concentrado. El filtrado de los concentrados conlleva su envío a la molienda secundaria durante un período de seis horas. En este estado, la partícula de oro se encuentra limpia y en óptimas condiciones para la amalgamación y cianuración, donde el mercurio y la amalgama son exprimidos en una lona, destilándose, y se procede a la solución del oro, respectivamente. El método seguido es la agitación neumática, que suelta aire comprimido para la elevación del concentrado por el tubo elevador. Prosiguen los efectos de decantación, operación, control del cianuro y del alcali libre, precipitación, clarificación, limpieza y función de los precipitados. En el laboratorio se realiza el control de muestras del circuito de flotación, cianuración y de las barras, utilizando los métodos de soluciones de cianuro, ensayo de concentrados, minerales de mina, cabeza y relaves y ensayos de los precipitados. Finalmente, los cuadros de consumo de reactivos, mostrarán la eficacia del sistema y los resultados económicos de la planta de beneficio, como los costos, eficiencia de plata y mano de obra.

Jul 20, 1957

By Pedro Dominguéz S

La exposición apunta al doble tratamiento metalúrgico para la recuperación del oro, cobre y plata contenidos en los minerales de la mina Calpas. Para ello, el conjunto de vetas de las minas,muestra las zonas en las que predomina el cuarzo y la pirita con oro y algunas trazas de cobre. En este punto, surge la cianuración como tratamiento para beneficiar aquellos minerales con cobre, como aquellos que no lo tienen y en el que las instalaciones de plantas de beneficio permitirá una producción mayor a su tonelada.

Jun 20, 1954

By Alexander Sutulov

El presente texto señala la importancia del beneficio de minerales sulfurados y oxidados de cobre a través de dos apartados: Los aspectos generales y la mineralurgia del cobre. Los primeros comprenden la disminución del contenido fino de las menas, materias primas complejas, aumento de escala, control automático y planta del futuro. Mientras que el segundo, describe la flotación de sulfuros, el proceso de segregación, tratamiento de óxidos, métodos hidrometalúrgicos y la lixiviación bacteriológica.

Nov 20, 1969

By Víctor Tenorio

Las restricciones sanitarias impuestas por la pandemia del COVID-19 constituyen un referente forzoso para replantear las actividades de explotación, con el fin de no afectar los objetivos de producción. El obligado distanciamiento social exige contar con equipos teleoperados, vehículos autónomos, una nueva infraestructura de transmisión de datos que permita interactuar a los equipos con eficiencia y seguridad, salas de control para la supervisión centralizada y la incorporación de dispositivos compatibles con la internet industrial de las cosas. Todo ello representa, de acuerdo con el autor de este texto, una oportunidad para reactivar las operaciones y nivelar la tasa de producción, instalando un proceso de cambio que va desde la gerencia hasta los operadores.

Jul 30, 2020

By Percy Chávez

Dado el avance de la globalización, las empresas mineras latinas se encuentran expuestas ante el poder de las empresas transnacionales -en tanto estas utilizan información estructurada, verificada y centralizada para tomar las decisiones más acertadas y tener el control de las condiciones operativas. En este sentido, el presente texto señala la experiencia realizada en la Cía. Minera Atacocha aplicando la información centralizada para el desarrollo de proyectos de infraestructura en sus operaciones mineras.

Aug 25, 2002

By Francisco Anglade

Dado que la simulación digital es una herramienta auxilar para los ingenieros de procesos -en tanto evalúa la factibilidad de un flowsheet propuesto y predice el efecto de una modificación para un flowsheet existente, su importancia también se extiende también a la evaluación de alternativas para las estrategias de control en los circuitos de la planta. En ese sentido, el presente trabajo señala los beneficios económicos y técnicos obtenidos en la planta San Rafael mediante el empleo de simuladores en los circuitos de molienda, chancado y concentración gravimétrica, los cuales permiten corroborar los cambios efectuados u optimizar los circuitos señalados de forma simple y rápida.

Sep 9, 2007

By A. M. Gaudin

The recent study by R. M. Hays(l) prompted the study summarized in this paper. In his Interesting paper, Mr. Hays shows fine results to be attainable by a relatively complex flowsheet on a semi-taconite, a manifestly difficult ore to treat. We obtained a semi -taconite from Minnesota, and treated this sample by wet magnetic separation alone. The device in which the separation was accomplished is the standard pilot-plant, laboratory separator in use at Magnetic Engineering Associates' laboratory (MEA) in Cambridge, Massachusetts. It consists of a cylindrical space which can be magnetized by turning on the magnet of the separator. In this cylindrical space, there is a canister which provides the special configuration of the magnetic field and magnetic field gradients that MEA considers to be required. The ore pulp is made to flow through the canister while the current is on. A portion of the pulp is retained in the canister, and the rest is evolved as a non-magnetic fraction. The laboratory device is cyclic, but it accurately predicts the results obtainable by an Industrial unit of either cyclic or continuous type (moving matrix). The ore tested was 99.5°%o -325 mesh, and approximately 75% -500 mesh. The concentrate from this ore was, therefore, eminently suitable for pelletizing. In passing the ore through the magnet, we had the choice of repeatedly passing the concentrate from the first step through the operation, or of repeatedly passing the non-magnetics. In our experiments, the first method was clearly superior from the stand¬point of the cleanliness of concentrate. Of the many tests which we have made, we think that we have to retain two which

Jan 1, 1971

By Samuel M. Brock

Problems related to strip and auger coal mining have grown with the development of the industry and the economy. New technology has produced equipment that has made mining by surface methods not only highly productive, but potentially highly destructive of water resources and natural environments. On the other hand, growth of the economy has produced an increased demand for clean water, and created new demands for amenity values that natural environments provide. Thus, opposing forces have created conflicts in resource use. And these conflicts have made surface mining highly controversial. Resolving the controversy will require the solving of complex economic and social problems. The essence of the economic problem created by surface mining is that, in the absence of proper regulation, substantial costs resulting from the process are borne by the public rather than the mine operator.

Jan 1, 1968