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By Merete Tangstad, Fei Li

This paper studies the quartz and carbon black pellets at elevated temperature with varying temperature and gas atmosphere. High-purity quartz and commercial ultra-pure carbon black was mixed (carbon content wt.15%), and then pelletized into particles of 1-3mm in diameter. The stoichiometric analysis of the pellet during heating is studied in thermogravimetric analysis (TGA) furnace at different temperature in CO and Ar atmosphere. The microstructure, phase changes and element content of sample before/after heating is characterized by X-ray diffraction, scanning electron microscope, X-ray fluorescence and LECO analyzer. The reaction process can be divided into two stages. Higher temperature and argon atmosphere are the positive parameters for SiC formation.

Jan 1, 2016

By G. Labonte

The behavior of four different redox sensing electrodes (gold spiral, black platinum, chalcopyrite, and galena) during roughing and cleaning flotation is examined and related to the flotation response. Although it is difficult to provide unequivocal interpretations of the different potentials measured, the results indicate that the solution potential (as sensed by the black platinum electrode) is different from that of the pulp potential (gold spiral) and is only weakly related to the flotation response. On the other hand, the potentials exhibited by the gold spiral and the two mineral electrodes are related to the floatation response. The gold and mineral electrodes exhibit different transcient responses during the addition of flotation modifiers (e.g. NaCN, SO2). These responses appear to be related to the reactivity of the minerals and could indicate the conditioning time required to achieve flotation or depression of selected minerals.

Jan 1, 1989

By Giacobbe Braccio, Alessandro Blasi, Assunta Romanelli, Massimo Morgana, Corradino Sposato

The solvent extraction technique is the only industrial way used to separate and purificate yttrium from other rare earths. In order to improve this process several extractants have been tested during last years. In this work, the behavior of sec-octylphenoxy acetic acid (CA-12) in Yttrium recovery from high concentrated heavy rare earth mixture was investigated. Sodium hydroxide solution was used in order to presaponify organic phase composed by CA-12 and Tributyl phosphate (TBP) diluted in kerosene. In the investigated condition, TBP confirmed its role of phase modifier not significantly altering the extraction behavior of CA-12. The CA-12-TBP system showed a high affinity in extraction for lighter rare earths such as Sm, Eu, and Gd, leaving yttrium in aqueous phase. Using a feed concentration (P [RE]) of 1 M, organic mixture is capable to extract around the 70% of metals in a single extraction test showing this extraction sequence Y < Lu < Yb < Tm < Er < Ho < Dy < Tb < Gd < Eu < Sm. Moreover for [CA-12] = 1.79 M and [RE] = 2 M the instability of extraction system occurs.

Mar 1, 2017

By Marwa Nabil, Alaa A. Ata

"Recent developments in the analysis of piled rafts has incorporated the load sharing of the raft and the piles to support the superstructure. In the piled-raft system, piles are cast monolithically with the raft and the load is partly transmitted by the raft to the soil directly below it, and partly by the piles to more competent deep soil. While these piles are effective in increasing the bearing capacity and reducing the settlements, they often lead to significant straining actions at the pile head-raft connection which may constitute the weakest link. An attempt to provide a more economical solution, that at the same time overcomes this weak link, is to disconnect the pile heads from the raft and introduce an intermediate cushion of compacted fill. In this case, the piles are considered as reinforcement to the subsoil and will also act as settlement reducers. This paper investigates the load transfers mechanism of the unconnected piled raft with cushion using ABAQUS finite elements Program. The main objective is to provide an in depth analysis of the raft–soil–pile interactions in multi-layered soil under static and seismic loads. The investigated system provides an economical alternative for traditional connected piled raft foundation, where there is no need to reinforce the piles, no need for pile head demolition or expensive waterproofing of the pile head connection. Cost analyses of unconnected versus connected piled raft systems confirmed a cost savings in the construction that may reach from 50 to 70 percent.INTRODUCTIONDesigners around the world have gained more confidence to use the piled-raft as a more realistic system where the raft and the piles share transferring the superstructure loads to shallow and deep soil layers. A further advancement is to use unconnected piled rafts as another practical and economical alternative to the traditional piled rafts. Unconnected piled raft is also synonymous to settlement reducing piles; or simply, soil improvement piles. Liang et al. (2003) has extended the concept of pile-raft-foundation to a new type of foundation called composite piled raft foundation or unconnected piled raft foundation. The foundation is composed of a sand/gravel cushion sandwiched between the raft and piles. The piles group may contain short and long piles. The short piles are constructed of flexible materials such as soil-cement columns or sand-gravel columns, and are used mainly to improve the bearing capacity of shallow soft soil; the long piles, which are made of relatively rigid materials such as concrete, and their main function is to reduce settlements. The cushion plays an important role in mobilizing the bearing capacity of the subsoil and in modifying the load transfer mechanism of the piles. In Shanghai, China, this system of unconnected piled raft has proved to be quite suitable and effective in coastal areas, where deep soft soil deposits exist."

Jan 1, 2016

By Takao Yasugi

The majority of copper in the raw material migrates to the de-copperized dross that forms when the crude lead produced in the blast furnace is treated in the de-copperizing process. The de-copperized dross is treated in the electric furnace producing matte, speiss, and crude lead. The de-copperized dross also contains the silver. Therefore, it is important to improve the rate of silver migration to the crude lead. For this reason, the behavior of silver between the matte, speiss and crude lead phases was examined. At the same time, several tests to improve the percentage of silver migrating to crude lead were conducted.

Jan 1, 2003

By Nabil F. Ismael

The axial capacity of step tapered bored piles in sand was examined by field tests at one site in Kuwait. Two straight piles, and two step tapered piles were load tested in compression to failure. All four piles were 3 m deep. The straight piles were 0.2 m in diameter. The step tapered piles had a diameter of 0.3 m for the upper segment which extended up to 40% of the pile length changing to 0.2 m diameter for the lower section. The soil profile consists of medium to dense sand with minor cementation and no groundwater was encountered. Both the ultimate bearing capacity and the settlement at working loads were examined. The axial capacity of the step tapered piles was greater, and the settlement at working loads was less, compared with the straight shaft piles. The increase in capacity is mainly attributed to the added side friction along the larger diameter top segment of the shaft.

Jan 1, 2008

By Thomas Havlik

It is proposed to realise the direct leaching, during which will be generated elemental sulfur and not sulfate or sulfuric acid as end product, under conditions that sulfur will not cover the leaching surface and Hot hinder the leaching course. The following improvements have been considered: -use of organic sulfur solvents -ultra high-frequency leaching -ultrasonic leaching -use of surface detergents or surfactants in leaching processes -simultaneously crushing and leaching These proposals are under investigation and preliminary results are promising

Jan 1, 1996

By Murali M. Gadde

Welded wire mesh is the most commonly used skin control technique in the United States underground coal mines. Currently, selection of the mesh is based on trial and error rather than any rigorous design methodology. Several factors affect a wire mesh?s performance including the amount of rock material to be supported and how the load is distributed, wire gauge, aperture size, grade of steel, weld strength, bolting pattern and sheet size. Although the best way to choose the mesh is to conduct full-scale physical load tests, because of the limitations on the number of variables that can be considered in such tests and the requirement of an elaborate test set-up, it may not always be possible to use this option. An alternative would be to use numerical modeling to study the load-deformation behavior of a wire mesh. In addition to providing a very detailed stress, strain distribution in the entire mesh, the advantage of this approach is the ease with which parametric studies can be conducted. In this paper it is shown that the load-deformation curves generated by nonlinear numerical models match closely with laboratory derived ones. Then, based on parametric studies, design guidelines are developed to choose the mesh appropriate for different loading conditions. The modeling studies also bring forth the limitations of the current lab studies. For example, under some conditions it was noticed that the small sheet size considered in lab tests would produce higher mesh deformations than a full-size one used in actual practice.

Jan 1, 2006

By T. Damyanov

Spherical grinding media (balls) are the most widely used media for comminution of ores by grinding. A modelling simulation study of the behavior of two grinding media in the grinding process was conducted to determine the possible advantages of the new shape milling bodies called tetraballpebs. Tetraballpebs are in the shape of tetrahedrons with spherical convex walls. A three dimensional CAD model of the mill drum with a diameter of 1200 mm was used. A continuous operating mode was simulated in terms of the 3D contact elements of the model (milling bodies and mill drum). Simulation tests were carried out in a typical grinding mode and at a typical rotational speed of the drum mill (75 per cent of the critical speed in cataracting mode). Studies carried out with both grinding media include equal number of milling bodies with the same weight and volume. Having thus ensured a uniform mass of the grinding media and same number of milling bodies, and constant other conditions and process parameters, conclusions can be drawn about the influence of the shape of the milling bodies on the grinding process. A kinematic analysis of the system using CAE (computer-aided engineering) model parameterization was conducted. The controlled parameters are: ? Power draw; ? Kinetic energy of each milling body; ? Motion of milling bodies inside the drum Keywords: grinding, grinding simulation, balls, tetraballpebs, DEM, CAD-CAE

Sep 1, 2012

By Yong Zhao, Yan-hui Sun

Behaviors and evolutions of MgO·Al2O3 in non-oriented silicon steel during calcium treatment were investigated by thermodynamic calculations and high-temperature experiments. MgO·Al2O3 inclusions were the main type of inclusions before calcium treatment, which is also confirmed by the stability diagram of MgO/MgO·Al2O3/Al2O3 from thermodynamic calculations. After calcium treatment, the majority of original MgO·Al2O3 inclusions were mainly modified to CaO-MgO-Al2O3 system inclusions, this would be beneficial to improve castability and product quality of silicon steel. But there was no modification happening to some MgO·Al2O3 spinels which were directly surrounded by CaS inclusions. The content of Al2O3 occasionally existed a sudden increase besides a common decrease in the product layer of CaO·MgO·Al2O3. Then the evolution mechanisms of MgO·Al2O3 inclusions were proposed in present work. Thus, Al/Mg atom ratio had a significant influence on the modification of MgO·Al2O3 spinel.

Jan 1, 2016

Behaviour of Bubble Clusters in a Turbulent Flow

Sep 13, 2010

By G. M. Evans, S. Mitra, G. J. Jameson, M. M. Hoque, E. Doroodchi, R. Moreno-Atanasio

In this study, the detachment behaviour of 314 μm diameter silica particles from a single 3 mm diameter bubble rotating in a confined cavity connected to a cross-flowing water channel was investigated. The liquid cross-flow generated a rotating flow inside the confined cavity, which was quantified using 2D particle image velocimetry (PIV) measurements. The fluctuating (x-y) velocity components inside the cavity for each cross-flow velocity, U, were then used to estimate the corresponding time/volume average turbulence intensity values, Ti. Turbulence intensity ranged from 9.3-16.2%. In the absence of a bubble, the rotating vortex within the cavity created a pressure field which decreased towards the centre of the vortex; wherein the lowest pressure zone was located at the centre of the cavity. The vorticity into the cavity was found to increase with increasing the turbulence intensity. A bubble, both without and with particles attached, was introduced into the cavity under different flow conditions and its motion was tracked using the shadowgraphy technique. Experimentally, it was found that the bubble-particle aggregate was trapped at the centre of the cavity (low-pressure region) following a spiral trajectory. An interface resolved 3D computational fluid dynamics (CFD) model was developed to predict the particle detachment conditions within the confined cavity. CFDpredicted vorticity in the absence of a bubble agreed well with experimental observation. The CFD analysis indicated that the vorticity inside the cavity was not significantly changed when a single bubble was introduced. On this basis, the computed vorticity was utilised in describing the force balance applied to the attached particle. Computationally, it was found that the critical turbulence intensity, beyond which the particle was detached from the bubble, was 14%. This value was consistent with the experimental observation of detachment at Ti at 15.7%, and above, but not at lower values. Keywords: Bubble, particle, turbulence intensity, vorticity, particle detachment, CFD, PIV

Jan 1, 2020

By G. Akdogan, S. M. Bradshaw, M. I. Isaacs, P. Van Wyk

In the mineral processing industry, Ni-Cu-Fe-S converter matte is leached in order to remove base metals from a concentrate containing platinum group metals (PGMs). This paper investigates the atmospheric leaching process, in order to develop a better understanding of the leaching behaviour of the base metals; in particular Cu, Fe, Ni, and the PGMs in particular Ru and Ir with key process variables, acid concentration, copper concentration under oxidative leaching conditions. Higher initial acid concentration resulted in a higher copper, iron and nickel extractions, as well as higher leaching rates together with faster Cu, Ru, Ir precipitation occurring. On the other hand, a higher initial copper concentration resulted in more nickel but less iron being extracted. Keywords: PGM, converter matte, leaching, precipitation

Jan 1, 2020

By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk

In the mineral processing industry, Ni-Cu-Fe-S converter matte is leached to remove base metals from a concentrate containing platinum group metals (PGMs). We investigated the atmospheric leaching process to develop a better understanding of the leaching behaviour of the base metals (Cu, Fe, and Ni) and the PGMs, in particular Ru, Ir, and Rh with respect to key process variables, acid concentration, and Cu concentration under oxidative and non-oxidative conditions. With oxidative leaching, a higher initial acid concentration resulted in higher Cu, Ni, and Fe extractions, as well as faster leaching reaction rates. A higher initial acid concentration also resulted in faster precipitation of Cu, Ru, and Ir under oxidizing conditions. Under non-oxidative conditions, Ni and Fe extraction was much slower, and the effect of initial acid concentration on Cu precipitation was less pronounced. The initial Cu concentration had a slightly smaller effect on the leaching behaviour of Fe and Ni, as well as precipitation of Ru, Ir and Rh. Moreover, a higher initial Cu concentration suppressed both Ni and Fe leaching and had a slight inhibiting effect on the precipitation behaviour of Cu, Ru, and Ir.

Nov 1, 2021

By B. Haugrud, E. McConaghy, M. Collins, G. Smith

"Laterite ore processed by the Ambatovy joint venture in Madagascar is primarily limonitic in nature, containing approximately 40–45 wt.% Fe and 1.1 wt.% Ni. The process selected for treatment of this ore considered the behaviour and deportment of iron in each step of the commercial flowsheet. Such considerations included nickel and cobalt recoveries, reagent consumptions, liquid-solid separation characteristics, and intermediate and final product purities. In this paper, the results for the first three years of commercial operation at Ambatovy are compared with the design parameters, with emphasis on the behaviour of iron.RÉSUMÉ Le minerai latéritique traité par l’entreprise commune Ambatovy au Madagascar contient principalement de la limonite, composée de 40–45 % en poids (wt%) de fer (Fe) et de 1,1 wt% de nickel (Ni). Le procédé choisi pour le traitement de ce minerai tenait compte du comportement et du maintien du fer à chaque étape du schéma de traitement commercial. Parmi les facteurs pris en compte figuraient les récupérations de nickel et de cobalt, les consommations d’agents réactifs, les caractéristiques de séparation des liquides-solides ainsi que la pureté des produits semi-fini et final. Cet article compare les résultats des trois premières années d’exploitation commerciale à Ambatovy aux paramètres d’étude, en insistant notamment sur le comportement du fer.INTRODUCTIONThe main component of nickeliferous laterite ore is iron, and the Ambatovy deposit in Madagascar is no exception. Ambatovy ore is primarily limonitic in nature, containing approximately 40–45 wt.% Fe and 1.1 wt.% Ni. The nickel content of the ore is approximately 1/40th that of the iron content by weight; therefore, successful recovery of nickel depends on close control of the behaviour of iron in the selected process.The Ambatovy area is located 80 km east of Antananarivo, the capital of Madagascar. Exploration dates back to 1960, when the Malagasy Service Géologique carried out a limited pitting and auger-drilling program. Phelps Dodge Corporation (now Freeport-McMoRan Copper & Gold, Inc.) was granted the mining rights to the property in 1995 and carried out significant resource definition, environmental assessment, and engineering studies between 1995 and 2001 (Chou, Rooke, Williams, & Hanks, 2000). In 2003, Dynatec Corporation, which was formed in 1997 by the merger of Dynatec International Ltd. and Sherritt International Consultants Inc., signed a joint venture agreement with subsidiaries of Phelps Dodge to evaluate the Ambatovy nickel project. Dynatec became extensively involved in the development of the project, including process selection and pilot plant testing in Fort Saskatchewan, Alberta (Collins et al., 2004, 2005; Collins & Vardill, 2005; Collins, Buban, Holloway, Masters, & Raudsepp, 2009). Dynatec acquired 100% of the project in 2005 and a joint venture between Dynatec, Sumitomo Corporation, Korea Resources Corporation (KORES), and SNC-Lavalin Inc. (SLI) was formed shortly thereafter to provide funding for further development. SLI was responsible for engineering, procurement, and construction management of the commercial facilities. Sherritt International Corporation reacquired Dynatec Corporation, including 40% ownership in the Ambatovy nickel project, in 2007. The current Ambatovy joint venture consists of an integrated nickel and cobalt mining, processing, refining, and marketing enterprise between subsidiaries of Sherritt (40% owner and mine and plant operator), Sumitomo Corporation (32.5% owner), and KORES (27.5% owner)."

Jan 1, 2017

By C. Allen

In 2004, Boliden Odda underwent an extensive modernisation project targeting mainly the leaching section of the plant. Direct leach technology was introduced as part of this project. The Direct Leach process, developed by Outokumpu, is an atmospheric oxidative leach of zinc sulphide concentrate. The effects of this new processing operation on behaviour of iron in the plant are discussed. As well, the filterability of the new residue on belt filters prior to its deposition in mountain caverns is also discussed. The solids from the direct leach process have been analysed by scanning electron microscopy, and the results of these analyses are presented.

Jan 1, 2006

By O A. Aladejebi, S Mitra, T Singh, D J. Pinson, S, S J. Chew, T Honey

Currently, many commercial sinter plants are exploring the potential addition of high-grade iron ore concentrates to improve the sinter grade. A better understanding of the ore blend, granule behaviour and green bed properties is critical to making this change and maintaining productivity in the sinter plant. This study compared the performance of a laboratory scale granulation drum to a commercial scale unit. The blend used was an Asia-Pacific style sinter blend containing iron ore concentrates. The operating conditions of the two granulation drums (laboratory and commercial scale) were fixed at the same Froude Number (0.00337), space factor (15 per cent) and residence time (4.5 mins). The granules were characterised by measuring their mean size, size distribution and green bed voidage. It was found that the laboratory scale granules were representative of commercial sinter plant granules at similar moisture content. When the moisture was fixed at ~6.9 per cent, granulation time had no significant effect. A further fundamental investigation was undertaken to measure the water holding capacity and intra-particle porosity of the individual ores used in this study. The kinetics of water absorption were measured which showed that water absorbs quickly into the ore particles within the first 60 seconds, slowing down until final saturation was attained after six hours. A linear relationship between the water holding capacity and intra-particle porosity was noted for different ore particle sizes. The results of this study provide a baseline understanding of the current commercial sinter blend and encourage exploring the specific effect of increasing the proportion of ultrafine concentrates in sintering in a future study.

Sep 18, 2023

By X. H. Zhang, J. G. Cai

This paper discusses the behaviour of large-span tunnels and caverns in hard rock in a major underground storage project. In-situ stresses were measured using hydraulic fracturing during site investigation and 3-D overcoring during construction, with both showing a horizontal stress ratio of 2-3 times the vertical stress. Rock reinforcement design was based on the Q-system combined with numerical modelling for special design cases. Tunnel design and performance were checked and monitored by in-situ instrumentation during rock excavation, including measurements of deformation, convergence, and load on rock bolts. Deformation measurements using borehole extensometers included one borehole drilled into the virgin rock before rock excavation, which provided a direct and very insightful comparison with the various deformation measurements made during rock excavation. These measurements coupled with numerical calculations have proven that the high horizontal stresses to be very favourable to the stability of the large openings.

Jan 1, 2003

By M. R. MacIver, M. Pawlik, S. Finora, H. Alizadeh

The dispersion of mature fine oil sands tailings (MFT) by the addition of sodium lignosulfonate was studied using contact angle measurements, optical scattering, and particle size measurements. Lignosulfonate caused the release of residual bitumen to the slurry surface and settlement of fines. Dynamic contact angle by captive bubble measurements were carried out on bitumen to determine the effect of the dispersant on the wettability of bitumen. Lignosulfonate caused a change in the aggregation state of the MFT and increased sedimentation of particles, as indicated by optical scattering measurements. Zeta potential measurements indicate that this change was caused by an increase in adsorption of lignosulfonate onto particles, which caused improved settling of the colloid. Ultraviolet Visible (UV) spectrophotometry and organic carbon content measurements showed that only a small amount of the reagent remains in the aqueous phase of the tailings, which is critical for decontamination of recycled water. Keywords: Oil sands tailings, bitumen recovery, dewatering, dispersion, surface chemistry

Jan 1, 2020

By B. M. England, L. C. Mackey

Magnesia minerals are included in most iron ore sinter mixes to provide the MgO requirements of blast furnace slag. The properties of these minerals have an influence on the eventual sintering properties of the mixes. A detailed study was undertaken of serpentine and dolomite and the use of limestone, olivine and magnesite was also investigated. A consideration of particle properties indicated that as these materials calcine a reduction in size can occur together with cracking and changes in surface properties. These changes could affect the permeability of the sintering bed and sintering performance. Studies of sintering reactions showed that magnesium and calcium, formed from the calcination of dolomite, are extremely mobile before the formation of melt. Evidence suggests that the movement of these oxides into surrounding areas is via a solid-state diffusion process. The diffusion of Ca into the surrounding hematite particles is faster than that of Mg, resulting in the formation of dicalcium ferrite and magnetite or magnesioferrite, the last two subsequently being converted to dicalcium ferrite in the presence of Ca with removal of Mg from the structure as ferroan periclase. Studies of pilot-plant sinters indicated that reaction mechanisms formulated from the bench-scale studies were occurring in actual sintering processes. The differences in sintering reactions between dolomite and serpentine were considered to be the major cause of differences in the availability of lime for bonding phase formation. Pilot-scale studies indicated that the sintering properties of a mix containing dolomite could be improved by increasing the basicity of the sinter mix while keeping the MgO level constant

Jun 18, 1905