Search Documents

By D. G. Collins

As part of its effort to develop ways to maximize resource recovery, the Bureau of Mines investigated the extraction of vanadium from Western phosphate beneficiation tailings with H2S04 and/or H3P04. Dissolution of the vanadium was accomplished by digesting a mixture of acid and a 50-pet-solids, tailings-water slurry. In the most effective method investigated, vanadium and phosphorus were leached by digesting the slurry at a constant boiling temperature (1000-1100 C) in a stirred reactor. In batch tests, maximum vanadium dissolution was 95 pet. In continuous-circuit tests designed to further evaluate vanadium dissolution at con-stant boiling temperature in a continuously stirred reactor, vanadium dissolution ranged from 70 to 85 pet. An economic evaluation of the process demonstrated that H2S04 consumption is the major cost factor. Based on the value of the vanadium product with no allowance for a phos-phate product, the cost of producing the V205 is more than twice its value. The potential for profit would depend upon the value of the phosphate fertilizer produced from the impure H3P04 remaining after vanadium extraction.

Jan 1, 1985

By B. J. Scheiner

As part of the goal to maximize minerals and metals recovery from primary domestic resources, design factors associated with minimizing current leakage in bipolar cell configurations were studied by the Bureau of Mines as a means of improving the efficiency of bipolar e1ectrooxidation cells. Initial studies that were conducted in a small bipolar cell operating at 140 to 145 volts and 15.4 amp indicated how design factors could be employed to minimize cur-rent leakage around adjacent electrodes during cell operation. Based on these results, a 40-electrode, 108-kva prototype of an industrial-sized cell was constructed and tested for extracting metal values from offgrade molybdenite concentrates. The feasibility of recovering molybdenum and rhenium from the oxidized pulp also was determined. Feed to the process sequence consisted of flotation concentrates containing 16 to 35 pet Mo as molybdenite and 6 to 15 pct Cu. E1ectrooxidation in the prototype cell resulted in 84 to 97 pct Mo and Re extraction with a corresponding energy consumption of 9 to 13 kwhr/1b Mo extracted.

Jan 1, 1979

By S. Benedict Levin

In the spring of 1944, during the emergency In the supply of strategic mica, the Bureau core-drilled six aggregating 913 feet, at the Blister mica Trim. Cheshire County, N.H. These holes indicated a downward extension or the mica shoot which was being mined at that time and developed information essential for economic mining of the deposit.

Jan 1, 1949

By J. K. Whyatt

The Bureau of Mines, under a cooperative agreement with Callahan Mining Corp., measured rock displacement at the 4,7S0-ft level of the 5,100-ft-deep rectangular, timbered Caladay Shaft in northern Idaho. Displacements were measured with multiple-position borehole exten-someters (MPBX) installed 4 ft above the face and timber extensometers (TE) installed with the timber sets. This report presents the displacement data along with preliminary, qualitative observations of rock behavior. The measured displacements showed an instantaneous response to shaft sinking and significant time dependency. The relative magnitudes of displacement measured at the shaft walls were heavily influenced by local geologic structure and distance from the shaft bottom.

Jan 1, 1987

By JOEL H. SWARTZ

During a series of resistivity measurements carried out in 1929 and 1930 a number of questions arose concerning the effect of topography on the character of the curves and the depths attained , the ratio of true depth to certain radii interpreted as representing depth , etc. To answer these questions it was decided to undertake a series of experimental investigations on artificial strata . It is the purpose of the present paper to present the results of the studies thus undertaken .

Feb 1, 1931

By John W. Buch

Safety and cost in mining coal beds under the extreme pressures found at depth, full extraction to conserve resources, and even surface subsidence to minimize damage of improved areas have directed much well-deserved attention, in the United Kingdom; to roof-control methods. Because the effects of pressure will be felt intensely as our Pennsylvania anthracite mines grow deeper, the senior author took advantage of an opportunity afforded by a mission to Europe3/ to observe, to a limited extent, the effects of pressures found in deep mines and the manner in which they are con trolled. Organized research relating to strata control has been carried on in Great Britain for nearly 25 years. These activities have been ably outlined by Dr. D. W. Phillips.4/ Physical properties of coal-measure rocks, movements of roof and floor, and types of face and roadway supports have been investigated. Same of the forces induced by the extraction of coal have been measured. The results of this research have been publicized and openly discussed, and much progress has been made in establishing a better factual understanding of roof-control problems and their solution.

Jan 1, 1951

By R. C. Annear

This report describes open, sublevel, and shrinkage stoping at the Greenwood mine, operated by Inland Steel-Co. The iron ore mine is in Marquette County, Mich., about 6 miles southwest of Ishpeming (fig. 1). The Greenwood is one of three active underground hard-ore mines on the Marquette range, the others being the Cliffs-Shaft and the Champion mines. The operation reflects an achievement in exploiting small, difficult-to-mine hard-ore bodies lying beneath a 200-foot overburden of glacial drift, which is partly water bearing. This report can indicate only briefly the efforts of personnel in overcoming adverse conditions in mining more than 2 million tons of ore, 80 percent of which was in lump form, for open-hearth production of steel. Significant data presented include descriptions of the principal mining methods employed, sublevel and shrinkage stoping; percent aged mining costs for the entire year 1957, covering both direct mining costs and general expenses; and performance records in units of labor, power, and supplies.

Jan 1, 1960

By F. P. Haver

The purpose of this investigation was to determine the effect of common impurities, that is, oxygen, nitrogen, carbon, and iron, on the Brinell hardness of electrolytic titanium. On a weight basis, nitrogen had the greatest hardening effect, followed by oxygen, carbon, and iron in order. The hardening effects of oxygen and carbon were almost identical up to a concentration of approximately 0.1 percent by weight. Above this concentration, the relative hardening effect of carbon decreased rapidly, possibly because of its limited solid solubility in a-titanium. Hardness vs. composition curves for both oxygen and nitrogen were essentially straight lines over the range of Brinell hardness numbers (B.h.n.) covered in the investigation. The hardness of titanium was also determined as a function of the percentage of impurity atoms. On this basis, iron in concentrations up to 0.17 atomic percent had a greater hardening effect than either oxygen or carbon. INTRODUCTION Determination of the as-cast hardness of arc-melted titanium is a method of quality control widely used in industry. Numerous studies4/ have been made of the effect of impurities on the hardness obtained by this method. However, most of them have been based on the use of either iodide titanium or commercially pure Kroll sponge (B.h.n. >90), as a starting material.

Jan 1, 1959

By G. E. McElroy, D. Harrington

In connection with the cooperative metal-mine dust and ventilation investigations of the U. S. Bureau of Mines and the U. S. Public Health Service , some underground data have been obtained with intent to ascertain the adaptability of the katathermometer for determining the comfort of working places in mines . This preliminary study indicates that the instrument will probably be useful for making routine determinations of comfort conditions in our mines , and that it may also prove an important accessory for investigative work on problems in ventilation and kindred subjects ; in both coal and metal mines , although the instrument should probably be altered somewhat for maximum utility under the varied conditions in the mines of the United States . The katathermometer is an instrument contrived by Dr. Leonard Hill , an eminent English physiologist , and its various features have been fully described by him in his book entitled " The Science of Ventilation and Open Air Treatment . " He made exhaustive experiments and concluded that the rate of cooling of the human body was the controlling factor in determining comfort or discomfort , and then set out to make an instrument that would measure this rate of cooling . The resulting instrument the katathermometer measures its own rate of cooling when its temperature approximates that of the human body and thus serves as an index of the rate of cooling of the body itself . - The instrument consists of an alcohol thermometer having a cylindrical bulb 1 inches long and 3/4 inches in diameter, and a stem about 8 inches long graduated from 95 to 100° F. This temperature range gives a mean temperature of 97.5° F. ( 36.5° C. ) , which is approximately that of the clothed body surface . The stem terminates in a small reservoir which serves the double purpose of acting as a safety overflow in case of overheating the bulb , and of insuring a regular rate of cooling by the time the meniscus has fallen to the 1000 point .

May 1, 1922

By M. O. Serbousek

The load-transfer mechanics of fully grouted roof bolts in coal mines have been investigated in laboratory and analytical studies. The purpose of this Bureau of Mines research is to increase understanding and better interpret data from routine field pull tests and to develop a numerical model of a grouted bolt that can be used in a global computer model of a mine roof. Analytical studies using closed-form solutions and finite-element techniques were compared to experimental results. Laboratory work includes variation of bolt length, hole diameter, and grouL type. Pull tests were pel'fol·med on 4-, 2-, and I-ft bolts in holes of 1-and I-3IB-in diameters. Both polyester resin and inorganic grouts were used as the anchorage medium. Strain gauges were installed on the bolts at several locations to observe the rate of load transfer from the bolt through the grout to the rock mass when a force was applied at the bolt end using standard jack pull testing procedures and equipment. The average anchorage length of 4-and 2-ft bolts was 22 in. Grout type and hole size variations did not produce a significant effect on the rate of load transfer from the bolt to the rock.

Jan 1, 1987

By D. R. Babich, E. R. Bauer

The U.S. National Institute for Occupational Safety and Health (NIOSH) is conducting a cross-sectional survey of equipment sound levels and worker noise exposures in the stone/aggregate mining industry. Six stone/aggregate mines (three surface and three underground) were recently surveyed, and the findings (ire presented here. The surveys consisted of sound-level measurements conducted around various equipment and machinery (including stone processing and crushing equipment) and full-shift dose measurements to determine worker noise exposures. The findings identify the equipment and machinery that are likely to cause worker overexposures and identify the workers found to he experiencing overexposures. In addition, the benefit of cabs in reducing mobile equipment operator noise exposure is discussed.

By L. E. Geyer

"The following list gives the title and author of various publications of the Ceramic Experiment Station, Columbus. Ohio, of the Bureau of mines, together with other ceramic publications of the bureau, which have been published in technical journals and by cooperating agencies. The list also includes the publications on ceramics which have been issued as bulletins, technical papers, or mimeograph Report of Investigations of the bureau.Papers Published in the Technical Press.The Effect of some Electrolytes on the Properties of Clays. Schurecht, H.G. Jour. Am. Cer. Soc., Vol. 1, #3, March, 1918.A Pycnometer Operated as a Volumeter. Schurecht, H.G. Jour. Am. Cer. Soc.,Vol. 1, #8, August, 1918.The Properties of some Ohio and Pennsylvania Stoneware Clays. Schurecht,H.G. Jour. Am. Cer. Soc., Vol. 1, #4, April, 1918.The Fusibility of Graphite Ash and its Influence on the Refractoriness of Bond Clay. Booze, M.C. Jour. Am. Cer. Soc., Vol. 2, #1. Jan., 1919.Behavior under Brass Foundry practice of Crucibles containing Ceylon, Canadian and Alabama Graphites. Stull, R.T. Jour. Am. Cer. Soc., Vol. 2, #3. March, 1919."

Oct 1, 1924

By C. R. Stephan, N. B. Greninger, J. R. Lipscomb

The U.S. Bureau of Mines and the U.S. Mine Safety and Health Administration (MSHA) are participating jointly in a research program to evaluate the strength characteristics and air-leakage resistance of various proposed seal designs for use in underground coal mines. The full-scale seals were constructed in the USBM's experimental mine at the Lake Lynn Laboratory, air-leakage tested, then subjected to pressure pulses of 20 psig or greater. bjected to pressure pulses of 20 psig or greater. In experiments prior to this study, seven seal designs using solid-concrete blocks were tested. Only the standard-type seal passed the explosion and air-leakage criteria. Tests also were performed on four seals constructed with low-density foam blocks. All four of these seal designs withstood the pressure pulse. In more recent studies, nine cementitious foam seal designs of varying thicknesses and densities were investigated. Six of the nine designs successfully survived the explosion overpressures. Six wood- block convergence seals also have been tested. The typical 3-ft-thick, wood-block seal design currently used in many coal mines did not maintain its integrity, in the absence of convergence forces, following the explosion test. Five modified wood-block seals successfully withstood the 20-psig pressure pulse. Based on these tests, three alternative seal construction materials, cementitious foam, low-density foam block, and wood, have been approved by MSHA for use in underground coal mines.

Jan 1, 1993

By D. E. Hirsch

The Bureau of Mines has developed a systematic procedure for separation, characterization, and semiquantitative analysis of high-boiling (350° to 550° C) distillates of crude oils. Isothermal and molecular distillation were used to prepare the 370° to 530° C distillate of Recluse, Wyo., crude oil. The distillate was separated into fractions by chemical treatment, silica-alumina gel adsorption, and gel permeation chromatography (GPC). The fractions were analyzed by use of GPC correlations and mass and nuclear magnetic resonance (NMR) spectrometry. The increased knowledge of petroleum composition obtained from the data will contribute to improved petroleum processing and utilization and energy conservation.

Jan 1, 1974

By I. D. Shah

The copper-nickel ore of the Duluth Gabbro Complex in northeastern Minnesota is a large potential domestic resource of cobalt and platinum-group metals. However, because of the low grade of the primary metal values (0.5 pct Cu, 0.15 pct Ni), the private sector has assigned a relatively low priority to the development of technology for processing this ore, anticipating that mining probably would not begin until the mid-1990's. Furthermore, preliminary processing flowsheets considered by the mining companies centered on the primary metal values. As part of an effort to help provide the basis for technology to recover critical and strategic minerals from domestic resources the Bureau of Mines is investigating methods to recover all of the mineral values, in the Duluth Gabbro material, with particular attention to the byproduct critical minerals. A key step in this process is the removal of a relatively large amount of iron present in the bulk sulfide flotation concentrate to permit subsequent extraction of mineral values. This report describes a direct smelting method that removes most of the iron and produces a copper-nickel-cobalt matte, an intermediate product from which the metal values subsequently are separated. Copper, nickel, and cobalt grade and recovery data are presented for the direct smelting method. Test results showed that under certain conditions some of the mineral values reported to the slag, requiring slag cleaning to recover them.

Jan 1, 1983

By G. E. McElroy

"while investigating the presence of heavy strata gases* in certain mines of the East Tintic mining district of Utah, a small, local body of light, very hot gas of high-nitrogen composition was noted in one of the mines. Observations and analyses indicate that this light gas was resulting from very rapid oxidation of finely disseminated pyrite, in lead-silver sulphide ore. The gas was actually mine air which had lost a large proportion of its oxygen content by reaction with the pyrite. This body of gas was hanging in a local high spot about 5 by 5 by 5 feet in size, caused by caving, at the end of a crosscut. Fifty feet from this spot, an air current of 6000 cubic feet per minute was entering the 5 by 7 foot cross-cat from a raise from below.On account of the vapor contained in the gas, the bottom level of the gas could be plainly seen and was practically a horizontal plane, but of slightly wavy appearance, coinciding with the point where an acetylene light was extinguished. This body of gas was visited on three occasions and samples obtained by means of evacaated bulbs and by water displacement. The temperature of the gas was ap¬proximately 175 degrees P. on all three occasions, so that sampling required thick gloves and quick action. Air three feet below the vapor line had a temperature of only 120 degrees F., and a relative humidity of 27 per cent. The stratification of the air and gas mixtures was so sharply defined that the sampler could hold his head a few inches below the vapor level for an appreciable period of time without any noticeable effect other than that due to the high temperature. At one foot below vapor level, it was 135 degrees F., and the relative humidity was 30 per cent. When a candle and an acetylene light were raised into the gas from below, the candle flame was extinguished at a point two inches lower than the acetylene flume, indicating a drop in oxygen content from about 16 per cent to 12 per cent (oxygen content of normal dry air 20.05 per cent) in the distance of two inches."

Sep 1, 1921

By R. W. Stahl, H. E. Sanford, J. B. Benson

"As movement or transportation of coal is second only in importance to actual mining, and as the latter is wholly dependent on the former, the efficiency of the haulage system often determines the efficiency of the entire plant. Safe or accident-free transportation is essential, also, because no attempt is made to divorce safety and efficiency, it being realized that they are inseparable.Most of the Ruhr mines were opened decades ago, and many features that were considered up-to-date then are now obsolete. Progress in developing haulage systems has been slow, chiefly because it would be very costly to change many to accomodate more modern equipment. These systems are being altered or modernized slowly, as capital permits. The only revolutionary changes that have been made in mine haulage are the use of larger locomo¬tives and cars, in the movement of shuttle cars, and in the adoption of skip hoisting. Most Ruhr shafts, however, will not accomodate large cars, the secondary roadways are too narrow for large locomotives, and the coal is too soft to permit skip hoisting because degradation would be too great. Therefore, notable advances have been made only at newer plants, where allowances have been made for modern equipment.The shafts are deep (average 2,300 feet) and of comparatively small diameter. The small bore was designed to reduce costs of sinking and lining. Generally, the shafts are lined throughout with masonry; however, most of the buntons and guides are wooden.The hoisting engines arc installed in masonry structures, and where more than one hoist is used they are placed on opposite sides of the shaft to eliminate as much noise as possible (fig. 1). This arrangement also prevents an engineer from acting on any signals except those transmitted to him. A few hoisting engines are mounted in the headframes (fig. 2). The hoisting engines are equipped with overwind, overspeed, and auxiliary braking devices, which are tested frequently and kept operative at all times. The signal code is displayed in view of the engineer, and a light or dial indicator informs him of the cage's position in the shaft. Many hoists are equipped with re¬cording devices, which show on a continuous chart the speed of hoisting as well as any delays throughout the 24-hour period.A Koepe system of winding is in general use because of the depth of shafts (fig. 3). With this system, a single rope passes over a single-groove, large-diameter sheave attached to the motive power, and the ends of the rope, after passing over the head sheaves, are attached to the cages. A flat tail rope suspended in the shaft and connected to the bottom of the cages serves to balance the system. Both steam and electric engines are used to activate the hoisting system, end the engines are capable of moving at least a 50-percent overload.The ropes are necessarily of large diameter (2-1/2 inches and greater), and flexibility decreases as rope diameter increases. To overcome the unwieldiness .of large-diameter ropes as shafts become deeper, a four-rope system is being tried at one mine (fig.4). In this system the load is equalized between four ropes which permits much smaller ropes to be used. All hoist ropes are inspected daily and discarded after 2 years service unless special permission for longer service is granted by the Mine Inspectorate, and then only after thorough visual and electromagnetic inspection."

Jan 1, 1950

By R. K. Koch

The vapor pressures of liquid columbium and liquid hafnium were deter-mined by the Langmuir free evaporation method as a part of the Bureau of Mines program on the study of transition metals. An electron-beam furnace with a water-cooled copper crucible was used for melting. Temperature was measured with a two-color ratio pyrometer. Least-squares analyses of the vapor pres-sure data gave the following equations: [Logp (atm) = 5 .429 -31,310 T] for liquid columbium in the range 2,740° - 3,140° K, and [Log p (atm) = 5,690 28 T] for liquid zirconium in the range 2,500° -2,810° K. Third-law evaluations of each data set gave mean heats of sublimation (298.15° K) of 175.1±3.2 kcal/mole and 148.3±1.2 kcal/mole for columbium and hafnium, respectively. Second-law standard heats of sublimation determined from sigma plots and from sigma-prime plots agreed fairly well with the third-law values. The sigma-prime plots gave standard entropies of sublimation of 30.96±0.84 eu and 33.S6±0.44 eu for columbium and hafnium, respectively.

Jan 1, 1968

By Dennis R. Dolinar, Lewis A. Martin

Cable bolt technology used by the U.S. coal industry was developed to a large extent in the 1990s. Today, these cable systems include both cable bolts and cable trusses to provide supplemental and secondary support in gate roads. This cable technology is significantly different than the cable systems in use in either U.S. hard-rock mines or Australian coal mines. Development of this technology was initiated and spurred by research efforts of the U.S. Bureau of Mines, and has continued under the health and safety programs of the National Institute for Occupational Safety and Health (NIOSH). It was also followed up by work of roof support manufacturers to create an essentially new support system. In this paper, the important support characteristics of both cable bolts and cable trusses are discussed. The design of cable systems and the basis for that design for tailgate and headgate situations are reviewed and explained. Case histories are presented on the application of these support systems based on experience gained at a number of in situ test sites.

Jan 10, 2000

By Larry A. Haas

The U.S. Bureau of Mines investigated the use of organic binders as substitutes for bentonite in agglomerating iron ore concentrate. Over 30 organic binders were evaluated at several dosage levels in laboratory tests. The binder groups producing the greatest green pellet strengths were natural gums (guars carboxyl methyl celluloses) and gelled starches. The nongelled and alkalized starches, starch acrylic copolymers) wood-related products, and dairy products were less effective but better than bentonite. The highest wet pellet drop numbers were obtained with binders that had a medium plate water absorption value (>500 and <10)000) in distilled water and a high slurry viscosity (>75 cP) at 6 pet solids. The highest dry compressive strengths were obtained with binders that gave the highest adhesive tensile strength (>4 kg/ cm2) on iron oxide lap-joint substrates. Pellets with 0.1 pct organic binder had lower compressive strengths and reduction disintegration indices than those with 1 pct bentonite, but higher reduction rates. Pellets with carboxyl methyl cellulose and gelled starch had higher softening temperatures than those with bentonite. Overall, the most promising binder is gelled starch. Its price makes it more cost effective than carboxyl methyl cellulose, and its pellets have metallurgical properties superior to those of bentonite pellets.

Jan 1, 1989