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By Carroll W. DeKock

Thermodynamic data for selected metal sulfates were critically evaluated and compiled as part of the Bureau of Mines program to provide a scientific base for use in developing new technology and predicting the feasibility of new processes. Values for Cp°, S°, H° - H°298, - (G° - H°298)/T, ?RC, ?Gf°, and log Kf as functions of temperature are given in tabular form. Thermodynamic data were compiled for Ag2SO4, A12(504)3, A12(S04)3?6H20, BaSO4, BeSO4, BeSO4?2H2O, BeSO4?4H20, CaSO4, CaSO4?1/2H20, CaSO4?2H2O, CdSO4, CdSO4?H20, CdS04?8/3H20, 2CdO?CdSO4, Cs2SO4, In2(S04)3, K2504, KA1(S04)2, KA1(S04)2?12H20, Li2SO4, L12SO4?H20, MgSO4, MgSO4?H2O, MgSO4?2H20, MgS04?4H20, MgS04?6H2O, MgS04?7H2O, Na2SO4, Na2S04?7H20, Na2SO4?10H20, (NH4)2SO4, NH4A1(S04)2, NH4A1(S04)2?12H20, PbSO4, Rb2SO4, T12SO4, and Zr(S04)2.

Jan 1, 1986

By B. W. Naugle

A small-scale laboratory coke oven similar to those described by Swiniarski, Cryan, and Altieri and Fuchs, Sandhoff, Taylor, and Gauger was built by the Bureau of Mines in 1943. Tests made since that time have indicated that such a small oven is of questionable value in predicting the coking pressures to be expected in commercial coke ovens. This summary of the work done has been prepared at the suggestion of the Advisory Committee to the Bureau of Mines-American Gas Association Survey of Carbonizing Prop¬erties of American Coals.

Jan 1, 1948

By Arnold F. Stalder

The measurement of various gas concentrations in the atmosphere at a particular location has become a problem of considerable importance. Levels that need to be monitored vary from the range of percent for constituents such as oxygen to parts per million levels for gases like nitrogen dioxide. In particular, mine air can become contaminated with noxious or toxic gases from several sources: fires within the mine, diesel-powered equipment, and explosive sources. The contaminants that result are carbon monoxide (CO), carbon dioxide (CO2), and oxides of nitrogen (NO and NO2). Additionally, oxygen (O2) may be depleted. Thus, the workman can be exposed to potentially toxic or asphyxiating atmospheres. A device was needed that will continuously monitor the mine air in working areas and provide warning of hazardous atmospheres. The Mine Air Monitor was conceived as being a portable, rugged instrument capable of measuring the concentration of the various atmospheric constituents in the mine environment. The unit was to provide both warning signals and quantitative measurements when hazardous contaminants existed at too high a level, or when the oxygen was being depleted. The initial concept involved optical sensors for all of the contaminating gases to be measured, namely CO, CO2, CH4, and NO2, and an electrochemical cell to monitor O2. When the explosion proof requirements of Schedule 2-G made the concept appear to be unfeasible from the standpoint of weight and portability, the program was redirected and a three channel monitor employing electrochemical sensors was adopted. In this case the gases to be monitored were O2, CO and NO2. The remainder of the program was oriented towards obtaining good, commercially available lectrochemical sensors for the above gases, testing them, reducing deficiencies noted during these tests, and making the necessary modifications to integrate the three sensors into a Mine Air Monitor suitable for the mine environment.

Jan 1, 1974

By G. A. Apell, E. G. Howe, S. W. Hazen

"INTRODUCTION As a small amount of manganese was produced from the Lake Valley mining district of Sierra County, N. Mex., during the First World War, the district was reexamined in March 1941 by John H. East, Jr., an engineer of the Bureau of Mines, as a possible source of manganese for use during the Second World War. Preliminary examination indicated a substantial reserve of 25 percent ore, so it was recommended that an exploratory program of mapping and sampling be undertaken by the Bureau.The program was started in the fall of 1941 and was completed the middle of 1942. The project 3/ was divided into two parts: The first, an underground sampling program, formed the basis for the second, or churn-drilling program. Mapping and sampling of old underground workings were begun in October and finished in November 1941, whereas churn drilling was begun in February and completed in June 1942."

Jun 1, 1947

By L. B. Berger

Studies showing the effect of mixing hot exhaust gases with the intake air of a four-stroke-cycle Diesel engine are described. The results indicate a marked increase in carbon monoxide in tip exhaust gases, a decrease in oxides of nitrogen, and no significant effect on aldehydes. The increase in carbon monoxide was greater at higher fuel-air ratios and was caused partly by the increase in fuel-air ratio end partly by the decrease in oxygen concentration resulting when exhaust has was added. The application of these results to the use of Diesel engines underground is considered.

Jan 1, 1940

By Aner W. Erickson

"Preliminary examination of tungsten deposits on the Mountain View property near Hyder, Alaska, was made by Neal M. Muir, an engineer of the Bureau of Mines daring the summer of 1942. Fifteen samples were cut, rough esti¬mates of ore reserves were made, and it was proposed to extend the drift on scheelite-bearing vein 300 feet in a northwesterly direction.From May 22 to October 24, 1944, an exploratory project was conducted on the property by the Bureau. In the course of this work, the camp buildings were rehabilitated; the dam, hydraulic line, and machinery were repaired; 226 feet of drift was driven; 80 groove samples aggregating 3.9 tons in weight were cut; a 6,000-foot surface and underground traverse was run; and the area was mapped in detail.In its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to the national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. R. S. Dean, assistant director.Special acknowledgment is doe Neal W. Muir, project engineer, and Robert S. Sanford, acting chief, Alaska Division, Mining Branch, for their supervision of the field work and revision of the report.Acknowledgment is also made to Silbak Premier, Ltd., for rendering valuable assistance in the repair of equipment and for extending various courtesies to Bureau of Mines personnel during the conduct of this project.The Mountain View property is located at latitude 55° 59' north, and longitude 130° 03' west in the Salmon River mining district of southeastern Alaska, about 5 miles in a northwesterly direction from the town of Hyder, which lies at the head of Portland Canal, as shown in figures 1 and 2. Vein outcrops and surface workings are at an elevation of 950 feet and occupy the west flank of a low ridge between Skookum and Fish Creeks, as shown in figure 3. The portal of the long adit exposing the vein at depth is on Skookum Creek about 550 feet north of the confluence of Skookum and Fish Creeks.Access to the property is over a 4-foot wide trail built and maintained by the United States Forest Service. This trail is suitable for pack animals and is adequate for transportation of supplies and material for exploratory work. During the periods of camp construction and past exploratory operations a 4,000-foot, single-cable, aerial tramway, now in disrepair, served for transportation of materials and all machinery from the Salmon River Highway to the property. The cost of such hauling was high, amounting to $12 a ton. Topography is suitable for construction of a ""cat road"" 2 miles in length, connecting the property with the Salmon River Highway. It is estimated that such a road could be built for $5,000 a mile, and supplies, machinery, and concentrates could be haled over it at a cost of less than $2.50 a ton."

Sep 1, 1946

By Sarkis G. Ampian

Published optical microscopic and X- ray diffraction characteristics of the following compounds are critically evaluated and compared with Bureau of Mines data : Tricalcium aluminate , calcium monoa luminate , dodecacalcium heptaluminate , dicalcium silicate , tricalcium silicate , and sodium aluminate . A recommended set of definitive optical and X- ray diffraction characteristics is presented . These values are used to identify products of the lime soda sinter process for production of alumina . Polymorphism of gamma- , beta- , and alpha prime - dicalcium silicate is reexamined , and new data are presented on polymorphism of tricalcium silicate and sodium aluminate by high- temperature X- ray diffractometry . Polymorphism is not observed for tricalcium aluminate , calcium monoaluminate , and dodecacalcium heptaluminate . Bureau of Mines data indicating a stoichiometry of 12Ca0.7A10 for the phase 5Ca0.3A1 0₂ are discussed . A critical review of the literature concerning calcium dia luminate and sodium undecaluminate ( 8 -A10 ) is also included .

Jan 1, 1964

1.0 SCOPE AND REGULATIONS 1.1 This specification covers the minimum requirements for material handling and associated equipment including design and materials. 1.2 This specification requires compliance with all federal, state, local laws and regulations which may be applicable including the Occupational Safety and Health Act, Construction Safety Act as well as rules, regulations and standards of the Secretary of Labor.

Jan 1, 1979

By John W. Buch

At a meeting of the Anthracite Investigations Advisory Committee in July 1944 at Washington, D. C., the initial work and objectives of the Anthracite Mechanical Mining Section of the Federal Bureau of Mines were discussed. It was learned that interest existed in an improved performance of mining thin, steeply pitching beds above the gangway by mechanical methods. One company offered the use of one of its mines for experimental work, and this offer was accepted. Following acceptance, an effort was made by Bureau engineers to devise a mechanical method with a performance better than that of a new hand method proposed by company engineers for an actual mining condition. The method proposed by the Bureau was to drive 30-degree slant chutes across a 10-foot bed pitching 85 degrees. These chutes were to be advanced by using a lightweight, compressed air-powered, shearing machine of German origin that had been tried in a flat Pennsylvania anthracite bed in 1934, and which did not then prove successful because of blasting difficulties. An attempt was made to obtain one of these machines from England, where it was known machines of this type had been used. Shortly thereafter John W. Buch was sent to Europe as a member of the Solid Fuels Mission to the European Theater of Operations organized by the Technical Industrial Intelligence Committee of the Joint Chiefs of Staff. Through his efforts the Bureau of Mines obtained two such machines, known as the Eickhoff model DEK, one from England and one from Germany. This report covers the preliminary testing of these machines in order to obtain mechanical operating data for use in determining the power requirements for cutting anthracite with machines of this design.

Jan 1, 1949

By M. S. Seehra, R. S. Pandurangi

"Investigations of the infrared spectra of crystalline and amorphous silica particles of different sizes (0.05, 5, 10, 15, 30, 45, and 260 um) in the range of 400-4000 cm-1 using Fourier transform infrared/photoacoustic spectroscopy we reported. The change in the intensity I of the signal with porosity e of powders follows the e/(1 - e) dependence for strong bands and e dependence for weaker bands as pre¬dicted by the theory of McGovern of al. For strong bands, I also follows the empirical relation I ~ D-n, where D Is the particle diameter in cm and n = 0.34-0.42. The anomalous positive frequency dependence of I on the modulation fre¬quency f observed for the stronger bands in the 45-pm and 260-pm particles Is believed to result from saturation. Some observations on the effect of changing the background from (carbon black) powder to pellet are also made.INTRODUCTIONSince the publication of the Rosencwaig—Gersho (RG) theory on the photoacoustic effect in solids (1, 2), Fourier transform infrared/photoacoustic spectroscopy (FTIR/PAS) has become an important technique for obtaining the IR spectra of surfaces and materials in their natural state (1-12). In the one-dimensional RG theory, the incident radiation, modulated at frequency f, is absorbed by the material to a depth pp = 1/B (B = absorption coefficient), thus setting up temperature variations in the material. These variations heat the adjacent gas/solid interface leading to the pressure fluctuations of the gas above the sample, which in turn is detected by microphone as a PA signal. The thermal wave originating from no deeper than the thermal diffusion length(2k/npcf) 1/2 in the material contributes to the PA signal (here k, p, and c are respectively the thermal conductivity, density, and specific heat of the material). Since u2, can be varied by varying the experimental parameter f, depth pro¬filing by PAS is possible and a number of papers on this subject have appeared in recent years (2-10). Another im¬portant phenomenon is saturation which occurs when the material thickness 1> u> us (1-12).The original promise of PAS for use with powder samples, without the need to ""prepare"" samples as in FTIR spectros-copy, has not yet been fully realized because of several com¬plications. Theoretical works by Monchalin et al. (13) and McGovern et al (14) showed that the interstial gas in the voids of the powders can act as amplifier and that, for the same mass, a finer powder is expected to yield higher PA signal than a coarser powder. Although in a number of earlier studies (15-21) an increase of PA signal with decreasing particle size has been observed, a quantitative check on the equations developed by McGovern et al. (14) has not yet been made. It is necessary to understand the particle size effects in PAS if the promise of PAS for IR spectroscopy of powders is to be realized. In this paper, we report results of a detailed study on the PAS of silica powders for the particle size range of 0.05-260 um and compare the results with theory (14). We have also investigated the frequency dependence of the variousIR modes in these powders and show that the saturation phenomenon affects at least some of the observations. Some observations on the effects of pellet vs powder background are also reported (22-24). Details of these findings are presented and discussed in this paper."

Jan 1, 1990

By S. H. Lorain

This paper is one of a series on mining methods and costs being published by the U. S. Bureau of Mines. The operations of the Quartz Hill Mining Co., near Dewey, Mont., afford an interesting example of the cost of mining small bodies of direct shipping ore; they also illustrate the effect of the unavoidable periods of unusually high exploration and development costs in this type of mining upon the cost per ton of producing ore. The importance of skilled geological guidance and the necessity of avoiding unnecessary overhead and capital expense at small mines are shown. Operating conditions at Quartz Hill are typical of those in many other mining districts of southwestern Montana. It is believed that the costs presented here may be of value in the preliminary estimation of costs to be expected by conservative operators under similar conditions elsewhere. The information contained in this paper was obtained during a visit to the Quartz Hill mine in August 1936.

Jan 1, 1937

By H. R. Batchelder

Much information on oxygen production and the manufacture of synthetic liquid fuels has been published during the past several years. From time to tine the investment and operating cost of oxygen plants of various sizes has been estimated. Surveys have been made so that the various processes by which oxygen is produced commercially might be compared. The gas-making processes in which oxygen is employed, which wore used in Germany during the war, have been described in T.O.M. reels, and this information has been published. Descriptions of pilot-scale or proposed commercial plants for the production of synthesis gas or hydrogen and their conversion to synthetic liquid fuels also have been published. In general, each of these publications has dealt with a particular phase of the over-all problem. The present paper will discuss the relationship between these phases: The factors that affect oxygen manufacture and costs, the methods for the use of oxygen and for the production of synthetic liquid fuels, and, to some extent, the economic factors that must be considered.

Jan 1, 1951

By D. B. Eccleston

Natural gas and mixtures of natural gas and hydrogen were used as fuels in a laboratory engine to determine the relationship of emissions to air-fuel ratio and to establish practical lean limits for air-fuel ratio. Synthetic gas manufactured from coal (Synthane) and natural gas were used as fuels in a vehicle to obtain comparative data on emissions and performance. Results showed that lean limits for air-fuel ratio when using hydrogen-enriched natural gas were extended significantly beyond Chat of natural gas. Synthane pro¬duced exhaust that was significantly less reactive than exhaust from natural gas. With lean air-fuel ratios, the acceleration performance of a vehicle fueled with Synthane was improved over its performance when fueled with natural gas.

Jan 1, 1972

By J. A. Rowland

Magnesium alloys containing nickel, nickel and manganese, lithium, lithium and manganese, and lithium and aluminum were investigated. Melting, casting, and mechanical working techniques and the heat treatment of various compositions were studied. Amenability to cold and hot working was shown for many compositions. The magnesium-nickel and magnesium-nickel-manganese alloys failed to develop superior mechanical properties and were very low in resistance to corrosion. The magnesium-lithium series, although entirely plastic, had low strength properties. The addition of small amounts of aluminum to the Mg-Li base did not affect greatly either the ductility or the strength; further additions developed increased strength, but only at room temperature, and the alloys became brittle with age. Continued study, concentrating on the ductile lithium-rich beta phase as a base composition for ternary and quaternary systems, is recommended.

Jan 1, 1956

By H. C. Young

This paper deals with roof bolting in Alabama coal mines and iron-ore mines from the time it was introduced in early May 1948 to May 1, 1953, a 5-year period. The Tennessee Coal & Iron Division of the United States Steel Corp. began systematic roof bolting in early May 1948 in a coal mine and in an iron-ore mine, which had some of the poorest roof conditions in the Alabama mines. After the efficiency of roof bolting had been proved by the Tennessee Co. it was gradually adopted by other companies throughout the State, until in May 1953 approximately 53 percent of Alabama's total coal production and 100 percent of Alabama's total iron-ore production, mined underground, was being produced from roof-bolted areas. Statistics in this report will show the advancement made in roof bolting in the 5 years and also the amount of roof bolting that was being done as of May 1, 1953. Significant progress has been made in the coal and iron-ore mines of Alabama in reducing the roof-fall fatality rates during the past several years by adopting systematic roof bolting. The groundwork was laid through successful experiments early in 1948 by the Tennessee Coal & Iron Division of the United States Steel Corp. in cooperation with the Federal Bureau of Mines. This experimental work was based upon the previous experience of the St. Joseph Lead Co.2/ in its Southeastern Missouri mines.

Jan 1, 1954

By Lloyd Carpenter

Eighteen elements were determined spectrochemically in vanadium metal and its compounds in the general range of 1 to 1,000 ppm by means of spark-ignited unidirectional arc excitation. The samples were converted to vanadium pentoxide and combined with a mixture of graphite, lithium carbonate, and gallium oxide. For the molybdenum determination, the oxidized samples were mixed with sodium chloride and packed in copper electrodes. Average precision of the method was 15.6 percent relative standard deviation and relative error was 4.4 percent.

Jan 1, 1963

By D. Harrington

An explosive may be defined as a substance (usually a mixture) that has the property of yielding, readily to combustion or oxidation upon application of flame or shock, the combustion or oxidation process being rapid and accompanied by formation of such relatively large quantities of gases that much violence and pressure are produced; these, in turn, react against their surroundings and cause what is termed an explosion. By their very nature their action is destructive and disruptive of adjunct materials; hence, all explosives axe potentially hazardous and every type of explosive, irrespective of its relative safety, should be handled, .stored, and used with utmost care at all times and under all conditions. It should always be remembered that any explosive can be rude safe only in certain of its features and under certain conditions and circumstance. If these facts (and they certainly are facts) are always kept in mind, most of the modern types of explosives can be utilized advantageously in our industrial life and with a considerable degree of safety. That commercial explosives can be handled. safely is borne out in part by the fact that in the past 15 years at least 3,000,000,000 pounds of the commercial explosive dynamite have been transported by railroads in the United State, without injury to any person, insofar as available records indicate.

Jan 1, 1939

By Wilbert J. Huff, Raymond H. Moore

"Black powder is employed widely in peace and war. Its properties are therefore of considerable interest to many. The Bureau of Mines frequently is asked to furnish information on its use and safe handling in the mining and mineral industries in times of peace and is now engaged in studies of its application to the arts of war.Black powder has been the agent in many accidents - some very disastrous - and its handling and use are deemed very hazardous. The belief is widespread that the hazards are due principally to the ease with which the powder is ignited by a hot spark or flame in contradistinction to high explosives; these usually are ignited only with difficulty, and some burn incompl0tely and to a certain extent are self-extinguishing. Primary precautions, .therefore, should be taken to prevent the access of heat, spark, and flame.In black powder manufacturing operations a frequent source of disaster is the initiation of fires and explosions in the wheel mills in which the sulfur, charcoal, and nitrate are incorporated. Long experience has indicated that the wheel mill probably will fire if the powder is not kept moist enough; manufacturing supervision calls for the maintenance of a minimum moisture content, at least during the milling. Accidents occur elsewhere in the manufacturing line, and in an endeavor to minimize these, particularly those happening in corning mills, one of the writers suggested many years ago that a suitable humidity be maintained in other operations in the hope that it would serve protectively as in the wheel mill. The experience of one company for many years with this practice was favorable. It seemed desirable therefore, to explore the question experimentally."

Nov 1, 1944

By Wing G. Agnew, Albert E. Long

"SUMMARY AND CONCLUSIONSTests conducted at Mount Weather indicate that clear water is the best bit coolant and cuttings-removal medium for diamond drilling. All of the mediums tested did show that drilling speed increased when drilling with the faster feed ratios (greatest pressure on the bits). In no case, how¬ever, did the increased drilling speed amount to over 16 percent, and even in a long hole the slight increase in drilling speed would be more than offset by the extra time consumed in setting up.Bit wear was excessive when lubricating agents were used, the most footage per bit was obtained when drilling with clear water in the normal manner, and the next best footage was obtained when drilling with circulated water containing no lubricating agent. The diamonds showed little or no wear in any of the bits, and all bits cut well throughout the tests. They were only taken out of service when erosion of the cast metal had progressed to the point where the diamonds were about to roll out. The lubricating agents evidently hold some of the cuttings in suspension, which in turn help to cut the rock but also wear the metal of the bit.No hard-matrix bits were tested, and it is possible that one or more of the lubricating agents might increase the efficiency of such a bit by keeping it sharp and doing away with the necessity of sharpening by sand blasting. Some tests are planned with hard-matrix-type bits and the same lubricating agents used in the tests under discussion, but it is realized that any drilling advantage gained by the bits sharpening themselves may but at least partly offset by excessive wear of the Pump parts."

Jan 1, 1945

By Welby G. Courtney

This publication reviews recent U.S. Bureau of Mines studies of frictional ignition of a methane-air environment by coal mining bits cutting into sandstone and the effectiveness of remedial techniques to reduce the likelihood of frictional ignition. Frictional ignition with a mining bit always involves a worn bit having a wear flat on the tip of the bit. The worn bit forms hot spots on the surface of the sandstone because of frictional abrasion. The hot spots then can ignite the methane-air environment. A small wear flat forms a small hot spot, which does not give ignition, while a large wear flat forms a large hot spot, which gives ignition. The likelihood of frictional ignition can be somewhat reduced by using a mushroom-shaped tungsten-carbide bit tip on the mining bit and by increasing the bit clearance angle; it can be significantly reduced by using a water spray nozzle in back of each bit, which is carefully oriented to direct the water spray onto the sandstone surface directly behind the bit and thereby cool the hot spots formed by the worn bit. A bit replacement schedule must be used to avoid the formation of a dangerously worn bit.

Jan 1, 1990