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By O. V. Suvorova, V. G. Minenko, D. V. Makarov, A. L. Samusev, E. A. Selivanova

"Saponite is a valuable marketable product widely used foundry, metallurgy and construction, in the chemical, food and consumer goods industries, in medicine, and in agriculture.The feasibility of producing of high-quality construction materials with enhanced physical-chemical and decorative characteristics from saponite-containing products has been given a scientific basis and experimentally validated. The compressive strength of the samples in the sintering temperature range of 800-1000 ?? varied between 35 and 80.9 MPa; the bending strength 8 and 26.7 MPa, which is superior to the high-grade ceramic bricks of the M-300 brand. It has been established that the saponite-containing product obtained using the electrochemical separation of process water has a high sorption capacitance relatively the heavy-metal ions such as nickel and copper (40.7 and 99.8 mg/g, respectively). As a result of sintering at 750 ?? the sorption capacity of the sorbent for the nickel and copper ions increased to 194.2 and 212.8. Using the XRD and SEM with energy-dispersive spectroscopy studies, we diagnosed the metal-containing phases and validated the metal sorption mechanism.This study opens up the possibility of practical realization of the saponite-containing product as high-quality building materials and heavy-metal sorbents while addressing the issue of process water treatment. INTRODUCTION The Lomonosov deposit of the Archangelsk diamondiferous province accommodates 10 kimberlite pipes. The anticipated volume of diamond-bearing ore and dump rock to be removed before reaching the open-pit mining limit is 300 mln t (Karpenko, 2009; Bezborodov, etal. 2003). Rock in the deposit is almost completely displaced by clay minerals, predominantly saponite, amounting to 90% in the vent facies (Karpenko, 2009)."

Jan 1, 2018

By Y. X. Yang

Bottom ash is a solid waste stream in a Waste-to-Energy (WTE) processing plant during the combustion of the municipal solid waste (MSW). In the Netherlands, bottom ash contains typically about 18% metals originated from the MSW, and current industrial practice could recover about 10% metals through magnetic and eddy current separators. The remaining 8% as the finer particles is difficult to recover through current physical separation technology. Among various alternatives, vitrification is one of the promising options to immobilize the ash and recover the remaining metals. During vitrification a homogeneous glassy slag and a Fe-Cu based alloy were obtained. In the cur-rent study, the metal alloy recovered from the bottom ash originated from a Dutch Waste-to-Energy plant contains about 82 wt% Fe, 12 wt% Cu and 6 wt% other alloying elements and impurities such as C, S, P, Ni etc. The generated alloy does not have direct commercial applications, and separation of copper from iron-based alloy is critical to obtain the market value of both copper and ferrous constituents. To find a suitable processing route of this metal alloy, various alternative approaches have been considered for an efficient removal of copper from the alloy, and the focus in the present study was on the sulphide treatment at elevated temperatures of 1400 ~ 1500oC. The tested sulphide systems include pure FeS, FeS containing sulphide mixture (such as Na2S and Al2S3), pyrite (FeS2) mineral, ZnS containing sludge as an industrial waste. It was found that the carbon saturation of the alloy is proved to be an essential condition for a proper phase separation. The results showed that FeS mixed with Na2S, ZnS containing sludge and pyrite are effective sulphide systems for copper removal with a removal efficiency of 92% by using pyrite and 95% by zinc sludge at a S/Cu ratio of around 7 times of the stoichiometry. The copper content drops from 12 wt% to about 2 wt%. However, it is still difficult to remove copper completely from the alloy in a single step, and a multi-step operation is needed. The present research is expected to contribute both to the utilization of the metal recovered from bottom ash, and to the general recycling of steel scrap where copper removal from the steel scrap is a critical issue.

Jan 1, 2014

By V. A. Luganov

The processing of pyrite concentrates may be accomplished with a preliminary enrichment due to withdrawal of iron sulfides from initial concentrate. The withdrawal of iron sulfides is possible with the help of magnetic separation when the magnetic iron sulfides (pyrrhotites) separate from non-magnetic fraction?the sulfides of non-ferrous metals. The conversion of non-magnetic pyrite to magnetic pyrrhotites of adjusted structure occurs because of roasting with the withdrawal a part of sulfur. The resultant pyrrhotites are strong ferromagnetic with hexagonal structure. This paper contains results of studying magnetic properties of pyrrhotites, findings of the de-composition of initial pyrite with the consequence homogenizing of product and hardening of product of decomposition in liquid nitrogen. Define the type of pyrrhotites super lattice structure, was established that at increasing of sulfur contention the magnetic properties of pyrrhotites are change ? pyrrhotite begin evince the properties of antiferromagnetic material and magnetic susceptibility of material is interruptive changing from 0 to 1.7×10-3~1.9×10-3 SI units/g system. The paper contains results of technological researching of pyrrhotizing-magnetizing roasting of pyrite concentrates in different condition: in unoxidizing, with the decreasing contention of oxygen and in autogenous regime in air atmosphere. Established that the magnetic susceptibility of products depend of pyrite degree dissociation and achieve 2×10-3~3×10-3 SI units/g system at 40%~45% desulphurization. Defined the conditions of steady regime autogenous roasting, at resultant products possess coefficient of magnetization, and this can be used magnetic separation for separating ferromagnetic pyrrhotites from gangues and non-magnetic sulfides of non-ferrous metals. This technology of pyrrhotizing roasting is recommended for effecting in industrial condition. The initial materials and products of roasting subjected to chemical, thermogravimetric, Moss-bauer spectroscopy and X-ray analysis, defined the magnetic properties.

Jan 1, 2014

By M. Saghaeian, R. Hejazi, M. Farahani, M. Dehghani, A. Tohry

"Wet tailing dams of iron ore processing plants typically contain a significant amount of valuable minerals. In more recent years, due to the increase in iron’s prices and technological innovations, as well as the low energy consumption which required for processing of materials from tailings, dams can consider as potential valuable deposits. However, the production of iron concentrate from tailings is usually complicated where the high moisture content of the material, the high clay content and the presence of chemicals of processing such as flocculants, acids and flotation reagents, all make materials highly sticky which can be easily swollen. In the present paper, the optimization of operational parameters to recover ultrafine hematite iron ore from the wet tailings dams of the Chador-malu iron ore mine was investigated. The optimization of operational parameters, showed that with modification of the washing unit components for slurry making, the challenge of constraints from feeding the plant could be overcome. To decrease the magnetite content in the tail stream of the medium intensity magnetic separation (MIMS) and subsequently increase the efficiency, the orifice of the cleaner tail flow exit pipe was changed from 7 inches to 3 inch and yoke angle changed from 14 to 8 degrees. These changes increased mass yield by 3% and decreased the magnetite content in the final tailings to 1.2%. By recirculating the cleaner SLons of final tailings within the circuit, the solid percentage of the feed to rougher SLons decreased to around 15%, and as a result the matrices were not overloaded that easily, and mass yield increased to about 13% from 7%. All the above mentioned optimizations were achieved without significantly affecting the concentrate Fe grade."

Jan 1, 2018

By D. Y. Liang

Rare metal ores have those features of high industrial value and bad performance in ore separation. Most of rare metals ores are with low grade of valuable components, rareness of useful minerals, complicated combination of associated minerals and high difficulty in separation and enrichment of minerals. For those single (Ta, Nb) or (Ta, Nb, Sn) ore occurred in granite and pegmatite, the ways of gravity separation and magneto electric separation to concentrate (Ta, Nb) minerals are adopted. There are many mines being explored successfully both at home and aboard. While, for complex (Nb-Zr-REE) ores associated with Be and Ti minerals, they are commonly considered as rich rare metals ore but more difficult to process. One of rare metals mine in Inner Mongolia has the features as with large reserves and high grade of columbium and zirconium and accompanies with REE and beryllium, therefore with significant industrial value. After the utilization of research method of process mineralogy, detailed mineralogy research has been made on the rare metals ore. The test results show that there are abroad isomorphism replacements among such elements, such as Ti, Mn, Fe, Nb and Ta, between Be and REE in metallic oxide minerals of that ore, which makes the mineral composition of that ore extremely complicated. This research identifies clearly the mineral composition, and investigate at the technological property and the occurrence of those elements as Nb, Zr, Be and REE in the rare metal ore. The achievements of this research provide important mineralogy basis for ore dressing research of refractory rare metallic ores.

Jan 1, 2014

By Jannie van Deventer

"Innovation in the minerals industry has been lagging behind comparable industries like oil and gas. An incremental innovation culture that tolerates long lead times between invention and adoption has been exacerbated by a research grant structure that inhibits radical idea generation. Entrepreneurs who can make the link between ore source, technology and finance will cause a shift in innovation culture and open up substantial opportunities in the minerals industry of the future. By extrapolating existing trends in technology within and outside mineral processing, a crystal ball vision of future innovation is shaped with the aim to lower energy and water demand, reduce CO2 emissions, decrease operating and capital costs, reduce environmental impact, and secure a social licence to operate. Advances in nanotechnology, advanced materials and biotechnology will impact mineral processing, but the initiative for technology transfer must come from mineral processors. Laminates of graphene oxide can offer efficient filtration and separation media, while microfluidic devices will be used for desalination, solvent extraction and analysis. Substantial progress is expected on benign lixiviants and separation agents, such as nanoscale supramolecular hosts that can serve as high-capacity, selective and recyclable ligands and sorbents, and solid aminobiphosphonate-based adsorbents. Radical ideas for the recovery of precious metals from non-assayable ores and the generation of energy above unity will be adopted in selected minerals projects. In-situ mining in which microbes generate lixiviants at mineral surfaces will simplify processing circuits. Specific ores will be subjected to microwave processing and electropulse liberation to enhance recovery. Ultrafine grinding using devices of low energy consumption will be done mainly dry, followed by dry separation. New flotation cells will remove efficiently either coarse particles or ultra-fine particles, with mineral surfaces being modified not just by new reagents but also by selective microbes. Innovation in mineral processing indeed has a bright future."

Jan 1, 2014

Micro-fine disseminated molybdenite was ground in a laboratory stirred mill using steel media and zirconium media respectively. The floatability of ground molybdenite and slurry chemistry was investigated. It was found that the total recovery of ground molybdenite using zirconium media was higher while the pH and Eh of the slurry are lower than that using steel media. When steel media was used, iron oxy-hydroxides had been generated coated on the surface of molybdenite, and decreased the floatability of molybdenite, especially of the -10µm particles. The iron and lead oxy-hydroxides was generated by the reaction between steel media with pyrite and galena associated with molybdenite. It was also found that changing the grinding media to inert can benefit the flotation of molybdenite. Keywords: stirred mill, grinding environment, floatability, micro-fine disseminated molybdenite, fine grinding

Sep 1, 2012

By B. Hosseini

Considering the subtractive trend of the sulfide and high-grade zinc ores in worldwide and also in Iran, Nowadays special attentions have been drawn to the extraction of zinc from its other resources such as low-grade oxide ores and secondary resources. Oxide ore of the eastern part of Mehdi-abad lead and zinc mine is silicate and has an average grade of 7% (with cut off grade of 4%). Main mineral of the Mehdi-abad ore is Hemimorphite and this mineral is associated with Goethite, Hematite, Ferrous Dolomite, and Manganese oxide mineral so that oxides of Iron, manganese and silica include almost 50% of the total ore. In this paper, the results obtained from the leaching kinetic study of the low-grade zinc oxide ore using Sulfuric acid are presented. The effects of particle size, reaction temperature, acid concentration, and solid percent on the dissolution rate have been investigated. The results obtained from the Taghochi approach showed that the zinc recovery is about 78% under the following optimized conditions: particle size: 106µm, leaching time: one hour, temperature: 45°C, acid concentration: 15% and solid percent: 15%. Kinetics study was revealed that zinc minerals leaching controlled by diffusion rate through the product layer during leaching time with the activation energy of 5 KJ/mol and compliance with the 1- (2/3. x) ? (1- x) 2/3 = k. t model. Keywords: leaching kinetics, kinetics models, sulfuric acid leaching, taguchi methods, low grade zinc ore, mehdi-abad mine

Sep 1, 2012

By A. Chattopadhyay

Porphyry copper deposits are the most important source of copper and also gold within the orogenic belts. These deposits are characterized by low grade copper ore (0.2% to 1% copper) and host precious metals like gold, silver and platinum. A characterization tool has been developed for complex porphyry type copper-gold deposits with an aim to quantify copper and precious metal deportment. This quantification is a challenging task due to low grades and also due to the presence of both visible and invisible precious metal content in different sulphide and non-sulphide phases. Studies were initiated on various complex, ore deposits and also on samples representing various processing streams such as flotation and leach products. This paper presents the development of a systematic approach to diagnostic metallurgy using state-of-the-art optical and automated mineralogy, micro-probe, dynamic SIMS and TOF-SIMS analysis for quantification of invisible and visible precious metals content in various species. The relevance of this characterization to metallurgy will also be briefly discussed in this paper.

Sep 1, 2012

By I. A. Khabarova

The paper presents the results of experimental investigations of the effect by high-power nano-second electromagnetic pulses (HPEMP) on change of surface composition, physical-chemical and flotation properties of pyrrhotite, and search of optimal combination of flotation reactants providing increase of metal extraction from disseminated copper-nickel ores. Preliminary electropulse effect on products before flotation allows to create optimal conditions for flotation separation of pentlandite and pyrrhotite owing to forming the new phases and defects on the surface of sulphides. It was established, that the yield of monomineral fractions of pyrite, pyrrhotite and chalkopyrite increases by 5%~15 %, compared with flotation with one butyl xanthenes (BX), during usage of combination of thionic carbamate (isopropylmethylthionocarbamate (ITC) or isopropylethyl- thionocarbamate (Z-200) with butyl xanthate (BX). Sorption of investigated reactants and strength of their fixing on the surface of minerals are examined; it helped to reveal the cause of rise of floatability of sulphide minerals for the case of combination of reactants. Preliminary high-pulse processing and reactant conditions with usage of combination of thionic carbamate and xanthate have been tested on the sample of disseminated copper-nickel ore from Norilsk region.

Jan 1, 2014

By L. Bbosa

Positron Emission Particle Tracking (PEPT) and the Discrete Element Method (DEM) are used to investigate Power Draw in a laboratory scale tumbling mill. The mill is run dry in batch mode at different speeds using mono-size charge of glass beads, and is mounted along with a torque transducer to measure power. Particle tracking information from PEPT is used to reconstruct the motion of glass beads and infer the overall charge behavior, while DEM is employed to simulate particle motion and interaction, with collision mechanics calculated using the Hertz-Mindlin contact model. For PEPT and DEM data, the product of torque and average angular velocities in discrete cells are accumulated to obtain mill power. This method is found to be within statistical agreement with measured power for all tests. Spatial distributions plotted from this approach highlight the regions of the mill that draw the greatest power. A second technique to obtain Power Draw from DEM data which sums particle forces against the mill geometry is similarly found to accurately predict mill power with lower statistical error. Keywords: Power Draw, PEPT, DEM

Sep 1, 2012

By G. Demi

Chromium ore exploitation has commenced in 1948 in Albania and there are produced about 24.3 million tons up to the end of 2006. Last years the prices and need were increased notably. Main export of chromium ores and concentrates was accomplished respectively 114 500 ton and 13 000 ton in People Republic of China during 2006 year. Location, status, reserves and grade of chromium deposits of Albania are presented in the paper. Chromium ore enrichment is related with their composition and Cr2O3 content, as well as with market requests. Actually, high grade chromium ores with Cr2O3 content over 38% ~ 40% are directly exported or treated in metallurgy, but last time have been exported and chromium ores with 28% ~ 30% Cr2O3 content for the reason that dressing plants can not be operated for investment lack. High grade chromium ores have been treated in heavy media separation plant before 1990. It is presented flow sheet, figures and necessity to put in operation HMS plant in the paper. Actually, low grade chromium ores with content 16% ~ 20% Cr2O3 are not enriched for the lack of investments, but before 1990 they have been concentrated in dressing plants producing chromium concentrates grade 48% ~ 50% Cr2O3. In the paper are shown technological schemes and industrial figures during more than 20 years operation and possibilities to reconstruct these mineral processing plants. Only chromium mineral processing plant of Bulqiza is in operation using as raw material its old existing tailings. The flow sheet and figures show that are possibilities to increase recovery and grade of concentrate in the plant. Separation and concentration of slimes in suitable equipment gives visible improvement of Cr2O3 recovery. Several tests have been carried out with flotation and magnetic separation methods for enrichment of low grade chromium ores. Flow sheet and figures of mineral processing ores content olivine as gangue mineral are interesting, because combination of gravimetric with magnetic methods is necessary in this case. In the paper are presented the tests and good results of low chromium ore pre concentration. Metallurgical treatment of chromium ores to produce Ferro chrome, as well as technological process, figures, consume of electrical power and materials in Elbasani and Burreli furnaces are shown and necessary investments to treat in metallurgy all produced chromium ores in Albania are considered.

Jan 1, 2014

By G. Y. Liu

The structure-activity relationships for four thionocarbamate collectors are discussed in this pa-per. These collector classes are alkyl alkyl thionocarbamates, allyl alkyl thionocarbamates, acyl al-kyl thionocarbamates and alkoxylcarbonyl alkyl thionocarbamates. The main emphasis will be to highlight the differences between collectors and their affinities for copper and iron sulfide minerals on the basis of data on electronic-structure properties obtained by vacuum and solution density functional calculations, flotation experiments and analysis measurements. The mechanism of interaction of these collectors with sulfide minerals is also discussed with perturbation theory. The theoretical study results indicate that acyl alkyl thionocarbamates and alkoxylcarbonyl alkyl thionocarbamates have best performance in these agents as flotation collectors with improved collecting power for copper sulfide minerals and excellent selectivity against iron sulfide minerals, which are consistent with the experimental data reported in the literature.

Jan 1, 2014

Datun Concentrator currently processes complex sulfide ores in Gejiu Municipality, Yunnan Province, China. The ore contains much higher arsenic than other ores. The run of mine ore is fed to the concentrator to recover copper and tin by bulk flotation and gravity concentration, and then the other sulphides, such as pyrite, arsenopyrite, etc. didn?t get utilized and are discarded as tailings due to the high arsenic content. In order to utilize the pyrites in the tailings, a series of tests have been conducted for finding the solution of arsenic removal from high arsenic-bearing pyrite concentrates through simple flotation process. By means of orthogonal experimental design, the optimized levels and main factors have been found out for the roughing stage. Through selection of the effective in-organic depressants for the arsenic-bearing minerals, the arsenic in the pyrite concentrate can be removed to meet the requirement of sulfuric acid plant (As%=0.5%) by the open flotation process, i.e., one-time roughing and two-time cleaning.

Jan 1, 2014

By S. A. Kubyshkin, A. A. Agafonov, A. L. Shakhnin, S. M. Sukharzhevsky, A. A. Komlev, N. V. Vorob’ev-Desyatovskii, A. Pichugina

Cyanidation of gold ore results in formation not only of Na[Au(CN)2], but also cyanometallate complexes of some transition metals. During subsequent gold extraction from such solutions and pulps, using activated carbons (??), a number of problems arise. An effective solution of the problem is not possible without detailed knowledge of the interaction mechanism of transition metals cyanide complexes with AC particles. The chemical properties of AC particles and graphene, saturated with [?u(CN)n](n-1)- (n=2, 3), were studied by XPS, ESR, SQUID, and DFT. The obtained results were compared with the data on AC adsorption of anionic form of Ag(I), Au(I), Cd(II), Hg(II), Cr(III), Fe(II), Fe(III), Co(III), Rh(III), Ni(II), Pd(II), Pt(II) and Pt(IV) cyanide complexes. The adsorption of [?u(CN)n](n-1)- (n=2, 3) on AC from aqueous solutions in air is accompanied with oxidation of ?u(I) atoms. Besides, Cu(II) and Cu(III) compounds were found on AC surface. Quantum-chemical calculations confirmed the possibility of formation of Cu(I) complex with carbene-like sites of AC. The reactions of [?u(CN)n](n-1)- (n=2, 3) complexes and aromatic carbenes and their cation-radical were theoretically studied at DFT PBE level to obtain the information on adsorption of cyanometallate complexes on AC. Carbenes with different fragments were regarded as a model of activated carbons, which have free edge sites with paired o and n electrons. It was shown that [Cu(CN)2]- bounds firmly with triplet carbene, if one Cu-CN bond breaks. The dissociation process occurs through a multi-step spin-crossing mechanism to reduce total spin multiplicity of the metal-carbene complex. The behavior of transition element complexes in contact with AC in aqueous solutions is determined by the following characteristics: geometrical structure of ionic complexes; nature of ligands bonded to the central atom; concentration of reactive oxygen species in solution and its pH; nature of binding sites of AC.

Jan 1, 2018

By Ying Gu

Automated mineralogy methods and tools, such as the Mineral Liberation Analyzer (MLA) and the QEMSCAN, are now widely used for ore characterization, process design and optimization. Several case studies published recently demonstrate that large gains can be obtained through grinding and flotation optimization guided by automated mineralogy data. However, since automated mineralogy can only provide the information pointing to where the process gains can be made, it does not directly impact the production gain. Thus, a question is often asked: how to value the contribution of automated mineralogy to process improvement of a particular plant. This appears to be a difficult question. On close examination however, it is found that this is essentially a question of the value of information and it is reasonably well documented in various other industries. Hubbard (2010), in chapter 7 ?Measuring the Value of Information?, dealt with exactly this type of problem. The value of information is the reduced risk of an investment and opportunity loss. The methods Hubbard developed can be applied to estimate the value of automated mineralogy, as well as metallurgical test work, which also produces information that reduces the risk of investment. This paper first introduces Hubbard?s theory on the value of information and how to measure it. It then applies his methods to estimate the value of automated mineralogy, using Anglo Platinum?s fine grinding project as an example. In this case, the value of automated mineralogy includes the reduction in investment risk worth US$ 62.5million, in project rejection worth US$197 million and in opportunity loss worth US$320 million. In the end, a general model is developed to allow the simulation of the value of automated mineralogy in different mining operations constrained by different parameters.

Sep 1, 2012

By S. J. Ma

To look into the ionic release laws of the sulphide tailings in some copper mine, the effects of the soaking period, temperature, oscillating speed, and pH of the solution on the heavy metals ionic re-lease were investigated through static soaking leaching experiments. The results show that Cu2+, Zn2+, Pb2+, Cr3+ are of different leaching behaviors with soaking period. The ionic concentration in soaking solution for four ions has a great gap. Zn2+ is more easily released out of sulfide tailings than Cu2+, Pb2+, Cr3+ , and the ion release concentrations are not proportion to their contents in the tailings. The time for each ion to reach its maximum concentration are different. The minimum concentration do not occur at the first day. Each ion concentration shows different fluctuation characteristic during soaking process. Solution pH, oscillating speed, and temperature affect the releases of Cu2+, Zn2+, Pb2+, Cr3+ out of the tailings to different extent. The effect of pH value on ion re-lease for the four ions ranks as Zn2+>Cu2+>Pb2+>Cr3+, the oscillating speed ranks as Pb2+>Zn2+>Cu2+>Cr3+, and the temperature ranks as Cr3+>Pb2+>Zn2+>Cu2+.

Jan 1, 2014

Under the AMIRA P9 project the three-product cyclone-an off-shoot of the conventional hydro-cyclone-that produces three distinct products has been developed. The three-product cyclone shows great promise as a classifier in mineral processing. Industrial and pilot plant trials performed to assess its performance in the classification of the UG2 platinum ore, indicate that the presence of an extra overflow product stream that captures the mid-sized particles, provides improved classification efficiency. To assess the split on component density, samples from the feed and product streams were screened and assays by size for chromite (? = 4.8) and silica (? = 2.65) were obtained. Results from tests performed using this type of hydrocyclone in a number of applications indicates that it can be applied successfully in circuit configurations where the conventional hydrocyc-lone is not suitable. Utilising the three-product cyclone to classify the UG2 platinum ore resulted in an intermediate overflow product stream containing the mid-sized low density silicates and relatively fine high density chromite particles while the finer overflow contained mostly fine silicates and chromite particles. The coarse chromite and silicates reported to the underflow. Due to the increased number of products, the method of using efficiency curves was extended to cater for the increased number of products in the three-product cyclone. Although significant differences in the classification performance of the three-product cyclone were noticed with variations in machine variables a consistent method of assessing the performance was applied. The efficiency curve was adopted and applied and separate efficiency curve properties were obtained for each product stream. The methodology was applied to the component data, and efficiency curve proper-ties for each key component were obtained and compared. This paper discusses the application of the efficiency curve to cyclones producing more than two products and extending the methodology to the different components in the feed.

Jan 1, 2014

By W. Y. Liu

A sulfate reducing bacteria strain (named SRB-A) is isolated from sanitary wastewater by using anaerobic technology of Hungate. The studies of physiological, biochemical and phylogenic of the isolated strain are carried out. The colonies of the strain are circle. Cells that are slightly curve, rod-shaped with the size of 1.0~3.0µm in length and 0.8~1.0µm in width. The optimum temperature for growth of the organism is 30~35°C. The optimum pH for growth is 7.0~7.2. Strain SRB-A can use sodium lactate, sodium citrate, sodium acetate, ethanol and acetone as electronic acceptor but can not use glycerol, glucose, sucrose and sodium oxatate. The isolated strain reduces sulfate, sulfide, sulfur, DSMO and FeCl3, then nitrate and nitrite can not be used. The strain has higher tolerance of NaCl, and the optimum growth occurs in the presence of 5%~8% (w/v) NaCl. The result of 16S rDNA sequence analysis indicates that the isolated strain SRB-A is the most similar to Desulfo-vibrio halophilus, and the level of the similarity was 98.4%. The isolated strain has a stronger ability to reduce sulfate, and the level of sulfate reduction reaches about 90% at pH 7 in the liquid medium. 0.6 to 0.8 is the optimum COD/SO42- in the medium for the isolated strain to show better ability to reduce sulfate. At pH 2.5 the level of removal of Cu2+ reaches 96.3%. Under the condition of pH 3.5, the level of removal of Zn2+ reaches 92.6%. When the value of pH reaches about 7, the Fe3+ is precipitated by the formation of Fe(OH)3, and Fe3+ is removed up to 89.4% at last.

Jan 1, 2014

By Ji Hoe Kwon

Hindered-settling column process has been used for the separation of mineral particles for many years. In this study, a model based on DEM (Discrete Element Method) was used to simulate the movements of particles in a settling column separation process. DEM model is capable of describing the motion of particles and calculating the impact forces between particle and particle, and particle and wall contact under various operating conditions. Drag force, rotation induced Magnus lift force, contact force and the gravitational force acting on individual particles were considered for establishing the mathematic models. The overall motion of the particles in water is satisfactorily simulated by the DEM, and the result shows good agreements with the result of lap-scale experiment.

Jan 1, 2014