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By G. S. Barry

INVESTIGATIONS to date have shown that, should there be the need or the appropriate economic stimulus, Canada's mineral resources are sufficiently extensive to allow considerable expansion of its non-fuel mineral industry, during the remaining part of this century and possibly beyond (1, 2). The availability of sufficient capital will be one of the critical factors which will determine whether this potential will be fulfilled. The following analysis centers on the capital requirements of the Canadian non-fuel mineral industry under one set of basic assumptions of capacity growth, cost of new and replacement capacity, rates of depletion and depreciation of mines and plant, and the cost of exploration and infrastructure. Mindful of the fact that exploration and development will not thrive in Canada unless a very positive approach is taken, the writers make no apologies for being "optimistic" about long-term production prospects. Furthermore, in the event that world demand does escalate as anticipated and the forecast realistically attainable levels of Canadian production are not reached, then Canada will not have reaped the full range of economic benefits available, and opportunities will have been lost. Projections for Canadian production between 1976 and 2000 are essentially based on the forecast published in the 1974 paper, "Towards a Mineral Policy for Canada - Opportunities for Choice (3), with some updating on the basis of recent developments.

Jan 1, 1977

By D. Ortiz, J. R. Frias, E. D. Mast, J. J. Fañas

Falconbridge Dominicana (Falcondo) has operated an integrated tpy nickel laterite mine and ferro-nickel processing plant since 1972 in the Dominican Republic. The operation includes mining, a processing plant, an oil refinery, and a power plant. Falcondo has improved process efficiency over the years via modernisation and better understanding of the process. The present business environment of high fuel prices and high nickel prices present a challenge and an opportunity to Falcondo's operation. This paper gives an update of Falcondo's process, improvements in energy consumption, factors affecting energy consumption and how Falcondo is facing up to the current business environment.

Jan 1, 2005

By J. D. Bosman, L. J. Gardner

"The Bushveld Complex is a large layered igneous intrusion, located in the northern parts of the Republic of South Africa. The complex hosts the largest known reserves of Platinum Group Metals in the world. On the western limb of the complex, mining of the Merensky economic horizon and UG2 chromitite layer has been conducted for many years by several mining companies, including Impala Platinum Limited. Over the past decade, Impala has planned a new generation of greenfield vertical shafts, commencing with comprehensive geological and geotechnical studies. As part of the geotechnical studies, numerous tests have been conducted to quantify the mechanical properties of the various near-reef rock types. These tests include point load tests conducted in the field, as well as uni-axial compressive strength, triaxial compressive strength, and Brazilian disc tensile strength tests conducted in specialist laboratories. The authors have compiled an extensive database containing a large number of tests for different rock types, ranging from felsic Anorthosite to mafic Pegmatoid. The database was analysed to quantify the mechanical properties and values for Mohr Coulomb and Hoek Brown failure criteria for each rock type typically exposed by mining. The paper will provide a data set of rock mechanical properties typically used in numerical modelling and other design processes. Using the significant number of tests available, data describing the variability of the various parameters will be included."

Jan 1, 2015

By J. A. du Plessis, C. Dorfling

Selenium, tellurium and other precious metals (OPMs, namely Rh, Ru and Ir) dissolve in the final leaching stage of base metal refineries. Se and Te are typically removed from the copper sulphate leach solution by precipitation with sulphurous acid. Recovery of dissolved OPMs is desirable because it will reduce OPM inventory and losses. Thiourea is an effective OPM precipitation reagent, but yields insufficient Te removal. Copper is known to enhance Te precipitation when using sulphurous acid as precipitation reagent. The primary objective of this project was to evaluate whether simultaneous precipitation of Se, Te and OPMs using thiourea with metallic copper as precipitation reagents is possible. Batch precipitation tests were performed to evaluate the effect of temperature (50 – 70°C), thiourea addition (160 – 430% excess) and copper addition (2 – 8 g/L) on Se, Te and OPM precipitation. Increasing the temperature from 50°C to 70°C resulted in an average increase of 55.6 percentage points for Se precipitation and 13.5 – 23.5 percentage points for OPM precipitation. The copper addition did not have a significant impact on the precipitation behaviour. Increasing the thiourea addition increased the precipitation of Se and Te, especially when the copper addition was low; Rh and Ru precipitation also increased with up to 10 and 12 percentage points, respectively. Despite these observations, the precipitation of Se was significantly faster when no thiourea was added. It is not currently clear why thiourea appears to inhibit the Se precipitation by reaction with metallic copper. In general, Te precipitation was low (less than 30%) at the conditions investigated. Simultaneous precipitation of Se, Te and OPMs at temperatures below 80°C does not appear to be a viable option; a multiple stage operation for sequential removal of Se and Te with copper followed by OPM precipitation with thiourea would be required.

Jan 1, 2016

By George W. Bain

The area in Quebec immediately north of the Ottawa river is underlain by a large area of granite gneiss intruded in lit-par-lit fashion into Grenville sediments and low silica intrusives of the Buckingham Series. This complex of metamorphic rocks is intruded by a much later magma found, chiefly, as a very large stock about 20 miles in diameter and extending from Brownsburg to Grenville, and as dykes and small outliers at various places adjacent to its outer margin. 1A similar stock at Rigaud, Quebec, is situated south of the Ottawa river and has been described by O. E. Le Roy. The earliest representatives of the later magma are a series of granodiorite dykes characterized by abundant hornblende, along with primary magnetite and subordinate sulphides scattered as roundish grains through anorthoclase and aligoclase feldspars and subordinate quartz. The rock is found as narrow dykes and shows no prominent secondary structures, either in the field or in thin sections under the microscope.

Jan 1, 1926

By J. N. Van der Merwe, M. Mathey

"We present an analysis of the mechanical properties of coal specimens from various coalfields and seams in South Africa. Our database comprises of 1800 test results from uniaxial and triaxial compression tests, as well as indirect tensile strength tests, which we collected from the various mining houses and research agencies in the country. We inspected the database for possible errors and present a brief description of the verification procedure in the paper.In the analysis, we reveal that the collected samples of strength and elastic properties of South African coals can be represented by single lognormal or normal distributions with only few outliers. This finding indicates that the samples realistically approximate the population of mechanical coal properties in the country and may suggest that the properties are randomly distributed. Significant coalfield- or seamspecific trends for the mechanical properties of coal are not clearly discernible from our data.Typical coefficients of variation for the individual mechanical properties range between 25-50 % on a country-wide and seam-specific level of analysis. Average uniaxial compressive strength values, however, are closely clustered for all seams. A comparison with data available from international coal strength studies show the distinct difference between South African coals and seams in countries of the Northern Hemisphere, where differences in the average coal seam strength are more pronounced.We observe that the number of specimens whose failure mode is influenced by the presence of natural discontinuities reduces drastically with the application of very small confining pressures to the specimens. Further, the strength-reducing influence of discontinuities diminishes with increasing confining pressures."

Jan 1, 2015

By R. Khettabi

The mechanical, thermal and bioproperties of titanium alloys allow their wide use in different industries. Compared to aluminum alloys, titanium alloys are very tough, making them that much more difficult to machine than aluminum alloys. Most studies conducted on these types of materials have mainly covered and made comparisons in terms of cutting speed, cutting force and mechanical properties. Recently however, their sustainability and environment parameters have begun to attract significant interest, and it has been found that machining processes generate particles that can be harmful for health and the environment. In this paper, particle emission is investigated during the turning of the titanium Ti6A14V and 6061-T6 aluminum alloys.

Jan 1, 2011

Surfaces forces have been measured between gold sphere and gold-coated glass plate in xanthate solutions using an atomic force microscope (AFM). The measurements conducted in potassium amyl xanthate (PAX) and potassium ethyl xanthate (KEX) solutions showed long-range hydrophobic forces, with the force curves showing no evidence for nanonubbles on the surface. The strongest hydrophobic force was measured at contact angle of 94° with a decay length of 23 nm. The hydrophobic force became weaker at higher concentrations and after a long immersion time, which may be attributed to the xanthate species adsorbed on top of the first mono layer. The hydrophobic force became stronger when the residual xanthate solution is displaced by pure water, indicating that hydrophobic force becomes the strongest in pure water.

Jan 1, 2009

By H. Al-Kazzaz

The 2-mm butt joints of ZE41A-T5 sand castings were laser welded using 1.6 mm EZ33A-T5 filler wire and a continuous wave Nd:YAG system at a power of 4 kW, surface defocusing and various welding speeds, Compared with the base metal, the fusion zone showed significant grain refinement due to high cooling rate, No grain coarsening was observed in the heat affected zone (HAZ). The porosity area percentage and total solidification crack length in the fusion zone (FZ) were reduced as the welding speed increased from 4 to 7 m/min, Fusion zone area, total penetration depth, and weld width decreased with increased welding speed, The hardness in the FZ was similar to or higher than the base metal after a natural aging of about one year, but there was a drop in the hardness of the HAZ, The HAZ width decreased with increasing the welding speed, Tensile test showed that a joint efficiency of approximately 75 ? 90 % was obtained.

Jan 1, 2005

By A. S. MacNeil

In the operation of any colliery, a factor of prime importance is power, of which there are three sources available--man, horse, and mechanical. It is obvious that man-power is by far the most expensive, .and that animal-power, also, is more costly than mechanical. In recognition of this fact, mine owners must, for economical ?reasons, reduce the use of man-and horse-power to the minimum by the increased use of machinery. In other words, they must aim at as complete mechanization as conditions will permit, taking advantage of existing physical factors that are favourable and making the necessary adjustments and modifications to meet the less favourable conditions. Intensive coal-mining, or the concentrated production of coal, has two distinct objectives: First, the maximum production from a limited area, in a given time, thereby reducing the pit-room to be maintained; and second, reduction in cost. To this end the coal should be mined, loaded and delivered to the surface by mechanical means wherever possible. To do this, however, requires the solution of many problems arising out of the varying conditions that obtain underground. The system of longwall mining lends itself to a more efficient scheme of mechanization than does pillar-and-room, as, in the former, the first step has already been taken by the removal of all the coal in one operation, and the opening-out of one face, the equivalent in mining area of fifteen or more rooms. Much has been clone of late towards mechanization in the longwall mines of the Sydney coal-field, and with gratifying results, but not without great difficulties and frequent disappointments. In 1923, an attempt was made with shaker conveyors. The introduction of conveying was a step to bridge the gap between the face, where the coal is produced, and the main transportation arteries leading to the slope or shaft. The receiving of the coal at the faces and its delivery to main loading points on main haulage-ways was the part allotted to the conveyors.

Jan 1, 1932

By R. Burns, A. I. A. Salama, M. W. Mikhail

"Large amounts of oil sand tailings are produced in the Fort McMurray area, including sand, clays, and misplaced bitumen. The objective of the present study (as part of the overall engineered tailings program) is to select and evaluate the role of hydrocyclones in removing most of the solids from the tailings slurry and producing an underflow product containing about 75% solids.Multistage cyclones were evaluated in pilot plant tests. Slurry feeds with different percents solids and increasing ratios of superfines (–44 µm) were used in testing multistage cyclone circuits. A two-stage Linatex separator circuit gave high recovery to the underflow of 98.8% to 99.6% by mass with the desired high solids content in the underflow of 73% to 75% by mass. Changes in feed solids content (20% to 50%) had little or no influence on cyclone underflow recovery and solids content. The keys to achieving such results were the apex control mechanism and operation at relatively low feed pressure (<60 kPa for 23 cm F cyclone) when the feed solids content was high. Increasing superfines above 7% by mass in the feed resulted in a significant reduction in the recovery to the underflow, probably due to the heavy medium generated by excessive amounts of clays in the cyclone. Pilot plant results were better than those predicted by available cyclone simulation models in terms of recovery and solids concentration in the underflow.Increasing cyclone diameter from 23 cm for the Linatex separator to 51 cm for the Krebs cyclone appears to have little or no effect on size cutpoint."

Jan 1, 1997

By G. S. Hume

Dr. K. A. Clark: No one will doubt the statement of fact that, during drilling operations through the bituminous sand beds in the Mildred-Ruth Lakes area, the core-barrel was found to contain bitumen with minor amounts of sand instead of bituminous sand. But many will doubt the interpretation of this fact as meaning that beds of bitumen occur interstratified with the bituminous sand beds. They will prefer to hold faith in the laws of physics, which deny that sand will float on oil or that fluid under pressure will not flow away through a permeable medium, until it is proved that the appearance of the oil in the core-barrel was not due to circumstances surrounding the drilling of the bituminous sand beds. The implication of the interpretation that sand is floating on oil is clear and it is unacceptable. Bituminous sand is unconsolidated sand more&apos; or less saturated with a viscous oil. It is as difficult to conceive of bituminous sand lying on top of a body of the viscous oil as it is to conceive of unconsolidated sand more or less saturated with water lying on top of a body of water. The only difference between the two concepts is that the oil is viscous whereas the water is fluid. Oil-soaked sand placed on viscous oil would, when released, sink through the oil slowly, whereas water-soaked sand would sink through the water quickly.

Jan 1, 1947

By Edouard Asselin, Tasawar Javed

This study was conducted as a part of ongoing work to characterize sulphide concentrate leach residues generated under CESL (Cominco Engineering Services Limited) and Vale pilot and demonstration plant medium temperature (150 °C) process conditions. Three different samples were analyzed. Derivative samples were prepared by extracting gypsum, sulphur and amorphous/poorly crystalline iron oxyhydroxide phases from the leach residues. Thermal behavior of the samples was studied by thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) in the temperature range 25 to 800 °C in both air and nitrogen atmospheres, with XRD analyses both before and after heating. Thermal transformation temperatures for different iron oxides/oxyhydroxides present in hydrometallurgical leach residues vary over a wide range which suggests the variable crystallinity of the phases. Raman spectroscopic analysis was carried out to help identify the type of iron phases in the residues. Furthermore, hydroxylamine hydrochloride (HaHC) and oxalate extractions were used to compare the fractionation of the amorphous/poorly crystalline iron phases in the residues. Given the compositions of the residues, any thermal events in the temperature range of 200 °C to 480 °C were attributed to amorphous/poorly crystalline iron phases.

Jan 1, 2014

By \/eena Sahajwalla, Alexander Blagus

This paper reports the effect of using High Density Poly-Ethylene (HDPE)/coke blends on the reduction behaviour of Mn3O4 to MnO at 1000°C. The results suggest that CH4 release increases with increasing HDPE addition. The results show that the rapid release of methane, over only the initial five minutes, limited the interaction of Mn3O4/MnO with CH4. With the devolatilisation of HDPE there was increased porosity in samples containing HDPE, assumed to be the major factor in differences of reduction rates.

Jan 1, 2011

By R. B. Harkness

Many of us are familiar with the history of oil in the Province of Ontario, but for the benefit of those who have never heard the story I will repeat it. In 185 7 J. H. Williams, of Hamilton, an old-country Scotchman, who had the advantage of experience gained from the primitive methods used for refining the oil collected at seepages in Roumania, heard of the "gum beds" along Black creek in Enniskillen township, Lambton county. He erected a small plant in the bush and refined illuminating oil, where the village of Old Springs now stands. The labor of collecting this thick ?gummy substance from the sluggish water of the creek, prompted him to dig a well, the next year ( 1858), in the hope of obtaining a greater quantity. When his excavation reached a gravel bed on top of the rock, oil, resembling "lubricating oil of commerce", rose several feet. Several of these wells were dug and his refining business flourished. The following year the Drake well, in Pennsylvania, was drilled into rock, resulting in an oil find which encouraged one James Shaw to make a similar attempt on Black creek. With a spring-pole drill he completed his well in the spring of 1861 to a depth of 160 feet, and at that depth struck a gusher that flowed uncontrolled for several days. Great excitement followed and the village of Oil Springs had a mushroom growth. The Petrolia field was discovered in 1865. Lick followed up the Thames with a spring-pole rig testing the formations along that river and discovered the original Bothwell field in 1865. During the sixties wells were drilled in many counties in southwestern Ontario.

Jan 1, 1924

By J. Satur

In copper mineral processing, pyrite coexisting with copper sulfide minerals like chalcopyrite is separated by flotation as tailings and its oxidation in tailing dams causes the formation of acid mine drainage. This paper proposes carriermicroencapsulation (CME) as a new method for suppressing pyrite flotability, as well as its oxidation. In this method, an organic carrier combined with Ti is used to form a thin Ti02 layer on pyrite, which gives a hydrophilic property and acts as a protective coating against oxidation. To form the coating, a ground pyrite sample was treated with Ti-catechol complex solution under various conditions. Bubble pick-up experiments and flotation experiments showed that the treatment of pyrite with Ticatechol complex changed the hydrophobic nature of pyrite into hydrophilic even in the presence of xanthate as a flotation collector. Oxidation testing of the CME-treated pyrite by 0.02 kmol m-3 HN03 showed that Fe release was suppressed by the CME treatment with respect to the control. This is assumed to be due to the formation of Ti02 coating on the pyrite surface. The effect of CME treatment on chalcopyrite wettability is also discussed.

Jan 1, 2007

By M. E. Holter

"Three main potash members are recognized within the Prairie Evaporite Formation of Saskatchewan and have been designated, in ascending order, the Esterhazy, Belle Plaine and Patience Lake members. Each is composed of sylvinite near the geographic center of the member and becomes increasingly carnallitic marginally. Each stratigraphically higher member has a narrower carnallitic margin. The sharp contact between carnallitic and non-carnallitic components of the formation describes a surface which may be traced regionally and is not related to bed-ding. The contact rises higher in the stratigraphic section toward margins of members. Within each of the three members, analyses indicate that carnallite becomes more abundant toward the north whereas sylvite and insolubles, increase toward the south. Within each member, areas rich in carnallite are coincident with areas in which the member as a whole is thicker than averag,e. The Belle Plaine Member contains the highest concentrations of carnallite, the Esterhazy the lowest. A maximum content of about 30 per cent sylvite is common to all three members. Insoluble contents increase in successively higher members.Map studies are combined to outline the economic potential of the potash beds in terms of depth to the top of the Prairie Evaporite, ""salt-back"" thicknesses and sylvite grades for each member."

Jan 1, 1971

By F. Tanaka

Copper losses to discard slag have long impacted on the profitability of copper smelters. Businesses based on the treatment of secondary materials have also revealed that copper losses are indices of precious-metals losses. Many custom smelters are thus required to obtain more reliable controls for reducing copper losses than ever before. Mitsubishi Materials Corp. has cooperated with academic research institutes in conducting research projects on the pyrometallurgical fundamentals of copper smelting systems, including mutual evaluation of magnetite behavior between synthetic and industrial slags. The state-of-the-art pyrometallurgy has subsequently been introduced to Naoshima smelter for controlling the Mitsubishi process. The revised controls function successfully and the operational results demonstrate that avoiding the discharge of solid magnetite from the S-furnace is quite effective to reduce copper losses. Magnetite behavior has been controlled over the Mitsubishi process so as to reduce copper losses while satisfying the needs of recycling businesses growing in Japan. In-situ estimation of magnetite behavior using the absorbed heat from the melts to cooling water will also be discussed.

Jan 1, 2007

By Corby G. Anderson, Caelen D. Anderson, Patrick R. Taylor

"The United States contains a variety of domestic rare earth element mineral sources containing such as ancylite, bastnasite, monazite, and xenotime. Research has been performed to investigate the fundamental surface chemistry involved in the froth flotation of these minerals, and apply the knowledge gained to substantiate the results through experimental testwork on a domestically sourced rare earth ore. This paper will outline the fundamentals and literature of rare earth mineral flotation, review its industrial applications and provide some recent research updates.THE RARE EARTH ELEMENTSRare earth elements (REE’s) are a unique family of elements with nearly identical physical and chemical properties. They account for approximately 1/6th of all naturally occurring elements, but the entire group occupies only one position on the periodic table. These 15 elements make up the lanthanide series (atomic numbers 57–71), and all but one (promethium) occur naturally. In addition to these 15 elements, yttrium and scandium are also considered rare earths since they tend to occur in the same deposits as the rare earths and share similar physical and chemical properties as seen in Figure 1. In particular Figure 2 denotes, a cartoon of the subtle differences in each caused by the 4f atomic sub shell (Gschneidner Jr., 1964). These subtle differences result in very difficult challenges in the selective concentration and final separation of each rare earth. (Anderson, 2015, Kronholm, Anderson, Taylor, 2013)Rare earths are separated into two different subsections; the “lights” or LREE’s (lanthanum57 through europium63) and the “heavies” or HREE’s (gadolinium64 through lutetium71). Yttrium is generally considered a heavy rare earth since its ionic radius is close to that of the HREE’s, while scandium is not considered either a light or a heavy."

Jan 1, 2016

By S. Glen

Cyanide management practices on modern gold plants are becoming more onerous, due to environmental pressures, particularly for signatories to the International Cyanide Management Code. Operations are therefore seeking to reduce levels of weak-acid dissociable (WAD) cyanide reporting to spigot discharge as well as to any eventual discharges from the tailings storage facility (TSF). Current gold industry standard processes primarily include the oxidation of cyanide by means of sodium meta-bisulfite (SMBS, or SO2) with air, Caro&apos;s acid (H2SO5) or hydrogen peroxide (H2O2). These processes require the transport and usage of expensive oxidizing reagents, along with the safety and environmental issues associated with these corrosive and toxic chemicals. Maelgwyn Mineral Services (MMS) has developed the MMS CN-DTM process, which utilizes the Aachen ReactorTM, a high-energy mass-transfer superoxygenation system, in conjunction with an activated carbon-based catalyst and no additional reagents, to increase the rate of cyanide oxidation to cyanate, the thermodynamically more stable form. Testwork conducted at the Maelgwyn Australia testwork facility in Perth Australia is described, at both pilot scale and continuous bench-scale, on a sample of tailings effluent obtained from an Australian gold plant. WAD cyanide is demonstrated to be lowered using the MMS CN-DTM process from an influent of 130 mg/L to the required levels for discharge to TSF (<50 mg/L). The continuous test results showed stable operation over three residence time turnovers. The pilot-scale results demonstrated the efficiency of the process at the reasonably large scales required for engineering cost estimation.

Jan 1, 2011