Search Documents

By H Fukaya T Miki, J Gamutan

Molybdenum disilicide (MoSi2) is a promising material for thermal applications due to its excellent heat and oxidation resistance. It can operate at temperatures of up to 1800°C as furnace heating elements and protect refractory metals such as molybdenum from rapidly reacting with air to form volatile molybdenum oxides at elevated temperature. In this work, the feasibility of forming MoSi2 on a molybdenum substrate by hot dipping in a silicon-saturated molten metal bath was investigated. This method is simple, predictable and can be used to coat large components and complex parts. It was found that tetragonal MoSi2 can be successfully synthesised on the surface of the substrate after dipping for 15 mins at 1000°C using molten tin (Sn), bismuth (Bi) and copper (Cu) baths. The growth of the MoSi2 layer was fast within the first 15 mins and then gradually slowed down with time. After dipping for 60 mins at 1000°C, the thickness of the MoSi2 layer were measured as 441.5, 19.5 and 13.1 μm for the copper, tin, and bismuth baths, respectively. The MoSi2 coating synthesised in this study provided oxidation resistance at 1150°C by forming a protective SiO2 layer on the surface. The SiO2 layer prevented the sample from rapidly oxidising by inhibiting direct contact between the molybdenum substrate and oxygen in the atmosphere. Compared to conventional methods, the proposed hot dipping method produces a MoSi2 layer more rapidly and at much lower operating temperatures. This makes it a more attractive option for coating large and complex components, with the potential to enable the use of MoSi2 in a wider range of applications.

Jun 19, 2024

Largely inherited from the past and from strictly internal laboratory use, the certification of reference material using round-robin assaying is often insufficient for the use made today for external assay laboratory control by client parties. Certification often needs to be revisited on the basis of existing round-robin data, especially to derive reproducibility parameters to the end of establishing probabilistic performance gates for operational error detection on a batch per batch basis (ie batch-ærejectionÆ). The most common difficulty arises when only a few certification samples have been analysed in one single batch by each laboratory, so that the round-robin data do not contain the full variability that needs to be quantified. Existing certification data sets from properly submitted round-robin samples were studied using analysis of variance to derive a remedial method, leading to the proposal of default correction factors to restore full variability estimates when no other avenue is available.

Jan 1, 2008

By Cole RT

The cultural ages of man have been defined in terms of smelting and hence as a prerequisite, mining for example the iron age and the bronze age. There could be no separation of the man from his role as the technologist (miner/ smelter) for his early metal working efforts were to enhance survival. In the millenniums since, the artisan specialist developed and the technologist emerged. The process is a sort of technical natural selection. From the generalist hunter, gatherer, miner, metalworker we advanced over the centuries with great 'steps for mankind' to the series of specialists each largely intent on securing his/her technical functions from the curious assaults of other tribal members. The relevance of all this to the theme, 'Past, present and future of the Victorian mining and metallurgical industries', is simply that people have always, and will always, be the moving force in our industries. It is the effectiveness of people now and in the future that this paper addresses.

Jan 1, 1982

A career in the mining industry is both challenging and rewarding but comes with some unique complications. Few other industries have such a far reaching effect on individualsÆ lifestyles. Furthermore, few people working within the resource sector could say their job has had no effect on their lifestyle. Mineral deposits in Australia seem to exist predominantly in remote locations like Telfer, Mount Isa and Olympic Dam. With this comes a choice for young professionals; one that is not easy to make, with either alternative often having its pitfalls. This remote nature usually requires professionals (especially graduates and juniors) to choose between a fly-in, fly-out location or relocation to a remote town with less facilities (and some may argue attractions) than their coastal cousins. The challenge for young professionals is to pursue a career that will satisfy their professional goals while developing and maintaining away of life that is emotionally fulfilling.

Jan 1, 2005

During the 1960s chalcocite ore was mined from the Black Rock open cut. A large amount of this uneconomic material was not treated by the No 3 Concentrator at the time and as a consequence a surface stockpile was created which contained 750 000 tonnes of material at an average of 1.5 per cent copper.Laboratory trials indicated that due to oxidation, an average of 25 per cent of the copper was water soluble and the remaining copper was leachable using a sulphate/ferriclbacterial leach. On the basis of these trials it was decided to investigate the feasibility of producing copper via a leach SX-EW process. The investigation proved the process was feasible, so began the design, construction and commissioning of a 10 tpd (cathode copper) Copper Leach SX-EW Pilot Plant. CMPS Pty Limited in a joint venture with John Holland Engineering Pty Limited were awarded the turnkey contract for the design, construction and commissioning of the Pilot Plant.

Jan 1, 1993

The blasting of the 2190_6095 stope at Kimberley Nickel MineÆs Sally Malay operation in Western Australia is an example of what can be achieved with electronic detonating systems when a drill and blast engineering team is faced with complex blast geometry and a major pump station in close proximity to the stope. Using Dyno NobelÆs HotShotÖ system, the engineering team successfully designed and initiated the 36.5 Kt stope firing, with a powder factor of 0.35, resulting in no damage to the pump infrastructure, better fragmentation of the ore and less overbreak in what had previously been a geotechnical and geometrically challenging stoping environment. This paper will discuss the design parameters used for this stope blast as well as the benefits the operation found in using precision detonator timing in this 252 hole shot over two levels using a combination of up and down and slashing rings that were initiated in four different directions.

Jan 1, 2007

Ordovician metasedimenIs near the Karamea Bend and east of Ihe upper Carboniferous Karamea batholith were intruded by acidic stocks during the Cretaeeous. K/ Ar dating of two of the stocks gave 110 ± 3 millionyears whereas the batholith granite gave 290 8 ± million years. All but one of the stocks mapped lie on an approximately ENE line along which they show gradation in composition, texture, and alteration.Most of the intrusions have produced homfelsic haloes in the surrounding rocks but the hydrothermal alteration centred near the head of Questa Creek is quite distinct. Here much wider zones of alteration are characterised by chlorite, green biotite, sericite, and quartz-orthoclase in order towards the centre, though no stock crops out. Each zone of stronger alteration is heralded by "spots" containing the next characteristic mineral.It is suggested that a late phase of the intrusive period that gave rise to the outcropping stocks also gave rise to a volatile-rich intrusion still hidden beneath the head of Questa Creek.

Jan 1, 1976

All sections of our community are becoming increasingly aware of the dangers of uncontroll- ed erosion associated with modern earthworksy whether they be concerned with the protection of capital structures, reforestation of mine tailings or generally the aesthetic and ecol- ogical impact. Because of the many ecological variances and climatic conditions no single technique may be offered as the complete answer. Rather that a combination of a series of techniques is nec- essary to achieve an individual end result. These techniques may appear to be expensive initially, but when considered in relation to the overall cost, and we realise that this work represents our only insurance of the stability of our project, the cost of stabilisation is insignificant. Once erosion has commenced the cost of stabilisation escalates dramatically which highlights the definite need to include the requirement of stabilisation in early design of your projects. Stabilisation should commence during construction to ensure that control of mobile soils is gained at the earliest possible time.

Jan 1, 1976

The role played by lawyers in business has, in the course of the last 15 to 20 years, changed perceptively. This development has coincided with, and indeed has been a reflection of, the changing nature of Australian business, especially as the mining industry established its predominance in the Australian economy. The nature and extent of governmental regulation of business, too, has changed markedly. As a consequence, there has been a qualitative'change in the nature of commercial law practice. For the needs of business to be met, lawyers have had to develop specialist skills in new areas. Furthermore, there has been the emergence of the "in-house" lawyer, who increasingly plays a primary rather than a subordinate role in corporate law practice. There is no evidence to suggest that this trend, which is by now so well established, will prove to be ephemeral. Instead, with all indications pointing towards even greater governmental regulation of business activities, the intimate role of the lawyer in business seems entrenched.

Jan 1, 1980

The Mineral Resources Act 1989-90 came into force on 1 Septem- ber 1990 and the Second Schedule of this Act set out the Savings, Transitional and Validation Clauses to this legislation. The Second Schedule gave rise to a number of interesting situa- tions however due to the fact that the time set aside to attend to these matters (the prescribed period) has now expired, with the exception of the points raised below, most of these situations are now history and are of no relevance. The Transitional provisions of the Second Schedule provided for a three month "prescribed period" in which certain actions were required to be undertaken to ensure tenements granted or applied for under the repealed legislation transitioned into the framework provided by the Mineral Resources Act. This Second Schedule of the Mineral Resources Act highlighted a number of anomalies which are still worthy of mention and are listed below.

Jan 1, 1991

By Pollard D. M

The removal of nickel from lead by sulfur drossing was investigated using a technique which models industrial batch decoppering practice. Successful denickeling to 0.005% (Ni)pb was consistently obtained in the absence of silver, well below the experimental equilibrium value of 0.015% but still above levels obtained in industrial practice. Silver appeared to have little effect upon denickeling. The final nickel content was dependent upon the initial nickel content, the total sulfur addition and the stirring time. The presence of nickel was found to give no assistance to successful decoppering. Simul- taneous removal of nickel and copper was observed at silver contents in excess of 0.02%. Extended stirring resulted in a further lowering of the nickel content but reversion of copper to the bullion was observed. Experimental work has shown that nickel can be removed by a standard decoppering operation; a procedure which is used in secondary lead re- fining. Alternatively nickel can be removed during initial decoppering in primary lead re- fining operations.

Jan 1, 1987

By Canterford J. H, Bologiannis F, Smith A. N

The Mutooroo copper mine is one of a number of deposits that have been evaluated by Adelaide and Wallaroo Fertilizers Ltd as a source of feed for the production of high- purity copper oxide at their Burra plant. For this deposit, the technique of solution mining or in-situ leaching appeared ideal. The Mutooroo production circuit and the results of the process optimization and environmental monitoring programmes are outlined. At the end of the experimental period described here, the production liquor typically contained I g/litre copper, yield- ing in excess of 5 t/month of cement product containing about 80 per cent copper. The environmental monitoring programme provided clear evidence that there had been no un- acceptable alteration to the properties of the groundwater in the country rock surround- ing the mineralized zone. It is anticipated that the experience gained at Mutooroo will be of considerable help in the development of other solution mining operations.

Jan 1, 1983

By Mansor A. N

Results are reported for the computer simulation of heap leaching of mixed copper oxide and sulphide ores. They resemble those obtained from testwork in terms of a substantial peak in the copper concentration of the pregnant solution, an initial period when no copper emerges and a lengthy period towards the end when the copper concentration and the daily increment in copper recovery are low. The simulation can be used to forecast process results before any column or similar testwork is performed. Potential applications of the simulation to process design, operating strategy and optimisation are discussed. Three modes of operation are identified that correspond to different performance patterns and dependencies on ore and process variables. The relative merits of different operating strategies for approaching the ideal performance are being investigated. For process design and development purposes, the simulation may be used with a limited testwork programme to achieve significant savings in time and resources.

Jan 1, 1989

By Rashad MZ

The evaluation of ore deposits consumes much effort, cost and time, hence research work must aim to minimize these inputs with no loss of accuracy. The present study is devoted to assess the optimum conditions and methods of calculations which give minimum costs of ore exploration. An area of (a x a) where "a" is the zone of influence of the semi-variogram, i.e. (2800 x 2800 square metres) located within the Abu Tartur plateau is the subject of the intensive study. The distances between boreholes are varied ie. a/4, a/6, a/8 and a/ 10 respectively. The average ore grade (G), thickness (t) and relative ore reserves (tG) are calculated by four methods. The results indicate that at a distance equal to a/5, the inverse distance squared method gives the best results. These parameters save about 50 percent of the cost of exploration with a map accuracy greater than 90 Percent.

Jan 1, 1987

This paper discusses a number of examples of how environmental factors have been incorporated into the water management aspects of mining projects. One example is the Kingston Lignite Project in the South-East of South Australia where the most significant environmental issue was considered to be the effect of drawdown from mine dewatering and depressurization upon the use of groundwater. By proposing an alternative mining method - the use of floating dredges rather than a two-pass dragline method - drawdown effects would no longer be a concern. A second example is the Pine Creek Gold Mine in the Northern Territory. In this case the principal area of interest from an environmental viewpoint was water management - in particular effluent disposal, contaminated seepage from overburden and tailings, and project water supply. Through an integrated approach to the management of wastes and water the potential for water quality impairment was significantly reduced and external water supply requirements were also significantly reduced.

Jan 1, 1987

The Vertical Crater Retreat (VCR) mining method was used to mine two rib pillars at New Broken Hill Consolidated Limited (NEHC) mine at Broken Hill. Experience gained in a trial VCR pillar stope was applied to the design of Panel 3CN pillar (P3CN). Restricted access and a central sandfilled plug in this pillar necessitated the use of angled blastholes and blasting of the stope in two sections. Borehole surveys and close charging supervision were necessary to block, charge and stem the spherical charges in the correct position. The laver sections of the VCR stope with rock walls attained an average slice advance of 2.2 m whereas the higher section of the st.ope between cemented fill walls attained an average slice advance of 3.4 m. Achieved fragmentation was extremely fine. External dilution was assessed at less than 10 per cent. A cement consolidated sandfill exposure of approximately 1300 m2 stood vertically with no significant slumping.

Jan 1, 1983

By S Latchireddi

Close circuiting autogenous and semi-autogenous mills is anenergy efficient way of grinding and a number of operations haveutilised this in the design of their comminution circuits. Owing tothe large flow of slurry through the mill that results fromoperating this way the grates and pulp lifters have to be designedto cope. However, the literature has little or no information onhow grate and pulp lifter size and design are related to theirability to remove slurry from the mill. Over the last few years theJKMRC has been researching this area and has developedrelationships between grate/pulp lifter design and flowratecapacity. At the same time it has determined the major causes ofpulp lifter inefficiency and a solution to preventing thisinefficiency (the Twin Chamber Pulp Lifter). This paperdescribes the models that have been developed through thisprogram and uses industrial scale data to illustrate their accuracy.Results from the industrial trials of the Twin Chamber PulpLifter are also presented.

Jan 1, 2001

By Cunningham CG

Many epithermal gold-silver deposits areknown to occur in the Neogene-Quaternary volcanic complex of the central Andean region of southern Peru, northern Chile, western Bolivia, and north-western Argentina, an area of about 300,000 km2 where these volcanic rocks constitute the dominant cover. Some of the gold-silver deposits were mined during Spanish colonial times, as early as the 16th century,- whereas others were not discovered until the 19th and 20th centuries. The extraordinary gold-silver potential of this young volcanic complex, however, was not recognized until the 1970's when the phenomenal increase in gold and silver prices stimulated new exploration. New discoveries were made, chiefly in southern Peru and northern Chile, of high-grade ores in old mining districts and large low-grade ore bodies, both in old districts and in new areas having no history of mining activity. Many additional gold and silver deposits remain to be discovered within and beneath the young volcanic complex of this region.

Jan 1, 1990

By Donchak P. J, Champion D. C, Fordham B. G, Domagala J

The Hodgkinson Province forms the northern part of the Tasman Orogen and contains the most extensive outcrops of Silurian - Devonian rocks in Queensland. Deep-water, marine siliciclastic sequences (mainly turbidites) dominate most of the province except near the western margin where mafic volcanics and fossiliferous limestones characterise much of the succession. It is difficult to apply normal stratigraphic mapping techniques to the Hodgkinson Province because of extensive stratal disruption by numerous thrust faults, the general lack of stratigraphic and structural markers, and the unfossiliferous nature of much of the succession. Nevertheless, several distinct units have been delineated although their internal stratigraphy or boundary or superpositional relationships are uncertain. Ordovician strata, as well as two major unconformities have been recognised in the western part of the province. Several models have been proposed to explain the evolution of the Hodgkinson Province. Although there is no general agreement most recent researchers favour an extensional tectonic regime.

Jan 1, 1990

By Dhawan AK

On 8 July 1993, a landslide of about one million cubic metres of rock blocked the river Satluj near Sanjay Vidyut Pariyojana - Bhaba project and caused flooding into the Bhaba Power House (120 MW) resulting in suspension of power generation. The concerned authorities desired an early removal of the blockade by an underwater blasting operation into the over topping water to reduce the water level at the blockade and resume power generation in the power house. In the absence of underwater drilling, it was essential for the blasting technique to be used where no cavity to confine the explosive was required. For this reason mud capping and plaster shooting with directional throw were used and additional specially fabricated mild steel pipe charges were used under high current for an underwater trenching operation. By employing these techniques the river blockade was removed up to the required depth and on 8 September 1993 the Power House resumed the power generation.

Jan 1, 1995