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By R T. A MacGillivray, S B. Curtis

Bacteriophage (phage) are viruses that infect bacteria. Protein coatings on the surface of the phage particle can be genetically engineered so that they bind to inorganic molecules. The filamentous phage particle is about 930 nanometres in length and 6.5 nanometres in diameter and consists of a single-stranded molecule of DNA surrounded by five different coat protein molecules denoted P3, P6, P7, P8 and P9. Peptide sequences in the P3 coat protein that bind to sphalerite and chalcopyrite have been identified. The binding is selective; phage with specific P3 peptide sequences bind to minerals but do not bind to silica or to pyrite. Two peptide sequences in the P8 coat protein that bind selectively to chalcopyrite and pyrite have also been identified. The amino acids in the P8 binding sequences are hydrophilic and thus a coating of a mineral particle with phage having these peptide sequences may render the particle hydrophilic. Experiments are underway to confirm this. Phage are relatively easy to grow and are not living organisms requiring an energy source to maintain life. Phage can also tolerate a range of pH and temperatures. Given this, and the ability to indentify phage coat proteins that bind selectively to a variety of inorganic molecules, phage have the potential to be useful tools in mineral processing and waste treatment.

Jan 1, 2008

By M S. Cassola

It’s expected that the world economy will face a stable and continuous growth in the demand of iron ore, reaching more than two billion tonnes per year within the next year. After decades exploiting resources with high content of iron ore, now the industry faces the challenge to exploit and beneficiate more complex ores.According to the industrial practice, the flotation technology is one of the most important and effective beneficiation processes to deal with low-grade iron ores around the world. However, even with this, it is still necessary to search for new processing routes or promote the optimisation of the existing circuits.The broad application of this technology is an outcome that deeply relies on the proper selection of flotation chemicals specifi cally designed for each system. New collectors are in continuous development as flotation performance significantly relies upon their optimisation.The reverse iron ore flotation in Brazil, mainly constituted by haematite and quartz, uses ether amines as collector for silica minerals and caustic corn starch as depressor for haematite. The process selectivity is highly impacted by the features of the etheramine, such as:• mono or di-etheramine,• neutralisation degree,• chain length,• branched or linear chain,• the flotation pH, and• the size distribution of the flotation feed.This paper describes the experience obtained from laboratory and industrial trials on different ores, conducted to improve the selectivity and recovery in the reverse iron ore flotation by selecting the required collector for low-grade ores.

Jul 11, 2011

By F Djukic, T Fisher, G Irving

Questionnaires were sent to 12 underground metalliferous mines in Queensland to enquire how these mines control diesel emissions from mobile diesel engines used underground. Where responses or controls were absent, discussion has been provided. A significant finding concerns secondary ventilation design rates. Some mines were designing ventilation rates to meet the superseded Mines Regulation Act of 1989 which required 0.04 m3/s/kW. The current Queensland Mining and Quarrying Safety and Health Regulation (2001) is risk based. In line with other jurisdictions, including New South Wales (NSW) and most Provinces in Canada, a minimum ventilation rate of 0.06 m3/s/kW is acceptable. However, this design ventilation rate will vary in practice depending on the diesel engines and controls. Dedicated ventilation engineers and technicians should be appointed to evaluate the effectiveness of the ventilation system. Personal exposure monitoring is required to confirm that exposure standards are not being exceeded. The primary control practice should be to reduce the emission at source. This can be ensured by purchasing low emission (Tier 2, Tier 3) equipment. In addition, the use of ultra low sulfur fuel (et al, 2002). Diesel fuel with a low aromatic content such as Eromanga diesel fuel will also mean employees are exposed to lower levels of poly-cyclic aromatic hydrocarbons. These controls should be carried out in parallel with good maintenance practices. Preventative maintenance should be programmed and emissions be routinely tested, including both gaseous and particulate pollutants and compared against defined criteria. According to McGinn, 2002, there are a number of fundamental tools necessary to carry out preventative maintenance. These are outlined in maintenance guidelines and best practices for diesel engines in underground mining produced for the Diesel Emissions Evaluation Program (DEEP). An effective diesel emission management system needs to be fully integrated within the Safety and Health Management System. These requirements are further discussed in this paper.

Jan 1, 2007

The Lane Cove Tunnel (LCT) is an important infrastructure link in New South Wales (NSW) and runs from the end of the Gore Hill Freeway at Artarmon at its eastern extremity, to the end of the M2 at North Ryde at its western extremity.  The LCT is 3.6 km long and generally consists of twin two/three lane unidirectional tunnels running largely under Epping Road from just east of Mowbray Road, west to the western end of the Gore Hill Freeway. The tunnel opened in early 2007. The presentation will provide a summary of the traffic and emission modelling performed for selected representative surface road sections in the vicinity of the Lane Cove Tunnel. An assessment of the predicted impact of vehicle emissions on ambient air quality in the corridor as a result of changed traffic conditions due to the tunnel opening will be presented. The traffic modelling and emission calculations were undertaken for the following two scenarios: Year 2006 û Lane Cove Tunnel no-build option, and Year 2006 û Lane Cove Tunnel build option. Vehicle emission calculations for the four main pollutants from vehicles: CO, VOC, NOx and PM10 on the surface roads in the vicinity of the Lane Cove Tunnel were performed using the predicted daily traffic for the two cases (no-build and build). The analyses indicated that the vehicle emissions for all pollutants are expected to significantly reduce in the corridor with the building of the Lane Cove Tunnel, including the areas in the vicinity of all tunnel portals, when compared to vehicle emissions for the no-build case.  As a result of the decreased vehicle emissions on the surface roads, the study concluded that the actual ambient air quality is expected to improve in the corridor including the tunnel portal areas after the Lane Cove Tunnel opening.

Jan 1, 2008

By P Holtham, R Dunne, D Stoll

Flash flotation is a process designed to remove coarse, liberated, fast floating minerals from hydrocyclone underflow. Irrespective of liberation, coarse particles would normally remain in a grinding circuit until they are reground fine enough to report to the hydrocyclone overflow. Additionally, minerals of high density also report to hydrocyclone underflow despite being fine in size and/or liberated because hydrocyclones separate on the characteristics of both particle size and density. Dense particles continually reporting to the hydrocyclone underflow can lead to over-grinding and the production of ultra fine particles. These particles exhibit slow flotation kinetics and thus are difficult to float in conventional flotation circuits. Therefore, removing coarse, liberated particles from the hydrocylcone underflow by flash flotation has the potential to improve recovery and can improve dewatering unit operations and reduce grinding costs.The impact on the overall performance of the flotation circuit by removing coarse, fast floating minerals prior to conventional flotation is not well understood. Ultimately, predicting the overall recovery improvement provides the justification for the installation of a flash flotation cell within the milling circuit. This paper will describe attempts to estimate flash flotation recovery improvements to the overall circuit using kinetic data from simplified batch cell flotation tests combined with limn-based modelling techniques.CITATION:Stoll, D, Dunne, R and Holtham, P, 2012. Modelling the impact of flash flotation from batch cell flotation tests using limn, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 179-184 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By J Manuel, L Lu

Increasing bed depth is one of the main options sinter plants consider to increase production, since it is an incremental improvement and less expensive compared with a new plant. To maximise the benefits of increased bed depth, correct blend design and plant operation is critical. This paper discusses test work conducted to show the effects of ore type and bed depth on sintering performance and the adjustments required in both fuel rate and lime addition depending on ore type. The differences in sinter plug macro and microstructure were also examined to show the effect of bed depth on ore assimilation and matrix formation. Finally, the benefits of blending ores to achieve the best sintering performance as bed depth increases is discussed.

Jan 1, 2007

By K G. Fleetwood

This paper proposes an approach to determine the influence of non-ideal detonation characteristics related to the charge diameter, explosive type and confinement conditions on the available shock energy of ANFO and a representative chemically-sensitised (gassed) emulsion. The proposed degrees of non-ideality of the two different blasting agents are indicated by the Gurney ratios, determined from existing cylinder expansion testing data. The influence of the non-ideal detonation properties on blast design and performance are also compared using a series of theoretical, equal powder factor open pit blasting patterns with hole diameters ranging from 102 mm to 270 mm. The non-ideal shock energy factor (NSEF), which is the available shock energy per tonne of blasted material (MJ/t), is used to compare the different blasting patterns as charged with either ANFO or the gassed emulsion of equal charge density (0.85 g/cm3). The intended purpose of this investigation is to provide explosive users with an approach to compare different explosive types or charge diameters in the absence of dedicated non-ideal detonation modelling, which is generally not available to explosives users.The results of the comparisons suggest that at low charge densities, the example gassed emulsion displays a higher velocity of detonation (VOD) than ANFO in smaller charge diameters but similar degrees of non-ideality (based on proposed Gurney ratios). The results also suggest that the confined, non-ideal gassed emulsion VOD at hole diameters greater than 270 mm can be less than ANFO due to the low density effects on the emulsion matrix. The differences in non-ideal detonation properties and Gurney ratios between the ANFO and gassed emulsion resulted in gassed emulsion NSEF values ranging from 15 per cent lower to 65 per cent higher than ANFO for equal powder-factor patterns in blasthole diameters from 102 mm to 270 mm.

Nov 8, 2011

By I M. Platten

Narrow reef gold deposits are generally less than 4 m in width and relatively complex geological phenomena. They often display variable geometry, attitude, continuity and internal architecture. Economic grades are mostly restricted to specific structural domain(s) and localised within discrete ore shoots that have a nuggety internal grade distribution. On account of the often extended history of geological events, the specific factors localising gold-rich domains are likely to be unique to a particular mine or even reef. These features lead to a high resource risk and require careful management during both evaluation and mining. The gross form, location and global continuity of gold reefs can generally be determined from surface diamond drilling leading to the definition of Inferred Mineral Resources. It is likely that for the definition of Indicated and Measured Mineral Resources underground development and/or close- spaced diamond drilling will be required. Understanding geometry and continuity permits the resource to be more effectively managed, lowering risk/uncertainty. This in turn will allow for well-informed financial and operational decisions. Most importantly, project expectations and milestones can be set at achievable levels.

Jan 1, 2008

Tunnels are being built around the world using TBMs and prefabricated segments or in situ concrete as linings. Clients demand high quality of these linings to guarantee a long-term stability and density of the tunnels. This paper describes the development and the use of segmental lining systems, including joints, important design criteria, installation procedures, possible mistakes and consequences, repair works and final results for different sites in Europe and around the world. The experience on these sites shows that damages may occur, if some essential aspects are not considered. These aspects include:parameters of the TBMs and back-up equipment such as fixation of jacking rams, movement of the back-up on the lining or ring reformer;parameters of the segments such as quality of moulds, quantity of reinforcement or structure of the joints; andparameters of the tunnel drive such as advance rate, ring-gap grouting or experience of the tunnel crew.All these aspects have to be considered very carefully in detail to get a good lining accepted in total.

Jan 1, 1999

By Morgan B. D

Since the mid 1950s, limonite deposits of a new type have been found in the northwest of Western Australia. The deposits consist of extensive fossil valley fillings up to several hundred feet in depth, of medium to high grade limonite, frequently containing limonitized fossil wood, and of Mesozoic or Tertiary age. The distribution of the deposits is closely linked with hilly outcrops of Archaean and Proterozoic jaspilite in the headwaters of the old valleys, from which the iron has been derived by leaching, and presumably re-precipitated by a process not unlike that which operates in forming bog iron deposits. Due to the relative resistance of tlie limonite to erosion, the rejuvenation of streams in the area in recent times has left limonitic remnants as mesas up to· several hundred feet above the levels of the present creeks, the courses of which generally are adjacent to or within a few miles of those of the old limonite filled valleys.The Robe River limonite deposits are the largest of this type known and can be traced for approximately 130 miles along the old stream, over 30 sq. miles of limonite remnants remaining at the present time.The present quantity of limonite in this system alone is probably in excess of 5,000,000,000 tons, and the original quantity must have exceeded four times this tonnage when allowance is made for erosion.Some thousands of millions of tons of this material contain in excess of 54 per cent Fe, with approximately 10 per cent combined water. The chief impurities are SiO2 and Al2O3, and minor elements are not present in objectionable amounts. A portion of these deposits was extensively tested by The Broken Hill Proprietary Company Limited (the B.H.P. Co. Ltd.) during 1962-1964. Most of the data presented in this paper are based on the work done on these deposits which are typical of those discussed. The overall problem of the origin of the limonite is discussed. It is apparent that the limonite originates from the jaspilitesof Archaean and Proterozoic age which form the highlands at the upstream ends of the deposits. The iron oxide has been chemically and/or mechanically derived from these jaspilites and deposited by one or more of the following mechanisms.A.-Chemical-sedimentary mainly by biological agenciesB.-Replacement of fluviatile sediments by iron-charged watersC.-Clastic sedimentary processesD.-Lateritization of fluviatile sediments.These various mechanisms are discussed; the authors favour machanismA.Manuscript received' at The Institute, 14th July, 1964.

Jan 1, 1964

By G E. Holt

Active EM subsurface imaging is a proprietary technique developed by Marschall Acoustics Instruments Pty Limited (MAI) to image subsurface features at depths useful for the mining industry. Similar in field operations to high resolution seismic surveying, the Active EM technique employs electromagnetic energy rather than elastic wave energy. Received backscattered energy in the Active EM technique is thus due to differences and contrasts in electromagnetic permeability and permittivity in the subsurface, analogous to LamTÆs constants in elastic wave imaging. Carrying the analogy to seismic imaging even further, the Active EM method employs high power transmissions of very wide-band coded signals of a controlled polarisation. Likewise, the array pattern and polarisation of the receiving transducers is also tightly controlled. Thus, in a certain mathematical sense, Active EM is the electromagnetic equivalent of high power high resolution vibroseis seismic surveying. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By R Schlueter, H Mischo

The mining industry is facing a variety of geological, technological and social challenges. Future deposits show a general tendency towards increasing depth with complex ores and decreasing grades. One promising approach to deal with low-grade ores is bioleaching in the form of heap and dump operations. Bioleaching is already a state-of-the-art technique, especially for the extraction of copper from sulfide ores. The next step in the development of this technology will be its application as an in situ technology. First attempts to adapt this technology in underground mining in the form of stoping and block caving have already been made. Both methods have to be carried out adjacent to conventional mining operations and therefore require much effort regarding drift development as well as extraction and transport. The adaption of bioleaching as a borehole mining method is the next step to establish an innovative in situ technique to meet future challenges.The Freiberg University of Mining and Technology established the Biohydrometallurgical Centre for Strategic Elements (BHMZ) to foster interdisciplinary research along the whole biohydrometallurgical process chain. In general, 13 different university institutes and several associated groups with about 30 PhD students are mainly focusing on the extraction of indium and germanium from deposits, tailings and recycling material. One of the core projects within the BHMZ is the design and implementation of an underground in situ bioleaching testing facility.This paper demonstrates the potential of in situ bioleaching under technological aspects. Furthermore, different conditioning methods to increase the permeability of the orebody will be explained, and the BHMZ’s underground testing facility will be presented.CITATION:Schlueter, R and Mischo, H, 2015. Potential and applications of underground in situ bioleaching, in Proceedings Third International Future Mining Conference, pp 205–212 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By A Calderon, J Harris, M Shi, D Viswanathan, C Ribeiro Duthie, P A. Kirsch

Mineral resource development activities impact the health and well-being of many people, from workers, to families and surrounding communities. In the current environment of corporate social responsibility life-of-mine planning considers that mining activities should be conducted in the best environmentally, socially and economically acceptable way for the entire life of the mine (ie from exploration to decommissioning and closure). In this context, the health impacts of mining extend throughout the life of the community from worker injury and chronic exposure to communicable and non-communicable causes of illness, through to family and community health and well-being. At the inaugural Life-of-Mine conference in July 2012, the authors proposed the life-of-mine in the life-of-community (LOMLOC) matrix as a framework for understanding issues at the interface between resource extraction operations and the surrounding environment.This paper reviews and compares health activities extracted from social and environmental reports published by selected major mining companies with American operations in Canada, Colombia and Brazil. These corporate approaches to public health management are mapped to the LOMLOC matrix to identify and compare trends and behaviour in corporate health investments. This analysis of how companies approach and prioritise health issues in the context of different regions, cultures and environmental drivers will serve as a resource for minerals industry managers, civil society and regulators regarding current health management approaches in this sector.CITATION:Ribeiro Duthie, C, Calderon, A, Viswanathan, D, ?Shi, M, Harris, J and Kirsch, P A, ?2014. Resource company investments in health – a life-of-mine / life-of-community perspective across America, in Proceedings Life-of-Mine 2014 , pp 349–364 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

The Central West of New South Wales is emerging as a significant metallogenic province. The development of Northparkes Mines (North Limited) and the Cadia Hill deposit (Newcrest) are establishing NSW as a highly prospective porphyry copper-gold province. Exploration in the area has been further buoyed by the Ridgeway discovery by Newcrest near Cadia. The fact that the Ridgeway prospect was discovered 300 m below surface under Tertiary basalt cover indicates that surface prospecting can no longer be considered alone as an adequate method to find significant new deposits.

Jan 1, 1997

On the 17th November, 1964, a new No., 2 lead blast furnace was blown in at Port Pirie. The furnace departed from previous designs by incorporating a centrally located continuous tapper for both lead bullion and slag. The use of a central tapper permitted a simple and effective layout for the handling of both products. Considerable development was necessary to bring the furnace to its present level of efficiency. Units vital to the continu- ous operation were developed to allow quick replacement, thus ensuring high time efficiency under varied operating and maintenance conditions. The furnace was designed with the following objectives in mind, 1. increased crucible life, 2. elimination of oxygen for slag tapping, 3. higher temperature slag for fuming operations-, 4. less operator skill needed, 5. reduced tapping tool consumption, 6. elimination of settler skull and scrap lead, 7. better control of blast air distributi.nn. And

Jan 1, 1975

Mineral sands are different to almost any other commodity; however, it shares similarities with other commodity types, such as the importance of quality constraints of iron ore and coal or the importance of physical properties of diamonds. The mineral sands industry consists of two principal product streams; titanium dioxide minerals û in the form of rutile, ilmenite and leucoxene, and zircon. The principal valuable heavy minerals (VHM) include ilmenite, leucoxene, rutile and zircon. Variations of other titanium minerals occur between the end members of ilmenite and rutile, including pseudo rutile and anatase. Most mineral sands deposits are found in unconsolidated fossil shorelines several hundreds of metres to tens of kilometres and occasionally hundreds of kilometres inland from the present coastline. Mineral sands orebodies essentially fall into two categories based on the mode of deposition: alluvial or aeolian. Alluvial deposits are further split into marine beach placers (or strandlines) and lacustrine heavy mineral (HM) accumulations. Exploration for mineral sands involves the positive identification of key criteria leading to the focus of exploratory surface sampling, augering and drilling. Assaying is primarily focused around determining the percentage of HM contained within a given sample. Other results of interest include clay fines, sand and oversize. Metallurgical/mineralogical assessment is often undertaken via laboratory scale bench tests that replicate the wet concentration and dry mill processing routes. The most critical component in resource assessment for mineral sands is about quantifying HM grade, then mineralogical assemblage and then quality of those mineral species. This will determine whether a mineral sand final product is marketable or not. Mining of mineral sands is conducted either wet or dry. Wet methods are generally preferred for large tonnage, unconsolidated and low clay orebodies. Where ground conditions are hard and orebodies are small, high grade and discontinuous, dry mining techniques are generally employed. Concentration of mineral sands from the primary ore is carried out in two sections; wet, utilising sizing and gravity differentiation between HM, VHM, clay and quartz, and dry, exploiting the magnetic, electrostatic and to a lesser extent specific gravity (SG) properties of the minerals of interest. Mineral sands exploration, mining and processing faces the same operating challenges as the rest of the resource sector. Added to this are the issues that are unique to mineral sands and to which the industry devotes considerable resources to developing solutions.

Jan 1, 2009

Various aspects concerning gold are mentioned below. These have no common theme but suggest points of interest any one of which, if warranted, could lead to development later and elsewhere. 'High level' auriferous gravels The gold deposits of Victoria are commonly classified as being either primary or secondary. Most primary occurrences comprise gold present in quartz reefs, together with other lode-like occurrences in which gold is associated with various sulphides, with or without quartz. Secondary occurrences are derived by physical release of primary gold and subsequent concen- tration of it as a constituent of sediments. Secondary gold deposits may be themselves eroded so leading to third or even fourth generation gold.

Jan 1, 1982

By A Nugraha, H Thanasekaran, K Tatetdagat

The Kanowna Belle gold mine is located in the Eastern Goldfields of Western Australia, approximately 18 km north-east of Kalgoorlie. The processing plant is designed to process 2 Mt/y and has the capability to treat both refractory and free milling ore from the Kanowna Belle and Kundana mining operations.The Kanowna Belle ore is refractory with the gold mineralisation occurring mostly as fine-grained inclusions in pyrite or as very fine-grained gold located in pyritic arsenic rich growth zones. The Kanowna Belle refractory process includes flotation, roasting of the flotation concentrate, and calcine leaching to extract the gold from the ore.Mineralogical analysis of feed and tailings streams from the flotation circuit have shown that the gold bearing minerals are well liberated and confirmed they are mainly associated with pyrite. Nearly 40% of the flotation circuit losses are in the -38 µm size fraction. To improve the flotation circuit recovery, the fine particle gold recovery was targeted. A Cavitation Tube column was selected for the site-based pilot test work program. This paper presents data generated from the on-site test work, and the benefits of the Cavitation Tube column to improve fine particle flotation.CITATION:Nugraha, A, Tatetdagat, K and Thanasekaran, H, 2018. Flotation circuit efficiency improvement at Northern Star Resources Limited’s Kanowna Belle gold mine, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 403–412 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By J Joy, A Bye, G V. Kizil

This paper presents an application of the newly developed risk-cost-benefit (RCB) framework to support risk management decisions for the selection of wall monitoring technologies at an open cut mine site. The RCB framework quantitatively assessed the risk of unstable slope-induced wall failure and its impact on both loss of life and coal recovery. The RCB framework was utilised in the selection of an optimum group of risk-controls to effectively manage the risk of wall failure to ensure safety and optimal production occurred. The RCB framework incorporates mathematical modules that integrated RCB calculations and risk-control effectiveness assessments to determine the risk reduction and financial impact of the examined safety initiatives.This paper provides an overview of the five-staged RCB framework, incorporating the RCB decision support tools, RCBGEN (Risk-Cost-Benefit Generator) and RCEMETHOD (Risk-Control Effectiveness Method), and demonstrates its application to slope stability risk management at the case study site. The RCB charts are designed to display a balance between risk, cost and benefit for easy interpretation by decision makers to support the objective selection of an optimum suite of risk-controls. The RCB analysis revealed that a combination of ævisual inspections, automatic extensometers and radarÆ for fast- and slow-wall failures with structure were sufficient to reduce the probability of loss of life (PLoL) to the æModerateÆ zone as defined by the Australian Geomechanics Society (AGS, 2007) for the case study site. The new framework presented in this paper provides a method to effectively determine the suitability of risk-controls and supports industry efforts to reduce risk to as low as reasonably practicable (ALARP).CITATION:Kizil, G V, Bye, A and Joy, J, 2012. Risk-cost-benefit analysis of early warning technologies impact for wall failure risk management in surface mines, in Proceedings Eighth Open Pit OperatorsÆ Conference , pp 55-64 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 18, 2012

By Mingmin Dou

The behaviour and deportment of indium during the precipitation of sodium jarosite from Fe2(S04)3 - Na2SO4 solutions were investigated. Indium is readily precipitated with sodium jarosite, and the extent of In precipitation increases as the In concentration of the solution increases. It was shown that In 3+ substitutes for Fe 3+ in the jarosite structure to form a nearly ideal solid solution series. On a molar basis, the precipitation of Fe is slightly favoured over that of In, and the difference is reduced as the pH increases. Sodium jarosite precipitation becomes kinetically rapid at temperatures >70¦C, but increasing temperatures in the range 70 to 150¦C affect neither the relative precipitation of In and Fe nor the composition of the jarosite product. Low Na2SO4 concentrations result in reduced product yields and jarosite precipitates in which H3O' > Na+. The hydronium-rich precipitates have reduced In contents. Increasing the ZnSO4 concentration of the solution slightly increases the quantity of jarosite formed and results in the incorporation of -0.3 per cent Zn in the jarosite structure. Otherwise, the presence of ZnSO4 has no significant effect on the composition of the jarosite. Seeding accelerates the rate of jarosite precipitation but has a negligible influence on the deportment of In. The jarosite precipitation reaction at 98¦C is relatively rapid and near-steady state conditions are achieved in - 6 h even in the absence of seed. The initially precipitated jarosite is slightly enriched in In with respect to Fe. The ferric ion concentration of the solution has a significant influence on both the amount of jarosite formed and its composition. In particular, the jarosites precipitated from dilute Fe3+ media have significantly enhanced In contents. Hence, it may be possible to recover - 25 per cent of the dissolved In, at the 1000 mg/L level, in a jarosite precipitate assaying - ten per cent In by the controlled oxidation-precipitation of sodium jarosite from a ferrous sulphate processing solution.

Jan 1, 1993