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By Mery-Cecilia Gómez-Marroquín

O presente trabalho trata da formação da ferrita de zinco a partir da mistura e posterior reação solido-solido entre o óxido de zinco e óxido de ferro - Fe2O3 puros em proporções equimolares. A faixa de temperatura onde teve lugar a formação foi entre 1073 e 1373 K. Testes de redução da ferrita de zinco sintética-ZF e pós de aciaria elétrica–EAFD foram realizadas usando misturas de CO e CO2 que variaram entre 50 e 100% CO. Ambos os testes (formação e redução de ZF e EAFD) foram suportados usando técnicas de caracterização física, química, estrutural e microscópica. No caso da redução, foi observado que tanto a temperatura como a percentagem de CO, foram os fatores que, mais afetaram a redução de ferrita de zinco contida no EAFD. A máxima percentagem de redução foi 85%, para 100% CO, 1373 K e 105 min, e 52%, para 50% CO, 1373 K e 105 min. Por outro lado, atingiu o 100% para 100% CO, 1273K, em 80.75 min, 60%, para 50% CO a 1373 K durante 105 min.

Aug 16, 2017

By Giuseppe Pintaude

The use of two-dimensional shape parameters to characterize abrasive particles is a possible approach to express their angularity. Nonetheless, in sliding abrasion, especially in pin abrasion testing, coated papers structure plays an important role and even its damage during the wear process should not be neglected. This manuscript discuss the limitations of two-dimensional shape descriptors in distinguishing wear caused by relatively hard particles, indicating that the wear data obtained in sliding abrasion tests are unable to distinguish different types of coated papers used when only the two-dimensional particle projection is considered for shape characterization.

Jul 31, 2018

By Jean Viana Bahia, Antônio Adel dos Santos, Vicente Tadeu Lopes Buono

During cold rolling of Cr-Mo alloyed DP steel, considerable oscillation of thickness may occur. The literature points out that such occurrence is due to non-uniform cooling of the coil after the hot rolling process. Since the austenite transformation in this steel continues after coiling, the microstructure and, consequently, mechanical properties are very susceptible to natural variations in cooling rates associated with distinct positions of the coil. The influence of coil cooling conditions on thickness oscillation during cold rolling was evaluated in this work by using both industrial experiments and dilatometer tests. It was verified that an industrial coil presented large variation of mechanical properties associated with its heterogeneous microstructure. Consequently, thickness oscillation occurred during cold rolling. Dilatometer tests simulating hot run-out table and coil cooling showed that the austenite transformation is very slow under small cooling rates that occur after coiling. Thus, the slow transformation rate makes the coil very susceptible to environmental conditions around it during its natural cooling and is responsible for variation in mechanical properties of the coil. To ensure the formation of a more homogeneous microstructure in the whole coil, it is necessary either to make use of technologies that improves the cooling uniformity or to adjust the steel alloy design. The latter alternative has been done with relative success by using conceptions with lower amounts of Cr and Mo.

Oct 1, 2019

By Hugo M. Checo

Friction-reducing textures for lubricated mechanisms have received much attention since the advent of microtexturing techniques. In this work we consider the piston ring/liner contact, numerically simulating the rings as they slide against a textured liner. This situation has not been sufficiently analyzed because its numerical complexity is much greater than that of texturing the rings. Further, we consider the actual typical geometries of oil-control, wiper and compression rings, under realistic loads and velocities. The results show the possibility of friction reduction when the texture on the liner is properly designed, identifying starvation alleviation as a crucial intervening mechanism.

Jul 31, 2018

By Mario González Ramírez

The safe transport of sour gas requires steels with enhanced hydrogen induced cracking (HIC) resistance. Centerline segregation bands of high hardness microconstituents and non-metallic inclusions are the heterogeneities usually linked to HIC failures in pipeline steels. Full-scale production heats of a new low Mn, Nb microalloyed steel were produced by different steel mills aiming at the application in sour gas environments. The new alloy design provides both effective strengthening and control of sulphide inclusions. Coil microstructure consisted of fine grained ferrite with a small volume fraction of uniformly dispersed eutectoid aggregates. Most importantly the microstructure was uniform in both the longitudinal and transverse directions and exhibited exceptional consistency. Samples from this steel were submitted to HIC testing according to NACE standards TM0284-2003 without any sign of cracking. The results, so far, confirm that this new alloy design provides the unique opportunity to economically produce a high strength pipe steel grade with improved sour service resistance for the linepipe industry.

Aug 8, 2018

By Milan Terčelj, Matej Drobne, Urška Klančnik, Peter Fajfar

The study of oxidation behavior of High Chromium Steel material used for surface layer of work rolls was carried out. Specimens taken directly from the roll were subjected to thermal fatigue in the temperature range between room temperature and 500 °C up to 700 °C by using thermo-mechanical simulator Gleeble 1500D. Our observation was focused on the impact of oxidation as a principal mechanism of degradation of the roll’s surface layer - mainly on the characteristics of oxidation propagation in relation to the test temperature and microstructure constituents characteristics of the material. Oxidation is considerably accelerated by certain characteristics of eutectic and primary carbides, i.e. their size (area), composition, morphology, orientation regarding to the water-cooled surface, etc. In the presented paper selected cases where emphasized oxidation takes place are investigated, analyzed and explained. Obtained results thus represent a contribution to explanation of conditions which lead to acceleration of oxidation behavior that in turn can lead to chipping or even early spalling of material from the roll surface layer.

Oct 1, 2019

By Ananda Moreira Vaz Ourique de Avila

High and intermediate temperature fuel cells (FC) are power generators characterized by high efficiency and their use in cogeneration systems. The single fuel cells are connected in series by the use of interconnects to form a fuel cell stack. Ferritic stainless steels have been used in the making of high and intermediate temperature operation solid oxide fuel cells interconnects. However, at high temperatures, on the order of 700-8500C, these steels can present significant oxidation and degradation processes, promoting increased electrical resistivity and corrosion losses that result in contamination of the electrodes and reducing the performance and the useful life of the FC. Intensive R&D activities have been made to minimize these problems and the use of composite coatings on metallic substrate has been considered. This paper evaluates the use of coatings of copper and nickel, with particles of La2O3, Y2O3, CeO2, LaCrO3 and doped chromites applied on ferritic stainless steels AISI 430, AISI 441 and Crofer22APU produced by electrodeposition. The produced samples were evaluated by microscopy techniques, gravimetric analysis and by electrothermal characterization. The most significant results were obtained with chromites coatings (LaCrO3 pure, mono- and multiple-doped) showing the combination of the best features of metal coatings, substrates and ceramic particles with semiconductor properties.

Aug 7, 2018

By Gerhard Finstermann, Ichiro Maeno, Takehiko Saito, Hironori Shimogama, Konrad Krimpelstätter

Automobile manufacturers are developing Electrified Vehicles with light steel body structure designs that reduce mass and therefore greenhouse gas emissions over the vehicle’s entire life cycle. This raises the demand for the production and development of Advanced and Ultra High-Strength Steels (AHSS / UHSS) and Electrical Steels with increased permeability and reduced core loss to improve energy conversion efficiency. To meet this requirements the steel market is tending towards new generations of AHSS with improved formability (3rd generation AHSS) and high-silicon steels with higher strength and thinner products. With this growing demand for advanced high-strength steels and electrical steels, producers are faced with a unique and interesting challenge in producing materials that strain or exceed the capabilities of existing mill equipment and automation designed to produce low- to medium-carbon sheet. While specialty steel producers have known for decades how to process special high-strength steels and thinner gauges, this equipment typically does not offer the yield and productivity desired by the market, necessitating innovation in re-engineering existing equipment to meet the market demands more economically than new construction. In the case of cold rolling, this can be supported through variable roll geometries, more effective roll-gap lubrication technologies, application of strip heaters (Warm Rolling) to reduce risk for edge crack propagation and strip breaks as well as continuous rolling managed by state-of-the-art automation technologies.

Oct 1, 2019

By Pedro Cunha Alves, Wagner Viana Bielefeldt, Vinicius Cardoso da Rocha, Augusto Lachini Pereira, Julio Aníbal Morales Pereira

The capacity of steelmaking slags (CaO-SiO2-Al2O3-MgO) on inclusion removal from liquid steel was investigated through experimental conditions. Laboratory experiments with slag and steel samples (with inclusion population known) were performed using a vertical electric resistance furnace at 1600 ºC. After the melting experiments, slag and steel samples were separated and analyzed regarding their chemical composition and inclusion population evolution. The capacity of slags on inclusion removal was evaluated based on the thermodynamics (solid and liquid phases proportion, phase composition and effective viscosity of slags) calculated using the FactSageTM 7.2. Results indicated that changes in the composition of slags (regarding CaO/SiO2 e Al2O3) presented effects on the steel cleanliness. The total inclusion density decreased in all steel samples and the removal of inclusions by slags shows a tendency to improve as their viscosity decreases (< 0.23 Pa.s).

Oct 1, 2019

By Carolina Gomes Dias Ribeiro

The modern composite materials, especially those reinforced with synthetic fibers such as glass and carbon, have been used since last century to attend the demands required by most technological fields, from home appliances to aerospace. Natural fibers composites with biodegradable polymer matrices are considered environmentally friendly materials and currently accepted as possible substitutes for synthetic composites. These green composites can be safely discarded or composted at the end of their life without harm to the environment. Another alternative for synthetic composites is to apply natural lignocellulosic fibers as reinforcement of conventional polymer matrices and already used in the automobile industry. In addition to the environmental and societal advantages of the green composites, the lignocellulosic fiber reinforced conventional polymer composite also has economical and technical advantages. In the case of a fiber collected as a waste, the price of the composite can be considerably lower than “fiberglass”. Furthermore, with high strength lignocellulosic fibers such as sisal, ramie and malva the specific strength of a composite may approach that of “fiberglass”. Therefore the objective of the present work is to investigate the mechanical behavior of polymer matrix composites reinforced with high volumes of natural malva fibers subjected to tensile stresses.

Aug 16, 2017

By José Fagundes Jr., Juliano Braz Possatti, Bruno Câmara Vieira, Gabriel Godinho Alves, Bruno Bastos da Silva Murad, Cristina Maria de Oliveira Roque

Driven by market trends, increasing environmental accountability, government regulations and fostered by the Company’s strategic plan, ArcelorMittal Tubarão has developed new steel products to deliver better solutions to fit each customer’s needs. This often translates in higher strength, more complex and dimensionally challenging (thinner and wider) steels to attend a broad array of goals, such as reduction of vehicles fuel consumption and carbon emissions, increase in fatigue performance of heat treated parts, higher load capacity per net weight in vessels or wagons and lower supplying lead time as ArcelorMittal Tubarão establishes itself as a domestic option for so far imported grades. Based on the annual Product Development Plan, a structured workflow involves technical discussions from an operational point of view about safety issues, metallurgical project, steel grade family definitions, offline simulations prior to field trials, deformation resistance and process parameters adjustments and scheduling strategy. As a result of the increasing synergy between the areas, the share of new materials developed in recent years has been sustainably increased up to 15% in 2018, adding value to the final product without impact on hot rolled coil output and with a low cobble index.

Oct 1, 2019

By D. A. Aranda-Regino, C. Gómez-de-la-Garza, J. Ramírez-Cuellar, L. A. Leduc-Lezama

The Pickling Line Tandem Cold Mill (PLTCM) at Ternium’s Pesqueria plant with a 5 stands, 6 high configuration started in 2013. At the time of the start up the work roll specification and grinding practices were stablished following a low risk policy to be able to sustain any start-up associated accident. Once a stable operation has been achieved both these policies are being modified to improve productivity and reduce costs. The specified hardness of the rolls has been increased and efforts are being made to optimize the grinding according to the rolling campaign length and materials. The fatigue damage in work rolls, after rolling and its removal by grinding was followed by hardness measurements made at the end of the rolling campaign and after grinding. Softening of the rolls after rolling was found mainly in final stands to be related to the averaged stress experienced during the campaign, the original roll hardness was recovered after grinding. Hardness evolution was also followed after each grinding step finding that the total amount of grinding could be reduced. The grinding practice was modified accordingly for the first stands and the yield of work rolls in them has improved.

Oct 1, 2019

By HaiWen Luo, Bin Hu

A ultra-high strength medium Mn steel with good ductility was designed and manufactured via the combination of warm rolling and V alloying, which produced not only the extensive precipitation of fine VC particles in both ferrite and austenite but also the bimodal size distribution of retained austenite (RA) grains. A substantial increase of yield strength up to 650 MPa was achieved due to the addition of V without deteriorating ductility. The coarse RA grains firstly transformed to martensite during yielding at the much higher stress threshold, followed by a significant work hardening due to dislocations multiplication, twinning-induced-plasticity (TWIP) and transformation-induced-plasticity (TRIP) in the ultrafine RA grains. The best combination of strength and ductility included 1.5 GPa ultimate tensile strength and 28% total elongation. This was achieved due to the sustainable TRIP and TWIP effects in the later straining stage resulting from the ultrafine austenite grains, the latter were reversely transformed from the recrystallized ferrite grains.

Oct 1, 2019

By Nestor Cezar Heck

Aim of the present work is to continue the theoretical evaluation of the slags of the fundamental system CaO-SiO2-CrOx-MgO (Ca-O-Cr-Si-Mg quinary system) at the temperature of 1,873 [K], with the help of a computational thermodynamic tool. Driving force for this and the previous research works is the understanding of chromium losses from the molten bath into the slag. Especially motivating is the presence of solid phases in the slag, since they may prevent refractory degradation and help in the production of foaming slags. Nevertheless, Cr-bearing solid phases can lead to Cr losses, being therefore detrimental. Determination of the states of thermodynamic equilibrium for this system using a slag with fixed composition as a start material were made using MgO amount as variable. Results show the impact of the MgO content on the equilibrium phases (molten metal, liquid slag, solids) and their composition for this system.

Jul 30, 2018

By Jörg Busch

The essential pre-requisite for attaining the high quality of product required from high-speed continuous production processes is the use of new measurement and control technologies. High availability and reproducible measuring results ensure the high level of process stability necessary for full continuous operation. The requirements for the optimisation of quality across the complete production process and for quality analysis systems will be discussed. This report will present examples of basic and new measurement technologies in Cold Rolling Mills and Processing Lines. The following gauging systems will be discussed in detail: Strip tension meter, roll force measurements, weighing systems and shapemeter rolls. The measuring and control systems in this presentation must be seen as high-tech solutions in the field of processing technology. The measuring methods and technologies described are, together with optimised process models and precision control loops and actuators, the main pre-requisites for achieving the quality of product required from high-speed continuous production processes. Interconnected quality management systems enable optimisation across the complete production process.

Jul 30, 2018

By Giuseppe Pintaude

This study aims to evaluate the effect of specimen preparation on the dry sliding wear behavior of CA-6 NM stainless steel. Two different surface finishing manufacturing processes were applied: lapping and metallographic polishing. The wear tests were conducted in reciprocating ball-on-flat system, performed for two loads: 5 or 8 N. For all test conditions, hardmetal ball was employed as counterbody. The surfaces were evaluated using 3D interferometry technique to determine their surface roughness, including texture analysis regarding isotropy. Surface characterization results indicated the presence of texturing and preferential orientation, since the parameter Str was smaller than 0.5 for samples of both the studied conditions. Two distinct levels of isotropy evaluated through Str parameter were achieved: 0.13 for lapping and 0.3 for metallographic polishing process. It is clear from wear tests that the variation of average surface roughness is the key point for tribological behavior of CA-6 NM stainless steel.

Jul 31, 2018

By Marjorie Benegra

This study aims to compare the wear resistance assessed in rubber wheel abrasion test of nickel aluminide coatings deposited by for Plasma Transferred Arc (PTA) and High Velocity Oxigen Fuel (HVOF) manufacturing, using the same raw material. A nickel aluminide powder was atomized and deposited on 316L steel plate substrate. After deposition, some specimens were submitted to a heat treating (1200 °C for 24 h followed by 760°C for 24 h). The coatings deposited using PTA developed different microstructures due to the incorporation of substrate elements, its performance was better than the HVOF coatings, although their Vickers hardness was similar. After heat treating, a significant variation in hardness and wear resistance was observed. For PTA specimens, there were decrease in hardness of 35%, while for HVOF ones this drop was approximately 20%. Nonetheless, the effect of thermal exposure in wear resistance was quite different: an increase of 21% was observed for HVOF coatings, while a reduction of 20% occurred in PTA ones. Microstructures modifications in PTA coatings were significant for their wear resistance. On the other hand, the reduction of porosity and sintering were responsible for a better performance of heat-treated HVOF coatings.

Jul 31, 2018

By Moisés Paulo Teixeira

The use of tailings for the synthesis of new materials is a worldwide concern today. This paper approaches the utilization of tailings of soapstone (steatite) in order to produce ceramics. The results show that the addition of soapstone in a ratio over 20% in the ceramic mass has enhanced the bending resistance of the ceramic samples when they were fired at temperatures of 900°C or 1000°C.

Oct 30, 2017

By Haruki Inami, Takashi Ishida, Kazuhiro Ohara, Hiroyuki Imanari

The highly competitive business environment of the international metals industry is driving demand for more cost-effective operation of steel making facilities, rolling mills, and strip processing lines. Achieving stable operation is vital if the steel industry is to produce high-quality products constantly and productively. In recent years, advances in computer processing speeds, data acquisition rates, and data storage capacity have rapidly led to greater use of the new technologies of big data, analytics, the IoT, and AI by control system designers and process engineers, and the introduction of industrial applications. The “Smart Rolling Mill” solutions for hot strip mills have been developed by our group with the goal of achieving sophisticated, state of the art, and automated operation in steel rolling mills. The various solution engines improve process stability, increase the performance of mill equipment, and provide improved process control. These solution engines are based on extensive knowledge of the rolling process and the associated control systems. Two solution engines in particular are the diagnosis systems for rolling condition and for product quality that contribute to cost-effective operation and lower yield loss. This paper focuses on the diagnosis systems for rolling condition and for product quality in hot strip mills. Advanced information technologies using big data analytics and machine learning are applied to real-time data collected from the automation system that controls operation and the rolling process. We have developed diagnosis solutions for rolling condition and product quality utilizing predictive and clustering diagnosis. Predictive diagnosis prevents serious problems by detecting changes in the state of the plant or in the rolling condition. Clustering diagnosis classifies patterns of fluctuation in product quality trend charts, providing effective tuning guidance for improving product quality. This paper describes these applications with several examples.

Oct 1, 2019

By Henrique Lacerda Eleutério, Aldo Henrique de Almeida Barbosa, Vicente Tadeu Lopes Buono

The automotive industry’s interest in galvannealed (GA) boron steel for hot forming processes application has been steadily increasing due to its excellent surface quality, galvanic protection provided to the parts, good paint adhesion and better weldability in relation to other coatings for this application. In this study, samples of 22MnB5 galvannealed steel were heat treated and hot stamped on a water cooled die in laboratory scale. The influence of heat treatment on stability of coating and steel was assessed by using initial heating rates 11.0ºC/s and 15.0ºC/s. Microstructural evolution of galvannealed coating and structural integrity of steel during hot forming were investigated by scanning electron microscopy with energy dispersive spectroscopy analysis (SEM/EDS/Line scan), X-ray diffraction (XRD) and optical microscopy (OM). It was possible to quantify the Fe-Zn phase evolution during hot forming, to understand the effect of these heating rates on the product properties and to establish an optimized heat treatment for hot forming of these steel. The heat treatment with the heating rate of 15.0ºC/s presented greater operational flexibility and final products free from surface defects or cracks in the substrate.

Oct 1, 2019