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By Thomas Kuhn, Carsten Ruehlemann, Christina Heller, Anna Wegorzewski

The commercial extraction of metals from manganese nodules on an industrial scale requires more than 50% of the investment necessary to realize manganese nodule mining. This is mainly due to the fact that a completely new metallurgical processing scheme for the extraction of both base metals (Ni, Cu, Co) and high-tech metals (Mo, Li, Ga) has to be developed and upgraded to industrial scale. There are a number of conventional processing technologies that combine hydro- and pyro-metallurgical approaches such as the INCO and CUPRION processes which have been developed in the 1970s and 1980s. Today, new approaches based on selective leaching with chelating agents and bioleaching try to minimize energy consumption and waste production. All of these extraction methods require knowledge how the metals are structurally bound in the manganese oxides. In this contribution we will review the current knowledge about the mineralogy of iron and manganese minerals in the different marine oxide deposits, present our results, and discuss the possible consequences for metal extraction.

Sep 1, 2014

By O. R. Eckstrand, M. Asif, P. L. Schwann, A. J. Naldrett, R. J. F. Scoates

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. PGE-bearing sulphide mineralisation is contained in the lower 600 m of the Upper Central Layered Zone of the intrusion. There are four regimes with distinctive crystallisation characteristics. PGE content is low, both in bulk rock and in terms of metal in 100% sulphides, in the sulphide-rich cumulates but increases sharply in the sulphide-poor cumulates at the base of regime 1. Increases in regime 2 have no such clear relationship with incoming cumulus sulphides. PGE contents are low throughout regime 3, but regime 4 has sulphides with high PGE content, decreasing rapidly upwards, at the base of many of its cyclic units. The observations are interpreted as indicating that sulphide saturation occurred in the middle of a cyclic unit in regime 1, after which fractional segregation of sulphide caused a systematic decrease in PGE content. The resulting contrast between 40 000 ppb PGE in sulphides below the mineralised zone and less than 1 000 ppb above is of practical importance in exploration for such zones. In regime 2 the magma chamber was open to fresh influxes and PGE content was not so sensitive to sulphide saturation. In many regime 4 units influxes of new magma caused immediate sulphide saturation and PGE depletion, so that PGE-rich cumulates do not underlie PGE-bearing sulphide zones. Theoretical analysis indicates that regime 1-type behaviour is likely to characterise intrusions below the level at which plagioclase has entered as a cumulus phase and regime 4-type behaviour above

Apr 1, 1994

By D. Bessinger, J. M. A. Geldenhuis

High titania slag is produced from the smelting of ilmenite. These slags contain approximately 85 per cent TiO2 and consist mainly of a M3O5 solid-solution phase. During cooling the slag can decrepitate to a fine particulate material, which decreases the value of the product. Based on X-ray diffraction analyses of the decrepitated slag after cooling, it was found that the M3O5 phase had almost disappeared. The disappearance of the M3O5 phase was linked to oxidation of the slag. A M6O11 phase formed in the decrepitated slag. It is postulated that decrepitation of high titania slag is caused by volume changes due to the oxidation of the M3O5 phase in the slag.

Jan 1, 2005

By Da Zhao Gu

An important problem in rock engineering is to control the properties of artificial rock. A compaction technique for casting artificial rock specimens with controlled properties is described, i.e. using a compression-testing machine to compress the mixture. Uniform density is necessary to achieve uniformity of properties of the specimens, and uniform density can be obtained by using the specific pressing method presented. Rebound and borax content are important to the technique and have been studied as well.

Jan 1, 1992

By Shawn Orser, Jennifer Waddell, Mike Sierakowski, Tom Barrett

Production evaluations were conducted at Daisy Gold Mine (Glamis Gold, formerly Rayrock), between August, 1997 and August, 1998 to quantify the effect of 3M fluorochemical surfactants (fluorosurfactants) on extraction kinetics and gold recovery in gold heap leach mining operations. Ore was treated at a level of 7-10 grams surfactant per ton of ore using 3M Pluorad TM Leach Mining Additive PC-GOLD. Kinetics and gold recovery were determined by solution assay for each of the tests. Both tests indicated improved kinetics, and data from Test 2 was used for determination of a quantitative increase in gold recovery resulting from PC-GOLD addition. A discussion of test results including methods used to determine gold recovery is provided.

Jan 1, 2000

By Dunkin H. H

Flotation tests in a laboratory flotation cell at pH 8-8.5 and other sui}plementary tests were carried out on sphalerite-quartz and sphalerite-pyrite-'quartz mixtures. Depression of sphalerite resulted vvhen the addition of copper sulphate exceeded an optimum value. Evidence that this depression was due to collector deficiency because of reaction between copper sulphate and collector is presented. It was not found possible to devise a direct analytical method suitable for .plant control of reagent addition. A possible means of control using potassium cyanide and a higher pH is discussed.INTRODUCTIONAt the Rosebery mill of Electrolytic Zinc Co. of Australasia Ltd., recovery 'of sphalerite in the zinc concentrate occasionally drops unexpectedly. Experiment in the mill and mill laboratory has suggested that one of the factors causing this may be the addition of more than an optimum amount of copper sulphate. On such occasions, an increase in the collector addition improves zinc recovery in the zinc concentrate, but only at the expense of sphalerite-pyrite selectivity.To examine the phenomenon more thoroughly, and if possible to find some means of determining the optimum addition of cepper sulphate and controlling the actual addition at this optimum, one of the authors (W. J. T.) was employed by the Electrolytic Zinc Co. of Australasia' to carry out investigations in the Mining Department, University of Melbourne, under the joint direction of R. B...

Jan 1, 1954

By Wu Jie Mei, Li Yao Liang, Franz-Werner Gerressen, Arthur Bi

Diaphragm walls (D-walls) are known as underground structural elements commonly used for retention systems and permanent foundation elements. In addition, they are also quite often used as deep groundwater barriers, called Cut-Off-Walls (COW). Shanghai ranks third among the most densely populated metropolises in the world. In 1990, only eight million people lived there. Today, Shanghai has about25 million inhabitants. The increasing demand to accommodate the infrastructure of growing megacities like Shanghai pushes the required depth for subway, sewage and foundation projects to the limit. Future projects will demand excavation depths of more than 100 m (328 ft) on a regular basis. Already carried out reference projects will be described and a general outlook for upcoming projects will be given. The paper also explains the installation process in general focusing on the use of trench cutter technology. INTRODUCTION D- walls are known as underground structural elements, commonly used as retention systems for excavation pits and shafts as well as permanent foundation walls or elements. It is anticipated that, with the increasing trend of utilizing more and more underground space to accommodate environmental considerations and urban/suburban development, there will be an increasing requirement for diaphragm wall usage in even more difficult conditions and with increasing depth. The trench cutter is the most important tool for performing this work. The hydraulic grab, a well-known and valuable excavation tool for d-walls reaches its limits in terms of depth and when cutting rock. Therefore the trench cutter technology will be in the focus of this paper. The trench cutter itself is a reverse circulation excavation tool. It consists of a heavy steel frame with two drive gears attached to its bottom end, which rotates in opposite direction around the horizontal axis. Cutter wheels are mounted onto the drive gears. As they rotate, the soil beneath the cutter wheels is continuously broken up, removed, mixed with the bentonite slurry in the trench and moved towards the opening of the suction box of the pump? A centrifugal pump located right above the cutter wheels conveys the slurry via a hose system up to a desanding plant. There the slurry loaded with soil and rock particles is cleaned and returned into the trench.

Jan 1, 2018

By W. J. Spat

Political risk is an integral part of the mining business in northern Andean countries. Peru, Ecuador, Colombia and Venezuela all have a higher than average political risk compared with other South American countries. Successful operations require good political-risk information, a thorough political-risk-management plan and a strategy to deal with political-risk perception on the part of the investing public. Colombia is perceived as about the riskiest place in the world to do business. A selection of recent headlines reads: “Colombia on the brink” (Economist, 1998), “Colombia’s ship of state is sinking” (Insight on the News, 1998), or simply “Bad news” (US Catholic, 1998). The World’s Most Dangerous Places rates Colombia as “currently the most dangerous place in the Western Hemisphere, and perhaps the world” (Aral and Pelton,1998). And many prospective investors and analysts say to Greystar Resources: “Yes, we love your results, but Colombia?”

Jan 1, 2000

Drill blasting is a widely used method for rock fragmentation in mining, quarrying and construction industries. Environmental effects such as air shocks, dust, flying rocks and ground vibration are unavoidable results and undesired effects of blasting. Among these ground vibrations can have a damaging effect and may influence on long distances. Therefore various researchers have developed mathematical models to predict ground vibration after blasting. These models take into account the amount of explosive, distance and several coefficients related to the field under investigation. The developed models to predict ground vibration may yield different results for the same case. Selection of the most suitable model requires engineering judgment and evaluation of models. At this point, a computerised system helps the engineer to evaluate and select the most suitable model in order to design and plan a blasting pattern. The safe charge of explosive and magnitude of vibration after blasting should be predicted beforehand. Therefore a computer program namely 'prediction of blast induced vibration' (P-BIV) has been developed. This paper introduces and presents a computer program (P-BIV) which includes the set of models developed to estimate ground vibration to provide blasting engineers a tool to determine the amount of explosive for safe blasting.

Dec 6, 2010

Dynamics of Three Phase Contact Line Motion in Liquid-Liquid-Solid Systems - Impact of Surface Roughness

Sep 13, 2010

By Christophe Bragard

The Los Angeles Metro Eastside Extension light rail project included a 1.5 mile underground segment, which consisted of twin 18'?10" ID tunnels, bored with two EPB-TBMs. One of the major project challenges after the completion of the bored tunnels was the excavation of six cross passages within alluvial geology below the water table and with low ground cover. Sequential excavation methods were employed and this paper details the design, ground treatment, support measures, and construction methods used to mine these cross passages beneath the congested urban streets of the City of Los Angeles.

Jan 1, 2008

By Jacques J. Eksteen

Any effort to improve the metallurgical control of industrial furnaces employed in the primary extraction of high carbon ferroalloys are bound to fail unless the variability of the melt is not fully accounted for. A number of sampling campaigns were performed on both 3phase AC submerged arc and single phase DC open arc furnaces at different smelter sites in South Africa where High Carbon Ferrochrome is produced. It was found that the heterogeneity between multiple samples during a single taps were much higher that for heterogeneity found within a sample. Moreover, this heterogeneity (as quantified by the relative standard deviation per tap) varied with the operating conditions of the furnace, the element monitored and the type of furnace. A relationship was found between the relative standard deviation of certain elements and the degree of subcooling of the melt.

Jan 1, 2006

A pilot steel ladle injection facility designed to assist in the production of high quality steels suitable for use in pipelines has been built and commissioned at the Basic Oxygen Steelmaking (BOS) plant at Port Kembla Works.The plant design and the injection procedure are described.The performance of the unit and some metallurgical results are discussed in terms of the addition to the steel ladle of various quantities of calcium silicide and a lime based material. The effects of these additions on sulphur content and inclusion morphology and hence on steel ductility are also presented. The influence of ladle lining on desulphurisation is illustrated.On the basis of the experience gathered in the pilot plant a permanent and more sophisticated injection facility has been designed.

Jan 1, 1983

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Jan 1, 2009

By M. A. Trevits

Mine seals are used in underground coal mines throughout the United States to isolate abandoned mining areas from the active mine workings. The objective of adding inert gas to a sealed mine area is to quickly reduce the oxygen concentration in the sealed area to a level that will not support combustion. In the US, this process is typically conducted from the ground surface and because surface-to-mine access is constrained by so many variables, it is very difficult to provide a source of inert gas to the place where it is needed underground. To alleviate this problem On Site Gas Systems, under a NIOSH contract, built a nitrogen (N2) generation plant that operates in the underground environment. The purpose of this work was to create a reliable in-mine mobile plant that would extract N2 gas from the mine atmosphere and use the gas to create and maintain a safe sealed mine area. The plant is based on a novel design using pressure swing adsorption technology and is sized to fit on a standard shield car or mine dolly for easy transport in and around an underground coal mine. The plant is capable of producing about 900 scf/min of N2 gas at ambient mine conditions. After an exhaustive series of laboratory tests, the plant was field tested at the NIOSH Safety Research Coal Mine (SRCM) where a portion of the mine was sealed and rendered inert. During the test, the movement of the injected gas was monitored at several underground points to observe the progress and extent of the inerting process. This paper describes the plant design and the results of the field test at the SRCM. Disclaimer: The findings and conclusions in this report are those of the authors and do not necessarily represent the views of NIOSH.

Jan 1, 2009

By Regina Maria Pinheiro

This work has for objectives to characterize a waste generated in the form of sludge during the treatment of the effluent of a paper making industry and to evaluate the effect of its incorporation in the amount of 10 wt.% on the properties and microstructure of a clayey body used for brick production. For the characterization of the waste the following techniques were used: X-ray diffraction, X-ray fluorescence, differential thermal analysis and termogravimetric analysis. Incorporated bricks were produced in industrial scale before firing at 750°C in a Modified Caieira type furnace. The physical and mechanical properties evaluated were water absorption and compression strength. The microstructure of the fired ceramic was evaluated by optical microscopy. The environmental evaluation was made by solution test and atmospheric emission by monitoring the release of SO2, NOx and particulate material. The results showed that, in agreement with the characteristics of the waste, its recycling into red ceramic can contribute to decrease the consumption of fuel during the firing stage. The properties of the fired ceramic attend the norms. With respect to the environmental aspect, the incorporation of the waste did not impact the environment.

Jan 1, 2009

As the question of zino recovery from lead blast furnace slags has lately become such an important subject with lead metallurgists, the following description of some of the work carried out in this oonnection by the Sulphide Corporation, at CockleCreek, should prove of interest to those concerned. Early in the life of the works it was realised by the metallurgical staff that a very wide field for investigation lay before them. At the head of these was the late Mr. F. H. Evans, and it was due to his work and suggestions that the question has grown from a mere hypothesis to a commercial undertaking, in so far as these works are concerned. A great deal of the early work was carried out in the form of small laboratory expe!iments, those giving the best results being ear-marked for subsequent trial on a larger scale. One of the main obstacles in the way of research was the lack of any data or information of similar work done in other...

Jan 1, 1920

By A. A. Beland, R. J. Dawson, S. Shewchuk

"Shovel buckets, scraper blades, dipper teeth, mine car wheels and hammermills are examples of equipment which require routine maintenance due to abrasion. Service life can be extended by the use 0/hard/acing and buildup materials. Mining and milling applications are described and field welding procedures discussed.A high-stress abrasion test used to select hard/acing and buildup materials/or hammers in a hammermill is described in detail. Field tests of the selected alloys confirmed their performance, and maintenance records showed a significant saving in down time and cost.The relationship between the abrasion resistance of the alloys and their hardness, work hardening, composition and microstructure is summarized. IntroductionLarge volumes of ore are handled daily by the mining industry. The abrasive nature of most ores results in extensive wear to both handling and processing equipment. If such wear is neglected it may cause lost production time and also, in extreme cases, require the complete replacement of expensive equipment. The well-planned maintenance of components subject to abrasive wear by means of buildup materials and hard facing can result in substantial economic benefits. Such benefits can , however, only be realized through the correct choice of welding process, consumables and deposition methods available to maintenance personnel. Hardfacing MethodsHardfacing is applied by a variety of methods; the three most widely used being arc welding, oxyfuel gas and thermal spraying. Table 1 summarizes the major processes used within each method. Filler metals in the form of rod, wire or powder are necessary to fulfill the individual requirements of each process. The filler rods are available in the cast form or, in the case of ductile metals or alloys, as wrought rod or tube. All types are supplied bare or flux covered. Wire is supplied in two forms, drawn flux cored and drawn solid. Powder filler metals are available in many metals or alloys; they may be simple mechanical mixtures or prefused and atomized alloys made to a specific size range and shape for optimum results for each applicable process."

Jan 1, 1980

By French D

In presenting this paper may I preface my remarks by recognizing the presence here to-day of the many delegates from the overseas mining communities throughout the world. That is to say - those delegates not representative of Companies resident in Australia. This does not mean that my comments following are directed solely to the Australian exporter - far from it. The Company which I represent is internationally based. The experiences we have had in dealing and negotiating with our good friends the mineral cargo shippers vary very little in any operational area. However for the purposes of this exercise this address is based on some of our experiences within the Australian trade scene with the emphasis on the fact that we believe it has application to all trading areas.

Jan 1, 1989

By H. J. de Haan, L. Schenk

Scope for Thermal Recovery in Shell's Heavy Oil Fields in Venezuela The main heavy oil reservoirs on the East coast of Lake Maracaibo (Fig. I), known as "Bolivar Coast", initially contained some 20 billion bbl of oil in place with gravities in the range of 10 to 15° API. The current total production rate is about 400,000 B/D. Since the recovery to date is on an average only 12.5 percent of the initial oil in place, these fields offer a vast potential for secondary recovery methods. The reservoirs are characterized by moderate depth (generally 1,000 to 3,000 ft; maximum 5,000 ft), good formation properties such as net oil sand thickness (50 to 300 ft), high porosity (30 to 40 percent) permeability (1 to 3 darcies) and oil saturation (initially about 80 percent) and high oil viscosity (100 to 10,000 cp in situ), all of which are favorable for the application of thermal recovery processes. Since 1957, steam drive, steam "soak" and underground combustion have been tested or are being tested in this area.1-3 This paper deals with a major steam drive test in the Tia Juana field. The test was commenced in Sept., 1961, on the basis of encouraging results of laboratory experiments and pilot field tests, which will be discussed briefly. Early Laboratory Investigation of the Steam Drive Process In 1956 a series of model experiments was carried out in the Koninklijke/Shell Laboratorium, Amster- dam, to investigate the displacement of heavy oil by steam.' The prototype studied was a horizontal, un-consolidated heavy oil reservoir, subjected to a linear steam drive. The model, representing a slab from this reservoir along the main flow direction, consisted of a steel tube filled with oil-saturated sand, provided with layers of rock at the top and bottom to simulate conductive heat losses to cap and base rock. Lateral heat losses, perpendicular to the main flow direction, were minimized by insulating the sides of the model. Heat flow and viscosity and gravity forces were scaled by taking the steam injection rate and sand permeability inversely proportional to the geometric reduction factor of the model, and using materials (oil, steam, cap rock, etc.) identical with those of the prototype. The main feature of the process was a frontal displacement mechanism that was observed within wide ranges of injection pressure and rate, oil viscosity, initial oil saturation and sand permeability. The high stability of this front can be attributed to the high volumetric steam flow rates, combined with the reduction in oil viscosity. High recoveries were obtained due to the low residual oil saturation of about 15 percent in the zone swept by steam. The latter value pertains to the specific test conditions (heavy oil, uncon-solidated sand) and may be lower for light oil, due to the effects of steam distillation. The applicability of this experimental approach is limited, as it does not take into account the fact that

Jan 1, 1970