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By Piotr M. Kapias

Keywords: extraction, lead refining, Pb-Tl solutions, PbCl2-TlCl solutions. The theoretical part of the paper presents an analysis of the conditions of Tl extraction from Pb using different extractants and determines the activity coefficients in liquid solutions of Pb-Tl and PbCl2-TlCl. The dependence of the solution activity coefficients upon the composition and temperature is presented in the form of Krupkowski and Krupkowski-Fitzner equations. An analysis and evaluation were made of the influence of the methods of PbCl2 introduction into a Pb-Tl solution upon the efficiency of the Tl extraction process under thermodynamic equilibrium conditions. The analysis made it possible to formulate relevant equations describing the dynamics of the process of Tl extraction from Pb under stirring conditions as well as under the extractant injection into the liquid Pb-Tl solution conditions. In the part concerning experimental work, results are given for tests on the Tl extraction process from Pb-Tl liquid solutions of initial Tl content of approximately 0.05% mass using PbCl2 or, alternatively, Cl2(g) conducted in laboratorial scale. The tests made it possible to establish the influence of time, temperature, mass and the method of introducing the extractants into the liquid upon the level of Tl extraction from a Pb-Tl solution. Labels used in the text. WT1m - TI content in metallic phase, % mass WT1s - TI content in chloride phase, % mass wpTlm - TI content in metallic phase in initial state, % mass W°Tlm - TI content in metallic phase in equilibrium conditions, % mass m°m - initial mass in metallic phase mm - mass in metallic phase mPbC12 - lead chloride mass fed to the system MPbC12-TIC1 - mass in chloride phase MPb - lead atomic mass, g/mole MT1 - thallium atomic mass, g/mole K - Nernst distribution coefficient Xi - mole friction of solution component X°PbC12 - mole friction of PbC12 in saturated solution X°T1C1 - mole friction of T1C1 in saturated solution T - temperature, K R - gas constant, J/(mole K) k - kinetic equation constant, 1/(%-min.) ?i - solution component activity coefficient e - extraction rate, %

Jan 1, 2008

[Consider a square block W in an ore body S2, to be valued from one centre sample w, and one corner sample w2 (Fig. 9.1). The sample set is ws = Iw,;w21. We can estimate the block average µw by the average of the sample values x, and x2: µw = 'z (x, + xz). (9.1) The error made is measured by the estimation variance: o' (ws to W) = 2 - (ws; W) - - (ws;ws) - - (W; W). (9.2) However, we know that the centre sample w, gives more information about the block value than the corner sample w2. In the example studied in § 8.4, where w, and w2 were considered to be points, we found that of (w, to W) was nearly one third smaller than o2E (w2 to W), therefore when estimating W one should give more weight to w, than to w2. In general, when evaluating a block W from a set of n samples ws, where WS = l w;w2; ... wn1, a better estimator of µw can be obtained if we give different weights to the sample values, depending on the size and the positions of the samples. Some desirable properties of such an estimator µw are: ? It should be a linear function of the sample values xi: n µw = bi xi (9.3) =t where bi = weight given to sample x . ? It should be unbiased, i.e. its expected value should be equal to the true block value: E [µw - µw] = 0. (9.4) ? The mean squared error of estimation of µw should be a minimum E [(µw - µw)2] = a minimum. (9.5) The estimator which satisfies these properties is a minimum variance, linear and unbiased estimator, and is known as the kriging estimator. The corresponding error of estimation is the kriging error. This estimator is also known as the BLUE (for Best Linear Unbiased Estimator) estimator. This was named by Matheron in acknowledgement of the early work of Krige's in the optimization of the evaluation of the South African gold mines. The following notations will be used: µK kriging estimator. o2k = o2K (w,, to W) kriging error.]

Jan 1, 1978

By M. A. Belokrys, F. O. Milovich, D. D. Aksenova, V. A. Ignatkina, V. A. Bocharov, A. A. Kayumov

Copper remains one of the most sought-after metals in the industry. Tennantite (Cu12As4S13) and tetrahedrite (Cu12Sb4S13) that occur in pyrite copper, copper-zinc and polymetallic ores are an additional reserve for increasing technological parameters of flotation. Pyrite mass (85% and more) has similar flotation properties to other sulfide minerals, and imperfection of reagent regime is a common problem that occurs during quality copper concentrate processing. Due to tennantite's and chalcopyrite's differences in flotation properties with butyl xanthate at pH > 10, tennantite often reports to the flotation tails. Hight alkalinity of the medium increases the oxidation level of sulfide minerals, thus increasing the concentration of S2O3 2-, SO3 2- SO4 2-. At processing facilities in the Russian Federation, the concentration of thiosulfate ions in pulp is in the range of 0.5 to 1.5 g/l and higher, which leads to a decrease in flotation activity of the tennantite. The effect of butyl xanthate (as standard), thionocarbamate, dithiophosphate and M-TF (a mixture of dithiophosphate and thionocarbamate) on monomineral (tennantite and pyrite) flotation in the presence of sodium thiosulfate was studied. The variable parameters of the "thiosulfate-collector" flotation complex were thiosulfate concentration (100-900); pH (8-12,5). The scientific methods included contact angle for hydration assessment; TEM for surface studies; UV spectroscopy and iodometric titration for solubility control. Comprehensive studies have established a connection between the concentration of thiosulfate ions and tennantite flotation selectivity. Flotation activity of tennantite is higher at pH 8 with a thiosulfate concentration under 300 mg/l. Pyrite remains active with butyl xanthate under the same conditions. TEM images of the surface films of the collectors on pyrite were acquired at pH 8. The MTF provides the biggest difference in adsorption, wettability and flotation activity between tennantite and pyrite at pH 8 and thiosulfate concentration under 300 mg/l, in comparison with butyl xanthate. The results of the research will be applied to improve selective reagent regimes of tennantite minerals flotation. Keywords: Tennantite, pyrite, chalcopyrite, sphalerite, flotation, sulfhydryl collectors, thiosulfate, adsorption, mechanism, reagent regime

Jan 1, 2020

1. Book reviews A report by the Monopolies and Mergers Commission on the efficiency and. costs in the development, production and supply of coal by the NCB (Chairman G. Le Quesne). London, Her Majesty's Stationery Office, Jun. 1983. £20 for report and appendices (2 vols). Reviewer: M. J. Martinson Canadian mines handbook 1983-84, edited by M. R. Brown. Toronto, Northern Miner Press Ltd, 1983. 444 pp. $22. Reviewer: Northern Miner Review Editor 2. New publications Developments in geophysical exploration methods-5, edited by A. A. Fitch. Barking. Applied Science Publishers Ltd (Ripple Road, Barking, Essex IG II OSA, England), 1983. 255 pp. £35.75. High-pressure researches in geoscience--behaviour and properties of earth materials at high pressures and temperatures, edited by W. Schreyer. Stuttgart, E. Schweizerbart'sche Verlagsbuchhandlung, 1983. 545 pp. DM 188. Dynamics of oil and gas accumulations, by Alain Perrodon. Pau, Elf Aquitaine (Documentation Centre Micoulau, 64018 Pau, France), 1983. 368 pp. 240 FF. New paths to mineral exploration, edited by F. Bender. Stuttgart, E. Schweizerbart'sche Verlagsbuchhandlung, 1983. 169 pp. DM 58. Results of the First Workshop on Standards in Geothermics, edited by R. Haenel and M. Gupta. Stuttgart, E. Schweizerbart'sche Verlagsbuchhandlung, 1983. DM 98. E&MJ book of jlowsheets edited by Paul C. Merritt. New York, McGraw-Hill, 1983. 214 pp. $42. 1983 E&MJ international directory of mining. New York, McGraw-Hill, 1983. 808 pp. $70. The future of heavy crude and tar sands - volume 11. New York, McGraw-Hill, 1983. 1300 pp. $1l0. 3. Mineral Policy and Energy publications Aluminium, by A. Johnston. 12 pp. . Arsenic, by J. J. Hogan. 4 pp. Cobalt, by D. G. Fong. 6 pp. Selenium and tellurium, by A. G. Johnston. 7 pp. Stone, by D. H. Stonehouse. 13 pp. Uranium, by R. T. Whillans. 16 pp. 4. Mintek publications Report M88 'l'he recovery of platinum-group metals and gold by the lead-collectionstep of thefire-assay procedure. Report MI04 The preparation and analysis of reference materials, and the provision of recommended values. Progress report no. 5. Report Mll1 The determination, by flow-injection analysis, of iron, sulphate, silver, and cadmium. Special publication 3 A guide to the presentation of papers.

Jan 1, 1983

[The following notations will be used: O an ore body. W a sample of size w located in O; the size of this sample. W a block or a sample, of size W, located in O; the size of this block or sample. z' a point in W. W' a block or a sample, of size W' greater than or equal to W, located in O; the size of this block or sample. z" a point in W'. y (h) point semivariogram in O. s (h) point covariogram in O. In the previous chapter, we saw that the point semivariogram y (h) usually cannot be estimated directly from the data available. Rather, the values of samples of size w are available in O, and from these a regularized semivariogram y w (h) can be estimated. The following relationship has been proved (5.8): Y w(h) = Y (w;w+h) - Y (w;w). y (w;w+h) is the average value of y (z' z") when z' takes all possible positions in a sample w and z" all possible positions in a sample w+h of the same size, h being the distance between w and w+h. y (w;w) is the value of y (w;w+h) for h = 0, i.e. the average value of y (z' z") when z' and z" take all possible positions in w. We also saw that the regularized covariogram aw(h) is related to the point covariogram a (h) as follows (5.9): w(h) Gr In the following chapters, it will be shown that calculation of the average value y of y, or -a of a, in the general case relating to samples or blocks W and W' which need not be of the same size, plays a very important part in all the practical applications of geostatistical theory. The purpose of this chapter is to introduce various methods of calculating y and a-. Furthermore, mathematical equations and graphs are provided which can be used when the point semivariogram can be represented by one of the more common equations, and when the blocks W and W' are of simple shape. By definition (Fig. 6.1): [ ] Y (W;W) = WW f dz' f y (z' z") dz" (6.1) in W z" in W']

Jan 1, 1978

By V. L. Nkuna, S. R. Amos, T. Naidoo

"Ivanhoe Mines’ Kamoa copper project is a recently discovered high-grade copper sulphide deposit in the Katanga Province of the Democratic Republic of Congo. The mineralization identified to date within the resource is typical of sedimentary-hosted stratiform copper deposits and comprises three distinct units: supergene, mixed, and hypogene mineralization. Since 2010, various metallurgical test work campaigns have been conducted on drill core from different areas within the deposit in line with resource expansion. The most recent bench-scale flotation test work has shown positive repeatable results. The work was conducted on a composite sample of drill core from the southern part of the Kamoa resource. The sample is representative of the first four to five years of planned production, when Ivanhoe Mines intends to produce clean, highgrade copper flotation concentrate. A detailed test work roadmap developed from first principles for the campaign led to an optimum flow sheet for treating the Kamoa mineralization. Copper recoveries of 88.3%, at a concentrate grade of 39.0% copper, were achieved using a composite sample — an improvement on the previously published 85.9% life-of-mine average copper recovery indicated in the November 2013 Kamoa Preliminary Economic Assessment. IntroductionThe Kamoa project is a newly discovered, very large, stratiform copper deposit with adjacent prospective exploration areas within the Central African Copperbelt, approximately 25 km west of the town of Kolwezi in the Democratic Republic of the Congo (DRC) and about 270 kilometres west of the provincial capital of Lubumbashi. Ivanhoe Mines holds its 95% interest in the Kamoa copper project through a subsidiary company, Kamoa Copper SA Limited SPRL, and DRC government owns 5%. The project location is indicated in Figure 1.In January 2013, a new independent mineral resource estimate ranked Kamoa as Africa's largest high-grade copper discovery and the world's largest undeveloped highgrade copper discovery. At this time, Ivanhoe Mines had estimated discovered Indicated Mineral Resources of 739 Mt grading 2.67% copper, containing 43.5 billion pounds of copper, and Inferred Mineral Resources of 227 Mt grading 1.96% copper, containing 9.8 billion pounds of copper, as demonstrated in the Preliminary Economic Assessment (PEA) (AMC, 2013). A 1% copper cut-off grade and a minimum vertical mining thickness of 3 m were applied in each classification."

Jan 1, 2016

By J. W. van der Merwe, C Strydom, D. C. Odendaal, M. I. Sampson

Keywords: Sphalerite, Bio leaching, Chemical leaching Sphalerite concentrates were prepared from tailings dam samples obtained from Rosh Pinah Mine in Namibia. The samples were subjected to froth flotation and concentrates containing between 7% and 14% Zn were prepared. Leaching of these froth flotation concentrates were studied in ferric chloride solutions at different Fe3+ concentrations for different times at different temperatures with the influence of other species on the kinetics in mind. Complementary to this research, GeoBiotics, LLC and Exxaro Resources have developed proprietary bioleaching technology for the oxidation of base metals concentrates using GEOCOAT bio heap leaching technology in a sulphate medium. The ferric chloride laboratory work was performed in a fluidising leach reactor. The studied material was obtained from flotation concentrate produced during an investigation into the recoverability of a tailings pile at Rosh Pinah mine in Namibia. The optimum conditions for the laboratory investigation were found to be a Fe3+ concentration of 0.3 mol/dm3 at 80°C. A control was performed by using synthetic zinc sulphide. GEOCOAT evaluation tests are performed for the purpose of evaluating the bioleaching of ore and flotation concentrates by means of mesophilic bacteria, Column tests were carried out on the flotation scavenger concentrate from Rosh Pinah to assess the application of the GEOCOAT® process for the oxidation of a low grade zinc concentrate. In this study an attempt was made to demonstrate the relationship between the Kinetic models and the experimental data by plotting the fraction of Zinc leached against time and applying the different equations to the data. The kinetic models were applied to the data obtained from both the test regimes. Habashi (1999) proposed that if a process is controlled by a chemical reaction at the interface (phase boundary controlled reaction), the following equation applies. kCt =1 ? (1-R) 1/3 Alternatively a process is controlled by diffusion through the product layer the following equation applies: [kt = 1 23- X (1 ? X) 2/3] As the anodic dissolution reaction progresses, reaction product forms either a more or less dense reaction product layer on surface As this product layer forms, a diffusion problem develops governed by the nature of the product layer. The conclusion from the study was that the kinetics is very dependent on the type of ore processed relating to the mineral composition of the ore body.

Jan 1, 2007

By R. P. King

Held on the 22nd March 1972 at Kelvin House. Four papers were presented at this colloquium, which was attended by approximately 120 people. The first paper, 'Flotation Research Work at the N.I.M. research group, University of Natal on the modelling of a Flotation Process' was presented by Dr R. P. King, the leader of the N.I.M. Research Group in the Department of Chemical Engineering at the University of Natal. A discussion panel, under the chairmanship of Dr R. E. Robinson with Mr M. Dawson (PMC), Mr E. Roux (FOSKOR), and Dr B. K. Loveday (NIM), discussed the potential application of the theoretical work on flotation modelling to industrial processes, and alternative approaches to providing a way of control of flotation plants. The second paper, 'Fundamental Studies of the Flotation Process the Work of the National Institute) for Metallurgy', was presented by Dr N. P. Finkelstein. The discussion panel for this paper was under the chairmanship of Professor D. D. Howat,and had as its members Mr H. P. Carlisle (JCI), Professor D. le Roux (University of Pretoria), and Mr E. Rudolph (Anglo American Research Laboratories). A lively discussion on this paper ensued, with several contributions from the floor. After lunch, Mr S. K. de Kok, Assistant Consulting Metallurgist, Anglo Vaal, presented a paper on 'The Flotation of Copper and Zinc Sulphide from Prieska Ore'. The paper was discussed by a panel comprising Dr V. C. Lovell (NIM), Mr A. Gilbert (General Mining), and Dr D. Legge (Anglo Vaal), under the chairmanship of Dr L. Bushell. This discussion, in which many members of the audience participated, revolved around the difficulties associated with the production of copper and zinc concentrates and the lack of fundamental information on the behaviour of copper and zinc sulphides in flotation. The final presentati0n was a paper, 'The Recovery by Flotation of Cassiterite contained in Gravity Concentration Plant Tailings', presented by Mr E. B. Viljoen (Metallurgy Department, Goldfields South Africa Limited). The discussion, led by a panel consisting of Mr O. Tant (Goldfields Laboratories), Mr J. Levin (NIM), and Mr R. I. Shanks (NIM), under the chairmanship of Mr H. Cross (Goldfields South Africa Limited) referred particularly to the use of new reagents for the flotation of tin, with particular emphasis on the fundamental relationship between reagent composition and its ability to float this type of mineral.

Jan 4, 1972

By N. W. Munro

SYNOPSIS Certain disadvantages associated with the use of Anfex have been raised on previous occasions. This interim investigation shows that by loading at lower pressures the sensitivity to initiation of Anfex can be improved. Associated with this is a reduction in velocity of detonation and charge density which should lead to more desirable fragmentation. The effect of lower loading pressure on other factors is also considered. INTRODUCTION Discussion at the Symposium on the use of Anfex in Underground Mining, conducted by the South African Institute of Mining and Metallurgy during May 1968 showed that there was considerable uncertainty and diversity of opinion on the characteristics of Anfex and its method of application. Some of the disadvantages associated with the use of Anfex were: Inadequate sensitivity to initiation; Excessive fragmentation of the rock and damage to the hanging and footwalls; Wastage as a result of blow-back; Poor water resistance. As a result of this, further investigations on the properties of Anfex have been carried out and, although these have not reached finality, it is considered that a progress review may be of interest and assistance to the mining industry. EXPERIMENTAL TECHNIQUE The work was carried out on a laboratory-scale where, for test purposes, the explosive was loaded into 1 in. (nominal) internal diameter steel pipes unless otherwise stated. Charging was conducted with a 1 in. (nominal) Schutte-Koerting eductor having a 0.2 in. internal diameter venturi nozzle, the Anfex being fed into the eductor from a conical hopper fitted directly above it. A 5 ft long copper loading tube with outside and internal diameters of 3/4 in. and 5/8 in., respectively, was fitted to the discharge end of the eductor. The remote end of the loading tube was inserted into the test pipe so that it was about 6 to 8 in. from the closed end of the pipe. The loading apparatus was withdrawn as the pipe filled, maintaining approximately the same stand-off distance throughout the operation. REVIEW Sensitivity to initiation Sensitivity of Anfex to initiation was found to deteriorate when the dynamic pressure of the air to the eductor was increased. This was attributed to increasing charge density and it was found that at a charge density of about 1.05 g/cm3, which

1. Mintek publications The folowing are available from Mintek (Private Bag X3015, Randburg, 2125 South Africa) at R35 (including GST) per copy to purchasers in South Africa and US$30 (including airmail postage) to purchasers elsewhere. Report M402 The preparation of synthetic fusion standards for use in the X-ray-fluorescence analysis of rocks and minerals, by RT. Eddy and J.J. Jacobs. Apr. 1990. 19 pp. Report M405 Slag-metal equilibria in the system Fe-Cr-Si-C-Ca-Mg-AI-O, by R.H. Eric and M. Akyizli. Aug. 1990. 29pp. Application Report no. 8 The development of a process for the recovery of gold from gold-bearing solutions by means of activated carbon or resin in a NIMCIX column. 1990. 19 pp. 2. New publications from Trans Tech The folowing are available from Trans Tech Publications Ltd, Old Post Road, Brookfield VT05036, USA. Efect of iron and silicon in aluminium and its aloys, edited by I. Kovacs. 1990. 450 pp. $124. Martensitic transformations, edited by B'.C. Muddle. 1990. 714 pp. $190. Ferites, edited by C.M. Srivastava. 1989. 2 vols. 1280 pp. $254. Properties and characterization of amorphous carbon films, edited by J.J. Pouch and S.A. Alterovitz. 1990. 714 pp. $152. Synthesis and properties of boron nitride, edited by J.J. Pouch and S.A. Alterovitz. 1990.426 pp. $192. Electronic structure and latice defects in aloys, edited by R. W. Siegel and F .E. Fujita. 1989. 320 pp. $78. 3. A new edition Tomorow's materials, by K.E. Easterling. London, The Institute of Metals (1 Carlton House Terace, London SWIY 5DB, England), 1990. 2nd ed. 170pp. US$29. 4. Books for exploration geologists The folowing books are obtainable from Elsevier Science Publishers, P .0. Box 211, 1000 AE Amsterdam, The Netherlands. Lateritic bauxites, by G. Bardossy and G.J.J. Aleva. 1990. 624 pp. DFL. 295. Platinum-group element exploration, by D.L. Buchanan. 1988. 186pp. DFL 150. Lead isotopes in mineral exploration, by B.L. Gulson. 1986. 246 pp. Dfl. 160. Prospecting and exploration of mineral deposits, by M. Kuzvart and M. B6hmer. DFL. 285. 5. Journal for earth scientists . Ore Geology Reviews, published by Elsevier Science Publishers, P.O. Box 211, 1000 AE Amsterdam, Netherlands. 6 issues per year. Annual subscription DFL 453 including postage.

Jan 1, 1990

By R. C. J. Goode, W. S. Rapson, W. R. Lawrie, L. W. P. Van Der Bosch

W. R. Lawrie (Member): As all the Institute members present are aware, the Ninth Commonwealth Mining and Metallurgical Congress was held in Great Britain from 3rd to 24th May, 1969. The Congress opened in London and the first week was devoted to technical sessions. Several receptions and other forms of entertainment were held in the evenings. The Congress was attended by some 1 200 delegates, many of whom were accompanied by their wives. As can be imagined a large organisation was needed to cater for all the whims of these delegates, to arrange accommodation and to provide transport for the technical trips, for the receptions and for the sight-seeing tours. Papers presented at the technical sessions proved of great interest. It was stimulating to hear of the developments taking place in the various branches of mining and metallurgy. The discussions which developed between men from so many different countries were thought provoking, led to new friendships and most of us made valuable contacts for the future. There were 141 papers presented in the one week. They were given in four separate halls with two, three and sometimes four papers coming up for discussion in each of the three sessions per day in each hall. Among the more interesting subjects were those concerning off-shore drilling and the facilities for production of petroleum and natural gas. Beach mining at Consolidated Diamond Mines drew a large audience. Automation, mechanization and other technical developments were well described and we were brought up to date with modern techniques of mineral prospecting. There was general discussion on the future of the mineral industries together with comments on the consumption and price trends of these metals and minerals. The future of uranium, of vital interest to us in South Africa, came in for much debate. During the first week, besides attending the technical sessions and seeing some of the sights of London, we were royally entertained. There was a banquet, attended by some I 400 people, where we were welcomed by Princess Alexandra, a reception by H.M. Government in the Banqueting House, and we were entertained at the House of Lords on a terrace overlooking the bustling and rather muddy river Thames. Then there was the visit to the Glyndebourne Opera. It is only in London that at 3 o'clock of an afternoon, nearly 1 000 people all togged up in dress suits and long dresses and carrying packets of sandwiches for supper could arrive at a station to catch a train, and not even cause a stir of interest or a raised eyebrow! This is the way we travelled 60 miles to the opera from London. Surely there can be no more picturesque or romantic a setting for an opera than this large 400-year old red brick manor house nestling in the green valleys of the unspoilt Sussex countryside. It was a glorious evening and though we returned somewhat late and tired, not one of us would have missed this experience. After the first week in London there was a choice of tours of one week to London and the Home Counties, Cornwall, a Geological tour to Scotland, South Wales, and North England. These were followed by further one week tours to Yorkshire and Lancashire, Scotland, West Country and Midlands, a Geological tour of Wales, and a Mining and Geological tour to Jurassic Iron Mines. We then returned to London for the final session and closing banquet. Post-congress tours were arranged to Europe and to Ireland. It was a wonderful Congress, a great experience, we made many friends and may there be many more congresses! . L. W. P. van den Bosch (Member): Much has already been said in appreciation of the excellent organisation and arrangements made for the delegates who attended this Congress. This report is confined to a brief discussion of the personal impressions gained from the papers presented and the technical visits attended. The papers covered a wide variety of subjects ranging from highly theoretical observations to practical descriptions of operations. There were three main themes, VIZ: 1. The attention given to research and its forceful application to practical operation. 2. A steady development in mechanization and automation leading to savings in manpower. 3. Improvization, modernization and adaptation of exisitng facilities. Thoughts on these themes can best be illustrated by comments on some of the industries visited. COAL The National Coal Board (N.C.B.) has been most progressive and all of us have heard of the Bevercotes Colliery with its completely automatic mining and coal handling equipment. This was not, unfortunately, on show but there is no doubt that this is one of the greatest advances in coal mining leading towards continuous production. Coal in Britain is fighting for its life against oil, North Sea gas, imported gases and nuclear power. Output is dropping, the less efficient collieries are closing down and efficiencies are steadily rising as the following tabulation indicates: In 1931: 1 million men produced 300 million tons of coal In 1947: 0.7 million men produced 230 million tons of coal In 1968: 0.4 million men produced 160 million tons of coal

By H. W. J. P. Neomagus, J. R. Bunt, T. S. Mthombo, C. A. Strydom

"Low-cost calcium lignosulphonate (CL), which is a byproduct of the wood pulping industry, was investigated as a potential binder during laboratoryscale pelletization of inertinite-rich high-ash coal fines from the Highveld Coalfield of South Africa. Coal-binder mixtures containing between 1 and 15% calcium lignosulphonate were prepared, pressed, and ultimate, proximate, porosity, XRD, and XRF analyses obtained. It was found that increased pressure during pelletization results in increased attractive forces, due to increased interparticle contact areas. FTIR analysis showed that chemical interactions occur between coal fines and the binder, as evidenced by the formation of new C-O ether-type bonds. The presence of moisture during pelletization enhanced surfactant activity of the binder. Chemical interactions between the coal and the binder seem to be mainly electrostatic, driven by Ca2+ from the calcium lignosulphonate, which may act as a bridge between the anionic parts of the binder and the surface of the coal. IntroductionCoal has over the years remained South Africa’s major energy source, with over 90% of the country’s electricity being produced via coal-fired processes (Arndt et al., 2016). Sasol’s coal conversion technology alone provides more than 40% of South Africa’s liquid fuel requirements (van Dyk, Keyser, and Coertzen, 2006). The production of high-grade coal requires the processing of run-of-mine (ROM) resources by a combination of processes which include crushing, screening, and washing (Radloff, Kirsten, and Anderson, 2003). These processes result in the generation of coal fines (< 0.5 mm) which, until recently, have been discarded into slimes dams (le Roux, Campbell, and Smit, 2012). Several issues are associated with slimes dams, among which are the costs of transportation of these fines from the place of origin to the discard point (often a considerable distance), and the potential environmental effects due to seepage of toxic materials into surrounding ecosystems (Clausen, 1973).Consequently, utilization of these coal fines is an area of great interest. Mechanical densification of fine coal by means of pelletization and/or briquetting to larger sizes for use in technologies that require lump coal, such as chain-grate stokers and fixed-bed gasifiers, has been shown not only to reduce environmental risks (Mangena et al., 2004), but also to significantly reduce storage and transportation costs (Mani et al., 2001). Pelletization is the process by which solid particles are consolidated into uniform, usually hard, impact-resistant agglomerates, rendering them useful as a fuel with sufficient calorific value for domestic and industrial utilization (Finney, Sharifi, and Swithenbank, 2009)."

Dec 1, 2018

Written contribution by J.F. Curtist The paper is an interesting exercise in the application of mathematics to a theoretical situation presumed to oc¬cur underground. However, some of the assumptions on which the calculations are based are unlikely to occur in any actual mining situation. Assumptions made in the paper Objections to these assumptions are noted seriatim. (1) `it is assumed that any loading-rate effect will be small and can be ignored&apos; (p. 3). A loading rate of the order of 50 kN-12 per cent of the maximum load-is customary to prevent the props being dislodged by the blast. (2) `it is unlikely that all the props will be installed with their full stroke available, but for the purpose of this analysis, it is assumed that this is the case&apos; (p. 3). A more reasonable assumption would be that, with the most careful selection of prop length and the most rigid control of stope width, the available stroke length would on average be reduced by the order of 70 mm on installation-20 per cent of full stroke. (3) `each support unit supports a block of 3,3 m2 bound¬ed by vertical fractures with zero cohesion that are parallel and at right-angles to the stope face respec¬tively&apos; (p. 5). Joughin and Jager have shown this to be an unwar¬ranted assumption in respect of the positioning, the direction, and the dip of the fractures present in a stope in rockburst conditions. If, as assumed, there was `zero cohesion&apos; between such blocks, the removal of a hydraulic prop in row 3 supporting such a block would ensure that it fell out before a profile prop could be installed in the same position. (4) `the height of each of these blocks is 3,0 m, the volume of each block is 9,9M3, the mass of each block is 27 225 kg&apos; (p. 5). The concept of individual props being affected by dis¬crete blocks of known and uniform dimensions of relatively low ground velocities (less than or equal to 2,16 m/s) acting in line with the axis of the prop is one that lends itself to neat mathematical calcula¬tions. It does not, however, bear much similarity to the actual conditions that are exposed underground in excavations where rockbursts occur. Ortlepp and co-workers concluded that `the impulse of the shockwave can cause the displacement of the

Jan 1, 1991

By J. Levin

Bond&apos;s Standard Work Index (SWi) indicates the grindability of an ore, and his Operating Work Index (OWI) indicates the performance of a grinding mil or circuit. The comparison of the two indices offers a measure of the efficiency of the grinding operation. Mil (or circuit) performance, particularly on the Witwatersrand, is often indicated by the index kilowatt -hours per tonne of minus 75 µm material produced (kWh/t minus 75µm or OE75)&apos; The paper shows that a standard kWh/t minus 75 µm index (SE75) can be obtained from the standard Bond grindability test (which provides the SWi), and asks whether the two E75 indices can be used in the various ways in which the two Work Indices are used. For the answer, the paper presents averaged values for the standard grindability indices of the gold ores of the Witwatersrand, averaged values for the performance of grinding mils operating on those ores, and the results of laboratory grinding tests on a composite of several Witwatersrand ores. The particle-size indicator for the calculation of the Wi indices, the am size, is constant in its relation to the largest particles present, whereas the percentage minus 75 µm, the indicator of size for the E75 index, varies with the degree of grinding in its relation to the size of the largest particles. Because of this difference, the standard Work Index increases as the grind becomes finer, whereas the standard kWh/t minus 75 µ value decreases. The Wi and E75 indices nevertheless serve similar purposes when applied to moderately fine grinding-finer than 70 per cent minus 75 µm. Open circuit laboratory grinding tests revealed three stages in the grinding process, and credible values for the open circuit Work Index were obtained only from the second stage. The conversion of the open circuit Work Indices to the equivalent of close circuit indices by the application of Bonds open circuit inefficiency factor (a constant for grinds indicated by the d80 size) was of limited success; however, the development of a conversion factor related to particle-size should not be difficult. Initially difficulty was experienced in the calculation of the 0E75 indices from the results of the laboratory tests, but it was eventually considered that a constant value of the index derived from the results would be close to the true open-circuit index. The open-circuit grinding test could there fore be a convenient method for the detection of differences in the grindability of ores.

Jan 1, 1992

By J. N. Van der Merwe

Following the Coalbrook disaster in 1960, research into coal pillar strength resulted in the adoption of the concept of a safety factor for the design of stable pillars in South African coal mining. At the time when the original statistical analysis was performed by Salamon and Munro in the early 1960s, 27 cases of failed pillar workings were considered suitable for inclusion in the database of failed pillars. Pillar failure did not stop after the introduction of the safety factor formula by Salamon and Munro (1967). In the ensuing years, pillars that were created before the application of the formula deteriorated and later failed, as did ones that were created after the introduction of the formula. This means that over time, the database of failed pillar cases increased in size, allowing ever more reliable analyses to be performed. The number of failed cases in the database had grown from the original 27 in the 1960s to 86 by 2011. All the failed cases are contained in the updated database. The database of stable pillars, which is also used in the derivation of strength formulae, has now been extended from 125 to 337 cases. The new database of intact pillar cases is more complete as it bridges the time gap between the Salamon and Munro (1967) and the Van der Merwe (2006) databases. The original requirements for inclusion into the database were satisfied in the compilation of this latest collection. The characteristics of the original database of intact pillars did not change in a meaningful way. The mining depth and pillar dimensions of the new database are largely as they were in the original database. Time-related trends with regard to pillar dimensions and depth of mining could not be found, indicating that the geometrical parameters of coal mining in South Africa have not changed meaningfully in approximately a century of mining. The characteristics of cases in the updated database of failed pillars does not differ substantially from the one published by Van der Merwe (2006). The same difference between that database and the original Salamon and Munro database, namely that the average safety factor of the failed cases had increased dramatically, from 1.0 to 1.5, is still apparent. This may be due to the inclusion of more failures from specific areas that exhibit a disproportionate number of failures at higher safety factors. These areas are the Vaal Basin, Klip River, and Free State coalfields. The new database confirms yet again that there is no correlation between the safety factors of failed pillars and their time of failure. The safety factor on its own is thus not a reliable predictor of longterm stability of pillars. Keywords coal pillar, stable pillar cases, pillar collapse, pillar data base.

Nov 1, 2013

By Franz E. Pawlek

Synopsis This is a summary of investigations in the field of pressure leaching carried out at the Institute for Extractive Metallurgy of the Technical University of Berlin-West during the last seven years. The efficient dispersion of gas in a liquid and its dissolutions as well as the events at the phase boundary when leaching ZnS are reported. At the end two examples are given for the use of pressure leaching in the processing of smelter by-products. INTRODUCTION About 20 years ago, experiments were independently started in Canada and in Berlin on the subject of dissolving sulfidic ores without preliminary treatment by means of leaching under increased oxygen pressure. In Canada ammoniacal solutions were mainly employed, and F. A. Forward and his co-workers were successful in applying this process on a large industrial scale1, 2. This process is used in Fort Saskatchewan to produce about 15,000 tons of Ni per year. In Berlin, investigations were started on leaching with acid solutions3, 4. This process had also been used on a large industrial scale in the D.S.A., but the choice of unfavourable working conditions led to great difficulties, and to giving up this process for industrial use. Later on in Berlin work was carried out especially on the kinetics of pressure leaching 5, 6, 7, 8, 9 and its applications to the processing of smelter by-products, in particular of mattes and speisses10, 11, 12, 13, 14. The dissolution of ores and by-products can be subdivided into four steps: 1. the efficient dispersion of the gas, so that its dissolution occurs over as great a surface area as possible, since only the dissolved oxygen reacts with the solid, 2. the suspension of the solid, so that the entire surface can take part in the reaction, 3. the phase boundary reaction, 4. the removal of the reaction products. The first two steps belong to the field of process engineering and will be discussed from this point of view. The aim of these experiments15 was to find out first of all the limits of efficiency of self-sucking stirrers in solutions of low viscosity with regard to the mass transfer. In addition, the effect of ultrasonics in the same reaction system was studied. The experiments were carried out in a lucite container as shown in Fig. 1. Four baffles of 0.1 d width were in the stirring vessel. The height of these baffles was adjustable. For every experiment one litre of liquid was used. An infinitely variable direct current motor, which was fixed with a hollow shaft, served as the driving power for the stirrer.

By H. J. R. Way

Dr H. J. R. Way: In his reply to my queries Mr Bath still adheres to his statement that it may be possible to replace the estimated R200 million reduction in gold revenue in 1980 by exports of ferro-chromium, and apparently based his conclusion on a growth rate in demand for corrosion resistant steels of 10 per cent per annum in the next few years. As I pointed out at the previous discussion at Middelburg this would entail a production of about one million tons of ferro-chromium in 1980. Exact statistics of South African ferro-chromium production are not available, a fact which is very much to be regretted. But statistics of exports of ferro-chromium are available from "Foreign Trade Statistics" of the Customs and Excise. These show that South Africa exported 99,580 short tons in 1967. The quantity of ferro-chromium consumed in South Africa in 1967 was fairly small and we can therefore assume that the production was 99,580 tons. For this amount to grow to 1,000,000 tons in 1980 would require a growth rate of 19.4 per cent per annum. At 10 per cent this would grow to 344,000 tons and at 7 per cent 240,000 tons. The following growth rates in the form of average trends are pertinent: STEEL - Per annum World steel ingot production - 1957-67 – 6.8 per cent Free-world ingot production - 1957-67 – 6.0 per cent Consumptions of crude steel by four major Free-world Consumers - 1957-67 - 5.6 per cent CHROMITE World production - 1952-67 - 2.5 per cent South African total sales - 1948-67 – 5.4 per cent South African exports - 1948-67 – 3.9 per cent United States consumption, very irregular, but - 1962-67 – 6.5 per cent FERRO-CHROMIUM - Per annum United States consumption - 1952-67 - 6.5 per cent South African exports - 1957-62 - 25.2 per cent South African exports - 1962-66 - 41.9 per cent South African exports - 1966-68 - 21.2 per cent These figures show that exports of ferro-chromium have been growing at a very high rate varying from 21.2 per cent to 41.9 per cent since 1957, but in view of the market situation it seems somewhat doubtful if that high rate can be maintained up to 1980. Of our 1966 exports U.S.A. took 63 per cent which was 53 per cent of their total imports. Their average consumption is trending at a growth rate of 6.5 per cent per annum from 1952-67, but the growth from 1964-66 was 5- 2 per cent and 1966-67, -12 per cent!

Mar 1, 1968

A banquet, attended by 467 members and visitors, was held at the Wanderers Club, Johannesburg, at 8 p.m. on Friday, 21st March, 1969, to celebrate the 75th Anniversary of the founding of the Institute. Introduction of Dr Carel de Wet R. C. J. Goode (President) Dames en here: Ons het &apos;n aantal vooraanstaande gaste in ons midde vanaand en mnr Maxwell sal u later meer van hulle vertel. Dit is my aangename plig om u voor te stel aan sy Edele, die Minister van Mynwese, van Beplanning, en van Gesondheid, Dr de Wet en sy gade, mev de Wet. Sy Edele Dr de Wet het geen bekendstelling nodig nie-alhoewel hy ons minister vir slegs die afgelope twee jaar is, het hy reeds talle funksies van ons Mynbedryf bygewoon en het baie vriende gemaak onder ons. Hy het homself baie bemind onder ons gemaak toe hy Wes-Driefontein onlangs besoek het om hulle ondersteuning en aanmoediging aan te bied in hulle uur van nood. The Honourable Dr de Wet was born in the Free State. He is a grandson of that very famous general Christiaan de Wet, who caused so much pain to the British forces and for so many months so successfully eluded them in the Transvaal and Orange Free State. He was educated at both the Pretoria and Witwatersrand Universities. He first practised medicine at Boksburg and then moved to Vanderbijlpark, so you see he has an early association with gold mining on the Witwatersrand, and in moving to the Vereeniging-Vanderbijlpark district he became closely involved in our coal mining and metallurgical industries. South Africa&apos;s first steel was poured from a l0-ton open hearth furnace belonging to the Union Steel Corporation in Vereeniging in 1913. Dr de Wet has been mayor of Vanderbijlpark and for several years has been their member of parliament. More recently, the Honourable Dr de Wet has filled with great honour that most important office of Ambassador for the Republic of South Africa in London. At present he wears two hats, in that he is Minister of Planning and of Health, but more important is his cloak, that of Minister of Mines, which I trust offers him the greatest comfort. To fulfill these three arduous tasks must demand of him a terrific devotion to duty, and in doing this he carries on that loyal tradition of service to his fatherland so evident in his grandfather. Dames en here, dit is vir my &apos;n groot genoeë om Sy Edele Dr de Wette vra om &apos;n heildronk in te stel op die Instituut vir Mynwese en Metallurgie. Toast to the Institute of Mining and Metallurgy Dr the Honourable C. de Wet (Minister of Mines): Mr President, ladies and gentlemen, Mr President you have introduced me gracefully to this distinguished company and I am appreciative of your remarks. I am fully conscious of the responsibilities that devolve upon me as Minister of Mines in a country where mining makes so vital a contribution to economic progress and development and has, in fact, laid much of the foundation on which our present proud edifice is built. The achievements of the mining and metallurgical industry in its diversified activities arouse feelings equivalent to paternal pride, but let me speedily add that in considering any family relationship that may exist, the Minister of Mines should not be regarded in the role either of a fairy godmother or an indulgent father.

The industrial relations handbook, by A. Pons. Juta (P.O. Box 14373, Kenwyn 7790). 1989. "&apos;"250 pp. Looseleaf binder. R180 + GST. Industrial laser materials processing. World Business Publications Ltd (4th Floor, Britannia House, 960 High Road, London N12 9RY, England). 1989. 180 pp. £310. Mining 1990. Longmans, Financial Times International Year Books, 1989. 592 pp. £90.00. Innovations in materials processing using aqueous, co/oid and surface chemistry, by F.M. Doyle, S. Raghavan, P. Somasundaran, and G.W. Waren (eds.). 300 pp. $125. Light metals 1989, by P.G. Camp bel (ed.). No. of pp. not available. $150. Process control and automation in extractive metalurgy, by R. Partelpoeg and D.C. Himmesoete. 225 $98. Process mineralogy VIl, by D.J. Carson and A.H. Vassiliou (eds.). 4oopp. $150. Super plasticity and super plastic forming, by C.H. Hamilton and N.E. Paton (eds.). 700 pp. $140. Supera/oys 1988, by S. Reichman, D. Duhl, G. Maurer, S. Antolovich, and C. Lund (eds.). 880pp. $99. Surface modification technologies, by T.S. Sudarshan and D.G. Bhat (eds.). 305 pp. $49. World survey of nonferous smelters, by J .C. Taylor and H.R. Traulsen (eds.). 365 pp. $90. Second Parsons International Turbine Conference. London, The Institute of Metals, 1989.270pp. £40. Mineral processing in the United Kingdom. London, Institution of Mining and Metalurgy, 1989. £25. Today&apos;s technology for the mining and metalurgical industries. London, Institution of Mining and Metalurgy, 1989. 623 pp. £60. 1989/1990 E&MJ international directory of mining. Chicago, Mining Information Services (P .0. Box 6500, Chicago, IL 60680, USA). 620 pp. US$95. Advances in project scheduling, edited by R. Stowinski and J. Weglarz. Amsterdam, Elsevier, 1989. 540 pp. Dfl. 270. Proceedings of the 3rd International Conference on Molten Slags and Fluxes. London, Institute of Metals, 1989. 335 pp. £38. Brochure on industrial screens. Obtainable from Philippe Lavernhe, Johnson Filtration Systems S.A., Z.I. Availes-en-Chatelerault, 86538 Naintre, France. 16 pp. Free. Numerical techniques, edited by P. Spiling. London, The Institute of Metals, 1989. 226 pp. £25. Phase diagrams of ternary iron aloys, Part 2, by V. Raghavan. New Delhi, Indian Institute of Metals, 1988. 360 pp. £95 (from the Institute of Metals, London). cas publications These publications are available from the Centre for Resource Studies, Queen&apos;s University, Kingston, Ontario K7L 3N6, Canada. Economic aspects of gold exploration: How much is too much, by B.W. Mackenzie and M. Dogget. 30 pp. $10.00. Mineral exploration and mine development potential in Ontario: Economic guidelines for government policy, by B.W. Mackenzie, M. Bilodeau, and M. Dogget. 180 pp. $25.00. Economic potential of base metal and gold mining in Newfoundland: Assessing the impact of regional developmentpolicy options, by B.W. Mackenzie, M. Bilodeau, and M. Dogget. 188 pp. $25.00. Publications of the AusIMM The folowing publications are available from The Australasian Institute of Mining and Metalurgy, P. O. Box 122, Parkvile, Vic 3052, Australia. Prepayment is required with al orders. The AusIMM 1989 Annual Conference 1989. $A 50. Mineral fuel alternatives and the greenhouse efect. July 1989. A$ 35. NQ gold &apos;89. Apr. 1989. $A 50. Second Large Open Pit Mining Conference. Apr. 1989. $A 50. Explo &apos;88. Nov. 1988. $A45. Mineral deposits of New Zealand, edited by Dr D. Kear. Monograph 13. 244 pp. $A 60. Field geologists&apos; manual, compiled by D.A. Berkman. 3rd edition. 1989. : 350pp. $A45. The rocks speak. Essays in geology-some personal responses of a wiling listener, by Haddon F. King. 300pp. $A45.

Jan 1, 1990

1. Mining directory The mining directory, 1990. Mines and mining equipment companies worldwide. Don Nelson Publications Limited (P.O. Box 193, Barnet, Herts EN4 BLP, England).2. Mintek reports The following reports are available from Mintek, Private Bag X3015, Randburg, 2125 South Africa. They are available at R25 (plus R3,25 GST) per copy to South African addressees, and US$25 per copy (including airmail postage) to addressees elsewhere. There is also an annual-subscription scheme for reports - R400 locally (plus R52 GST) and US$400 (including airmail postage) abroad. The subscription covers al the unrestricted reports published between 1st April and 31st March of successive years, which usualy amount to between 20 and 30. Report M392 Computer programs for optimization by the modified simplex method, by G.L. Moore. Sep. 1989. 25 pp. R25 + R3,25 GST in South Africa; US $25 elsewhere. Report M393 The preparation and certification of fourteen South African silicate rocks for use as reference materials, by E.J. Ring. Sep. 1989.21 pp. R25 + R3,25 GST in South Africa; US $25 elsewhere. Report M395 The separation of trace elements in high-purity rhodium and iridium materials, by R.V.D. Robet and S.M. Graham. Nov. 1989. 10 pp. R25 + R3,25 GST in South Africa; US $25 elsewhere. 3. Publications from Trans Tech The publications listed in this section are available at the prices given from Trans Tech Publications, P .0. Box 1254, D-3392 Clausthal-Zelerfeld, West Germany. Handling of bulk solids. Theory and practice, by P.A. Shamlou. 1988. 200 pp., US$ 59.50. Acoustic emission lmicroseismic activity in geologic structures and materials, by H.R. Hardy and F.W&apos;. Leighton. Vol. I: 1977, 490 pp., US$45.00. Vol. 11: 1980, 500 pp., US$45.00. Vol. Il: 1983, 680pp., US$6O.00. Vol. IV: 1989, 720pp., US$ 75.00. Open pit mine design models. An introduction with FORTRANI77 programs, by E. Alaphia Wright. Early 1990, approx. 200pp., US$75.00. Bucket wheel excavator, by W. Durst and W. Vogt. 988, 450pp., US$118.00. Continuois-surjace mining, by T.S. Golosinski and F.G. Boehm (eds.). 1987, 720pp., US$128.00. Mining-science and technology. 1987, 1430pages, US$ 118.00. Practical handbook for underground rock mechanics, by T.R. Stacey and C.H. Page. 1986, 150pp., US$ 38.00. Professional users handbook for rock bolting, by B. Stilborg. 1986, 150pp., US$38.00. The lighting of underground mines, by D.A. Troter. 1982, 220pp., US$48.00. Elements of hydraulic coal mine design, by M.L. Jeremic. 1982, 16Opp., US$38.00. Continuum theory of rock mechanics, by Cs. Assonyi and R. Richter. 1979, 365 pp., US$ 58.00. Shear and bond in reinforced concrete, by G. Florin.1980, 86 pp., US$ 24.00. Theory and design of surface structures: slabs and plates, by G. Florin. 1980, 222 pp., US$ 24.00. Mineral processing laboratory manual, by A.-Z. Abouzeid. January 1990, approx. 200pp., US$48.00. Weighing and proportioning of bulk solids, by Hendrik Colijn. 2nd ed. 1983, 4OOpp., US$60.00. Solid-liquid flow. Slurry pipeline transportation, E.J. Wasp et al. 1977, 240pp. US$ 58.00. Optimum pipe size selection, by C.B. Nolte. 1978, 304 pp., US$ 60.00.Field instrumentation in geotechnical engineering, T.H. Hanna. 1985, 854pp., US$98.00. The 1990 yearbook and directory. Powder and bulk solids handling and processing. 1989/90, approx. 300 pp., US$ 124.00.

Jan 1, 1990