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By S. Pathak, B. Nilsen

Abstract: In recent years, probabilistic approach with the calculation of probability of failure instead of a factor of safety against failure is emerging in practice. The main objective of the paper is to discuss a probabilistic approach in rock slope stability analysis for Himalayan conditions. Due to the fragile geology brought about by the tectonic movements along the hill slopes, dramatic variations of the topography and intensive surface runoff during every monsoon season, serious slope failures occur frequently in Himalayan region. Slope failures have also been triggered by seismic activities. The probabilistic approach is applied to stability analysis for a road cut along the Desander back slope of the Kali Gandaki hydropower project in Nepal. It is concluded that the probability approach offers a more accurate grasp of the actual condition than any factor of safety. Zusammenfassung: In den letzten Jahren ist es mehr gewöhnlich geworden, ein stochastisches Verfahren und eine Berechnung von der Wahrscheinlichkeit eines Zusammenbruchs statt einer Berechnung von Sicherheitsfaktoren zu verwenden. Das Hauptziel dieses Artikels ist das stochastische Verfahren in Stabilitätsanalyse von Gebirghängen, welches an Himalayische Verhältnisse angewandt worden ist, zu diskutieren. Wegen der spröden Geologie die durch tektonische Bewegungen entstanden ist und den dramatischen topographischen Variationen sowie viel Oberflächenwasser während des Monsuns, kommen in der Region des Himalayas oft mehrere erhebliche Abhangszusammenbrüche vor. Abhangszusammenbruche ist auch von seismische Aktivität ausgelöst worden. Das stochastisches Verfahren ist auch benutzt worden, um die Stabilität von einem Wegschnitt in dem Desander Gebiet von dem Kali Gandaki Wasserwerk-Projekt zu analysieren. Die schlussfolgerung ist, dass die Ergebnisse eines stochastisches Verfahren die wirkliche Verhältnisse eines Abhangs besser beschreibt als der Sicherheitsfaktor. Résumé:- Ces dernières années, une approche probabiliste basée sur le calcul d’une probabilité de cassure au lieu d’un facteur de sécurité préventif d’une cassure est de plus en plus utilisée. L’objectif principal de ce papier est de discuter une approche probabiliste de la stabilité de versants rocheux en himalaya. Due à la fragile géologie causée par les mouvements tectoniques sur les versants de collines, aux dramatiques variations de topographie, ainsi qu’au lessivage intense du relief à chaque mousson, de sérieux glissements de terrains se produisent fréquemment en Himalaya. Les glissements de terrain sont aussi déclenchés par l’activité sismique. Cette approche probabiliste est appliquée aux analyses de stabilité d’une section de route le long du versant arrière Desander du projet « hydropower » du Kali Gandaki au Népal. On en conclut que l’approche probabiliste offre une estimation plus précise des conditions actuelles que n’importe quel facteur de sécurité.

Jan 1, 2003

By G. du T. Judeel

An investigation was carried out to determine whether a numerical model could be constructed that would produce results that realistically represent actual ground deformations in and around a vertical shaft. The ground deformation was brought about by the partial extraction of the shaft pillar. A special characteristic of the rock masses, affected by the shaft pillar extraction, was that the shaft was located in poor quality rock masses. After the extraction of a portion of the shaft pillar, excessive deformations occurred at the shaft/reef intersection. Therefore, a decision was taken to extract the entire shaft pillar protecting the shaft by a proposed waste-cut across the shaft. The effects of stress and displacement on the shaft were investigated by using inelastic numerical modelling in different stages. A calibrated numerical model was constructed producing modelled results comparable to the actual displacements along the shaft. Des recherches ont été poursuivies pour déterminer si on pouvait construire un modèle numérique qui donnerait des résultats représentant avec réalisme les déformations réelles du terrain à l’intérieur et autour d’un puits vertical. La déformation du terrain était entraînée par l’extraction partielle du massif de protection. Une caractéristique spéciale des masses rocheuses, affectées par l’extraction du massif de protection, était que le puits était situé dans des masses rocheuses de qualité inférieure. Après l’extraction d’une portion du massif de protection, des déformations excessives se sont produites à l’intersection du puits avec le filon. Par conséquent, la décision a été prise d’extraire le massif de protection en entier par une coupe de déblais à travers le puits. Les effets de contraintes et décalage furent étudiés en utilisant une modélisation numérique inélastique à des stages différents. Un modèle numérique calibré fut construit, donnant des résultats modelés comparables aux décalages réels le long du puits. Eine Untersuchung wurde durchgeführt um festzustellen, ob ein numerisches Modell konstruiert werden könnte, das Resultate produzieren würde, welche realistisch aktuelle Bodendeformationen in und um einen vertikale Schacht darstellen. Die Bodendeformation resultierte teilweise aus der Extraktion des Schachtpfeiler. Eine spezielle Eigenschaft der Gesteinsmassen, beeinflußt durch die Schachtpfeilerextraktion, war, daß der Schacht in Gesteinsmassen geringer Qualität situiert war. Nach der Extraktion eines Teils der Schachtpfeiler, traten übermäßige Deformationen am Schacht/Riff Kreuzungspunkt auf. Folglich wurde die Entscheidung getroffen, die gesamten Schachtpfosten zu extrahieren und den Schacht mittels eines geplanten Verlustschnittes quer zum Schacht zu schützen. Die Auswirkungen des Druckes und der Versetzung auf den Schacht wurden unter Anwendung unelastischer numerischer Modelle in unterschiedlichen Stadien untersucht. Ein kalibriertes numerisches Modell wurde konstruiert, welches berechenete Ergebnisse mit den tatsächlichen Versetzungen entlang des Schachtes vergleicht.

Jan 1, 2003

By J-C. Lv, S. Zhao, F-L. Zhang, T. Yan

"To eliminate nozzle clogging during continuous casting of ship plate steel and reduce the calcium addition required, the composition of CaO-MgOAl2O3 inclusions in the liquid phase region must be controlled. Thermodynamic calculations using FactSage show that when the balanced Al content is 0.03 mass %, aCa in the liquid steel is 1–10 ppm, and aMg is 0.01–0.3 ppm; and when the balanced Al content is 0.06 mass %, aCa in the liquid steel is 1–30 ppm, and aMg is 0.05–0.9 ppm. The CaO-Al2O3-CaS inclusions can be controlled in the liquid region below 1600°C at aCa values of 5 ppm, 15 ppm, and 30 ppm, and the balanced Al content should be controlled in the range of 0.001–0.050, 0.005–0.250, and 0.010–0.50 mass %, respectively. Based on theoretical analysis, the refining slag composition should be controlled to 45–53 mass % CaO, 30–37 mass % Al2O3, 6–12 mass % SiO2, and 6–8 mass % MgO. Optimization of the slag system and steel composition can reduce, or even eliminate, the requirement for calcium treatment. The total oxygen content in the slab can be controlled to 15–21 ppm, with typical micro-inclusions ??10 ??m in size, with compositions in the CaO-Al2O3-MgO and CaO-Al2O3-CaS systems. Introduction With the rapid growth in steel output in China and the changes in the macroeconomic environment, competition in the steel industry has become more intense. The technology for economical cleaning of high-grade steel is important for improving product quality and reducing production costs. However, the functions of refining equipment have not been fully taken into consideration, and the combination of refining methods has not been optimized completely. These problems have become a bottleneck, restricting modern steel enterprises from developing an economic clean steel production process. Ship plate steel produced by the converter long process has been selected as the example in this study. The composition of the steel is shown in Table I. This steel is a high-strength low-alloy steel for rolling media and heavy plates, mainly used for ocean-going vessels and other steel structures. The carbon content in the steel is far from the peritectic point, and the crack sensitivity of the slab surface is weak, so impurities and gas content are strictly limited. Therefore, the process route BOF (basic oxygen furnace) – LF (ladle furnace) – CC (continuous casting) needs to be studied."

Jan 1, 2018

By Y. P. Shoupletsov

ABSTRACT. A retrospective analysis of some geomechanical classifications for rock masses is presented. It is shown that estimates of rock mass strength according to geomechanical classifications developed, e.g., for construction of tunnels and for ore mines can differ very much. Development of specifically oriented classifications for rock masses with certain geomechanical properties is required. ZUSAMMENFASSUNG. Es wurde eine retrospektive Analyse einiger geomechanoschen Klassifikationen von Gesteinsmassiven durchgefuhrt. Es idt aufgezeigt worden, dass die Bes-timmung der Festigkeit des Massivs nach geomechanischen Klassifikationen, die z.B. fur den Bau von Tunnelen und fur Erzbergwerke entwickelt wurden, sich um etliche Male unterscheiden kann. Es ist eine Entwicklung von spezialisierten Klassifikationen fur Gesteinsmassive mit bestimmten geomechanischen Eigenschaften erforderlich. RESUME. Il a ete fait l’analyse retrospective de certaines classifications geomecaniques des massifs de roche. Il a ete montre que les estimations de solidite du massif suivant les classifications geomecaniques etudiees, par exemple, pour la construction des tunnels et pour les puits de minerai peuvent differer en quelques fois. Il est donc necessaire d’etudier les classifications specialisees pour les massifs aux proprietes geomecaniques particulieres.

Jan 1, 2003

By U. C. Galimidi, J. M. Stewart, A. J. Van Rensburg

The effect of body movement on convective heat transfer from a man performing a block-stepping task was investigated experimentally by direct measurements of convective heat transfer. A series of experiments was conducted in which a nude man was required to stand at rest or to block step at 12 and 24 steps per minute. Wind speed, which was kept constant during each experiment, spanned the range 0,5 to 3,5 m/so Air temperature was kept constant at 43 °C in all the experiments. The results showed conclusively that the convective heat-transfer coefficient depends on the stepping rate. The effect of body motion can be regarded as being equivalent to an increase in the velocity of the free stream. The equivalent increase in air speed was found to be 0,36 and 0,77 m/s for 12 and 24 steps per minute respectively. Data from various sources, including the present study, indicate that wind speed should be increased by about 0,30,0,55, and 0,80 m/s to account for low, moderate, and vigorous body movements respectively. These findings are of direct relevance to the practical assessment of heat stress.

Jan 1, 1979

By W. R. Matizamhuka

"The consolidation of nano-sized composite materials presents a challenge using conventional hot pressing methods. Spark plasma sintering (SPS) technology has shown great promise in the successful sintering of nanoreinforced composite materials. This qualitative review seeks to impart knowledge gathered, and progress made over the years on the consolidation of nanocomposite materials using SPS technology. The review is aimed at introducing this technology to the South African science and engineering community. Emphasis is on improving the mechanical properties of structural ceramic nanocomposite materials, which over the years have shown great promise in a wide range of applications, including transport, energy, mining, and the environment. Although success has been achieved within the laboratory for research purposes, there are still great opportunities to commercialize the technology for the production of larger components with more complex shapes.IntroductionSince the pioneering work of Niihara and Nakahira (1991) over a decade ago there have been extensive attempts to harness the potential of nanostructural metals, ceramics, and composites in a number of applications (Niihara and Nakahira, 1991; Selaho et al., 1997; Sekino and Niihara, 1995; Khalil, 2012; Aalund, 2008). It is generally realized that reducing the grain size of materials to nanoscale offers a significant improvement in properties. Attempts to synthesize nanostructured compacts by conventional sintering methods have not succeeded owing to the uncontrollable high rates of grain growth driven by long dwelling times at the sintering temperatures and large powder surface areas (Sergueeva et al., 2009; Gua, Khora, and Chieng, 2004; Tang et al., 2009). Following the development of spark plasma sintering (SPS) technology, it is now possible to process nanocrystalline materials with controlled grain growth. SPS, also referred to as the field-assisted sintering technique (FAST) or pulsed electric current sintering (PECS), was developed with the aim of improving on the well-established hot pressing (HP) technology (Kessel and Hennicke, 2007;"

Jan 1, 2016

By S. W. Evans, G. Pienaar

Weldable steel plate with a good combination of strength and toughness is currently produced from 0,12 to 0,28 per cent carbon low-alloy steel heat-treated by roller quenching and tempering. Alternatively, steel plate of the same strength can be produced at a lower production cost by the use of very-low-carbon steel (0,03 to 0,08 per cent carbon) processed by in-line quenching without tempering. This paper reports the results of experimental work on these steels, and compares them with the properties of conventional steel. On thinner sections, it was found that the properties of the experimental steels compare favourably with those of conventional grades.

Jan 1, 1989

By Z. Zitron, G. J. de Korte, D. W. Horsfall

This paper summarizes work carried out on the treatment of fine coal, nominally classified as minus 0,5 mm (wedge-wire screen), which is removed from the raw coal prior to the treatment of the plus 0,5 mm sizes. The minus 0,5 mm coal divides, for treatment purposes, into fines, nominally between 500 and 150 !tm, and ultrafines, nominally minus 150 !tm. Studies on processes for the treatment of minus 0,5 mm coal are discussed, and the lower size limit beneficiated is indicated for each process. The installation and operational results from a pilot froth-flotation plant treating minus 150!tm coal are described.

Jan 1, 1986

By M. B. C. Brandt

The near-surface wave attenuation factor k (kappa), which describes the attenuation of seismic waves with distance in the upper 1–3 km of the Earth, was determined for the Far West Rand gold mining area using seismic data recorded by station Parys (PRYS) of the South African National Seismograph Network. Twenty micro-events in the magnitude range 0.7 ? ML ? 1.8 for the period 1 July to 15 November 2015 were analysed. For the analysis a 10-second window for the S phase portion of the vertical component seismogram was selected. The result was an average k = 0.048 ± 0.014 s, which is much higher than for a stable continental region where k = 0.006 s. This is because the assumed Brune source model is inappropriate for describing mining-related events that often have moment tensors with a volumetric (implosive) component. The average k was calculated to be 0.098 ± 0.038 s for explosions of a similar magnitude. This higher value derived for mining-related k may be employed as a means of correcting the Brune source spectrum to calculate seismic moment as well as corner frequency for events in the mining areas of South Africa.

Jan 1, 2017

By A. C. Lawrence, K. F. Mauer

Human factors in stope productivity -a field experiment by K. F. MAUER, M.A. (Visitor), and A. C. LAWRENCE, B.Econ., D.Com. (Member) An experiment in which three human variables were manipulated in eight stopes was conducted in a gold mine over a period of roughly six months. The three variables, which each had two levels, concerned the degree of movement from gangs, the quality of the Bantu production supervisors, and the extent to which gangs were composed of a single ethnic group (Malawians). Time was included as a variable with three levels in the analysis of the findings. On the average, stable gangs produced 12 per cent more than gangs with a high percentage of transfers, gangs with better production supervisors were more successful by nearly 9 per cent than those with poorer production supervisors, and homogeneous gangs were more productive than heterogeneous ones by as much as 15 per cent. In addition, it was found that a number of the variables exercised a joint influence on stope productivity and that the effects of the variables were accentuated by the len gth of time they had been in operation. V

Jan 10, 1973

By K. B. Owusu, W. Skinner, R. K. Asamoah, J. Karageorgos, M. Zanin, C. Greet

High Pressure Grinding Rolls (HPGR) are mostly used prior to pelletising processes to increase the specific surface area (SSA) of iron ore concentrate. For expressing SSA, the Blaine index is utilised as one of the most important dimensional properties of iron ore pellet feed. ISO 21283 is a standard test method that explains the manual of Blaine air-permeability apparatus for determination of this parameter. In this standard, the disaggregation method is based on passing the minus of 1 mm samples from the 0.150 mm sieve. The disaggregation process has an effective role on the results of Blaine airpermeability test especially for regrinding HPGR products. In this research, firstly the Blaine index of samples was measured without disaggregation. Following this, disaggregation was done by passing the minus of 1 mm samples through three sieves with different dimensions, 0.150, 0.090 and 0.045 mm, separately, and the Blaine index was calculated for each one. Finally, lab-mill with rubber balls, called Jar mill, was investigated as another option. Screen analysis and image analysis with SEM were performed to evaluate the effects of the sample's disaggregation on the size distribution and agglomeration of samples. The results showed that the disaggregation method with sieve size 0.150 mm, according to ISO 21283, was not applicable for HPGR products because the particles were still stuck together. In addition, the disaggregation method with the sieve size 0.045 mm or with Jar mill offered reasonable results. Keywords: Disaggregation, Blaine index, specific surface area, regrinding HPGR, ISO 21283, Jar mill

Jan 1, 2020

By B. Besa, S. Nalukui

Globally, the demand for mineral products is ever increasing. Extraction of these mineral resources results in the continuous production of a huge volume of waste material, including tailing dumps. The mass of tailings usually exceeds the actual resource and often contains hazardous contaminants. This study investigated the effects of tailings disposal on soil, water, and air quality in the Nampundwe area. Water, soil, and dust samples were collected from different locations in the surrounding communities. The constituents analysed in the samples included copper, cobalt, iron, sulfate, and silica. According to the results obtained, some seepages occurred from the tailings impoundment to the shallow aquifer in the area. However, the general water quality meets the Zambia Environmental Management Agency (ZEMA) statutory limits. Recorded concentrations of sulfate (1500 mg/l), copper (1.5 mg/l), cobalt (1.0 mg/l), iron (2.0 mg/l), and silica were between 0.003 mg/l and 705 mg/l, which is far below ZEMA’s statutory limit. Silica concentration was also evident in the air. The highest concentration recorded was 260 ppcc (particle per cubic centimeter) recorded in July 2019 from the northern direction of the tailings dam. The concentration was below the statutory limit of 350 ppcc. The topsoil from the northern part of the tailings recorded a silica dust concentration of 39.9 ppcc. Iron was evident in the underground soil with a concentration of 8.01 ppcc, cobalt 0.005 ppcc, copper 0.051 ppcc, while sulfate was recorded as 0.41 ppcc.

Oct 9, 2024

By Y. Mitani, M. Zhang, M. Takeda, T. Esaki

Despite their inadequacy, assumptions of isotropy and homogeneity are often applied to the analyses of in situ permeability tests. In this paper, we exam the effects of anisotropy and heterogeneity on Pressure Pulse Test (PPT) and Constant Head Injection Test (CHIT) by means of numerical approaches. Some new findings that offer practical considerations in properly interpreting in-situ permeability tests are presented. Malgré leur manque de précision inhérente, les assomptions d'anisotropie et d'hétérogénéité sont souvent utilisées lors de test de perméabilité in situ. Dans cette étude, nous examinons les effets de l'anisotropie et de l'hétérogénéité sur le test par pression pulsée et le test à injection à charge hydraulique constante par le biais de la simulation numérique. Des nouveaux résultats permettant une interprétation pratique et claire des test de perméabilité in-situ sont présentés. Trotz ihrer inhärenten Ungeeignetheit werden häufig Annahmen über Isotropie und Homogenität auf Analysen von in-situ Permeabilitätstests angewendet. In diesem Papier untersuchen wir die Effekte von Anisotropie und Heterogenität auf Durck-Impuls-Test (PPT) und Konstant-Kopf-Einspritztest (CHIT) mit numerischen Ansätzen. Einige neue Befunde, die zu praktischen Erwägungen zur richtigen Interpretation von in-situ Permeabilitätstests führen, werden vorgestellt.

Jan 1, 2003

By J. H. van Dalen, P. J. Brandt, F. W. Wessels

A maximum of ten process streams (Merrill barren solutions) can be monitored sequentially with this on-line analyser, and gold concentrations as Iow as 0,005 mg/I can be determined. The design is a further development of the Tell-tale analyser constructed by the Corner House Laboratories during the period 1965-69. The barren solution is preconcentrated automatically by solvent extraction, the solvent being a solution of I per cent Aliquat 336 in di-isobutyl ketone. An aqueous-to-solvent ratio of 40: I is maintained. The extracted gold in the organic phase is determined by flame atomic absorption, each analysis taking approximately II minutes. The long-term reproducibility of the absorbance readings over a 24-hour period of repetitive sampling of four simulated process streams varied from 6,9 to 4,1 per cent relative standard deviation for gold concentrations of 0,0 I to 0,05 mg/I.

Jan 1, 1980

By M. Coetzee

The susceptibility of experimental low-nickel Cr-Mn-N stainless steels to hot cracking, sensitization, and pitting corrosion in the as-welded condition was investigated. These steels were developed for deep-drawing applications and are similar in composition to type 201 stainless steel. In order to obtain good formability, the rapid rate of work-hardening (characteristic of the 200-series steels) was decreased by the addition of copper. The behaviour of two sets of alloys during fusion welding was investigated: 17Cr-7Mn-4Ni-o.5Cu steels containing 0.001 to 0.27 per cent nitrogen, and 17Cr-7Mn-2Ni-o.1N steels with copper contents varying between 0.01 and 3.11 per cent. Al the steels in these two sets initially solidify as d-ferrite, which transforms partially to austenite during cooling. As the nitrogen level increases, the microstructure of an autogenous-weld metal ranges from large amounts of d -ferrite, martensite, and Widmanstätten austenite, to austenitic structures with small amounts of vermicular d -ferrite. The formation of d -ferrite during solidification and the presence of ferrite retained in the weld metal indicate that the experimental alloys will not be susceptible to hot cracking during welding. Except for the alloy with 0.27 per cent nitrogen, the resistance to pitting corrosion of the experimental steels in the as-welded condition is inferior to that of type 304 stainless steel. None of the experimental steels is susceptible to intergranular attack in the as welded condition. The alloys with 0.19 and 0.27 per cent nitrogen have properties (corrosion and microstructure) similar to those of type 304 stainless steel in the as-welded condition.

Jan 1, 1996

By M. C. J. van der Merwe

"Carboxymethyl cellulose is an organic binder used in the iron ore pelletizing industry. The basic principles of how carboxymethyl cellulose (CMC) solutions behave during the pelletizing process and how these principles affect the drop and compression strengths of the pellets are poorly understood. The aim of the investigation was therefore to gain knowledge on the behaviour of CMC during the pelletizing of haematite concentrate.Haematite pellets with different additions of CMC (0.1–0.4 wt%), were subjected to drop tests, compression tests, and free moisture content analysis. The relationship between the drop strength, compression strength, free moisture content, elapsed time, and CMC concentration was analysed.The drop strength had a strong correlation with the free moisture content of the haematite pellets, with a correlation coefficient of 0.94. The compression strength of the CMC-bonded haematite pellets increased as the free moisture content decreased, reaching a maximum upon depletion of the free moisture content. Haematite pellets with CMC concentrations of 0.1 and 0.2 wt% developed most of their strength within the first day after pelletizing, whereas pellets with concentrations of 0.3 and 0.4 wt% developed most of their strength between one and two days after pelletizing. The time within which CMC-bonded haematite pellets develop most of their strength is therefore dependent on the CMC concentration. IntroductionFines are produced during the beneficiation of iron ore. These fines are separated from the lump ore and can be upgraded to produce a concentrate, which is used as a raw material for the production of pellets. Pellets in turn form a key burden material for direct reduction processes as well as the blast furnace (Zhu et al., 2015).Inorganic binders such as bentonite have been used predominantly in the iron ore pelletizing process to obtain pellets with suitable properties (Eisele and Kawatra, 2003). These binders, however, have the disadvantage of introducing impurities into the pellets. This has resulted in organic binders being pursued as suitable replacements for inorganic binders, of which carboxymethyl cellulose (CMC) shows good potential. Although CMC has been used as an organic binder in iron ore pelletizing, the fundamental principles of how it behaves during pelletizing and how these impact on pellet properties are poorly understood."

Jan 1, 2017

By I. V. Samarasekera, E. B. Hawbolt

A review of recent work being conducted at the university of British Columbia on the modeling of the microstructural evolution during the hot rolling of steel is presented. A mathematical model of heat transfer was developed to describe the thermal field in a slab during rough and finish rolling. The model for rough rolling, discussed in this review, also simulates the growth of oxide scale on the slab surface. To quantify the heat transferred from the slab to the work rolls, instrumented samples of MSI3O4 L stainless steel, 0,05 per cent carbon steel, and 0,05 per cent carbon steel with 0,025 per cent

Jan 1, 1995

By L. S. Linda, P. G. H Pistorius

Ferritic stainless steel is utilized to fabricate automotive exhaust systems using a ferritic weld metal. Ductility of the weld metal is higher if its microstructure contains a significant proportion of equiaxed grains. The formation of equiaxed (rather than columnar) grains is favoured by a higher titanium weld metal content. In this study, the Ti content of ferritic stainless steel weld metal was changed by using Tifree (Type 436) and Ti-containing (441) ferritic stainless steel as base metals. The metal-cored welding consumable contained 0.4% Ti. Gas–tungsten arc welding and gas–metal arc welding processes were compared. The weld metal Ti content ranged from zero to 0.5% Ti, as determined from scanning electron microscopy supplemented by inductively coupled plasma optical emission spectroscopy. Cross-sections of the weld beads were subjected to point counting (to estimate the fraction of equiaxed grains) and image analysis (to estimate the average grain size). Point counting proved to be more reliable. The fraction of equiaxed grains was sensitive to the Ti content, but not to the welding process. Below 0.4% Ti, the fraction of equiaxed grains gradually increased with an increase in the weld metal Ti content; above 0.4% Ti, the fraction of equiaxed grains rapidly increased with increasing Ti content. The transition in behaviour at 0.4% Ti corresponded to a Ti content at which Ti-rich precipitates became stable at the estimated liquidus temperature of the weld metal.

Jul 2, 2022

By S. Fuchida, Y. O. Zubair, C. Tokoro

Mining of As-bearing minerals had resulted in the release of arsenic species predominantly As(III), which is known to be more toxic, and undue exposure to it is detrimental to human organ systems. Many materials have been examined for As(III) removal, but it is still challenging to advance sustainable materials for effective removal of As(III). In this paper, a more eco-friendly and superparamagnetic Fe0-Fe3O4 composite was synthesised and evaluated for heterogeneous catalytic oxidation and removal of As(III) with peroxymonosulfate (PMS, KHSO5). The kinetic removal studies showed that removal of As(III) was probably through a chemical process and the Elovich model best represented the experimental data. The removal capacity for As(III) on Fe0-Fe3O4 with PMS (1.76 mmol/g) is superior to that without PMS (0.83 mmol/g). Combined results from XPS and ESR showed that As(III) was fully transformed to As(V) through catalytic oxidation by Fe0-Fe3O4/PMS and afterwards enhanced its removal. The removal mechanism of arsenic was ascribed to the formation of outer-sphere (electrostatic attraction) and inner-sphere complexes. The adsorbent can be separated easily from water due to its excellent magnetisation (64.5 emu/g) and also has good reusability potential as more than 85% of the initial concentration of As(III) was immobilised after five consecutive cycles. Keywords: Arsenite, Fe0-Fe3O4 composite, catalytic oxidation, removal mechanism

Jan 1, 2020

By S. Stuurman

Inorganic acids such as sulphuric acid have found use together with certain reducing agents in leaching of copper-cobalt oxide ores. These reagents are not ideal due to the adverse effect the inorganic acids generally have on the environment and the high costs of the reducing agents. In this study a copper-cobalt oxide ore from the Central African Copperbelt was leached in two different environments; sulphuric acid in conjunction with hydrogen peroxide as a reducing agent and tartaric acid. The effects of acid concentration, reducing agent concentration, and temperature were independently determined for both leaching environments. The sulphuric acid concentration was varied between 0.4 M and 1.2 M and the concentration of hydrogen peroxide between 4.0 M and 6.5 M, while the tartaric acid concentration was varied between 0.15 M and 0.35 M. The temperature was varied between 20°C and 50°C. The results showed that the extraction of both copper and cobalt increased with sulphuric acid concentration, reaching a peak at approximately 0.8 M and then decreasing at higher acid concentrations. A similar increase and decrease in metal extraction was observed when the reducing agent was increased. In leaching with tartaric acid, the extraction of cobalt was much higher than that of copper, although extraction of both metals increased with acid concentration. Additions of small amounts of hydrogen peroxide were found to increase cobalt extraction in tartaric acid but had a minimal effect on copper. An increase in the solution temperature had a significant effect in the organic acid environment, with the effect on cobalt extraction being much more pronounced than on copper.

Jan 1, 2014