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By Peter S. Jack

"IntroductionTHE ORES treated at the concentrator of the Britannia Mining and Smelting Company, Limited, Britannia Beach, B.C., have always contained some lead, but it was not until 1950 that the combination of lead headings and lead price was such that recovery of this metal at Britannia became worthwhile. In that year, with the mining of a new orebody, the lead in the mill feed was raised from 0.07 per cent to 0.15 per cent. Chalcopyrite, sphalerite, and pyrite concentrates are produced by flotation at Britannia, •and 95 per cent of the lead in the mill feed reports with the chalcopyrite concentrate, so that the rise in lead headings was reflected almost wholly in the lead content of the copper concentrate. In 1950, investigation was started to determine if some of this lead could be recovered economically."

Jan 1, 1953

By T. Guan, G. Fu, X. Zhou, L. Deng

"Currently, tailings water is required to be recycled in minerals processing plants. When the flotation tailings water of complex copper-sulfur-tungsten polymetallic ore is reused to the flotation of copper-sulfur ore, a portion of tungsten would be lost in copper concentrate or sulfur concentrate due to the addition of the collectors used for oxidized ore which are also effective for the sulfide minerals in the process of tungsten flotation. At the same time, the technical index of copper concentrate and sulfur concentrate would be seriously affected by tailings water. Our experimental researches of many years show that the copper concentrate with a grade of 18.36% Cu at a recovery of 76.67% is obtained for the raw ore containing 0.60% Cu, 18.99% S, 0.16% WO3 in small locked cycle test using recycled water, through simple pretreatment of the tailings water from tungsten flotation and adding special regulator CW and new tungsten collector TM. The result is close to the performance without using tailings water. And, in the continuous pilot experiment which was continuously conducted for 4 days with the same technology, the following results was obtained: the copper concentrate with a grade of 21.74% Cu, the recovery was 71.55%; the sulfur concentrate with a grade of 45.16% S, the recovery was 80.10%; the tungsten concentrate with a grade of 42.63% WO3, the recovery was 54.62% relative to raw ore (the recovery relative to scheelite was 76.47%). The throughput of the continuous pilot experiment is 1.0~1.2 t/d, and the raw ore contains 0.56% Cu, 18.80% S, 0.14% WO3 on average.INTRODUCTIONMining industry is one of the most important developing fields, it supplies raw materials for industrial production as well as discharges much waste water. Tailings water is the main source of beneficiation waste water, it would result in severe environmental pollution if discharged directly. Generally, the tailings water would bring undesirable effect on flotation index after simple pretreatment by lime (Kalin, Fyson, & Wheeler, 2006). On the other hand, the treatment of tailings water through ion-exchange (Cui & Liu, 2015) before recycling is of high cost. Generally, in the flotation of Cu-S-W polymetallic ore, when the tailings water from tungsten flotation is treated simply by lime and recycled to the flotation of sulfide minerals, the flotation index of sulfide minerals decreases, and a portion of oxide mineral would be lost in the sulfide concentrate. As a result, the recycle rate of this kind of tailings water is relatively low, some of the tailings water is discharged after simple treatment and then environmental pollution is caused subsequently. One of the effective ways to improve beneficiation performance and increase the recycle rate of tailings water is to conduct research on developing recycle technology for flotation tailings water of complex copper-sulfur-tungsten polymetallic ore."

Jan 1, 2016

By Jin-Hwa Song

Rolling temperatures and cross rolling ratios were varied to investigate the effect of crystallographic texture of alpha-phase on the anisotropy of mechanical properties in modified Ti-6A1-4V alloy. Hot rolling method was unidirectional and cross rolling, during which the rolling temperature was in the range of 830°C and 920°C. Cross rolling ratios were varied from 0.3 to 1.0 at 875°C. For unidirectional rolling, as the rolling temperature increased texture changed from the mixed basal and transverse texture to the simple transverse texture. Contrary to other work, it was observed that the maximum intensity of transverse components increased with the increase in rolling temperature. For cross rolling, on the other hand, the transverse texture component was almost suppressed at 830°C, giving rise to a symmetrical basal texture. With increasing cross rolling temperature, the transverse texture components developed again. A simple transverse texture, which showed two maxima appearing circularly 90° apart, was observed at 920°C. It was found that unidirectional rolling could not eliminate the transverse texture, which resulted in the anisotropy of mechanical properties. The anisotropy of mechanical properties obtained from tensile and V-notch Charpy test was closely related to the crystallographic texture and its intensity at each rolling condition. To obtain the isotropy of mechanical properties by cross rolling, it is suggested that cross-rolling ratios should be controlled above 0.5. The variation of rolling temperatures and directions has great influence on the anisotropy of impact value rather than tensile strength.

Jan 1, 2004

By Richard S. Allen

"The casual visitor is not apt to think of the Adirondacks as a one-time hive of mining and manufacturing activity. However, where there are mountains there are usually minerals and northern New York State is no exception.The Adirondacks are a rocky shield, a great stone cap pulled down over what is now northern New York. The bedrock consists of layered metamorphic rocks which were once sandstones or limestones on the bottom of a shallow sea that covered the region 1000 million years ago. The highlands are composed for the most part of the igneous rock anorthosite. Ancient earth upheavals at temperatures of at least 750°C mixed molten masses of anorthosite and the minerals it contained with the older metamorphic rock, resulting in deposits of iron-titanium oxide s, red garnet and other valuable minerals. Of these, the most readily recognizable was iron.The first hint of the existence of iron ore in the Adirondack Lake Champlain region of upper New York State seems to have come from a Swedish naturalist, Peter Kalm (1716-1769), who travelled through French Canada and visited the military outpost of Fort St. Frederic in 1749. In July of that year, Kalm wrote:""Among the kinds of sand which are found on the shores of Lake Champlain; one is black and the other garnet-colored... and they sparkle when the sun shines. All the grains of this sand without exception are attracted to the magnet, the uppermost or black sand being about a quarter inch deep...""Concerned primarily with the fur trade, the officers and men who occupied this remote bastion of La Belle France were apparently unaware of the industrial and commercial possibilities beneath their feet. No deposit of iron was then known to exist any closer than the Three River s area in Lower Canada."

Jan 1, 1983

By J. J. O?Neill

Introduction The Beattie mine is the first of its character to be exploited in Quebec. It is primarily a large low-grade gold deposit containing values which a few years ago would not have been considered as ore. Much interest is attached to this development as its success may mean a greatly enlarged scope to gold mining in Canada on deposits which have formerly been considered worthless. Because of its potential importance as a pioneer in low-grade gold mining, the Quebec Bureau of Mines decided to make a careful detailed study of the Beattie in the hope not only of assisting in its development, but of stimulating the search for similar essential geological conditions in other parts of the Province. This paper is a summary of the results obtained during two months on the property in 1932, supplemented by a few trips underground in 1933. The full report will appear in the Annual Report of the Quebec Bureau of Mines for 1932, Part C. Location and Means of Access: The Beattie ore-body is situated two miles west and one half mile north of the centre of Duparquet township, and approximately 22 miles north 28° west of the town of Noranda. Until the fall of 1932, access to the property was from LaSarre, on the Canadian National railway, over a thirty-mile water route with one portage 600 feet long; about 2,000 tons of machinery and supplies were taken in by that route. An automobile road, nine miles long, now connects the property with the Makamik highway, and a narrow-gauge railway, without ballast, gives outlet for concentrates from the mill to the C.N.R. tracks of the Rouyn-Taschereau line, nineteen miles distant.

Jan 1, 1934

By Jorge Blanco, Joaquin Gotor, Enrique Delgado, Carlos Frias

Since 2009 Cobre las Cruces (CLC) has successfully operated a sustainable mining business near Seville, Spain, applying the most advanced hydrometallurgical technologies to process secondary copper sulphide ores through atmospheric leaching in ferric sulphate media and using oxygen sparging in a cascade of ten reactors. In comparison to conventional copper smelters, the CLC hydrometallurgical process does not generate SO2 gas, airborne emissions or slags. The copper ore is ground and sent directly to atmospheric leaching reactors; flotation is not required, and consequently, copper extraction is maximized at 93-95%, while producing 72,000 t/y copper cathodes of the highest purity (99.999 wt.% Cu, Grade A). Reserves for the CLC deposit were estimated at 16 million tonnes of ore averaging over 6 wt.% Cu and containing principally a chalcocite mineralization. Other copper bearing species include digenite, covellite, chalcopyrite, bornite and enargite. Pyrite represents over 70 wt.% of the ore. In the CLC leaching process, chalcocite reacts with ferric sulphate at approximately 90 ºC and copper is released into solution while ferric ions are reduced to ferrous ions. The ferric sulphate leachant is regenerated continuously by oxygen injection and consumes sulphuric acid. It is remarked that pyrite plays a crucial role to yield high copper leaching rates. When pyrite is oxidized, a small proportion of iron is co-leached and some sulphuric acid is generated. The CLC leaching technology has been designed to allow a certain level of pyrite oxidation, which is positive in many ways: (i) to maintain a Fe/Cu ratio in solution; (ii) to facilitate Fe(II) oxidation; (iii) to produce a high redox potential; and (iv) to counterbalance a bleed solution that removes some iron. Moreover, galvanic interaction between pyrite (cathode) and chalcocite (anode) can substantially increase atmospheric leaching kinetics and efficiency (copper recovery).

Jan 1, 2016

By D. J. Archambeault, A. Saigal

Substantial cost savings have been demonstrated by material design changes after initial product development. As more information about a product's operating environment becomes available to a designer, it is possible to consider a more costeffective material that still meets or exceeds the design intent, such as minimum low cycle fatigue life. This is especially true in the aircraft engine industry, where precise operating cycle data is not available until after the first engine is built and tested. A methodology for predicting estimated low cycle fatigue life has been developed to investigate potential material change candidates for an aft cooling plate. A twodimensional macromechanical finite element model (FEM) has been developed using ANSYS and used to determine the effects of varying material properties. It is shown that slight changes in density, coefficient of thermal expansion and modulus of elasticity have profound effects on component and effective stresses, and therefore, estimated low cycle fatigue (ELCF) life. Aerospace

Jan 1, 2006

By J. R. Perumareddi, V. S. Sastri, M. Elboujdaini

It is well known that high strength steels used in aerospace industry, are generally susceptible to hydrogen embrittlement during surface treatment such as electroplating with zinc on cadmium. Hydrogen embrittlement reduces ductility and results in brittle fracture rather than failure by plastic deformation. Hydrogen embrittlement of high strength steels is mitigated by surface treatment such as plating with other metals. Data on the hydrogen contents of steels before and after surface treatment by hot extraction-thermal conductivity, secondary ion mass spectrometry (SIMS) and UV-visible spectroscopy along with the mechanism are presented.

Jan 1, 2006

By L. Hacini, N. Van L ê, P. Bacher, D. Thibault

Manufacturer welded components may suffer from high level of residual stresses which can cause premature cracking and decrease the life of the components if they reach values close to the yield strength of the material. In the present work, a robotized hammer peening technique is simulated by an impact machine and the residual stresses generated by the indentation are measured. To better understand phenomena behind residual stresses relaxation by hammer peening, the impact energy level was changed. 304L steel plates were hammer peened with 10 impacts. The contact between the hammer and sample surface was always at the same location. The strains on the surface close to the impact location were recorded during the test using strain gauges to follow residual stresses variations. At the end of the test residual stresses were measured indepth using hole drilling technique at 8mm from the impact center. The micro-hardness was monitored to evaluate the affected zone by the hammer peening. This approach gave a good estimation of the energy and number of blows to be used for efficient relaxation of the manufactured parts.

Jan 1, 2006

By W. Andrew Falls

Although we have yet to reach the midway point in the decade, the copper concentrate market has already witnessed some of the most volatile swings in history, moving from record high treatment and refining charges in 1991-92 to historic lows, in real terms, during the past year. What has been the cause for such volatility? By and large the swings can be attributed to factors of supply and demand in the "custom" copper concentrate market. For example, two relatively recent events which had a major impact on the supply-demand balance were the shutdown of the Bougainville copper mine in Papua New Guinea in 1989 due to rebel insurgency and the startup of the La Escondida mine in Chile in 1992. The first event, threw a balanced to slightly surplus concentrate market into a substantial deficit, forcing treatment terms down as smelters, caught short by the loss of concentrate supplies scrambled to cover their positions. The second event, brought over 300,000 mt per year of new copper in concentrate to the market, more than reversing the losses from the Bougainville shutdown. In combination with other additions to mine capacity via new mines or expansions, the custom concentrate market moved into a huge oversupply in 1991-92 and many mines found themselves unable to place uncommitted tonnage. But even this event was quickly overcome by the use of underutilized capacity at non-traditional buyers, such as those in the C.I.S., Zambia, or those which were not traditionally buyers of custom materials. All of this has happened in the space of five short years, a mere snapshot in the history of the market. I'll return to these points a little further on, but first I would like to review the fundamentals which govern the copper concentrate market.

Jan 1, 1995

By A. A. Shirzadi, E. R. Wallach

"Liquid gallium has been used successfully to modify/remove the surface oxides prior to diffusion bonding similar and dissimilar nickel-base superalloys. Using this approach, bonds in nickel-base superalloys with ""virtually invisible interfaces"" were produced, and the compositions in the bond region were very close to those of the bulk alloys. Room temperature tensile and bend tests showed no preferentially failure at the bond lines. Creep tests on samples made between two different Inconel alloys also showed failure away from the joint, i.e. in the parent metal of the Inconel alloy with lower creep resistance. The high temperature lifetimes of these samples were as long as those of the unbounded Inconel, confirming that the joining approach has no adverse effect on the nickel-base superalloys being joined."

Jan 1, 2006

By C. M. Trigg

"PEC uranium deposit, 100 km southwest of Coppermine, was discovered by diamond drilling in 1976 following ground and airborne geophysical surveys, geological mapping, geochemical surveys and boulder prospecting that were initiated as the result of the discovery of uraniferous sandstone outcrops in 1969 by geologists of Aquitaine Company of Canada Ltd.The deposit is within gently northeasterly dipping medium to coarse-grained Unit 11 quartzitic sandstone of Neohelikian Dismal Lakes Group. The deposit is from 10 m to 70 m above the base of the sandstone which, beneath the deposit, non-conformably overlies weathered and altered Aphebian granite of Great Bear Batholith or unconformably overlies rubble breccia, conglomerate and medium-grained Unit 8 sandstone of Paleohelikian Hornby Bay Group.A northeasterly trending, 500 m wide graben, bounded by the steeply dipping northeasterly striking Imperial and Aquitaine faults, contains the deposit which is 1.1 km long by up to 340 m wide. The deposit overlies a post-Hornby Bay Group, pre-Dismal Lakes Group topographic high. Uranium principally occurs as stratabound, often peneconcordant bands; a lesser amount of uranium is fracture controlled.Stratabound uranium exists in gently easterly dipping, subparallel bands ranging in thickness from 1.5 m to 6.0 m. Pitchblende, coffinite and sooty black uranium oxides occur as interstitial disseminations and grain coatings subparallel to bedding; they also replace pyrite and form narrow veinlets.Small amounts of torbernite, carnotite and cuprosklodowskite coat pitchblende and are disseminated within mineralized bands. Pyrite, marcasite, chalcopyrite, chalcocite, cove/lite, digenite, azurite, malachite, arsenopyrite, glaucodot, niccolite, bravoite (? ), goethite, hematite and magnetite as well as quartz, barite, calcite, biotite, chlorite and clay minerals exist within the mineralized bands. Uranium grades of 0.1 % to 0.3 % U3O8 over thicknesses of 1 m to 2 m are typical.A steeply dipping fracture zone near the Imperial fault contains sooty black uranium oxides, torbernite, carnotite and cuprosklowdowskite as well as sulphides, cobalt arsenides, quartz and carbonate. The zone may reach 70 m long; its true width is about 1.9 m. Uranium grades range up to 5.18% up, over0.9m.Pitchblende and coffinite from PEC deposit have been dated at 1.08 ± .10 Ga with possible remobilization at .45 Ga. The deposit contains an inferred 3,150 tonnes of U3O8."

Jan 1, 1986

By Ahmad Ghahreman, Lin Li

"In this study, the Fe(II)/Fe(III) redox reaction kinetics on the surface of pyrite, have been investigated in a 0.5 mol L-1 sulfuric acid solution for a temperature range of 22 to 65°C. Based on mixed potential theory, chronoamperometry is introduced to study the Fe(II)/Fe(III) kinetics by subtracting the current density of pyrite oxidation in an iron-free acidic solution from that in an iron-containing solution at the same applied polarized potential. Tafel behavior was established by this method to analyze the kinetics of the Fe(II)/Fe(III) redox reactions. The results showed that exchange current densities increased slightly with temperature, however remained on the order of 10-5 A cm-2. The activation energy for Fe(II) oxidation and Fe(III) reduction on the pyrite surfaces was calculated to be 102.0 and 32.7 kJ mol-1, respectively. Anodic transfer coefficients also increased, from 0.24 to 0.39, with increasing temperature, which indicates a weakened n-type semiconductor property at higher temperatures. Electrochemical impedance spectroscopy measurements have indicated that at lower anodic over potentials the charge transfer is the rate determining step of pyrite oxidative dissolution in sulfuric acid solution. In the presence of Fe ions, the major contribution of the total current density comes from the Fe(II)/Fe(III) redox reaction. INTRODUCTION Pyrite, an abundant sulfides mineral in the nature, is commonly considered a valueless gangue mineral frequently associated with other valuable sulfide minerals such as chalcopyrite, or metals such as gold, or coal (Lin & Say, 1999). Pyrite oxidation has been the subject of extensive research in view of gold metallurgy, as oxidation of pyrite is the initial step to break down the pyrite lattice and expose the encapsulated fine gold particles (Gasparrini, 1983). Fe(III) ion and dissolved oxygen (DO) have generally been considered as the two most important oxidants with respect to pyrite oxidation, having been studied extensively in previous research (Zheng, Allen, & Bautista, 1986; King Jr & Lewis, 1980). The process of pyrite oxidation can be viewed as a series of reactions amongst pyrite, ferrous, ferric and oxygen in which pyrite is initially oxidized by the dissolved oxygen in water forming ferrous (Eq. 1), and then the ferrous also is oxidized by he dissolved oxygen to form ferric (Eq. 2). The ferric, produced by reaction 2, then could potentially oxidize pyrite (Eq. 3) and convert to ferrous."

Jan 1, 2017

By A. M. Brown, P. V. Straznicky

Dimpling as a means of flush countersinking rivets is an old process predominantly used in secondary structures. The introduction of GLARE as an aerospace material has renewed interest in dimpling and its possible application in primary structures. The dimpling process is able to prevent the creation of a machined knife-edge in the thin aluminum plies of the GLARE sheets. In addition, dimpling eliminates the need to use reduced height rivets, such as the NAS 1097 rivet style. This investigation expands on an earlier study into dimpling of GLARE by Rans and Straznicky. In order to tailor the dimpling process to GLARE, FEM simulations were developed. After verification, a study was performed to find the best parameters for dimpling GLARE3-2/l. Coupon fatigue tests were carried out and the dimpled joints demonstrated increased fatigue lives over the conventional machine countersunk joints. Future wide panel fatigue tests are planned to confirm the usefulness of dimpling thin GLARE laminates.

Jan 1, 2006

By Alexander Smith

"The three principal known mineral deposits of the Taku River area lie in the Tulsequah synclinorium. The axis of this north-south trending structure is along Tulsequah River valley; about 6 miles east of the eastern contact of the Coast Range batholith.The one proven mine of the area, the Polaris-Taku, is on the west side of the valley. It is a gold property, the gold occurring in fine needles of arsenopyrite disseminated in carbonatized volcanics. The mine was originally called the Whitewater, and the adjacent area the Whitewater gold belt. During the years 1937 to 1942 gold having a value of $3,284,000 was produced from 313,500 tons of ore milled."

Jan 1, 1954

By K. Bachmann, M. Rudolph, U. A. Peuker, H. H. Duong, T. Heinig, T. Leißner, H. Schubert, Helmholtz-Institute Freiberg for Resource Technology, Technische Universität Bergakademie Freiberg

"Minerals can be liberated by random fracture of particles into smaller fragments or by detachment along phase boundaries. These two mechanisms represent borderline cases. When ores get comminuted the liberation of minerals is achieved to some extent by both mechanisms. This article describes a method to determine the extent of transgranular and intergranular fracture on surface exposure of minerals based on 2-dimensional liberation analysis.The approach uses the non-biased surface information like phase specific surface area (PSSA), phase specific free surface (PSFS) and phase specific locked surface (PSLS) of minerals and their change with comminution. The amount of transgranular and intergranular fracture on surface exposure can be calculated using the phase specific surface parameters.A sedimentary rock (apatite ore), an igneous rock (nepheline-syenite) and an artificial material (copper slags) were ground to different fineness. Based on the mineral liberation analysis (MLA) of feed and products, the extent of phase boundary fracture on the surface exposure of the minerals is studied.INTRODUCTIONMinerals can be liberated ether by comminution or by detachment (Gaudin, 1939). Liberation by comminution is a random fracture mechanism, which is not being influenced by ore texture, grain boundaries and mineral features (transgranular fracture). Liberation by detachment represents a fracture along grain boundaries (intergranular fracture). Random fracture often is named as the dominating mechanism for the liberation of ore minerals. This has been the basis to simplify models for liberation modelling (Barbery, 1991; King, 1979; Meloy, 1984) assuming that the probability of cracks moving along grain boundaries is zero. Thus, no interfacial area is lost during comminution."

Jan 1, 2016

By C. A. Pickles, K. Mackowiak

Black Thor chromite ore from the Ring of Fire deposit in Northern Ontario was carbothermically reduced in a microwave system to produce a ferrochromium alloy. The as-received ore contained 43.0% Cr2O3, 19.9% Fe2O3, 14.5% MgO, 13.4% Al2O3, and 7.0% SiO2. Activated charcoal was utilized as the reducing agent. Firstly, TGA/DTA and permittivity studies were carried out in order to determine the relationship between the reduction process and the microwave susceptibility. Secondly, microwave reduction experiments were performed on the chromite ore. The variables investigated were; the amount of carbon, processing time, input power and type of atmosphere. A maximum chromium grade of 76.1% and a chromium metallization of 82.7% were obtained for a processing time of 20 minutes, a power input of 800 W, and a carbon addition of 15% in an argon atmosphere.

Jan 1, 2017

By K Morrison

Different individuals have calculated the boundary stresses around elliptical openings in an infinite elastic medium for various conditions of loading. With caution, such calculations are useful in indicating stress trends in mining. This paper illustrates an application to caving operations and suggests that abnormal field stress would have an adverse effect. Introduction GELDART and Udd (1), applying elastic theory, confirmed, and set out graphically, the stress distributions on the surface of elliptical openings with axis ratios varying from 1.0 (a circle) to infinity (a crack). The loading conditions varied from uniaxial to hydrostatic, and inclinations for the opening, with respect to the stress axis, varied from 0° to 90°. As most mine openings can be generalized into this elliptical conception, the usefulness of the presentation lies in the fact that given reasonable estimates for the stress ratio, the axis ratio, and its inclination, then the trend in stress concentrations as an opening develops can be readily approximated.

Jan 1, 1964

By B. Schulz, T. Leißner, R. G. Merker

"Ores enriched in critical rare earth elements (CREE) keep on being of particular interest. The CREE are Nd, Eu, Tb, Dy, including Y. In conjunction with beneficiation tests on Y-mineral bearing flotation tailings of complicated mineralogy, the Mineral Liberation Analyses (MLA) was used to work out processing characteristics fraction-wise in terms of modal mineralogy, mineral recovery, locking and liberation, and particle size.Size fractions from mechanical sieving (“real fractions”) as well as fractions created virtually by using filters on the MLA-data of the unsieved head material (“virtual fractions”) were investigated comparatively thereby. The ""virtual-sizing-approach"" features a much simpler sample preparation procedure and considerably lower cost if a fraction-wise investigation of a head sample is needed. It can be conveniently applied to intimately locked ores needing a fine grinding to a particle size distribution (PSD) range below 25 microns for instance. However, its practical use is sometimes disputed in terms of the reliability of the results. Results are shown for the main Y-bearing mineral xenotime and selected main gangue minerals of a low grade REE-ore.The influence of sample representativeness, sample preparation and particle counting statistics turned out to be of crucial importance. Given that all preconditions for reliable results are met, locking characteristics, modal mineralogy, and even PSD trends can be read from virtual fractions.The authors encourage processing engineers to use the virtual approach. They propose practical measures to improve the reliability of the MLA results, identify and tackle conflicting results, and mitigate evaluation problems that may arise."

Jan 1, 2016

By Hyumng Sup Choi

The role of the interfacial electrical 'Condition on the adsorption of col-lectors on mineral surfaces has been studied by electrophoretic mobility and adsorption measurements made on zircon. From the investigation of the electrokinetic properties of zircon, H+ and OH-are seen to act as potential determining ions, thus controlling the electrical nature of this mineral. The isoelectric point of zircon occurs at a pH of approximately 5.0, and it is evident, therefore, that the zircon surface would be positively charged below a pH of 5.0 and negatively charged above this pH. The adsorption of collectors therefore de-pends strongly on the pH of the solution; anionic collectors are adsorbed on positively charged surfaces and cationic collectors on negatively charged surfaces. This, in turn, de-fines the effective flotation condition, with respective collectors, for this mineral. The above results have been correlated with the flotation behaviour obtained by the simplified flotation test using a modified Hallimond tube.

Jan 1, 1963