Search Documents

By A. Anderko, V. G. Papangelakis, G. Moldoveanu, G. Azimi, M. Carlos

"OLI Analyzer is a software package that uses the powerful Mixed Solvent Electrolyte (MSE) model to simulate the behavior of multicomponent electrolyte solutions from infinite dilution to the limit of fused salt, and from temperatures below the freezing point up to near critical temperature of the mixture. The software also allows the creation of thermodynamic parameters for new chemical systems unavailable yet in public-domain or commercial software databanks. This communication reviews the basics of the model and provides some examples of modeling hydrometallurgical applications with emphasis on high temperature applications, including calcium sulfate scale formation in autoclaves, high temperature pH inference and iron control. INTRODUCTIONModeling of electrolyte systems has been of particular interest to various industrial processes, such as separation processes (e.g., solution crystallization, extractive distillation, seawater desalination or bio-separations), environmental applications (e.g., gas treatment, wastewater treatment or chemical waste disposal) and hydrometallurgy (e.g., pH control and neutralization, iron control, scaling and fouling of equipment). Using a chemical model, time-effective predictions of various properties of electrolytes can be obtained, which is beneficial not only during process monitoring, but also during process optimization and process scale up. As a result, pilot scale studies can sometimes be eliminated where budgetary constraints exist. Development of such a powerful model requires the use of a speciation-based model, in which solution chemistry is explicitly addressed (as compared with some models that treat electrolytes either as undissociated or fully dissociated systems), despite being computationally challenging. In addition, as a feature of electrolyte systems, speciation equilibria inherently influence the phase equilibria due to complex formation, ion pairing, and acid-base reactions. Therefore, how the electrolyte solutions behave at various conditions may differ significantly due to the non-ideality, which must be carefully addressed to obtain a model that is applicable to a wide range of conditions such as concentration, temperature, pressure and solvent system."

Jan 1, 2012

By A. F. Buckham

Introduction Several basins of the Nanaimo series, a group of coal-bearing sedimentary rocks of Upper Cretaceous age, underlie parts of Vancouver island and the adjacent gulf islands. One, the Nanaimo basin, occurs on the southern half of the west shore of the gulf of Georgia. About fifty square miles at the north end of this basin are known to be underlain by productive coal seams, this area being known as the Nanaimo coal field. Coal has been mined from two horizons- that of the Wellington seam, fairly low in the series, and that of the Newcastle and Douglas seams, about the middle of the series. Coal has been mined here since the fall of 1852. About fifty million tons have been produced, almost half the total production of British Columbia. About seventy-two years ago, James Richardson of the Geological Survey made a reconnaissance of the coal measures on Vancouver island, and thirty-five years ago C. H. Clapp mapped and reported on most of the Nanaimo coal field. Twenty-four years ago, J. D. MacKenzie extended the work to those areas not mapped by Clapp. MacKenzie died before the results of his work could be published, but did issue a revised estimate of the Goal Resources of Southern Vancouver Island. Work by the present writer is a further contribution by the Geological Survey to knowledge of the island coal measures. Having spent more time in the field, and having had more data at his disposal than were available to his predecessors, the writer has been able to throw additional light on the Nanaimo, and other, coal fields on Vancouver island. He is indebted to Canadian Collieries (Dunsmuir), Limited, and to its officials for access to much valuable information in their possession.

Jan 1, 1947

By Sergio Bustos

A significant expansion project is under way at KATCO?s Torkuduk In Situ Leaching (ISL) operation to increase uranium production up to about 4000 tU/year. Higher flows and lower uranium concentration are expected in the rich solutions coming from the well fields. Therefore, extra adsorption and elution columns and modified operating conditions are required to deal with the increased demand for uranium transfer from the ISL solutions to the eluate solution, which goes to the uranium precipitation section. Resin adsorption and elution performance have been interpreted and projected by using Mac Cabe-Thiele equilibrium diagrams. The resin load, the adsorption mass transfer coefficient, the adsorption zone height and the eluate concentration have been estimated for the expected changing operating conditions associated to the future mine plan. This information has allowed to improve the present operation results and to define the main process design criteria for the expansion project.

Aug 1, 2010

By David Runnels

The Mount Wright iron are mine and upgrading plant were brought on line in the fall of 1975. The mine is located near the Quebec - Labrador border some six hundred miles northeast of Montreal. This paper describes the crushing, grinding and concentrating facilities at Mount Wright, and some design: criteria used in equipment selection and flow sheet design. Also mentioned are some "asbuilt" modifications. A brief description of the over-all flowsheet is also included. Introduction IN SEPTEMBER 1970, the Quebec Cartier Mining Company started development of the Mount Wright iron ore mine. The estimated are reserve is in excess of 1,000,000 ,000 long tons of concentrates, with an average crude are grade of 31.5% Fe. The run-of-mine ore is crushed, ground and concentrated to a product having 66% Fe and 5% silica at an annual concentrate production r ate of 18.4 million long tons. The daily production rate of over 50,000 long tons of concentrate necessitates a daily mine output of approximately 250,000 long tons of material, of which 50% is waste.

Jan 1, 1977

By B. Currie

Maintenance of quality electrowon copper requires an electrolyte which has suitable chemical and physical characteristics. The proper design and operation of the solvent extraction plant is essential to the quality of the electrolyte sent to electrowinning. An aspect that is not well appreciated is that the return electrolyte can have negative effects on the operation of the solvent extraction plant. Poor SX plant operation creates below optimum electrolyte conditions. High Eh in the return spent electrolyte can degrade the SX reagent with large decreases in copper transfer capacity and increases in internal entrainment. The synergistic interaction of the SX and EW plants needs a single-source design approach to address the interactions. The design elements in the SX and EW plants required to manage the electrolyte conditions are discussed.

Jan 1, 2014

By H. J. McQueen

Pyro-reduction of ores to metal products developed markedly through the industrial revolution into the great depression. Nineteenth century resource and environmental sustainability were haphazardly improved by many process changes, although the motivation was primarily reduction in labor, feed stocks and fuel. Some notable achievements were coke and hot air for blast furnaces (later from waste heat stoves), puddling of wrought iron and steel ingot production with convertors advancing into oxygen use and continuous slab, billet and strip casting. Although advances in one sector were often counteracted by fall-backs in others, there was progress in that the resource consumption and pollution per unit of production was decreased. Improvements in the 2 decades following WW2 were mixed but popular notice of environmental hazards forced governments to legislate pollution controls and initiate steps in resource conservation. The energy crisis of the 1970’s saw an industrial energy-saving campaign and legislation of technology assessment procedures. Up until mid 18th Century, the training of iron masters depended on apprenticeship with some formalized knowledge from medieval books such as those of Biringuccio (1540) and Agricola (1556). The advances were very slow partly due to absence of scientific concepts of the smelting process. Nevertheless, some iron masters succeeded in improving the process and described procedures to instruct others. With the surge of steam power and the reverberatory puddling process for ductile wrought iron (WI), machinery changed from wood (iron strap reinforced) to WI machinery. With the clarification of the reduction and oxidation mechanisms by Cavendish and Lavoisier (~1780), productivity in iron production surged. The mechanical testing and microscopy of Kirkaldy (1862) spurred understanding of processing and properties of WI and steel. The various forms of C in steels were determined by chemists at the end of the 19th Century. It also became possible to control metal and slag chemistry in the open hearth furnace. But understanding of the transformations during heat treatment of steel only came in the first decades of the 20th Century.

Jan 1, 2012

By E. Peters

Roasting processes are divided into several elementary mechanisms, any of which could be significant or pre-dominant in a particular roast. The elementary processes considered in-elude beat transfer, gas-solid inter-actions with accompanying mass transfer between the bed and furnace atmosphere, vapor phase transport processes in solid-solid interactions, and solid phase diffusion processes. Examples are chosen of processes in which one of these mechanisms pre-dominates and some recently obtained data is presented to support the existence and significance of these mechanisms. Proposals are also made for future research in these areas, and for utilizing the information in the improvement of roaster capacities’ OASTING of ores as a preparative treatment for smelting or leaching has been practiced for so long that its origin has been lost in antiquity, but little has been under-stood of its basic nature until fair-ly recent times. The nominal chemistry of roasting processes is now understood; that is, the initial chemical com-pounds present in the ores or con-

Jan 1, 1961

By Lewis Finch

Oil and .gas reservoirs exist under pressure within the pore spaces of rock structures or traps. Wells are drilled to produce these reservoirs. Under primary operation, the natural energy of expanding fluids in and adjacent to the reservoir forces or drives oil and gas to the wells. There are three basic sources of energy: dissolved gas, water, and gas cap. Typical recovery by primary methods is only 10 to 25 per cent of the oil in place for the dissolved gas drive but is generally higher for the others. Secondary recovery involves the injection of water or gas to supplement natural energy, thereby increasing recovery over that obtainable by primary operation alone. In many cases ultimate recovery with secondary methods is 1.2 to 2.0 times the expected primary recovery. The type programme adaptable in a field depends on its 'primary performance and on certain reservoir characteristics. In the United States, application of secondary recovery methods is becoming increasingly important. About 22 per cent of United States oil production now comes from fields in which injection projects are operating. In 1953, nearly 1.4 million barrels of oil daily came from such fields, more than double the amount in the early 40's. Ultimate primary recovery from known pools is estimated at roughly 73 billion barrels. Secondary recovery projects already in operation will increase this to almost 80 billion, an increase of almost 10 per cent. Unitized secondary recovery projects have been very successful. From unitized projects alone, industry reserves of oil in the United States have been increased by 3 1/2 billion barrels. In Canada, secondary recovery has not been so wide spread mainly because D-3 reef reservoirs which have held the major reserves are under water drive. However, appreciable amounts of water are being injected in the Redwater D-3, Leduc D-2 and Joarcum Viking reservoirs, and gas in the Golden Spike D-3. In both countries, possible achievements in increased recovery through secondary recovery methods now in use and by new ones which may be developed through research and field trial are a challenge to the scientist and the industry.

Jan 1, 1956

By P. R. A. Andrews, R. K. Collings

"In cooperation with le Ministère de l'Énergie et des ressources, Québec, le Centre de Recherches minérales, Sainte-Foy, Québec, and various silica producers, selected deposits of Quebec silica were identified in the southern region of the province and sampled to provide material for evaluation as glass and foundry sand by CANMET. The samples included both sandstone and quartz/quartzite. Head sample analyses ranged from 94.66% to 99.54% SiO2, 0.038% to 0.230% Fe2O3, and 0.16% to 4.51% Al2O3.Impurities included pyrite, iron oxides, and iron staining on quartz grains; carbonates as calcite; and alumino-silicates as clay and/or feldspar. Processing included size reduction to grain size, about 600 µm, by jaw, roll and cone crushers, and grinding in a muller-mixer. Removal of fines was achieved by attrition scrubbing and washing. Further removal of impurities was achieved by reverse flotation of iron oxide and alumino-silicate minerals employing both anionic and cationic collectors. Flotation resulted in a substantial improvement in the quality of most sands, the quartz concentrates analyzing 99.08% to 99.80% SiO2, 0.014% to 0.048% Fe2O3, and 0.06% to 0.49% Al2O3. Removal of iron oxide minerals was also investigated using the Sala HGMS. Iron oxide analyses of the non-magnetic fractions were comparable to the iron oxide analyses of the quartz concentrates obtained by flotation, 0.013% to 0.054% Fe2O3. On the basis of the samples submitted, silica from 5 of the 6 deposits studied has potential as source material for glass sand. Foundry tests showed that 3 of the 4 samples submitted for evaluation have potential as foundry sand."

Jan 1, 1987

By Y. Thibault, G. Deschênes

An open-pit mine, located in Mexico, processes an ore a rate of 4000 tpd, using conventional cyanidation and AYR. A laboratory study was conducted to increase silver extraction and to reduce the concentration of cyanide in leaching. The sample contained 0.41 g/t Au, 125 g/t Ag, 99% gangue minerals, 0.7% pyrite, 0.07% sphalerite, 0.03% chalcocite. Silver was present as acanthite, stromeyerite, silver mercury/halogen, silver with copper in solid solution and jalpaite. The plant conditions (2400 ppm NaCN) produced 90.2% gold extraction (residue at 0.04 g/t Au) and 92.7% silver extraction (leach residue at 9.1 g/t Ag). The CELP (CANMET Enhanced Leaching Process) produced 97.0% silver extraction (residue at 3.8 g/t) and 90.2% gold extraction using 500 ppm NaCN. The incremental gross revenue was estimated at $US7.6 million and the reduction of cyanide costs was $2.9 million per year (79%).

Jan 1, 2011

By R. P. Viljoen, A. D. Scheglov, A. L. Sokolov

"Abstract -The distribution of mineralized provinces is analyzed on the basis of their genetic link with specific blocks of the earth's crust including ancient platforms, mobile belts and zones of tectonic­ magmatic activation. Mobile and fold belts surround the Siberian platform in Russia and the Kaapvaal craton in South Africa, with decreasing age zoning away from ancient platform margins. The main differences in the geological development of the two cratonic areas are: (1) the long period before the final stabilization of the Siberian platform (3600 Ma to 1600 Ma) and the comparatively short period of time for the stabilization of the Kaapvaal craton (3600 Ma to 3050 Ma) and (2) the intensive multiple activation of the marginal zones of the Siberian platform and the tectonically­ controlled, magmatic sedimentary, intracratonic activity, typical of the Kaapvaal craton. Mineralization of the Siberian platform is largely characterized by marginal reactivation zones of differing ages although mineralized intracratonic Cu-bearing basins of Proterozoic age are also known. Mineralization of the Kaapvaal craton is mainly related to the formation of the intracratonic basins i.e., Witwatersrand (Au, U) and Transvaal (Au). The latter is characterized by multi-age volcanic-intrusive activity including the emplacement of Bushveld Complex (Cu, Ni, Pt, Cr, Au, V). The Siberian platform is characterized by the prolonged development of inherited mineralization from Archean until the late Mesozoic. The main period of mineralization in the Kaapvaal craton is restricted to the middle Proterozoic.The Baykal-Patomskaya and Namaqua-Natal mobile zones occupy similar positions adjacent to the Siberian and Kaapvaal cratons, respectively, and demonstrate similar modes of metallogenic development: i.e., the early formation of exhalative Pb-Zn-Cu deposits during the early stage and magmatic Cu deposits during the late stage. The more remote mobile belt near the Siberian plat­ form, the Trans-Baykal, is characterized by intensive multi-age mineralization (Wo, Mo, Sn, fluorite), related to a period of tectonic-magmatic activation. The Saldania Belt occupies a similar position near the Kaapvaal craton but is known for its poor Au, and Cu rnineralization. lt does, however, have some similarities with Trans-Baykal Belt in regard to Mo-W bearing granitoids.The phenomenon of interference of geosynclinal, orogenic, platform, and tectono-magmatic activation regimes is known for the Russian section of the Pacific Ocean Volcanic Belt."

Jan 1, 1994

By Delio J-J Tortosa, Fred F. Langford

"The Cenex orebody occurs at the intersection of northwest and northeast-trending fault zones that formed during post-Hudsonian uplift. The ore is localized in breccia zones, along faults, and in veins and adjacent wallrocks. The host rocks are Tazin quartzo-fe/dspathic mylonites and ultramylonites and chloritesericite- quartz-graphite-feldspar mylonite schist. The uraniumbearing minerals are finely disseminated pitchblende and uraniferous titanate.The earliest mineralization may have been associated with /ate-stage retrograde metamorphism in the mylonite schist. The main stages of mineralization were associated with brecciation, hematization, carbonatization, and chloritization of the mylonites and ultramylonites. Uranium mineralization was clearly much later than any igneous or metamorphic activity associated with the Hudsonian orogeny.Late post-orogenic uplift, erosion, and deposition of the Martin continental clastics in fault basins were coeval with uranium mineralization. The deposit is consistent with a meteoric-hydrologic system constituting a source for orebearing fluids, hence the close spatial relationship of the uranium deposits in the Beaverlodge area with the basal unconformity of the Martin Group."

Jan 1, 1986

By S. C. Livanou, S. P. Tampouris, E. N. Zevgolis

In ferronickel (Fe-Ni) production from oxidized nickeliferous ores, mechanical losses of ferronickel in the slag are reduced by magnetic separation. Slag from the electric furnaces (E/Fs) contains 0.16% Ni. Its magnetic separation gave a pre-concentrate with 0.76% Ni, weighing approximately 6.5% of the feed. Nickel recovery was 29.7%. This pre-concentrate was then treated in a second (concentration) plant. Concentration treatment involves screening, crushing and magnetic separation. A pre-concentrate with 0.76% Ni gave a magnetic concentrate with 2.58% Ni and a non¬magnetic part with 0.35% Ni. Smelting of the non-magnetic part without the addition of a reduction agent in a laboratory electric arc furnace, gave a ferronickel alloy with approximately 20% Ni and a slag with 0.16% Ni.

Jan 1, 2005

By A. Y. Smith, R. J. Allan, E. H. W. Hornbrook, R. W. Boyle, W. Dyck

"HYDROGEOCHEMICAL METHODS in the Canadian Shield can be based on analyses of the following :(1) spring waters and their precipitates;(2) stream and river waters;(3) lake and muskeg waters;( 4) ground waters from drill holes, wells, faults, etc.;(5) waters issuing from diamond drill holes, faults, shear zones, etc. into mine workings and open pits; also analyses of precipitates associated With these waters.The first four can be utilized in both reconnaissance and detailed surveys. The last is suitable only for detailed work.For hydrogeochemical methods of prospecting to be effective, the following conditions must be present. 1. Natural waters must come into contact with mineral deposits and remain in contact with them long enough for the solution of detectible amounts of ore, gangue or indicator elements. 2. Dispersion patterns must be present in the hydrologic systems in order to trace the elements back to their source. These patterns may take the form of trains (e.g., increasing amounts of elements upstream toward t he source (s), Figure 1 ) or halos (e.g., increasing amounts of elements in bodies of water toward the source (s), F igures 2 and 3)."

Jan 1, 1971

By W. S. McDonald

PRACTICALLY all dusts derived from organic matter are explosive and instances are recorded of explosions-some of them extremely violent-having occurred in grain elevators and flour mills. While a discussion of the explosibility of dusts in general, doubtless, would be of more than academic value, it will be of greater interest, on this occasion, to consider various phases of the problems connected with the hazards arising from coal dust. Extensive and valuable research has been carried out during the past few decades on the subject of coal-dust explosions and a great part of this work has been concerned with the preventive effect of stone or other incombustible dusts. Four men have been outstanding in this very substantial achievement. The first is Dr. W. Galloway, who succeeded in demonstrating by experiments that one pound of coal dust mixed with 150 cu. ft. of air formed an explosive mixture. The next is Sir W. Garforth, who proved that stone dust is an effective preventive for coal-dust explosion. The third is G. Haon, and last but not least, L. G. Hill, both of whom laboured incessantly to produce a suitable stone-dust and a satisfactory method of application. Today, mining men all over the world are satisfied and convinced that stone dust, if properly applied, will prove effective in greatly minimizing, if not completely preventing, explosions of coal dust, as has been demonstrated in experimental mines, as well as in actual explosions, in practically every coal mining industry.

Jan 1, 1938

By H. C. Gunning

DURING the past year the Cadillac-Malanie area in northwestern Quebec has been catapulted to the front as one of Canada's most active gold mining districts. Late in 1934 the area was lolling along in the doldrums, with one producing mine and a handful of active prospects. 1935 passed with only slightly increased activity, but saw the start of production at Canadian Malartic mine. Lightning struck in April, 1936, when a new and phenomenally rich ore-body was found in O'Brien Gold mine, and by midsummer the camp was ablaze with activity. An important new discovery on the Pan-Canadian property, and pleasing underground developments at Sladen Malarric, East Malartic, and Lapa Cadillac, in addition to other new developments, lent fodder to the flame, and at present several dozen properties are being actively developed. For the past three seasons, the Geological Survey of Canada has been engaged in a fairly detailed study of the geology and mineral deposits across Cadillac, Malarric, and Fourniere townships. Ir is the purpose of this paper to present a brief preliminary statement of the structural and economic geology and to discuss some of the more important problems that have been found to exist. The reader is requested to remember that the paper is a preliminary one and that therefore the conclusions presented are open to revision. It is impossible to make full acknowledgment for help received, for the writers are indebted to practically every operator and prospector in the area for generous co-operation in the work, and to several private, provincial, and federal geologists for data and frank discussion of problems encountered. Over a score of student assistants from McGill, Queen's, and Toronto have given excellent service. Published reports by Wilson, Cooke, James, Mawdsley, L. V. Bell, and J. J. O'Neill greatly facilitated the work. For adequate control surveys and a topographic base-map, the writers are greatly indebted to H. N. Spence.

Jan 1, 1937

By L. Hacini

The start-up is the most critical phase of the cell life, as an uncontrolled start-up could lead to early infiltrations, instabilities, and in some cases to the cell death. Lots of efforts are put to increase the lifespan of cells, as it has a major impact on both the operating costs and the environmental footprint of the aluminum industry. Obviously, a true size test on a cell is a resources- and time-consuming approach that could be used only to validate mature concepts. Moreover, numerical modelling is a low-cost and versatile tool capable to test a wide range of potential ideas and concepts. In the present article, a thermal electrical mechanical slice model is presented. This model describes the preheating and bath periods of a P155 aluminum cell start-up, as used at the Grande Baie smelter. The impact of sodium diffusion and expansion is also included in the model. This model will be useful to study different problematical issues such as the global behaviour of lining materials, shell and cradle deformations during start-up and several start-up scenarios. Such a model will also be able to answer some interrogations regarding early infiltrations and their impact on the lifespan of the electrolysis cell.

Jan 1, 2011

By G. M. Mason

History Due to its strong affinity for oxygen, aluminium as an element was isolated only after many other rarer metals had been prepared and studied. It was just over one hundred years ago that two scientists, Hans Christian Oersted and Friedrich Wohler, produced the first few pellets of aluminium and determined its physical properties. These early investigators used metallic potassium as a reducing agent. Later, St. Claire Deville, by using sodium instead of potassium, improved the yield in the reduction and produced some pounds of aluminium. From a figure of about $110 per pound in 1855, the price had fallen to about $4 per pound by 1886. In that year, a very important discovery was made independently by Charles Martin Hall in Oberlin , Ohio, and Paul . Heroult in France. Stated in its simplest terms, the discovery of Hall and Heroult was that aluminium could be produced by electrolyzing a solution of the oxide in molten cryolite. The application of the Hall-Heroult process made the metal immediately available in commercial quantities and, by 1900, the price had fallen to 23 cents per pound. The growth of the industry in the past fifty years is well known, and is outside the scope of this paper. It is, perhaps, not generally known that aluminium was first produced in Canada at Shawinigan Falls in 1901. Since that time, production has been continuous at one or more smelters in the Province of Quebec. The largest of these smelters, which is also the largest aluminium smelter in the world, is at Arvida, Quebec, on the Saguenay river. A large power potential and access to ocean shipping were the two principal reasons for the establishment of aluminium production facilities in the Saguenay district. It is interesting to note that the aluminium industry, as a large user of power, took an active part in the early industrial development at Niagara Falls and Shawinigan Falls, and is now repeating the process in the Saguenay valley.

Jan 1, 1949

The influence of joint orientation and joint persistence, on the mechanical behaviour of jointed rock masses under uniaxial compression, has been studied systematically. The joint inclination angle ß was varied from 0° to 90° with an increment of 15°. The joint continuity factor k was taken as 0.2, 0.4, 0.6 and 0.8. The peak strength, Young’s modulus, the complete axial stress-axial strain curves, the cracking process and the characteristic of the fragments, were investigated. It was found that the anisotropic response of the jointed specimens was governed by the micro-mechanism, such as crack initiation, propagation and coalescence, crack opening or closing, and frictional slip of cracks or joints. With the increase of joint continuity factor, the axial stress-axial strain curves change from single-peak to multipeak, the peak strength and Young’s modulus decrease. The specimens with medium joint inclination angle (30°,45° and 60°) has lower energy dissipation and strength due to stepped or shear failure, while specimens with small and large joint inclination angle (0°, 15°, 75° and 90°) has higher energy dissipation and strength due to axial cleavage or crushing failure.

Jan 1, 2015

By Ursula M. Franklin

Old iron nails are one of the most common objects which entice the general public to ask questions about the history of metallurgy. There is a lot of history in old nails - history of the manufacturing industry, and social and economic history. Nails, therefore, are fine teaching tools; whether students have to acquire metallurgical skills or explore the structure and properties of wrought iron, whether they want to look into the history of inventions and the development of machinery, studying nails tells a story better than any teacher or any book. I have used this approach often and the following note is based on several student projects, particularly the work of Carmina Herrero and Vicky Marchant. Nails, those essential metallic fasteners, have long been with us. Their size, shape and design is basically a compromise between the makers' ability to control and manipulate material and the demands of the intended application. There were copper and bronze nails in antiquity, but in this paper I want to deal only with iron nails. In Rome, iron nails were common, and Cleere carried out the fine metallographic investigations on a large stock of nails recovered from a Roman fort site in Scotland. Those nails were hand forged; sorting them at the site on the basis of length, shape of head and shape of shank (in cross section) indicated that there seemed to have been some nail standardization. It appears that the Roman smiths used a series of heading dies starting with a 1/s-in. size. Each successive size increased by approximately 1/16-in. The metallographic inspection of the microstructures of the nails showed that the smaller nails were made in the one operation; i.e. both the tapering and the formation were accomplished on the heated rod without reheating. However, in the case of the larger nails, the nail had to be reheated for the tapering after the head had been forged. Most nails were tapered on all four sides of the shank and the shanks were square in cross section; only one group had rounded shanks. Most heads were flat disks, but in one group the heads were pyramids and another group had conic heads. Figure 1 shows the procedure used to produce the pyramidal heads. Obviously, Roman nail making was sophisticated and each nail design was meant for a particular use.

Jan 1, 1999