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By J. C. O'Rourke

"Gibraltar Mines Ltd. has been operating its open pit copper mine for fifteen years. In that time, over 140 million tons of waste and low-grade material has been placed on the mine waste dumps. Laboratory and in situ testing indicated that enough leachable copper was recoverable from the dumps to justify a leaching operation which would include the construction of a solvent extraction-electro winning plant. The plant, which was commissioned in October 1986, was designed to process 3000 USGPM of dilute copper solution to produce 5000 tons per year of high-quality cathode copper.This paper deals with the start-up and initial year of operation of this plant. The three areas: leaching, solvent extraction, and electrowinning are presented with emphasis on the innovations which were made to help overcome the problems unique to the Gibraltar operation.The Leaching CircuitThe mine waste dumps are leached to produce a pregnant copper solution as feed to the SX-EW plant. To achieve this the dumps are sprinkled with a mildly acidic solution which percolates through the dumps. In travelling through the dumps the solution contacts the surfaces of the liberated copper minerals and dissolves the soluble copper into the form of copper sulphate. The leaching reaction is achieved by a combination of bacterial action to oxidize the sulphides and solubilization of the copper into the acid solution.For the bacterial action to occur the dumps must be near the ideal pH of 1.9 to 2.1 and the necessary elements of the reaction must be present. Because a bacterial reaction is involved there is a lag time between the time when the conditions for bacterial growth are achieved and when the bacteria are in their active growth phase. Laboratory leaching tests with Gibraltar ore indicated that bacterial action takes two to three months to reach its maximum rate (Fig. I).The expected lag time for the planned rate of bacterial leaching prompted Gibraltar to start irrigating the dumps in late June 1986 for a plant start in early fall. The lag time proved to be longer than expected and the dumps took until November to start producing copper at the expected rate (Fig. 2)."

Jan 1, 1988

By Y. Wang, J. D. Miller, C. L. Lin, Virginia Tech

Conventional flotation machines are typically limited to a particle topsize of 150-200 microns due to inherent constraints created by the pulp and froth phases. To overcome these limitations, a novel fluidized-bed flotation system called the HydroFloatTM Separator has been developed specifically for the purpose of floating coarse particles containing only small amounts of exposed hydrophobic minerals. Over the last decade, this technology has been successfully applied to industrial minerals with several full-scale units installed to recover particles up to and exceeding 3,000 microns diameter. More recently, sulfidebased test work has shown that this novel device is also capable of recovering metalliferous values at a grind size that is much coarser than currently used in industrial concentrators. In the current study, high resolution X-ray microtomography (HRXMT) was used to experimentally compare the degree of exposed grain surface area necessary to recover coarse particles using the HydroFloatTM technology to that attainable using a traditional mechanical flotation cell. The data indicate that exposed grain surface area is a critical factor for coarse particle flotation. For the gold-bearing sulfide ore examined in this study, the HRXMT data suggest that near complete recoveries of coarse (850x500 µm) multiphase particles containing as little as 1% exposed grain surface area were realistically attainable using the HydroFloatTM technology. As such, this new technology may offer a unique opportunity for increasing concentrator capacity by increasing the primary grind size needed for rougher/scavenger separations.

Jan 1, 2016

By A. M. Girodo

"Dorbyl Heavy Engineering has been manufacturing winders since 1949 mostly for the South African mining industry.Table 1 shows that the vast majority of winders have been double drum winders. At the greater depths with larger ropes being employed, it became apparent that multi-rope winders would be needed. The high stress variation in Koepe winder ropes at great depths especially beyond 2000 m, ruled out this possibility. Thus the original concept was borne for the Blair multi-rope winder where the stress level variations in the rope would be as per the well known, tried and tested double drum winder. The Blair multi-rope was also devised to increase payload by using multiple ropes.With the increasing costs of transporting men and material coupled with fact that orebodies are getting deeper, various feasibility studies have been carried out by South African mining houses. For this reason Dorbyl Heavy Engineering has done conceptual design work of both double drum and Blair multi-rope winders with diameters up to 8.5 m dia (still well within our manufacturing capabilities). These feasibility studies have looked at depths approaching 4000 m*.This paper covers the typical duties leading to the choice of single drum, double drum, Koepe and Blair multi-rope hoists on South African gold mines. A brief synopsis of Dorbyl hoists in use in the South African mining industry, with some indications of future trends, will be discussed.With current installed depths of wind approaching 2500 m, the Blair multi-rope hoist has been used extensively for the heavier payloads.Some of the main considerations pertinent to the design of the Blair multi-rope hoist are illustrated together with the implications of using this type of hoist to winding depths of3000 m to 4000 m in the foreseeable future."

Jan 1, 1995

By Mohammed Rachek

Résumé : la mine d?Elhammam, opération du groupe minier Marocain Managem, est située au sud de la ville de Meknes à 63 km, elle exploite un gisement de fluorine depuis 1974. La minéralisation se présente sous forme de deux filons principaux orientés N45° avec un pendage variant de 65 à 90° NW, entre ces deux filons on note la présence d?une succession de filons satellites sécants. La méthode d?exploitation pratiquée depuis le démarrage de la mine est celle des chambres magasins, elle assure une cadence d?extraction annuelle de 250000 tonnes. Cette méthode favorisée par une très bonne compétence mécanique des épontes de la minéralisation a offert à l?exploitation une rentabilité très satisfaisante grâce à son faible coût mine. Les travaux de recherche géologique menés en parallèle à l?exploitation ont permis la découverte d?un nouveau secteur ?K-Est Gouaïda? (KEG) qui fait l?extension nord-est du gisement principal, la minéralisation de ce secteur se présente sous forme de deux filons très étendus latéralement (900 m d?extension) et présentant une puissance minéralisée irrégulière et très faible 1.2 m en moyenne, les épontes de la minéralisation sont constituées de schistes de qualité mécanique très faible. Vers la fin des années 1990, l?exploitation s?est orientée vers le développement minier du secteur KEG. Ce développement consiste à faire le choix adéquat de la méthode et de l?infrastructure minière pour l?exploitation de ce nouveau secteur, KEG. La méthode des chambres magasins, pratiquée dans le gisement principal avec un faible coût mine, n?est pas praticable dans le nouveau secteur à cause de la qualité de ses terrains, l?irrégularité de la morphologie de sa minéralisation et de la faible puissance des ses filons. Seule la méthode des tranches montantes remblayées (TMR) peut être applicable techniquement vu les spécifications suscitées de la nouvelle minéralisation, la TMR doit être appliquée sous sa variante mécanisée pour faire face au niveau exigé de la production. Après le pilotage de l?exploitation par TMR mécanisée dans le secteur KEG, il a été confirmé que cette méthode donne une grande satisfaction en matière de stabilité des terrains, sécurité, sélectivité, productivité et récupération du gisement, néanmoins elle reste pénalisée par un coût mine trop élevé pour garder le niveau de rentabilité recherché par l?exploitation d?un produit de faible valeur marchande telle que la fluorine. Dans l?objectif de rentabiliser l?exploitation du secteur KEG qui représente en réserves l?équivalent d?une durée de vie de 4 à 5 ans et d?assurer la pérennité de l?activité, l?exploitation en collaboration avec Reminex, la filiale d?ingénierie de Managem, a adapté une nouvelle variante de la TMR mécanisée dite TMR avec plan incliné sur remblai. Cette nouvelle variante de la TMR consiste à réduire au maximum les travaux dans le stérile en reconstituant un plan incliné sur le remblai à l?intérieur des filons pour faire évoluer en vertical l?exploitation des tranches en montant vers la tête d?un panneau de minerai. La variante des tranches montantes remblayées mécanisées avec plan incliné sur remblai a été imaginée et appliquer en 1978 dans la mine de fluorine de Burc située au Sud-Ouest de la France (Sicard et Mailloux, 1983). Imaginée pour une cadence annuelle de 30000 tonnes et une mécanisation très modérée cette variante a été adaptée par l?exploitation de la mine d?Elhammam en 2002 pour un haut degré de mécanisation et une cadence d?extraction annuelle de 250000 tonnes de minerai. Cette variante de la TMR est appliquée depuis le début de 2003 dans les chantiers du secteur KEG, elle présente les mêmes avantages techniques que la TMR mécanisée classique et elle a permis la réduction du volume des travaux d?infrastructure de 17.65 m à 6.25 m de travaux par 1000 tonnes de minerai. Ceci s?est traduit par une baisse du coût technique de la mine de 34% ce qui a donné un nouveau souffle à la mine pour assurer sa production et pour poursuivre la recherche géologique d?éventuelles zones à mettre en valeur.

Oct 1, 2004

By J. E. Hawley

"The zinc-lead deposit of the Lake Geneva Mining Company is on lot 7, con. VI, Hess township, Sudbury district, Ontario, about 10 miles northwest of the northern rim of the Sudbury Basin. Though a relatively small deposit, it shows some rather interesting relations to cross-cutting, pre-ore, quartz diabase dykes, which merit description.The deposit was discovered in October 1924 by J. H. Collins beneath iron-stained drift and oxidized sulphides. This proved to be the northwestern extremity of the orebody, the remainder of which extends southeast below swampy ground. Exploration began in 1927. In 1928 a vertical shaft was sunk to 250 feet and a level established at 235 feet. Later the shaft was deepened to 400 feet and new levels opened at 315 and 375 feet. In 1943 an inclined winze was sunk below the vein from the 315-foot level to a vertical depth of 640 feet, and two additional levels were opened at 525 and 615 feet respectively.The geology of the area has been described by T. T. Quirke (1), F. F. Osborne (2), F. J. Alcock (3), and Ralph Tuck (4). Private reports have also been made by Carl Tolman, J. E. Gill, and K. W. Fritzsche. Tuck's paper, covering the work completed to 1930, gives a detailed account of the character of the ore and enclosing rocks.Up to May 1944, when the property was closed, all ore above the 375-foot level and a small tonnage from below this elevation had been removed. Ore mined from 1941 to 1944 yielded the following:"

Jan 1, 1954

By A. H. Lang

Introduction The recent uranium discovery at Theano point, lake Superior, is probably a rediscovery of the first reported Canadian uranium occurrence. A description of material from the original discovery was published in 1847 by J. L. LeConte, and many attempts have been made to relocate the deposit. Such attempts have in the past been unsuccessful because of vagueness in the original description of the locality. Besides being a prospect that seems to merit development work, the Camray discovery is important because it reaffirms the occurrence of pitchblende in the eastern part of the Precambrian shield. Much staking followed the announcement of the discovery, and some additional finds have been reported. Location The Camray discovery is at the shore of Theano point, lake Superior, about seventy miles north of Sault Ste. Marie (see Figure 1). It is in township 29, range XIV, district of Algoma. The showing is two miles from Highway No. 17, and is reached by a rough trail that leaves the highway at mileage 72.9 from Sault Ste. Marie. There are no towns of any size nearer than Sault Ste. Marie.

Jan 1, 1949

By M. D. Lawton, P. Steen

"Drilling results from the established levels at AngloRouyn Mines Limited had indicated inadequate tonnages to meet the planning schedule. It was decided to develop the main zone of the orebody below the bottom working level of the mine. The orebody dips north at an average of 50 degrees and plunges to the west at about 10 degrees. Due to the need for rapid development of this area, a decision was made to use trackless equipment.This paper describes the method used and highlights the use of small 5-ton diesel trucks as carriers for the 2-cu.yd LHD machine. The method achieved advances of about 1,000 feet per month, at a dip of 12 degrees over a length of close to 2,000 feet, using as few as 20 men per day."

Jan 1, 1971

By J. Costigan, C. Corless

In 1997, damage as a result of Castrol R40 entering the INCO pressure carbonyl plant carrier gas stream was becoming increasingly severe. The oil in the gas stream was adversely affecting both equipment availability and process control resulting in rising unit costs. The main source of the Castrol R40 was determined to be the carrier gas and low pressure gas blowers. Plant personnel initiated a plan to prevent the Castrol R40 from entering the carrier gas stream by replacing the mechanical shaft seals with Ferrofluidics seals on these blowers. The following paper details a brief case history of the Castrol R40 in the carrier gas including impact on the plant. This will be followed by a technical discussion of the new sealing arrangement that was developed by plant personnel, Roots Blower and Ferrofluidics. Lastly, this paper will update the status of the blower upgrade project and document the results to date.

Jan 1, 2000

By Richard P. Curtin, John M. Goris, Lewis A. Martin

Cable bolt supports are being recognized as an effective ground control system in under-ground coal mines in North America, and their use has increased considerably during the past few years. The U.S. Bureau of Mines personnel are conducting both laboratory and field tests to evaluate the performance of these supports under a variety of conditions and to establish realistic design guidelines. This paper describes efforts to evaluate the capability of cable bolts to resist the high shear forces often present in longwall operations. Shear tests were conducted on pairs of 0.025 m3 (0.88 cu. ft) concrete blocks having joint surfaces ranging from rough to smooth. Tests were conducted on blocks both with and without reinforcement with 15.2 mm (0.6 in.) diameter steel cables. During each shear test, the loads and displacements along the normal and shear axes, as well as loads on the cable, were monitored. Cableloads were determined using strain gauges attached to the outside surfaces of the barrel-and-wedge anchors used for pretensioning the cables. Test results show that a cable bolt placed across a joint more than doubled shear resistance of shear blocks having both smooth and rough joints.

Jan 1, 1996

By R. E. Molnar, P. A. Riveros, V. M. McNamara

"This paper describes some recent research done at CANMET in the areas of ion exchange and A VR (Acidification- Volatilization Reneutralization), as applied to the recovery of gold and cyanide, respectively. It also discusses the ways in which these two technologies may be combined in order to minimize the environmental impact of gold milling operations and optimize reagent usage. IntroductionGold milling operations can essentially be divided into those that carry out a liquid/solid separation after leaching and those that recover gold directly from a leach pulp. The former produce a barren solution which may contain considerable amounts of cyanide, either free or cornplexed with metals. The latter produce a similar solution but this is now part of a slurry rather than a clear stream. Due to its toxicity, any excess cyanide must be destroyed before the effluent is discharged into the environment. Ideally, this should be (and sometimes is) accomplished by natural degradation. However, in many cases natural degradation alone cannot remove the last traces of rnetallocyanide compounds from the effluent and , as a result, most Canadian gold producers utilize a supplementary chemical oxidation system. This not only increases the operating costs, but concerns have also arisen in recent years about the formation of ammonia as a result of the chemical oxidation of cyanide (via CN--CNO--HCNO-NH3) ·"

Jan 1, 1993

By Barry James

"This paper discusses past and current energy use patterns in the mining and manufacturing sectors of the industrial minerals industry. Information is presented on the primary energy input types as purchased by the industry, the quality and form of the energy actually required by the various production processes, and the residual form of this energy, either embodied in the product or rejected in gaseous and liquid waste heat streams. With the continuing concerns about the availability of energy combined with the rapidly increasing cost of energy as a production input, the reduction of energy usage through improved efficiency will undoubtedly be an increasing priority for the industry during the 1980s. Reduced energy consumption through investment to improve energy efficiency appears to be advantageous from both the corporate and national perspectives.IntroductionEnergy, like labour and materials, is one of the basic production input s to the various mining, processing and manufacturing production stages in the industrial minerals industry. Energy costs, as a percentage of total production costs, have been well above the average for industry in Canada, accounting for more than 50 cents out of every dollar in the most extreme cases. Consequently, energy has always been a relatively important management concern in the industrial minerals industry.The energy supply and price situation in Canada and internationally has been changing rapidly since 1973, following a long period characterized by declining real energy prices and an abundance and wide choice of energy supplies. It is generally accepted that energy prices will continue to increase rapidly, and that there will be uncertainties about the long-term continuity of supply of some energy types. In essence, a period of relative stability has been replaced by a period of relative uncertainty. In such a changing situation, a reassessment of the role of energy as a production input is appropriate.The following sections outline some of the effects of the changing energy scene on the industrial minerals industry. These effects are dealt with primarily in terms of energy costs, because, in most circumstances, a change in the cost of energy as a production input is the end result of both energy price and energy supply changes."

Jan 1, 1981

By K. S. Raja, B. McNall, B. Pesic

"High-level radioactive wastes are stored in large underground storage tanks made of low-carbon steel. The wastes consist of concentrated solutions of sodium nitrate (NaNO3) and sodium hydroxide (NaOH), and the radionuclides 137Cs, 99Tc, and 90Sr. The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV), which in turn modifies the kinetics of corrosion of the storage tank. To understand the influence of technetate ions on the corrosion of steel, electrochemical polarization studies of A 537 steel samples were carried out in 1 M NaNO3 + 0 .05 M S r(NO3)2 + 0.1 M NaOH with and without addition of HReO4 at different temperatures (24 – 85 °C). The concentration of HReO4 was varied from 0.014 – 0.04 M.INTRODUCTIONAqueous processing of spent nuclear materials generates a large amount of high-level radioactive wastes. The wastes are primarily salt solutions of sodium hydroxide and sodium nitrate which also contain fission products such as 137Cs, 99Tc, and 90Sr. Among the high level radioactive fission products, Tc-99 is of great importance because of its high concentration, long half-life (2.1 x 105 years), high solubility in geologic waters as technetate, and rapid diffusivity through the geologic systems. The solubility of technetate ions varies depending on the oxidizing conditions prevailing in the storage containers. High level radioactive wastes are stored in single shell or double shell tanks made of low carbon steels such as ASTM type A15, A516-70 and A537. Most of the available literature on corrosion of steel in simulated radio active waste environments pertains to nitrate induced stress corrosion cracking (Subramanian & Mickalonis, 2005). The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV). Corrosion of steel and formation of Fe(II) and Fe(III) will affect adsorption and reduction of Tc species. The radioactive species can irreversibly be sorbed on the steel surface by oxidation of Fe(II) to more stable Fe(III) and fixed as less soluble Tc(IV)/Fe(III). The solubility of Tc species is also affected by other factors such as dissolved oxygen, local pH, temperature etc. How the corrosion behavior of steel will be affected in the presence of Tc species is not clearly understood.Cartledge (Cartledge, 1960) demonstrated that passivation of iron can be achieved in the presence of oxygen along with suitable inhibitor ions/molecules of the general formula XO4 n-, such as pertechnetate (TcO4 -). The pertechnetate ion is univalent. Since it is derived from a strong acid, no buffering action can be expected from this ion. The redox potential of the reaction (1) is 0.738 VSHE (Pourbaix, 1974)."

Jan 1, 2012

By Sukumar Bandopadhyay, Arunapuram Sundararajan

"Unique production and environmental problems are associated with multiple seam mining where dragfines are used for overburden and interburden removal. On the production side, the problems are decreased dragfine efficiency in chopdown operations, the general need for spoil rehandle, complications in sequencing stripping and coal handling operations, and potential stability problems in highly stacked spoil. Many variations of dragline methods have been reported in the literature to encounter these problems. Because of the physical properties and peculiar hydrology of sub-arctic region mining of multiple seams in such areas probably could not be done with the methods used in temperate regions.The properties of thawed material would make spoil hard to place in a stable manner and thus would influence the mini sequence. For instance, multiple seam mining which requires some rehandling of spoil and prolonged exposure of overburden and interburden material might be precluded by the instability of thawed spoil and therefore mining techniques have to be modified. Since the deployment and operation of a dragline in modes different from conventional schemes will affect productivity, it will be necessary to study the effects on production of changing the dragfine operational schemes. This paper presents a heuristic simulation model of multi-seam dragline operation of a sub-arctic mine that can be used to analyze the handling of overburden and detailed study of the dragfine performance."

Jan 1, 1986

By M. Reda

Erosion corrosion is acceleration in the rate of corrosion attack in metal due to the relative motion of a corrosive fluid and a metal surface [1]. The increased turbulence caused by pitting on the internal surfaces of a tube can result in rapidly increasing erosion rates and eventually a leak [2]. Engineers and scientists in different disciplines have worked for many years on methods of complete protection from flow induced corrosion or partially reducing corrosion of this type, and they have proposed or applied different countermeasures [2]. The accident at the Surry-2 nuclear power plant (USA) and other similar incidents have once again disturbed the scientific-technical community. This has forced the plant operating personnel and the management to undertake wide-ranging measures in order to discover on time, assess, and monitor such cases. In these extreme cases, protective coating and even metallic bulk material coating (the substrate itself) may suffer considerably from mechanically induced damage [2]. At high velocities, the "leaching out" dissolution reaction of particular, for example, steel elements at the solid-liquid interface become the rate determining step. One practical example for the difference between erosion corrosion and flow induced corrosion is the famous steam eruption from a Japanese [3, 4] nuclear power plant cooling system at the pressurized water reactor (PWR), turbine and in the condenser-steam generator connecting pipe. The rupture occurred in the carbon steel pipe connecting the condenser and steam generator. The damage occurred in the easily eroded/corroded carbon steel at a vulnerable location downstream of an orifice plate, In general, when there is significant reduction in pipe thickness through erosion/corrosion, distinctive patterns are visible, but those patterns were not observed in this case, Thus one can speculate that another phenomenon is possibly controlling, Fluid flow within pipes reduces the pipe thickness leading to an eventual rupture, The thickness reduction mechanism is erosion/corrosion, One example is "cavitations corrosion", Erosion and corrosion occur at the same time, and it is difficult to determine which one is dominant, Therefore, the term, "erosion/corrosion," is used [5]. In the atomic energy field, the terms "Flow Accelerated Corrosion" and "Flow Induced Corrosion" are also used. It is the purpose here to show that during flow induced corrosion a different mechanism may possibly be operating and in some cases it can be different from the well known erosion corrosion. Another example is fretting failures in early Canadian nuclear steam generators which was thought to be due to excessive vibration caused by high.

Jan 1, 2010

By Kenneth G. Thomas

Since approximately 2003 we have witnessed the unprecedented escalation in commodity prices. Coupled with economic chaos following the 2008 economic downturn this has caused difficulties in controlling schedule, capital costs and operating costs for mining projects. Once again escalation has returned to commodity prices fuelled by growth in the BRIC countries especially China and Brazil. This is further exasperated by the missing generation of skilled technical personnel not graduating from universities in the 1980s and 1990s owing to depressed commodity prices. This paper examines the six tenets for successful project implementation.

Jan 1, 2011

By M. Abumiya, N. Onodera

Stabilization of arsenic via the precipitation of large-sized scorodite (FeAsO4·2H2O) particles usually involves the use of expensive autoclave systems operated under high temperature and pressure conditions. Alternatively, DOWA developed a novel scorodite synthesis process (DMSP®) wherein the Fe(II) ions in solution containing As(V) ions were oxidized by O2 gas under atmospheric pressure. In this process, crystalline scorodite particles were formed via the formation of a gel-like precursor containing Fe(II). Based on this concept, in this study, we have demonstrated the synthesis of scorodite particles by the addition of Fe(III)-containing solution to the experimental solution containing Fe(II) and As(V) ions, without the O2 gas oxidation process. Ferric sulfate (Fe2(SO4)3) was used as the source of Fe(III) ions. Results indicate the precipitation of scorodite particles, comparable to that of the O2 gas oxidation method.

Jan 1, 2014

By Norman B. Davis

THE ceramic group of industries is comprised of those engaged in the manufacture of cement, glass, artificial abrasives, whiteware, including earthenware, stoneware, porcelain tableware, porcelain sanitary ware, electrical porcelain, floor and wall tile, porcelain enamel on metals, refractories of all kinds, sewer-pipe and structural clay products, such as terra cotta, brick, and hollow tile. The various sub-divisions of the industry produce a wide range of articles on which we depend for our creature comforts from day to day, perhaps to a greater extent than we generally realize. The industry, in turn, depends on a great number of minerals, and chemical products derived from minerals, and it is the object of this brief paper to present a list of these with notes indicating the particular applications. In order to bring home the importance of the industry to your daily life, stop and consider the many things around you accepted as a matter of course. Cement provides the smooth surfaces of many of our highways, city streets, and sidewalks. It enters into nearly all types of construction, alone or in combination with other clay products. Glass we hardly appreciate because we can see through it so easily, but it is there to serve us in windows, doors, and other light-transmitting structures. Glass is the universal means of transporting liquids and beverages, our beverages are usually served in it, and, with the recent development in fine spun glass textiles, there is a possibility of glass clothing in the future. Chinaware, a general term for table dishes, may be earthenware (not vitrified), semi-porcelain, or bone china, but it is before us three or more times a day ?and we seldom think of the minerals that have made these products possible. Floor tile, wall tile, and other ceramic specialties for interior and exterior use and decoration please the eye and provide sanitary surroundings.

Jan 1, 1938

By J. F. Liu, L. Chen, C. P. Wang

"Calcite-cemented joints abound in the rock masses of Beishan area, which is the most potential area for the high-level radioactive waste (HLW) disposal of China. The mechanical properties of Beishan granite containing a calcite-cemented joint with a dip angle of 82° was investigated under uniaxial compression and the acoustic emission (AE) characteristics were also studied in this paper. Compared to intact granite, the calcite-cemented joint caused a decrease more than 50% in uniaxial compressive strength and a decrease more than 90% in shear strength. The Young’s modulus was also decreased, while the circumferential deformation of jointed granite was sharply increased. The AE monitoring system successfully recorded the process of micro-crack development and the results indicated that the risk of rock-burst could be reduced due to the appearance of calcite-cemented joint.INTRODUCTIONThe properties of jointed rocks differ considerably from that of intact rock. Due to the difficulties in specimen preparation, analogue experiments with artificially prefabricated fractures are often used to study the mechanical behavior of jointed rock (Chen et al. 2012; Kulatilake et al. 2001; Singh et al. 2001). However, natural joints are not quite similar to the artificial fractures and it is necessary to investigate the mechanical behavior of jointed rocks. Xie et al. 2011 studied the mechanical properties of marbles with natural joints by uniaxial compression tests and found that the uniaxial compressive strength of jointed rock is greatly decreased. With the unaxial compression tests, Jacobsson 2005, 2007 tested the intact and jointed granites, which were taken from the potential site for high-level radioactive waste (HLW) disposal of Sweden. However, no significant difference in strength or modulus was found. The above research results are inconsistent and it indicates the complexity of the mechanical properties of natural joints."

Jan 1, 2015

By B. K. Mishra, Avijit Biswal, B. C. Tripathy, Abhijeet Singh, K. Sanjay, T. Subbaiah

We studied theeffect of anode substrates such as pure lead (Pb), lead antimony (Pb-Sb), and lead-silver (Pb-Ag) on the structural and electrochemical properties of electrolytic manganese dioxide (EMD). X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and chemical analyses were used to determine the structural and chemical characteristics of the EMD samples. The charge-discharge profile was studied in 9 M KOH using a galvanostatic charge-discharge unit. In all the substrates the current efficiencies were more than 99% except with Pb-Sb where it was 90%. Results revealed the nature of the substrate strongly affected the morphology of the deposited material which in turn affected the electrochemical properties of the EMD samples. XRD analyses revealed that the nature of the anode did not affect the crystal structure of the deposited EMD and all the samples were predominantly ?-MnO2, which is electrochemically active for energy storage applications. The EMD deposited on lead substrate showed superior discharge capacity of 245 mAhg-1 when compared with other substrates.

Jan 1, 2014

By C. Schmidt, M. Kohnk, C. Siemers, J. Kiese

The application of conventional titanium alloys is limited to 550°C due to their poor oxidation resistance. In addition, severe grain growth is observed in single-phase titanium alloys in long-term runs at elevated temperature leading to a degradation of their mechanical properties. In exhaust applications in automotive or aerospace engineering, products are often manufactured by cold-deformation like deep-drawing or rolling which is normally difficult in oxidation-resistant titanium alloys due to the presence of titanium-silicides. Therefore, in the current study, titanium alloys based on CP Titanium Grade 1S (soft grade) were developed showing (1) improved oxidation resistance due to a concerted addition of silicon, iron and niobium, (2) microstructure stability by the precipitation of hafnium-silicides mainly on the grain boundaries and (3) good cold-deformation properties. The industrial production route was developed so that the new class of Ti-Si-Fe-Nb-Hf-alloys is now ready for application in exhaust systems of planes or cars at minimum 800°C.

Jan 1, 2015