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By Yum Xiaoquan, Turgut Yalcin

"A laboratory study was carried out to determine the potential role and effect of ultrasonic irradiation in the flotation of a Sudbury copper-nickel sulphide ore. The use of ultrasound was tested separately at the pulp preconditioning, collector conditioning and flotation stages. While no significant benefits were evident in the latter two cases, ultrasonic preconditioning of pulp improved the grade-recovery performance and had the prospect of reducing reagent consumption rates. Tests were conducted on both the normal and oxidized ore samples, and several variables were investigated, including ultrasound frequency (25 kHz and 45 kHz), ultrasonic power (up to 1.6 W/cm2), duration of ultrasonic treatment (up to 60 minutes), and the intensity of pulp agitation employed during the application of ultrasound. Ultrasound frequency of 25 kHz and duration of 15 minutes yielded satisfactory results. Changes were found to occur in the temperature, pH and Eh of the pulp during ultrasonic processing. The favorable effects of ultrasound observed in this study were attributed primarily to its surface cleaning capability.INTRODUCTIONThe use of ultrasound for the surface cleaning of objects is well known. Ore flotation is based essentially on the surface properties of minerals, and hence stands to benefit from ultrasonic treatment which may help restore mineral surface characteristics that might have been lost or modified through oxidation, etc. Expected outcomes of this method of treatment include improved flotation kinetics, higher recovery, better selectivity, and savings in reagent consumption, as has been demonstrated by various researchers (Aldrich and Feng 1999, Celik 1989, Ozkan 2002, Letmathe et al. 2002, Nicol et al. 1986)."

Jan 1, 2005

By H. Wyslouzil

"The Kelsey Centrifugal Jig is a gravity separation device which utilizes the principles of the conventional mineral jigs but with the additional feature of being able to vary the apparent gravitational field. This is accomplished by utilizing the specific induced movements of the conventional jig within a centrifuge.Pilot plant trials have been underway since July 1988 to evaluate the potential applicability of this technology to various process streams at Rio Kemptville Tin.The grade/recovery relationships for samples treated in the jig were consistently better than results obtained from tables. Recoveries of more than 90% were attained at concentrating factors ranging up to 20. When compared with electrostatic separators, the jig achieved equivalent metallurgical results in a two stage process, without the expensive requirement of filtration and drying. Recoveries exceeding 96% were achieved with final concentrate grades averaging higher than 60% tin.INTRODUCTIONMineral jigs have been used for hundreds of years. Many different types have been developed, and each one has numerous variations. In recent years, the idea of applying centrifugal forces to conventional jigs has been put to practical tests and today a number of units are in commercial production. In principle, by enhancing the apparent gravitational field, it should be possible to recover finer particles by overcoming viscosity and surface effects which tend to limit existing gravity devices. In addition, it may be possible to use gravity to separate minerals with much smaller specific gravity differences."

Jan 1, 1990

By Jessica Barber

Problem ? Mining operations consistently need equipment that is available, and able to perform to its maximum potential ? The most difficult part of a Maintenance Manager?s job is often a lack of knowledge on how long their equipment has to last ? The short term view can lead to interim fixes that accumulate into larger problems ? It is always difficult to justify major overhauls and upgrades when there is pressure to meet mine plan production targets

May 1, 2008

By R. Dahlke, J. A. Finch

"A campaign was undertaken during the greater part of 2001 at Noranda’s Brunswick Mine Concentrator to investigate the role of gas (air) superficial rate distribution (Jg profile) to the cells in the final Zn cleaning stage (bank of seven cells). Three profiles were tested: Balanced (each cell with same Jg), Increasing (from cell 1 to 7), and Decreasing, along with an “as found” profile in a parallel control bank. The experimental design allowed for two confounding factors, changes in ore type and circulating load. The Increasing profile consistently gave the best metallurgy (down-the-bank grade / recovery). The reason for improved performance was traced to the response of the first few cells. The Increasing profile gave the highest selectivity of sphalerite against non-sulphide gangue (NSG) in these cells with relatively even recovery per cell down the bank (10-15% based on feed to each cell). The other profiles gave lower selectivity and higher zinc recovery in the first cells (up to 25% in cell 1), which combined to reduce overall bank performance. The increased selectivity with the Increasing profile is attributed to the low gas rate in the first cells reducing water recovery and hence limiting entrainment of NSG gangue. The Increasing profile was subsequently configured for all four stages in the zinc cleaner circuit.INTRODUCTIONThe performance of a flotation circuit is largely the result of the operator’s response to visual clues. This includes manipulation of the gas (air) input and how it is distributed to cells in a bank. A lack of sensors prescribes this approach. Over the past ten years the Mineral Processing Group at McGill University have developed a set of gas dispersion sensors including one to measure gas superficial rate (or simply “gas rate”), i.e., volumetric gas rate per unit cell crosssectional area, Jg (Gomez and Finch, 2002). The device collects bubbles in a tube immersed in the pulp and infers Jg from the pressure-time curve generated after a valve is closed and air starts to accumulate. The usual units are cm/s. It is robust, reliable and suited for plant use.A version of the Jg sensor was tested extensively during 2000 at Noranda’s Brunswick Mine Concentrator (Dahlke et al., 2001). The results were sufficiently encouraging that a sensor was fabricated to suit local requirements (Insta-Jg). The sensor detected malfunctioning field instruments and flotation mechanisms, and demonstrated that gas distribution to cells in a bank “as found” had no particular pattern, or profile. Preliminary testing suggested that a balanced profile (i.e., all cells with the same gas rate) gave superior metallurgy (grade / recovery down the bank) than the “as found” profile. This observation prompted a focused campaign to explore the impact of the gas rate (Jg) profile, introducing the notion of “gas distribution management”."

Jan 1, 2004

By S. Yalcin, S. Chang, M. Oliazadeh

"Present day ferrochrome demand is on the rise, as more steel products require this material as an alloying element. It is projected that the stainless steel demands will grow by about 6% per year to 2020; as such, the supply and demand for ferrochrome appears promising. Chromite is the only economical source of chromium, which is commonly upgraded by gravity techniques and used to produce ferrochrome. The gravity separation methods are not able to treat particles finer than 0.1 mm efficiently. Therefore, in processing chromite ore, a large quantity of fine tailings; some 25% of the mineral values have been reported as lost in slimes during processing. The chromite content of these tailings is typically 10-20% Cr2O3 and accumulates into a large stockpile/pond. A chromite concentrator project in Canada, considers a cut-off grade of 20% Cr2O3. This indicates further processing might be required to recover chromite from low-grade stockpile when the high-grade deposits are depleted. Low-grade ores normally indicates disseminated chromite ores with low liberation and consequently fine comminution. This paper reviews the techniques for treating chromite from fine material and provides some examples of successful operations in fine chromite recovery. Beneficiation techniques for fine particles include gravity separation, magnetic separation, and flotation. Several case studies are presented here that used one of the aforementioned methods or a combination of them.INTRODUCTIONChromium is one of the essential element and important material for production of ferrochrome alloys and special steel. Chromium occurs as chromium spinel, a complex mineral with chemical composition of (Fe, Mg) O (Cr, Al, Fe)2 . Chromite ore is exclusively found in ultramafic igneous rocks. Major associated gangue minerals are talc, quartz, serpentine and iron oxides.Chromite is a heavy mineral, with a specific gravity in the range of 4-5, relative to associated gangue minerals in a chromite ore, which makes gravity concentration a suitable process. This is generally true for coarse particles, ranging from 1 mm to 100 mm. Typically, the ore is prepared by crushing (and grinding if necessary) to a suitable size and the material is sized for the appropriate beneficiation techniques. It is common to use heavy medium separation (e.g. dense media drums, dense media cyclones, or Dyna Whirlpool) to treat coarse size and intermediate size particles (1 – 100 mm). Intermediate and fine particles (20 – 0.1 mm) could be treated by jigs. Spirals, shaking table, sluices, and Reichert cones can upgrade fine particles. Figure 1 shows a typical chromite beneficiation process flowsheet. As can be seen, it consists of three major sections: feed preparation (crushing, screening), de-sliming, and concentration. Beneficiation recoveries range from 80 to 85%, although the ratio of upgrading is only 2 to 3."

Jan 1, 2013

By T. Yalcin

"This paper describes the development of a mathematical model for determining the liberation of an ore at various grinding sizes, based on the combined results of microscopic counting, grinding tests, and chemical analysis.The method is illustrated with an application to the magnetite ore of Sherman Mine in Temagomi, Ontario. For this ore, a degree of liberation of 98.7% was determined at a grinding size of 90% passing 44 microns, which closely corresponds to the final grinding size employed at the Sherman Mine Concentrator.Introduction Liberation characteristic of ores have direct and significant bearing on overall economics of concentration processes.Target grades and recoveries can be achieved only it minerals are adequately liberated prior to separation. Degree of liberation depends on the extent of size reduction. However, due to the high costs associated with size reduction processes, it is important to keep size reductions within limits of satisfactory liberation. Prevention of excessive size reduction is also necessary because of inefficient mineral separations in very fine sizes. Hence, a study of reduction size — liberation relationship is essential for optimum profit from milling operations.A number of procedures have been developed for liberation studies (1-12), but there is lack of method for universal adoption.A new approach is presented in this paper that might provide a realistic estimate of liberation and give a practical guidance as to the degree of size reduction required for satisfactory liberation."

Jan 1, 1985

By Andrew Bamber

The introduction of pre-concentration technology into the underground narrow-vein mining scenario has the potential to change the entire economics of utilizing bulk-mining methods in these situations. An idealized integrated underground mining and processing system, comprising elements of bulk mining, underground preconcentration and backfill systems is presented. Through simulation and a systems engineering approach, the implications of enabling the utilization of bulk mining methods in a narrow vein deposit through the adoption of this technology is considered. Parameters considered include orebody characteristics, ore mineralogy, grade, metal value, mining rate and cost.

Oct 1, 2004

By D. M. Wyslouzil

"This paper was prepared for presentation at the 16th Canadian Mineral Processor's Annual Meeting, Ottawa, Ontario, Jan. 17 to Jan. 19, 1984.This paper gives an account of the development of treatment procedures for the differential flotation of refractory copper-zinc ores. Special references are made to the effectiveness of various zinc depressants and their combinations.Studies carried out on refractory copper-zinc ores demonstrated that conventional zinc depressants such as cyanide and zinc sulphate were not particularly effective when secondary copper minerals were present in the ore; the flotation activity of sphalerite was enhanced in the presence of cyanide.Among the various zinc depressants evaluated, the following depressant combinations were found most effective: Zn(OH) 2-S02 , 802-CaO, Na2S-Na2S03-S02, Na 2 S-S02 and Na 2S-S0rDS22.The practical application of any of these systems depends on the type of ore treated and other conditions such as pH, levels and points of collector and depressant additions.In this paper the effect of each depressant combination on different ores is described with reference to the selection of collectors."

Jan 1, 1984

By R. E. Jones

"Crusher sizing and application in mining operations is the selection of a crusher or a series of crushers to reduce run of mine ore to a size suitable for either autogenous or conventional grinding. It is important that the crusher or crushers be sized to operate within the range to which they have been designed. By the range to which they have been designed, we mean that the reduction ration must be held between specified limits. Reduction ration is the relationship between feed size to product size.In todays plants reduction is usually accomplished in three stages by primary, secondary and tertiary crushers.Primary crushers are either jaw or gyratory and are designed to handle run of mine feed at an open side setting of 5-1/2” to 7”. Reduction ration should not exceed 7 to 1.Jaw CrushersThe model size of a jaw crusher signifies the feed opening. A model 60 x48 jaw has a feed opening 60” wide by 48” long. The 48” is the dimension between the top of the swing jaw and the top of the stationary jaw. The 60” is the width between the two side frames. The crusher open side setting is the discharge opening at the bottom of the crushing chamber with the jaws in an open position. When corrugated jaw plates are used, the open side setting is measured from tip of one jaw plate to the valley of the opposite jaw plate. If a jaw crusher has a 6” open side setting with a 1” jaw motion, you could also say it has a 5” closed side setting."

Jan 1, 1974

By Scott A. Stebbins

Cost evaluation models constructed specifically to evaluate the economic potential of an individually motorized railcar system of ore and waste transport demonstrate that the approach may be considerably more cost effective than traditional rubber-tired haulage methods. The system design places a motorized drive unit on each railcar, as opposed to the more common configuration in which a series of un-motorized cars trail behind a single locomotive. These motorized railcars are directed to various load and dump points by a computerized dispatch system, and as such have the advantage of operating unmanned. In addition, the tractive effort of the rail-type drive system is noticeably more efficient than that of the rubber-tired mode of transport. The savings are realized primarily through comparative reductions in the requirements for labor and, to a lesser degree, energy.

Nov 1, 2011

By Bradford C. Wesstrom, Ricardo Parra

The Freeport McMoRan El Paso Refinery uses co-generation to produce some of its electricity and all of its steam. This paper will cover the operation of the co-generation plant natural gas turbine at a fixed RPM for blade longevity and energy output. The by-product heat from the turbine passes through boilers with additional heat from a duct burner to produce steam for the Tank House and auxiliary operations. The steam demand varies dramatically throughout the day based on unloading activities in the Tank House. The use of an automated steam control system within the El Paso Refinery will help stabilize line pressure by incrementally controlling steam consumption based on electrolyte temperature. This will minimize steam line pressure fluctuations. INTRODUCTION In the mid 1920’s the Nichols Copper Company of Laurel Hill, New York recognized the need for a modern copper refining facility in the southwest. Due to the many railroad heads, affordable power and abundant labor supply, and the close proximity to regional copper smelters in Mexico, Arizona, and New Mexico, El Paso became the logical location. In December 1928, ground was broken for the joint venture refinery between the Nichols Copper Company, Phelps Dodge, and the Calumet and Arizona Mining Company. In September 1930, Nichols Copper Company became a part of Phelps Dodge Corporation after a stock exchange. In July 1938, Nichols Division officially became Phelps Dodge Refining Corporation. In March 2007, Freeport McMoRan Copper & Gold acquired Phelps Dodge. Energy costs (electrical and thermal) are critically important in the viability of modern copper electrorefineries. The El Paso Refinery produces electricity and steam through its cogeneration system. The El Paso cogeneration facility is a natural gas, 15-megawatt facility containing five turbine generators and associated waste heat recovery boilers. The facility is divided into two phases. Phase I consists of two Allison 2.2-megawatt turbine generators. Phase II consists of three Solar Taurus 3.5-megawatt turbine generators. Presently three units in Phase II are operated. The Phase I units were purchased and installed in 1986 and the Phase II units in 1992 (Solar 1991). The facility operated at full capacity until 2003 when steam demand was significantly reduced due to decrease in cathode production and closure of the copper sulfate and precious metal operations. Phase I units were taken out of service and put on care and maintenance status.

Jan 1, 2019

By Julie Culverhouse, Dennis Grimm, Kieran Harding, Jean-Francois Boulanger

"Agrium’s Canadian Phosphate Business (CPB) is comprised of Kapuskasing Phosphate Operations (KPO) in Northern Ontario, Canada’s only operating phosphate mine, and Redwater Phosphate Operations (RPO) in Alberta, which manufactures the fertilizer from KPO’s concentrate.Production from KPO’s South Pit commenced in 2009 and introduced contaminant problems: high aluminium from crandallite and kaolinite clays. These issues caused a drastic decrease in P2O5 recovery and throughput in both plants. KPO attempted to reduce Al clays by means of aggressive desliming. Meanwhile RPO experienced high amounts of dissolved metals in their feed that are detrimental to fertilizer production.This paper covers the mineralogy of the problem, its impact on contaminant separation at KPO, on RPO’s process and on Agrium’s Canadian Phosphate Business as a whole.Potential solutions to the problem are discussed and analysed, including a process change to deslime high aluminium streams more aggressively and high grade ore flotation, which is atypical at KPO. The latter is a demonstration of the value of communication between the concentrator and the client, as KPO accepted a recovery loss and increased production costs in order to increase overall CPB profits. General lessons learned are discussed, followed by a section on ore blending.INTRODUCTIONAlthough the existence of the Kapuskasing phosphate deposit has been known since the 1970s, it’s only since 1999 that Agrium has been operating the Kapuskasing Phosphate Operations (KPO). The mine consists of three major pits (Center, North and South) from which a mining contractor hauls the apatite ore to the Agrium concentrator. The beneficiation plant processes the ore, separating contaminants such as Fe, Mg and Al which are detrimental to its client, Agrium’s Redwater Phosphate Operations (RPO). The KPO concentrate is finally thickened, filtered and dried before being shipped by rail to RPO.At the Redwater plant, the KPO concentrate is added to a sulfuric acid solution in an attack tank, to create a phosphoric acid solution and gypsum:"

Jan 1, 2011

By Sengpasith Houngaloune

Arsenic, which is a toxic and carcinogenic element, causes serious environmental problems throughout the world. It is also known as a major contaminant in the non-ferrous mining and extractive metallurgical industries, thus its disposal is one of the most important environmental issues for the mining and metallurgical industries. In order to ensure a safe disposal environment for the final wastes, stabilization of arsenic has been studied extensively with various approaches. Solidification/stabilization (S/S) represents one of the most effective methods to reduce the availability of arsenic in soil and waste by transforming toxic or potentially hazardous phases into less hazardous ones. Cement based S/S processes could reduce the solubility of arsenic in solid waste, using inorganic binders such as cement, lime, and pozzolanic materials. A new tailings management technique, called cemented paste backfill (CPB), has become widely employed for improving mining techniques and for tailing storage purpose and this technique could also enhance arsenic stabilization, by fixing the contaminants in the binder matrix. Disposal of arsenic in the form of scorodite (FeAsO4?2H2O) has been widely accepted as currently the most suitable method for stabilization and the safest known storage material. The Bio-scorodite process has been reported to be more economic and environmentally friendly method than the chemical crystallization processes. Retention of arsenic by schwertmannite (Fe8O8(OH)6SO4), a metastable ferric oxyhydroxy sulfate mineral, has gained more attention in the recent years. Schwertmannite has a large specific surface area and high capacity to adsorb arsenic in solution. Several researchers have reported that the transformation of schwertmannite to goethite could be retarded by the presence of adsorbed arsenic; therefore schwertmannite might be viable alternative for long-term storage of arsenic. In this paper, various approaches used in arsenic stabilization are reviewed with emphasis on the development in the recent years.

Aug 1, 2013

By D. M. Fraser

"Brunswick Mining and Smelting Corporation Limited operates two mines; one open pit (No. 6) and one underground (No. 12), approximately 20 miles south-west of Bathurst, New Brunswick. Both are massive sulphide deposits containing copper, lead, zinc and silver. The No. 12 property began operation in 1963 and is presently being mined at a rate of 3600 tons per day underground and is in the completion stages of an expansion to achieve 11,000 tons per day underground by the end of 1930.Originally at Brunswick Mining, acid mine drainage was added to tailings and neutralized by an excess of lime in the tailings. A conventional recycle system was established with a biostabilization pond for the treatment of thiosalts, a liming station and sludge settling area for neutralization of acidic water and a final reclaim pond with a pumping station for reclaim water.We found that not more than one third of the reclaim water could be used as it upset the flotation circuit every time it was used. It was established that the mine water and surface drainage were the cause due to oils and detergents in the water. It was also found that the biostabilization pond method Cf thiosalt treatment was not efficient for year round operation in our climate.In 1974, we reviewed the problems and began a 3 phase program to control effluents from the property:"

Jan 1, 1980

By Adrian Rosen

When one thinks of innovation and leadership in wireless communications, one would rarely consider a potash mine to be leading the way. Agrium Incorporated has proven that they are leaders and innovators, as is evident in their recent deployment of a large-scale 802.11 wireless network in their underground potash mine located at Vanscoy, Saskatchewan. 802.11 is an IEEE standard for Wireless Local Area Network (WLAN) technology. Rather than simply replace an aging communications infrastructure, Agrium chose to let technology provide the framework for future success

May 1, 2006

By Norman O. Lotter

The problem of quantifying the full performance potential of an ore body in a concentrator, and how to configure a flowsheet to achieve that potential, either for a new operation or an existing one, is a strategic challenge. Modern flowsheeting technology that has been developed over the last twenty years has provided a suitable platform to achieve this. The integrated use of geology, compositional and quantitative mineralogy, sampling models, quality controls, and mineral processing, including flotation testing, has evolved into what is now called process mineralogy. Two specific tools have been developed and validated as standard methods in this toollbox. These are statistical benchmark surveying and high-confidence flotation testing. Both of these have borrowed from the sampling theories of Pierre Gy and from geostatistics. Additionally, they work on a replicate measurement and averaging basis, thus reducing the overall random error level. With this arrangement, one is in a position to characterize the ore from true samples and identify and quantify the economic minerals present in a manner that easily brings out the processing implications and likely grades and recoveries. In particular, the approach captures the variation in the ore body, which, if properly translated into the flowsheet design, minimizes the risk that unexpected responses will develop in the concentrator operations. A further advantage is that successful plant trials are now possible and practical. An overview of this approach is presented with two case studies.

Jan 1, 2011

By Tony Lipiec, Chris Fleming, Larry Urbanoski

In 2009, the Canadian Mineral Processors (CMP) became aware that Canadian securities regulators were amending the contents of National Instrument 43-101. NI 43-101 is a set of regulations which establish how ore resources and reserves are presented to the investing public. The documents produced under NI 43-101 are central to the ability of many companies to raise financing for their projects. With the increase of metallurgical complexity, and decrease of head grades encountered in new deposits, the role of the Qualified Person (QP) in determining process performance has become increasingly critical in determining the classification category of resources and reserves. Given the challenges confronted by those involved in defining the concentration and extraction of minerals and metals, there is a need to provide support to these QPs. To address these concerns, the CMP established a sub-committee in 2010 to create a set of guideline documents to assist the QP involved in process matters as to what should be included at the various levels of study supporting the establishment of resources and reserves in NI 43- 101. The results of the sub-committee work are presented and the considerations in the writing of the documents are discussed.

Jan 1, 2011

Conventional waste management practices produce two waste streams for the construction of separate disposal facilities. The design of tailings impoundments is usually controlled by physical stability. Waste rock materials offer high shear strength characteristics for waste dump construction, however the hydraulic properties promote oxidation. The problem of oxidation is significantly reduced for tailings due to a fine texture that augments water saturation. Co-mixing of tailings and waste rock involves the intimate blending of tailings and waste rock to create a new material with superior physical and hydraulic properties. The new material has a low hydraulic conductivity, low compressibility, high water retention capacity and high shear strength. Co-mixed tailings and waste rock restrict oxygen entry and water seepage to minimize acid generation and metal leaching. Co-mixed tailings and waste rock may be used to construct cover systems, internal barriers and seals, confinement structures and full depth waste repository. The results of a laboratory program to characterize the physical and hydraulic properties of Comix tailings and waste rock are presented here. Various ratios of tailings were blended with three distinct waste rock materials. The saturated hydraulic conductivity for the Co-mixed materials was found to vary between 2 x 10-7 m/s and 5 x 10-8 m/s depending on blend ratio, waste rock type and compaction. This paper introduces concepts for the co-disposal of tailings with waste rock and evaluates the hydraulic behaviour of a Co-Mix waste system. The potential benefits of Co-Mix are shown for a typical mine.

Nov 1, 2002

By M. Pourkani, M. Karga, Samid Banis, Andre Laplante, G. Langari-Zadeh

"The Sarcheshmeh mine processes 40,000 t/d of ore grading 0.9% Cu and 0.035% Mo. Grinding is effected in single stage ball mills using 80 mm forged steel balls, with an average consumption of 850 g/t. One of its 5 m diameter, 8 m length ball mills was emptied to measure the ball size distribution. The broken balls were first separated from the total charge, and the remaining balls classified into five size intervals of +7O mm, -70 +60 mm, -60+50 mm, -50+40 mm, -40 mm.The charge was composed of 280,534 balls (excluding broken balls) with a total mass of 305,180 kg. It was found that 4.0 % of the balls were broken; the size distribution of the charge was also markedly different from the desired one, in particular for the small-sized balls. For instance, 9% of the balls were expected to measure 2.54 to 3.18 cm in diameter, but none was found. On the other hand, the amount of top size balls was 30% higher than expected. The radial hardness of balls, which was determined by cutting the balls in halves, showed that the hardness sharply drops when the balls become smaller than 65 mm. The unexpected ball size distribution was attributed to the rapid change in the balls radial hardness. Based on the measured ball size distribution, a new ball make-up charge which uses 80% of 80 mm and 20% of 60 mm balls instead of 100% of 80 mm was proposed and implemented. The effect of the new ball make-up procedure in terms of ball consumption and grinding efficiency is being investigated."

Jan 1, 1999

By Joseph L. Fournier

Suncor Oil Sands employs delayed coking technology in converting bitumen into synthetic crude oil. Currently up to 10,000 m3 of delayed coke (coke) is produced per day as a byproduct of the upgrading process, of which up to 9,000 m3 per day is placed in dry storage on Lease 86/17. A review was completed to examine the case history of leachate potential experiments from the dry storage of coke and the environmental relevance of coke leachate studies conducted over the past decade. The review included an evaluation of the potential impacts of environmental conditions within the location of coke storage, including precipitation pH, as well as daily and annual ozone trends. Coke leachate potential has historically been characterized using standard leachate testing protocols (i.e., TLCP, SPLP) together with other studies that have employed strong acids and oxidizing agents in the extraction fluids. The present paper highlights prevailing conditions in the Athabasca Valley air-shed with emphasis given to ambient ozone (oxidizers), as well as precipitation pH and acid input deposition rates, and will demonstrate that TCLP / SPLP tests lack the intended environmental relevance relative to the conditions under which coke is stored.

May 1, 2011