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By d&apos, Alton AJ, Rigden DT

Modern petroleum refining offers a complexity of environments, each requiring different metals for the satisfactory performance of-the various sections of the refinery, and this paper first outlines the varied enva.x¦on-ments thus met.It follows that the metal types in use will also vary to suit each particular environment, and the paper' consequently covers the use of ferrous-metals, ranging from plan carbon steels to the high alloy types and the non-ferrous metals, particularly copper and its alloys.The failures of some,of these metals and alloys are then illustrated by experiences it Kwinana. These failures are duo to (a) corrosion, (b) erosion, (c) faulty welding, and (d) mechanical defects,' of which the first is by far the most prevalent. The protective measures taken to prevent subsequent failures are then given under one or other of the following headings :(1) alterations in process conditions, (2) the use of alternative ,alloys,(3) suitable heat treatment, (4) redesign of the failed section, (5) cathodic protection, and (6) use of corrosion inhibitors.Reference is then made to the use of specialised metals and alloys.Metals, generally in the form of oxides or salts, are also used as catalysts in refining processes. Activated alumina is used, combined with silica .forScracking' of heavy oils, and as a support -for platinum, cobalt, molybdenum, nickel and similar metals, which catalyse hydro-genation and dehydrogenation-processes. .In the final formulation of petroleum products metallic compounds may be added. Reference is made to the large quantities of lead used by the petroleum industry and to the use of metallic soaps and detergents in the formulation of lubricating oils and greases.

Jan 1, 1962

By Clappison D. J

Since its formation in Papua New Guinea and raising of A$2 million in 1980, Niugini Mining Limited (NML) has grown to a company capitalised on the Australian Stock Exchange at about A$350 million. In 1995 the company produced some 237 000 ounces of gold, 700 000 ounces of silver and nearly 5000 tonnes of copper from its operations at Red Dome, in North Queensland and San Cristobal in The Atacama Desert of Northern Chile. This production contrasts with Niugini Mining's first mining venture at Mt Victor in the Eastern Highlands of PNG which yielded 20 000 ounces of gold and 11 600 of silver between 1987 and 1989. Following the formation of an exploration joint venture in 1982 with Kennecott Explorations (Australia) Ltd, now a subsidiary of RTZ, Niugini Mining's early recognition of the gold potential of volcanic rocks at plate margins led to discovery of the Lihir deposit in July 1982. This deposit containing about 42 million ounces of gold in resources, is one of the largest undeveloped gold deposits in the world. Following raising of equity funds through the float of Lihir Gold Ltd and debt finance in 1995, construction of the mine at a cost of US$673 million is now underway with first full-scale production at approximately 600 000 ounces of gold per year expected in early- 1998.

Jan 1, 1996

By D Craw

The Hyde Macraes Shear Zone is a mineralised low-angle shear within the Otago Schist traceable for ~30 km with a NW strike. It is been actively mined along 12km of this strike, producing >6 Moz of gold. The shear zone consists of greenschist facies rocks with a mineralogy only subtly different from that of the host schist. Pervasive fluid flow has occurred along grain boundaries and within microshears which have been enhanced by the deposition of hydrothermal graphite. We model the development of these microshears using a threedimensional numerical code. For an inhomogeneous initial rock with lithostatic fluid pressures and a dynamic permeability deformed under dextral non-coaxial flow, deformation is distributed into weak shear bands. Graphite deposition and associated reaction-softening has a dramatic effect on the development of model shear zones. Graphite is deposited into a shear band, weakening it and further localising the deformation into that shear band, producing an anastomosing and interconnected shear zone structure such as observed in the HMSZ. The degree of graphite precipitation and graphitic-induced weakening are varied in the models. More graphite precipitation with a low degree of reaction-softening results in more diffuse shear bands. In contrast less graphite deposition but with a high degree of reaction-softening more leads to the development of more focused shear bands. Graphite deposition has clearly controlled the formation of the HMSZ structure, and is an important indicator of potentially mineralised structures elsewhere.

Jan 1, 2007

By McOnie A. W, Rutherford PG

A volcanic sequence is described from the Golden Cross Mine, Waihi, New Zealand. The sequence includes seven lithostratigraphic units comprising flow and pyroclastic units of Coromandel Group andesite and dacite and overlying Whitianga Group dacite and rhyolite which is intruded by the Golden Cross dacite porphyry and rhyolite dykes. The sequence is mineralized and is unconformably overlain bv_ two post-mineral units, the lacustnne Waitekauri beds and Omahine Subgroup andesite. Detailed structural analysis of mine data has identified four deformational events (D 1-D4) and related these to the gold-silver mineralizing events. Faulting was coeval with the mineralization and directly controlled the development, localization, style and geometry of the ore shoots. Mineralization developed in competent lithologies where dilation occurred during faulting. The Empire Fault is the master shear which controlled fluid flow. Mineralized veining developed in response to tectonic pulses occurring at slightly different stages as represented by the underground Empire vein complex and the open pit vein array. The mineralizing events culminated with the deposition of barren calcite veins. Post-mineral movement along the Western Boundary fault appears to have offset the ore body.

Jan 1, 1995

The role of metals in the economy is discussed with regard to the flow of metals through to final demand and is illustrated by data for seven metals. Factors influencing the changing pattern of metal consumption are described, including relative prices. A des- cription and discussion of current metal demand forecasting methodologies precedes a discussion firstly of broad economic trends and secondly of the evolving pattern of metal consumption relative to GDP (metal consumption intensity), as technology and other factors change and as economies mature. The tendency for metal consumption intensity to plateau and decline when economies reach a certain region of per capita GDP, following a rapid rise early in the industrial- ization process, is shown in comparative data for seven metals and six countries.

Jan 1, 1979

By Taylor G. R

Fluid inclusions within quartz accompanying several stages of mineralization at Hillgrove are de cri bed. Pyrite-arsenopyrite-gold mineralization shows uncorrected filling temperatures of between 195°C and 250°C. Later stibnite-antimonide-siderite and stibnite-calcite mineralization has filling temperatures between 100°C and 195°C and a bimodal distribution of temperature peaking at 175°C and 145°C, possibly correlated with the two stages of mineral deposition. Secondary included fluids within an earlier generation of deformed quartz veins are derived from hydrothermal fluids contemporary with the main-stage mineralizing fluids described above. Primary inclusions within latestage, cross-cutting quartz-chlorite-calcite veins show these veins to be unrelated to the mineralization.A correlation between filling temperatures and salinities indicates that mineralization accompanied the mixing of a hot, partly saline, fluid (at 5 per cent equivalent NaCI) with cooler, less-saline meteoric or connate water. Over a vertical distance of 200 m, equivalent mineral assemblages were deposited over the same temperature range. Studies on single crystals suggest rapid deposition with fluid temperature dropping 45°C during their growth. Ore mineragraphy and the fluid inclusion data suggest that the metals were transported by sulphur-poor, relatively low-temperature, low-salinity solutions, possibly as carbonate complexe , and that a vertical zonation of the W-Sb-Au mineralization is compatible with the mixing of this hydrothermal fluid with cooler groundwater. Regional metallogenic and geological considerations suggest that ore metals are derived from the remobilization of deep-seated stratabound deposits or from metamorphic fluids expelled from deepseated volcanoclastic sediments.

Jan 1, 1984

The Quioma Mine is located along the axis of the Cordillera Oriental, 130 km southeast of Cochabamba, South Central Bolivia. Silver, lead, zinc, antimony, and gold have been intermittently produced from veins in the Quioma area since Colonial times. Mineralization occurs within steeply dipping fissure veins transecting moderately folded Lower Ordovician sediments. Tectonic activity is early to mid-Tertiary and the vein system parallels the fold axis of a major northwest-southeast striking, doubly plunging anticline. Vein sets occur within a 2 km wide band over a strike distance of 13 km along the northeast limb of the anticline. Economic mineralization occupies syntectonic pre-mineral fault zones developed in more competent stratigraphis units of Lower Ordovician clastic sediments. Veins average 55 cm in width, although mineralized structures up to 3 m wide with a known strike length of several hundred meters have been mined. Mineralization consists of siderite, argentifferous galena, sphalerite, and quartz, with minor amounts of chalcopyrite, barite, and bournonite. Pyrite is rare except at the Boston vein where it occurs with stibnite that contains trace amounts of gold. A marked characteristic of veins in the district is evidence of repeated stages of movement during mineralization. Intrusive rocks are rare in the Quioma area. Narrow porphyritic dikes of Andesitic composition averaging 1 m in thickness have been observed. These dikes occasionally show a close spatial relationship to the veins and are often kaolinized and carbonitized. Vein and dike contacts are sharp and alteration does not appear to extend into the wall rock. Mineral zoning is suggested by antimony mineralization observed in peripheral areas of the anticline.

Jan 1, 1987

By Smith DM Jr

Silver deposits, in which silver forms at least fifty percent of the value of the ore, are abundant and large on the east side of the Pacific and are absent in the western Pacific. To determine if this uneven distribution is related to features of consuming plate tectonic boundaries which dominate the metallogeny of the Pacific Rim, the variation of Ag/Au in porphyry copper deposits was used to estimate the relative silver content of magma generated in subduction zones. Porphyry copper provinces with high Ag/Au occur in regions of the eastern Pacific where silver deposits are abundant, suggesting that the distribution of silver deposits is controlled by the relative abun- dance of silver in subducted ocean crust. Ocean crust being subducted in the eastern Pacific is mostly less than 50 million years old in contrast to most ocean crust in the western Pacific which is much older. Enrich- ment of silver in young ocean crust at spread- ing centers may reflect metallogenetic evolution over geologic time. Silver may be transported to the surface in volcanic rocks, and deposits are common where felsic varieties are abundant. The high ,solubility of silver in natural waters provides a natural storage mechanism for silver weath- ered from these rocks and ultimately circulated in near-surface hydrothermal systems where many silver deposits form. The regional distribution of silver deposits is not influenced by discoverability, vertical metal zoning, or regional tectonic style. The effect of igneous differentiation is unclear.

Jan 1, 1987

By Williams SR

Column Flotation cannot be used indiscriminately. Based on extensive pilot plant experience at Lakefield Research, a number of limiting parameters have been identified for the application of column cell flotation. Parameters of importance are the use of wash water, flotable mineral content, pulp viscosity, type of mineral selectivity being sodght and degree of mineral liberation. The paper discusses when wash water should be used and the positioning of a column within the circuit as this is important to maintain a sound water balance for the circuit and prevent excessive circulating loads. Other areas of debate are pulp chemistry, very low and high weight recovery, for which the conventional column is a poor selection of equipment, and treatment of complex ores, where the separation of valuable minerals is more difficult than non-sulphide, sulphide mineral separation. Based on these observations, the application of column flotation must be carefully considered or can be optimised.

Jan 1, 1993

By Koppe JC, Strieder AJ

The Rivera Crystalline Island (RCI) is an erosional window of the intracontinental Parana Basin that outcrops in the Rivera Department, north of Uruguay. RCI is made up mainly by Precambrian granites, metasediments and granite-gneisses. This island is crosscut by a dextral transcurrent shear zone system, the Rivera Shear System (RSS). The bulk strain ellipsoid was defined by previous work and has allowed the evaluation of shear dynamics. The geometry of the shear system is made up of two shear directions: E-W (P-shear), which turn right to NW-SE direction (R-shear), leading to the development of extensional bends. The shear zone system was developed in brittle-ductile to brittle regimes, under temperature conditions compatible with greenschist facies metamorphism. The shear zones are marked by an intensive fracture cleavage development. Mylonites develop only in narrow, discontinuous higher strain zones. Internally, the shear zones are dominated by intrusive rocks, mainly granites, dacites and diorites. Hydrothermal alteration has been developed in several areas.The economic significance of RCI is given by several small gold deposits, which have been exploited since 1869. One major new gold mine is under development, the San Gregorio Gold Mine. This gold deposit is locally controlled by a dilatant site where R-shear turns right to P-shear. Mine lithologies were deeply altered by hydrothermal fluids in the dilatant structure. This work presents the lineament-structural analysis carried out to identify similar structural patterns in all RCI sites favourable to host other gold deposits. The exploration program also considered remote sensing, geology, geophysical and geochemical survey.

Jan 1, 1997

The Mammoth Copper Deposit consists of three distinct orebodies adjacent to the Mammoth Fault. This fault is arcuate, changing from a normal tension fault to a shear strike fault just to the north of the mine. Movement on the fault was probably contemporaneous with deposit- ion of the adjacent sediments. In the upper levels the No. 1 orebody occurs within a brecciated zone in the footwall of the fault, but at depth the No. 2 and 3 orebodies are stratabound by two brecciated lithologic horiz- ons. The host rocks are impure sandstones, arkoces and quartzites, which in the mine area are near the top of the Lower Proterozoic Myally Beds. Overlying these beds is a conglom- erate siltstone sequence which has been assumed to be the base of the Gunpowder Creek Formation. North and south of the mine the conglomerate rests on an erosional unconformity representing a major time break, but in the mine the uncon- formity and conditions of deposition of the conglomerate are obscure. Some mineralization is contained within the conglomerates. The sulphides present are chalcocite, bornite, chalcopyrite and pyrite. Chalcocite is dominant in the upper levels but could be en- riched by supergene processes. At depth, bornite becomes the dominant copper sulphide with lesser amounts of chalcopyrite, pyrite and primary chalcocite. Throughout the orebody minor digenite and covellite occur and arsenic is a minor constituent bound up with the pyrite. The bulk of the sulphides occur in stringers, fractures and breccia interstices but finer grained primary bedded sulphides can be observed. The genesis is probably a complex process in- volving active tectonic movements extending from deposition to post lithification giving numerous phases of brecciation and redistribut- Ion.

Jan 1, 1974

By M D. Rosengren, G Gregor, M F. Young

Over the last 15 years the silver/lead/zinc ore treated at Mount Isa became increasingly complex and lower grade. Metal recoveries dropped dramatically, causing a serious decline in profitability. The ætraditionalÆ response of increasing tonnage to reduce unit cost was unsuccessful, since the additional tonnage was even lower quality ore. A major technical and capital program in the 1990s restored metallurgical performance, but business return was still too low and ore quality continued to decline. In 1996 a new, holistic approach integrated the steps of geology, mining, concentrating, smelting, and refining. Previous assumptions about æfixedÆ and æmarginalÆ costs in mining and processing were shown to be wrong. Detailed analysis showed that some ore sources were reducing profit. This led to a fundamental redesign and downsizing of both Mount Isa and Hilton mines. The result was dramatic increases in head grades, metallurgical performance and plant stability without any capital expenditure. The business is now smaller, but more profitable.

Jan 1, 1998

By Watson DF

Calculation of the amount of metal in an ore deposit or mining block should be approached by multiplication and integration of appropriate numerical manifolds describing the spatial distribution of the relevant variables, viz. grade, specific gravity and also thickness for bivariate data. Construction of a numerical manifold necessarily involves some form of interpolation but detailed characteristics of this are often not specified in various automatic methods, some of which even provide manifolds with discontinuities. A manifold used in calculations should describe in a geologically plausible way the spatial distribution of the variable of interest. Different approaches to the problem are discussed and compared. Particular computational inconsistencies emerge when "accumulation" is used as a variable in calculations of average grade. If an ore deposit is variable in relation to its sampling and especially if selection of mining blocks according to grade cut-off is a necessary operational decision, the biases introduced by accumulation methods can bring about serious problems of over-evaluation. Modern computational techniques make unnecessary the use of accumulations; because of potential inconsistencies it would seem unwise to use them in any ore reserve computation.

Jan 1, 1987

By Biswas AK, Hayes P

During the reduction of iron oxide pellets in the blast furnace it has been found that catastrophic swelling (up to 300% volume increase) can occur. Although the burden preparation conditions can be designed to avoid this phenomenon the exact reason and mechanism of the swelling has yet to be clearly identified. Swelling of the burden is undesirable since it reduces the interparticulate voidage in the blast furnace thus reducing gas flow through the stack resulting in low production rates of iron. The present study differs significantly from previous experiments in that reduction is carried out on single crystals of wustite thus the problems of control of gas composition and specimen preparation are minimised. The microstructures formed on reduction have been examined by optical and scanning microscopy. Pure wustite and wustite doped with various levels of CaO have been examined after reduction in controlled CO-CO 2 gas mixtures at 968¦C. The catastrophic swelling on reduction coincides with the formation of an unusually open iron structure in which the iron appears as whiskers or needles as previously reported. The spacing and thickness of the needles are shown to vary with impurity content and gas composition. Metallographic examination has shown in addition, however, that the whiskers do not necessarily constitute the only product form of the iron produced and in CaO containing wustites with less than - 2% CaO there is a transition from needle growth to porous growth of iron. Thus the % swelling of the oxide particles is dependent on the initial size of the oxide grains. Samples of FeO - 10% CaO exhibited a previously unreported product inorphology associated with the nucleation of 2CaO.Fe203.

Jan 1, 1980

The first stage in the refining of lead blast furnace bullion is the removal of copper and is normally done as a batch process in open kettles.A number of attempts have been made to establish continuous processes operating in reverberatory type furnaces, but the growth of accretions in the furnace has always presented a serious problem.The Broken Hill Associated Smelters Pty. Ltd. (RH.A.S.) at Port Pirie have overcome this problem by constructing a reverberatory furnace and ancillary cooling system of a novel design.Although a number of mechanical and metallurgical problems still remain to be solved, it is claimed that a workable continuous copper drossing process has been established.INTRODUCTIONLead bullion emerging from the blast furnaces at Port Pirie is at a temperature of about 1100°C and contains, among other impurities, about 1 per cent of copper.The first stage of refining is the removal of this copper by a drossing operation and in the past this was done, batchwise, by allowing the bullion to cool back in 100 ton kettles.At about 700°C, copper dross begins to separate as a crust on the surface of the kettle and this separation was allowed to continue down to about 450°C when the crust was brokenup and skimmed manually using a long handled, balanced, spoon. The dross was then smelted in a reverberatory furnace to produce a saleable copper matte and separate out lead bullion, which was returned to the drossing kettles. The copper content of the drossed bullion was then further reduced by a sulphur treatment process.The drossing operations involved hard manual labour under arduous conditions and the pouring of hot bullion into...

Jan 1, 1963

By C Rizos, A Ng

Land surface deformation can be caused by underground mining activities. The maximum subsidence normally occurs directly above the location of the excavation of the coal seam. In the case where the longwall mining technique is applied, the magnitude and shape of the subsidence bowl are constrained by the longwall structure (pillar). This paper describes the use of satellite radar interferometry for monitoring surface subsidence due to underground mining, as a cost-effective geodetic technique and complementary to conventional ground surveying techniques. This paper uses data acquired by the current generation of SAR satellites û the European ENVISAT and the Japanese ALOS û to monitor ground subsidence in the southern highland coalfield in New South Wales, Australia. An accumulated DInSAR subsidence mine map is produced using six successive ALOS acquisitions. The results are post-analysed with the aid of geographic information systems (GIS) and validated using ground survey data.

Jan 1, 2008

By H Zhang, Y Wang, S Sukenaga, H W. Ni, H Shibata, W Z. Mu

The crystallisation behaviour of low melting point CaO-SiO2-Al2O3-MgO inclusions greatly affect the deformability of inclusions during the rolling process. The crystallisation characteristics of CaO-SiO2- Al2O3-MgO melts representing the oxide inclusions in Si-Mn killed steel were systematically investigated. The effect of Al2O3 and MgO contents on the crystallisation change were analysed under a fixed CaO/SiO2 in the complex inclusions. The continuous-cooling-transformation (CCT) and time-temperature-transformation (TTT) experiments were conducted. The results showed that the increase of MgO content increases the crystallisation ability of CaO-SiO2-Al2O3-MgO inclusions, while the increase of Al2O3 content has the opposite effect. The viscosity, liquidus temperature of oxide melt and also the initial crystallisation potential might be the reasons for the change in crystallisation behaviour. Also, the crystallisation activation energy could semi-quantitatively characterise the crystal growth during the crystallisation of inclusions. To obtain low melting point plasticized CaO-SiO2-Al2O3-MgO (CaO/SiO2=1) system inclusions, the Al2O3 content of the system needs to be controlled larger than 15 wt per cent and the MgO content should be kept at a small amount.

Aug 21, 2024

By Mistra M, Hu JS, Wadsworth ME

The fluorite/oleate system has been studied extensively since the begin- nings of flotation research. The well-defined relatively simple crystal structure of fluorite and its ionic bonding make it a model system for study. Our understanding of fluorite/ oleate flotation chemistry continues to grow but as yet remains incomplete. Besides a review of our understanding of this system, recent findings are presented in this paper, and new research horizons are identified.

Jan 1, 1984

By Hoffmann CF, White NC, Tedder IJ, Wood DG

Since the discovery of Pajingo in 1984, the northern Drummond Basin has emerged as a significant new gold province, and has become the focus of intense exploration for epithermal gold mineralisation. Prospects in the Conway area are hosted by felsic to intermediate lavas and volcaniclastic rocks near the base of the Drummond Basin sequence. These Drummond Basin rocks appear to represent favourable hosts to mineralisation because they are cut by structures which could have focussed and channelled fluids on a regional scale, and because they constitute a possible source of gold and, perhaps more significantly, sulphur for the transport of gold. Prospects in the Conway area are up to 15 km2 in area, and are of the adularia-sericite type. They illustrate many of the classic features (siliceous sinters, alteration mineralogy, and fluid characteristics) recognised in epithermal deposits. K-Ar dating of sericite alteration in three of the prospects has produced a range of ages from 283 to 334 Ma, suggesting that the systems are the product of multiple hydrothermal events.

Jan 1, 1990

By Bingwen Z, Fengyi K

The hydraulic-stowing mining method is most effective for mining thick coal seams. It is superior to the sliced cover- caving and artificial mining method and the fully mechanized sublevel-caving mining method for the following reasons - a much higher recovery rate is achieved, there is much less surface subsidence and roof pressure, there is no hidden danger of gob fire, and much less methane emission and coal dust problems, etc.. However, its superiority is overshadowed by its backward stowing technique which makes mechanisation of mining and stowing difficult, causes bleed water interference to production and to the environment and is uneconomic because of the high cost of stowing material. These disadvantages limited its application to coal seams that are difficult and not suitable to be mined by other mining methods. The remedy is in reforming it thoroughly to permit mining of otherwise unminable seams and this paper presents the reformation.

Jan 1, 1992