Search Documents

By Denise Cristina Oliveira Nascimento

Environmental considerations in addition to technical, economical and societal benefits are increasingly promoting the substitution of natural fibers for glass fiber in polymer matrix composites. However, natural fibers are heterogeneous in their dimensions, specially the cross section, which plays an important role in their mechanical strength. It has been found that the equivalent diameter of fibers such as sisal, ramie, pineapple and curaua correlates to different levels of tensile resistance. Piassava is a promising stiff natural fiber for composite reinforcement. In this work, a statistical analysis of tensile strength of piassava fibers using the Weibull methodology was performed. An attempt to correlate the fiber strength, obtained in tensile tests, with the diameter, precisely measured by means of a profile projector, was carried out. The results revealed an inverse dependence between the piassava fiber diameter and corresponding tensile strength. Fracture tip observation by SEM suggested a possible mechanism that could justify this inverse correlation.

Jan 1, 2010

By M. D. Strachan

Technical & Procurement Services Limited (TECHPRO) in Ashford, Kent, UK, have been appointed as Project Managers for the major rehabilitation of the Copper Smelting complex of Nkana Division, Zambia Consolidated Copper Mines Limited, (ZCCM) Zambia. In outline, the overall scope covers three main areas: a) Transfer and implementation of new technology into Zambia for the production of primary copper. b) Replacement of gas collection and gas treatment circuits to guarantee high quality feed to the acid plants. c) Completion of a number of minor projects in the copper smelter and associated utility plants to complement changes in the primary smelting technique. This paper describes the Project Management methodology and style used by TECHPRO to tackle typical problems that arise in retrofit projects of this type. Reference is made specific aspects of the smelter projects to illustrate solutions to the problems. The subjects. addressed highlight the complexities not only of having a -Client 5,000 miles from the Project Office, but also the difficulty of co-ordinating and controlling the performance of min sub-contractors who are also geographically distant.

Jan 1, 1991

By Sergio N. Monteiro

Polymeric composites reinforced with natural fibers are increasingly been used in several engineering applications, from automotive parts to building construction elements. In addition to the relatively low cost, the natural fibers are also appraised by their renewable and biodegradable characteristics. Fibers extracted from the crust of coconut fruits, also known as coir fibers have been investigated for a possible use in composite materials. In the present work, the coirfiber/polyester matrix interfacial strength was evaluated by means of pullout tests. The variation of the pullout tensile stress vs. the embedded coir fiber length permitted to determine the critical fiber length and, thus, to calculate the interfacial strength. Observations by SEM complemented the results from pullout tests, indicating that coir fibers have a potential for application aspolymeric composites that could replace conventional materials such as wooden and gypsumpanels.

Jan 1, 2006

By Huang Kai

By adding the solid oxalate acid powder into the solution of nickel chloride or its ammonia coordinated solution, the uniform compound particles were prepared and the precipitated particles were transferred to the mono-dispersed NiO particles by calcination. In this study, the various experimental conditions were investigated, the characteristics of the corresponding obtained particles were analyzed, and the formation mechanism of the particles was elucidated. It was found that the solid oxalate acid provided the solid-solution interface for the precipitation and induced the nucleation and growth of the product particles.

Jan 1, 2005

By Lifeng Zhang

The transport of fluid, heat ,and particles (bubbles and solid inclusions) in flowing molten steel is investigated in steel refining ladles, the continuous casting tundish, continuous casting mold and strand, and steel ingot casting processes. The two-equation k-?? model is used to simulate the turbulence. Multiphase fluid flow is numerically simulated with a Lagrangian-Eulerian approach, an Eularian-Eulerian approach and the Volume Of Fluid (VOF) method. The simulation can predict inclusion trajectories, inclusion removal fraction, free surface waves and other phenomena, which can be used to optimize these important metallurgical operations.

Jan 1, 2006

By Chen Song

Keywords: Co3O4, Cobalt Compounds, Morphology, Urea, Homogeneous Precipitation Depending on experimental condition, precipitation from cobalt nitrate and chloride solution in the presence of urea yield dispersed cobalt compounds with different chemical compositions and morphologies. The effects of concentration of cobalt solution and urea, agitation, on precipitation morphology were investigated experimentally. Generally in closed systems the particles are identified as cobalt (II) basic carbonate with needle type shape. In open system, spherical and plate-like precipitations of cobalt (II) basic cyanate are formed. The chemical formula of cobalt compounds was confirmed. They are CoII,III(OH)0.83(CO3)0.49 Ay?0.14 H2O (in tightly-capped reactor: A stands for NO3?, Cl?; y[A]molecular weight < 12.9) and CoII,III(OH)0.83(NCO)XAy?0.14 H2O. (in open reactor A stands for: NO3?, Cl?; 42 x + y[A]molecular weight < 44.82). The main reason was that the primary particles had different chemical compositions for the effects of the different kinds of anions and stoichio-chemical compositions of the primary particles. The effect degree of the anions depended on the co-existing anion radius in the reaction solution. According DTA-TG analysis of the cobalt compounds, the latter particles transform to Co3O4 powders on calcining. The shape of the Co3O4 particle with porous character has inheritance with precipitation. In this paper, it concludes that the particle formed by the principle of nucleation-aggregation in aqueous solution. The process of aggregation has played an important role in formation of particles. During calcination, the aggregation would be destroyed partly.

Jan 1, 2005

By F. A. Myzenkov

The technology developed by the authors uses new methods for raw material smelting in electric furnaces, a new autogenous method and apparatus for subliming smelting for antimony trioxide production and separation of antimony and gold. Concentrate produced from the ore deposits in Yakutia has the following average contents of main constituents, % by weight: 29.4 Sb, 1.2 Fe, 13.1 S, 40.0 SiO2, 0.2 As, 2.6 CaO and 45 g/t of Au. Unlike the technology used abroad a new autogenous method makes it possible to increase considerably specific capacity and reduce gold losses with antimony trioxide by several times. At the same time mineralogical composition of trioxide has improved considerably ? it has mainly a cubic base with prevalence of senarmontite. The content of a main component (Sb2O3) in the final product has increased from 99.0% up to 99.6% which means better quality and makes it suitable for use in special technologies. Despite a lower antimony content of the concentrate (29.4% as compared with over 33% as common in the world practice), an antimony recovery of 85.3% into a commercial-grade product has been achieved, as well as a gold recovery of 96.65% into a gold-antimony alloy. The technology for processing gold-antimony materials developed and introduced at the Ryaztsvetmet plant is unique in the world with respect to gold recoveries.

Jan 1, 2006

By Jeremy Gregory

The disposal of end-of-life electronics is an issue receiving increasing scrutiny. This paper evaluates several alternatives for recycling cathode ray tubes (CRTs) within monitors and televisions. The primary recycling options for the glass, reuse in new CRTs or as a smelter flux, are examined from economic and environmental standpoints. The economics are modeled using a cost model that includes dependencies on processing costs, transportation logistics, and incoming material composition. The environmental consequences are modeled using life cycle assessment methodologies to determine the energy embodied in each processing alternative. Results map out preferred processing alternatives across a range of technological and operational conditions. The results indicate that economic costs and environmental consequences are heavily impacted by transportation. The preferred destination of CRT glass for a recycler is highly dependent on the proximity of the consumer to the recycler, although it is generally economically advantageous for the recycler to extensively dismantle the CRTs.

Jan 1, 2006

By A. L. D. Skury

In the synthesis of diamond, the precursor graphite must present a degree of crystallinity to assure optimum yield and quality for the transformed crystals. X-ray diffraction, SEM and TEM analyses were carried out to investigate the structural and morphologic transformations produced in natural graphite by high pressure-high temperature treatment. The present study had as its objective to characterize the morphological and structural changes suffered by a natural graphite that was subjected to high pressure and high temperature treatments in the region of diamond thermodynamic stability. The results indicate that the material that constitutes the gasket, for the deformable capsule, could act as catalyst in the graphite recrystallization process.

Jan 1, 2006

By Sergio Neves Monteiro

The efficiency by which an applied load is transmitted through the composite structure depends on the strength of the interface between the matrix and the second phase. In fiber reinforced composites, the interfacial shear stress plays a major role in the composite capacity to support the applied load. This interfacial stress can be obtained by means of pullout tests using the fiber embedded to a certain length in a socket of the matrix material. In the present work, pullout tests were performed to evaluate the interfacial shear stress of ramie, a relatively strong natural fiber, reinforcing polyester matrix composites. The general result permitted to calculate a critical length for the ramie fiber embedded in polyester resin. From this critical length, the value of the interfacial shear stress was calculated. An interpretation of this result together with SEM observation displayed a relatively weak bond between the ramie fiber and the polyester matrix.

Jan 1, 2010

By Zhi-xiang Cui

Effects of flux, vulcanizing agent and reductant on slag cleaning in new-type slag cleaning furnace (Φ3.6 × 8.1 m) were investigated under the conditions including smelting temperature of 1200 and 1250 °C, settling time of 30 and 60 min, and Fe/SiO2 of 1.7–1.9. The results show that addition of SiO2, B2O3 or CaF2 into original copper smelting slag can improve settling separation effect. Though no effect on copper recovery, addition of FeS can provide heat required by reaction with oxygen and reduce copper dissolution in spinel phase and slag. Copper content in discarded slag can be controlled at 0.26% under the optimum comprehensive conditions with ratio of oxygen to natural gas of 1.6.

By Junfeng Shen

Geosynthetic clay liner (GCL) is a kind of waterproofing material used widely in engineering. The waterproof mechanism is understood in terms of bentonite particles becoming a water-obstructcolloid layer after they absorb water and swell. The swell stress, however, has not been determined directly till now. In our experiment, the swell stresses of the GCL under saturated and water absorbing conditions are measured directly using a custom-made instrument. The results show that (1) the instrument designed by the authors performed satisfactorily and the test results are reproducible; and, (2) The trend line of swell stress variation with time can be divided into three segments. The first segment is characterized by a quick increase of the swell force in the first 0?50 hours. The swell stress increases by 7.00×10-4?1.00×10-3 Mpa / hour. The second segment shows a slow increase of the swell stress during the 50?1730 hours. The swell force increases by 7.54×10-6?2.02×10-5Mpa / hour. The third segment is characterized by little variation in the swell stress after 1730 hours. In this segment, the average value of the swell stress measurements is 0.0719Mpa and the maximum value is 0.0729Mpa. It is suggested that the swell stress is mainly raised by water entering the pores among montmorillonite particles and the interstitial layers in individual montmorillonite crystals, leading to an increase in volume and manifested as a stress on the surrounding materials.

Jan 1, 2006

By Jiann-Yang Hwang

Microwave heating has been proved an effective method to rapidly heat iron oxide. This offers an opportunity to apply microwave heating in the steelmaking process. The reduction reaction of iron oxide is traditionally achieved at high temperature with reducing gases such as H2 and CO generated from various sources, including coke, coal, and natural gas. This study investigates the differences in iron oxide reduction using conventional and microwave heating under H2 and CO atmospheres. A special microwave thermal gravimetric device was designed and built to facilitate the investigation. With this device, iron oxides can be heated by electric resistance heating, microwave heating, or a combination of methods. The incoming CO and/or H2 also can be preheated to simulate a potential utilization of recovered heat. The iron oxide weight and temperature can be monitored during an entire reduction period. A series of reduction experiments have been conducted. The results are presented and discussed.

Jan 1, 2006

By Timo Kankaanpää

Keywords: Solvent extraction, dispersion, phase separation, CFD The liquid-liquid dispersion phases are separated by gravity in a solvent extraction settler. This separation step is made more effective by picket fences. The picket fence geometry and its physical placement have a significant effect on the separation process, because the purpose of a fence is to smoothen and control organic-aqueous dispersion flow in the first part of the settler and achieve a deep and dense dispersion layer in the front end of the settler resulting in a clean phase separation. In this study, physical phenomena in the solvent extraction process and phase separation in a solvent extraction settler with and without picket fences have been examined using a commercial CFX software package. It can be concluded that the used CFD-approach proved to be a complementary tool for optimizing and designing the solvent extraction settler.

Jan 1, 2005

By Qingwei Wang

Heavy metal-containing wastewater from hydrometallurgical processes of lead-zinc was treated by biologics in a 200 m3/h industrial scale experiment. The result shows that Zn concentration declined from 50.28 mg/L~240.81 mg/L to 0.21 mg/L~1.98 mg/L, Pb from 1.00 mg/L~13.47 mg/L to 0.083 mg/L~0.71 mg/L, Cu from 0.24 mg/L~2.38 mg/L to 0.059 mg/L~0.40 mg/L, Cd from 2.12 mg/L~23.47 mg/L to 0.011 mg/L~0.071 mg/L and As from 0.50 mg/L~6.00 mg/L to 0.005 mg/L~0.10 mg/L. The concentrations of the above heavy metals in the treated water were lower than that in Integrated Wastewater Discharge Standard (GB8978~1996) in China. Furthermore, the treated wastewater was recycled and reused in smelter plant. Zinc content in hydrolytic sludge reached up to 34.04%, which indicates that this sludge can be used to recover valuable metals.

Jan 1, 2010

By A. J. Sideris

It is known that Mg can act as a catalyst/solvent in the high pressure high temperature diamond synthesis. However, above pressure levels of the order of 7 GPa, and temperatures from 1700 ? 1800oC, it was not possible yet to use Mg for the industrial production of diamond. A possible alternative is the use of MgNi based alloys. However, owing to the great Mg reactivity, it was consider, so far, a difficult task to deal with such alloys. The present work presents successful results regarding the production of MgNi alloys, with different composition, at high pressure conditions. The behavior of the alloys and their microstructural characterization is analyzed.

Jan 1, 2006

The effect of rare earth element Y (0-2.0at.%) on the microstructure of TiAl alloys at the as cast and rapidly solidified conditions has been investigated. The results show that the addition of Y greatly refined the microstructure of TiAl alloys at both conditions. The refinement is more significantly with higher Y content. The refinement of Y in the cast alloys is attributed to that the strip-shaped Y-rich phase locating on the grain boundaries impedes the grain growth during solidification. In the rapidly solidified alloys, Y-rich phase dispersing uniformly as spherical particles in the matrix acts as heterogeneous nucleation sites which increases the nucleation rate of ??phase during the ????phase transformation, and produces a refined initial microstructure during solidification. Higher cooling rate restricts the grain growth during subsequent cooling.

Jan 1, 2010

By Tian Sugui

By direct aging treated, creep properties measurement and microstructure observation, the influences of the direct aging treatment on the creep behaviors of Hot Continuous Rolled GH4169 superalloy are investigated. Results show that the creep resistance of Hot Continuous Rolled GH4169 superalloy may be obviously improved by directly aged treatment. Under the applied stress of 700MPa at 660, the creep lifetime of the alloy is enhanced to 126h from 60h. During hot continuous rolling, the deformation features of the alloy are the twinning and the double orientations slipping of the dislocation activated within the twinning regions. After direct aging treated, the alloy displays a smaller grain size, and the finer g² phase is dispersedly precipitated in the matrix of the alloy, which is thought to be a main reason of enhancing creep lifetime of the alloy.

Jan 1, 2010

By Jana Dobrovska

The paper deals with new approach for measurement and evaluation of chemical microheterogeneity of elements in polycomponent metallic systems (i. e. steels, Ni-alloys). The method is based on the original mathematical model for determination of distribution curves of dendritic segregation of selected elements and on the original mathematical model for determination of the effective partition coefficients of these elements in the structure of analyzed alloy. Application of the method at research of chemical heterogeneity of continuously cast steel slab is also presented. The original results of measurement of dendritic microheterogeneity of eight elements (Al, Si, P, S, Ti, Cr, Mn and Fe) in structure of nine zones of a transversal section of slab are given.

Jan 1, 2006

By Ludovic Charpentier

Production of metallic wires directly from liquid jets would avoid drawbacks of extrusion (space needed, damaging, cost?) and enable recycling. But liquid jets tend to break, due to capillary instabilities, unless a solid layer (coating or start of solidification) surrounds it. We recently developed a process to produce tin wires, cooled by water flow parallel to the jet. Superficial oxidization of tin produces a glass coating around the jet. Studies showed the length of wires increased when increasing speed of tin jets, and that water average speed should be the closest possible to the jet one to have smooth fibers. Producing 1 mm diameter wires is possible. The length of wires is limited by the experimental setup, which does not provide possibilities to coil the wire. Most of other metals do not generate glass-like oxides. The lack of coatings makes it necessary to reduce the capillary instabilities to obtain fibers.

Jan 1, 2006