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By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

RECOMMENDATIONS FOR FURTHER WORK Based on the development effort and full-scale tests conducted during this program, a number of technical areas for future research and development have been identified. Further work in these areas would help to improve the reliability, speed of operation and efficiency of the remote sealing system. Recommendations for future work are summarized as follows 1. Development of an Inert Gas Generator For the sake of expediency in conducting the field test program, fresh air was used as the fluidizing medium for the fly ash. However, in an actual mine fire application the use of fresh air is likely to be prohibited. An inert gas, such as nitrogen, carbon dioxide or air containing less than 8 percent oxygen would be required. Using combustion as a means of reducing the oxygen content of air appears to be an attractive solution to the generation of the high flow rates of gas required (2500 to 5000 scfm). Such an inert gas generator would serve a dual purpose for the overall fire extinguishing operation. First, it would provide the inert gas for fluidizing the fly ash. Second, it could be used for inerting the fire area after the seals had been placed, thereby reducing the time required to extinguish the fire. It is recommended that the Bureau undertake a program to develop a field-operable, inert gas generator to satisfy these two requirements. 2. Development of a Field-Operable Sonar Initial Probing System A first stage prototype of a sonar initial probing system was developed during this present program. The results obtained with

Jan 1, 1973

By W. J. Pena, C. W. Owings

"Generally, the hazard of cool-dust explosions in tipples and cleaning plants is not given the consideration that is given it underground. This lack of consideration is probably due to failure to appreciate the potential hazard. An explosion in a tipple or cleaning plant is basically little or no different from an explosion underground. If bituminous-coal dust is raised into a cloud in the air and comes in contact with arcs from motor brushes, switches, or open flame, the dust is very likely to ignite, and flame will very probably propagate or extend through it if the quantity of dust per unit of air space is sufficient. The open space in a tipple or cleaning plant may reduce the violence of the explosion, but it is not likely to prevent ignition or propagation of flame.The movement of coal through a tipple or cleaning plant naturally puts into suspension a large amount of dust, which finally settles on exposed surfaces. Any disturbance that will put this dust into suspension in a sense enough cloud can result in the dust being ignited by an arc or open flame if one should be present. An explosion of bituminous-coal dust in a tipple or cleaning plant generally can be prevented either by keeping it thoroughly clean or by removing all sources of ignition, or both.The tests at the U.S. Bureau of Mines Experimental mine have shown that the explosibility of coal dust is proportional (other things being equal) to the ratio of the volatile matter to the volatile matter plus the fixed carbon, indicated thus:The volatile ratio for the Pittsburgh coal bed is calculated as follows:Therefore, as the volatile matter decreases the liklihood of ignition decreases; however, coal-dust explosibility depends on other factors also, such as fineness, dryness, and cloud density; and under some conditions other factors also intervene.Proof of the explosibility of coal dust in the absence of explosive gas has been shown in numerous cases in mines and mine plants and also by a series of tests. In these tests a dense cloud of dust is blown onto an open flame or an electric arc, almost invariably with resultant exploding of the dust. The Safety Division of the United States Bureau of Mines has made a number of demonstrations of the explosibility of Pittsburgh coal-bed dust, using a small gallery or box in which a cloud of coal dust is blown onto a lighted match; larger-scale tests have been made with an electric arc as the igniting agent. Bituminous-coal dust is readily ignited with a medium arc, but with low-volatile coals a larger arc is required. For test purposes, a 100-ampere arc has been used. Ignition has occurred readily under these conditions with Pocahontas No. 5 coal dust with ratios of volatile to total combustible of 0.232 to 0.253, and with Pocahontas No. 3 coal dust with a combustible ratio of 0.242. Lower Kittanning coal dust, with a ratio of 0.187, did not give definite ignitions, and Pocahontas No. 4 dust did not explode, although part of the coal-dust cloud ignited. It is probable that even the low-volatile coal dust will be found to be explosive with a higher-amperage electric arc as the initiating agent."

Jul 1, 1936

By RUDULF KUDLICH

Pennsylvania anthracite coal is almost universally recognized to be the solid fuel best suited for domestic use when cleanliness , convenience and cost are considered . At various times and in various localities , however, conditions so affect the supply that it becomes insufficient or is too high in price and recourse must be had to other fuels as substitutes . In practically every district in the United States where anthracite has been the common domestic fuel , some other fuel is available as a substitute . In even the most severe climates such fuels are used either as emergency substitutes for anthracite , or as the ordinary domestic fuel . There may be some drawback to the use of such fuel , such as the need of more frequent attention to the furnace , smoke , soot and dust , in the case of solid fuels lower in price than anthracite , but these inconveniences must be accepted as necessary accompaniments to a decreased fuel bill . The cleanliness and ease of handling anthracite in the house must be considered in the light of a luxury and a higher cost of heating with this fuel must be expected . That a growing number of people are willing to pay for such added convenience is evident from the increasing mumber of heating installations using oil , gas and electricity , all of which are more convenient and usually more expensive even than anthracite .

Aug 1, 1923

By Edward F. Divers

A new nonclogging water spray system for continuous-mining machines has been developed under contract with the Bureau of Mines. This paper presents installation and operating guidelines for the system, which consists of improved and easily maintained machine-mounted hardware, including an inline Y-strainer, a hydrocyclone, a backup filter, and two quick-opening valves for flushing particulates from the strainer and hydrocyclone. Underground tests with continuous-mining machines have shown that when properly installed and maintained, the new sys tern virtually eliminates nozzle clogging and thus greatly reduces spray maintenance. The sys tern is relatively inexpensive and has been installed on typical continuous-mining machines for a total cost under $1,000.

Jan 1, 1976

Pillars with width-to-height ratios of less than 1.0 are frequently created in underground hard rock mines. The strength of slender pillars can be estimated using empirically developed equations. However, the equations can provide variable results when the width-to-height ratios approach 0.5. This paper investigates some of the issues affecting pillar strength at low width-to-height ratios in hard brittle rock. The investigation includes an evaluation of empirical pillar strength data presented in the literature and observations of pillar performance in underground limestone mines in the eastern United States, supplemented by numerical modeling in which failure processes and sensitivity of slender pillars to variations in rock mass properties are evaluated. The results showed that the strength of slender pillars is more variable than that of wider pillars. The numerical model results demonstrated the increasing role of brittle rock failure in slender pillar strength. The absence of confinement in slender pillars can result in a fully brittle failure process, while wider pillars, fail in a combined brittle and shearing mode. The onset of spalling in slender pillars occurs at or near the ultimate strength, while this is not the case for wider pillars. Slender pillars are shown to be more sensitive to the presence of discontinuities than wider pillars, which can partly explain the increased variability of slender pillar strength. Two examples are presented that illustrate failure initiation by brittle spalling and the sensitivity of slender pillars to the presence of discontinuities.

By J. D. Davis

Coke Since the beginning of manufacturing of metallurgical coke in the United States, which dates from about 1859, Pennsylvania has main tamed supremacy in coke production Available statistics for the year 1880 show an output of 3,338,300 short tons, which was neatly trebled by the end of the succeeding 10 years. From this time on the increase was steady, though not rapid, and in 1922 the total production was 13,991,892 tons, which is approximately 37 per cent of the total coke production of the United States. The main reason for the rapid development of the coke industry in Pennsylvania lies in the abundance of coals particularly adapted to beehive coking, for which purpose the Pittsburgh bed in the Connellsville district has long been looked upon as standard At first practically all metallurgical coke was made in beehive ovens, the only exception being the short lived and wasteful method of coking in piles, byproduct owns did not make then appearance until after 1893 The suitability of a beehive coking coal cannot be accurately predicted from its chemical analysis, but it can be said, perhaps, that the volatile matter should be about 32 per cent, and that the oxygen content should not be mole than 10 pet cent or less than 4 per cent The sulphur and phosphorus content should be small-not over 1 25 per cent sulphur and under 0 02 pen cent phosphorus-and the ash content should not be over 7 per cent The Pittsburgh bed at Connellsvnlle fills these requirements well, as may be seen from the following representative analysis. Analysts of coal from Pittsburgh bed Moisture 1 70 Volatile matter 31 10 Fixed carbon 59 80 Ash 7 40 Sulphur 0 85 B t u 13,990

Jan 1, 1928

By C. H. Gorski

Evaluation of raw materials for mineral wool is one phase of the Bureau of Mines broad program for the more effective utilization: of our mineral resources. The experimental work and test-evaluation results on several raw materials as useful components for the production of mineral wool are presented in this report. Samples from all sections of the United States, including copper slag from Tacoma, Wash., pebble phosphate slime from Florida, and granites from Massachusetts and Minnesota, have been blown into mineral wool successfully in the laboratory tests. Maximum conservation of the Nation's mineral and manpower resources requires maximum utility of those resources. Al though the domestic reserves of oil, gas, and coal are tremendous, judicious use of these fuels through the use of proper insulation will insure the highest thermal efficiency. The effectiveness of mineral wool as a heat-insulating material has assumed an increasingly important role in the national economy, and it has become a fuel saver in countless applications. The most immediate concern to many is the use of mineral wool in the home, which promotes uniform temperature and minimizes drafts by reducing heat transfer through the walls, ceiling, and floors. There are, however, many industrial and commercial uses that require large volumes of mineral wool each year.

Jan 1, 1951

By M. J. Friedel, D. F. Scott, T. J. Williams

In an effort aimed at monitoring mining-induced stress changes that may influence ground failure, the US Bureau of Mines conducted a series of active 3-D seismic tomographic surveys at the Homestake (Lead, South Dakota) and Lucky Friday (Mullan, Idaho) mines. Existing rock bolts were used to mount geophones and as strike points for introducing seismic energy using a 3.6 kg sledge hammer. Travel time measurements were recorded spanning up to 160 m between drifts at several levels. The tomographic uncertainty was minimized by computing iso-velocity surfaces of constant probability based on statistics from multiple reconstructions and a threshold criteria. Periodic imaging using tomographic velocity surfaces demonstrated that temporal and spatial changes in the local stress field occurred in response to ground failure and stope advancement at a gold and silver mine, respectively. Keywords: Temporal imaging; Mine-induced stress; Seismic tomography; Geophysics

Sep 9, 1996

By R. L. Hopkins

The work described was performed to determine whether sulfur compounds of the thienothiophene class occur in crude oil. The presence or absence of various classes of sulfur compounds in crude oils is of interest and value to petroleum science. The Bureau of Mines, for the first time, identified hydro-carbon products of desulfurization that point directly to the identity of two individual thienothiophenes, namely 3-methylthieno[2,3-b]thiophene and 2-meth-ylthieno[3,2-b]thiophene, in Wasson, Texas, crude oil. These identifications, described in detail, were accomplished using microdesulfurization, mass spectrometry, and gas-liquid chromatography.

Jan 1, 1966

By H. L. Riley, B. W. Gandrud

"INTRODUCTION AND SUMMARYIn connection with a program of research work on coal at its Southern Experiment Station, the Bureau of Mines, in cooperation with the University of Alabama, conducts washability studies of samples of coal from coal fields in Alabama and other Southern States in which commercially important deposits of coal occur. The first such study on coal from a bed in the Arkansas field has been completed, and the results are presented in this report.One of the main objectives of a washability study is to obtain technically and commercially important data in connection with the best methods for preparing and utilizing the Nation's limited reserves of good coking coal. Such information is important from the standpoint of conservation in that it facilitates selection of preparation methods that will yield a good grade of coking coal with a minimum of losses of coal in the rejects.The coal on which this report is based was obtained by underground and tipple sampling at the quality mine of the Quality Excelsior Coal Co. about 3 miles east of Hackett, Ark. This mine operates in the Upper Hartshorne bed, which, as the main source of coal in what is known as the Hackett-Excelsior district, yields an excellent grade of low-volatile coking coal, which is marketed at steel plants in Colorado and California. Production from this bed by the major producers in the Hackett Excelsior district was at the rate of about 125,760 tons annually in 1949, according to the Keystone Coal Buyers Manual. 2/In the laboratory, the tipple sample was crushed to 6-inch top size and screened on a 2-inch round-hole screen. The 2-inch to 0 undersize, amounting to 71.4 percent of the total sample, was fractionated into a series of screen sizes and float-and-sink products to get data for determining the washability characteristics of the coal. Before the screening and float-and-sink tests were made, however, machine cuttings, which are now gobbed underground, were added to the 2-inch to 0 sample. Enough of these cuttings were added so that the resulting mixture was considered representative of what the 2-inch to 0 run-of-mine coal would be if all machine cuttings, including the part now being gobbed, were brought to the tipple as a part of the run-of-mine coal.The mixture obtained referred to in this report as the run-of-mine or raw coal."

Mar 1, 1953

By Maria I. De Rosa

Table 37 and figure 13 show the number of fires and fire injuries for surface stone mines by state during 1990-2001. Table 37 also shows the injury risk rates, employees' working hours, and lost workdays. In all, 96 fires occurred in 31 states and 1 fire occurred in Puerto Rico. Sixty-eight of the fires caused 67 injuries and 1 fatality (including 6 fires and 5 injuries involving contractors). The yearly average was eight fires and 5.6 injuries. The Ewhr value was 689 x 106 hr (Irr = 0.02), and the LWD value was 7,399. Indiana had the most fires (eight fires and four injuries), followed by Georgia (seven fires and seven injuries) and Pennsylvania (seven fires and five injuries). Of these states, Georgia had the highest injury risk rate value (Irr = 0.058). Table 38, partly illustrated in figure 14, shows the number of fires, fire injuries, fire fatalities, risk rates, employees' working hours, and lost workdays by time period. The number of fires and fire injuries show an increase during the second period followed by a decrease during most of the remaining periods. Employees' working hours increased during most of the periods. The In values follow patterns similar to those shown by the injury values. Tables 39-44 show the number of fires by ignition source, method of detection and suppression, equipment involved, location, and burning material by time period. Figure 15 shows the major variables related to fires for 1990-2001. Table 45 shows the number of fire injuries per number of fires causing injuries and total fires by year, ignition source, equipment involved, and location.

Jan 1, 2004

By Jr. Schnakenberg

The National Institute for Occupational Safety and Health (NIOSH) has been working with diesel emissions control technology and the underground mining industry for a number of years. Underground isolated zone studies provided the emissions reduction performance of all of the alternative technologies currently available. A NIOSH/MSHA guide is available which provides mines with information and a process for selecting diesel particulate filters (DPF). Recent NIOSH experience suggests that more attention may be needed in managing the issues associated with diesel emissions and their control. The author argues that a holistic approach is needed which involves several key mine operations departments or disciplines by positing that workplace air can be considered as the product of a complex manufacturing process and examining how that process could be managed.

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

4. Guidelines for Implementing the Emergency Escapeway Standards for Metal and Nonmetal Mines The technical discussion of each escapeway component precedes the specific guidelines for the component. Generally, the technical discussion provides the background and reasoning behind the guidelines. Section 5 is a discussion of general escapeway requirements, including the escape route, fire retardants, warning systems, ventilation systems, escapeway signs and signals, auxiliary transportation and fuel storage. The discussion is followed by a list of guidelines pertaining to the escapeways. Section 6 is a summary of the computer simulation of an escapeway system for Mine "C". A complete documentation of the simulation is included in Appendix A and B. Section 7 covers emergency hoisting requirements and concludes with the guideline, for emergency hoists, their inspection and use. Section 8 is a discussion of refuge chambers and life support and is concluded with guidelines for the application o f this equipment.

Jan 1, 1976

By Donald A. Wilson

As part of a continuing effort to maximize metal recovery from domestic secondary resources, the Bureau of Mines investigated a process for recovering the metallic portion of scrap alkaline batteries. A pyrometallurgical method for recovering nickel and cadmium from Ni-Cd scrap batteries previously developed on a laboratory scale, was scaled up to 25-and 43-pound charges. The method employed reduction and/or decomposition in a retort using a minimum of 2.5 percent carbon as a reductant. Metallic cadmium was distilled at atmospheric pressure and a minimum of 900° C. Purity of the recovered cadmium was 99.8 percent minimum and the nickel-iron residue contained less than 0.02 percent cadmium.

Jan 1, 1981

By W. K. Tolley

This report presents data collected during research by the Bureau of Mines on corrosion of grinding media. Corrosion rates of eight alloys commonly used in grinding media were tested in synthetic mill water using an ultrasonic grinding device especially designed for this work. Electro-chemical measurements showed variations in corrosion rates for these alloys between 9.8 mpy for medium-carbon steels and 0.14 mpy for high chromium white irons. Bureau data are discussed along with data from the literature to indicate that corrosion causes less than 10 pct of the wear of grinding media in commercial grinding mills. A comparison of corrosion rates for various types of grinding media shows that alloying elements and electrochemically active inclusions in steel affect the corrosion behavior of the media.

Jan 1, 1984

By K. D. Plants, J. H. Holden, L. F. Willmott

Pulverized high- volatile A bituminous coal was gasified with oxygen and superheated steam in a pressure - gasification pilot plant equipped for steampickup feeding . The pilot plant operated satisfactorily at relatively high steam- to - coal ratios , but steam- to - coal ratios could not be reduced much below 0.5 lb / lb without condensation of steam or softening of the coal . Carbon gasified , gas composition , and coal and oxygen requirements were essentially the same as for a pilot plant equipped with a fluidized coal feeder . Average results from the pilot plant equipped for steam- pickup feeding were coal requirement , 37.3 lb/M ( 1,000 ) scf of CO + H₂ produced ; oxygen requirement , 358 scf /M scf CO + H₂ produced ; and carbon gasified , 87.7 percent .

Jan 1, 1964

It is suggested in chapter 1 that emergency activities (including escape) are not individualistic. They tend to be group responses. If escapes from mine fires are group activities, then preparation for such events must take group behavior into account. This chapter explores the hypothesis that the miners who escaped from the three mines under study did so as members of groups. For development of this chapter, the database was examined for evidence of the existence of escape groups and for instances when individualistic behavior was paramount. Illustrations of group and/or individualistic behavior were analyzed and representative examples are provided in the following discussion. The nature of groups was discussed in chapter 3 and the following working definition was offered: "We mean by a group a number of persons who communicate with one another often over a span of time, and who are few enough so that each person is able to communicate with all the others, not at second-hand, through other people, but face-to-face" [Homans 1950]. To determine whether or not groups existed during the fire evacuations, it is important that the concept of group be clearly defined. Therefore, the discussion started in chapter 3 will be elaborated here. The defining characteristics of group given in chapter 3 were taken from Homans [1950]. They include size, person-to-person com¬munication, feelings that members have for each other, explicit and implicit rules for behavior, and common activities. An additional characteristic that is sometimes used to define groups is cohesiveness. Kiesler and Kiesler [1970] state, "Cohesiveness would include not only the attraction that the group holds for its members but also any other force operating on the individual to stay in the group." Variables said to contribute to cohesiveness include "(1) the attractiveness of a group for its members," and "(2) the coordination of the efforts of the members" [Keisler 1970]. One source of the attraction to a group occurs when "the goals or exterior tasks confronting the group are consistent with those of the individual person, and can best be handled by group action" [Cartwright and Zander 1968, in Davis 1969]. In other words, a common goal and a coordinated effort mounted to achieve that goal contributes toward the creation of a cohesive group. As discussed in the earlier review of research (chapter 1), groups have frequently been studied in laboratory or simulation settings. These methods allowed control over variables of interest. Kiesler and Kiesler [1970] state, however, that they "find group variables conceptually imprecise and experimentally difficult to work with." Experimental control, in other words, is difficult to achieve in the study of groups. The richness of the naturalistic mine fire data may provide an opportunity for an examination of groups that cannot be found in laboratories or simulations because this environment was not

Jan 1, 2000

By Donald P. Blasko

The Bureau of Mines investigated two areas of the Alaska Peninsula (Iniskin Peninsula and Becharof Lake) where oil and gas seeps were known to occur in an attempt to determine (1) whether the seeps are still active and (2) the amount of bitumen contained in the drainage leaving the seeps. The oil, water, oil-water, and gas were sampled and analyzed. Five oil samples were taken at four separate oil seeps. The API gravity of the oil ranged from 8.90 to 21.4° and the sulfur content was from 0.12 percent to 0.59 percent. Four of the seven gas samples obtained revealed fair high caloric values, ranging from 746 to 924 Btu/cu ft, and averaging 844 Btu/cu ft. A total of 44 water samples were obtained. Bitumen content of the water was as high as 9,773 mg/l at one seep, but averaged less than I mg/l where the seep-drainage water entered the Gulf of Alaska.

Jan 1, 1976

By Maria I. De Rosa

The U.S. Bureau of Mines performed experiments to determine if the primary gas toxicities evolved during the early (-300° C) and later (>400° C) combustion stages of mine conveyor belts could be predicted by a smoke particle characteristic. The experiments were conducted in an approximately 20-L furnace at set furnace temperatures of 150°, 250°, and 1,000° C, with a furnace airflow of 10 L/min. The variables studied, as a function of time, included hydrogen chloride and carbon monoxide concentrations, the average smoke particle diameter (d8 and number concentration (no), and the product of the average smoke particle diameter and concentration (dgn0) Other variables included the sample and furnace temperatures and the sample mass weight loss. Results show that the inverse of the smoke particle diameter-concentration product (ldgn0), correlates directly with the hydrogen chloride and carbon monoxide toxicities released in large quantities during the early and later stages of combustion.

Jan 1, 1989

By H. M. Lawrence

The recovery of phosphate rack from the ores in the land-pebble district of Florida is a simple washing and screening operation. In the gashing plants coarse phosphate only is saved. Log-Washer overflows and screen-undersize products containing an appreciable content of fine phosphate are discarded. The phosphate grains in the material discharged to waste are generally finer in size than the mesh--14 to 20 mesh or 0.346 to 0.03 inch--of the finest screen in the washer. The operators state that the washers ordinarily recover from 50 to 60 per cent of the phosphate content of the matrix mined. Any increase that can be effected in the recovery of phosphate would be of advantage to the industry and would conserve the mineral resources of the country. In considering possible methods that might increase the recovery obtained in phosphate-washing plants the application of flotation, if it could be successfully developed, seemed to warrant investigation.

Jan 1, 1928