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By J. A. Finch, Zhenghe Xu

The competitive adsorption of xanthates on sulphide minerals in a binary mineral system (pentlandite and pyrrhotite) was studied using the pseudo-in-situ technique of attenuated total-reflectance FTIR spectroscopy. The minerals were placed in the same collector solutions, either separated by a glass wall or in direct contact with each other before magnetic separation and separate analysis. The effect of mineral interaction on xanthate adsorption was clearly demonstrated spectroscopically for the first time. At low concentrations of xanthate, its adsorption on pentlandite was activated by physical contact with pyrrhotite; the effect may be attributed to the enhancement of electron transfer through electrical contact between the two minerals. The results emphasise the need for caution in extrapolating results obtained from single-mineral studies to flotation practice

Jun 18, 1905

By M. J. Howes

The high degree of mechanisation, which is mainly diesel-powered, has a significant effect on heat loads; heat output from this source often exceeds the heat flow from the surrounding rock. The extensive use of diesel-powered equipment also influences ventilation rates and minimum values are necessary to ensure that emissions of diesel exhaust are adequately diluted. Many Australian mines are in subtropical or tropical areas with high ambient wet- and dry-bulb temperatures on surface. This, coupled with the large amount of heat from mechanisation, usually means that refrigeration is required at much shallower depths. A secondary problem is associated with the definition of acceptable thermal environment conditions, which are sometimes based on the assumption of no air movement. This gives rise to very stringent thermal environment acceptance criteria, which, in some areas, would prohibit work on surface, let alone underground

Jun 12, 1905

By R. K. Dunham, D. J. Reddish, X. L. Yao

Paper presented at the conference: Risk assessment in the extractive industries, held in Exeter, UK, 23-24 March 1994, and first published London: IMM, 1994, preprint volume, 10pp., 10 refs. The integrated approach combines a powerful ground movement prediction program with a knowledge-based expert system. ESDAS (Expert Structural Damage Assessment System) was developed to evaluate mining subsidence damage in the form of risk and in terms of the three vital contributing components (mining factors, site factors and structural factors). Using a certainty factor risk assessment technique, the system can be used to predict the likely damage to a particular structure subjected to mining subsidence. A previously developed powerful ground movement prediction program, SWIFT (Subsidence With Influence Function Techniques), has been combined with the expert system to allow the mining factor to be more accurately determined in a broader range of mining layout. Since SWIFT can be calibrated to any particular coal field using local subsidence data, it is believed that the integrated system could be used in any coal field worldwide for the assessment and control of mining subsidence damage risks

Dec 1, 1995

By M. Feely, W. G. O'Keefe, C. O'Reilly, M. P. Holdstock

A petrographic and microthermometric study of fluid inclusions in the Kentstown Granite, crosscutting quartz (VI) and calcite+quartz (V 2) veins in the granite and calcite+quartz (V 2) veins in the overlying sediments was performed on samples taken from the borehole. Comparisons of the type 1, type 2 and type 3 fluid inclusion populations recorded in the present study with those from other Irish Caledonian granites strongly suggest a similar fluid evolutionary history. Furthermore, the low-temperature CaC12-rich brines (type 5) of this study, which must be syn- to post-Lower Carboniferous in age, have correlatives both in Irish Caledonian granites and in the Lower Carboniferous base-metal deposits of the Irish midlands

Jun 19, 1905

By R. A. Ixer, R. A. Lord, H. M. Prichard, A. J. Boyce, P. McConville, C. T. Pillinger, I. P. Wright, J. Maynard

Analysis of 62 samples show that the sulphides throughout the igneous stratigraphy have a magmatic signature, with the exception of the uppermost gabbros and the lowermost basal thrust talc-carbonate lithologies. Mean delta-34S values for whole-rock samples from harzburgites, dunite pods in harzburgite, crustal dunites and wehrlites, the main and high-level pyroxenites and gabbros suggest that the primary sulphides derived their sulphur from a magmatic source enriched in 34S. This finding is compatible with the proposed origin of the ophiolite above a subduction zone. Values for pyrite mineralisation in the uppermost part of the gabbros are thought to result from precipitation from a seawater-derived fluid, while isotopically light sulphur in the basal thrust could have been introduced from underlying metasediments. The replacement of pentlandite by heazlewoodite has not led to sulphur fractionation

Jun 19, 1905

By A. M. Tunstall, N. Djordjevic, H. A. Villalobos

The damage zone behind a typical smooth-wall blast in the open pit was assessed by visually examining diamond drill core to identify blast-induced cracking, mapping core rock quality designations to identify changes in fracture frequency and conducting uphole seismic testing to determine changes in rock mass characteristics. The results from the three techniques show reasonable correlation. They suggest that major damage, in the form of fracturing of intact rock, occurs at least 7 m behind the smooth-wall blast and significant damage, in the form of opening and extension of calcite-filled fractures, at least 12 m from the blast. At greater distances the dominant damage mechanism is the loosening of existent joints within the rock mass. In the trachytes at El Soldado these damage mechanisms correspond to peak particle velocities of 2 000, 900 and 500 mm/s respectively

Jun 19, 1905

By R Lastra, J. A. Finch

An artificial standard material has been developed and used to examine the robustness of some of the procedures for correcting stereological bias. Different mineral liberation distributions were constructed from the standard material. The particles were mounted, sectioned and the sectioning data measured with an electron microscope interfaced to an image analyser. Four correction procedures were used and the corrected and true liberation distributions compared. It was found that the large-sections correction provided a simple, uncorrupted correction. Hill's fast approximation performed well except in cases of narrow liberation distributions; the sectioning data appeared to support the assumption that the locked section and locked particle distributions are identical. Barbery's correction performed well in most cases, having difficulty only with the very irregular liberation distribution. The PARGEN correction was able to provide a good estimate of the true amount of free material, but had difficulty in predicting the locked particle distribution

Jun 21, 1905

By J. Hurdley, J. A. Plant, H. Robotham, P. R. Simpson, G. C. Lalor

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). The results of orientation studies for a regional geochemical survey of Jamaica and the CARICOM countries of the Caribbean region are described. The survey is designed to provide systematic geochemical information for a wide variety of applications and, especially, to form a basis for agricultural development in the region

Jul 1, 1991

By Boorder De, B. S. Panov, A. B. Westerhof, V. A. Korcemagin

Paper presented at the conference on Economic geology in Europe and beyond II, models for <mineral deposits> in sedimentary <basins>, held in Keyworth, UK, 13-14 April 1994. The Hg and Sb deposits of the Mediterranean and Circum-Pacific Belts are often found at elevated structural levels, suggesting that their preferential occurrence in young orogenic belts is not a fundamental metallogenic feature but merely reflects their chances of surviving post-orogenic peneplanation. In western Europe their emplacement appears often to be related to late orogenic extensional events accompanied by a notable increase in heat flow. Although Nikitovka and Almaden have quite different settings, both appear to be related to deep-reaching shears. Together with brittle fault zones at higher levels, these provided pathways for fluid phases that originated at least partially within the mantle. The Nikitovka deposits are located in the Donets segment of the 2 000 km Pripyat-Dniepr-Donets palaeorift in the East European Platform. Initiated in the mid-Devonian with a possible Precambrian precursor, its listric boundary faults displace the Moho from a depth of about 50 km north and south of the rift to 35 km along the axes of the Pripyat and Dniepr segments. The steep central anticline of the Donets segment, within which the main Hg-Sb district is located, is interpreted to be associated with a reactivated fault reaching into the upper mantle. The Almaden syncline, formed during the Variscan Orogeny, may be an older pull-apart basin or half-graben associated with the collapse of the Cadomian Orogenic Belt. It is situated on a major ENE-WSW-striking shear zone which may represent a Late Cadomian transfer zone reaching into the mantle

Apr 1, 1995

By A. M. R. Neiva

The WNW-ESE-trending hydrothermal veins cut alternating mica schists and quartzites of mainly Ordovician age and, to the west, a Hercynian muscovite-biotite granite. They have been prospected and developed to a depth of 300 m and reserves of 20 t Au estimated. The paragenetic sequence and chemical compositions of the ore minerals are generally similar to those at Jales to the south. Gold, electrum and aurian silver form inclusions in arsenopyrite, pyrite, galena, sphalerite, pyrrhotite and quartz and also occur in veinlets that cut these minerals. Silver has been found in gold, electrum, aurian silver, tetrahedrite, freibergite and the Ag-Pb-Sb sulphide owyheeite. Early arsenopyrite crystallised at an estimated 480 degrees C and the more common, later arsenopyrite in which Au and Ag are generally included at 430-300 degrees C. Sphalerite crystallised at 307-100 degrees C. Monoclinic pyrrhotite may have been formed by the inversion of hexagonal pyrrhotite at 248 degrees C

Jun 16, 1905

By P. E. J. Pitfield, S. D. G. Campbell

The regional shear zone runs along or near the southern margin of the Chinhoyi greenstone belt. It hosts four of the seven mines in the southern part of the belt with recorded production above 100 kg Au, including the top two current producers. Displacement occurred in the late Archaean, producing a shear zone with a trend ranging from northeast at Golden Kopje to east at Muriel. The orebodies at the two mines formed synchronously with the shearing and show strong but contrasting structural controls on mineralisation. The Golden Kopje orebodies plunge to the southwest, parallel to the intersection of curved foliation with discrete shear planes and sub-perpendicular to local stretching lineations. The Muriel orebodies plunge steeply west but parallel to local stretching lineations. The greatest fluid flow during mineralisation of the shear zone was along either the intersection of fabrics (Golden Kopje) or the extension direction (Muriel). There is no unique relation between the orebodies and the extension or shear direction. Where earlier mining has not established the directions of the oreshoots it is essential to understand the possible structurally controlled geometries of orebodies before planning a drilling programme to evaluate their potential

Apr 1, 1996

By A. K. Tripathy, P. K. Pattnayak, H. S. Ray

The effects of water addition on the solid-state reaction between Cr2O3 and Na2CO3 at low temperatures (up to 873 K) were investigated to determine its possible influence on the reaction rate and the degree of conversion to soluble chromate. Experiments at high temperatures were conducted for comparison. It was found that adding water to the mixture before roasting enhanced both reaction rate and yield significantly. The reactions followed the Lesokhin-Tempelman equation at low temperature and the Ginstling-Brounshtein equation at above 973 K; the respective activation energies were 95 and 22 kJ/mol

Jun 19, 1905

By J. D. T. Capocchi, M. B. Mourao

The rate of reaction between iron oxides and carbonaceous materials, agglomerated as pellets, was studied experimentally by measuring the weight loss as a function of time. The effects of temperature, carbon type, inert gas flow rate, pellet size and additions (sodium. carbonate and Portland cement) were determined. It was shown that the value of the apparent activation energy can display large deviations under different experimental conditions; in the present work it was found to be 226.6 kJ/mol. The reaction with coke is slower than with charcoal, and the rate increases as the flow of inert gas in the reaction vessel decreases. Comparison of the rates for pellets of different sizes has shown that for small pellets the initial rate is faster but that it slows down at high conversions owing to the penetration of inert gas into the pellet. Additions of sodium carbonate and Portland cement increase the rate; sodium. carbonate promotes the catalysis of the Boudouard reaction, which is the slowest of the partial reactions. The increase in the rate with Portland cement is attributed to the release of water vapour

Jun 18, 1905

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. Phases of the Ir sub-group are present either as inclusions in or interstitially to chromite and are unaffected by (or only altered in situ during) hydrothermal processes. By contrast, almost all phases of the Pd sub-group are located in a secondary textural setting - in fractures in chromite or between fragments of brecciated chromite. The different settings indicate that the mineralisation episodes were associated with magmatic and hydrothermal stages respectively. The presence of an included Pd-group mineral in a hydrothermally Pd-group mineralised chromitite sample suggests that the hydrothermal Pd-group minerals were at least partly derived by remobilisation from magmatic deposits in the chromitite pod. These observations indicate that Pd-group elements are more mobile than Ir-group elements under hydrothermal conditions and point to the potential for hydrothermal platinum and palladium mineralisation in favourable environments

Apr 1, 1994

By J Kokado, N Hatta, S Yabushita

A theoretical model is described for prediction of the capacity of fines from porous ores, such as cokes and sintered ores, to be removed by a pneumatic, horizontal-type classifier prior to charging into a blast furnace. First, the influence of variation in the apparent density and drag coefficient of porous ores on removal efficiency is analysed from a stochastic standpoint. The effect on efficiency of collisions between particles in the classifying region is then examined analytically in relation to the ratio of the mass flow rates of particles and air (the loading ratio). Finally, a theoretical model is constructed that takes these factors into account. Theoretical and experimental results are compared and classifying efficiency is discussed from both experimental and theoretical viewpoints.

Dec 1, 1993

By V. A. Melezhik, P. K. Skufin, L. P. Nilsson

these factors into account. Theoretical and

Aug 1, 1994

By P. H. Williams, D. J. Morris

The co-disposal of coarse and fine coal wastes by combined pumping through a pipeline to subaerial deposition was pioneered in Australia in 1990 by Jeebropilly colliery in Queensland. Significant segregation of fines is found to occur in its co-disposal delta, leading to the formation of distinct mainly coarse upper and fine-dominated lower segments; the upper delta drains rapidly and is able to support traffic on its surface immediately after deposition. An existing theory of subaerial deposition, originally developed for mine tailings alone and later extended to trial co-disposal, is shown to apply also to the upper segment of the full-scale Jeebropilly delta

Jun 19, 1905

horizontal-type classifier prior to charging into a blastfurnace.

Apr 1, 1995

By J. S. Duval

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). The compilation of the National Uranium Resource Evaluation aerial gamma-ray data to produce maps of the apparent surface concentrations of potassium, uranium and thorium for the conterminous USA has resulted in a reasonably accurate representation of the distribution of these elements in the surface rocks and soils. This claim is supported by the general agreement between the mapped geology and the patterns seen in the data

Jul 1, 1991

By Seong-Taek Yun, Chil-Sup So, Seung-Jun Youm

The greisen-bordered quartz veins are spatially, temporally and genetically associated with a late Cretaceous granite intruding an early Palaeozoic, limestone-rich formation. Paragenetic data indicate three stages of hydrothermal mineralisation, the first typically in or within 500 m of the granite stock and showing vertical zoning between deeper Mo and higher W, the other two more abundant in the upper and outer parts of the mineralised area. Fluid inclusion and stable isotope data indicate that hydrothermal veins formed over a temperature range of 120-395 degrees C from low-salinity fluids. Early wolframite and molybdenite deposition in stage I occurred at temperatures of 300-395 degrees C from magma-derived, low-salinity, CO2-rich fluid, mainly as a result of fluid boiling and associated CO2 effervescence. Progressively larger volumes of local meteoric water entering the system led to the successive deposition of scheelite in stage I vugs, stage II base-metal sulphides and stage III fluorite-carbonates. Remobilisation of W and its later deposition of scheelite in the outer and shallower portions of the system occurred at 215-275 degrees C and stage II and III mineralisation from lower-temperature fluids that became progressively lighter in stable isotopes. It is concluded that the influx of meteoric water increased with distance from the cooling pluton

Jun 18, 1905