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By A. Gülmez

The complex ore deposit containing fluorite, barite and bastnaesite minerals is located in Beylikova Region of Sivrihisar town of Eskisehir Province of Turkey. The ore contains 40.80% CaF2; 35.35% BaSO4; 2.01%Ce; 1.5% La; 0.39% Nd and 0.1% Th. Barite recovery from this ore by flotation of the HCl leached tailings is presented in this paper. Rare earths are recovered by leaching. The leached residue (tailings) containing fluorite and barite is subjected to froth flotation to recover barite. The effect of pH and collector concentration on the flotation of barite have been studied in this work.

Sep 1, 2012

By A. N. Zagorodnyaya

The results of research on recovery of ammonium perrhenate from by-products of lead production are presented in the article. For the first time in the world, rhenium marketable products were produced on lead plant of Kazakhstan. Distribution of rhenium in lead production has been studied. During oxidative agglomeration of lead charge, 67.43% rhenium is sublimated and at that, 67.27% rhenium is trapped by the dusts of a system of gas purification, out of them 6.21% is transferred into different solutions, 1.89% into slime and only 0.09% into exhaust. During agglomerate smelting, up to 72% of its rhenium is sublimated and condensed in the dusts also. At leaching stage of sulphate product under dusts processing by the method of sulphatization, 15% of its content in the dusts is transferred into solution. The sorption method on the ionite ?N-21 has been proposed for recovery of rhenium from the solutions of sulphatization. At the same time, rhenium recovery from the dusts into commodity was 13%. The method of direct hydrometallurgy - leaching the dusts by solutions of sulphuric acid under presence of manganous concentrates, has been proposed as alternative method of recovery. This method has allowed increasing recovery of rhenium and other metals from the dusts into solution up to 90%~95%. Rhenium solvent extraction by ??? has been proposed for recovery of rhenium from the leaching solutions. At that, extraction of rhenium into marketable product from the dusts is above 75%.

Jan 1, 2014

By X. J. Lu

Purified Na-montmorillonite samples were used as the starting materials to prepare organically modified montmorillonites (OM), and a series of OM samples were prepared by intercalation of al-kyl quaternary ammoniums with different alkyl chain length. The interlayer spacing (d001) of the OM was determined by small angle X-ray diffraction and its gelating performance was characterized by measuring the viscosity of OM/dimethylbenzene mixture. The effects of alkyl chain length, dosage of alkyl ammonium, intercalation duration and layer charge of the starting material on the OM structure and gelating properties were investigated. According to the results, the adsorption quantity of the alkyl ammonium is dependent on the hydrocarbon chain length, the dosage of the alkyl ammonium and the retention time. The adsorption quantity of the alkyl ammonium increases with the chain length and the dosage, and extra adsorption more than the CEC of the montmorillonite sample was observed under the dosages of more than 1.3 CEC. The interlayer spacing (d001) of the OM shows a dynamic variation with the dosage and the retention time, and super interlayer spacings greater than the length of the alkyl ammonium were observed under larger dosages and shorter retention times. However, the gelating performance of OM does not follow the variations of the adsorption quantity of alkyl ammonium, an optimum viscosity value of OM/ dimethylbenzene gel was observed with the moderate adsorption of the alkyl ammoniums. Furthermore, the layer charge plays an important role on the gelating performance of OM. The OM synthesized by the starting material with lower layer charge shows better gelating performance in the dimethylbenzene solution.

Jan 1, 2014

By R. S. Wang

The flotation of pyrite which be pretreated by electrochemical ways under external controlled voltages in different pH is explored. The floatability of pyrite is increased indistinctively after being pretreated in acidic and xanthate environment; Whereas, it is increased obviously between 400~800 millivolt in alkaline and xanthate condition. The reason for higher recovery of pyrite is that oxida-tion reaction, which results in S0 and S02, takes place on its surface, and that ethyl xanthate is oxi-dized into dixanthogen. In the meantime, the kinetics and mechanism is also studied.

Jan 1, 2014

By N. Acarkan

Beneficiation of the pyrite concentrate of the Kastomonu-Küre (Northern Turkey) copper ore seems to be attractive due to its high Cu, Co, and Zn contents. Pyrite concentrate were used in the experimental studies. Cu, Co, and Zn were recovered from the concentrate by the sulphatizing roasting, leaching and the precipitation using H2S. Sulphatizing roasting experiments were carried out in a rotary furnace and the optimal roasting conditions were found to be at 650°C roasting temperature and 3.0 h roasting period and addition of Na2SO4 of 3 % for the concentrate containing 0.58% Cu, 0.22% Co, and 0.04% Zn. Then, the roasted product was repeatedly leached with 10 g/L H2SO4 solution. Optimal conditions were found to be 60 oC leaching temperature, 2 h leaching period, and 30% pulp density. Leaching efficiencies for Cu and Co were over 99 %. The valuable metals in the pregnant solution were selectively precipitated by H2S as sulfides. Selective precipitation of Cu, Zn, Co was achieved by adjusting the pH and the temperature of the leach solution. Final metal recoveries of 99.20% Cu, 99.40% Co, and 95.60% Zn were attained. The precipitated sulphides are marketable products. Roasting gases with their 15% SO2 content are suitable for the production of H2SO4 and the leach residues can be integrated with the iron ore processing plant as they contain 57.50 % Fe, 17.70% gangue (SiO2, CaO, etc.), 0.04% S, and 0.06% non-ferrous metals.

Jan 1, 2014

This article takes the OMRON C200HE PLC for example introducing its application in mica-paper production equipment, including style selection, address assignment of I/O point, and programming for different function. In the transformation process of simulated data and digit data, the corresponding relations between two data and so on are also discussed.

Jan 1, 2014

By Zhangm Zeqiang, Manman Lu, Hanquan Zhang, Hong Yu, Jintao Fu

"Pelletizing is an important technique in the ironmaking industry. Artificial and natural magnetites are materials that are widely utilized in the iron ore pelletizing process. In this work, the pelletizing characteristics of these two types of magnetite have been investigated in detail. The obtained results shown that in contrast to natural magnetite, the artificial magnetite concentrate exhibits stronger hydrophilicity, lower electronegativity, larger specific surface area, and rougher surface. In addition, the green pellets produced from the artificial magnetite concentrate are characterized by a higher compressive strength as compared to that of the pellets obtained from the natural magnetite concentrate. However, the shock temperature of the artificial magnetite pellets around 255 C is significantly lower than the threshold specified by the industry. The balling characteristics of the material obtained by mixing 20% of the artificial magnetite concentrate with 80% of the natural magnetite concentrate are considerably improved with respect to those of the individual components.INTRODUCTION Pelletization is an essential process of the ironmaking industry in China. Since the pellets produced from iron ore exhibit high mechanical strength, good particle granularity, and uniform shapes, pelletizing high-grade iron ores with good metallurgical reducibility can lower the coke ratio, improve their technico-economic index, and reduce the cost of processing pig iron in blast furnaces[1, 2]. Presently, high-grade magnetite is a material utilized for pelletizing various iron ores across the globe. However, its natural deposits have been depleting rapidly in recent years; as a result[3], China’s dependence on the foreign high-grade iron ores exceeded 70% in 2009 and reached the level of 87% in 2016. Hence, possible methods for the efficient cultivation of limonite, siderite, hematite, and other refractory minerals that correspond to low-grade, finely sized, inhomogeneous, and scattered iron ores have attracted significant attention [4, 5]. In particular, magnetization reduction roasting and magnetic separation techniques, which are widely utilized for obtaining high-grade artificial magnetite, represent effective ways of processing iron ores that can alleviate the scarcity of natural magnetite resources [6, 7]. The artificial magnetite produced by magnetization reduction roasting exhibits different characteristics as compared with those of natural magnetite (including the degree of hydrophilicity, surface potential, specific surface area, and other surface physicochemical properties[8-11], which significantly affect its pelletizing behavior. In this work, the surface characteristics of artificial and natural magnetites are investigated in detail, and their effect on their pelletizing properties (such as green ball strength, heat stability, and pelletization rate) are examined."

Jan 1, 2018

By B. Y. Tuo

This article presents results of studies performed to determine the feasibility of using low-grade limonite ores from Yunnan deposit. Laboratory tests and commercial trials have shown that the magnetic separation can be performed with a high high-grade concentrates. The quality of the preparation concentration meets the requirements for blast-furnace smelting. The results as a whole demonstrate the feasibility of utilizing bank limonite ore. Yunnan limonite?s magnetic separation, roasting magnetic separation and flotation experimental study shows that grade of the ore grade can been from 32.91% heighten to 58.64%, a recovery of iron is 90.87%, productive rate is 51% through orthogonal test optimization; roasting magnetic separation can obtain that the grade of iron preparation concentrate is 61.16%, recovery is 67.39%, productive rate is 36%. As far as economy and enviormental protection is concerned, strong mag-netic suggested a more appropriate process. Keywords: Limonite; Roast; Magnetic separation

Jan 1, 2014

By M. Marinov

The Bulgarian deposits of quartz-kaolin raw materials are localized in the NE Bulgaria. For many years, the quartz-kaolin sand separation has been performing by water washing technology. After wet separation the raw material yields two products ? washed kaolin (different grades) and quartz sand (different grades). Research and development program has started to improve the quartz-kaolin sand separation. The program has undertaken an increasing of processing capacity, to decrease the losses in the tailings and to provide production of new quartz sand grades. The kaolin-silica raw materials from Vetovo open mine and the technological tailings from Vetovo processing plant were characterized. It was established that there are a lot of losses of quartz in final tailings. New approach on kaolin-silica raw material separation was tested in laboratory scale. The test work was performed on Derrick Stacksizer screening machines. The results of laboratory experiment show that there are possibilities to increase the quartz sand recovery and to start the production new grade sand. The full-scale pilot test was performed including the following units: two Derrick Stacksizer screening machines equipped with 0.430 mm and 0.150 mm opening Derrick Urethane Panel, respectively; Flat bottom DN 500 Hydrocyclone and DN 100 Hydrocyclon. The pilot test data clearly demonstrate that the Derrick Stacksizer screening machines are suitable for Bulgarian silica-kaolin raw material. Based on the test data a new quartz-kaolin separation technology was developed. The new technology was introduced in Vetovo processing plant increasing processing capacity and decreasing the losses of quartz in final tailings. Additionally the production of silica sand grade PK 0.16 is increased and starts the production a new grade PK 0.10.

Sep 1, 2012

By A. V. Byvaltsev

Adsorption of cyanide complexes of gold, silver, copper, mercury, nickel, cobalt, iron, zinc and cadmium has been studied. Adsorption isotherms of the mentioned metals from individual solutions for different free cyanide concentrations have been obtained. Values of the constants of Freundlich isotherm equation have been calculated. Metal cyanide complexes affinity to activated carbon was determined.

Jan 1, 2014

By Thenepalli Thriveni, Seong-Young Nam, Nam-Il Um, Joobeom Seo

In the present work, we report a novel microstructure of synthesized scalenohedral PCC (precipitated calcium carbonate) without any additives by a simple and ecofriendly carbonation process carried out in a liquid-gas system on the crystal growth of the scalenohedral calcite phase. Especially, the process parameters of Ca(OH)2 concentration and CO2 flow rates were investigated to enhance the sensitivity of the process. The highest average length of the scalenohedral calcite was obtained at pH 6.0, temperature 450C, Ca(OH)2 concentration 0.2M, CO2 flow rate 80mL/min, and total volume 1L. The utilization of flue gas-derived CO2 from coal fired power plants could be a form of carbon capture and storage using carbonation reaction with scalenohedral PCC. Finally, the synthesized scalenohedral PCC was used as a filer for ONP recycling. We demonstrated all these experiemnts at semi pilot plant scale.

Jan 1, 2014

By Ye Chen, Jianhua Chen, Meng Liu, Yuqiong Li, Xiao Mu, Cuihua Zhao

"Sulfidization-amine is the most effective method for the recovery of smithsonite (ZnCO3), however the interface interaction details remain unclear. The sulfidization-amine flotation mechanism of smithsonite has been studied by Density Functional based Tight Binding (DFTB+) method in this paper. The slab model of ZnCO3 (101) surface was built and the adsorptions of a monolayer of HS- and S2- ions were conducted to model the sulfidization effect on the ZnCO3 (101) surface adsorption. DDA hardly interacts with the hydrated ZnCO3 (101) surface. Under the low concentration of Na2S, HS- ions form a Zn-SH-SH structure on the ZnCO3 (101) surface, which hinders the interaction between DDA and surface Zn atoms. Under the high concentration of Na2S, a layer of ZnS is formed on ZnCO3 (101) surface, which is favorable for the adsorption of DDA on the surface. This is consistent with the flotation practice where smithsonite flotation requires a large amount of sodium sulfide. The results could provide a microscopic investigation into the sulfidization-amine flotation mechanism of smithsonite.INTRODUCTIONSmithsonite (ZnCO3) is an important and typical oxide mineral of zinc. It is a semi-soluble salt mineral with a solubility product constant of 1.46 × 10-10 (Weast, 1973). The most common and effective method to recover oxidized zinc ores is froth flotation (Caproni et al., 1979; Pereia and Peres, 2005; Kashani and Rashchi, 2008). It is well known that the flotation of oxidized zinc minerals is much more difficult than the flotation of zinc sulphide minerals (Hosseini and Forssberg, 2007).The recovery of zinc oxide ores with poor floatability attracts more and more attention due to the depletion of easy-recovered of zinc sulfide ores.Sulfidization-amine flotation, which using Na2S as sufidizing agent and amine as collector (Mckenna et al., 1949; Rey, 1954; Abramov, 1961; Rey, 1979; Hosseini and Forssberg, 2007). This method is the most successful technology used for zinc oxide minerals flotation in large-scale industrial applications since it was invented in the 1950s (Önal et al., 2005; Pereira and Peres, 2005). There have been numerous experimental researches on the sulfidization-amine flotation of smithsonite. Shi et al., (2013) studied solution chemistry of smithsonite flotation system. Feng and Wen (2017) studied the formation of zinc sulfide species on smithsonite surfaces and its response to flotation performance. Wu et al., (2017) investigated the sulfidization behavior of smithsonite with the use of zeta potential, inductively coupled plasma (ICP), scanning electron microscope (SEM), and X-ray photoelectron spectroscopic (XPS). Their measurement results confirms the chemisorption of sulfur ions and the formation of ZnS film on the smithsonite surface after Na2S treatment, however the influence of HS- ions on the surface and the influence of sulfidization on the amine adsorption have not been discussed."

Jan 1, 2018

By S. Z. Shafaei

An experimental investigation has been carried out using a laboratory scale Denver flotation cell. For evaluation of cokeable coal of Alborze Sharghi coal washing plant, the full factorial method was used to statistically design and analyse the experiments. The 2 factorial interaction model were developed for combustible recovery and ash content as response and diesel dosage, conditioning time, feed percent solids and rotor speed as factors. Model validation and residual analysis were con-ducted and results indicated that the fitness, predictability power and residual distributions of models were good. The effect of parameters and interactions were examined and it has been demonstrated that rotor speed, solid percent and interaction between diesel dosage and solid percent were more important terms of all responses. A product with approximately 78% combustible recovery and 10% ash content was obtained at 4000gr/ton diesel fuel oil (high level), 30 sec conditioning time (low level), feed percent solids of 15% (low level) and 800 rpm rotor speed in appropriate condition.

Jan 1, 2014

By M. I. Panayotova

Some of effluents released by copper smelting plants are highly acidic (pH = 0~1) and contain arsenic and copper in relatively high concentrations (10~20 g/L). Usually arsenic is removed by precipitation with different reagents, such as lime, iron salts, calcium salts, aluminium salts, etc. Precipitates (often voluminous) that require further handling are formed and copper and other valuable components are lost. A method is presented for copper and arsenic extraction from acidic effluents. Effluents are treated in specially designed closed electrochemical cell without chemicals? addition. Gases formed are collected and treated for decomposing the eventual traces of As-bearing compounds and ensuring the environment protection. Initially copper of grade of 85 % is electro-won. Further about half of the initially available arsenic is separated as low-soluble, low volume mixture of intermetallic compounds, oxides and some elemental arsenic. At the next stage the main part of the left arsenic is immobilized as low soluble stable compound. Arsenic content in the treated acid is in the range 0.20~0.25 g/L. Acidity of treated effluent after first two stages remains practically unchanged and the solution can be re-used. Physicochemical and electrochemical processes, governing copper and arsenic removal, are discussed.

Jan 1, 2014

By J-P Franzidis, P. O. Gyebi

"Coal-water mixtures (CWM) of concentrated fine coal may be transported in pipelines but this is influenced by both CWM rheology and stability. Here, a low viscosity is required to reduce power requirements, as well as good stability for transport and storage. The objectives of this study are to investigate the importance of surface charge, solids concentration and dispersant addition on the rheology and stability of a fine Witbank coal-water mixture (<75 m). Zeta potential, rheology and stability were measured with a Malvern Zetasizer, a AR1500EA rheometer and a static rod penetration test, respectively. Sendep 30D, Sendep 30F and Norilose 8058, all supplied by Senmin International, were used as dispersants, at dosages of between 0.1 to 0.5% dry coal (w/w). Solids concentration was varied from 10 to 58% (w/w). The zeta potential was found to be positive at low pH and decreased sharply with increasing pH to a minimum of -50 mV at pH 10. The zeta potential decreased with increasing dispersant concentration for all dispersants. The lowest zeta potential of -63 mV was obtained for Norilose 8058 at a dosage of 0.3%. CWM rheology was Newtonian at lower solids concentrations but became non-Newtonian at solids concentrations over 40% (w/w), with an initial yield stress and pseudo plastic behavior. The yield stress decreased sharply with increasing dispersant concentration for all dispersants. The lowest yield stress was obtained for Norilose 8058. The addition of dispersants resulted in significant improvements in stability. A penetration ratio of over 70% was obtained for Norilose 8058 after 10 days. In summary, the addition of dispersants resulted in a decrease in the zeta potential which increased the electrostatic repulsive forces between particles, thus improving both CWM rheology and static stability.INTRODUCTION Coal Water Mixtures South Africa’s energy economy depends heavily on coal. It accounts for about 70% of primary energy consumption, 93% of electricity generation and 30% of liquid petroleum fuels (Eberhard, 2011). The transportation of coal to export markets and power generation stations is a problem in the South African coal industry due to ageing and inefficient rail infrastructure. This problem is intensified by the long distance of coal haulage, delays in the time required to load and unload wagons, and environmental challenges related to air pollution and water contamination. Fine coal may be transported more efficiently and economically in a pipeline as a highly concentrated coal water mixture (CWM). Typically a fine coal CWM will contain 60-75% coal, 25-40% water and nearly 1% of dispersing additives (Atesok et al., 2005; Dincer et al., 2003). However, the transport of CWMs in pipelines is strongly influenced by both CWM rheology and stability. Here, a low viscosity is required to reduce power requirements, as well as good stability for transport and storage. These quantities are affected by the coal composition/mineralogy, solids concentration, particle size and size distribution, particle shape, inter-particle forces and dispersant type and dosage (Laskowski, 2001)."

Jan 1, 2018

By Y. B. Zhu

Soil reconstruction and improvement trials and vegetation experiment is carried out at Shuilong-shan acid rock waste dumps at Dexing Copper Mine in China. pH value, Cu2+, Pb2+, Zn2+, etc. concentration in acid rock drainage (ARD) is also monitored every month since 2005. The results of experiment show that: Lime and topsoil stripped from open-pit is appropriated soil improvement material. Full cover soil improvement method is suitable for flat area, contour soil improvement method and hole soil improvement method is appropriate for slope area. The optimal plant species is ligustrum lucidum Ait,Lespedeza bicolor, Paspalum notatum, Veti-veria zizanioides, Eragrostis pilos and Neyraudia reynaudian. It is the best for Arbor, shrub and grass to be arranged in pairs or groups in order to remold optimal landscape. Pilot sites, covering 3ha, is established. Vegetation coverage reaches 90% in platform area, 40% in slope area. pH value in ARD increased slightly, Cu2+, Pb2+ concentration in ARD decreased, Zn2+ concentration in ARD decreased and varied slightly.

Jan 1, 2014

By Susanna G. de Jager, Francis W. Petersen

"The aim of the project was to develop a methodology applicable to different South African coal types to be able to predict with a high degree of certainty what kind of reagent will be suitable for flotation of a certain coal type.The study included 5 coal samples from different collieries and included Highveld seam 3 and 4 coal (as one sample), Waterberg coal (zone 10 -11), Highveld seam 5 upper coal and Witbank seam 2 and seam 4 coal. Seam 3 and 4 (mixture) coal, Waterberg and the seam 5 upper coal were all found to be vitrinite rich coals. The coal characterisation study included petrographic analysis, proximate analysis, float-sink analysis, oxygen-containing functional groups, surface extraction, flotation release analysis and contact angle measurements.The flotation tests showed that the best reagents to float all of the coal samples studied are iso-decanol and dodecene. These reagents produced flotation products that are near to the release curve. Statistical relationship for predicting ash content and yield that can be expected for a certain coal type and selected collector was obtained. From the relationship, the accuracy of the yield is above 95% (p-value below 0.05) with a linear regression of 0.9289. The accuracy of the ash is slightly lower with a linear regression of 0.7841 but also above 95%."

Jan 1, 2003

Calaverite is a gold telluride found in the Kalgoorlie region, Fiji, Cripple Creek Colorado and numerous other locations. It is known that a high pH is necessary for calaverite cyanidation, with the leach rate increasing substantially above pH 12 due to the hydroxide ion concentration. In most circumstances lime is used to achieve high pH, however lime saturates at approximately pH 12, limiting the maximum pH obtainable in a critical region for calaverite leaching. Plant observations, laboratory experiments and thermodynamic modelling show that the maxi-mum hydroxide ion concentration that can be achieved with lime (CaO) is strongly dependent on common ions. The presence of calcium, as commonly found in saline waters, substantially diminishes the maximum pH that can be obtained with lime. Conversely the presence of sulfate ions, as generated through oxidation of sulfides, substantially increases the maximum pH that can be achieved with lime. Sulfide oxidation during cyanide leaching of complex ores may generate acid and sulfate ions, making overdosing with lime at the front of the circuit, or staged addition down the leach train, important to maintaining the maximum hydroxide concentration.

Jan 1, 2014

By Long Han, Jianyuan Liu, Ping Ying

"Particle-bed compressive stressing is the main work mechanism of comminution by high pressure grinding rolls(HPGR). An experimental study on comminution and mineral liberation of two copper sulfide ores was carried out using a piston-die compressive stressing rig to simulate the situation of comminution with HPGR as the final-grinding device. The tests carried out include compressive comminution tests on particle-bed with narrow-size feed, and the locked-cycle comminution test on particle-bed with broad-size feed, which was then compared to a corresponding locked-cycle test of ball-mill grinding. The narrow-size feed is made up of particles in the size range 2.36~3.35 mm, whereas the broad-size feed of particles in the size range 0~3.35 mm. The liberation analysis for copper-mineral in the comminution products was accomplished using BPMA system – an automatic mineral liberation analyzer developed by BGRIMM. The influences of the stressing intensity and the method of comminution on the copper mineral liberation are discussed in terms of product size distribution, copper-metal deportation among size fractions, distribution of copper mineral among particle-size and particle-grade classes, degree of mineral liberation in size class as well as degree of mineral liberation overall.INTRODUCTION Traditionally, comminution process commonly applied in mineral processing is a flowsheet consisting of crushing of crude ore with conventional crushers, followed by grinding of the crushed ore in tumbling mills. In last decades, the energy-efficient HPGR (high-pressure grinding rolls) has found its application in mineral processing, mostly as tertiary or quaternary crusher to generate a fine-crushed product either as feed to subsequent grinding or as feed to a pre-beneficiation process before further grinding. Compared with the process of conventional crushing followed by grinding in ball mill, this mode of HPGR-application can achieve energy saving to some extent by reducing particle size of the feed to ball milling, and by reducing amount of the feed to ball milling if a significant portion of tailings in relatively coarse particle-size range can be discarded at the pre-beneficiation stage. In recent years, the approaches of letting HPGR take more comminution work from ball mill by applying it in semi-finish grinding mode or even finish grinding mode have been discussed (Burchardt, 2014). Although HPGR finish-grinding has been successfully applied in the cement industry for grinding of cement clinker and raw materials, this mode of HPGR application has yet rarely been implemented in mineral processing, despite the advantage of more energy-saving and other potential benefits such as preferential breakage, internal damage of particles and enhanced mineral liberation which may lead to a better downstream processing performance. The reasons for the retardation of the progress of this kind of HPGR-application in the mineral industry lies not only in that a finish-grinding with HPGR has to be operated in dry condition whereas most of ore-beneficiation processes like flotation are operated in wet condition, but also in that there are large variety of ore materials with various complexity of processing technology, which need to be addressed on a case-by-case basis with a lot of test work, in order to evaluate the potential advantages or disadvantages of this application."

Jan 1, 2018

By Y. M. Zhu

Lead in environment often causes a serious health hazard. The removal of Pb2+ from aqueous phase is a beneficial project. In this paper, deposited Saccharomyces cerevisiae (S.c.) was chosen as adsorbent, Pb2+ ions as adsorbate, and the process of biosorption was studied. The dynamics of the adsorption was investigated. The adsorption mechanism of Pb2+ by S.c. cells was also investigated by detecting microstructure, zeta potential under different pH value, FT-IR spectra of the S.c. particles before and after biosorption. It was shown that the biosorption of Pb2+ by deposited S. c. is a rapid process, and the adsorbing equilibrium is reached within 10 minutes. The Zero point of zeta potential of S.c. cells is pH=3.3. When 2.0<pH<3.3, there exists biosorption (biosorption rate 76%~88%), which means static bio-sorption been not the only kind of biosorption. FT-IR spectrum analysis showed that groups on bacteria surface were mainly characteristic groups of protein and amylase; oxo-groups and nitric-groups on S.c. cell surface could chelate with heavy metal ions. Chemical adsorption might exist in the process.

Jan 1, 2014